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WO2018196032A1 - Détergent de chasse d'eau et procédé pour sa préparation - Google Patents

Détergent de chasse d'eau et procédé pour sa préparation Download PDF

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Publication number
WO2018196032A1
WO2018196032A1 PCT/CN2017/083429 CN2017083429W WO2018196032A1 WO 2018196032 A1 WO2018196032 A1 WO 2018196032A1 CN 2017083429 W CN2017083429 W CN 2017083429W WO 2018196032 A1 WO2018196032 A1 WO 2018196032A1
Authority
WO
WIPO (PCT)
Prior art keywords
parts
paste
detergent
toilet
stirring
Prior art date
Application number
PCT/CN2017/083429
Other languages
English (en)
Chinese (zh)
Inventor
龚彩萍
Original Assignee
龚彩萍
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 龚彩萍 filed Critical 龚彩萍
Publication of WO2018196032A1 publication Critical patent/WO2018196032A1/fr

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J131/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid, or of a haloformic acid; Adhesives based on derivatives of such polymers
    • C09J131/02—Homopolymers or copolymers of esters of monocarboxylic acids
    • C09J131/04—Homopolymers or copolymers of vinyl acetate
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02—Non-macromolecular additives
    • C09J11/04—Non-macromolecular additives inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02—Non-macromolecular additives
    • C09J11/06—Non-macromolecular additives organic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J129/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal, or ketal radical; Adhesives based on hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Adhesives based on derivatives of such polymers
    • C09J129/02—Homopolymers or copolymers of unsaturated alcohols
    • C09J129/04—Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2237—Oxides; Hydroxides of metals of titanium
    • C08K2003/2241—Titanium dioxide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
    • C08K2003/3009—Sulfides
    • C08K2003/3036—Sulfides of zinc
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
    • C08K2003/3045—Sulfates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/08—Stabilised against heat, light or radiation or oxydation

