WO2008123323A1 - Procédé de fabrication de polyol et le polyol obtenu - Google Patents
Procédé de fabrication de polyol et le polyol obtenu Download PDFInfo
- Publication number
- WO2008123323A1 WO2008123323A1 PCT/JP2008/055777 JP2008055777W WO2008123323A1 WO 2008123323 A1 WO2008123323 A1 WO 2008123323A1 JP 2008055777 W JP2008055777 W JP 2008055777W WO 2008123323 A1 WO2008123323 A1 WO 2008123323A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- polyol
- castor oil
- group
- compounds
- initiator
- Prior art date
Links
- 229920005862 polyol Polymers 0.000 title abstract 5
- 150000003077 polyols Chemical class 0.000 title abstract 5
- 238000000034 method Methods 0.000 title abstract 4
- 239000004359 castor oil Substances 0.000 abstract 4
- 235000019438 castor oil Nutrition 0.000 abstract 4
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 abstract 4
- 239000003999 initiator Substances 0.000 abstract 3
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 2
- 238000010538 cationic polymerization reaction Methods 0.000 abstract 2
- 150000002391 heterocyclic compounds Chemical class 0.000 abstract 2
- 238000007142 ring opening reaction Methods 0.000 abstract 2
- 239000002028 Biomass Substances 0.000 abstract 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 abstract 1
- 150000001639 boron compounds Chemical class 0.000 abstract 1
- 239000006227 byproduct Substances 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 150000004292 cyclic ethers Chemical class 0.000 abstract 1
- 125000004122 cyclic group Chemical group 0.000 abstract 1
- 125000004407 fluoroaryl group Chemical group 0.000 abstract 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract 1
- 239000002685 polymerization catalyst Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4891—Polyethers modified with higher fatty oils or their acids or by resin acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/04—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers only
- C08G65/06—Cyclic ethers having no atoms other than carbon and hydrogen outside the ring
- C08G65/08—Saturated oxiranes
- C08G65/10—Saturated oxiranes characterised by the catalysts used
- C08G65/12—Saturated oxiranes characterised by the catalysts used containing organo-metallic compounds or metal hydrides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
- C08G65/2603—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds the other compounds containing oxygen
- C08G65/2615—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds the other compounds containing oxygen the other compounds containing carboxylic acid, ester or anhydride groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
- C08G65/2642—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the catalyst used
- C08G65/2645—Metals or compounds thereof, e.g. salts
- C08G65/2654—Aluminium or boron; Compounds thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Polyethers (AREA)
- Polyurethanes Or Polyureas (AREA)
Abstract
