WO2007100309A1

WO2007100309A1 - Versatile additive to lubricating and fuel materials and fuels containing said additive

Info

Publication number: WO2007100309A1
Application number: PCT/UA2006/000015
Authority: WO
Inventors: Oleksandr Adolfovich Ozeryansky
Original assignee: Ozeryansky Oleksandr Adolfovic
Priority date: 2006-03-02
Filing date: 2006-03-28
Publication date: 2007-09-07
Also published as: CN101180384A; EP1990397A4; UA88878C2; CN101180384B; EP1990397A1

Abstract

The claimed inventions relate to petrochemistry, in particular to additives for lubricating and fuel materials and to a versatile additive-containing fuel for internal combustion engine, diesel fuel and a furnace fuel for furnaces of heat-and-power generating plants and metal melting furnaces. The inventive additive contains 0.1-82% of monoatomic aliphatic saturated C1-C4 alcohol, 0.1-16% of water- and/or alcohol-soluble ammonium salt of saturated monocarboxylic C2-C5 acid and/or 0.1-44% of carbamide and water up to 100%. The fuel contains a mixture of liquid hydrocarbons and the additive dissolved therein. Gasoline, diesel fuel and furnace fuel are used in the form of the liquid hydrocarbon mixture. The additive is embodied in the form of the versatile additive having the above-mentioned composition taken in a quantity raging from 0.000005 to 0.005%. The liquid hydrocarbon mixture is also embodied in the form of a colza oil and/or a diesel fuel and/or a colza oil methyl ether. Said invention makes it possible to reduce a soot deposit formation during the operation of engines, decrease the toxicity of exhaust gases and the wearing of metal components of engine fuel systems by increasing a molar refraction due to formation of a double ion layer in friction pairs.

Description

Universal additive for lubricants and fuel materials and fuel containing it

The present invention relates to the field of petrochemistry, in particular, to additives for lubricants and fuel materials, as well as fuel for internal combustion engines, diesel fuel and heating oil for furnaces of heat and power generating stations and metal melting furnaces, which include a universal additive.

Closest to the proposed universal additive in technical essence is a universal additive for lubricants and fuel materials containing an aliphatic C ₁ -C ₄ monohydric alcohol and water / RF Patent N ° 2034905 for invention, IPC 6 C10L1 / 18, C10L1 / 22, Date Publications: 1995.05.10 /. In addition to the mentioned ingredients, the known additive contains urea and acetic acid. The disadvantage of the described additive is that during its use some metal structures of the fuel system, in particular carburetor internal combustion engines, are subject to increased corrosion and wear, which reduces the engine's life.

Closest to the proposed fuel for an internal combustion engine is a fuel comprising a mixture of liquid hydrocarbons and a small amount of additive dissolved in a mixture of liquid hydrocarbons / RF Patent Ns 2057787 for invention, IPC 6 C10L1 / 18, C10L1 / 22, C10L1 / 28; Date of publication: 1996.04.10 /. Mentioned fuel contains gasoline and kerosene-gas oil fractions, as well as nitrates of organic alcohols, a copolymer of higher esters of carboxylic acids with vinyl monomers, a metal polymer of organic acids and polymethylsiloxane. The described fuel allows to increase the combustion of hydrocarbon fuel due to its supplement with additives containing metals, but the presence of metals in the fuel enhances the wear and corrosion of metal parts, which reduces the engine resource. Closest to the proposed fuel for a diesel engine is a fuel comprising a mixture of liquid hydrocarbons and a small amount of additive dissolved in a mixture of liquid hydrocarbons / RF Patent M> 2057787 for invention, IPC 6 C10L1 / 18, C10L1 / 22, C10L1 / 28; Date of publication: 1996.04.10 /. Mentioned fuel contains gasoline and kerosene-gas oil fractions, as well as nitrates of organic alcohols, a copolymer of higher esters of carboxylic acids with vinyl monomers, a metal polymer of organic acids and polymethylsiloxane.

The described fuel allows to increase the combustion of hydrocarbon fuel due to its supplement with additives containing metals, but the presence of metals in the fuel increases the wear and corrosion of metal parts of the fuel system of the engine, which reduces its resource.

The author did not identify fuel compositions that are used exclusively as heating oil for furnaces of heat and power generating stations and metal-smelting furnaces, therefore, the fuel closest to the proposed one is a mixture of liquid hydrocarbons containing a small amount of an additive dissolved in a mixture of liquid hydrocarbons / RF Patent N ° 2246528 for the invention, IPC 7 C10L1 / 22, Date of publication: 2005.02.20 /.