Definitions

  • the invention relates to a cleaning agent, in particular to a cleaning agent for a toilet bowl and a preparation method thereof.
  • the toilet After using the toilet every time, if only the tap water is used to flush the toilet, not only can the bacteria in the toilet be cleaned, but also the toilet taste is difficult to eliminate.
  • the toilet cleaner When using the toilet cleaner, the toilet can be kept bright and clean, and the odor can be quickly removed.
  • the conventional toilet cleaning agent has poor durability, bactericidal effect is not obvious, and the effective substances in the storage process are easily decomposed, and the conventional cleaning agent for the toilet generally contains the finished phosphorus product, which causes certain pollution to the natural environment.
  • a detergent for a toilet bowl comprising 5-7 parts by weight of water, 4-6 parts of sodium petroleum sulfonate, 26-30 parts of sodium dodecylbenzenesulfonate, and a blue dye. 6-10 parts, 11-13 parts of sustained release excipient, 0.9-1.5 parts of inorganic nano antibacterial powder, 35-40 parts of imidazoline, and 1.5-3.5 parts of trimethylolpropane.
  • the sustained release excipient is a mixture of xanthan gum and stearic acid.
  • the inorganic nano antibacterial powder is a commercially available transparent paste composed of a zinc salt, nano titanium dioxide, and silicon oxide.
  • the scent of the modified nano-fragrance may be a spice such as pine, pine, grass or the like.
  • the invention also provides a preparation method of the above-mentioned toilet cleaner, comprising the following steps:
  • Step 1 Accurately weigh the tap water, put it into a stainless steel bucket, add sodium petroleum sulfonate while stirring slowly, and then dissolve the solid sodium sulfonate solid, then slowly pour it into the kneading machine with stirring heating device, under slow stirring Adding sodium dodecylbenzene sulfonate, at this time, a chemical reaction occurs in the kneader and generates heat.
  • the blue dye, the diluted excipient, and the inorganic nano antibacterial powder are sequentially added in the hot state, and the heating temperature in the kneader is maintained at 40. -80 ° C, stirring and kneading time is 0.5-1 h, and then naturally cooled to prepare a paste-like preform cleaning paste;
  • Step 2 Add nano-fragrance, original name powder in a kneading machine containing a paste-like pre-form cleaning paste, Stirring was continued for 30 min until the paste was uniform and then processed into a finished product.
  • the cleaning agent for toilets of the invention releases effective substances in water, and achieves the effects of deodorization, scale inhibition and bacteriostasis during flushing.
  • This product is a phosphorus-free formula and does not cause secondary pollution to the environment.
  • Detergent cleaner including 5 parts by weight of water, 4 parts of sodium petroleum sulfonate, 26 parts of sodium dodecylbenzene sulfonate, 6 parts of blue dye, 11 parts of slow release excipient, inorganic nano antibacterial powder 0.9 Parts, 35 parts of imidazoline and 1.5 parts of trimethylolpropane.
  • the sustained release excipient is a mixture of xanthan gum and stearic acid;
  • the inorganic nano antibacterial powder is a commercially available transparent paste composed of zinc salt, nano titanium dioxide and silicon oxide;
  • the fragrance of the modified nano essence The type may be a spice such as pine, pine, grass or the like.
  • the preparation method of the cleaning agent for toilets of the present invention comprises the following steps:
  • Step 1 Accurately weigh the tap water, put it into a stainless steel bucket, add sodium petroleum sulfonate while stirring slowly, and then dissolve the solid sodium sulfonate solid, then slowly pour it into the kneading machine with stirring heating device, under slow stirring Adding sodium dodecylbenzene sulfonate, at this time, a chemical reaction occurs in the kneader and generates heat.
  • the blue dye, the diluted excipient, and the inorganic nano antibacterial powder are sequentially added while maintaining the heating temperature in the kneader at 70. °C, stirring and kneading time is 0.5h, and then naturally cooled to form a paste-like preform cleaning paste;
  • Step 2 Add nano-flavor and original powder in a kneading machine containing a paste-like pre-form cleaning paste, and continue stirring for 30 minutes until the paste is uniform, and then processed into a finished product.
  • the toilet cleaning agent is put into the toilet tank, avoid blocking the water outlet.
  • the toilet cleaner is partially dissolved in the water tank. Press the pump button after each use of the toilet.
  • the surface of the flushed toilet bowl is clean and free of stains. ,odorless.
  • Detergent cleaner 6 parts by weight of water, 4 parts of sodium petroleum sulfonate, 30 parts of sodium dodecyl benzene sulfonate, 8 parts of blue dye, 12 parts of slow release excipient, inorganic nano antibacterial powder 1 Parts, 38 parts of imidazoline and 2 parts of trimethylolpropane.
  • the sustained release excipient is a mixture of xanthan gum and stearic acid;
  • the inorganic nano antibacterial powder is a commercially available transparent paste composed of zinc salt, nano titanium dioxide and silicon oxide;
  • the fragrance of the modified nano essence The type may be a spice such as pine, pine, grass or the like.
  • the preparation method of the cleaning agent for toilets of the present invention comprises the following steps:
  • Step 1 Accurately weigh the tap water, put it into a stainless steel bucket, add sodium petroleum sulfonate while stirring slowly, and then dissolve the solid sodium sulfonate solid, then slowly pour it into the kneading with stirring heating device.
  • sodium dodecylbenzene sulfonate is added.
  • a chemical reaction occurs in the kneader and generates heat.
  • the blue dye, the diluted excipient, and the inorganic nano antibacterial powder are sequentially added while maintaining the kneading.
  • the heating temperature in the machine is 40 ° C
  • the stirring and kneading time is 1 h, and then naturally cooled to prepare a paste pre-form cleaning paste;
  • Step 2 Add nano-flavor and original powder in a kneading machine containing a paste-like pre-form cleaning paste, and continue stirring for 30 minutes until the paste is uniform, and then processed into a finished product.
  • the toilet cleaning agent is put into the toilet tank, avoid blocking the water outlet.
  • the toilet cleaner is partially dissolved in the water tank. Press the pump button after each use of the toilet.
  • the surface of the flushed toilet bowl is clean and free of stains. ,odorless.
  • Detergent cleaner 7 parts by weight of water, 4 parts of sodium petroleum sulfonate, 27 parts of sodium dodecyl benzene sulfonate, 8 parts of blue dye, 13 parts of slow release excipient, inorganic nano antibacterial powder 1.2 Parts, 38 parts of imidazoline and 3 parts of trimethylolpropane.
  • the sustained release excipient is a mixture of xanthan gum and stearic acid;
  • the inorganic nano antibacterial powder is a commercially available transparent paste composed of zinc salt, nano titanium dioxide and silicon oxide;
  • the fragrance of the modified nano essence The type may be a spice such as pine, pine, grass or the like.
  • the preparation method of the cleaning agent for toilets of the present invention comprises the following steps:
  • Step 1 Accurately weigh the tap water, put it into a stainless steel bucket, add sodium petroleum sulfonate while stirring slowly, and then dissolve the solid sodium sulfonate solid, then slowly pour it into the kneading machine with stirring heating device, under slow stirring Adding sodium dodecylbenzene sulfonate, at this time, a chemical reaction occurs in the kneader and generates heat.
  • the blue dye, the diluted excipient, and the inorganic nano antibacterial powder are sequentially added while maintaining the heating temperature in the kneader at 70. °C, stirring and kneading time is 1h, then naturally cooled to make a paste-like preform cleaning paste;
  • Step 2 Add nano-flavor and original powder in a kneading machine containing a paste-like pre-form cleaning paste, and continue stirring for 30 minutes until the paste is uniform, and then processed into a finished product.
  • the toilet cleaning agent is put into the toilet tank, avoid blocking the water outlet.
  • the toilet cleaner is partially dissolved in the water tank. Press the pump button after each use of the toilet.
  • the surface of the flushed toilet bowl is clean and free of stains. ,odorless.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Adhesives Or Adhesive Processes (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Detergent Compositions (AREA)