L'invention porte sur un procédé de fabrication d'un polyol ayant une proportion de biomasse élevée en amenant l'oxyde d'éthylène à subir de manière égale une addition par ouverture de cycle à de l'huile de ricin ou à un condensat d'huile de ricin comme amorceur en présence d'un catalyseur et en formation des groupes hydroxyle primaires à un rendement élevé tout en empêchant l'amorceur de se décomposer et de générer par là un sous-produit à faible masse moléculaire. L'invention porte également sur un polyol obtenu par le procédé. Le procédé pour la production de polyol comprend l'opération consistant à amener un ou plusieurs composés hétérocycliques à subir une addition par ouverture de cycle à au moins un amorceur choisi parmi l'huile de ricin et les condensats d'huile de ricin en présence d'un catalyseur pour la polymérisation cationique. Il est caractérisé par le fait que les composés hétérocycliques sont constitués par un ou plusieurs composés choisis dans le groupe constitué par les éthers cycliques et les esters cycliques, au moins une partie de ceux-ci étant constituée par l'oxyde d'éthylène, et que le catalyseur de polymérisation cationique est au moins un élément choisi dans le groupe constitué par les composés de l'aluminium et les composés du bore ayant chacun un groupe fluoroaryle ou un groupe fluoroaryloxy.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2009509151A JP5206671B2 (ja) | 2007-03-28 | 2008-03-26 | ポリオールの製造方法および該ポリオール |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2007085610 | 2007-03-28 | ||
JP2007-085610 | 2007-03-28 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2008123323A1 true WO2008123323A1 (fr) | 2008-10-16 |
Family
ID=39830811
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/JP2008/055777 WO2008123323A1 (fr) | 2007-03-28 | 2008-03-26 | Procédé de fabrication de polyol et le polyol obtenu |
Country Status (3)
Country | Link |
---|---|
JP (1) | JP5206671B2 (fr) |
TW (1) | TW200904852A (fr) |
WO (1) | WO2008123323A1 (fr) |
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2012201749A (ja) * | 2011-03-24 | 2012-10-22 | Dai Ichi Kogyo Seiyaku Co Ltd | ポリオキシアルキレン誘導体の製造方法及び該製造方法で得られるポリオキシアルキレン誘導体 |
US20130261205A1 (en) * | 2010-11-22 | 2013-10-03 | Bater Intellectual Property GmbH | Process for the preparation of polyricinoleic acid ester polyols having primary hydroxyl end groups |
US8642668B2 (en) | 2007-06-22 | 2014-02-04 | Asahi Glass Company, Limited | Polymer-dispersed polyol and process for producing flexible polyurethane foam |
JP2016532736A (ja) * | 2013-10-10 | 2016-10-20 | ビーエーエスエフ ソシエタス・ヨーロピアBasf Se | 新規の機能性流体組成物 |
JP2017531719A (ja) * | 2014-10-22 | 2017-10-26 | ダウ グローバル テクノロジーズ エルエルシー | 高い一級ヒドロキシルポリオールのための二重触媒系 |
JP2017222625A (ja) * | 2016-06-17 | 2017-12-21 | 三菱ケミカル株式会社 | ジオール化合物、該ジオール化合物から製造されるポリカーボネート樹脂、ポリカーボネートポリオール樹脂、ポリエステル樹脂、ポリエステルポリオール樹脂及びポリウレタン樹脂 |
WO2019055741A1 (fr) * | 2017-09-14 | 2019-03-21 | Northwestern University | Procédé de production de tensioactifs et de lubrifiants |
WO2019055742A1 (fr) * | 2017-09-14 | 2019-03-21 | Dow Global Technologies Llc | Procédé de préparation de tensioactifs et de lubrifiants |
WO2019055740A1 (fr) * | 2017-09-14 | 2019-03-21 | Dow Global Technologies Llc | Catalyseur acide de lewis pour polymérisation |
