WO2015053225A1 - Kit cosmétique et kit d'agent de traitement capillaire, et méthode de traitement capillaire - Google Patents
Kit cosmétique et kit d'agent de traitement capillaire, et méthode de traitement capillaire Download PDFInfo
- Publication number
- WO2015053225A1 WO2015053225A1 PCT/JP2014/076710 JP2014076710W WO2015053225A1 WO 2015053225 A1 WO2015053225 A1 WO 2015053225A1 JP 2014076710 W JP2014076710 W JP 2014076710W WO 2015053225 A1 WO2015053225 A1 WO 2015053225A1
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- WIPO (PCT)
- Prior art keywords
- agent
- hair
- hair treatment
- acid
- treatment
- Prior art date
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- 239000001026 semi permanent hair color Substances 0.000 description 1
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- SQVRNKJHWKZAKO-OQPLDHBCSA-N sialic acid Chemical compound CC(=O)N[C@@H]1[C@@H](O)C[C@@](O)(C(O)=O)OC1[C@H](O)[C@H](O)CO SQVRNKJHWKZAKO-OQPLDHBCSA-N 0.000 description 1
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- AJPJDKMHJJGVTQ-UHFFFAOYSA-M sodium dihydrogen phosphate Chemical compound [Na+].OP(O)([O-])=O AJPJDKMHJJGVTQ-UHFFFAOYSA-M 0.000 description 1
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 description 1
- HRZFUMHJMZEROT-UHFFFAOYSA-L sodium disulfite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])(=O)=O HRZFUMHJMZEROT-UHFFFAOYSA-L 0.000 description 1
- BTURAGWYSMTVOW-UHFFFAOYSA-M sodium dodecanoate Chemical compound [Na+].CCCCCCCCCCCC([O-])=O BTURAGWYSMTVOW-UHFFFAOYSA-M 0.000 description 1
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- KMPHTYSTEHXSTL-UHFFFAOYSA-M sodium;2-hydroxypropanoate;2-hydroxypropanoic acid Chemical compound [Na+].CC(O)C(O)=O.CC(O)C([O-])=O KMPHTYSTEHXSTL-UHFFFAOYSA-M 0.000 description 1
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- 235000002906 tartaric acid Nutrition 0.000 description 1
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- 239000001027 temporary hair color Substances 0.000 description 1
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
- BORJONZPSTVSFP-UHFFFAOYSA-N tetradecyl 2-hydroxypropanoate Chemical compound CCCCCCCCCCCCCCOC(=O)C(C)O BORJONZPSTVSFP-UHFFFAOYSA-N 0.000 description 1
- DZKXJUASMGQEMA-UHFFFAOYSA-N tetradecyl tetradecanoate Chemical compound CCCCCCCCCCCCCCOC(=O)CCCCCCCCCCCCC DZKXJUASMGQEMA-UHFFFAOYSA-N 0.000 description 1
- DLYUQMMRRRQYAE-UHFFFAOYSA-N tetraphosphorus decaoxide Chemical compound O1P(O2)(=O)OP3(=O)OP1(=O)OP2(=O)O3 DLYUQMMRRRQYAE-UHFFFAOYSA-N 0.000 description 1
- RYCLIXPGLDDLTM-UHFFFAOYSA-J tetrapotassium;phosphonato phosphate Chemical compound [K+].[K+].[K+].[K+].[O-]P([O-])(=O)OP([O-])([O-])=O RYCLIXPGLDDLTM-UHFFFAOYSA-J 0.000 description 1
- 235000019818 tetrasodium diphosphate Nutrition 0.000 description 1
- KWXLCDNSEHTOCB-UHFFFAOYSA-J tetrasodium;1,1-diphosphonatoethanol Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P(=O)([O-])C(O)(C)P([O-])([O-])=O KWXLCDNSEHTOCB-UHFFFAOYSA-J 0.000 description 1
- UEUXEKPTXMALOB-UHFFFAOYSA-J tetrasodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O UEUXEKPTXMALOB-UHFFFAOYSA-J 0.000 description 1
- OULAJFUGPPVRBK-UHFFFAOYSA-N tetratriacontyl alcohol Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCO OULAJFUGPPVRBK-UHFFFAOYSA-N 0.000 description 1
- 230000001225 therapeutic effect Effects 0.000 description 1
- SHWIJIJNPFXOFS-UHFFFAOYSA-N thiotaurine Chemical compound NCCS(O)(=O)=S SHWIJIJNPFXOFS-UHFFFAOYSA-N 0.000 description 1
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- 239000004408 titanium dioxide Substances 0.000 description 1
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 1
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- GYDJEQRTZSCIOI-LJGSYFOKSA-N tranexamic acid Chemical compound NC[C@H]1CC[C@H](C(O)=O)CC1 GYDJEQRTZSCIOI-LJGSYFOKSA-N 0.000 description 1
- 229960000401 tranexamic acid Drugs 0.000 description 1
- ILJSQTXMGCGYMG-UHFFFAOYSA-N triacetic acid Chemical compound CC(=O)CC(=O)CC(O)=O ILJSQTXMGCGYMG-UHFFFAOYSA-N 0.000 description 1
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 1
- 229940118594 trimethylolpropane triisostearate Drugs 0.000 description 1
- VLPFTAMPNXLGLX-UHFFFAOYSA-N trioctanoin Chemical compound CCCCCCCC(=O)OCC(OC(=O)CCCCCCC)COC(=O)CCCCCCC VLPFTAMPNXLGLX-UHFFFAOYSA-N 0.000 description 1
- 229960005066 trisodium edetate Drugs 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- UJMBCXLDXJUMFB-UHFFFAOYSA-K trisodium;5-oxo-1-(4-sulfonatophenyl)-4-[(4-sulfonatophenyl)diazenyl]-4h-pyrazole-3-carboxylate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)C1=NN(C=2C=CC(=CC=2)S([O-])(=O)=O)C(=O)C1N=NC1=CC=C(S([O-])(=O)=O)C=C1 UJMBCXLDXJUMFB-UHFFFAOYSA-K 0.000 description 1
- SOBHUZYZLFQYFK-UHFFFAOYSA-K trisodium;hydroxy-[[phosphonatomethyl(phosphonomethyl)amino]methyl]phosphinate Chemical compound [Na+].[Na+].[Na+].OP(O)(=O)CN(CP(O)([O-])=O)CP([O-])([O-])=O SOBHUZYZLFQYFK-UHFFFAOYSA-K 0.000 description 1
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- 235000010374 vitamin B1 Nutrition 0.000 description 1
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- 235000019154 vitamin C Nutrition 0.000 description 1
- 239000011718 vitamin C Substances 0.000 description 1
- 235000019165 vitamin E Nutrition 0.000 description 1
- 239000011709 vitamin E Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000010497 wheat germ oil Substances 0.000 description 1
- 239000012463 white pigment Substances 0.000 description 1
- 239000000811 xylitol Substances 0.000 description 1
- 235000010447 xylitol Nutrition 0.000 description 1
- HEBKCHPVOIAQTA-SCDXWVJYSA-N xylitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)CO HEBKCHPVOIAQTA-SCDXWVJYSA-N 0.000 description 1
- 229960002675 xylitol Drugs 0.000 description 1
- 239000001052 yellow pigment Substances 0.000 description 1
- 239000009538 yokuinin Substances 0.000 description 1
- 239000011592 zinc chloride Substances 0.000 description 1
- 235000005074 zinc chloride Nutrition 0.000 description 1
- 229940105125 zinc myristate Drugs 0.000 description 1
- UHVMMEOXYDMDKI-JKYCWFKZSA-L zinc;1-(5-cyanopyridin-2-yl)-3-[(1s,2s)-2-(6-fluoro-2-hydroxy-3-propanoylphenyl)cyclopropyl]urea;diacetate Chemical compound [Zn+2].CC([O-])=O.CC([O-])=O.CCC(=O)C1=CC=C(F)C([C@H]2[C@H](C2)NC(=O)NC=2N=CC(=CC=2)C#N)=C1O UHVMMEOXYDMDKI-JKYCWFKZSA-L 0.000 description 1
- GBFLQPIIIRJQLU-UHFFFAOYSA-L zinc;tetradecanoate Chemical compound [Zn+2].CCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCC([O-])=O GBFLQPIIIRJQLU-UHFFFAOYSA-L 0.000 description 1
- OJYLAHXKWMRDGS-UHFFFAOYSA-N zingerone Chemical compound COC1=CC(CCC(C)=O)=CC=C1O OJYLAHXKWMRDGS-UHFFFAOYSA-N 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
- FYGDTMLNYKFZSV-BYLHFPJWSA-N β-1,4-galactotrioside Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@H]1O[C@@H]1[C@H](CO)O[C@@H](O[C@@H]2[C@@H](O[C@@H](O)[C@H](O)[C@H]2O)CO)[C@H](O)[C@H]1O FYGDTMLNYKFZSV-BYLHFPJWSA-N 0.000 description 1
- OENHQHLEOONYIE-JLTXGRSLSA-N β-Carotene Chemical compound CC=1CCCC(C)(C)C=1\C=C\C(\C)=C\C=C\C(\C)=C\C=C\C=C(/C)\C=C\C=C(/C)\C=C\C1=C(C)CCCC1(C)C OENHQHLEOONYIE-JLTXGRSLSA-N 0.000 description 1
