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WO2018171252A1 - Composition pesticide contenant de la benzisothiazolinone et du thidiazuron - Google Patents

Composition pesticide contenant de la benzisothiazolinone et du thidiazuron Download PDF

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Publication number
WO2018171252A1
WO2018171252A1 PCT/CN2017/113936 CN2017113936W WO2018171252A1 WO 2018171252 A1 WO2018171252 A1 WO 2018171252A1 CN 2017113936 W CN2017113936 W CN 2017113936W WO 2018171252 A1 WO2018171252 A1 WO 2018171252A1
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Prior art keywords
composition according
pesticidal composition
active component
bit
mbit
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PCT/CN2017/113936
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English (en)
Chinese (zh)
Inventor
仲汉根
季红进
花伟
季定根
韦建峰
王莹
王英
Original Assignee
江苏辉丰生物农业股份有限公司
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Publication of WO2018171252A1 publication Critical patent/WO2018171252A1/fr

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Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
    • A01N43/80—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
    • A01N47/36—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< directly attached to at least one heterocyclic ring; Thio analogues thereof

Definitions

  • the invention belongs to the field of agricultural plant protection, and in particular relates to a pesticide composition with improved properties, in particular to a pesticide composition comprising benzisothiazolinone and thibenzo.
  • Benzoisothiazolinones are a new type of broad-spectrum fungicide mainly used for the prevention and treatment of various bacterial and fungal diseases such as cereal crops, vegetables and fruits.
  • the mechanism of bactericidal action mainly includes destroying the nuclear structure of the pathogen, causing it to lose the heart part and failing to death and interfering with the metabolism of the pathogenic cells, causing its physiological disorder and ultimately leading to death. It can effectively protect plants from pathogens in the early stage of disease occurrence. Increasing the dosage after disease occurrence can obviously control the spread of pathogens, thus achieving the dual functions of protection and eradication.
  • Common benzisothiazolinones include: 1,2-benzisothiazolin-3-one, 2-methyl-1,2-benzisothiazolin-3-one or 2-butyl- 1,2-Benzoisothiazolin-3-one.
  • Pyraclostrobin is a new type of high-efficiency plant growth regulator. When it is absorbed by plants, it can promote the separation of petioles and stems and form natural shedding. It can be widely used in pesticides and fertilizers. It has strong biological activity, and its ability to induce plant cell division and callus formation is many times higher than that of general cytokinins. Improve crop absorptive capacity and increase photosynthesis, so as to increase production and enhance the purpose. It can be used in various kinds of melons, fruits, vegetables, seedlings, flowers, food, tobacco and other crops, and can also be used for tissue culture, genetic engineering, etc. In production, it can significantly improve crop yield, improve quality and use less, has no pollution to the ecological environment, and is non-toxic to humans, animals, birds, bees and natural enemies.
  • Another object of the present invention is to provide a preparation method comprising the two active ingredients A and B pesticide compositions and Use in the agricultural field for disease prevention and disease resistance or for promoting plant growth.
  • the object of the invention can be achieved by the following measures:
  • a pesticidal composition comprising two active components A and B, wherein the active component A is a structural compound having the formula (I), wherein the active component B is thidiazuron,
  • R is selected from H or a C 1 - C 8 alkyl group.
  • the C 1 -C 8 alkyl group in the present invention means a linear or branched alkyl group having 1 to 8 carbon atoms, and includes a C 1 alkyl group (e.g., methyl group) and a C 2 alkyl group (e.g., ethyl group). , C 3 alkyl (such as n-propyl, isopropyl), C 4 alkyl (such as n-butyl, isobutyl, tert-butyl, sec-butyl), C 5 alkyl (such as n-pentyl, etc.) , C 6 alkyl, C 7 alkyl, C 8 alkyl. It includes, but is not limited to, C 1 -C 6 alkyl, C 1 -C 5 alkyl, C 1 -C 4 alkyl, and the like.
  • R is selected from H or a C 1 -C 4 alkyl group.
  • R is selected from the group consisting of H, -CH 3 or -C 4 H 9 .
  • A is 1,2-benzisothiazolin-3-one (abbreviated as BIT in the specification).
  • R is CH 3
  • A is 2-methyl-1,2-benzisothiazolin-3-one (abbreviated as MBIT in the specification).
  • R is C 4 H 9
  • A is 2-butyl-1,2-benzisothiazolin-3-one
  • the "butyl group” in the formula is preferably n-butyl (instruction Referred to as BBIT).
  • the weight ratio between the two components is 1: (0.01 to 1), and in order to further enhance the effect of the composition of the present invention, the weight ratio between the two components is further optimized to be 1: (0.0111 to 1).
  • the weight ratio between the two components of A and B can be arbitrarily adjusted within the range of the following ratios: 1:1, 2:1, 3:1, 4:1, 5:1 , 6:1, 7:1, 8:1, 9:1, 10:1, 11:1, 12:1, 13:1, 14:1, 15:1, 16:1, 17:1, 18 1, 19: 1, 20: 1, 21: 1, 22: 1, 23: 1, 24: 1, 25: 1, 26: 1, 27: 1, 28: 1, 29: 1, 30: 1 32:1, 33:1, 34:1, 35:1, 36:1, 37:1, 38:1, 39:1, 40:1, 41:1, 42:1, 43:1, 44 1, 45: 1, 46: 1, 47: 1, 48: 1, 49: 1, 50: 1, 51: 1, 52: 1, 53: 1, 54: 1, 55: 1, 56: 1 , 57:1, 58:1, 59:1, 60:1, 61:1, 62:1, 63:1, 64:1, 65:1, 66:1, 67:1, 68:1, 69 1, 70: 1, 71:1, 72: 1, 73