A disadvantage of the described fuel is that during its use as a heating fuel for furnaces of heat and power generating stations and metal-smelting furnaces, such an amount of additive is required that the use of such fuel with an additive becomes unprofitable.

In the described fuel compositions, the effect of increasing the thermal efficiency of the engine is achieved only by increasing combustion and is not associated with ion processes in the cylinder, since for a significant effect on these processes the compounds in the composition

SUBSTITUTE SHEET (RULE 26) fuels must be able to form a stable ionized atmosphere around gas particles. An indicator of this property is the polarization of the molecules of the compound in the external electric field of the central ion of the compound. A measure of polarization is molar refraction, a function of the refractive index of a substance, its molecular weight and density, independent of the state of aggregation and temperature. Molar refraction, Rm, m ³ / mol, is determined by the formula: Rm = (n ² -l) / (n ² + l) M / p, where n is the refractive index of the substance;

M is the molecular weight, kg / mol; p is the density, kg / m ³ .

Molar refractions of known additives have relatively low values, not exceeding 3 * 10 ^" m / mol, therefore, such additives practically do not affect ionic processes during fuel combustion and do not contribute to an increase in the thermal efficiency of the engine.

The basis of the proposed inventions is the task of creating such compositions of fuel and universal additives to fuel and lubricants, which during their use both for motor (transmission) oils, lubricants, gasolines, and for kerosene, diesel fuel, heating oil and fuel oil, allowed in addition to reducing the formation of soot during the operation of engines and reducing the toxicity of exhaust gases, reduce the wear of metal elements of the fuel systems of engines by creating conditions for molar refraction by the formation of a double ion layer in friction pairs.

The proposed, as well as the well-known, universal additive to fuel materials, contains aliphatic Cj-C ₄ monohydric saturated alcohol and water, and, in accordance with the invention, it additionally contains water and / or alcohol-soluble ammonium salt of saturated mono-basic carbonic C ₂ -C ₅ acid and / or carbonic acid and / or urea with

SUBSTITUTE SHEET (RULE 26) this ratio of ingredients, in mass. %: aliphatic Ci-C ₄ monohydric saturated alcohol OD -82 water and / or alcohol-soluble ammonium salt of the limiting monobasic carboxylic C ₂ -C ₅ acid and / or carbonic acid OD-16 and / or carbamide OD-44 water - up to 100.

The first variant of the proposed fuel for an internal combustion engine contains a mixture of liquid hydrocarbons and an additive dissolved in a mixture of liquid hydrocarbons, and, in accordance with the invention, gasoline is used as a mixture of liquid hydrocarbons and a universal additive to fuel materials is used as an additive, the composition of which is given higher, with this ratio of ingredients, in wt.%: universal additive - 0.0000050 ... 0.0008 gasoline - the rest.

The second variant of the proposed fuel for an internal combustion engine contains a mixture of liquid hydrocarbons and an additive dissolved in a mixture of liquid hydrocarbons, and, in accordance with the invention, fuel oil is used as a mixture of liquid hydrocarbons, and as a additive is a universal additive to fuel materials, the composition of which is given higher, with this ratio of ingredients, in wt.%: universal additive - 0.00001 ... 0.005 fuel oil - up to 100. The first version of the proposed fuel for a diesel engine contains a mixture of liquid hydrocarbons s and an additive dissolved in a mixture of liquid hydrocarbons, and, in accordance with the invention, diesel fuel was used as a mixture of liquid hydrocarbons, and as a additive, a universal additive to fuel materials, the composition of which is given above, with this ratio of ingredients, in mass. %: universal additive - 0.00001 ... 0.0025 diesel fuel - up to 100.

SUBSTITUTE SHEET (RULE 26) The second variant of the proposed fuel for a diesel engine contains a mixture of liquid hydrocarbons and an additive dissolved in a mixture of liquid hydrocarbons, and, in accordance with the invention, rapeseed oil and / or diesel fuel and / or rapeseed oil methyl ester are used as a mixture of liquid hydrocarbons, and as an additive - a universal additive to fuel materials, the composition of which is given above, with this ratio of ingredients, in mass%: universal additive - 0.00001 ... 0.0025 diesel fuel and / or rapeseed methyl ester about oil - 10 ... 90 rapeseed oil - up to 100.