- 229930007845 β-thujaplicin Natural products 0.000 description 1
- QUEDXNHFTDJVIY-UHFFFAOYSA-N γ-tocopherol Chemical class OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1 QUEDXNHFTDJVIY-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/22—Peroxides; Oxygen; Ozone
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/36—Carboxylic acids; Salts or anhydrides thereof
- A61K8/365—Hydroxycarboxylic acids; Ketocarboxylic acids
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/04—Preparations for permanent waving or straightening the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/10—Preparations for permanently dyeing the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/80—Process related aspects concerning the preparation of the cosmetic composition or the storage or application thereof
- A61K2800/88—Two- or multipart kits
- A61K2800/882—Mixing prior to application
Definitions
- the present invention relates to a cosmetic kit and a hair treatment kit. More specifically, the present invention relates to a cosmetic kit, a hair treatment agent kit, and a hair treatment method for obtaining a cosmetic and a hair treatment agent by mixing A agent, B agent, and C agent.
- Non-Patent Document 1 discloses a method for removing oxidative stress by utilizing the antioxidant action of hydrogen.
- Patent Document 1 discloses a method for producing a powdery magnesium-based hydride by reacting a single magnesium with a hydrogen molecule.
- the powdery magnesium-based hydride stores hydrogen in advance, and hydrogen is efficiently generated by reacting with water.
- Patent Document 2 discloses a powder bath cosmetic in which hydrogen is generated by containing finely divided magnesium hydride and reacting with water.
- this powder bath cosmetic requires a large amount of water in order to generate sufficient hydrogen at the time of use, and the water used for the reaction of the powder bath cosmetic needs to be hot water.
- Hydrogen acts as a therapeutic antioxidant by selectively reducing cytotoxic oxygen radicals. Nature Medicine 13 688-694 (2007)
- the main object of the present invention is to provide a novel technique capable of effectively preventing oxidative stress due to active oxygen and free radicals on the skin and hair.
- a cosmetic kit is obtained by mixing A agent, B agent and C agent at the time of use.
- a kit for a hair treatment agent comprising: Examples of the hair treatment agent obtained using the kit for hair treatment agent according to the present invention include a permanent agent and a hair dye.
- the agent A and the agent B may be mixed in advance. Moreover, you may mix the said B agent and the said C agent previously.
- the agent A, the agent B, and the agent C can be mixed at the time of use to obtain a hair treatment agent.
- the substance in which the aqueous solution that can be contained in the agent B of the kit for hair treatment according to the present invention exhibits acidity include citric acid, magnesium chloride, hydrogen peroxide, and the like.
- the contact step (I) in which the agent A containing magnesium hydride is brought into contact with the hair A contact step (II) in which a B agent containing a substance whose aqueous solution shows acidity is brought into contact with the hair; A contact step (III) in which C-agent containing water is brought into contact with hair;
- the hair treatment method is performed simultaneously or in any order.
- a heating step (IV) for heating the hair can be further performed.
- the effect of preventing oxidative stress on the skin and hair is drastically improved as compared with the conventional technology, and further, the moisture content in the skin and hair is reduced. A new action such as raising can be realized.
- Cosmetic kit and hair treatment kit The cosmetic kit and hair treatment kit according to the present invention are broadly classified into (1) A agent containing magnesium hydride, (2) B agent containing a substance whose aqueous solution is acidic, and (3) water. C agent containing. And cosmetics or a hair treatment agent is obtained by mixing these A agent, B agent, and C agent.
- the reaction formula for producing magnesium hydride is represented by the following formula (1).
- Magnesium hydride powder is charcoal gray and stable in the air, but in water it decomposes while reacting with water and releasing hydrogen. Therefore, the magnesium hydride in the agent A used in the present invention has occluded hydrogen in advance, and can react with the water in the agent C and be hydrolyzed to release hydrogen. It is.
- the reaction formula in which magnesium hydride reacts with water is represented by the following formula (2).
- magnesium hydride used in the present invention has a hydrogen storage amount per mass of 7.6% (w / w), which is much higher than the hydrogen storage material.
- the amount of hydrogen generated by hydrolysis is the hydrogen storage amount of magnesium hydride. It is 15.2% (w / w), which is twice this. Therefore, when hydrogen is generated from water using a metal that has a higher ionization tendency than hydrogen, or when hydrogen in the hydrogen storage material is taken out by dissolving (decomposing) the hydrogen storage material in water, Occurrence can be expected.
- magnesium hydride exists as a solid at room temperature and is sufficiently hydrolyzed with moisture in the cosmetics and hair treatment agent to generate a large amount of hydrogen as described above. It is possible to sufficiently obtain the effect of hydrogen while fully exhibiting the original effect.
- magnesium hydride is a harmless substance
- Mg (OH) 2 after hydrogen generation is a safe substance as it is also used for pharmaceuticals. From these points, if the compound that generates hydrogen is magnesium hydride, it is possible to manufacture, transport, and use the hydrogen generating material more safely.
- the reaction of the above formula (2) has a problem that the surface of magnesium hydride is covered with Mg (OH) 2 with the reaction, and the reactivity gradually deteriorates. Moreover, the temperature at the time of reaction needs to be higher than normal temperature. In order to solve the above-mentioned problems, the reaction of the above formula (2) efficiently generates hydrogen even at room temperature by containing a substance whose aqueous solution is acidic in agent B and making the reaction solution acidic. Is possible.
- cosmetics obtained using the cosmetic kit according to the present invention include skin care products such as creams, emulsions, lotions, gels, packs, masks, cleansing oils, massage oils, eyeliners, mascaras, eyebrows, Makeup products such as lip liners, foundations, makeup bases, body soaps, cleansing products such as face wash, antiperspirants, shampoos, rinses, treatments, conditioners, hair creams, hair set agents, hair restorers, etc. Etc.
- the cosmetic kit according to the present invention is characterized by mixing agent A, agent B and agent C at the time of use.
