WO2008123199A1 - 可溶性多官能ビニル芳香族共重合体及びその製造方法 - Google Patents
可溶性多官能ビニル芳香族共重合体及びその製造方法 Download PDFInfo
- Publication number
- WO2008123199A1 WO2008123199A1 PCT/JP2008/055447 JP2008055447W WO2008123199A1 WO 2008123199 A1 WO2008123199 A1 WO 2008123199A1 JP 2008055447 W JP2008055447 W JP 2008055447W WO 2008123199 A1 WO2008123199 A1 WO 2008123199A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- meth
- polyfunctional vinyl
- aromatic compound
- acrylic acid
- acid ester
- Prior art date
Links
- 229920001577 copolymer Polymers 0.000 title abstract 6
- 229920002554 vinyl polymer Polymers 0.000 title abstract 5
- 238000004519 manufacturing process Methods 0.000 title 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 abstract 5
- -1 divinyl aromatic compound Chemical class 0.000 abstract 4
- KAKZBPTYRLMSJV-UHFFFAOYSA-N vinyl-ethylene Natural products C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 abstract 4
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 abstract 3
- 239000000470 constituent Substances 0.000 abstract 3
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 abstract 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 abstract 2
- 150000001491 aromatic compounds Chemical class 0.000 abstract 2
- SCYULBFZEHDVBN-UHFFFAOYSA-N 1,1-Dichloroethane Chemical compound CC(Cl)Cl SCYULBFZEHDVBN-UHFFFAOYSA-N 0.000 abstract 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 abstract 1
- 230000001588 bifunctional effect Effects 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 abstract 1
- 238000005979 thermal decomposition reaction Methods 0.000 abstract 1
- 239000008096 xylene Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F212/02—Monomers containing only one unsaturated aliphatic radical
- C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
- C08F212/06—Hydrocarbons
- C08F212/08—Styrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F212/34—Monomers containing two or more unsaturated aliphatic radicals
- C08F212/36—Divinylbenzene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/40—Esters of unsaturated alcohols, e.g. allyl (meth)acrylate
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
高温での熱履歴に対しても優れた耐熱分解性を有し、硬化性、加工性に優れる制御された分子量分布と溶剤可溶性を兼ね備えた可溶性多官能ビニル芳香族共重合体を提供する。 この可溶性多官能ビニル芳香族共重合体は、ジビニル芳香族化合物、モノビニル芳香族化合物及び（メタ）アクリル酸エステルを共重合して得られ、ジビニル芳香族化合物の構造単位、モノビニル芳香族化合物の構造単位及び（メタ）アクリル酸エステルの構造単位を有し、Ｍｎが５００～１，０００，０００であり、Ｍｗ／Ｍｎが５０．０以下であり、トルエン、キシレン、テトラヒドロフラン、ジクロロエタン又はクロロホルムに可溶である。また、ジビニル芳香族化合物と（メタ）アクリル酸エステルの代わりに、両方の特性を備える２官能（メタ）アクリル酸エステルを使用した可溶性多官能ビニル芳香族共重合体を開示する。
