+

WO2008107571A3 - Silicates mixtes de lithium. - Google Patents

Silicates mixtes de lithium. Download PDF

Info

Publication number
WO2008107571A3
WO2008107571A3 PCT/FR2008/000148 FR2008000148W WO2008107571A3 WO 2008107571 A3 WO2008107571 A3 WO 2008107571A3 FR 2008000148 W FR2008000148 W FR 2008000148W WO 2008107571 A3 WO2008107571 A3 WO 2008107571A3
Authority
WO
WIPO (PCT)
Prior art keywords
silicates
mixed lithium
lithium silicates
mixed
space group
Prior art date
Application number
PCT/FR2008/000148
Other languages
English (en)
Other versions
WO2008107571A2 (fr
Inventor
Gerard Quoirin
Jean-Marie Tarascon
Christian Masquelier
Charles Delacourt
Philippe Poizot
Francis Taulelle
Original Assignee
Centre Nat Rech Scient
Gerard Quoirin
Jean-Marie Tarascon
Christian Masquelier
Charles Delacourt
Philippe Poizot
Francis Taulelle
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Centre Nat Rech Scient, Gerard Quoirin, Jean-Marie Tarascon, Christian Masquelier, Charles Delacourt, Philippe Poizot, Francis Taulelle filed Critical Centre Nat Rech Scient
Priority to EP08761851A priority Critical patent/EP2118007A2/fr
Priority to CA002677711A priority patent/CA2677711A1/fr
Priority to JP2009548714A priority patent/JP2010517913A/ja
Publication of WO2008107571A2 publication Critical patent/WO2008107571A2/fr
Publication of WO2008107571A3 publication Critical patent/WO2008107571A3/fr

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B33/00—Silicon; Compounds thereof
    • C01B33/20—Silicates
    • C01B33/32—Alkali metal silicates
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/131—Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/139—Processes of manufacture
    • H01M4/1391—Processes of manufacture of electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/485—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
    • H01M4/505—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
    • H01M4/525—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Electrochemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Silicon Compounds (AREA)
  • Secondary Cells (AREA)

Abstract

L'invention concerne des silicates mixtes de lithium. Les silicates mixtes ont la formule Li2MII(1 x)MIIIxSiO4(OH)x (I) dans laquelle 0≤ x≤ 1 et M est Fe, Co, Mn ou Ni. Ils sont caractérisés en ce qu'ils sont sous forme de particules substantiellement sphériques et non coalescées, ayant une dimension de 400 à 600 nm et qu'ils ont une structure dans le groupe d'espace Pna21 et éventuellement dans le groupe d'espace Pccn. Les silicates sont obtenus par précipitation en milieu aqueux ô partir de précurseurs. Utilisation comme matière active d'électrode pour des dispositifs électrochimiques.
PCT/FR2008/000148 2007-02-09 2008-02-07 Silicates mixtes de lithium. WO2008107571A2 (fr)

Priority Applications (3)

Application Number Priority Date Filing Date Title
EP08761851A EP2118007A2 (fr) 2007-02-09 2008-02-07 Silicates mixtes de lithium.
CA002677711A CA2677711A1 (fr) 2007-02-09 2008-02-07 Silicates mixtes de lithium
JP2009548714A JP2010517913A (ja) 2007-02-09 2008-02-07 混合されたケイ酸リチウム

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR0700932 2007-02-09
FR0700932A FR2912398B1 (fr) 2007-02-09 2007-02-09 Silicates mixtes de lithium

Publications (2)

Publication Number Publication Date
WO2008107571A2 WO2008107571A2 (fr) 2008-09-12
WO2008107571A3 true WO2008107571A3 (fr) 2009-06-25

Family

ID=38466368

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/FR2008/000148 WO2008107571A2 (fr) 2007-02-09 2008-02-07 Silicates mixtes de lithium.

