+

WO2008101603A3 - Nouveau catalyseur et hydrogénations associées - Google Patents

Nouveau catalyseur et hydrogénations associées Download PDF

Info

Publication number
WO2008101603A3
WO2008101603A3 PCT/EP2008/000995 EP2008000995W WO2008101603A3 WO 2008101603 A3 WO2008101603 A3 WO 2008101603A3 EP 2008000995 W EP2008000995 W EP 2008000995W WO 2008101603 A3 WO2008101603 A3 WO 2008101603A3
Authority
WO
WIPO (PCT)
Prior art keywords
sintered metal
metal fibers
alkynols
hydrogenation
oxide layer
Prior art date
Application number
PCT/EP2008/000995
Other languages
English (en)
Other versions
WO2008101603A2 (fr
Inventor
Werner Bonrath
Martin Grasemann
Albert Renken
Natalia Semagina
Lioubov Kiwi-Minsker
Original Assignee
Dsm Ip Assets Bv
Werner Bonrath
Martin Grasemann
Albert Renken
Natalia Semagina
Lioubov Kiwi-Minsker
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dsm Ip Assets Bv, Werner Bonrath, Martin Grasemann, Albert Renken, Natalia Semagina, Lioubov Kiwi-Minsker filed Critical Dsm Ip Assets Bv
Priority to CN2008800055172A priority Critical patent/CN101616733B/zh
Priority to EP08707639A priority patent/EP2125199A2/fr
Publication of WO2008101603A2 publication Critical patent/WO2008101603A2/fr
Publication of WO2008101603A3 publication Critical patent/WO2008101603A3/fr

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/60—Platinum group metals with zinc, cadmium or mercury
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/652—Chromium, molybdenum or tungsten
    • B01J23/6525—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/90—Regeneration or reactivation
    • B01J23/96—Regeneration or reactivation of catalysts comprising metals, oxides or hydroxides of the noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/391—Physical properties of the active metal ingredient
    • B01J35/393—Metal or metal oxide crystallite size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/50—Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
    • B01J35/58—Fabrics or filaments
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0215—Coating
    • B01J37/0225—Coating of metal substrates
    • B01J37/0226—Oxidation of the substrate, e.g. anodisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/024—Multiple impregnation or coating
    • B01J37/0242—Coating followed by impregnation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/024—Multiple impregnation or coating
    • B01J37/0244—Coatings comprising several layers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/48—Liquid treating or treating in liquid phase, e.g. dissolved or suspended
    • B01J38/50—Liquid treating or treating in liquid phase, e.g. dissolved or suspended using organic liquids
    • B01J38/52—Liquid treating or treating in liquid phase, e.g. dissolved or suspended using organic liquids oxygen-containing
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/17—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by hydrogenation of carbon-to-carbon double or triple bonds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00—Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/30—Scanning electron microscopy; Transmission electron microscopy
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/44—Palladium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B01J37/036—Precipitation; Co-precipitation to form a gel or a cogel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16—Reducing
    • B01J37/18—Reducing with gases containing free hydrogen
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

L'invention concerne un catalyseur structuré à base de fibres métalliques frittées (SMF) revêtues par une couche de ZnO imprégnée de nanoparticules de Pd; des réactions d'un produit de départ organique avec de l'hydrogène en présence dudit catalyseur ainsi que des vitamines, caroténoïdes, des ingrédients de parfum, et/ou des aliments ou ingrédients alimentaires préparés au moyen de cette réaction.
PCT/EP2008/000995 2007-02-19 2008-02-09 Nouveau catalyseur et hydrogénations associées WO2008101603A2 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
CN2008800055172A CN101616733B (zh) 2007-02-19 2008-02-09 基于包覆有经钯纳米颗粒浸渍的氧化锌层的经烧结金属纤维的用于炔醇氢化的催化剂
EP08707639A EP2125199A2 (fr) 2007-02-19 2008-02-09 Nouveau catalyseur et hydrogénations associées

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP07003423.6 2007-02-19
EP07003423 2007-02-19

Publications (2)

Publication Number Publication Date
WO2008101603A2 WO2008101603A2 (fr) 2008-08-28
WO2008101603A3 true WO2008101603A3 (fr) 2008-12-18

Family

ID=39643801

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2008/000995 WO2008101603A2 (fr) 2007-02-19 2008-02-09 Nouveau catalyseur et hydrogénations associées

Country Status (3)