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2009509096A JP5406709B2 (ja) | 2007-03-26 | 2008-03-24 | 可溶性多官能ビニル芳香族共重合体及びその製造方法 |
| CN2008800094694A CN101641380B (zh) | 2007-03-26 | 2008-03-24 | 可溶性多官能乙烯基芳香族共聚物及其制造方法 |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2007-079413 | 2007-03-26 | ||
| JP2007079413 | 2007-03-26 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO2008123199A1 true WO2008123199A1 (ja) | 2008-10-16 |
Family
ID=39830696
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/JP2008/055447 WO2008123199A1 (ja) | 2007-03-26 | 2008-03-24 | 可溶性多官能ビニル芳香族共重合体及びその製造方法 |
Country Status (4)
| Country | Link |
|---|---|
| JP (1) | JP5406709B2 (ja) |
| KR (1) | KR101469592B1 (ja) |
| CN (2) | CN102718914B (ja) |
| WO (1) | WO2008123199A1 (ja) |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2008239781A (ja) * | 2007-03-27 | 2008-10-09 | Nippon Steel Chem Co Ltd | 可溶性多官能ビニル芳香族共重合体の製造方法及びその共重合体 |
| WO2009110453A1 (ja) * | 2008-03-04 | 2009-09-11 | 新日鐵化学株式会社 | 多官能ビニル芳香族共重合体、その製造方法及び樹脂組成物 |
| JP2011127008A (ja) * | 2009-12-18 | 2011-06-30 | Nippon Steel Chem Co Ltd | 脂環式構造を有する可溶性多官能（メタ）アクリル酸エステル共重合体及びその製造方法 |
| WO2011105473A1 (ja) * | 2010-02-26 | 2011-09-01 | 新日鐵化学株式会社 | 硬化性樹脂組成物、その硬化物並びに光学材料 |
| JP2011207968A (ja) * | 2010-03-29 | 2011-10-20 | Nippon Steel Chem Co Ltd | アルコール性水酸基を有する可溶性多官能（メタ）アクリル酸エステル共重合体及びその製造方法 |
| JP2012184344A (ja) * | 2011-03-07 | 2012-09-27 | Nippon Steel Chem Co Ltd | 脂環式構造を有する可溶性多官能（メタ）アクリル酸エステル共重合体、硬化性樹脂組成物、硬化物及び光学材料 |
| JP2012530836A (ja) * | 2009-06-22 | 2012-12-06 | ユニリーバー・ピーエルシー | 分岐ポリマー分散剤 |
| WO2013069077A1 (ja) * | 2011-11-07 | 2013-05-16 | 新日鉄住金化学株式会社 | 高分岐型超高分子量体を含有するスチレン系樹脂組成物の製造方法およびその組成物 |
| EP3858877A4 (en) * | 2018-09-28 | 2022-05-25 | NIPPON STEEL Chemical & Material Co., Ltd. | MULTIFUNCTIONAL AROMATIC VINYL COPOLYMER AND METHOD FOR MAKING IT, COPOLYMER RUBBER OBTAINED THEREfrom, RUBBER COMPOSITION, RUBBER RETICULATE MATERIAL, AND PNEUMATIC PART |
| JP7571456B2 (ja) | 2020-10-19 | 2024-10-23 | 株式会社レゾナック | 極性基含有２－アルケニルモノマー共重合体及びその製造方法、並びに酸素バリア性積層体 |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101841595B1 (ko) * | 2011-03-07 | 2018-03-23 | 신닛테츠 수미킨 가가쿠 가부시키가이샤 | 지환식 구조를 가지는 가용성 다관능 (메타)아크릴산에스테르 공중합체, 경화성 수지 조성물, 및 경화물 |
| TW201329618A (zh) * | 2011-09-26 | 2013-07-16 | Nippon Steel & Sumikin Chem Co | 感光性樹脂組成物及乾膜阻劑 |
| CN107108782B (zh) * | 2014-12-26 | 2019-12-03 | 日铁化学材料株式会社 | 末端改性可溶性多官能乙烯基芳香族共聚合物及其应用 |
| EP3536723B1 (en) * | 2016-11-01 | 2023-01-25 | NIPPON STEEL Chemical & Material Co., Ltd. | Copolymer rubber and method for producing same, and crosslinked rubber composition |