The third variant of the proposed fuel for a diesel engine contains a mixture of liquid hydrocarbons and an additive dissolved in a mixture of liquid hydrocarbons, and, in accordance with the invention, rapeseed oil methyl ester is used as a mixture of liquid hydrocarbons, and a universal additive to fuel materials is used as an additive, composition which is given above, with this ratio of ingredients, in wt.%: universal additive - 0.00001 ... 0.0025 rapeseed oil methyl ester - up to 100.

The fuels for furnaces of heat and power generating stations and metal melting furnaces contain a mixture of liquid hydrocarbons and an additive dissolved in a mixture of liquid hydrocarbons, and, in accordance with the invention, fuel oil is used as a mixture of liquid hydrocarbons, and a universal additive to fuel materials is used as an additive, the composition of which is given above, with this ratio of ingredients, in mass%: universal additive - 0.00001 ... 0.005 fuel oil - up to 100.

The author found in some organic compounds the ability to high polarization, characterized by molar refraction values not less than 5 * 10 ^'5 m ³ / mol, qualities that during the combustion of the fuel provide rapid accumulation of excess negative ions in the combustion chamber due to their diffusion from internal

SUBSTITUTE SHEET (RULE 26) the surface of the cylinder to its volume, which leads to the formation of electrostatic pressure of mutually repulsive charges of the same name in the direction of the working surface of the piston. The occurrence of such electrostatic pressure is due to the conversion of part of the thermal energy of the molecules of the substances of the combustion products into the potential energy of ions in the electrostatic field of the space charge. With an increase in working volume due to the movement of the piston, this potential energy is completely converted into useful work. Thus, the total fraction of heat that is converted to work in the presence of an electrostatic composite energy is greater than in the diabetic expansion process that occurs in the absence of ion diffusion. The addition of organic substances with the indicated properties in the form of additives to the fuel provides an increase in the value of the thermal efficiency of the engine and a reduction in the toxicity of exhaust gases by lowering the working temperature in the cylinder. In addition, the absence of solid particles and halogens in the combustion products, together with a reduced combustion temperature, helps to reduce engine wear and extend the life of catalytic filters.

The proposed universal additive to fuel materials is a compound having the following structural formula:

X or

Ri-N - C = O

I I

R ₂ X

where Ri is a substituted or unsubstituted aryl, alkyl or alkenyl radical;

SUBSTITUTE SHEET (RULE 26) R ₂ is hydrogen, an aryl or alkyl radical;

X is a substituted or unsubstituted amino group, a substituted or unsubstituted aryl, alkyl or alkenyl radical.

Examples of such compounds are dibenzalacetone (the molar refraction value is 7.29 * 10 ^"5 m ³ / mol), salicylic acid N-phenylamide (the molar refraction value is 6.04 * 10 ^{" 5} m ³ / mol), N ₅ N ¹ - dimethyl-N, N'-diphenylurea (the value of molar refraction is 7.22 * 10 ^"5 m ³ / mol), N, N'-diphenyl-N, N'-diethylurea (the value of molar refraction is 8.15 * 10 ^"5 m ³ / mol) or N, N'-diisopropyl-N, N'-diphenylurea (the molar refraction value is 9.08 * 10 ^{" 5} m ³ / mol). In addition to the above, other compounds can be used, meeting the above requirements.

The proposed universal fuel additive can be introduced by conventional methods. As a rule, it is administered as a concentrate containing the additive itself and its liquid carrier. Such concentrates usually contain from 5 to 50 wt.% Additives, mainly in the form of a solution in the oil product. Organic solvents, for example, petroleum fractions, aromatic hydrocarbons, paraffin hydrocarbons, can be used as liquid carriers. The liquid carrier must be selected with the condition of its compatibility with the additive and fuel.

The author experimentally identified the optimal ingredients and their ratio in the proposed compositions of the universal additives to fuel materials and fuel. Thus, the presence of ammonium salts of a limiting monobasic carboxylic C ₂ -C ₅ acid and / or carbonic acid (water and / or alcohol soluble) as a part of a universal additive to fuel materials provides the necessary two-layer ionic coating. The optimum amount of the aforementioned substance was 0.1-16 mass%. When the amount of ammonium salts is less than ODmacc.%, The effect of using a universal additive to fuel materials is practically not manifested. An increase in the aforementioned substance to more than 16 mass% is not economically justified, since it is not significantly

