WO2005054345A1 - Ruban pour processus de production de carte de cablage en forme de film - Google Patents
Ruban pour processus de production de carte de cablage en forme de film Download PDFInfo
- Publication number
- WO2005054345A1 WO2005054345A1 PCT/JP2004/017046 JP2004017046W WO2005054345A1 WO 2005054345 A1 WO2005054345 A1 WO 2005054345A1 JP 2004017046 W JP2004017046 W JP 2004017046W WO 2005054345 A1 WO2005054345 A1 WO 2005054345A1
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- WO
- WIPO (PCT)
- Prior art keywords
- resin
- film
- tape
- production process
- sheet
- Prior art date
Links
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 30
- 229920005989 resin Polymers 0.000 claims abstract description 30
- 239000011347 resin Substances 0.000 claims abstract description 30
- 239000000945 filler Substances 0.000 claims abstract description 29
- 239000009719 polyimide resin Substances 0.000 claims abstract description 15
- 229920005992 thermoplastic resin Polymers 0.000 claims abstract description 13
- 239000004721 Polyphenylene oxide Substances 0.000 claims abstract description 8
- 229920000570 polyether Polymers 0.000 claims abstract description 8
- 150000008365 aromatic ketones Chemical class 0.000 claims abstract description 7
- 229920002492 poly(sulfone) Polymers 0.000 claims abstract description 7
- 229920006259 thermoplastic polyimide Polymers 0.000 claims abstract description 7
- 238000005452 bending Methods 0.000 claims description 9
- 238000000034 method Methods 0.000 description 25
- 239000000758 substrate Substances 0.000 description 15
- 239000002245 particle Substances 0.000 description 12
- 229920001187 thermosetting polymer Polymers 0.000 description 11
- 229920001721 polyimide Polymers 0.000 description 10
- 230000000052 comparative effect Effects 0.000 description 9
- 239000000047 product Substances 0.000 description 9
- 239000010410 layer Substances 0.000 description 7
- 238000012545 processing Methods 0.000 description 7
- 239000000463 material Substances 0.000 description 6
- 239000011342 resin composition Substances 0.000 description 6
- 238000001125 extrusion Methods 0.000 description 5
- 239000000835 fiber Substances 0.000 description 5
- 238000010438 heat treatment Methods 0.000 description 5
- 238000003475 lamination Methods 0.000 description 5
- 239000000155 melt Substances 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 125000006850 spacer group Chemical group 0.000 description 4
- 239000000454 talc Substances 0.000 description 4
- 229910052623 talc Inorganic materials 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 3
- 239000003365 glass fiber Substances 0.000 description 3
- 229910044991 metal oxide Inorganic materials 0.000 description 3
- 150000004706 metal oxides Chemical class 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 238000000465 moulding Methods 0.000 description 3
- 229910052710 silicon Inorganic materials 0.000 description 3
- 239000010703 silicon Substances 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
- 239000004642 Polyimide Substances 0.000 description 2
- 229920004738 ULTEM® Polymers 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 229920006351 engineering plastic Polymers 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- -1 polyethylene terephthalate Polymers 0.000 description 2
- 229920000139 polyethylene terephthalate Polymers 0.000 description 2
- 239000005020 polyethylene terephthalate Substances 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 239000012779 reinforcing material Substances 0.000 description 2
- 241000531908 Aramides Species 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- 229920000049 Carbon (fiber) Polymers 0.000 description 1
- 241001391944 Commicarpus scandens Species 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- 229920000106 Liquid crystal polymer Polymers 0.000 description 1
- 239000004977 Liquid-crystal polymers (LCPs) Substances 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 239000004696 Poly ether ether ketone Substances 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004962 Polyamide-imide Substances 0.000 description 1
- 239000004734 Polyphenylene sulfide Substances 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 229920004710 VICTREX® PEEK 450G Polymers 0.000 description 1
- 229920004695 VICTREX™ PEEK Polymers 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 229920003235 aromatic polyamide Polymers 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- JUPQTSLXMOCDHR-UHFFFAOYSA-N benzene-1,4-diol;bis(4-fluorophenyl)methanone Chemical compound OC1=CC=C(O)C=C1.C1=CC(F)=CC=C1C(=O)C1=CC=C(F)C=C1 JUPQTSLXMOCDHR-UHFFFAOYSA-N 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000004917 carbon fiber Substances 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000000748 compression moulding Methods 0.000 description 1
