+

WO2006117177A1 - Procede de revetement de composants soumis a l'usure et composant dote d'un revetement - Google Patents

Procede de revetement de composants soumis a l'usure et composant dote d'un revetement Download PDF

Info

Publication number
WO2006117177A1
WO2006117177A1 PCT/EP2006/004075 EP2006004075W WO2006117177A1 WO 2006117177 A1 WO2006117177 A1 WO 2006117177A1 EP 2006004075 W EP2006004075 W EP 2006004075W WO 2006117177 A1 WO2006117177 A1 WO 2006117177A1
Authority
WO
WIPO (PCT)
Prior art keywords
components
coating
flame spraying
hard metal
nickel
Prior art date
Application number
PCT/EP2006/004075
Other languages
German (de)
English (en)
Inventor
Alfred Flamang
Original Assignee
Alfred Flamang
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Alfred Flamang filed Critical Alfred Flamang
Publication of WO2006117177A1 publication Critical patent/WO2006117177A1/fr

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
    • C23C4/04—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the coating material
    • C23C4/06—Metallic material

Definitions

  • the invention relates to a method for coating components subject to wear, in particular components in large diesel engines, the components being coated with a hard metal layer by applying a powdered hard metal consisting of at least one hard material and a binding agent to the components by means of high-speed flame spraying.
  • the invention further relates to a coated component which is produced by the method according to the invention.
  • components subject to wear means components which are subject to wear at very high temperatures, in particular above 500 ° C. and for example up to 1000 ° C.
  • the invention is particularly suitable for coating components in large diesel engines of seagoing ships, in particular for coating piston heads in these engines, but also for coating the valve plates of the exhaust valves.
  • the invention teaches a method for coating components subject to wear, in particular components in engines or large diesel engines of the type mentioned above, which is characterized in that chromium carbide (Cr 3 C 2 ) is used as the hard material.
  • the pulverulent hard metal is sintered from at least one hard material and from at least one binder.
  • the components, in particular the components in engines or large diesel engines, are therefore coated with a hard metal layer by applying a powdered hard metal to the components by means of high-speed flame spraying.
  • the hard metal consists of a hard material in the form of chromium carbide and a binder or is sintered from a hard material in the form of chromium carbide and a binder.
  • the coating according to the invention is used for components which are exposed to high temperature of in particular over 500 0 C and are hitzekorrosionsbeetzschlagt.
  • HVOF High Velocity Oxygen Fuel
  • It is a process in which the spray material is heated in a fuel gas / oxygen flame or in a fuel liquid / oxygen flame, as is the case with flame spraying, whereby the speed of the particles is several times higher than with conventional flame spraying. This is achieved by the fact that the combustion takes place under high pressure, so that the hot gas jet flows out at around 2000 m / sec. It will powdery spray material is injected into the hot gas jet. The clearly visible supersonic nodes in the gas jet are a characteristic of the high flow velocity.
  • the hard metal consists of 40 to 95% by weight, preferably 50 to 94% by weight, of hard materials in the form of chromium carbide and the remainder in each case of binding agent.
  • the hard metal expediently consists of 60 to 94% by weight, preferably 70 to 94% by weight, preferably 80 to 94% by weight and particularly preferably 85 to 94% by weight of hard materials in the form of chromium carbide and the remainder each from binding agent.
  • the binder contains nickel, namely an essential component of the binder consists of nickel, namely preferably at least 40% by weight, preferably at least 50% by weight, of the binder.
  • the hard metal is a binder in the form of nickel or pure nickel and / or nickel-chromium and / or nickel-copper.
  • the hard metal expediently consists of 40 to 95% by weight, preferably 50 to 94% by weight, preferably 60 to 94% by weight, very preferably 70 to 94% by weight, particularly preferably 80 to 94% by weight % By weight and very particularly preferably 85 to 94% by weight of hard material in the form of chromium carbide and the remainder in each case from binding agent in the form of nickel or pure nickel and / or nickel-chromium and / or nickel-copper.
  • the use of nickel or pure nickel as a binder is particularly preferred.
  • One embodiment that has proven itself is characterized in that it consists of 90% by weight of chromium carbide as the hard material and 10% by weight of nickel as the binder.
  • high-speed flame spraying is used for coating the Components carried out as liquid fuel high-speed flame spraying.
  • the spray material is heated in a liquid fuel / oxygen flame.
  • the high-speed flame spraying is carried out as kerosene high-speed flame spraying.
  • the spray material is heated in a kerosene / oxygen flame.
  • a coating according to the invention applied to a component has a layer thickness of advantageously 700 to 3000 ⁇ m, preferably from 750 to 2800 ⁇ m, preferably from 800 ⁇ m to 2600 ⁇ m, very preferably from 900 to 2200 ⁇ m and particularly preferably from 1000 to 2000 ⁇ m.
  • a coating according to the invention applied to a component has a layer thickness of advantageously 700 to 3000 ⁇ m, preferably from 750 to 2800 ⁇ m, preferably from 800 ⁇ m to 2600 ⁇ m, very preferably from 900 to 2200 ⁇ m and particularly preferably from 1000 to 2000 ⁇ m.
  • the coating is expediently applied with the proviso that it has a porosity of 0.4 to 0.8%.
  • the invention also relates to a coated component which was produced with the aid of the method according to the invention.
  • These components are preferably, but not limited to, pistons of engines or large diesel engines, in particular their piston heads, or also valve disks of exhaust valves.
  • a large number of components, preferably engine components can be coated with the coating according to the invention.
  • the invention is further based on the recognition that with the inventive method unstressed Chromkarbid Anlagenensysteme high quality can be prepared which are suitable for use at very high temperatures up to 1000 0 C.
  • unstressed Chromkarbid Anlagenensysteme high quality can be prepared which are suitable for use at very high temperatures up to 1000 0 C.
  • a considerable increase in the working temperature of engines or large diesel engines is therefore possible, as well as a considerable increase in the efficiency of these engines.
  • a considerable reduction in pollutant emissions in particular a considerable reduction in nitrogen oxide emissions, is achieved.
  • the coating according to the invention is distinguished by excellent corrosion resistance even at very high temperatures.
  • Chromium carbide layer systems are made possible that have an adhesive tensile strength of 60 to 70 MPa (measured according to DIN EN 582).
  • Fig. 1 shows a piston from an engine in side view
  • Fig. 2 is a side view of an engine part partially in section.
  • a piston head 1 of a piston 2 for engines or large diesel engines is preferably provided with a coating 3 according to the invention. It is also beneficial to the To provide the valve plate 4 of an outlet valve 5 assigned to the piston 2 with the coating 3 according to the invention (FIG. 2). Combustion chamber 6 is arranged between piston crown 1 and outlet valve 5. Due to the coating 3 according to the invention, it is possible in the exemplary embodiment to raise the permissible working temperature in the combustion chamber 6 to 500 to 550 ° C. Without a coating 3 according to the invention, only a working temperature between 350 and 400 ° C. would be possible.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Plasma & Fusion (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Coating By Spraying Or Casting (AREA)