SUBSTITUTE SHEET (RULE 26) affects the increase in the intensity of fuel combustion. Mentioned substance in the proposed composition plays the role of an ionizing agent. Urea also play the same role in the proposed composition. They can replace, as part of a universal additive to fuel materials, ammonium salts with a limiting monobasic carboxylic C ₂ -Cs acid and / or carbonic acid (water and / or alcohol soluble), or they can be used independently, or together with the mentioned ammonium salts. The optimal, determined experimentally, the amount of urea is 0.1-44 mass%. When the amount of urea is less than 0.1 mass% and in the absence of ammonium salts of a limiting monobasic carboxylic C ₂ -C ₅ acid and / or carbonic acid (water and / or alcohol soluble), the effect of using a universal additive to fuel materials is practically not felt. An increase in urea to more than 44 mass% is not justified, since it leads to the destruction of acquired ionic structures. The spatial structure of the saturated hydrocarbon molecule, a traditional fuel for internal combustion engines, when aliphatic C ₁ -C ₄ -CnHpTa and acetic acid are added to it with the above ratio of components, contributes to the destruction of the side branching chains in the pre-flame period without creating peroxide - the root cause of detonation . This increases the burning rate of the fuel, since in this case oxygen more intensively replaces hydrogen, covering most of the hydrocarbons. At the same time, the amount of generated heat increases, that is, the efficiency of the engine increases, soot on the working surface of the piston-cylinder group decreases and the toxicity of the exhaust gases not only during prolonged operation of the diesel engine, but also during its heating.

In the first embodiment of the proposed fuel for an internal combustion engine, gasoline is used as the most common mixture of liquid hydrocarbons. Experiments have shown that the optimal amount of a universal additive for gasoline is its amount in the range of 0.0000050 ... 0.0008 mass%. So, with the amount of universal

SUBSTITUTE SHEET (RULE 26) additives less than 0.0000050 mass%, the effect of its use with gasoline is practically not felt. Using it in an amount greater than 0.0008 mass% is not economically feasible, since it does not contribute to increasing the intensity of fuel combustion. In the second embodiment of the proposed fuel for an internal combustion engine, fuel oil is used as a mixture of liquid hydrocarbons. The optimal amount of universal additive for fuel oil, as shown by experiments, is its amount in the range of 0.00001 ... 0.005 mass%. Thus, when the amount of universal additive is less than 0.00001 mass%, the effect of its use with fuel oil is practically not felt. Using it in an amount greater than 0.005 mass%, is not economically feasible, since it does not increase the intensity of fuel oil combustion.

In the first embodiment of the proposed fuel for a diesel engine, diesel fuel is used as a mixture of liquid hydrocarbons. The optimal amount of universal additive for diesel fuel, as shown by experiments, is its amount in the range of 0, 00001 ... 0.0025 mass%. So, with the amount of universal additive less than 0.00001 mass%, the effect of its use with diesel fuel is practically not felt. Using it in an amount greater than 0.0025 mass% is not economically feasible, since it does not increase the intensity of fuel combustion.

In the second embodiment of the proposed fuel for a diesel engine, rapeseed oil is used as a mixture of liquid hydrocarbons. The optimal amount of universal additives for rapeseed oil, as shown by experiments, is its amount in the range of 0.00001 ... 0.0025 mass%. So, with the amount of universal additive less than 0.00001 mass%, the effect of its use with rapeseed oil is practically not felt. Using it in an amount greater than 0.0025 mass% is not economically feasible, since it does not contribute to increasing the intensity of fuel combustion.

In the third embodiment of the proposed diesel engine fuel, methyl ether was used as a mixture of liquid hydrocarbons

SUBSTITUTE SHEET (RULE 26) rapeseed oil. The optimal amount of universal additive for rapeseed oil methyl ester, as shown by experiments, is its amount in the range of 0.00001 ... 0.0025 mass%. So, when the amount of universal additive is less than 0.00001 mass%, the effect of its use with rapeseed oil is practically not felt. Using it in an amount greater than 0.0025 mass%, is not economically feasible, since it does not increase the intensity of fuel combustion.

In the proposed heating fuel for furnaces of heat and power generating stations and metal melting furnaces, fuel oil was used as a mixture of liquid hydrocarbons. The optimal amount of universal additive for fuel oil, as shown by experiments, is its amount in the range of 0.00001 ... 0.005 mass%. So, when the amount of universal additive is less than 0.00001 mass%, the effect of its use with fuel oil is practically not felt. Using it in an amount greater than 0.005 mass%, is not economically feasible, since it does not contribute to increasing the intensity of fuel combustion.