| CN109385021A (zh) * | 2017-08-04 | 2019-02-26 | 广东生益科技股份有限公司 | 一种热固性树脂组合物及使用其制作的半固化片与覆金属箔层压板 |
| CN111620982B (zh) * | 2020-06-04 | 2023-02-10 | 南亚新材料科技股份有限公司 | 热固性树脂组合物及使用其制作的粘结片、覆金属箔层压板与印刷线路板 |
| CN114516962B (zh) * | 2020-11-19 | 2024-04-26 | 北京鼎材科技有限公司 | 一种高透光敏树脂及使用其的彩色光敏树脂组合物 |
| CN114276627B (zh) * | 2021-11-30 | 2024-08-23 | 南亚新材料科技股份有限公司 | 含乙烯基共聚物的热固性树脂组合物及其应用 |
| TWI845083B (zh) | 2022-12-23 | 2024-06-11 | 財團法人工業技術研究院 | 具有乙烯基的共聚物與樹脂組成物 |
| CN116063606A (zh) * | 2023-03-21 | 2023-05-05 | 世名(苏州)新材料研究院有限公司 | 一种高频高速ccl用乙烯基树脂及其制备方法 |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0892322A (ja) * | 1994-07-28 | 1996-04-09 | Nippon Steel Chem Co Ltd | 樹脂架橋体 |
| JPH08176240A (ja) * | 1994-12-26 | 1996-07-09 | Hitachi Chem Co Ltd | 透明樹脂、その製造法及びプラスチックレンズ |
| JPH08208746A (ja) * | 1994-10-28 | 1996-08-13 | Sumitomo Chem Co Ltd | メタクリル酸メチル系重合体 |
| JPH10330425A (ja) * | 1997-05-30 | 1998-12-15 | Mitsubishi Rayon Co Ltd | スチレン系樹脂用加工助剤およびそれを用いたスチレン系樹脂組成物 |
| JP2000128908A (ja) * | 1998-10-23 | 2000-05-09 | Daicel Chem Ind Ltd | スチレン系重合体及びその製造方法 |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2294467A (en) * | 1940-07-20 | 1942-09-01 | Fleetwings Inc | Landing gear |
| JPH04252213A (ja) * | 1990-12-26 | 1992-09-08 | Akira Matsumoto | （メタ）アクリロイル基を側鎖に有するビニル重合体の製造法 |
| JPH09286822A (ja) * | 1996-04-24 | 1997-11-04 | Mitsui Toatsu Chem Inc | 熱硬化性樹脂 |
| JP4507381B2 (ja) * | 2000-10-11 | 2010-07-21 | 日油株式会社 | 脱架橋型樹脂の製造方法 |
| JP4338951B2 (ja) * | 2002-10-01 | 2009-10-07 | 新日鐵化学株式会社 | 可溶性多官能ビニル芳香族共重合体及びその重合方法 |
| WO2005073264A1 (ja) * | 2004-01-30 | 2005-08-11 | Nippon Steel Chemical Co., Ltd. | 硬化性樹脂組成物 |
| JP4717358B2 (ja) * | 2004-01-30 | 2011-07-06 | 新日鐵化学株式会社 | 可溶性多官能ビニル芳香族重合体の製造方法 |
| CN101137940B (zh) * | 2005-03-08 | 2010-08-25 | 新日铁化学株式会社 | 体相位全息图记录用感光性树脂组合物和使用了其的光信息记录介质 |
-
2008
- 2008-03-24 KR KR1020097021460A patent/KR101469592B1/ko not_active Expired - Fee Related
- 2008-03-24 WO PCT/JP2008/055447 patent/WO2008123199A1/ja active Application Filing
- 2008-03-24 CN CN201210208954.2A patent/CN102718914B/zh not_active Expired - Fee Related
- 2008-03-24 JP JP2009509096A patent/JP5406709B2/ja not_active Expired - Fee Related
- 2008-03-24 CN CN2008800094694A patent/CN101641380B/zh not_active Expired - Fee Related
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0892322A (ja) * | 1994-07-28 | 1996-04-09 | Nippon Steel Chem Co Ltd | 樹脂架橋体 |
| JPH08208746A (ja) * | 1994-10-28 | 1996-08-13 | Sumitomo Chem Co Ltd | メタクリル酸メチル系重合体 |
