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WO2008123164A1 - Procédé de fabrication d'un polymère de diène conjugué modifié, polymère de diène conjugué modifié, et composition de caoutchouc - Google Patents

Procédé de fabrication d'un polymère de diène conjugué modifié, polymère de diène conjugué modifié, et composition de caoutchouc Download PDF

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Publication number
WO2008123164A1
WO2008123164A1 PCT/JP2008/055340 JP2008055340W WO2008123164A1 WO 2008123164 A1 WO2008123164 A1 WO 2008123164A1 JP 2008055340 W JP2008055340 W JP 2008055340W WO 2008123164 A1 WO2008123164 A1 WO 2008123164A1
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WO
WIPO (PCT)
Prior art keywords
conjugated diene
diene polymer
modified conjugated
rubber composition
producing
Prior art date
Application number
PCT/JP2008/055340
Other languages
English (en)
Japanese (ja)
Inventor
Masahiro Shibata
Takaomi Matsumoto
Tamotsu Nagaoka
Takuo Sone
Toshihiro Tadaki
Original Assignee
Jsr Corporation
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Jsr Corporation filed Critical Jsr Corporation
Priority to CN2008800133487A priority Critical patent/CN101668780B/zh
Priority to BRPI0809111-0A priority patent/BRPI0809111B1/pt
Priority to US12/532,764 priority patent/US8178626B2/en
Priority to JP2009509086A priority patent/JP5728807B2/ja
Priority to EP08738733.8A priority patent/EP2130842B1/fr
Publication of WO2008123164A1 publication Critical patent/WO2008123164A1/fr
Priority to US13/347,115 priority patent/US9206264B2/en

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/42—Introducing metal atoms or metal-containing groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
    • C08C19/00—Chemical modification of rubber
    • C08C19/12—Incorporating halogen atoms into the molecule
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
    • C08C19/00—Chemical modification of rubber
    • C08C19/30—Addition of a reagent which reacts with a hetero atom or a group containing hetero atoms of the macromolecule
    • C08C19/42—Addition of a reagent which reacts with a hetero atom or a group containing hetero atoms of the macromolecule reacting with metals or metal-containing groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
    • C08C19/00—Chemical modification of rubber
    • C08C19/30—Addition of a reagent which reacts with a hetero atom or a group containing hetero atoms of the macromolecule
    • C08C19/42—Addition of a reagent which reacts with a hetero atom or a group containing hetero atoms of the macromolecule reacting with metals or metal-containing groups
    • C08C19/44—Addition of a reagent which reacts with a hetero atom or a group containing hetero atoms of the macromolecule reacting with metals or metal-containing groups of polymers containing metal atoms exclusively at one or both ends of the skeleton
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L15/00—Compositions of rubber derivatives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L21/00—Compositions of unspecified rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/01—Use of inorganic substances as compounding ingredients characterized by their specific function
    • C08K3/013—Fillers, pigments or reinforcing additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/02—Elements
    • C08K3/04—Carbon
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/34—Silicon-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/34—Silicon-containing compounds
    • C08K3/36—Silica
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/54—Silicon-containing compounds
    • C08K5/548—Silicon-containing compounds containing sulfur
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L7/00—Compositions of natural rubber
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
    • C08L9/02—Copolymers with acrylonitrile
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
    • C08L9/06—Copolymers with styrene

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

L'invention porte sur un procédé de fabrication d'un polymère de diène conjugué modifié, comprenant une étape consistant à obtenir un polymère de diène conjugué modifié par réaction avec un halogénure métallique d'un polymère de diène conjugué, qui est obtenu par liaison d'un groupe alcoxysilyle et d'un groupe amino primaire protégé de façon facultative à un polymère contenant au moins une unité de diène conjugué et a une masse moléculaire moyenne en poids de 150 000-2 000 000. Ce procédé permet d'obtenir de façon souhaitable un polymère de diène conjugué ayant une viscosité Mooney élevée, une excellente stabilité de forme et une bonne aptitude au façonnage.
PCT/JP2008/055340 2007-03-23 2008-03-21 Procédé de fabrication d'un polymère de diène conjugué modifié, polymère de diène conjugué modifié, et composition de caoutchouc WO2008123164A1 (fr)

Priority Applications (6)

Application Number Priority Date Filing Date Title
CN2008800133487A CN101668780B (zh) 2007-03-23 2008-03-21 改性共轭二烯系聚合物的制造方法、改性共轭二烯系聚合物及橡胶组合物
BRPI0809111-0A BRPI0809111B1 (pt) 2007-03-23 2008-03-21 Método para a produção de um (co)polímero à base de dieno conjugado modificado, (co)polímero à base de dieno conjugado modificado e composição de borracha
US12/532,764 US8178626B2 (en) 2007-03-23 2008-03-21 Method for producing modified conjugated diene based (co)polymer, modified conjugated diene based (co)polymer, and rubber composition
JP2009509086A JP5728807B2 (ja) 2007-03-23 2008-03-21 変性共役ジエン系重合体の製造方法、変性共役ジエン系重合体、及びゴム組成物
EP08738733.8A EP2130842B1 (fr) 2007-03-23 2008-03-21 Procédé de fabrication d'un polymère de diène conjugué modifié, polymère de diène conjugué modifié, et composition de caoutchouc
US13/347,115 US9206264B2 (en) 2007-03-23 2012-01-10 Method for producing modified conjugated diene based (co)polymer, modified conjugated diene based (co)polymer, and rubber composition