Abstract

L'invention concerne un procédé de revêtement de composants soumis à l'usure. Les composants sont revêtus d'une couche de métal dur par application par métallisation au pistolet à haute vitesse d'un métal dur pulvérulent composé d'au moins un matériau dur et d'un liant sur les composants. On utilise comme matériau dur du carbure de chrome.
PCT/EP2006/004075 2005-05-03 2006-05-02 Procede de revetement de composants soumis a l'usure et composant dote d'un revetement WO2006117177A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE200510020999 DE102005020999A1 (de) 2005-05-03 2005-05-03 Verfahren zur Beschichtung von verschleißbeaufschlagten Bauteilen und beschichtetes Bauteil
DE102005020999.8 2005-05-03

Publications (1)

Publication Number Publication Date
WO2006117177A1 true WO2006117177A1 (fr) 2006-11-09

Family

ID=36764204

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2006/004075 WO2006117177A1 (fr) 2005-05-03 2006-05-02 Procede de revetement de composants soumis a l'usure et composant dote d'un revetement

Country Status (2)

Country Link
DE (1) DE102005020999A1 (fr)
WO (1) WO2006117177A1 (fr)

Citations (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2438998A1 (de) * 1973-08-15 1975-03-06 Union Carbide Corp Pulver, verfahren zu seiner herstellung und daraus hergestellte ueberzuege und gegenstaende
DE3515107C1 (de) * 1985-04-26 1986-07-31 Goetze Ag, 5093 Burscheid Spritzpulver fuer die Herstellung verschleissfester und ausbruchsicherer Beschichtungen
JPS63190154A (ja) * 1987-01-30 1988-08-05 Riken Corp 耐摩耗表面層及びその形成方法
JPH02159359A (ja) * 1988-12-12 1990-06-19 Babcock Hitachi Kk 高エネルギー溶射用クロム炭化物−メタル複合粉末
US5098748A (en) * 1988-01-29 1992-03-24 Mazda Motor Corporation Method of producing a flame-spray-coated article and flame spraying powder
JPH06221438A (ja) * 1993-01-25 1994-08-09 Riken Corp 溶射ピストンリング
DE19700835A1 (de) * 1996-01-19 1997-07-24 Nippon Piston Ring Co Ltd Kompositpulver und Verfahren zum Bilden einer selbstschmierenden Kompositschicht und dadurch gebildete selbstschmierende Bauteile
JPH1171664A (ja) * 1997-08-29 1999-03-16 Nippon Piston Ring Co Ltd 内燃機関用摺動部材
EP0960954A2 (fr) * 1998-05-28 1999-12-01 Sulzer Metco (US) Inc. Poudre de carbure de chrome et de nickel-chrome
SE516491C2 (sv) * 1996-01-24 2002-01-22 Nippon Piston Ring Co Ltd Kolvring med flamsprutad kompositbeläggning
DE10046956A1 (de) * 2000-09-21 2002-04-25 Federal Mogul Burscheid Gmbh Thermisch aufgetragene Beschichtung für Kolbenringe aus mechanisch legierten Pulvern
DE10061750A1 (de) * 2000-12-12 2002-06-20 Federal Mogul Burscheid Gmbh Wolframhaltige Verschleißschutzschicht für Kolbenringe
DE10061749A1 (de) * 2000-12-12 2002-06-20 Federal Mogul Burscheid Gmbh Verschleißschutzschicht für Kolbenringe mit sehr kleinen Wolfram-Karbiden
DE10200508A1 (de) * 2001-01-10 2002-07-11 Dana Corp Verschleißfester Überzug zum Schutz einer Oberfläche
DE10061751C1 (de) * 2000-12-12 2002-07-25 Federal Mogul Burscheid Gmbh Verschleißschutzschicht für Kolbenringe
JP2003336742A (ja) * 2002-05-21 2003-11-28 Riken Corp ピストンリング及びその製造方法