  • composition of the present invention is effective for controlling the true and bacterial diseases of crops, and more importantly, the combination of the two can better regulate the growth of crops, promote the health effects of crops, and improve crops. Production.
  • the present invention provides the use of a pesticide composition comprising component A (one of benzisothiazolinones) and component B (thiabendazole) in the field of disease prevention or disease promotion or promotion of crop growth in the agricultural field, in particular It is used for regulating crop growth and improving disease resistance in rice, corn or fruit trees.
  • component A one of benzisothiazolinones
  • component B thiabendazole
  • composition of the present invention can also be used in combination with other pesticides (such as fungicides, insecticides, herbicides, plant growth regulators), fertilizers, etc., and these are mixed with Commonly used pesticides or fertilizers disclosed in the art.
  • pesticides such as fungicides, insecticides, herbicides, plant growth regulators
  • fertilizers etc.
  • the active ingredient containing the pesticide composition of the present invention and a thiazole fungicide such as prochloraz or prochloraz copper salt, prochloraz, etc.
  • a thiazole fungicide such as prochloraz or prochloraz copper salt, prochloraz, etc.
  • triazole fungicide such as tebuconazole, prothioconazole
  • methoxy acrylates such as azoxystrobin, pyraclostrobin, picoxystrobin, ether oxystrobin, etc.
  • thiocarbamate fungicides such as mancozeb, desen Union, Daisen Zinc, etc.
  • composition of the present invention can be made into a pesticide-acceptable dosage form from the active ingredient and the pesticide adjuvant. Further, the composition comprises from 1.0001 to 85.0001% by weight of the active ingredient and from 98.9999 to 14.9999% by weight of the auxiliary agent in a pesticide-acceptable dosage form.
  • composition may specifically comprise an agrochemical adjuvant, such as one or more of a carrier, a solvent, a dispersing agent, a wetting agent, an adhesive, a thickener, a binder, a surfactant, and a fertilizer, during application. It is possible to mix commonly used auxiliaries.
  • an agrochemical adjuvant such as one or more of a carrier, a solvent, a dispersing agent, a wetting agent, an adhesive, a thickener, a binder, a surfactant, and a fertilizer, during application. It is possible to mix commonly used auxiliaries.
  • Suitable auxiliaries may be solid or liquid, they are usually materials commonly used in the processing of dosage forms, such as natural or regenerated minerals, solvents, dispersants, wetting agents, adhesives, thickeners, binders or fertilizers. .
  • the active component A may be first dissolved in a basic substance to form a benzisothiazolin metal salt.
  • Suitable basic substances include: alkali metal carbonates, alkali metal hydroxides (such as hydroxides). Sodium, potassium hydroxide), alkali metal alkoxy carbonate, alkali metal alkoxide or magnesium methoxide.
  • the method of application of the compositions of the invention comprises the use of the compositions of the invention for aerial parts of plants, in particular leaves or foliage. You can choose to soak or apply to the surface of the control object.
  • the frequency of administration and the amount administered will depend on the biological and climatic conditions of the pathogen.
  • the plant growth site such as rice fields, may be wetted with a liquid formulation of the composition, or the composition may be applied to the soil in solid form, such as in the form of granules (soil application), the composition may be passed from the soil to the plant through the roots of the plant. In vivo (systemic action).
  • compositions may be applied only with the active ingredient or may be mixed with an additive (agrochemical adjuvant). use.
  • composition of the present invention can be prepared into a pesticide-acceptable dosage form such as a wettable powder, a suspension, a water-dispersible granule, an aqueous emulsion or a microemulsion, an emulsifiable concentrate, a dispersible oil suspension, a suspoemulsion, an oil suspension or a micro Capsule type and the like.
  • a pesticide-acceptable dosage form such as a wettable powder, a suspension, a water-dispersible granule, an aqueous emulsion or a microemulsion, an emulsifiable concentrate, a dispersible oil suspension, a suspoemulsion, an oil suspension or a micro Capsule type and the like.
  • a pesticide-acceptable dosage form such as a wettable powder, a suspension, a water-dispersible granule, an aqueous emulsion or a microemulsion, an emul
  • composition of the present invention can be prepared into various dosage forms by a known method, and the active ingredient and the auxiliary agent, such as a solvent, a solid carrier, and, if necessary, can be uniformly mixed and ground together with the surfactant to prepare a desired preparation. Dosage form.
  • the above solvent may be selected from aromatic hydrocarbons, preferably containing from 8 to 12 carbon atoms, such as a mixture of xylenes or substituted benzenes, phthalates such as dibutyl phthalate or dicaprylic acid, aliphatic hydrocarbons such as rings.
  • aromatic hydrocarbons preferably containing from 8 to 12 carbon atoms, such as a mixture of xylenes or substituted benzenes, phthalates such as dibutyl phthalate or dicaprylic acid, aliphatic hydrocarbons such as rings.
  • Hexane or paraffin alcohol and ethylene glycol and their ethers and esters, such as ethanol, ethylene glycol, ethylene glycol monomethyl; ketones, such as cyclohexanone, highly polar solvents such as N-methyl-2 Pyrrolidone, dimethyl sulfoxide or dimethylformamide, and vegetable or vegetable oils such as soybean oil.