- 239000011889 copper foil Substances 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- NJLLQSBAHIKGKF-UHFFFAOYSA-N dipotassium dioxido(oxo)titanium Chemical compound [K+].[K+].[O-][Ti]([O-])=O NJLLQSBAHIKGKF-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000012760 heat stabilizer Substances 0.000 description 1
- 238000007731 hot pressing Methods 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 239000012784 inorganic fiber Substances 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000006082 mold release agent Substances 0.000 description 1
- CWQXQMHSOZUFJS-UHFFFAOYSA-N molybdenum disulfide Chemical compound S=[Mo]=S CWQXQMHSOZUFJS-UHFFFAOYSA-N 0.000 description 1
- 229910052982 molybdenum disulfide Inorganic materials 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920002312 polyamide-imide Polymers 0.000 description 1
- 229920001230 polyarylate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 229920002530 polyetherether ketone Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920000069 polyphenylene sulfide Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 239000012255 powdered metal Substances 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 239000011265 semifinished product Substances 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000000807 solvent casting Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 230000000930 thermomechanical effect Effects 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 239000010981 turquoise Substances 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K1/00—Printed circuits
- H05K1/02—Details
- H05K1/03—Use of materials for the substrate
- H05K1/0313—Organic insulating material
- H05K1/0353—Organic insulating material consisting of two or more materials, e.g. two or more polymers, polymer + filler, + reinforcement
- H05K1/0373—Organic insulating material consisting of two or more materials, e.g. two or more polymers, polymer + filler, + reinforcement containing additives, e.g. fillers
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K1/00—Printed circuits
- H05K1/02—Details
- H05K1/03—Use of materials for the substrate
- H05K1/0393—Flexible materials
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K2201/00—Indexing scheme relating to printed circuits covered by H05K1/00
- H05K2201/01—Dielectrics
- H05K2201/0104—Properties and characteristics in general
- H05K2201/0129—Thermoplastic polymer, e.g. auto-adhesive layer; Shaping of thermoplastic polymer
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K2201/00—Indexing scheme relating to printed circuits covered by H05K1/00
- H05K2201/02—Fillers; Particles; Fibers; Reinforcement materials
- H05K2201/0203—Fillers and particles
- H05K2201/0206—Materials
- H05K2201/0209—Inorganic, non-metallic particles
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K2201/00—Indexing scheme relating to printed circuits covered by H05K1/00
- H05K2201/02—Fillers; Particles; Fibers; Reinforcement materials
- H05K2201/0203—Fillers and particles
- H05K2201/0242—Shape of an individual particle
- H05K2201/0245—Flakes, flat particles or lamellar particles
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05K—PRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
- H05K2201/00—Indexing scheme relating to printed circuits covered by H05K1/00
- H05K2201/06—Thermal details
- H05K2201/068—Thermal details wherein the coefficient of thermal expansion is important
Definitions
- the present invention relates to a tape for a production process of a film-like wiring board that requires excellent heat resistance and mechanical strength.
- polyether aromatic resins have been widely and widely known as engineering plastics having excellent heat resistance, mechanical properties, and the like. Further, in order to expand the use of these resins, attempts have been made to improve the properties of super engineering plastics such as polyether aromatic ketone resin, thermoplastic polyimide resin and the like by adding fillers. For example, it has been proposed to add various inorganic fiber fillers to improve the mechanical strength and heat resistance (JP-A-63-22854).
- Examples of film-like wiring boards (hereinafter simply referred to as boards) required for electronic components include FPC (flexible wiring board), TAB (tape-automated bonding), and COF (chip-on). There is something called 'film).
- Production process tapes such as lead tapes and space tapes are used in the production and shipping processes of these film substrates.
- various metallic resins are employed in consideration of the heat resistance temperature, mechanical properties, cost, and the like in the process.