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2007-077963 2007-03-23
JP2007077963 2007-03-23

Related Child Applications (2)

Application Number Title Priority Date Filing Date
US12/532,764 A-371-Of-International US8178626B2 (en) 2007-03-23 2008-03-21 Method for producing modified conjugated diene based (co)polymer, modified conjugated diene based (co)polymer, and rubber composition
US13/347,115 Continuation US9206264B2 (en) 2007-03-23 2012-01-10 Method for producing modified conjugated diene based (co)polymer, modified conjugated diene based (co)polymer, and rubber composition

Publications (1)

Publication Number Publication Date
WO2008123164A1 true WO2008123164A1 (fr) 2008-10-16

Family

ID=39830661

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2008/055340 WO2008123164A1 (fr) 2007-03-23 2008-03-21 Procédé de fabrication d'un polymère de diène conjugué modifié, polymère de diène conjugué modifié, et composition de caoutchouc

Country Status (7)

Country Link
US (2) US8178626B2 (fr)
EP (1) EP2130842B1 (fr)
JP (1) JP5728807B2 (fr)
KR (1) KR101475966B1 (fr)
CN (1) CN101668780B (fr)
BR (1) BRPI0809111B1 (fr)
WO (1) WO2008123164A1 (fr)

Cited By (21)

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JP2009263511A (ja) * 2008-04-25 2009-11-12 Bridgestone Corp 空気入りタイヤ
JP2010215716A (ja) * 2009-03-13 2010-09-30 Bridgestone Corp 変性共役ジエン重合体又は共重合体の製造方法、その方法により得られた変性共役ジエン重合体又は共重合体、ゴム組成物及びタイヤ
WO2012073880A1 (fr) * 2010-12-01 2012-06-07 Jsr株式会社 Procédé de production d'un caoutchouc diénique conjugué et modifié, caoutchouc diénique conjugué et modifié et composition de caoutchouc
US20130023624A1 (en) * 2010-04-16 2013-01-24 Asahi Kasei Chemicals Corporation Method for Producing Modified Conjugated Diene-Based Polymer, Modified Conjugated Diene-Based Polymer, and Modified Conjugated Diene-Based Polymer Composition
EP2425990A4 (fr) * 2009-04-30 2013-06-12 Bridgestone Corp Pneu
JP2014501327A (ja) * 2010-12-31 2014-01-20 株式会社ブリヂストン 加水分解性官能基を含むポリマーの安定化
US20140371383A1 (en) * 2011-08-26 2014-12-18 Asahi Kasei Chemicals Corporation Method for Producing Modified Conjugated Diene Polymer, Modified Conjugated Diene Polymer, Modified Conjugated Diene Polymer Composition, Rubber Composition and Tire
WO2017061831A1 (fr) * 2015-10-08 2017-04-13 주식회사 엘지화학 Polymère diénique conjugué modifié, procédé de préparation associé et composition de caoutchouc le contenant
WO2018025998A1 (fr) * 2016-08-05 2018-02-08 住友化学株式会社 Procédé de fabrication de polymère à base de diène conjugué modifié, et procédé de fabrication de composition de polymère
JP2018513907A (ja) * 2015-04-10 2018-05-31 シントス エス．アー．Ｓｙｎｔｈｏｓ Ｓ．Ａ． ［ビス（トリヒドロカルビルシリル）アミノシリル］官能化スチレンおよびその調製方法
KR20180087380A (ko) 2016-06-24 2018-08-01 제이에스알 가부시끼가이샤 변성 공액 디엔계 중합체의 제조 방법, 변성 공액 디엔계 중합체, 중합체 조성물, 가교체, 타이어 및 화합물
WO2018181176A1 (fr) * 2017-03-31 2018-10-04 住友化学株式会社 Polymère de diène conjugué et son procédé de production
WO2020179705A1 (fr) 2019-03-07 2020-09-10 Jsr株式会社 Procédé de production d'un polymère diène conjugué modifié, polymère diène conjugué modifié, composition polymère, corps réticulé et pneu
WO2020196899A1 (fr) 2019-03-27 2020-10-01 Jsr株式会社 Polymère diénique conjugué hydrogéné, composition polymère, corps réticulé, et pneu
JP2022516666A (ja) * 2019-09-11 2022-03-01 エルジー・ケム・リミテッド 変性共役ジエン系重合体、およびそれを含むゴム組成物
WO2022196643A1 (fr) 2021-03-15 2022-09-22 株式会社Ｅｎｅｏｓマテリアル Polymère de diène conjugué et procédé de production associé, composition polymère, produit réticulé, et pneu
WO2023074773A1 (fr) 2021-10-29 2023-05-04 株式会社Ｅｎｅｏｓマテリアル Procédé de production d'un polymère à base de diène conjugué modifié, polymère à base de diène conjugué modifié, composition de polymère, produit réticulé, pneu et composé
WO2023085309A1 (fr) 2021-11-10 2023-05-19 株式会社Ｅｎｅｏｓマテリアル Procédé de production d'un polymère diène conjugué modifié, polymère diène conjugué modifié, composition polymère, corps réticulé et pneu
WO2024029624A1 (fr) 2022-08-05 2024-02-08 株式会社Ｅｎｅｏｓマテリアル Polymère de diène conjugué modifié et procédé pour le produire, composition polymère, produit réticulé et pneu
US12110353B2 (en) 2019-09-11 2024-10-08 Lg Chem, Ltd. Modified conjugated diene-based polymer, method for preparing the same and rubber composition including the same
US12162964B2 (en) 2019-09-11 2024-12-10 Lg Chem, Ltd. Modified conjugated diene-based polymer and rubber composition including the same