The proposed universal additive is also used as an additive to lubricants, in particular, to engine lubricants and oils of cars and trucks, gear oils, gear and cylinder oils. The optimal amount of universal additive in the lubricant is its amount in the range of 0.00001 ... 0.15 mass%, since it is with this amount of additive that a double ion layer is formed, which helps to reduce friction and the wear rate of friction pairs. So, when the amount of universal additive is less than 0.00001 mass%, the effect of its use with lubricant is practically not felt. Using it in an amount greater than 0.15 mass%, leads to the destruction of the two-layer ionic formation, which leads to the disappearance of the desired effect of use.

Examples. A universal additive for lubricants and fuel materials was prepared by simply mixing the listed ingredients in

SUBSTITUTE SHEET (RULE 26) the above volume ratio and was stirred until complete dissolution of the ammonium salts and / or urea.

For experimental verification of the effectiveness of the proposed universal additives to fuel materials, 13 formulations were prepared, 9 of which showed optimal results, shown in table 1.

The tests were carried out according to standard methods on automobiles ZIL-130, 138, GAZ-24, BAZ-21011, 2103, TOYOTA CAMRY 2.4, TOYOTA CRESIDA 1.6; LAZ-699P and Ikapyc-280 buses: The CO and CH contents were determined according to GOST 21393-75, the surface of the combustion chamber according to GOST 20991-75 (for gasoline engines) and GOST 20303-74 for diesel engines. The test results are shown in table 2. As an example, the table shows the results of testing the universal additive to fuel materials on the engine of a GAZ 24 car (AI-93 gasoline), smoke was determined for diesel fuel on engines: Ikapyc-280 bus, KamAZ-5220 car , SCANIA 3664, VOLVO FH-12, RENAULT 5489, TOYOTA HIACE 95 hp, TOYOTA DYNA 2t. 95 h.p.

The content of solids was determined according to GOST 6370-83. Mechanical impurities in the study of all the proposed compositions of the fuel materials available devices are not identified.

As can be seen from the table, the use of a universal additive to fuel materials of the proposed composition (examples 1-5) can reduce the amount of harmful emissions into the atmosphere (CO and CH) by 5-20 times compared to gasoline without the proposed universal additive to fuel materials (example 15 ) and 5-10 times in comparison with the additive prototype (example 14). At the same time, engine power increases by 18-40% (in the prototype - by 4-5%), and fuel consumption decreases by 15-27% (in the prototype - by 4-5%). The smoke of diesels in which fuel with an additive was used is reduced by 6-19 times (in the prototype - by 1.5-2 times). To a large extent, the formation of soot on the surface of the piston-cylinder group of the engine is prevented. Total Status Score

SUBSTITUTE SHEET (RULE 26) the surface of the combustion chamber decreases from 6.5 to 1.3-1.4 points for gasoline (in the prototype - b points). The best results achieved for different types of engines are given in tables 3 and 4.

Thus, the use of the proposed additive can have a large economic effect, since it allows to reduce the amount of harmful emissions into the atmosphere, reduce fuel and oil costs, increase engine power, and extend the engine overhaul.

The proposed heating fuel for furnaces of heat and power generating stations and metal-smelting furnaces was tested on a short drum furnace, a fuming furnace, PTK-4 boilers, a thermal power plant, and a Marten furnace. The test results are shown in table 5.

Comparative tests of traditional and proposed fuel compositions showed the advantages of the latter, which are to reduce the amount of harmful emissions and increase the efficiency of the engine (table 1), as well as reduce engine wear by 1.5 ... 2.0 times, without harmful effects spark plugs and extending the life of catalytic filters by 20% ... 4O%.

An experimental verification of the effectiveness of the proposed universal additive was tested on 14 samples of lubricants of the brands: ANGROL (TU 0253-270-05742746-94 / 3 /), VELS TRANS (TU 0253-071-00140636-95 / 7 /), " NORSI "(TU 38.601-07-19-93 IAI)," SAMOIL 4405 "(TU 38.301-13-012-97 / 61), ESSO ATF D, ESSO TORQUE FLUID 30, ESSO GEAR ОIL LS 85W-90, ESSO TORQUE FLUID 50, ESSO TORQUE FLUID 62, Mobile SHC 75W-90 LS, Mobile HD 80W-90, Mobile HD SOW-90, Mobile GX 80W-A, Mobile ATF SHC. The verification results are shown in table 6.

SUBSTITUTE SHEET (RULE 26) Table 1

The quantitative composition of the samples of the proposed universal additives to fuel materials

with

ABOUT

H

her

Table 1

M

ABOUT

H

S

Table 2 Research results (+)

W

>

Joint venture

ABOUT

H

(+) - the numbers of the examples in Table 2 correspond to the numbers of the examples in Table 1. Column JVs 14 shows the results of studies of fuels with a prototype additive. In column JMa 15 - gasoline without additives.