- agent A, agent B and agent C are applied to the skin and hair while the hydrolysis reaction of magnesium hydride in agent A and water in agent C proceeds. Can be applied. Therefore, the generated hydrogen can be directly absorbed by the skin and hair.
- the hydrolysis reaction between the magnesium hydride in the agent A and the water in the agent C continuously proceeds even after being applied to the skin and hair. Therefore, the generated hydrogen can be continuously absorbed by the skin and hair.
- the cosmetic kit according to the present invention stores magnesium hydride, which is highly reactive with water, separately for agent A and agent C, the magnesium hydride is stable even when stored for a long time. Yes, it is possible to store hydrogen efficiently.
- the hair treatment agent obtained using the kit for hair treatment agent according to the present invention can be prepared in various forms, and is not particularly limited.
- cream, lotion, gel, paste There are powder, solid, foam, spray, etc.
- a propellant such as LPG, DME, hexane or the like is mainly blended, or a non-gas foam type may be used.
- Specific examples include permanent agents, hair straighteners, hair dyes, hair dyes and the like.
- the hair dye is a so-called quasi-drug, and examples thereof include permanent hair dyes such as hair colors for fashion dyeing and hair coloring for gray hair dyeing.
- a bleaching agent such as a hair bleach that removes hair color pigments and changes the hair color, a decoloring agent, and the like are also a type of hair dye.
- the hair dye include semi-permanent hair dyes such as hair manicure, color shampoo, and color rinse, color sprays, color sticks, and the like, and temporary hair dyes that can be temporarily dyed and washed with shampoo.
- the hair and scalp are always damaged.
- treatment such as treatment is generally performed before or after hair treatment in order to protect or recover the hair and scalp from damage.
- the hair treatment agent obtained from the hair treatment agent kit according to the present invention contains hydrogen having a function of protecting and recovering from damage in the hair treatment agent. Therefore, since the hair and scalp can be simultaneously protected during the hair treatment, damage during the hair treatment can be drastically prevented as compared with the conventional method.
- the hair treatment agent obtained from the kit for hair treatment agents which concerns on this invention can improve the effect of hair treatment. That is, compared with the case where the conventional hair treatment agent is used, the case where the hair treatment is performed using the hair treatment agent obtained using the kit for hair treatment agent according to the present invention has a permanent effect and curly hair correction.
- the effect of hair treatment such as the effect and coloring property of hair dye is improved.
- the hair treatment agent obtained from the kit for hair treatment agent according to the present invention can also improve the sustainability of the hair treatment. That is, compared to the case of using a conventional hair treatment agent, the case where the hair treatment is performed using the hair treatment agent obtained from the hair treatment agent kit according to the present invention, the permanence persistence and the curly hair persistence are maintained. The durability of the hair treatment such as the property and dyeing durability is improved.
- the present invention is preferably used for a permanent agent, a hair straightener and a hair dye among the hair treatment agents.
- a hair straightener and a hair dye active oxygen is generated.
- this active oxygen is present inside or on the hair and inside or on the scalp, damage to the hair or scalp proceeds.
- the hair treatment agent obtained from the kit for hair treatment agent according to the present invention is used, active oxygen is generated, and at the same time, hydrogen in the hair treatment agent removes active oxygen. Damage can be almost certainly prevented.
- the hair treatment agent obtained from the hair treatment agent kit according to the present invention not only prevents a decrease in the amount of water accompanying damage to the hair and scalp, but also generates new water using the generated active oxygen.
- the hair treatment agent obtained from the kit for hair treatment agents according to the present invention is used as a hair treatment agent that generates active oxygen, an advantageous effect of generating new water can be obtained.
- the agent A, agent B and agent C constituting the hair treatment agent kit according to the present invention may be mixed in advance, but in the present invention, it is particularly preferable to mix the agent A and agent C at the time of use. That is, A agent, B agent and C agent are all stored separately and mixed at the time of use, A agent and B agent are mixed in advance, and C agent is added and mixed at the time of use, B agent and C agent It is preferable to design in any form of mixing the agent A at the time of use in a premixed state. By mixing the A agent and the C agent at the time of use, the hair treatment agent is applied to the hair and scalp while the hydrolysis reaction of the magnesium hydride in the A agent and the water in the C agent is in progress. be able to. Therefore, the generated hydrogen can be directly absorbed by the hair and scalp.
- the hydrolysis reaction between the magnesium hydride in the A agent and the water in the C agent continues even after the hair treatment agent is applied to the hair and scalp. Therefore, the generated hydrogen can be continuously absorbed by the hair and scalp.
- the hair treatment agent obtained from the kit for hair treatment agent according to the present invention can be blended into the first agent and / or the second agent of a permanent agent, a hair straightener and a hair dye. Moreover, it is also possible to mix
- the first agent Since the first agent has a function of causing hair to swell and infiltrate the hair with chemicals and dyes, by blending the hair treatment agent obtained from the hair treatment agent kit according to the present invention into the first agent, This is because the generated hydrogen can efficiently penetrate into the hair.
- a hair straightener, a hair dye, the first agent, the second agent, and other components to be mixed in the acid rinse a normal permanent agent, a hair straightener, a hair dye, and other normal hair treatment
- Arbitrary components used in the pharmaceutical field can be blended within a range not impeding the effects of the present invention.
- the first agent contains various alkali agents
- the second agent contains hydrogen peroxide, bromic acid or a bromate salt such as sodium bromate, etc.
- the acid rinse agent contains various alkalis incorporated in the first agent.
- An acid for neutralizing the agent can be blended.
- Agent A Agent A contains magnesium hydride.
- the method for obtaining the magnesium hydride in the agent A used in the present invention is not particularly limited, but it can be produced efficiently by the methods disclosed in, for example, Japanese Patent No. 4083786 and Japanese Patent No. 4425990. Is possible.
- a raw material powder containing magnesium as a main component is held in a hydrogen gas atmosphere sealed in a sealed container, While maintaining the pressure of the hydrogen gas atmosphere at a predetermined pressure, the temperature of the hydrogen gas atmosphere in the enclosure is on the equilibrium curve between the reaction in which single magnesium and hydrogen molecules combine to produce magnesium hydride and the reverse reaction.
- the coating on the surface of the raw material powder is removed by maintaining the temperature at a temperature higher than the temperature corresponding to the predetermined pressure and at a temperature difference from the temperature within a predetermined value for a predetermined first period.
- the temperature is lower than the temperature corresponding to the predetermined pressure on the equilibrium curve, and the temperature difference from the temperature is a predetermined value.
- the temperature by maintaining a predetermined second period, the production of magnesium hydride from the raw material powder.
- magnesium hydride having a high hydrogenation rate can be efficiently produced.
- a compressed product is prepared by compressing a plurality of flakes mainly composed of magnesium and compressing them in a hydrogen gas atmosphere. You may make it react with gas.
- magnesium hydride is manufactured from flakes containing magnesium as the main component, so it is safer and more efficient to use magnesium hydride with a high hydrogenation rate compared to manufacturing from powder raw materials that may cause dust explosion. Can be manufactured automatically.
- the mass is measured, and it is obtained as in the following formula (1).
- the magnesium hydride obtained by the above method usually has a hydrogenation rate of about 70 to 100%, more preferably about 90 to 100%.
- Magnesium hydride has a higher hydrogenation rate than other hydrogen storage alloys and is stable against chemical deterioration. Therefore, it is a very excellent hydrogen storage material that is easy to handle in terms of workability such as transportation, supply, and storage.
