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WO2009009158A3 - Production métathétique de polymères fonctionnalisés - Google Patents

Production métathétique de polymères fonctionnalisés Download PDF

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Publication number
WO2009009158A3
WO2009009158A3 PCT/US2008/054395 US2008054395W WO2009009158A3 WO 2009009158 A3 WO2009009158 A3 WO 2009009158A3 US 2008054395 W US2008054395 W US 2008054395W WO 2009009158 A3 WO2009009158 A3 WO 2009009158A3
Authority
WO
WIPO (PCT)
Prior art keywords
functionalized
metathetic
unsaturated polymer
production
containing cyclic
Prior art date
Application number
PCT/US2008/054395
Other languages
English (en)
Other versions
WO2009009158A2 (fr
Inventor
Daniel J Arriola
Francis J Timmers
Paul C Vosejpka
Nicole L Wagner
Original Assignee
Dow Global Technologies Inc
Daniel J Arriola
Francis J Timmers
Paul C Vosejpka
Nicole L Wagner
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Global Technologies Inc, Daniel J Arriola, Francis J Timmers, Paul C Vosejpka, Nicole L Wagner filed Critical Dow Global Technologies Inc
Publication of WO2009009158A2 publication Critical patent/WO2009009158A2/fr
Publication of WO2009009158A3 publication Critical patent/WO2009009158A3/fr

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08CTREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
    • C08C19/00Chemical modification of rubber
    • C08C19/04Oxidation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22Organic complexes
    • B01J31/2265Carbenes or carbynes, i.e.(image)
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08CTREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
    • C08C19/00Chemical modification of rubber
    • C08C19/28Reaction with compounds containing carbon-to-carbon unsaturated bonds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00Chemical modification by after-treatment
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00Chemical modification by after-treatment
    • C08F8/46Reaction with unsaturated dicarboxylic acids or anhydrides thereof, e.g. maleinisation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/50Redistribution or isomerisation reactions of C-C, C=C or C-C triple bonds
    • B01J2231/54Metathesis reactions, e.g. olefin metathesis
    • B01J2231/543Metathesis reactions, e.g. olefin metathesis alkene metathesis
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82Metals of the platinum group
    • B01J2531/821Ruthenium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82Metals of the platinum group
    • B01J2531/825Osmium

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

L'invention concerne un procédé pour préparer un polymère fonctionnalisé, dont les étapes impliquent de mettre en contact un catalyseur de métathèse dans des conditions de métathèse avec une composition comprenant : (a) au moins un polymère éthyléniquement insaturé caractérisé en ce que le polymère insaturé est essentiellement immunisé contre la dégradation métathétique ; (b) au moins un éthylène fonctionnalisé contenant un composé de réactif cyclique ou acyclique, le polymère éthyléniquement insaturé et l'éthylène fonctionnalisé contenant un composé de réactif cyclique ou acyclique ayant un degré combiné de substitution de 4 ou moins de 4 ; et (c) facultativement un ou plusieurs solvants ou diluants, et de récupérer le produit fonctionnalisé de réaction polymère résultant.
PCT/US2008/054395 2007-03-21 2008-02-20 Production métathétique de polymères fonctionnalisés WO2009009158A2 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US91922307P 2007-03-21 2007-03-21
US60/919,223 2007-03-21

Publications (2)

Publication Number Publication Date
WO2009009158A2 WO2009009158A2 (fr) 2009-01-15
WO2009009158A3 true WO2009009158A3 (fr) 2009-04-16

Family

ID=40229366

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2008/054395 WO2009009158A2 (fr) 2007-03-21 2008-02-20 Production métathétique de polymères fonctionnalisés

Country Status (1)