- TAB which is one of the film-like substrates
- TAB products themselves can be used as lead tapes in predetermined processes during processing and production on reels "1", or TAB semi-finished products. May be used. In this case, expensive TAB products will be defective and productivity will be reduced.
- thermosetting polyimide resin sheets are sometimes used in the TAB production process.
- a thermosetting polyimide sheet it is necessary to use a relatively thick sheet to satisfy mechanical strength, which is not preferable in terms of production cost. Since thermosetting polyimide resin sheets are produced by a solvent casting method, the productivity of relatively thick sheets is low and the production cost is high.
- As another process tape used in the production process of a film-like substrate there is a space tape for preventing products from sticking to each other. Examples of the space tape requiring heat resistance include metal such as SUS and a relatively thick thermosetting polyimide resin sheet.
- metal space tape requiring heat resistance include metal such as SUS and a relatively thick thermosetting polyimide resin sheet.
- all of these sheets are expensive and the production cost increases.
- metal space tapes are heavy and reduce productivity. If exceptional heat resistance is not required, a polyethylene terephthalate sheet or the like may be used.
- Patent Document 1 JP-A-63-22854
- the present invention solves the above problems, and provides a low-cost resin composition for a film or sheet that is excellent in heat resistance and mechanical properties, has high sheet productivity and high productivity, and is low in cost. is there. Further, the present invention provides a film-like tape for a substrate production process, which is produced using the film or sheet.
- the “sheet” includes a film.
- the present invention is a sheet comprising at least one thermoplastic resin selected from polysulfone resin, thermoplastic polyimide resin and polyether aromatic ketone resin, and a plate-shaped filler.
- Its folding endurance [IS P 8155: tension 250g, bending speed; 175 times per minute, bending surface 0.38R) is 10 times or more, and the linear expansion coefficient is 50ppmZ ° C or less.
- An object of the present invention is to provide a tape for a wiring board production process.
- the average particle diameter of the plate-like filler is preferably 0.1 to 20 ⁇ m, and the aspect ratio is preferably 5 or more.
- the amount of the plate-shaped filler is preferably 5 to 60 parts by weight based on 100 parts by weight of the thermoplastic resin.
- the plate-like filler is preferably at least one filler selected from metal oxides such as silicon, aluminum, and magnesium.
- the process tape of the present invention can be produced by a melt extrusion method with high production efficiency.
- it is suitable as an industrial film-like substrate production tape. It is.
- the polysulfone resin used in the present invention is not particularly limited, but a polysulfone resin having a repeating unit represented by (!) In formula (1)-(8) is particularly preferred.
- thermoplastic polyimide resin used in the present invention is not particularly limited, but those having a repeating unit represented by the formula (9)-(11) are particularly preferable.
- An example of such a structure is ULTEM (trade name) manufactured by US GE.
- SILTEM trade name manufactured by GE, which has flexibility by silicone modification to improve bending strength.
- thermoplastic polyether aromatic ketone resin used in the present invention is not particularly limited, but preferably has a repeating unit represented by the formulas (12) to (13).
- VICTREX's PEEK (trade name registered) has such a structure.
- the addition amount of the plate-like filler in the present invention is 5 to 60 parts by weight, preferably 10 to 40 parts by weight, based on 100 parts by weight of the thermoplastic resin. If the amount is less than the above range, the heat resistance and dimensional stability of the obtained resin composition are not sufficient. If the amount is more than the above range, the moldability of the resin composition will be reduced.
- the plate-shaped filler used in the present invention preferably has an average particle diameter of 0.1 to 20 m. More preferably, the average particle size is 0.5-10 m, most preferably 2-8 m.
- the process tape has insufficient properties such as heat resistance and dimensional stability. In addition, the fluidity during resin processing is poor and processing becomes difficult, which is not preferable.
- the average particle diameter of the plate-shaped filler is larger than the above range, the appearance of the molded product is not preferable, and it is difficult to obtain smoothness of the surface. Absent.
- the mechanical strength and dimensional stability of the resin composition are dramatically improved by the plate-like filler.
- This plate-shaped filler suppresses the linear expansion inherent to the resin particularly when the process tape is used in a high-temperature region, and reduces the dimensional change due to the softening of the resin, thereby improving the mechanical strength and the dimensional stability.