- the moisture-absorbing component only needs to contain a component that absorbs moisture, such as silica, sodium sulfate, magnesium sulfate, copper sulfate, calcium chloride, magnesium chloride, alumina, diphosphorus pentoxide, diatomaceous earth, and zeolite. Etc.
- the average particle diameter of the magnesium hydride used in the present invention is not particularly limited, but is preferably 20 ⁇ m or less, and more preferably 5 ⁇ m or less.
- an average particle diameter is a 50 wt% diameter obtained by measuring the particle size distribution of magnesium hydride.
- the 50 wt% diameter is a particle diameter having a 50% cumulative frequency. That is, the particle size is obtained when the magnesium hydride particles having a smaller particle size are accumulated in order and the accumulated value reaches 50%.
- the magnesium hydride content in the cosmetic kit and hair treatment kit according to the present invention can be freely set as long as the effects of the present invention are not impaired.
- the content of magnesium hydride is particularly preferably set to 0.01 to 5% by mass. By setting the content of magnesium hydride to 0.01% by mass or more, a sufficient amount of hydrogen can be generated continuously. Moreover, the amount of unreacted magnesium hydride remaining on the skin or hair can be reduced by setting it to 5% by mass or less.
- B agent B agent contains the substance which aqueous solution shows acidity.
- Substances in which the aqueous solution in the agent B used in the present invention is acidic are generally used in cosmetics, hair treatment agents, etc., and are substances that do not affect the human body in small amounts, and substances that show acidity when used as aqueous solutions. If so, one or more known substances can be freely selected and used.
- linear fatty acids such as formic acid, acetic acid, propionic acid, butyric acid, valeric acid, oxalic acid, malonic acid, succinic acid, glutaric acid, adipic acid, pimelic acid, fumaric acid, maleic acid, phthalic acid, isophthalic acid, terephthalic acid Dicarboxylic acids such as acids, acidic amino acids such as glutamic acid and aspartic acid, glycolic acid, malic acid, tartaric acid, lactic acid, hydroxyacrylic acid, ⁇ -oxybutyric acid, glyceric acid, tartronic acid, salicylic acid, gallic acid, tropic acid, ascorbic acid , Oxyacids such as gluconic acid, organic acids such as citric acid; phosphoric acid, sulfamic acid, boric acid, metaboric acid, potassium dihydrogen phosphate, sodium dihydrogen phosphate, sodium sulfite, potassium sulfite, sodium
- an organic acid is preferable, and citric acid is most preferable.
- magnesium chloride is most preferable among the Lewis acid catalysts.
- an oxidizing agent such as hydrogen peroxide contained in a general hair treatment agent can also be used as a substance whose aqueous solution shows acidity.
- the content of the substance in which the aqueous solution in the cosmetic kit and hair treatment kit according to the present invention is acidic can be freely set as long as the effects of the present invention are not impaired.
- a sufficient amount of hydrogen can be continuously generated by setting the content of the substance in which the aqueous solution is acidic to a weight ratio of 0.5 or more with respect to magnesium hydride 1.
- it can prevent that the hydrolysis reaction rate of magnesium hydride and water increases too much, and can generate hydrogen continuously and stably.
- C agent C agent contains water.
- the water in the C agent used in the present invention is generally used for cosmetics, hair treatment agents and the like, and is readily available. Further, it may be a single component or a mixed component. Examples of the water include raw water, tap water, distilled water, purified water, pure water, deionized water, fresh water, hard water, and soft water.
- each agent of the cosmetic kit and hair treatment kit according to the present invention can be prepared by a known method, and within a range that does not interfere with the effects of the present invention with commonly used components, for example, a moisturizing agent, Surfactant (anionic surfactant, cationic surfactant, amphoteric surfactant, nonionic surfactant, etc.), oil (hydrocarbon oil, synthetic ester oil, silicone oil, liquid oil, solid oil, wax, etc.) , Higher fatty acids, higher alcohols, powder components, water-soluble polymers (natural, semi-synthetic, synthetic), thickeners, UV absorbers, sequestering agents, lower alcohols, saccharides (monosaccharides, oligosaccharides, polysaccharides), Organic amines, pH adjusters, vitamins, antioxidants, antioxidant assistants, other components that can be blended, and the like can be blended as necessary. However, it is not limited to these examples.
- humectant examples include polyglycerin such as glycerin, diglycerin, triglycerin, tetraglycerin, ethylene glycol, 1,3-butylene glycol, 1,4-butylene glycol, propylene glycol, dipropylene glycol, polyethylene glycol, 1 , 3-propanediol, glucose, maltose, maltitol, sucrose, fructose, xylitol, sorbitol, maltotriose, threitol, erythritol, amylolytic sugar reducing alcohol, polyglycerin derivative, polyoxyalkylene alkyl glucoside and the like.
- polyglycerin such as glycerin, diglycerin, triglycerin, tetraglycerin, ethylene glycol, 1,3-butylene glycol, 1,4-butylene glycol, propylene glycol, dipropylene glycol, polyethylene
- Anionic surfactants include, for example, fatty acid soaps (eg, sodium laurate, sodium palmitate, etc.); higher alkyl sulfates (eg, sodium lauryl sulfate, potassium lauryl sulfate, etc.); alkyl ether sulfates (eg, POE lauryl sulfate triethanolamine, POE sodium lauryl sulfate, etc.); N-acyl sarcosine acid (eg, lauroyl sarcosine sodium, etc.); higher fatty acid amide sulfonates (eg, N-myristoyl-N-methyl taurine sodium, coconut oil fatty acid) Methyl tauride sodium, lauryl methyl tauride sodium, etc.); Phosphate ester salts (POE oleyl ether sodium phosphate, POE stearyl ether phosphate, etc.); Sulfosuccinate (eg, -2-sodium
- Examples of the cationic surfactant include alkyltrimethylammonium salts (eg, stearyltrimethylammonium chloride, lauryltrimethylammonium chloride, etc.); alkylpyridinium salts (eg, cetylpyridinium chloride, etc.); distearyldimethylammonium dialkyldimethylammonium chloride; Poly (N, N'-dimethyl-3,5-methylenepiperidinium chloride); alkyl quaternary ammonium salt; alkyldimethylbenzylammonium salt; alkylisoquinolinium salt; dialkyl morpholinium salt; POE alkylamine; Examples include amine salts; polyamine fatty acid derivatives; amyl alcohol fatty acid derivatives; benzalkonium chloride; benzethonium chloride and the like.
- alkyltrimethylammonium salts eg, stearyltrimethylammonium chloride, lauryltrimethylammonium
- amphoteric surfactants examples include imidazoline-based amphoteric surfactants (eg, 2-undecyl-N, N, N- (hydroxyethylcarboxymethyl) -2-imidazoline sodium, 2-cocoyl-2-imidazolinium hydroxide). Side-1-carboxyethyloxy disodium salt, etc.); betaine surfactants (for example, 2-heptadecyl-N-carboxymethyl-N-hydroxyethylimidazolinium betaine, lauryldimethylaminoacetic acid betaine, alkylbetaine, amide betaine) , Sulfobetaine, etc.).
- imidazoline-based amphoteric surfactants eg, 2-undecyl-N, N, N- (hydroxyethylcarboxymethyl) -2-imidazoline sodium, 2-cocoyl-2-imidazolinium hydroxide).