Country Link
WO (1) WO2009009158A2 (fr)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FI123188B (fi) 2005-04-05 2012-12-14 Bayer Oy Ultraäänellä havaittavissa oleva kohdunsisäinen järjestelmä
US8372930B2 (en) * 2008-06-20 2013-02-12 Exxonmobil Chemical Patents Inc. High vinyl terminated propylene based oligomers
US8283419B2 (en) 2008-06-20 2012-10-09 Exxonmobil Chemical Patents Inc. Olefin functionalization by metathesis reaction
WO2010051268A1 (fr) 2008-10-31 2010-05-06 Dow Global Technologies Inc. Procédé de métathèse d'oléfines employant un complexe bimétallique du ruthénium avec des ligands pontants hydrido
EP2484700B1 (fr) 2011-02-04 2013-10-09 LANXESS Deutschland GmbH Caoutchoucs nitriles fonctionnalisés et leur fabrication
US8841397B2 (en) 2011-03-25 2014-09-23 Exxonmobil Chemical Patents Inc. Vinyl terminated higher olefin polymers and methods to produce thereof
US8940839B2 (en) 2011-03-25 2015-01-27 Exxonmobil Chemical Patents Inc. Diblock copolymers prepared by cross metathesis
US8835563B2 (en) 2011-03-25 2014-09-16 Exxonmobil Chemical Patents Inc. Block copolymers from silylated vinyl terminated macromers
US8623974B2 (en) 2011-03-25 2014-01-07 Exxonmobil Chemical Patents Inc. Branched vinyl terminated polymers and methods for production thereof
US8399724B2 (en) 2011-03-25 2013-03-19 Exxonmobil Chemical Patents Inc. Vinyl terminated higher olefin copolymers and methods to produce thereof
ES2808548T3 (es) * 2013-01-17 2021-03-01 Pat&Co Bvba DIU híbrido liberador de cobre con brazo de retención conectado a un cuerpo sin marco
EP2835381A1 (fr) 2013-08-09 2015-02-11 Lanxess Elastomers B.V. Copolymères oléfiniques fonctionnalisés
CN106589245B (zh) * 2015-10-20 2018-11-30 中国石油化工股份有限公司 一种改性三元乙丙橡胶及其制备方法
CN106589246B (zh) * 2015-10-20 2018-11-30 中国石油化工股份有限公司 一种改性三元乙丙橡胶及其制备方法
CN112457435A (zh) * 2019-09-06 2021-03-09 中国石油化工股份有限公司 一种改性三元乙丙橡胶及其制备方法
CN113896837A (zh) * 2020-06-22 2022-01-07 中国石油化工股份有限公司 改性三元乙丙橡胶及其制备方法

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1264127A (fr) * 1968-06-10 1972-02-16
GB1508871A (en) * 1975-05-21 1978-04-26 Japan Synthetic Rubber Co Ltd Copolymers of norbornene derivatives and process for producing same
JP2005139284A (ja) * 2003-11-06 2005-06-02 National Institute Of Advanced Industrial & Technology 官能基化ポリプロピレンの製造方法

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1264127A (fr) * 1968-06-10 1972-02-16
GB1508871A (en) * 1975-05-21 1978-04-26 Japan Synthetic Rubber Co Ltd Copolymers of norbornene derivatives and process for producing same
JP2005139284A (ja) * 2003-11-06 2005-06-02 National Institute Of Advanced Industrial & Technology 官能基化ポリプロピレンの製造方法

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
MARCINIEC B ET AL: "Functionalization of 1,2-polybutadiene by ruthenium complex catalysed coupling with vinylsilanes", POLYMER, ELSEVIER SCIENCE PUBLISHERS B.V, GB, vol. 38, no. 20, 1 January 1997 (1997-01-01), pages 5169 - 5172, XP004087908, ISSN: 0032-3861 *
MATHERS R T ET AL: "Cross Metathesis Functionalization of Polyolefins - SUPPORTING INFORMATION", CHEMICAL COMMUNICATIONS, 22 January 2004 (2004-01-22), XP002514148, Retrieved from the Internet <URL:http://www.rsc.org/suppdata/cc/b3/b313954a/> [retrieved on 20090206] *
MATHERS R T ET AL: "Cross Metathesis Functionalization of Polyolefins", CHEMICAL COMMUNICATIONS 20040221 GB, no. 4, 21 February 2004 (2004-02-21), pages 422 - 423, XP002514147, ISSN: 1359-7345 *

Also Published As

Publication number Publication date
WO2009009158A2 (fr) 2009-01-15

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