WO2008120666A1 - Method for producing bisphenol compound and cation-exchange resin catalyst - Google Patents
Method for producing bisphenol compound and cation-exchange resin catalyst Download PDFInfo
- Publication number
- WO2008120666A1 WO2008120666A1 PCT/JP2008/055884 JP2008055884W WO2008120666A1 WO 2008120666 A1 WO2008120666 A1 WO 2008120666A1 JP 2008055884 W JP2008055884 W JP 2008055884W WO 2008120666 A1 WO2008120666 A1 WO 2008120666A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- cation
- exchange resin
- compound
- resin catalyst
- mercapto group
- Prior art date
Links
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 title abstract 5
- 239000003729 cation exchange resin Substances 0.000 title abstract 5
- -1 bisphenol compound Chemical class 0.000 title abstract 4
- 239000003054 catalyst Substances 0.000 title abstract 4
- 229930185605 Bisphenol Natural products 0.000 title abstract 3
- 238000004519 manufacturing process Methods 0.000 title abstract 2
- 125000003396 thiol group Chemical group [H]S* 0.000 abstract 4
- 150000001875 compounds Chemical class 0.000 abstract 2
- 125000003118 aryl group Chemical group 0.000 abstract 1
- 150000001728 carbonyl compounds Chemical class 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 125000006575 electron-withdrawing group Chemical group 0.000 abstract 1
- 125000005843 halogen group Chemical group 0.000 abstract 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 1
- 125000000547 substituted alkyl group Chemical group 0.000 abstract 1
- 125000003107 substituted aryl group Chemical group 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
- C07C37/11—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by reactions increasing the number of carbon atoms
- C07C37/20—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by reactions increasing the number of carbon atoms using aldehydes or ketones
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/06—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing polymers
- B01J31/08—Ion-exchange resins
- B01J31/10—Ion-exchange resins sulfonated
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C39/00—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a six-membered aromatic ring
- C07C39/12—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a six-membered aromatic ring polycyclic with no unsaturation outside the aromatic rings
- C07C39/15—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a six-membered aromatic ring polycyclic with no unsaturation outside the aromatic rings with all hydroxy groups on non-condensed rings, e.g. phenylphenol
- C07C39/16—Bis-(hydroxyphenyl) alkanes; Tris-(hydroxyphenyl)alkanes
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Disclosed is a method for producing a bisphenol compound, which enables to produce a bisphenol compound with high conversion rate and high selectivity. Also disclosed is a cation-exchange resin catalyst having high activity. Specifically, a phenol compound is reacted with a carbonyl compound in the presence of a cation-exchange resin catalyst having a constitutional unit represented by the general formula (1) below and a compound having a mercapto group or a protected mercapto group, or alternatively in the presence of a cation-exchange resin catalyst having a constitutional unit obtained by modifying a constitutional unit represented by the general formula (1) below with a compound having a mercapto group or a protected mercapto group. (In the formula (1), R1, R2 and R3 independently represent a hydrogen atom, an optionally substituted alkyl group, an optionally substituted aryl group or a halogen atom; X represents an electron-withdrawing group substituting only one aromatic ring bonded to the main chain of the cation-exchange resin; and n represents an integer of 1-4.)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2007-092697 | 2007-03-30 | ||
| JP2007092697 | 2007-03-30 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO2008120666A1 true WO2008120666A1 (en) | 2008-10-09 |
Family
ID=39808248
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/JP2008/055884 WO2008120666A1 (en) | 2007-03-30 | 2008-03-27 | Method for producing bisphenol compound and cation-exchange resin catalyst |
Country Status (4)
| Country | Link |
|---|---|
| JP (1) | JP2008273951A (en) |
| KR (1) | KR20090123846A (en) |
| TW (1) | TW200916437A (en) |
| WO (1) | WO2008120666A1 (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2010173949A (en) * | 2009-01-28 | 2010-08-12 | Mitsubishi Chemicals Corp | Method for producing bisphenols |
| US8445731B2 (en) | 2009-01-22 | 2013-05-21 | Mitsubishi Chemical Corporation | Process for producing bisphenol compound |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5332846B2 (en) * | 2009-04-10 | 2013-11-06 | 三菱化学株式会社 | Strongly acidic ion-exchange resin catalyst for bisphenol compound production and method for producing bisphenol compound using the same |
| KR101644362B1 (en) * | 2013-12-31 | 2016-08-02 | 주식회사 삼양사 | Cation exchange resin for bisphenol synthesis and method for preparing the same, and method for synthesizing bisphenol by using the cation exchange resin |
| CN113574041B (en) * | 2019-03-18 | 2023-10-13 | 三菱化学株式会社 | Bisphenol production method and polycarbonate resin production method |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH05111641A (en) * | 1991-03-07 | 1993-05-07 | Dow Chem Co:The | Oxidation resisting cation-exchange resin |
| JPH07116525A (en) * | 1993-10-21 | 1995-05-09 | Tokyo Organ Chem Ind Ltd | Cation exchange resin |
| JP2002060360A (en) * | 2000-08-16 | 2002-02-26 | Mitsubishi Chemicals Corp | Bisphenol production method |
| JP2003160526A (en) * | 2001-11-27 | 2003-06-03 | Manac Inc | Method for producing dimer and trimer of hydroquinone |
-
2008
- 2008-03-27 WO PCT/JP2008/055884 patent/WO2008120666A1/en active Application Filing
- 2008-03-27 KR KR1020097004164A patent/KR20090123846A/en not_active Withdrawn
- 2008-03-27 JP JP2008083620A patent/JP2008273951A/en active Pending
- 2008-03-28 TW TW097111633A patent/TW200916437A/en unknown
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH05111641A (en) * | 1991-03-07 | 1993-05-07 | Dow Chem Co:The | Oxidation resisting cation-exchange resin |
| JPH07116525A (en) * | 1993-10-21 | 1995-05-09 | Tokyo Organ Chem Ind Ltd | Cation exchange resin |
| JP2002060360A (en) * | 2000-08-16 | 2002-02-26 | Mitsubishi Chemicals Corp | Bisphenol production method |
| JP2003160526A (en) * | 2001-11-27 | 2003-06-03 | Manac Inc | Method for producing dimer and trimer of hydroquinone |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8445731B2 (en) | 2009-01-22 | 2013-05-21 | Mitsubishi Chemical Corporation | Process for producing bisphenol compound |
| JP2010173949A (en) * | 2009-01-28 | 2010-08-12 | Mitsubishi Chemicals Corp | Method for producing bisphenols |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2008273951A (en) | 2008-11-13 |
| KR20090123846A (en) | 2009-12-02 |
| TW200916437A (en) | 2009-04-16 |
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