WO2008120666A1 - ビスフェノール化合物の製造方法、及び陽イオン交換樹脂触媒 - Google Patents
ビスフェノール化合物の製造方法、及び陽イオン交換樹脂触媒 Download PDFInfo
- Publication number
- WO2008120666A1 WO2008120666A1 PCT/JP2008/055884 JP2008055884W WO2008120666A1 WO 2008120666 A1 WO2008120666 A1 WO 2008120666A1 JP 2008055884 W JP2008055884 W JP 2008055884W WO 2008120666 A1 WO2008120666 A1 WO 2008120666A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- cation
- exchange resin
- compound
- resin catalyst
- mercapto group
- Prior art date
Links
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 title abstract 5
- 239000003729 cation exchange resin Substances 0.000 title abstract 5
- -1 bisphenol compound Chemical class 0.000 title abstract 4
- 239000003054 catalyst Substances 0.000 title abstract 4
- 229930185605 Bisphenol Natural products 0.000 title abstract 3
- 238000004519 manufacturing process Methods 0.000 title abstract 2
- 125000003396 thiol group Chemical group [H]S* 0.000 abstract 4
- 150000001875 compounds Chemical class 0.000 abstract 2
- 125000003118 aryl group Chemical group 0.000 abstract 1
- 150000001728 carbonyl compounds Chemical class 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 125000006575 electron-withdrawing group Chemical group 0.000 abstract 1
- 125000005843 halogen group Chemical group 0.000 abstract 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 1
- 125000000547 substituted alkyl group Chemical group 0.000 abstract 1
- 125000003107 substituted aryl group Chemical group 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
- C07C37/11—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by reactions increasing the number of carbon atoms
- C07C37/20—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by reactions increasing the number of carbon atoms using aldehydes or ketones
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/06—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing polymers
- B01J31/08—Ion-exchange resins
- B01J31/10—Ion-exchange resins sulfonated
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C39/00—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a six-membered aromatic ring
- C07C39/12—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a six-membered aromatic ring polycyclic with no unsaturation outside the aromatic rings
- C07C39/15—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a six-membered aromatic ring polycyclic with no unsaturation outside the aromatic rings with all hydroxy groups on non-condensed rings, e.g. phenylphenol
- C07C39/16—Bis-(hydroxyphenyl) alkanes; Tris-(hydroxyphenyl)alkanes
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
高転化率、且つ高選択率でビスフェノール化合物を製造することができるビスフェノール化合物の製造方法、及び、高活性を有する陽イオン交換樹脂触媒を提供する。 下記一般式（１）で表される構成単位を有する陽イオン交換樹脂触媒及びメルカプト基或いは保護されたメルカプト基を含有する化合物、又は、下記一般式（１）で表される構成単位がメルカプト基或いは保護されたメルカプト基を含有する化合物で変性された構成単位を有する陽イオン交換樹脂触媒、の存在下、フェノール化合物とカルボニル化合物とを反応させる。 〔式（１）中、Ｒ１、Ｒ２、及びＲ３は、各々独立に、水素原子、置換基を有していてもよいアルキル基、置換基を有していてもよいアリール基、又はハロゲン原子を表し、Ｘは陽イオン交換樹脂の主鎖に結合している一つの芳香環のみに置換している電子求引性基を表し、ｎは１乃至４の整数である。〕
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2007-092697 | 2007-03-30 | ||
| JP2007092697 | 2007-03-30 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO2008120666A1 true WO2008120666A1 (ja) | 2008-10-09 |
Family
ID=39808248
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/JP2008/055884 WO2008120666A1 (ja) | 2007-03-30 | 2008-03-27 | ビスフェノール化合物の製造方法、及び陽イオン交換樹脂触媒 |
Country Status (4)
| Country | Link |
|---|---|
| JP (1) | JP2008273951A (ja) |
| KR (1) | KR20090123846A (ja) |
| TW (1) | TW200916437A (ja) |
| WO (1) | WO2008120666A1 (ja) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2010173949A (ja) * | 2009-01-28 | 2010-08-12 | Mitsubishi Chemicals Corp | ビスフェノール類の製造方法 |
| US8445731B2 (en) | 2009-01-22 | 2013-05-21 | Mitsubishi Chemical Corporation | Process for producing bisphenol compound |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5332846B2 (ja) * | 2009-04-10 | 2013-11-06 | 三菱化学株式会社 | ビスフェノール化合物製造用強酸性イオン交換樹脂触媒及び、それを用いたビスフェノール化合物の製造方法 |
| KR101644362B1 (ko) * | 2013-12-31 | 2016-08-02 | 주식회사 삼양사 | 비스페놀 합성용 양이온 교환 수지 및 그 제조 방법, 및 이 양이온 교환 수지를 이용한 비스페놀의 합성 방법 |
| CN113574041B (zh) * | 2019-03-18 | 2023-10-13 | 三菱化学株式会社 | 双酚的制造方法以及聚碳酸酯树脂的制造方法 |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH05111641A (ja) * | 1991-03-07 | 1993-05-07 | Dow Chem Co:The | 酸化抵抗性陽イオン交換樹脂 |
| JPH07116525A (ja) * | 1993-10-21 | 1995-05-09 | Tokyo Organ Chem Ind Ltd | 陽イオン交換樹脂 |
| JP2002060360A (ja) * | 2000-08-16 | 2002-02-26 | Mitsubishi Chemicals Corp | ビスフェノールの製造方法 |
| JP2003160526A (ja) * | 2001-11-27 | 2003-06-03 | Manac Inc | ヒドロキノンの二量体及び三量体の製造方法 |
-
2008
- 2008-03-27 WO PCT/JP2008/055884 patent/WO2008120666A1/ja active Application Filing
- 2008-03-27 KR KR1020097004164A patent/KR20090123846A/ko not_active Withdrawn
- 2008-03-27 JP JP2008083620A patent/JP2008273951A/ja active Pending
- 2008-03-28 TW TW097111633A patent/TW200916437A/zh unknown
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH05111641A (ja) * | 1991-03-07 | 1993-05-07 | Dow Chem Co:The | 酸化抵抗性陽イオン交換樹脂 |
| JPH07116525A (ja) * | 1993-10-21 | 1995-05-09 | Tokyo Organ Chem Ind Ltd | 陽イオン交換樹脂 |
| JP2002060360A (ja) * | 2000-08-16 | 2002-02-26 | Mitsubishi Chemicals Corp | ビスフェノールの製造方法 |
| JP2003160526A (ja) * | 2001-11-27 | 2003-06-03 | Manac Inc | ヒドロキノンの二量体及び三量体の製造方法 |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8445731B2 (en) | 2009-01-22 | 2013-05-21 | Mitsubishi Chemical Corporation | Process for producing bisphenol compound |
| JP2010173949A (ja) * | 2009-01-28 | 2010-08-12 | Mitsubishi Chemicals Corp | ビスフェノール類の製造方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2008273951A (ja) | 2008-11-13 |
| KR20090123846A (ko) | 2009-12-02 |
| TW200916437A (en) | 2009-04-16 |
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