AU2003273015A1 (en) * 2002-10-15 2004-05-04 Kabushiki Kaisha Riken Piston ring and thermal sprayed coating for use therein, and method for manufacture thereof
JP2004307975A (ja) * 2003-04-10 2004-11-04 Riken Corp 摺動部材
EP1600523A1 (fr) * 2004-05-24 2005-11-30 Dana Corporation Revêtement résistant à l'usure pour segments de pistons

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2129874C (fr) * 1993-09-03 1999-07-20 Richard M. Douglas Poudre pour vaporisation thermique
US6186508B1 (en) * 1996-11-27 2001-02-13 United Technologies Corporation Wear resistant coating for brush seal applications

Patent Citations (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2438998A1 (de) * 1973-08-15 1975-03-06 Union Carbide Corp Pulver, verfahren zu seiner herstellung und daraus hergestellte ueberzuege und gegenstaende
DE3515107C1 (de) * 1985-04-26 1986-07-31 Goetze Ag, 5093 Burscheid Spritzpulver fuer die Herstellung verschleissfester und ausbruchsicherer Beschichtungen
JPS63190154A (ja) * 1987-01-30 1988-08-05 Riken Corp 耐摩耗表面層及びその形成方法
US5098748A (en) * 1988-01-29 1992-03-24 Mazda Motor Corporation Method of producing a flame-spray-coated article and flame spraying powder
JPH02159359A (ja) * 1988-12-12 1990-06-19 Babcock Hitachi Kk 高エネルギー溶射用クロム炭化物−メタル複合粉末
JPH06221438A (ja) * 1993-01-25 1994-08-09 Riken Corp 溶射ピストンリング
DE19700835A1 (de) * 1996-01-19 1997-07-24 Nippon Piston Ring Co Ltd Kompositpulver und Verfahren zum Bilden einer selbstschmierenden Kompositschicht und dadurch gebildete selbstschmierende Bauteile
SE516491C2 (sv) * 1996-01-24 2002-01-22 Nippon Piston Ring Co Ltd Kolvring med flamsprutad kompositbeläggning
JPH1171664A (ja) * 1997-08-29 1999-03-16 Nippon Piston Ring Co Ltd 内燃機関用摺動部材
EP0960954A2 (fr) * 1998-05-28 1999-12-01 Sulzer Metco (US) Inc. Poudre de carbure de chrome et de nickel-chrome
DE10046956A1 (de) * 2000-09-21 2002-04-25 Federal Mogul Burscheid Gmbh Thermisch aufgetragene Beschichtung für Kolbenringe aus mechanisch legierten Pulvern
DE10061750A1 (de) * 2000-12-12 2002-06-20 Federal Mogul Burscheid Gmbh Wolframhaltige Verschleißschutzschicht für Kolbenringe
DE10061749A1 (de) * 2000-12-12 2002-06-20 Federal Mogul Burscheid Gmbh Verschleißschutzschicht für Kolbenringe mit sehr kleinen Wolfram-Karbiden
DE10061751C1 (de) * 2000-12-12 2002-07-25 Federal Mogul Burscheid Gmbh Verschleißschutzschicht für Kolbenringe
DE10200508A1 (de) * 2001-01-10 2002-07-11 Dana Corp Verschleißfester Überzug zum Schutz einer Oberfläche
JP2003336742A (ja) * 2002-05-21 2003-11-28 Riken Corp ピストンリング及びその製造方法
AU2003273015A1 (en) * 2002-10-15 2004-05-04 Kabushiki Kaisha Riken Piston ring and thermal sprayed coating for use therein, and method for manufacture thereof
EP1564309A1 (fr) * 2002-10-15 2005-08-17 Kabushiki Kaisha Riken Segment de piston et revetement applique par un projection a l'arc a utiliser pour le segment, ainsi que procede de fabrication de ce segment
JP2004307975A (ja) * 2003-04-10 2004-11-04 Riken Corp 摺動部材
EP1600523A1 (fr) * 2004-05-24 2005-11-30 Dana Corporation Revêtement résistant à l'usure pour segments de pistons