(++) - the first indicator is determined at the minimum idle speed; 2nd - at maximum idle. Note: the additive was introduced into gasoline in an amount of 0,00065 mass%; to diesel fuel - 0.00165 mass%.

Table 3

Comparative indicators of fuel consumption for different engines of cars and buses

SUBSTITUTE SHEET (RULE 26) Table 4

Comparative indicators of engine power and harmful emissions during its operation

w n

H

-l

ABOUT

H

W

m

CD

(+) - the first indicator is obtained at the minimum idle speed; 2nd - at maximum. 5 Note: the proposed additive was introduced into gasoline in an amount of 0,00065 mass%; diesel fuel - 0.00165 mass%.

Table 5

Comparative indicators of the specific costs of fuel oil for different types of boiler furnaces

W

m

ABOUT

H and

Note: the additive was introduced into fuel oil in an amount of 0.0022 - 0.0026 mass%.

Table b

Oil and gaseous oil test results: using additives

ABOUT

Claims

CLAIM

1. A universal additive for lubricants and fuel materials containing aliphatic Ci-C ₄ monohydric saturated alcohol and water, characterized in that it additionally contains water and / or alcohol-soluble ammonium salt of saturated mono-basic carbonic C ₂ - C ₅ acid and / or carbon acid, and / or urea with such a ratio of ingredients, wt.%: aliphatic Ci-C ₄ monohydric saturated alcohol - 0.1-82 water and / or alcohol-soluble ammonium salt of saturated monobasic carboxylic C ₂ -C ₅ acid and / or carbon acids - 0.1-16 and / or urea - 0.1-44 ode - to 100.

2. Fuel for an internal combustion engine containing a mixture of liquid hydrocarbons and an additive dissolved in a mixture of liquid hydrocarbons, characterized in that gasoline is used as a mixture of liquid hydrocarbons, and as an additive, a universal additive to fuel materials according to claim 1, wherein ratio of ingredients, wt.%: universal additive - 0.0000050 ... 0.0008 gasoline - up to 100.

3. Fuel for an internal combustion engine containing a mixture of liquid hydrocarbons and an additive dissolved in a mixture of liquid hydrocarbons, characterized in that fuel oil is used as a mixture of liquid hydrocarbons, and as an additive, a universal additive to fuel materials according to claim 1, wherein ratio of ingredients, wt.%: universal additive - 0.00001 ... 0.005 fuel oil - up to 100.

4. Fuel for a diesel engine containing a mixture of liquid hydrocarbons and an additive dissolved in a mixture of liquid hydrocarbons, characterized in that as a mixture of liquid hydrocarbons

SUBSTITUTE SHEET (RULE 26) diesel fuel was used, and as an additive - a universal additive to fuel materials according to claim 1, with this ratio of ingredients, wt%: universal additive - 0.00001 ... 0.0025 diesel fuel - up to 100.

5. Fuel for a diesel engine containing a mixture of liquid hydrocarbons and an additive dissolved in a mixture of liquid hydrocarbons, characterized in that rapeseed oil and / or diesel fuel and / or rapeseed oil methyl ester are used as a mixture of liquid hydrocarbons, and as an additive, rapeseed oil - universal additive to fuel materials according to claim 1, with this ratio of ingredients, wt%: universal additive - 0.00001 ... 0.0025 diesel fuel and / or rapeseed oil methyl ether - 10 ... 90 rapeseed oil - up to 100.

6. Fuel for a diesel engine containing a mixture of liquid hydrocarbons and an additive dissolved in a mixture of liquid hydrocarbons, characterized in that methyl ether of rapeseed oil is used as a mixture of liquid hydrocarbons, and as an additive, a universal additive to fuel materials according to claim 1, with this ratio of ingredients, mass%: universal additive - 0.00001 ... 0.0025 rapeseed oil methyl ester - up to 100.

7. Fuel oil for furnaces of heat and power generating stations and metal-smelting furnaces containing a mixture of liquid hydrocarbons and an additive dissolved in a mixture of liquid hydrocarbons, characterized in that fuel oil is used as a mixture of liquid hydrocarbons, and as a additive is a universal additive to fuel materials according to claim 1, with this ratio of ingredients, wt.%: universal additive - 0.00001 ... 0.005 fuel oil - up to 100.

SUBSTITUTE SHEET (RULE 26)