- hydrophilic nonionic surfactants include POE sorbitan fatty acid esters (for example, POE sorbitan monooleate, POE sorbitan monostearate, POE sorbitan monooleate, POE sorbitan tetraoleate, etc.); POE sorbite fatty acid ester (Eg POE sorbite monolaurate, POE sorbite monooleate, POE sorbite pentaoleate, POE sorbite monostearate, etc.); POE glycerin fatty acid esters (eg POE glycerin monostearate, POE glycerin monoisostearate) POE monooleate such as POE glycerin triisostearate); POE fatty acid esters (for example, POE distearate, POE monodiolate, distea) POE alkyl ethers (for example, POE lauryl ether, POE o
- hydrocarbon oil examples include liquid paraffin, isododecane, isohexadecane, ozokerite, squalane, pristane, paraffin, ceresin, squalene, petrolatum, microcrystalline wax, and the like.
- Synthetic ester oils include isopropyl myristate, cetyl octanoate, octyldodecyl myristate, isopropyl palmitate, butyl stearate, hexyl laurate, myristyl myristate, decyl oleate, hexyl decyl dimethyloctanoate, cetyl lactate, myristyl lactate Lanolin acetate, isocetyl stearate, isocetyl isostearate, cholesteryl 12-hydroxystearate, ethylene glycol di-2-ethylhexanoate, dipentaerythritol fatty acid ester, N-alkyl glycol monoisostearate, neopentyl glycol dicaprate, apple Acid diisostearyl, di-2-heptylundecanoic acid glycerin, tri-2-ethylhexanoic acid
- silicone oil examples include linear polysiloxanes (for example, dimethylpolysiloxane, methylphenylpolysiloxane, diphenylpolysiloxane, etc.); cyclic polysiloxanes (for example, octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohexyl).
- silicone resins that form a three-dimensional network structure various modified polysiloxanes (amino-modified polysiloxane, polyether-modified polysiloxane, alkyl-modified polysiloxane, fluorine-modified polysiloxane, etc.) It is done.
- liquid fats examples include avocado oil, camellia oil, macadamia nut oil, corn oil, olive oil, rapeseed oil, sesame oil, persic oil, wheat germ oil, sasanqua oil, castor oil, linseed oil, safflower oil, cottonseed oil, eno oil , Soybean oil, peanut oil, tea seed oil, kaya oil, rice bran oil, snail oil, Japanese drill oil, jojoba oil, germ oil and the like.
- solid fat examples include cocoa butter, coconut oil, hardened coconut oil, palm oil, palm kernel oil, owl kernel oil, hardened oil, owl, and hardened castor oil.
- waxes examples include beeswax, candelilla wax, cotton wax, carnauba wax, bayberry wax, ibota wax, montan wax, nukarou, kapok wax, sugar cane wax, jojoballow, shellac wax, and the like.
- higher fatty acid examples include lauric acid, myristic acid, palmitic acid, stearic acid, behenic acid, oleic acid, undecylenic acid, toluic acid, isostearic acid, linoleic acid, linolenic acid, eicosapentaenoic acid (EPA), docosahexaenoic acid ( DHA) and the like.
- higher alcohols examples include linear alcohols (eg, lauryl alcohol, cetyl alcohol, stearyl alcohol, behenyl alcohol, myristyl alcohol, oleyl alcohol, cetostearyl alcohol); branched chain alcohols (eg, monostearyl glycerin ether (batyl alcohol) ), 2-decyltetradecinol, phytosterol, hexyldodecanol, isostearyl alcohol, octyldodecanol and the like.
- linear alcohols eg, lauryl alcohol, cetyl alcohol, stearyl alcohol, behenyl alcohol, myristyl alcohol, oleyl alcohol, cetostearyl alcohol
- branched chain alcohols eg, monostearyl glycerin ether (batyl alcohol)
- 2-decyltetradecinol eg., phytosterol, hexyldodecanol, isostearyl alcohol, o
- the powder component examples include inorganic powders (for example, talc, kaolin, mica, sericite (sericite), muscovite, phlogopite, synthetic mica, saucite, biotite, permiculite, magnesium carbonate, calcium carbonate, silicic acid.
- inorganic powders for example, talc, kaolin, mica, sericite (sericite), muscovite, phlogopite, synthetic mica, saucite, biotite, permiculite, magnesium carbonate, calcium carbonate, silicic acid.
- natural colors e.g., chlorophyll, beta-carotene, etc.
- Natural water-soluble polymers include arabia gum, tragacanth gum, galactan, guar gum, locust bean gum, tamarint gum, carob gum, caraya gum, carrageenan, pectin, agar, quince seed (malmello), algae colloid (gypsum extract), starch (rice, corn) , Potato, wheat), plant water-soluble polymers such as glycyrrhizic acid; microbial water-soluble polymers such as xanthan gum, dextran, succinoglycan, and bullulan; animal water-soluble polymers such as collagen, casein, albumin, and gelatin Etc.
- Semi-synthetic water-soluble polymers include starch-based water-soluble polymers such as carboxymethyl starch and methylhydroxypropyl starch; methylcellulose, nitrocellulose, ethylcellulose, methylhydroxypropylcellulose, hydroxyethylcellulose, sodium cellulose sulfate, hydroxypropylcellulose, carboxy Examples thereof include cellulose-based water-soluble polymers such as methyl cellulose (CMC), crystalline cellulose, and cellulose powder; and alginic acid-based water-soluble polymers such as sodium alginate and propylene glycol alginate.
- CMC methyl cellulose
- alginic acid-based water-soluble polymers such as sodium alginate and propylene glycol alginate.
- Synthetic water-soluble polymers include vinyl water-soluble polymers such as polyvinyl alcohol, polyvinyl methyl ether, polyvinyl pyrrolidone, and carboxyvinyl polymer (Carbopol); polyethylene glycol 20,000, 4,000,000, and 600, Polyoxyethylene water-soluble polymers such as 000; copolymer water-soluble polymers such as polyoxyethylene polyoxypropylene copolymers; acrylic water-soluble polymers such as sodium polyacrylate, polyethyl acrylate, and polyacrylamide In addition, polyethyleneimine, cationic polymer and the like can be mentioned.
- vinyl water-soluble polymers such as polyvinyl alcohol, polyvinyl methyl ether, polyvinyl pyrrolidone, and carboxyvinyl polymer (Carbopol); polyethylene glycol 20,000, 4,000,000, and 600, Polyoxyethylene water-soluble polymers such as 000; copolymer water-soluble polymers such as polyoxyethylene polyoxypropylene copolymers; acrylic water-soluble
- inorganic water-soluble polymer examples include bentonite, AlMg silicate (beegum), laponite, hectorite, and anhydrous silicic acid.
- thickeners examples include karaya gum, carob gum, dextrin, sodium pectate, and dialkyldimethylammonium cellulose sulfate.
- ultraviolet absorber examples include benzoic acid-based ultraviolet absorbers (for example, paraaminobenzoic acid (hereinafter abbreviated as PABA), PABA monoglycerin ester, N, N-dipropoxy PABA ethyl ester, N, N-diethoxy PABA ethyl ester.
- PABA paraaminobenzoic acid
- PABA monoglycerin ester N, N-dipropoxy PABA ethyl ester
- N, N-diethoxy PABA ethyl ester examples include benzoic acid-based ultraviolet absorbers (for example, paraaminobenzoic acid (hereinafter abbreviated as PABA), PABA monoglycerin ester, N, N-dipropoxy PABA ethyl ester, N, N-diethoxy PABA ethyl ester.
- PABA paraaminobenzoic acid
- sequestering agent examples include 1-hydroxyethane-1,1-diphosphonic acid, 1-hydroxyethane-1,1-diphosphonic acid tetrasodium salt, disodium edetate, trisodium edetate, and tetrasodium edetate. , Sodium polyphosphate, sodium metaphosphate, gluconic acid, phosphoric acid, ascorbic acid, succinic acid, edetic acid, ethylenediamine hydroxyethyl triacetic acid trisodium, and the like.