Country Link
EP (1) EP2125199A2 (fr)
CN (1) CN101616733B (fr)
WO (1) WO2008101603A2 (fr)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104136120A (zh) * 2012-02-24 2014-11-05 帝斯曼知识产权资产管理有限公司 包含钴铬钼-合金的金属粉末状催化剂

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101780406B (zh) * 2009-01-19 2012-06-27 中国科学院化学研究所 一种纳米金属催化剂及其制备方法与应用
EP2528882B1 (fr) 2010-01-28 2016-11-30 DSM IP Assets B.V. Procédé d'hydrogénation
WO2012001166A1 (fr) * 2010-07-01 2012-01-05 Dsm Ip Assets B.V. Nouveau catalyseur structuré
CN102503772A (zh) * 2011-10-11 2012-06-20 上海博鹤企业发展有限公司 一种生产2-甲基-3-丁烯-2-醇的方法
BR112014010078B1 (pt) * 2011-10-27 2020-10-13 Dsm Ip Assets B.V. processo de hidrogenação de um composto
US20150025267A1 (en) * 2012-02-24 2015-01-22 Dsm Assets B.V. Metal powderdous catalyst comprising a fe-alloy
CN104136115A (zh) * 2012-02-24 2014-11-05 帝斯曼知识产权资产管理有限公司 用于氢化工艺的金属粉末状催化剂
US9421536B2 (en) 2012-04-18 2016-08-23 Dsm Ip Assets B.V Device useful for hydrogenation reactions (II)
KR102082530B1 (ko) * 2012-04-18 2020-02-27 디에스엠 아이피 어셋츠 비.브이. 수소화 반응에 유용한 장치(i)
JP6238211B2 (ja) * 2012-04-18 2017-11-29 ディーエスエム アイピー アセッツ ビー．ブイ． 水素化反応に有用な装置（ｉｉｉ）
EP3052460B1 (fr) * 2013-09-30 2024-12-04 DSM IP Assets B.V. Nouveau système catalytique pour des hydrogénations sélectives
CN109382100A (zh) * 2018-11-12 2019-02-26 大连理工大学 一种选择加氢获取1,4-丁烯二醇的含锌金属间化合物催化剂及其制备方法
JP7631239B2 (ja) * 2019-06-21 2025-02-18 コモンウェルス サイエンティフィック アンド インダストリアル リサーチ オーガナイゼーション 足場を触媒的にコーティングするためのプロセス
CN114073959B (zh) * 2020-08-19 2023-08-29 中国石油化工股份有限公司 一种丁烯氧化脱氢催化剂及其制备方法和应用
CN115368209B (zh) * 2022-08-30 2023-09-19 万华化学集团股份有限公司 一种甲基丁烯醇的制备方法

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3192168A (en) * 1959-02-02 1965-06-29 Rhone Poulenc Sa Palladium-tin catalysts
JP2002170429A (ja) * 2000-11-29 2002-06-14 C Uyemura & Co Ltd 高密度触媒核分散層を有する基体並びに改質酸化亜鉛皮膜を有する導電性物品及びその作製方法
US20030187294A1 (en) * 1997-08-13 2003-10-02 Celanese Chemical Europe Gmbh Process for producing catalysts comprising nanosize metal particles on a porous support, in particular for the gas-phase oxidation of ethylene and acetic acid to give vinyl acetate
WO2005030390A1 (fr) * 2003-05-07 2005-04-07 Battelle Memorial Institute Catalyseurs de reformage d'alcools a la vapeur et procedes de reformage d'alcools a la vapeur
CN1721063A (zh) * 2004-07-13 2006-01-18 中国科学院大连化学物理研究所 一种甲醇氧化重整制氢催化剂及制法和应用
JP2007244963A (ja) * 2006-03-14 2007-09-27 Ihi Corp メタノール改質触媒及びその製造方法及びメタノール改質方法及びメタノール改質器

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3192168A (en) * 1959-02-02 1965-06-29 Rhone Poulenc Sa Palladium-tin catalysts
US20030187294A1 (en) * 1997-08-13 2003-10-02 Celanese Chemical Europe Gmbh Process for producing catalysts comprising nanosize metal particles on a porous support, in particular for the gas-phase oxidation of ethylene and acetic acid to give vinyl acetate
JP2002170429A (ja) * 2000-11-29 2002-06-14 C Uyemura & Co Ltd 高密度触媒核分散層を有する基体並びに改質酸化亜鉛皮膜を有する導電性物品及びその作製方法
WO2005030390A1 (fr) * 2003-05-07 2005-04-07 Battelle Memorial Institute Catalyseurs de reformage d'alcools a la vapeur et procedes de reformage d'alcools a la vapeur
CN1721063A (zh) * 2004-07-13 2006-01-18 中国科学院大连化学物理研究所 一种甲醇氧化重整制氢催化剂及制法和应用
JP2007244963A (ja) * 2006-03-14 2007-09-27 Ihi Corp メタノール改質触媒及びその製造方法及びメタノール改質方法及びメタノール改質器

