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WO2008149841A1 - Method for producing β-fluoro-α,β-unsaturated carbonyl compound - Google Patents

Method for producing β-fluoro-α,β-unsaturated carbonyl compound Download PDF

Info

Publication number
WO2008149841A1
WO2008149841A1 PCT/JP2008/060147 JP2008060147W WO2008149841A1 WO 2008149841 A1 WO2008149841 A1 WO 2008149841A1 JP 2008060147 W JP2008060147 W JP 2008060147W WO 2008149841 A1 WO2008149841 A1 WO 2008149841A1
Authority
WO
WIPO (PCT)
Prior art keywords
fluoro
producing
carbonyl compound
unsaturated carbonyl
compound
Prior art date
Application number
PCT/JP2008/060147
Other languages
French (fr)
Japanese (ja)
Inventor
Takafumi Yoshimura
Shoji Hara
Tsuyoshi Fukuhara
Original Assignee
National University Corporation Hokkaido University
Mitsubishi Gas Chemical Company, Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by National University Corporation Hokkaido University, Mitsubishi Gas Chemical Company, Inc. filed Critical National University Corporation Hokkaido University
Priority to JP2009517859A priority Critical patent/JPWO2008149841A1/en
Publication of WO2008149841A1 publication Critical patent/WO2008149841A1/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/63—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by introduction of halogen; by substitution of halogen atoms by other halogen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
    • C07C49/20—Unsaturated compounds containing keto groups bound to acyclic carbon atoms
    • C07C49/227—Unsaturated compounds containing keto groups bound to acyclic carbon atoms containing halogen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
    • C07C49/76—Ketones containing a keto group bound to a six-membered aromatic ring
    • C07C49/82—Ketones containing a keto group bound to a six-membered aromatic ring containing hydroxy groups
    • C07C49/835—Ketones containing a keto group bound to a six-membered aromatic ring containing hydroxy groups having unsaturation outside an aromatic ring

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Disclosed is a commercially excellent method for producing a β-fluoro-α,β-unsaturated carbonyl compound, which is useful in applications to functional chemicals such as pharmaceutical products, with high yield and high selectivity. Specifically disclosed is a method for producing a β-fluoro-α,β-unsaturated carbonyl compound, wherein a β-dicarbonyl compound is reacted with a specific fluoroamine.
PCT/JP2008/060147 2007-06-08 2008-06-02 Method for producing β-fluoro-α,β-unsaturated carbonyl compound WO2008149841A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2009517859A JPWO2008149841A1 (en) 2007-06-08 2008-06-02 Process for producing β-fluoro-α, β-unsaturated carbonyl compound

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2007-152608 2007-06-08
JP2007152608 2007-06-08

Publications (1)

Publication Number Publication Date
WO2008149841A1 true WO2008149841A1 (en) 2008-12-11

Family

ID=40093657

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2008/060147 WO2008149841A1 (en) 2007-06-08 2008-06-02 Method for producing β-fluoro-α,β-unsaturated carbonyl compound

Country Status (2)

Country Link
JP (1) JPWO2008149841A1 (en)
WO (1) WO2008149841A1 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2013508446A (en) * 2009-11-05 2013-03-07 ロディア オペレーションズ Method for producing alkyl hydroperoxide compound

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
KOBAYASHI S. ET AL., TETRAHEDRON LETTERS, vol. 45, no. 6, 2 April 2004 (2004-04-02), pages 1287 - 1289, XP004484833 *
KOBAYASHI S. ET AL., TETRAHEDRON, vol. 60, no. 32, 2 August 2004 (2004-08-02), pages 6923 - 6930, XP004522095 *
STEPANOV I.V. ET AL., ZHURNAL ORGANICHESKOI KHIMII, vol. 22, no. 1, 1986, pages 227 - 228 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2013508446A (en) * 2009-11-05 2013-03-07 ロディア オペレーションズ Method for producing alkyl hydroperoxide compound
JP2015078239A (en) * 2009-11-05 2015-04-23 ロディア オペレーションズＲｈｏｄｉａ Ｏｐｅｒａｔｉｏｎｓ Alkyl hydroperoxide compound production method

Also Published As

Publication number Publication date
JPWO2008149841A1 (en) 2010-08-26

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