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WO2009009158A3 - Metathetic production of functionalized polymers - Google Patents

Metathetic production of functionalized polymers Download PDF

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Publication number
WO2009009158A3
WO2009009158A3 PCT/US2008/054395 US2008054395W WO2009009158A3 WO 2009009158 A3 WO2009009158 A3 WO 2009009158A3 US 2008054395 W US2008054395 W US 2008054395W WO 2009009158 A3 WO2009009158 A3 WO 2009009158A3
Authority
WO
WIPO (PCT)
Prior art keywords
functionalized
metathetic
unsaturated polymer
production
containing cyclic
Prior art date
Application number
PCT/US2008/054395
Other languages
French (fr)
Other versions
WO2009009158A2 (en
Inventor
Daniel J Arriola
Francis J Timmers
Paul C Vosejpka
Nicole L Wagner
Original Assignee
Dow Global Technologies Inc
Daniel J Arriola
Francis J Timmers
Paul C Vosejpka
Nicole L Wagner
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Global Technologies Inc, Daniel J Arriola, Francis J Timmers, Paul C Vosejpka, Nicole L Wagner filed Critical Dow Global Technologies Inc
Publication of WO2009009158A2 publication Critical patent/WO2009009158A2/en
Publication of WO2009009158A3 publication Critical patent/WO2009009158A3/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
    • C08C19/00—Chemical modification of rubber
    • C08C19/04—Oxidation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2265—Carbenes or carbynes, i.e.(image)
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
    • C08C19/00—Chemical modification of rubber
    • C08C19/28—Reaction with compounds containing carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/46—Reaction with unsaturated dicarboxylic acids or anhydrides thereof, e.g. maleinisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/50—Redistribution or isomerisation reactions of C-C, C=C or C-C triple bonds
    • B01J2231/54—Metathesis reactions, e.g. olefin metathesis
    • B01J2231/543—Metathesis reactions, e.g. olefin metathesis alkene metathesis
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/821—Ruthenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/825—Osmium

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

A process for preparing a functionalized polymer, the steps of the process involving contacting a metathesis catalyst under metathesis conditions with a composition comprising: (a) at least one ethylenically unsaturated polymer characterized in that the unsaturated polymer is substantially immune to metathetic degradation; (b) at least one functionalized ethylene containing cyclic or acyclic reagent compound, wherein the ethylenically unsaturated polymer and the functionalized ethylene containing cyclic or acyclic reagent compound have a combined degree of substitution of 4 or less than 4; and (c) optionally one or more solvents or diluents, and recovering the resulting functionalized polymeric reaction product.
PCT/US2008/054395 2007-03-21 2008-02-20 Metathetic production of functionalized polymers WO2009009158A2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US91922307P 2007-03-21 2007-03-21
US60/919,223 2007-03-21

Publications (2)

Publication Number Publication Date
WO2009009158A2 WO2009009158A2 (en) 2009-01-15
WO2009009158A3 true WO2009009158A3 (en) 2009-04-16

Family

ID=40229366

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2008/054395 WO2009009158A2 (en) 2007-03-21 2008-02-20 Metathetic production of functionalized polymers

Country Status (1)

Country Link
WO (1) WO2009009158A2 (en)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FI123188B (en) 2005-04-05 2012-12-14 Bayer Oy With ultrasound detectable intrauterine system
US8372930B2 (en) * 2008-06-20 2013-02-12 Exxonmobil Chemical Patents Inc. High vinyl terminated propylene based oligomers
US8283419B2 (en) 2008-06-20 2012-10-09 Exxonmobil Chemical Patents Inc. Olefin functionalization by metathesis reaction
WO2010051268A1 (en) 2008-10-31 2010-05-06 Dow Global Technologies Inc. Olefin metathesis process employing bimetallic ruthenium complex with bridging hydrido ligands
EP2484700B1 (en) 2011-02-04 2013-10-09 LANXESS Deutschland GmbH Functionalised nitrile rubbers and their manufacture
US8841397B2 (en) 2011-03-25 2014-09-23 Exxonmobil Chemical Patents Inc. Vinyl terminated higher olefin polymers and methods to produce thereof
US8940839B2 (en) 2011-03-25 2015-01-27 Exxonmobil Chemical Patents Inc. Diblock copolymers prepared by cross metathesis
US8835563B2 (en) 2011-03-25 2014-09-16 Exxonmobil Chemical Patents Inc. Block copolymers from silylated vinyl terminated macromers
US8623974B2 (en) 2011-03-25 2014-01-07 Exxonmobil Chemical Patents Inc. Branched vinyl terminated polymers and methods for production thereof
US8399724B2 (en) 2011-03-25 2013-03-19 Exxonmobil Chemical Patents Inc. Vinyl terminated higher olefin copolymers and methods to produce thereof
ES2808548T3 (en) * 2013-01-17 2021-03-01 Pat&Co Bvba Copper-releasing hybrid IUD with retention arm attached to a frameless body
EP2835381A1 (en) 2013-08-09 2015-02-11 Lanxess Elastomers B.V. Functionalized olefinic copolymers
CN106589245B (en) * 2015-10-20 2018-11-30 中国石油化工股份有限公司 A kind of modified EPT rubber and preparation method thereof
CN106589246B (en) * 2015-10-20 2018-11-30 中国石油化工股份有限公司 A kind of modified EPT rubber and preparation method thereof
CN112457435A (en) * 2019-09-06 2021-03-09 中国石油化工股份有限公司 Modified ethylene propylene diene monomer rubber and preparation method thereof
CN113896837A (en) * 2020-06-22 2022-01-07 中国石油化工股份有限公司 Modified ethylene propylene diene monomer and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1264127A (en) * 1968-06-10 1972-02-16
GB1508871A (en) * 1975-05-21 1978-04-26 Japan Synthetic Rubber Co Ltd Copolymers of norbornene derivatives and process for producing same
JP2005139284A (en) * 2003-11-06 2005-06-02 National Institute Of Advanced Industrial & Technology Method for producing functionalized polypropylene

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1264127A (en) * 1968-06-10 1972-02-16
GB1508871A (en) * 1975-05-21 1978-04-26 Japan Synthetic Rubber Co Ltd Copolymers of norbornene derivatives and process for producing same
JP2005139284A (en) * 2003-11-06 2005-06-02 National Institute Of Advanced Industrial & Technology Method for producing functionalized polypropylene

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
MARCINIEC B ET AL: "Functionalization of 1,2-polybutadiene by ruthenium complex catalysed coupling with vinylsilanes", POLYMER, ELSEVIER SCIENCE PUBLISHERS B.V, GB, vol. 38, no. 20, 1 January 1997 (1997-01-01), pages 5169 - 5172, XP004087908, ISSN: 0032-3861 *
MATHERS R T ET AL: "Cross Metathesis Functionalization of Polyolefins - SUPPORTING INFORMATION", CHEMICAL COMMUNICATIONS, 22 January 2004 (2004-01-22), XP002514148, Retrieved from the Internet <URL:http://www.rsc.org/suppdata/cc/b3/b313954a/> [retrieved on 20090206] *
MATHERS R T ET AL: "Cross Metathesis Functionalization of Polyolefins", CHEMICAL COMMUNICATIONS 20040221 GB, no. 4, 21 February 2004 (2004-02-21), pages 422 - 423, XP002514147, ISSN: 1359-7345 *

Also Published As

Publication number Publication date
WO2009009158A2 (en) 2009-01-15

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