Abstract

L'invention concerne un détergent de chasse d'eau et un procédé pour sa préparation. Le détergent de chasse d'eau comprend, en parties en poids : 5-7 parties d'eau, 4-6 parties de sulfonate de sodium de pétrole, 26-30 parties de dodécylbenzènesulfonate de sodium, 6-10 parties d'un colorant bleu, 11-13 parties d'un excipient à libération prolongée, 0,9-1,5 partie d'une poudre antibactérienne nanométrique inorganique, 35-40 parties d'imidazoline et 1,5-3,5 parties de triméthylolpropane. Le détergent décrit libère des substances actives dans l'eau, ce qui permet d'obtenir des effets de désodorisation, d'inhibition de tartre et de bactériostase pendant le rinçage et est exempt de phosphore et ne provoque pas de pollution secondaire dans l'environnement.
PCT/CN2017/083429 2017-04-27 2017-05-08 Détergent de chasse d'eau et procédé pour sa préparation WO2018196032A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN201710287119.5A CN107057608A (zh) 2017-04-27 2017-04-27 一种白乳胶黏合剂及其制备方法
CN201710287119.5 2017-04-27

Publications (1)

Publication Number Publication Date
WO2018196032A1 true WO2018196032A1 (fr) 2018-11-01

Family

ID=59604665

Family Applications (2)

Application Number Title Priority Date Filing Date
PCT/CN2017/083430 WO2018196033A1 (fr) 2017-04-27 2017-05-08 Adhésif de latex blanc et son procédé de préparation
PCT/CN2017/083429 WO2018196032A1 (fr) 2017-04-27 2017-05-08 Détergent de chasse d'eau et procédé pour sa préparation

Family Applications Before (1)

Application Number Title Priority Date Filing Date
PCT/CN2017/083430 WO2018196033A1 (fr) 2017-04-27 2017-05-08 Adhésif de latex blanc et son procédé de préparation

Country Status (2)

Country Link
CN (1) CN107057608A (fr)
WO (2) WO2018196033A1 (fr)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109943261A (zh) * 2018-11-03 2019-06-28 上海贝尔化工有限公司 一种无甲醛木材压板胶及其制备工艺

Citations (5)

* Cited by examiner, † Cited by third party
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CN1690182A (zh) * 2004-04-27 2005-11-02 天津科技大学 抽水马桶清洁剂
CN102260598A (zh) * 2011-06-24 2011-11-30 东莞爱屋氏日用品有限公司 一种杀菌洁厕块
CN102367399A (zh) * 2011-05-25 2012-03-07 王国松 卫生泡泡
CN103266024A (zh) * 2013-05-24 2013-08-28 苏州富通高新材料科技股份有限公司 多用途杀菌清洁剂
CN106906055A (zh) * 2017-04-27 2017-06-30 龚彩萍 一种抽水马桶用清洁剂及其制备方法

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CN101037578A (zh) * 2007-04-30 2007-09-19 湖南神力实业有限公司 一种纳米防霉快干白乳胶及其制备方法
JP2009046542A (ja) * 2007-08-16 2009-03-05 Koyo Sangyo Co Ltd パテ組成物及びこれを用いて補修した化粧合板
CN101402835B (zh) * 2008-01-25 2010-12-15 盐城华贸包装有限公司 一种纸制品包装白乳胶粘合剂
CN102485820A (zh) * 2010-12-06 2012-06-06 圣象实业（江苏）有限公司 一种环保高粘度白乳胶及其制备方法
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CN1690182A (zh) * 2004-04-27 2005-11-02 天津科技大学 抽水马桶清洁剂
CN102367399A (zh) * 2011-05-25 2012-03-07 王国松 卫生泡泡
CN102260598A (zh) * 2011-06-24 2011-11-30 东莞爱屋氏日用品有限公司 一种杀菌洁厕块
CN103266024A (zh) * 2013-05-24 2013-08-28 苏州富通高新材料科技股份有限公司 多用途杀菌清洁剂
CN106906055A (zh) * 2017-04-27 2017-06-30 龚彩萍 一种抽水马桶用清洁剂及其制备方法

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Title
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Also Published As

Publication number Publication date
CN107057608A (zh) 2017-08-18
WO2018196033A1 (fr) 2018-11-01

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