- lower alcohols examples include ethanol, propanol, isopropanol, isobutyl alcohol, t-butyl alcohol and the like.
- Monosaccharides include, for example, tricarbon sugars (eg, D-glyceryl aldehyde, dihydroxyacetone, etc.); tetracarbon sugars (eg, D-erythrose, D-erythrulose, D-treose, erythritol, etc.); pentose sugars (eg, L-arabinose, D-xylose, L-lyxose, D-arabinose, D-ribose, D-ribulose, D-xylulose, L-xylulose, etc .; hexose (eg, D-glucose, D-talose, D) -Bucicose, D-galactose, D-fructose, L-galactose, L-mannose, D-tagatose, etc.); pentose sugar (eg, aldheptose, heproose, etc.); octo
- oligosaccharides examples include guanthianose, umbelliferose, lactose, planteose, isoliquinoses, ⁇ , ⁇ -trehalose, raffinose, lycnose, umbilicin, stachyose verbus courses and the like.
- polysaccharide examples include cellulose, quince seed, chondroitin sulfate, starch, galactan, dermatan sulfate, glycogen, gum arabic, heparan sulfate, hyaluronic acid, tragacanth gum, keratan sulfate, chondroitin, xanthan gum, mucoitin sulfate, guar gum, dextran, kerato sulfate. , Locust bean gum, succinoglucan, caronic acid and the like.
- amino acids examples include neutral amino acids (eg, threonine, cysteine, etc.); basic amino acids (eg, hydroxylysine, etc.), and the like.
- amino acid derivatives include acyl sarcosine sodium (lauroyl sarcosine sodium), acyl glutamate, acyl ⁇ -alanine sodium, glutathione, pyrrolidone carboxylic acid and the like.
- organic amines examples include monoethanolamine, diethanolamine, triethanolamine, morpholine, triisopropanolamine, 2-amino-2-methyl-1,3-propanediol, and 2-amino-2-methyl-1-propanol. Is mentioned.
- pH adjusting agent examples include buffers such as lactic acid-sodium lactate and succinic acid-sodium succinate.
- vitamins examples include vitamins A, B1, B2, B6, C, E and derivatives thereof, pantothenic acid and derivatives thereof, and biotin.
- antioxidants examples include tocopherols, dibutylhydroxytoluene, butylhydroxyanisole, gallic acid esters and the like.
- antioxidant assistant examples include phosphoric acid, ascorbic acid, maleic acid, malonic acid, succinic acid, fumaric acid, kephalin, hexametaphosphate, phytic acid, ethylenediaminetetraacetic acid and the like.
- preservatives ethyl paraben, butyl paraben, etc.
- anti-inflammatory agents eg, glycyrrhizic acid derivatives, glycyrrhetinic acid derivatives, salicylic acid derivatives, hinokitiol, zinc oxide, allantoin, etc.
- whitening agents For example, placenta extract, saxifrage extract, arbutin, etc.
- various extracts eg, buckwheat, auren, shikon, peonies, assembly, birch, sage, loquat, carrot, aloe, mallow), iris, grape, yokuinin, loofah, Lily, saffron, nematode, ginger, hypericum, onionis, garlic, capsicum, chimpi, toki, seaweed, etc.
- activator for example, royal jelly, photosensitizer, cholesterol derivative, etc.
- blood circulation promoter for example, royal jelly, photosen
- the hair treatment method according to the present invention is a method in which at least the contact steps (I) to (III) are performed simultaneously or in any order. Moreover, a heating process (IV) can also be further performed as needed.
- each step will be described in detail. The details of agent A, agent B and agent C used in each step are the same as agent A, agent B and agent C used in the cosmetic kit and hair treatment agent kit described above. I will omit the explanation.
- the contact step (I) is a step of bringing the agent A containing magnesium hydride into contact with the hair.
- the specific method is not particularly limited as long as magnesium hydride can be brought into contact with the hair, and can be freely set.
- a propellant such as LPG, DME, or hexane is mainly blended, and a non-gas foaming type may be used.
- the contact step (I) by mixing magnesium hydride with a known hair treatment agent such as a permanent agent and a hair dye, and applying this to the hair.
- a known hair treatment agent such as a permanent agent and a hair dye
- Contacting step (II) is a step of bringing hair B into contact with hair containing a substance whose aqueous solution shows acidity.
- the specific method is not particularly limited and can be freely set as long as the hair can be brought into contact with an acidic substance.
- the B agent containing a substance whose aqueous solution is acidic is prepared in a cream, lotion, gel, paste, powder, solid, foam or spray form, and this is applied to the hair.
- a propellant such as LPG, DME, or hexane is mainly blended, and a non-gas foaming type may be used.
- the contact step (II) by mixing a substance in which the aqueous solution shows acidity with a known hair treatment agent such as a permanent agent and a hair dye, and applying this to the hair.
- a known hair treatment agent such as a permanent agent and a hair dye
- known hair treatment agents containing substances whose aqueous solutions exhibit acidity are used. It can also be used as the B agent of the present invention.
- the contact step (III) is a step of bringing the C agent containing water into contact with the hair.
- the specific method is not particularly limited as long as the hair can be brought into contact with water, and can be freely set.
- the C agent containing water is prepared in the form of cream, lotion, gel, paste, powder, solid, foam or spray, and this is applied to the hair.
- a propellant such as LPG, DME, or hexane is mainly blended, and a non-gas foaming type may be used.
- the contact step (III) by mixing water with a known hair treatment agent such as a permanent agent and a hair dye, and applying this to the hair.
- a known hair treatment agent such as a permanent agent and a hair dye
- a known hair treatment agent containing water may be used as the C agent of the present invention. Is possible.
- the hair treatment method according to the present invention is performed before the hair treatment method according to the present invention is performed, the hair is wetted with a pre-shampoo or a spray bottle, and the hair treatment method according to the present invention is performed in a state where the hair is wet. It is also possible to obtain the same effect as in (III).
- the contact steps (I) to (III) described above can be performed all at the same time. For example, by adding magnesium hydride and a substance whose aqueous solution shows acidity to a known hair treatment agent containing water and applying it to the hair, the contact steps (I) to (III) are substantially simultaneously performed. It can be carried out. Further, by adding magnesium hydride to a known hair treatment agent containing a substance whose aqueous solution is acidic and water, the contact steps (I) to (III) are substantially performed by applying this to hair. Can be done simultaneously.
- the contact steps (I) to (III) can be performed in any order.
- the agent A containing magnesium hydride and the agent B containing a substance whose aqueous solution is acidic are applied to the hair in any order. can do.
- the agent A containing magnesium hydride and the agent B containing a substance whose aqueous solution exhibits acidity may be applied to the hair in a premixed state.
- the agent A containing magnesium hydride can be applied to the hair before or after applying a known hair treatment agent containing a substance whose aqueous solution is acidic and water.
- a agent containing magnesium hydride, B agent containing a substance whose aqueous solution shows acidity, and C agent containing water it is also possible to apply to the hair simultaneously or in any order.
- the A agent, the B agent, and the C agent are applied to the hair at the same time, they can be applied as they are, or they can be mixed and applied on the spot. It is also possible to apply a mixture of agent A, agent B and agent C in advance.
- Heating step (IV) is a step of heating the hair after the contact steps (I) to (III). Usually, the contact steps (I) to (III) are carried out, followed by a standing step for a predetermined time, and then the heating step (IV) is carried out after removing the hair treatment agent from the hair with a shampoo or the like.
- heating process (IV) is not an essential process in this invention, in order to improve the water
- the heating temperature in the heating step (IV) is not particularly limited as long as the effects of the present invention are not impaired, and can be freely set according to the equipment and purpose used for heating.