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US9309388B2 (en) * 2011-02-14 2016-04-12 Jsr Corporation Rubber composition, method for producing same, and tire
HUE025588T2 (en) 2012-02-29 2016-05-30 Trinseo Europe Gmbh Production Process of Dene Polymers
WO2013184813A1 (fr) * 2012-06-06 2013-12-12 Firestone Polymers, Llc Procédé de fabrication de polymères stabilisés par une base, compositions de polymères et articles contenant de tels polymères
US9611364B2 (en) 2012-06-06 2017-04-04 Firestone Polymers, Llc Method of making alkoxysilane stabilized polymers, and polymer compositions
KR101249352B1 (ko) 2012-09-24 2013-04-02 금호석유화학 주식회사 에테르 그룹과 디알킬아미노 그룹이 동시에 포함된 알킬알콕시실란 화합물과 이의 제조방법
KR101365902B1 (ko) * 2013-01-14 2014-03-12 금호석유화학 주식회사 공역 디엔계 고분자의 말단 변성제
KR101310868B1 (ko) 2013-02-26 2013-10-14 금호석유화학 주식회사 알콕시실란 유도체에 의해 말단 변성된 공역 디엔계 고분자
KR101508519B1 (ko) 2013-08-27 2015-04-07 금호석유화학 주식회사 알콕시실란 단위가 포함된 공역 디엔계 랜덤 공중합체
KR101704862B1 (ko) * 2013-09-30 2017-02-08 주식회사 엘지화학 개질 공액 디엔계 중합체, 그 제조방법 및 고무 조성물
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KR101700954B1 (ko) 2014-11-05 2017-01-31 금호석유화학 주식회사 말단 변성 공액 디엔계 중합체 및 그 제조방법
CN107207632B (zh) * 2015-02-26 2020-04-14 日本瑞翁株式会社 改性共轭二烯系橡胶的制造方法
BR112017026162B1 (pt) * 2015-06-12 2022-02-15 Asahi Kasei Kabushiki Kaisha Polímero com base em dieno conjugado modificado e método de produção do mesmo, composição de borracha e pneu
JP6686308B2 (ja) * 2015-07-13 2020-04-22 横浜ゴム株式会社 難燃ホース用ゴム組成物及び難燃ホース
KR101923160B1 (ko) 2015-12-24 2018-11-29 주식회사 엘지화학 변성 공액디엔계 중합체, 이의 제조방법 및 변성제
WO2018043699A1 (fr) * 2016-09-02 2018-03-08 株式会社クラレ Composition de caoutchouc
KR101926619B1 (ko) 2018-03-29 2018-12-11 금호석유화학 주식회사 기능성 단량체를 포함하는 공중합체 및 그 제조방법
DE102018211763B4 (de) 2018-07-16 2025-02-13 Continental Reifen Deutschland Gmbh Schwefelvernetzbare Kautschukmischung, Vulkanisat und Fahrzeugreifen
KR102786941B1 (ko) * 2019-10-31 2025-03-25 가부시키가이샤 에네오스 마테리아루 변성 공액 디엔계 중합체 및 그의 제조 방법, 중합체 조성물, 가교체 및 타이어

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CN101668780A (zh) 2010-03-10
EP2130842B1 (fr) 2013-05-15
KR20090122473A (ko) 2009-11-30
CN101668780B (zh) 2012-11-28
US20120108737A1 (en) 2012-05-03
BRPI0809111A2 (pt) 2014-08-26
US8178626B2 (en) 2012-05-15
US9206264B2 (en) 2015-12-08
EP2130842A1 (fr) 2009-12-09
EP2130842A4 (fr) 2010-12-01
US20100152369A1 (en) 2010-06-17
KR101475966B1 (ko) 2014-12-23
JPWO2008123164A1 (ja) 2010-07-15
JP5728807B2 (ja) 2015-06-03
BRPI0809111B1 (pt) 2018-08-14

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