Country Status (6)

Country Link
EP (1) EP2118007A2 (fr)
JP (1) JP2010517913A (fr)
CN (1) CN101652321A (fr)
CA (1) CA2677711A1 (fr)
FR (1) FR2912398B1 (fr)
WO (1) WO2008107571A2 (fr)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5350849B2 (ja) * 2009-03-23 2013-11-27 株式会社豊田中央研究所 リチウム二次電池
WO2011103554A1 (fr) 2010-02-22 2011-08-25 Massachusetts Institute Of Technology Carbophosphates et composés associés
JP5653637B2 (ja) * 2010-03-01 2015-01-14 古河電気工業株式会社 正極活物質材料、正極、２次電池及びこれらの製造方法
JP5566723B2 (ja) * 2010-03-01 2014-08-06 古河電気工業株式会社 微粒子混合物、活物質凝集体、正極活物質材料、正極、２次電池及びこれらの製造方法
CN101920972B (zh) * 2010-06-28 2011-12-14 宁波大学 一种用于锂离子电池的硅酸钴锂正极材料的制备方法
EP2588412A1 (fr) * 2010-06-30 2013-05-08 Höganäs AB Matériau de cathode en silicate double de lithium et fer et sa production
WO2012127762A1 (fr) * 2011-03-23 2012-09-27 ヤマハ発動機株式会社 Composition électriquement conductrice, système de dispersion, procédé de production d'une composition électriquement conductrice et batterie à électrolyte solide
JP5754808B2 (ja) * 2011-10-13 2015-07-29 太平洋セメント株式会社 二次電池用正極活物質及びその製造方法
WO2014155408A1 (fr) * 2013-03-25 2014-10-02 株式会社豊田自動織機 Composé de silicate de lithium contenant de l'hydrogène, son procédé de production, matériau actif positif pour batterie secondaire à électrolyte non aqueux, électrode positive pour batterie secondaire à électrolyte non aqueux et batterie secondaire à électrolyte non aqueux
KR101527286B1 (ko) * 2013-09-30 2015-06-09 고려대학교 산학협력단 리튬 이차 전지용 음극의 형성 방법
CN110127712A (zh) * 2019-05-15 2019-08-16 浙江工业大学 常压水解法制备具有微纳结构的介孔硅酸锂空心球的方法
CN118039890B (zh) * 2024-01-18 2025-02-14 深圳新源邦科技有限公司 一种硅钼酸锂材料及其制备方法和应用

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4764497A (en) * 1981-12-23 1988-08-16 Tokuyama Soda Kabushiki Kaisha Amorphous, spherical inorganic compound and process for preparation thereof
WO2002027824A1 (fr) * 2000-09-26 2002-04-04 HYDRO-QUéBEC Procédé de synthèse de matériau à base de lixm1-ym'y(xo4)n
WO2004056704A1 (fr) * 2002-12-20 2004-07-08 Rockwood Additives Limited Procede de production de compositions de silicate de magnesium synthetique

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4764497A (en) * 1981-12-23 1988-08-16 Tokuyama Soda Kabushiki Kaisha Amorphous, spherical inorganic compound and process for preparation thereof
WO2002027824A1 (fr) * 2000-09-26 2002-04-04 HYDRO-QUéBEC Procédé de synthèse de matériau à base de lixm1-ym'y(xo4)n
WO2004056704A1 (fr) * 2002-12-20 2004-07-08 Rockwood Additives Limited Procede de production de compositions de silicate de magnesium synthetique

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
ARROYO-DE DOMPABLO ET AL: "On-demand design of polyoxianionic cathode materials based on electronegativity correlations: An exploration of the Li2MSiO4 system (M=Fe, Mn, Co, Ni)", ELECTROCHEMISTRY COMMUNICATION, ELSEVIER, AMSTERDAM, NL, vol. 8, no. 8, August 2006 (2006-08-01), pages 1292 - 1298, XP005591198, ISSN: 1388-2481 *

Also Published As

Publication number Publication date
WO2008107571A2 (fr) 2008-09-12
JP2010517913A (ja) 2010-05-27
CA2677711A1 (fr) 2008-09-12
FR2912398B1 (fr) 2009-04-24
FR2912398A1 (fr) 2008-08-15
EP2118007A2 (fr) 2009-11-18
CN101652321A (zh) 2010-02-17