JP2019218267A (ja) * | 2018-06-14 | 2019-12-26 | 株式会社日本触媒 | トリアリールホウ素化合物を含む組成物 |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US11421077B2 (en) * | 2020-06-12 | 2022-08-23 | Bionanofoam Llc | Bio-based and hydrophilic polyurethane prepolymer |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
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JP2000344881A (ja) * | 1998-07-10 | 2000-12-12 | Sanyo Chem Ind Ltd | 新規ポリオキシアルキレンポリオールおよび開環重合体の製造法 |
JP2003183383A (ja) * | 2001-12-14 | 2003-07-03 | Nippon Shokubai Co Ltd | 低臭気なアルコールの環状エーテル付加物の製造方法 |
JP2005082732A (ja) * | 2003-09-10 | 2005-03-31 | Sanyo Chem Ind Ltd | 開環重合体の製造法 |
JP2005320437A (ja) * | 2004-05-10 | 2005-11-17 | Honda Motor Co Ltd | 自動車座席用ウレタンフォーム |
JP2006104404A (ja) * | 2004-10-08 | 2006-04-20 | Toyota Boshoku Corp | 乗り物シート用ポリウレタンパッド |
-
2008
- 2008-03-26 JP JP2009509151A patent/JP5206671B2/ja not_active Expired - Fee Related
- 2008-03-26 WO PCT/JP2008/055777 patent/WO2008123323A1/fr active Application Filing
- 2008-03-28 TW TW97111483A patent/TW200904852A/zh unknown
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2000344881A (ja) * | 1998-07-10 | 2000-12-12 | Sanyo Chem Ind Ltd | 新規ポリオキシアルキレンポリオールおよび開環重合体の製造法 |
JP2003183383A (ja) * | 2001-12-14 | 2003-07-03 | Nippon Shokubai Co Ltd | 低臭気なアルコールの環状エーテル付加物の製造方法 |
JP2005082732A (ja) * | 2003-09-10 | 2005-03-31 | Sanyo Chem Ind Ltd | 開環重合体の製造法 |
JP2005320437A (ja) * | 2004-05-10 | 2005-11-17 | Honda Motor Co Ltd | 自動車座席用ウレタンフォーム |
JP2006104404A (ja) * | 2004-10-08 | 2006-04-20 | Toyota Boshoku Corp | 乗り物シート用ポリウレタンパッド |
Cited By (49)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8642668B2 (en) | 2007-06-22 | 2014-02-04 | Asahi Glass Company, Limited | Polymer-dispersed polyol and process for producing flexible polyurethane foam |
US20130261205A1 (en) * | 2010-11-22 | 2013-10-03 | Bater Intellectual Property GmbH | Process for the preparation of polyricinoleic acid ester polyols having primary hydroxyl end groups |
US9328196B2 (en) * | 2010-11-22 | 2016-05-03 | Bayer Materialscience Ag | Process for the preparation of polyricinoleic acid ester polyols having primary hydroxyl end groups |
JP2012201749A (ja) * | 2011-03-24 | 2012-10-22 | Dai Ichi Kogyo Seiyaku Co Ltd | ポリオキシアルキレン誘導体の製造方法及び該製造方法で得られるポリオキシアルキレン誘導体 |
JP2016532736A (ja) * | 2013-10-10 | 2016-10-20 | ビーエーエスエフ ソシエタス・ヨーロピアBasf Se | 新規の機能性流体組成物 |
US10941367B2 (en) | 2013-10-10 | 2021-03-09 | Basf Se | Functional fluid composition |
JP2017531719A (ja) * | 2014-10-22 | 2017-10-26 | ダウ グローバル テクノロジーズ エルエルシー | 高い一級ヒドロキシルポリオールのための二重触媒系 |
JP2017222625A (ja) * | 2016-06-17 | 2017-12-21 | 三菱ケミカル株式会社 | ジオール化合物、該ジオール化合物から製造されるポリカーボネート樹脂、ポリカーボネートポリオール樹脂、ポリエステル樹脂、ポリエステルポリオール樹脂及びポリウレタン樹脂 |
JP2020534388A (ja) * | 2017-09-14 | 2020-11-26 | ダウ グローバル テクノロジーズ エルエルシー | ルイス酸重合触媒 |
US11001669B2 (en) | 2017-09-14 | 2021-05-11 | Dow Global Technologies Llc | Lewis acid polymerization catalyst |
WO2019055734A1 (fr) * | 2017-09-14 | 2019-03-21 | Dow Global Technologies Llc | Procédé de fabrication de polyols |
WO2019055727A1 (fr) * | 2017-09-14 | 2019-03-21 | Dow Global Technologies Llc | Procédé de préparation de polyols |
WO2019055725A1 (fr) * | 2017-09-14 | 2019-03-21 | Northwestern University | Procédé de fabrication de polyols |