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
TRIBOLET P ET AL: "Palladium on carbon nanofibers grown on metallic filters as novel structured catalyst", 15 August 2005, CATALYSIS TODAY, ELSEVIER, PAGE(S) 337 - 343, ISSN: 0920-5861, XP004998972 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104136120A (zh) * 2012-02-24 2014-11-05 帝斯曼知识产权资产管理有限公司 包含钴铬钼-合金的金属粉末状催化剂
CN104136120B (zh) * 2012-02-24 2017-02-22 帝斯曼知识产权资产管理有限公司 包含钴铬钼‑合金的金属粉末状催化剂

Also Published As

Publication number Publication date
CN101616733B (zh) 2013-05-15
EP2125199A2 (fr) 2009-12-02
WO2008101603A2 (fr) 2008-08-28
CN101616733A (zh) 2009-12-30

Similar Documents

Publication Publication Date Title
WO2008101603A3 (fr) Nouveau catalyseur et hydrogénations associées
WO2009043496A3 (fr) Catalyseur résistant au frittage pour l'hydrogénation et la déshydrogénation et son procédé de fabrication
WO2006005479A3 (fr) Procede continu de metathese avec des catalyseurs au ruthenium
BR112012019797A2 (pt) processo de hidrogenação.
MY161990A (en) Monolith catalyst and use thereof
WO2009106621A8 (fr) Procédé de production de composés carbonylés oléfiniquement insaturés par déshydrogénation oxydative d'alcools
MY146792A (en) Catalysts containing tungsten compounds and method for dehyrating glycerine
MX2016002376A (es) Catalizadores para la oxidacion de monoxido de carbono y/o compuestos organicos volatiles.
MY151251A (en) Supported composite particle material, production process of same and process for producing compounds using supported composite particle material as catalyst for chemical synthesis
WO2012059808A8 (fr) Pot catalytique pour gaz d'échappement d'automobile
MX2014008253A (es) Catalizadores de hidrogenacion con soportes modificados con cobalto.
WO2010002534A3 (fr) Réacteur rotatif à lit fixe à cisaillement élevé
MX2012004840A (es) Catalizadores para hacer acetato de etilo a partir de acido acetico.
WO2006105799A3 (fr) Procede d'hydrogenation selective d'acetylene en ethylene
MX345473B (es) Catalizadores de oxidación diesel, sistemas y métodos de tratamiento.
WO2008136264A1 (fr) Catalyseur sur support pour réaction d'hydrogénation/déshydrogénation, procédé de fabrication du catalyseur et procédé de stockage/alimentation en hydrogène utilisant ledit catalyseur
EA201170581A1 (ru) Способ получения катализатора окисления и катализаторы, полученные данным способом
WO2007130908A3 (fr) Catalyseur fischer-tropsch
EP2208529A3 (fr) Catalyseur de reformage d'hydrocarbures, son procédé de préparation et pile à combustible comprenant le catalyseur de reformage d'hydrocarbures
WO2010096336A3 (fr) Catalyseur de reformage
WO2009023064A3 (fr) Catalyseur et procédé d'époxydation directe
WO2009151255A3 (fr) Catalyseur d’oxydation de contact en phase gazeuse d’un hydrocarbure, son procédé de préparation et procédé d’oxydation en phase gazeuse d’un hydrocarbure utilisant ce catalyseur
WO2009029535A3 (fr) Processus de production chimique, systèmes et compositions de catalyseur
UA100395C2 (en) Process for a reduction in the amount of sulphur compounds, hydrogen cyanide and formic acid in synthesis gas
WO2011086343A3 (fr) Catalyseur amélioré

Legal Events

Date Code Title Description
WWE Wipo information: entry into national phase

Ref document number: 200880005517.2

Country of ref document: CN

WWE Wipo information: entry into national phase

Ref document number: 2008707639

Country of ref document: EP

WWE Wipo information: entry into national phase

Ref document number: 5323/DELNP/2009

Country of ref document: IN

NENP Non-entry into the national phase

Ref country code: DE

121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 08707639

Country of ref document: EP

Kind code of ref document: A2

点击 这是indexloc提供的php浏览器服务，不要输入任何密码和下载