- the heating temperature in the heating step (IV) is preferably 60 to 230 ° C., more preferably 100 to 230 ° C., and still more preferably 180 to 220 ° C. The reason for this is as follows.
- the result is that the amount of water in the hair is increased by heating the hair.
- the heating temperature By setting the heating temperature to 60 ° C. or higher, the moisture content in the hair can be increased more reliably. Moreover, the hair damage by heat can be prevented by setting heating temperature to 230 degrees C or less. Furthermore, as shown in the Example mentioned later, it is possible to raise the moisture content in hair, so that heating temperature is made high.
- the heating method in the heating step (IV) is not particularly limited as long as the effects of the present invention are not impaired, and a heat treatment apparatus or the like used in normal hair treatment can be freely selected and used.
- a heat treatment apparatus or the like used in normal hair treatment can be freely selected and used.
- exothermic devices such as a hair dryer, hot curler, heater, and hair iron can be used.
- Heating step (IV) can be performed in two stages. For example, after removing the hair treatment agent from the hair with a shampoo, etc., first the water on the hair surface is evaporated with a drier etc., and then the hair is heated at a higher temperature using a hair iron etc. It is also possible to increase the amount of water inside more effectively.
- pre-shampooing can be performed before the actual hair treatment in order to remove dirt, hair dressing, and the like attached to the hair surface.
- This pre-shampoo is not an essential step in the hair treatment method according to the present invention, but is preferably performed when, for example, silicone oil or the like is attached to the hair. By performing pre-shampooing, the hair treatment effect can be further improved.
- a hair treatment agent is prepared according to the type of hair treatment to be performed. More specifically, for example, all or a part of the A agent, B agent, and C agent of the present invention are mixed with the first permanent agent and / or the second permanent agent to obtain a hair treatment agent (permanent treatment). Agent), or all or part of agent A, agent B, and agent C are mixed with hair dye first agent and / or hair dye second agent to prepare a hair treatment agent (hair dye). Can be prepared. In this way, by mixing all or part of the A agent, B agent, and C agent of the present invention into the permanent agent or hair dye, the active oxygen generated by the treatment while performing the permanent treatment or hair color treatment. Is removed by hydrogen in the hair treatment agent to prevent damage to the hair and scalp, and at the same time, the amount of moisture in the hair is increased by the combination of hydrogen and active oxygen, and the hair quality can be improved.
- a hair treatment agent hair quality improving agent
- hair treatment agent hair quality improving agent
- an oxidizing agent that generates active oxygen during hair treatment.
- oxidizing agent examples include bromate such as sodium bromate and potassium bromate; perborate such as sodium perborate; hydrogen peroxide and the like.
- the hair treatment agent is applied to the hair.
- the method for applying the hair treatment agent to the hair can be performed according to a conventional method depending on the type of the hair treatment agent. For example, in the case of permanent treatment, after applying the first agent of the permanent agent with the hair fixed in a desired shape, it is allowed to stand, rinse, etc. if necessary, and then apply the second agent of the permanent agent. be able to.
- a method of applying the mixture of the hair dye first agent and the hair dye second agent prepared in the preparation of the hair treatment agent to the hair as it is can be used.
- the A agent, the B agent, and the C agent of the present invention can be applied to the hair in a state where all or a part thereof is mixed with a hair treatment agent such as a permanent agent or a hair dye.
- a hair treatment agent such as a permanent agent or a hair dye.
- the hair treatment agent containing all or part of the agent A, agent B and agent C of the present invention may be further applied to the hair. it can.
- the hair treatment agent it is preferable to apply the hair treatment agent while the hair is wet.
- the hair treatment agent By applying the hair treatment agent while the hair is wet, the hair treatment agent can be applied more uniformly.
- the hair treatment agent since the hair is wet, substantially the same effect can be obtained without bothering the contact step (III) of bringing the C agent containing water into contact with the hair.
- the hair treatment agent After applying the hair treatment agent to the hair, the hair treatment agent is left as it is for a predetermined time.
- hydrolysis reaction of magnesium hydride in the agent A and water in the agent C continuously proceeds on the surface of the hair, inside the hair, and the scalp, and hydrogen is generated.
- the time for leaving is not particularly limited, and can be freely set according to the purpose of hair treatment, the quality of the hair, the degree of damage to the hair and / or the scalp, and the like.
- it is preferably left for 5 to 30 minutes, more preferably left for 10 to 20 minutes.
- heating can be appropriately performed in accordance with the type of hair treatment agent and the like when left.
- the method for removing the hair treatment agent is not particularly limited, and can be removed using water, a shampoo agent, a rinse agent, or the like.
- treatment such as treatment can be performed as appropriate.
- the method for the drying treatment is not particularly limited, and examples thereof include a method of drying using a hair dryer after towel drying according to a conventional method.
- the drying process it is possible to perform drying by natural drying.
- the moisture content in the hair is improved by heating the hair after the contact steps (I) to (III). Therefore, in the present invention, it is preferable to perform a drying treatment by heating.
- Example demonstrated below shows an example of the typical Example of this invention, and, thereby, the range of this invention is not interpreted narrowly.
- Example 2 Cream After preparing agent A, agent B and agent C with the formulation shown in Table 2 below, cream was prepared by mixing agent A, agent B and agent C.
- Example 3 Lotion After preparing agent A, agent B and agent C with the formulation shown in Table 3, the agent A, agent B and agent C were mixed to prepare a lotion.
- Agent A Agent B and Agent C in the formulation shown in Table 4 below, the Agent A Agent, Agent B, and Agent C are mixed, and then Agent Permanent Agent First Agent. Was prepared.
- Perm Agent Second Agent After preparing Agent A, Agent B and Agent C in the formulation shown in Table 5 below, Perm Agent Agent 2 is prepared by mixing Agent A, Agent B and Agent C. Was prepared.
- Hair dye No. 1 agent After preparing agent A, agent B and agent C with the formulation shown in Table 6 below, hair agent No. 1 is prepared by mixing agent A, agent B and agent C. One agent was prepared.
- hair dye No. 2 agent After preparing agent A, agent B and agent C with the formulation shown in Table 7 below, hair agent No. 2 is prepared by mixing agent A, agent B and agent C. Two agents were prepared.
- Hair dye A hair dye was prepared by mixing the hair dye first agent prepared in Example 6 and the hair dye second agent prepared in Example 7.
- Cosmetic fluid A cosmetic fluid was prepared in the same manner as in Example 1 without blending the agent A during the blending shown in Table 1.
- Cosmetic fluid A cosmetic fluid was prepared in the same manner as in Example 1 without blending the B agent during the blending shown in Table 1 above.
- Comparative Examples 1, 3, 4 and 6 in which neither A agent nor hydrogen water was blended, no color reaction was observed even when methylene blue was added dropwise.
- Comparative Example 2 in which the B agent was not blended, no color reaction was observed immediately after the methylene blue was dropped, but the color gradually showed coloration. However, the coloration was very thin. In addition, it remained very light and did not disappear after 13 hours.
- Comparative Examples 5, 7 and 8 in which hydrogen water was blended in place of the A agent and the C agent showed a color reaction immediately after dropping methylene blue, but all the color reaction disappeared after 3 minutes. From this result, it was found that the hydrolysis reaction of magnesium hydride progressed very slowly and slowly if the B agent was not added even when the A agent was added. Moreover, it was possible to generate hydrogen by adding hydrogen water, but it was found difficult to generate hydrogen continuously.