Non-Patent Citations (5)

* Cited by examiner, † Cited by third party
Title
PATENT ABSTRACTS OF JAPAN vol. 012, no. 472 (C - 551) 9 December 1988 (1988-12-09) *
PATENT ABSTRACTS OF JAPAN vol. 014, no. 417 (C - 0756) 10 September 1990 (1990-09-10) *
PATENT ABSTRACTS OF JAPAN vol. 018, no. 594 (M - 1703) 14 November 1994 (1994-11-14) *
PATENT ABSTRACTS OF JAPAN vol. 1999, no. 08 30 June 1999 (1999-06-30) *
PATENT ABSTRACTS OF JAPAN vol. 2003, no. 12 5 December 2003 (2003-12-05) *

Also Published As

Publication number Publication date
DE102005020999A1 (de) 2006-11-09

Similar Documents

Publication Publication Date Title
DE60005416T2 (de) Thermische Sprühbeschichtung für Ventilsitze sowie Ventilschieber
DE69703144T2 (de) Eine verschleissfeste Beschichtung für Bürstendichtungen
EP2746613B1 (fr) Disque de frien pour véhicule
DE10200508A1 (de) Verschleißfester Überzug zum Schutz einer Oberfläche
DE112009002015B4 (de) Turbolader und Schaufellagerring hierfür
CH627129A5 (fr)
DE102008056578B4 (de) Verfahren zur Herstellung einer Erosionsschutzschicht für aerodynamische Komponenten und Strukturen
DE112009002014T5 (de) Turbolader und Verstellschaufel hierfür
DE2842848C2 (de) Werkstoff zum Überziehen von Gegenständen
EP0931172B1 (fr) Segments de piston revetus resistants a l'usure pour moteurs a combustion interne et procede de production correspondant
DE112015004758T5 (de) Kolbenring und verbrennungskraftmaschine
DE102007029992A1 (de) Kolbenring
DE2128621A1 (de) Gleitringdichtung für einen umlaufenden Regenerativwärmetauscher
WO2006117177A1 (fr) Procede de revetement de composants soumis a l'usure et composant dote d'un revetement
DE3590031T (de) Werkstoff zum Flammspritzen und sein Herstellungsverfahren
DE2856232A1 (de) Thermisch und korrosiv hoch beanspruchtes tellerventil
EP3433396B1 (fr) Soupape revetée pour moteurs à combustion
DE19603515C1 (de) Spritzwerkstoff auf Eisenbasis zum Herstellen einer korrosionsbeständigen Beschichtung, Herstellungsverfahren für die Beschichtung sowie Verwendung der Schicht
EP2537959A1 (fr) Revêtement multicouches anti-usure et procédé de fabrication
DE2639325A1 (de) Nickel-basis-legierung
DE3517914C2 (fr)
WO1982001898A1 (fr) Procede pour revetir un metal d'une couche de protection resistant a la corrosion de gaz chaud
DE102007026746A1 (de) Flammspritzpulver und Verfahren zur Herstellung einer hochtemperaturbeständigen Beschichtung
DE102006040360A1 (de) Wärmedämmstoff mit hoher zyklischer Temperaturbelastbarkeit
DE1917099A1 (de) Ventil fuer einen Verbrennungsmotor

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application
NENP Non-entry into the national phase

Ref country code: RU

WWW Wipo information: withdrawn in national office

Country of ref document: RU

122 Ep: pct application non-entry in european phase

Ref document number: 06742758

Country of ref document: EP

Kind code of ref document: A1

点击 这是indexloc提供的php浏览器服务，不要输入任何密码和下载