Similar Documents

Publication Publication Date Title
WO2008107571A3 (fr) Silicates mixtes de lithium.
WO2008043790A3 (fr) Procédé de production d'oxydes métalliques, d'hydroxydes métalliques et/ou d'oxy-hydroxydes métalliques nanoparticulaires à surface modifiée
WO2010104346A3 (fr) Matière active d'électrode positive pour pile secondaire au lithium et pile secondaire au lithium comprenant celle-ci
WO2012033389A3 (fr) Matériau actif d'électrode positive pour un accumulateur au lithium, procédé de fabrication de ce matériau et accumulateur au lithium comprenant ce matériau
WO2008126364A1 (fr) Lithium/manganèse destiné à une batterie secondaire à électrolyte non aqueux, son procédé de production et batterie secondaire à électrolyte non aqueux associée
WO2006105848A3 (fr) Nanomateriau cristallin conduisant les ions et procede de fabrication
WO2009041606A1 (fr) Poudre de ferrite pour aimants lié, procédé de fabrication de la poudre, et aimants liés obtenus à l'aide de celle-ci
WO2010047524A3 (fr) Phosphate de fer lithié de structure olivine et son procédé de préparation
MY158720A (en) Dispersible sulphur fertilizer pellets
WO2007050984A3 (fr) Nanoparticules de carbone fluorescentes
DE602006013100D1 (de) Wasserbasierte dispersionen von metall-nanopartikeln
WO2012115411A3 (fr) Matière active d'électrode positive ayant des caractéristiques de puissance fournie améliorées, et accumulateur au lithium la comprenant
WO2012138127A3 (fr) Matière d'électrode positive pour une batterie secondaire au lithium pour améliorer le rendement, et batterie secondaire au lithium la comprenant
WO2012144785A3 (fr) Matière active d'électrode positive et batterie secondaire au lithium la comportant
WO2008151049A3 (fr) Nanoparticules fonctionnalisées par des acides nucléiques pour des applications thérapeutiques
WO2007099469A3 (fr) Particule pour libération contenant un agent avantageux
WO2011053933A3 (fr) Matières actives pour batteries au lithium-ion
MY159795A (en) Process for making printing ink
WO2011155787A3 (fr) Hydrotalcite de teneur en sodium limitée à un volume ultra-bas, une méthode de préparation de l'hydrotalcite et composition de résine synthétique contenant celle-ci
WO2009028326A1 (fr) Procédé de production de sulfure métallique
WO2011037972A3 (fr) Phosphates de manganèse et matériaux actifs d'électrode apparentés
WO2009117410A3 (fr) Formation de particules nanostructurées de médicaments médiocrement solubles dans l'eau et récupération par des techniques mécaniques
BR112012012339A2 (pt) método para controlar micro-organismos fitopatogênicos, suspensão aquosa de partículas de sal de cobre e uso de suspensão
WO2012039563A3 (fr) Matière active d'électrode positive comprenant de l'oxyde de manganèse et de lithium et batterie rechargeable à électrolyte non aqueux
EP3165587A3 (fr) Procédé de réduction d'évolution de sulfure d'hydrogène à partir d'asphalte et d'évolution de sulfure de fiouls lourds à partir d'asphalte et de combustibles lourds

Legal Events

Date Code Title Description
WWE Wipo information: entry into national phase

Ref document number: 200880010766.0

Country of ref document: CN

WWE Wipo information: entry into national phase

Ref document number: 2677711

Country of ref document: CA

ENP Entry into the national phase

Ref document number: 2009548714

Country of ref document: JP

Kind code of ref document: A

NENP Non-entry into the national phase

Ref country code: DE

WWE Wipo information: entry into national phase

Ref document number: 2008761851

Country of ref document: EP

121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 08761851

Country of ref document: EP

Kind code of ref document: A2

点击 这是indexloc提供的php浏览器服务，不要输入任何密码和下载