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WO2008105538A1 - Composé polymérisable de cristaux liquides, composition polymérisable de cristaux liquides, substance polymère et anisotrope sur le plan optique de cristaux liquides - Google Patents

Composé polymérisable de cristaux liquides, composition polymérisable de cristaux liquides, substance polymère et anisotrope sur le plan optique de cristaux liquides Download PDF

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Publication number
WO2008105538A1
WO2008105538A1 PCT/JP2008/053670 JP2008053670W WO2008105538A1 WO 2008105538 A1 WO2008105538 A1 WO 2008105538A1 JP 2008053670 W JP2008053670 W JP 2008053670W WO 2008105538 A1 WO2008105538 A1 WO 2008105538A1
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Prior art keywords
liquid crystal
polymerizable liquid
compound
composition
polymerizable
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PCT/JP2008/053670
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English (en)
Japanese (ja)
Inventor
Kei Sakamoto
Yoshihide Yachi
Naoto Kogoshi
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Zeon Corporation
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Publication date
Application filed by Zeon Corporation filed Critical Zeon Corporation
Priority to JP2009501323A priority Critical patent/JPWO2008105538A1/ja
Publication of WO2008105538A1 publication Critical patent/WO2008105538A1/fr

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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K19/00—Liquid crystal materials
    • C09K19/04—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit
    • C09K19/38—Polymers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K19/00—Liquid crystal materials
    • C09K19/04—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit
    • C09K19/06—Non-steroidal liquid crystal compounds
    • C09K19/32—Non-steroidal liquid crystal compounds containing condensed ring systems, i.e. fused, bridged or spiro ring systems
    • C09K19/322—Compounds containing a naphthalene ring or a completely or partially hydrogenated naphthalene ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C233/00—Carboxylic acid amides
    • C07C233/01—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms
    • C07C233/16—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by singly-bound oxygen atoms
    • C07C233/24—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by singly-bound oxygen atoms with the substituted hydrocarbon radical bound to the nitrogen atom of the carboxamide group by a carbon atom of a six-membered aromatic ring
    • C07C233/27—Carboxylic acid amides having carbon atoms of carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms having the nitrogen atom of at least one of the carboxamide groups bound to a carbon atom of a hydrocarbon radical substituted by singly-bound oxygen atoms with the substituted hydrocarbon radical bound to the nitrogen atom of the carboxamide group by a carbon atom of a six-membered aromatic ring having the carbon atom of the carboxamide group bound to a carbon atom of an acyclic unsaturated carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C235/00—Carboxylic acid amides, the carbon skeleton of the acid part being further substituted by oxygen atoms
    • C07C235/42—Carboxylic acid amides, the carbon skeleton of the acid part being further substituted by oxygen atoms having carbon atoms of carboxamide groups bound to carbon atoms of six-membered aromatic rings and singly-bound oxygen atoms bound to the same carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C235/00—Carboxylic acid amides, the carbon skeleton of the acid part being further substituted by oxygen atoms
    • C07C235/42—Carboxylic acid amides, the carbon skeleton of the acid part being further substituted by oxygen atoms having carbon atoms of carboxamide groups bound to carbon atoms of six-membered aromatic rings and singly-bound oxygen atoms bound to the same carbon skeleton
    • C07C235/44—Carboxylic acid amides, the carbon skeleton of the acid part being further substituted by oxygen atoms having carbon atoms of carboxamide groups bound to carbon atoms of six-membered aromatic rings and singly-bound oxygen atoms bound to the same carbon skeleton with carbon atoms of carboxamide groups and singly-bound oxygen atoms bound to carbon atoms of the same non-condensed six-membered aromatic ring
    • C07C235/58—Carboxylic acid amides, the carbon skeleton of the acid part being further substituted by oxygen atoms having carbon atoms of carboxamide groups bound to carbon atoms of six-membered aromatic rings and singly-bound oxygen atoms bound to the same carbon skeleton with carbon atoms of carboxamide groups and singly-bound oxygen atoms bound to carbon atoms of the same non-condensed six-membered aromatic ring with carbon atoms of carboxamide groups and singly-bound oxygen atoms, bound in ortho-position to carbon atoms of the same non-condensed six-membered aromatic ring
    • C07C235/60—Carboxylic acid amides, the carbon skeleton of the acid part being further substituted by oxygen atoms having carbon atoms of carboxamide groups bound to carbon atoms of six-membered aromatic rings and singly-bound oxygen atoms bound to the same carbon skeleton with carbon atoms of carboxamide groups and singly-bound oxygen atoms bound to carbon atoms of the same non-condensed six-membered aromatic ring with carbon atoms of carboxamide groups and singly-bound oxygen atoms, bound in ortho-position to carbon atoms of the same non-condensed six-membered aromatic ring having the nitrogen atoms of the carboxamide groups bound to hydrogen atoms or to acyclic carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
    • C08F20/10—Esters
    • C08F20/26—Esters containing oxygen in addition to the carboxy oxygen
    • C08F20/30—Esters containing oxygen in addition to the carboxy oxygen containing aromatic rings in the alcohol moiety
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K19/00—Liquid crystal materials
    • C09K19/04—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit
    • C09K19/06—Non-steroidal liquid crystal compounds
    • C09K19/08—Non-steroidal liquid crystal compounds containing at least two non-condensed rings
    • C09K19/10—Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing at least two benzene rings
    • C09K19/20—Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing at least two benzene rings linked by a chain containing carbon and oxygen atoms as chain links, e.g. esters or ethers
    • C09K19/2007—Non-steroidal liquid crystal compounds containing at least two non-condensed rings containing at least two benzene rings linked by a chain containing carbon and oxygen atoms as chain links, e.g. esters or ethers the chain containing -COO- or -OCO- groups
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K19/00—Liquid crystal materials
    • C09K19/52—Liquid crystal materials characterised by components which are not liquid crystals, e.g. additives with special physical aspect: solvents, solid particles
    • C09K19/54—Additives having no specific mesophase characterised by their chemical composition
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K19/00—Liquid crystal materials
    • C09K19/52—Liquid crystal materials characterised by components which are not liquid crystals, e.g. additives with special physical aspect: solvents, solid particles
    • C09K19/58—Dopants or charge transfer agents
    • C09K19/586—Optically active dopants; chiral dopants
    • C09K19/588—Heterocyclic compounds
    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
    • G02B1/04—Optical elements characterised by the material of which they are made; Optical coatings for optical elements made of organic materials, e.g. plastics
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    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K19/00—Liquid crystal materials
    • C09K19/04—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit
    • C09K2019/0444—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit characterized by a linking chain between rings or ring systems, a bridging chain between extensive mesogenic moieties or an end chain group
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    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K19/00—Liquid crystal materials
    • C09K19/04—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit
    • C09K2019/0444—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit characterized by a linking chain between rings or ring systems, a bridging chain between extensive mesogenic moieties or an end chain group
    • C09K2019/0448—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit characterized by a linking chain between rings or ring systems, a bridging chain between extensive mesogenic moieties or an end chain group the end chain group being a polymerizable end group, e.g. -Sp-P or acrylate
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K19/00—Liquid crystal materials
    • C09K19/04—Liquid crystal materials characterised by the chemical structure of the liquid crystal components, e.g. by a specific unit
    • C09K19/06—Non-steroidal liquid crystal compounds
    • C09K19/34—Non-steroidal liquid crystal compounds containing at least one heterocyclic ring
    • C09K19/3402—Non-steroidal liquid crystal compounds containing at least one heterocyclic ring having oxygen as hetero atom
    • C09K19/3405—Non-steroidal liquid crystal compounds containing at least one heterocyclic ring having oxygen as hetero atom the heterocyclic ring being a five-membered ring
    • C09K2019/3408—Five-membered ring with oxygen(s) in fused, bridged or spiro ring systems