  • the above solid carriers are typically natural mineral fillers such as talc, kaolin, montmorillonite or activated clay.
  • a highly dispersible silicic acid or a highly dispersible adsorbent polymer carrier such as a particulate adsorbent carrier or a non-adsorbing carrier, and a suitable particulate adsorbent carrier is porous, such as pumice, bentonite or Bentonite; a suitable non-adsorbing carrier such as calcite or sand.
  • a large amount of pre-granulated materials of inorganic or organic nature can be used as a carrier, in particular dolomite.
  • Suitable surfactants are lignosulfonic acid, naphthalenesulfonic acid, phenolsulfonic acid, alkaline earth metal or amine salts, alkylarylsulfonates, alkyl groups Sulfates, alkyl sulfonates, fatty alcohol sulphates, fatty acids and sulfated fatty alcohol glycol ethers, as well as condensates of sulfonated naphthalene and naphthalene derivatives with formaldehyde, naphthalene or naphthalene sulfonic acid with phenol and formaldehyde Condensate, polyoxyethylene octyl phenyl ether, ethoxylated isooctyl phenol, octyl phenol, nonyl phenol, alkyl aryl polyglycol ether, tributyl benzene poly
  • the two active ingredients in the compositions of the present invention exhibit synergistic effects, the activity of which is more pronounced than the expected sum of activity using a single compound, and the individual activity of a single compound.
  • the synergistic effect is manifested by allowing for a reduced application rate, a broader fungicidal control profile, quicker effect, longer lasting control effect, better control of plant harmful fungi by only one or a few applications, and broadening of possible application. Intervals. These properties are particularly desirable in the practice of plant fungi control.
  • the composition of the present invention is compounded with Significant synergistic effect; 2, because the chemical composition of the two single agents of the composition is very different, the mechanism of action is completely different, there is no cross-resistance, and the resistance problem caused by the separate use of the two single agents can be delayed;
  • the composition of the invention can well regulate crop growth, improve disease resistance and stress resistance, promote crop health and increase crop yield.
  • the active ingredient A and the B active ingredient are sufficiently mixed with various auxiliary agents and fillers, and are pulverized by an ultrafine pulverizer to obtain a wettable powder.
  • Active component A BIT
  • thidiam thidiam
  • Example 1 2.2% BIT ⁇ thiatoron WP
  • Active component A (MBIT) and thidiazuron to prepare wettable powder
  • Example 5 2.2% MBIT ⁇ thiazolon wettable powder
  • MBIT was 3%
  • thiablon 0.0999%
  • the remaining components were prepared in accordance with the method of Example 2.
  • Example 7 9.1503% MBIT ⁇ thiazolon wettable powder
  • Example 8 12.12% MBIT ⁇ thiazolon wettable powder
  • Active component A (BBIT) and thidiazuron to prepare wettable powder
  • BBIT was 3%
  • thiazole was 0.0999%
  • the remaining components were prepared in accordance with the method of Example 2.
  • Example 11 9.1503% BBIT ⁇ thiazolon wettable powder
  • Example 12 12.12% BBIT ⁇ thiazolon wettable powder
  • the active ingredient A and the active ingredient B, and the components such as a dispersing agent, a wetting agent, a thickener and water are uniformly mixed according to the formulation, and after being sanded and/or sheared at a high speed, a semi-finished product is obtained. After the analysis, the water is added and uniformly filtered to obtain the finished product.
  • Active component A BIT
  • Example 13 8% BIT ⁇ thiazolone suspension
  • Example 14 6.12% BIT ⁇ thiazolone suspension
  • Example 15 10.1429% BIT ⁇ thiazolone suspension
  • Active component A (MBIT) and thidiazuron preparation suspension
  • Example 17 8% MBIT ⁇ thiazolone suspension
  • MBIT was 6%
  • thiabendazole was 0.12%
  • the remaining components were prepared in accordance with the procedure of Example 14.
  • MBIT was 3%
  • thiabendazole was 0.0333%
  • the remaining components were prepared in the same manner as in Example 16.
  • Active component A (BBIT) and thidiazuron preparation suspension
  • BBIT was 6%
  • thiabendazole was 0.12%
  • the remaining components were prepared in the same manner as in Example 14.
  • BBIT was 3%
  • thiazole was 0.0333%
  • the remaining components were prepared in accordance with the procedure of Example 16.
  • the active ingredient A and the active ingredient B, and the auxiliary agent and the filler are uniformly mixed according to the formula, and are pulverized into a wettable powder by a jet stream, and then added with a certain amount of water to be mixed and squeezed, and sieved to obtain water dispersion. Granule products.
  • Active component A BIT
  • thidiazuron to prepare water-dispersible granules
  • Example 25 4.2% BIT ⁇ thiazolon water dispersible granules
  • Example 26 10.25% BIT ⁇ thiaphenon water dispersible granules
  • Example 27 15.1875% BIT ⁇ thiaphenon water dispersible granules
  • Active component A (MBIT) and thidiazuron to prepare water-dispersible granules
  • Example 28 4.2% M BIT ⁇ thiazolon water dispersible granules
  • Example 29 10.25% MBIT ⁇ thiaphenon water dispersible granules
  • Example 30 15.1875% MBIT ⁇ thiaphenon water dispersible granules
  • Active component A BBIT
  • thidiazuron to prepare water-dispersible granules
  • Example 31 4.2% B BIT ⁇ thiaphenon water dispersible granules