WO2019055740A1 (fr) * | 2017-09-14 | 2019-03-21 | Dow Global Technologies Llc | Catalyseur acide de lewis pour polymérisation |
US11970574B2 (en) | 2017-09-14 | 2024-04-30 | Dow Global Technologies Llc | Process of manufacturing surfactants and lubricants |
KR20200047678A (ko) * | 2017-09-14 | 2020-05-07 | 다우 글로벌 테크놀로지스 엘엘씨 | 루이스 산 중합 촉매 |
KR20200052900A (ko) * | 2017-09-14 | 2020-05-15 | 다우 글로벌 테크놀로지스 엘엘씨 | 폴리올을 제조하는 방법 |
KR20200053530A (ko) * | 2017-09-14 | 2020-05-18 | 다우 글로벌 테크놀로지스 엘엘씨 | 폴리올을 제조하는 방법 |
KR20200055739A (ko) * | 2017-09-14 | 2020-05-21 | 노쓰웨스턴유니버시티 | 폴리올을 제조하는 방법 |
KR20200055742A (ko) * | 2017-09-14 | 2020-05-21 | 노쓰웨스턴유니버시티 | 폴리올을 제조하는 방법 |
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JP2020534395A (ja) * | 2017-09-14 | 2020-11-26 | ダウ グローバル テクノロジーズ エルエルシー | ポリオールの製造プロセス |
WO2019055742A1 (fr) * | 2017-09-14 | 2019-03-21 | Dow Global Technologies Llc | Procédé de préparation de tensioactifs et de lubrifiants |
JP2020534390A (ja) * | 2017-09-14 | 2020-11-26 | ノースウェスタン ユニバーシティ | ポリオールの製造プロセス |
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JP2020534391A (ja) * | 2017-09-14 | 2020-11-26 | ノースウェスタン ユニバーシティ | ポリオールの製造プロセス |
WO2019055741A1 (fr) * | 2017-09-14 | 2019-03-21 | Northwestern University | Procédé de production de tensioactifs et de lubrifiants |
WO2019055731A1 (fr) * | 2017-09-14 | 2019-03-21 | Northwestern University | Procédé de fabrication de polyols |
US11186683B2 (en) | 2017-09-14 | 2021-11-30 | Dow Global Technologies Llc | Process of manufacturing surfactants and lubricants |
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US11958936B2 (en) | 2017-09-14 | 2024-04-16 | Dow Global Technologies Llc | Process of manufacturing polyols |
JP7263323B2 (ja) | 2017-09-14 | 2023-04-24 | ノースウェスタン ユニバーシティ | ポリオールの製造プロセス |
JP7263322B2 (ja) | 2017-09-14 | 2023-04-24 | ダウ グローバル テクノロジーズ エルエルシー | ルイス酸重合触媒 |
CN111263784B (zh) * | 2017-09-14 | 2023-05-12 | 陶氏环球技术有限责任公司 | 制造多元醇的方法 |
CN111263785B (zh) * | 2017-09-14 | 2023-06-09 | 陶氏环球技术有限责任公司 | 路易斯酸聚合催化剂 |
CN111225938B (zh) * | 2017-09-14 | 2023-06-16 | 陶氏环球技术有限责任公司 | 制造表面活性剂和润滑剂的方法 |
JP7315539B2 (ja) | 2017-09-14 | 2023-07-26 | ダウ グローバル テクノロジーズ エルエルシー | ポリオールの製造プロセス |
JP7372636B2 (ja) | 2017-09-14 | 2023-11-01 | ノースウェスタン ユニバーシティ | ポリオールの製造プロセス |
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KR102602895B1 (ko) | 2017-09-14 | 2023-11-16 | 다우 글로벌 테크놀로지스 엘엘씨 | 폴리올을 제조하는 방법 |
KR102603166B1 (ko) | 2017-09-14 | 2023-11-16 | 노쓰웨스턴유니버시티 | 폴리올을 제조하는 방법 |
KR102603117B1 (ko) | 2017-09-14 | 2023-11-17 | 노쓰웨스턴유니버시티 | 폴리올을 제조하는 방법 |
KR102603979B1 (ko) | 2017-09-14 | 2023-11-21 | 다우 글로벌 테크놀로지스 엘엘씨 | 루이스 산 중합 촉매 |
US11912822B2 (en) | 2017-09-14 | 2024-02-27 | Dow Global Technologies Llc | Process of manufacturing polyols |
JP7163078B2 (ja) | 2018-06-14 | 2022-10-31 | 株式会社日本触媒 | トリアリールホウ素化合物を含む組成物 |
JP2019218267A (ja) * | 2018-06-14 | 2019-12-26 | 株式会社日本触媒 | トリアリールホウ素化合物を含む組成物 |
Also Published As
Publication number | Publication date |
---|---|
JPWO2008123323A1 (ja) | 2010-07-15 |
TW200904852A (en) | 2009-02-01 |
JP5206671B2 (ja) | 2013-06-12 |
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