- the plate-shaped filler used in the present invention has excellent dispersibility in the base resin and can be uniformly dispersed in the resin, so that the entire resin composition imparts uniformly good dimensional stability. it can.
- the resin composition of the present invention desirably has a uniform mixture of the resin and the plate-like filler. Yes.
- the plate-like filler used in the present invention preferably has an aspect ratio of 5 or more.
- the aspect ratio of the plate-shaped filler is represented by the average particle diameter Z and the average thickness of the plate-shaped filler. If the particles have a spherical shape and an aspect ratio of less than 5, linear expansion is not sufficiently reduced, which is not preferable. In addition, if the particles have an aspect ratio of 100 or more and are close to fibrous, the melt fluidity of the resin will decrease, and the resin will be oriented in the flow direction. A sheet having characteristics cannot be obtained.
- the material of the plate-shaped filler used in the present invention is not particularly limited, but a material mainly composed of a metal oxide such as silicon, aluminum, or magnesium can be used. . These may be used alone or in combination.
- the resin sheet for a process tape of the present invention may include a fiber reinforcing material (glass fiber, carbon fiber, potassium titanate fiber, ceramic fiber, aramide fiber, Boron fiber, etc.), granular or irregular reinforcing materials (calcium carbonate, clay, turquoise, my strength, graphite carbon, molybdenum disulfide, etc.), conductivity improving materials (carbon, zinc oxide, titanium oxide, etc.) ), Thermal conductivity improvers (such as powdered metal oxides), antioxidants, heat stabilizers, antistatic agents, ultraviolet absorbers, lubricants, mold release agents, dyes, pigments, and other thermoplastic resins ( Polyamide type, polycarbonate type, polyacetanol type, PET type, PBT type, polyphenylene sulfide type, polyarylate type, fluorine type, polyether-tolyl type, liquid crystal polymer type, etc.), thermosetting resin (phenol type, Epoxy-based, silicon-based, polyamide-imide, etc.) may be used
- the method of adding and mixing the resin component and the plate-shaped filler is not particularly limited, and various mixing and mixing means are used.
- a filler when a filler is added to a thermoplastic resin, each may be separately supplied to a melt extruder and mixed.
- only the powder raw material may be dry-preliminarily mixed using a mixer such as a Henschel mixer, a ball mixer, a blender, or a tumbler, and then melt-mixed using a melt mixer.
- a forming method suitable for the resin used as the base material can be used.
- a seed molding method may be used.
- secondary processing such as slitting to a predetermined width, forming of a concave and convex mold, application of a surface conductive layer, and an antistatic layer may be performed.
- the raw resin is melt-extruded and formed into a sheet.
- the method of extrusion and the method of taking over are not particularly limited.
- the sheet may have either a single-layer structure or a multilayer structure, and is not particularly limited.
- thermoplastic resin layer is produced by melt extrusion, and then a thermosetting polyimide resin layer is formed.
- a thermosetting polyimide resin sheet may be laminated and laminated by a lamination method during melt extrusion of a thermoplastic resin.
- the number of laminations and the lamination method are not particularly limited, but a heat-sealing lamination or a lamination method using an adhesive can be used.
- the thermoplastic resin layer of the present invention may be combined to form a multilayer structure.
- the tape for the production process of the present invention needs to have heat resistance.
- a heating step such as drying or baking
- the difference in dimensional change during heating between the film-shaped substrate and the spacer tape be as small as possible. If the values of the respective coefficients of linear expansion are significantly different, the film-like substrate and the spacer tape for producing the film-like substrate come into contact during the heating process, and the function of the spacer cannot be obtained.
- the film-shaped substrate is made of thermosetting polyimide / copper foil, and their linear expansion coefficient is 20-30 ppmZ ° C. Therefore, the tape for process of the present invention is desired to have a linear expansion coefficient of 50 ppmZ ° C or less.
- the appropriate range of such physical properties depends on the relative value between the tape for the production process and the film-like substrate used, so generally 50 ppm / ° C or less is practically used in most cases. Often there is no problem.
- the linear expansion coefficient of the sheet in the present invention is larger than 50 ppm / ° C, the difference in dimensional change between the sheet and the film-like substrate during the heating step becomes too large to cause a problem during the step.