  • Example 32 10.25% BBIT ⁇ thiaphenon water dispersible granules
  • Example 33 15.1875% BBIT ⁇ thiazolon water dispersible granules
  • Dilute BIT and thiexone with acetone according to a certain concentration spray the stems and leaves on the crops, and measure the effects of various concentrations on the growth of the crops in the field, including the plant height, ear length, grain weight, disease resistance and yield. Wait for a comprehensive evaluation.
  • Plant height control rate (clear water control plant height - treated plant height) / clear water control plant height * 100%
  • Ear length increase rate (plant ear length after treatment - clear water control plant ear length) / clear water control plant ear length * 100%
  • Grain 1000-grain weight increase rate (1000-grain weight of treated grain - 1000-grain weight of grain of clear water control) / Grain 1000-grain weight of clear water control *100%
  • BIT and thiabendazole have a good synergistic effect.
  • BIT and thidiazepine mixed in different ratios, relative to BIT, thidiazepine single agent, and water control, the growth regulation of oats The effect is obvious, mainly in 1.
  • composition of the present invention There is a significant increase in the unit yield of oats.
  • MBIT and thidiazepine were diluted with acetone according to a certain concentration, and sprayed twice after pear flowering and pear fruit setting, and the effects of each ratio on crop growth were measured in the field, including longitudinal diameter, transverse diameter, fruit setting rate, Comprehensive evaluation of disease resistance, fruit weight, and plant yield.
  • the fruit setting rate of the MBIT and the thiabendazole complex pear has a significant improvement effect; 2.
  • the yield is also improved due to the increase of the fruit setting rate; 3.
  • MBIT also has a certain regulating effect on the growth of grapes.
  • the leaves can make the leaves thicker, enhance photosynthesis, promote the inner nutrient transmission of pears, and increase the sugar and moisture of pears.
  • the weight of the fruit is correspondingly increased, thereby significantly increasing the unit yield of the pear; 4
  • the synergistic effect of thiampone and MBIT can have significant preventive and therapeutic effects on some major diseases of pear such as black spot disease.
  • BBIT and thiablon were diluted with acetone at a certain concentration, and the crops were sprayed with stems and leaves.
  • the effects of various concentrations on crop growth were measured in the field, including plant height, fruit length, fruit diameter, disease resistance and yield. Wait for a comprehensive evaluation.
  • Plant height control rate (clear water control plant height - treated plant height) / clear water control plant height * 100%
  • Fruit length increase rate (fruit length after treatment - clear water control fruit length) / clear water control fruit length * 100%
  • Fruit diameter increase rate (fruit diameter after treatment - clear water control fruit diameter) / clear water control fruit diameter * 100%
  • the cucumber plant can be dwarfed, the cucumber can be controlled to control the length of the cucumber, which is good for pollination; 2.
  • the volume of the cucumber can be increased, and the yield can be increased; 3.
  • BBIT has a certain systemic effect on cucumber, and the gray mold of cucumber
  • the fungal diseases have certain protective effects, while the thiabendazole has certain resistance to disease and stress, and the two have a significant synergistic effect after mixing; 4.
  • the unit yield of the composition of the invention on cucumber Has a significant boost.
  • Spraying was carried out using the formulation examples of the present invention, three replicates, and the results were averaged.
  • the experimental data from Table 4 shows that the product of the present invention is applied during the development of soybeans, and can effectively regulate the healthy growth of soybeans.
  • Dwarf soybean plants can be effectively controlled to control the growth of soybeans and prevent soybeans from lodging.
  • BIT has a good systemic effect on soybeans and has a protective effect on soybean growth prevention of fungal diseases, while thiabendazole has soybeans. Growth has certain resistance to disease and stress, and the two have a synergistic effect after compounding; 3.
  • the composition of the invention has a significant effect on the unit yield of soybean.
  • Application period two sprays were carried out 10 days before flowering and 12 days after flowering.
  • Application period rice at the end of the Qisui period.
  • the number of panicles in rice (the number of grains per panicle was more than 5 grains per serving), the total number of grains per panicle, the number of grains per panicle, the seed setting rate, and the yield per mu were calculated. The yield was calculated and statistical analysis was performed.
  • the test results show that the application of the preparation product of the invention at the end of rice seeding can effectively regulate the healthy growth of rice.
  • Dwarf rice plants effectively control rice control and prevent rice from lodging; 2. It can increase the number of panicles in rice and increase the seed setting rate of rice; 4.
  • BBIT has certain systemicity to rice, and rice grain Fungal diseases such as blight have a certain protective effect, while thiabendazole has certain resistance to disease and stress, and it has significant synergistic effect after mixing; 5.
  • the composition of the present invention is applied to rice Unit yield has a significant boost.