- Example 4 and Comparative Example 4 prepared in Experimental Example 1 were applied to the left and right sides of the same subject's hair, and evenly wrapped around a 7.0 mm diameter rod. , Left for 15 minutes. Thereafter, it was subjected to intermediate washing using 36 ° C. lukewarm water, and the second permanent agent of Example 5 and Comparative Example 5 prepared in Experimental Example 1 was applied to the left and right sides of the same subject's hair, and left for 15 minutes. did. Then, it wash
- the wave effect was stronger in the case where the permanent treatment was performed using the permanent agents of Examples 4 and 5, and the sustaining effect was maintained. The nature was also high.
- the case where the hair dyeing process is performed using the hair dyes of Comparative Examples 6 and 7 is the hair dyeing process.
- Example 4 In Experimental Example 4, it was examined how the moisture content, strength, and appearance of hair change when the hair treatment according to the present invention is used in combination in a hair treatment step using a known hair treatment agent. .
- a known hair treatment agent Adiro (registered trademark) manufactured by Maltbane Professional Co., Ltd. is used as the first agent of the hair dye (hair color agent), and 1.8% hydrogen peroxide ( Sowan Co., Ltd.) was used.
- the hair dye first agent and the second agent were mixed, and 0.3 g of magnesium hydride was added thereto and mixed to prepare a hair treatment agent.
- the prepared hair treatment agent was applied to the whole hair of three subjects who had been pre-shampooed, and allowed to stand for 15 minutes. Then, it wash
- Results The results of water content measurement for each subject are shown in Table 11 below, and the average value is shown in FIG. Moreover, the result of the intensity
- the cosmetic kit and hair treatment kit according to the present invention can secure sufficient hydrogen during use and can remove oxidative stress. In addition, stability during long-term storage is high.
- the cosmetic kit according to the present invention can provide the skin with a lift-up effect, a tightening effect, and a sagging / wrinkle-preventing effect by continuing use. Therefore, the cosmetic kit according to the present invention can be applied in a wide range of fields for the purpose of promoting health and anti-aging.
- the main components of the agent A, agent B and agent C according to the present invention do not affect other agents or dyes in the hair treatment agent when used as a hair treatment agent kit, It does not affect the color development when dyeing hair. Rather, as shown in the embodiment, the effect and sustainability can be improved. Therefore, when the kit for hair treatment agents according to the present invention is used, the hair treatment and the removal treatment of oxidative stress due to hydrogen can be performed integrally. Therefore, compared to the prior art, damage to the hair, scalp and the like given during the hair dyeing process is reduced, and it is possible to perform hair care at the same time in one process.
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Abstract
Le problème décrit par la présente invention est de pourvoir à une nouvelle technologie au moyen de laquelle le stress oxydatif de la peau et des cheveux peut être prévenu de façon efficace, ledit stress oxydatif étant provoqué par l'oxygène actif et des radicaux libres. La solution de l'invention porte sur un kit cosmétique qui comprend un agent (A) contenant de l'hydrure de magnésium, un agent (B) contenant une substance qui présente une acidité dans une solution aqueuse, et un agent (C) contenant de l'eau, un produit cosmétique étant obtenu par mélange de l'agent (A), de l'agent (B), et de l'agent (C) au moment de l'utilisation. L'invention concerne également un kit d'agent de traitement capillaire qui comprend un agent (A) contenant de l'hydrure de magnésium, un agent (B) contenant une substance qui présente une acidité dans une solution aqueuse, et un agent (C) contenant de l'eau.
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JP2015541568A JP6356138B2 (ja) | 2013-10-09 | 2014-10-06 | 毛髪処理剤用キット及び毛髪処理方法 |
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JP2013223669 | 2013-10-09 | ||
JP2013-223669 | 2013-10-09 |
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WO2015053225A1 true WO2015053225A1 (fr) | 2015-04-16 |
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PCT/JP2014/076710 WO2015053225A1 (fr) | 2013-10-09 | 2014-10-06 | Kit cosmétique et kit d'agent de traitement capillaire, et méthode de traitement capillaire |
Country Status (3)
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JP (1) | JP6356138B2 (fr) |
TW (1) | TW201526943A (fr) |
WO (1) | WO2015053225A1 (fr) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2016010139A1 (fr) * | 2014-07-18 | 2016-01-21 | 株式会社ヴェルシーナ | Agent d'enduisage cosmétique, procédé de production d'un produit de charge cosmétique à base d'hydrogène, et produit de charge cosmétique à base d'hydrogène |
JP2017088518A (ja) * | 2015-11-05 | 2017-05-25 | Cts株式会社 | マッサージ方法及びマッサージ用セット |
JP2018523714A (ja) * | 2015-08-21 | 2018-08-23 | コングク ユニバーシティ インダストリアル コーオペレーション コーポレーション | 水素水を含むヘアパーマ形成用酸化剤及びこれを用いたヘアパーマ形成方法 |
Families Citing this family (1)
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DE4420449C5 (de) | 1994-02-15 | 2004-02-05 | Thermoselect Ag | Verfahren zum Lagern von heterogenem Müll |
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JP2003095915A (ja) * | 2001-09-25 | 2003-04-03 | Shiseido Co Ltd | 皮膚外用組成物 |
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WO2007055146A1 (fr) * | 2005-11-10 | 2007-05-18 | Hiromaito Co., Ltd. | Agent générant de l'hydrogène et utilisation de celui-ci |
JP6081729B2 (ja) * | 2012-07-31 | 2017-02-15 | クラシエホームプロダクツ株式会社 | 水素発生用組成物 |
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- 2014-10-06 WO PCT/JP2014/076710 patent/WO2015053225A1/fr active Application Filing
- 2014-10-06 TW TW103134768A patent/TW201526943A/zh unknown
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WO2009084743A1 (fr) * | 2007-12-28 | 2009-07-09 | Miz Co., Ltd. | Préparation externe pour utilisation préventive ou thérapeutique |
JP2012171875A (ja) * | 2011-02-18 | 2012-09-10 | Dr's Choice Co Ltd | 粉末浴用化粧料 |
JP2013253036A (ja) * | 2012-06-07 | 2013-12-19 | Kracie Home Products Ltd | 血行促進剤、発汗促進剤及び浴用組成物 |
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JP2014084233A (ja) * | 2012-10-19 | 2014-05-12 | Seiji Endo | 水素発生用乾燥シート |
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WO2016010139A1 (fr) * | 2014-07-18 | 2016-01-21 | 株式会社ヴェルシーナ | Agent d'enduisage cosmétique, procédé de production d'un produit de charge cosmétique à base d'hydrogène, et produit de charge cosmétique à base d'hydrogène |
JPWO2016010139A1 (ja) * | 2014-07-18 | 2017-04-27 | 株式会社ヴェルシーナ | 化粧用塗布剤、化粧用水素充填物の製造方法および化粧用水素充填物 |
JP2018523714A (ja) * | 2015-08-21 | 2018-08-23 | コングク ユニバーシティ インダストリアル コーオペレーション コーポレーション | 水素水を含むヘアパーマ形成用酸化剤及びこれを用いたヘアパーマ形成方法 |
EP3354252A4 (fr) * | 2015-08-21 | 2019-08-07 | Konkuk University Industrial Cooperation Corp. | Agent oxydant destiné à permanente des cheveux contenant de l'eau hydrogénée, et méthode de permanente des cheveux correspondante |
JP2017088518A (ja) * | 2015-11-05 | 2017-05-25 | Cts株式会社 | マッサージ方法及びマッサージ用セット |
Also Published As
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JP6356138B2 (ja) | 2018-07-11 |
JPWO2015053225A1 (ja) | 2017-03-09 |
TW201526943A (zh) | 2015-07-16 |
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