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Liquid Crystal Substances (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

La présente invention concerne des composés polymérisables de cristaux liquides de la formule (I) suivante; une composition polymérisable de cristaux liquides contenant l'un quelconque des composés et un composé chiral polymérisable; et un polymère de cristaux liquides, etc. obtenu par la polymérisation du composé ou de la composition. Cette invention concerne un composé polymérisable de cristaux liquides et une composition polymérisable de cristaux liquides à partir desquels un polymère de cristaux liquides présentant une anisotropie optique extrêmement élevée et une excellente solubilité dans des solvants organiques et excellant en compatibilité avec divers additifs, tels que des agents d'alignement, qui peuvent être formés; et un polymère de cristaux liquides, etc. obtenu par la polymérisation du composé ou de la composition. Dans la formule (I), M1 représente un hydrocarbure aromatique en C6 à C24 ayant trois ou quatre liaisons; chacun de Y1 à Y8 représente -C(=O)-O-CH2CH2-O-, -C(=O)-O-CH2CH2-, etc.; chacun de G1 à G3 représente un groupe aliphatique bivalent en C1 à C20, etc.; chacun de Z1 à Z3 représente un groupe alcényle en C2 à C10, etc.; chacun de A1 et A2 représente un groupe contenant un cycle aromatique bivalent ou trivalent en C4 à C24, etc.; et chacun de a et b vaut 0, 1 ou 2, c 1 ou 2, et chacun de p, q et r 0 or 1.
PCT/JP2008/053670 2007-03-01 2008-02-29 Composé polymérisable de cristaux liquides, composition polymérisable de cristaux liquides, substance polymère et anisotrope sur le plan optique de cristaux liquides WO2008105538A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2009501323A JPWO2008105538A1 (ja) 2007-03-01 2008-02-29 重合性液晶化合物、重合性液晶組成物、液晶性高分子及び光学異方体