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  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

La présente invention concerne une composition pesticide, dont les matières actives comprennent A et B, la matière active A étant un composé ayant la structure de formule (I), et la matière active B étant du thidiazuron, et le rapport en poids des deux constituants étant de 1:(0,01-1). L'invention concerne en outre un procédé de préparation et une application de la composition. Les résultats d'expérience démontrent que la composition selon l'invention peut réguler efficacement la croissance des cultures, améliorer la résistance aux maladies et la tolérance au stress, favoriser la santé des cultures, et augmenter le rendement des cultures.
PCT/CN2017/113936 2017-03-21 2017-11-30 Composition pesticide contenant de la benzisothiazolinone et du thidiazuron WO2018171252A1 (fr)

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CN201710167383.5A CN106922683A (zh) 2017-03-21 2017-03-21 含有苯并异噻唑啉酮和噻苯隆的农药组合物
CN201710167383.5 2017-03-21

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CN103314968A (zh) * 2013-06-09 2013-09-25 江苏辉丰农化股份有限公司 具有增效作用的杀菌组合物
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CN106332893A (zh) * 2016-08-22 2017-01-18 江苏辉丰农化股份有限公司 一种农药组合物
CN106342854A (zh) * 2016-08-22 2017-01-25 江苏辉丰农化股份有限公司 一种农药组合物
CN106359430A (zh) * 2016-08-22 2017-02-01 江苏辉丰农化股份有限公司 一种农药组合物
CN106922683A (zh) * 2017-03-21 2017-07-07 江苏辉丰农化股份有限公司 含有苯并异噻唑啉酮和噻苯隆的农药组合物

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