| JPH08176240A (ja) * | 1994-12-26 | 1996-07-09 | Hitachi Chem Co Ltd | 透明樹脂、その製造法及びプラスチックレンズ |
| JPH10330425A (ja) * | 1997-05-30 | 1998-12-15 | Mitsubishi Rayon Co Ltd | スチレン系樹脂用加工助剤およびそれを用いたスチレン系樹脂組成物 |
| JP2000128908A (ja) * | 1998-10-23 | 2000-05-09 | Daicel Chem Ind Ltd | スチレン系重合体及びその製造方法 |
Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2008239781A (ja) * | 2007-03-27 | 2008-10-09 | Nippon Steel Chem Co Ltd | 可溶性多官能ビニル芳香族共重合体の製造方法及びその共重合体 |
| WO2009110453A1 (ja) * | 2008-03-04 | 2009-09-11 | 新日鐵化学株式会社 | 多官能ビニル芳香族共重合体、その製造方法及び樹脂組成物 |
| JP5315334B2 (ja) * | 2008-03-04 | 2013-10-16 | 新日鉄住金化学株式会社 | 多官能ビニル芳香族共重合体、その製造方法及び樹脂組成物 |
| US8404797B2 (en) | 2008-03-04 | 2013-03-26 | Nippon Steel Chemical Co., Ltd. | Polyfunctional vinyl aromatic copolymer, process for producing the same, and resin composition |
| JP2012530836A (ja) * | 2009-06-22 | 2012-12-06 | ユニリーバー・ピーエルシー | 分岐ポリマー分散剤 |
| JP2011127008A (ja) * | 2009-12-18 | 2011-06-30 | Nippon Steel Chem Co Ltd | 脂環式構造を有する可溶性多官能（メタ）アクリル酸エステル共重合体及びその製造方法 |
| WO2011105473A1 (ja) * | 2010-02-26 | 2011-09-01 | 新日鐵化学株式会社 | 硬化性樹脂組成物、その硬化物並びに光学材料 |
| JP5281710B2 (ja) * | 2010-02-26 | 2013-09-04 | 新日鉄住金化学株式会社 | 硬化性樹脂組成物、その硬化物並びに光学材料 |
| US8853291B2 (en) | 2010-02-26 | 2014-10-07 | Nippon Steel & Sumikin Chemical Co., Ltd. | Curable resin composition, cured article thereof, and optical material |
| JP2011207968A (ja) * | 2010-03-29 | 2011-10-20 | Nippon Steel Chem Co Ltd | アルコール性水酸基を有する可溶性多官能（メタ）アクリル酸エステル共重合体及びその製造方法 |
| JP2012184344A (ja) * | 2011-03-07 | 2012-09-27 | Nippon Steel Chem Co Ltd | 脂環式構造を有する可溶性多官能（メタ）アクリル酸エステル共重合体、硬化性樹脂組成物、硬化物及び光学材料 |
| WO2013069077A1 (ja) * | 2011-11-07 | 2013-05-16 | 新日鉄住金化学株式会社 | 高分岐型超高分子量体を含有するスチレン系樹脂組成物の製造方法およびその組成物 |
| EP3858877A4 (en) * | 2018-09-28 | 2022-05-25 | NIPPON STEEL Chemical & Material Co., Ltd. | MULTIFUNCTIONAL AROMATIC VINYL COPOLYMER AND METHOD FOR MAKING IT, COPOLYMER RUBBER OBTAINED THEREfrom, RUBBER COMPOSITION, RUBBER RETICULATE MATERIAL, AND PNEUMATIC PART |
| JP7571456B2 (ja) | 2020-10-19 | 2024-10-23 | 株式会社レゾナック | 極性基含有２－アルケニルモノマー共重合体及びその製造方法、並びに酸素バリア性積層体 |
Also Published As
| Publication number | Publication date |
|---|---|
| KR101469592B1 (ko) | 2014-12-05 |
| CN101641380B (zh) | 2013-09-25 |
| JP5406709B2 (ja) | 2014-02-05 |
| CN101641380A (zh) | 2010-02-03 |
| CN102718914A (zh) | 2012-10-10 |
| CN102718914B (zh) | 2015-04-22 |
| JPWO2008123199A1 (ja) | 2010-07-15 |
| KR20100015575A (ko) | 2010-02-12 |
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