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2007051440 2007-03-01
JP2007-051440 2007-03-01

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WO2008105538A1 true WO2008105538A1 (fr) 2008-09-04

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JP (1) JPWO2008105538A1 (fr)
KR (1) KR20100014882A (fr)
CN (1) CN101622219A (fr)
WO (1) WO2008105538A1 (fr)

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2012010918A3 (fr) * 2010-07-21 2012-03-29 Medicontur Orvostechnikai Kft. Dispositifs optiques
WO2012105393A1 (fr) * 2011-02-03 2012-08-09 シャープ株式会社 Dispositif d'exposition, dispositif d'affichage à cristaux liquides ainsi que leur procédé de fabrication
WO2015004947A1 (fr) * 2013-07-10 2015-01-15 Jnc株式会社 Composé polymérisable, composition polymérisable et élément d'affichage à cristaux liquides
JP2015526390A (ja) * 2012-06-12 2015-09-10 エルジー・ケム・リミテッド 重合性液晶化合物、これを含む液晶組成物及び光学異方体
US9207360B2 (en) 2011-04-27 2015-12-08 Zeno Corporation Polymerizable compound, polymerizable composition, polymer, and optically anisotropic body
JP2016190850A (ja) * 2013-07-01 2016-11-10 エルジー・ケム・リミテッド ポリオルガノシロキサン化合物、製造方法およびこれを含むコーポリカーボネート樹脂
CN106256874A (zh) * 2015-06-17 2016-12-28 捷恩智株式会社 聚合性液晶组合物、聚合性液晶层、液晶膜、光学补偿元件及光学元件
JP7547913B2 (ja) 2019-12-16 2024-09-10 Jnc株式会社 化合物、液晶組成物および液晶表示素子

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2011122298A1 (fr) * 2010-03-31 2011-10-06 日本ゼオン株式会社 Composé chiral polymérisable, composition cristalline liquide polymérisable, polymère cristal liquide et matériau optiquement anisotrope
JP6222085B2 (ja) * 2012-05-30 2017-11-01 日本ゼオン株式会社 重合性化合物、重合性組成物、高分子、及び光学異方体
WO2013187668A1 (fr) * 2012-06-12 2013-12-19 주식회사 엘지화학 Composé à cristaux liquides polymérisable, composition à cristaux liquides contenant celui-ci, et corps anisotrope optique
JP6042538B2 (ja) 2012-06-28 2016-12-14 エルジー・ケム・リミテッド 重合性液晶化合物、これを含む液晶組成物及び光学異方体
WO2014003416A1 (fr) * 2012-06-28 2014-01-03 주식회사 엘지화학 Composé cristal liquide polymérisable, et composition de cristaux liquides et corps optiquement anisotrope le comprenant
KR102212172B1 (ko) * 2012-07-09 2021-02-03 제온 코포레이션 중합성 화합물, 중합성 조성물, 고분자, 광학 이방체, 및 중합성 화합물의 제조 방법
JP6485354B2 (ja) * 2013-08-22 2019-03-20 日本ゼオン株式会社 重合性化合物、重合性組成物、高分子、及び光学異方体
CN104090431B (zh) * 2014-07-02 2016-09-28 京东方科技集团股份有限公司 一种胆甾相液晶聚合物取向层及其制备方法、液晶显示面板
WO2019003812A1 (fr) * 2017-06-30 2019-01-03 日本ゼオン株式会社 Couche optiquement anisotrope et son procédé de production, stratifié optiquement anisotrope, article multicouche pour une utilisation de transfert, plaque de polarisation et dispositif d'affichage d'image
CN108530300B (zh) * 2018-06-07 2021-03-23 江苏创拓新材料有限公司 一种可聚合单体化合物及其制备方法

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Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2012010918A3 (fr) * 2010-07-21 2012-03-29 Medicontur Orvostechnikai Kft. Dispositifs optiques
WO2012105393A1 (fr) * 2011-02-03 2012-08-09 シャープ株式会社 Dispositif d'exposition, dispositif d'affichage à cristaux liquides ainsi que leur procédé de fabrication
US9207360B2 (en) 2011-04-27 2015-12-08 Zeno Corporation Polymerizable compound, polymerizable composition, polymer, and optically anisotropic body
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