- the process-step tape of the present invention has a bending strength of 10 times or more.
- Film substrate When processing in the form of S-reel, it is necessary that these process lead tapes and space tapes are also reel-shaped. If the bending strength is less than 10 times, it is easy to break during roll-to-roll line transfer for calorie in a reel shape, and there is a problem in use.
- the value of the bending strength (times) is preferably as large as possible, and more preferably 10 times or more. It is particularly preferably at least 15 times, more preferably at least 20 times.
- UDEL P—1700NT (trade name) manufactured by Solvay Advanced Polymers
- N-Talc L-1 aspect ratio 25 Average particle size: 5 / ⁇ ⁇
- each material was supplied to a twin-screw extruder with the composition shown in Table 1 and Table 2, and melt-blended to produce a bellet.
- Table 1 and Table 2 the composition shown in Table 1 and Table 2, and melt-blended to produce a bellet.
- the numerical values of the blending amounts in the respective Examples and Comparative Examples are parts by weight.
- the pellets thus produced were melt-extruded using a single screw extruder and a ⁇ die to obtain a sheet-like sample.
- a sheet-like sample was obtained by hot pressing.
- Various evaluations were performed based on the following.
- Folding strength is measured using a 0.2 mm thick sheet sample
- Alumina particles (* 5) 0 0 0 10 20 Plate-like filler (* 6) 0 0 0 0 0 0 0 Plate-like filler (* 7) 0 0 0 0 0 0 Folding strength [times] 28 120 2 9 7 lines expansion coefficient [P pmZ ° C] 55 55 48 54 48 properties heat resistance X ⁇ O ⁇ moldability OO ⁇ XX
- a tape for a production process of a low-cost film-shaped substrate excellent in heat resistance, mechanical properties, moldability, dimensional stability, and workability can be obtained.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Abstract
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2005515897A JPWO2005054345A1 (ja) | 2003-12-05 | 2004-11-17 | フィルム状配線基板の生産工程用テープ |
KR1020067013497A KR101146967B1 (ko) | 2003-12-05 | 2004-11-17 | 필름 모양의 배선 기판을 위한 제조 공정 테잎 |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2003-407330 | 2003-12-05 | ||
JP2003407330 | 2003-12-05 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2005054345A1 true WO2005054345A1 (fr) | 2005-06-16 |
Family
ID=34650306
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/JP2004/017046 WO2005054345A1 (fr) | 2003-12-05 | 2004-11-17 | Ruban pour processus de production de carte de cablage en forme de film |
Country Status (5)
Country | Link |
---|---|
JP (1) | JPWO2005054345A1 (fr) |
KR (1) | KR101146967B1 (fr) |
CN (2) | CN1886448A (fr) |
TW (1) | TW200518932A (fr) |
WO (1) | WO2005054345A1 (fr) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2009144058A (ja) * | 2007-12-14 | 2009-07-02 | Toyobo Co Ltd | 自動車外板部材。 |
JP2016079335A (ja) * | 2014-10-21 | 2016-05-16 | 三菱樹脂株式会社 | フィルム |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR101501957B1 (ko) * | 2008-09-08 | 2015-03-12 | 신닛테츠 수미킨 가가쿠 가부시키가이샤 | 고열전도성 폴리이미드 필름, 고열전도성 금속장 적층체 및 그 제조방법 |
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JPS6348835A (ja) * | 1986-08-19 | 1988-03-01 | Sumitomo Bakelite Co Ltd | フイルムキヤリアテ−プ |
JPS6454792A (en) * | 1987-08-26 | 1989-03-02 | Sumitomo Bakelite Co | Film carrier tape |
WO2002018495A1 (fr) * | 2000-08-29 | 2002-03-07 | Otsuka Chemical Co., Ltd. | Composition de resine, objet moule fabrique a partir d'une telle composition et utilisation correspondante |
JP2002338823A (ja) * | 2001-05-21 | 2002-11-27 | Mitsubishi Plastics Ind Ltd | 基板用耐熱フィルムおよびこれを用いたプリント配線基板 |
JP2003128931A (ja) * | 2001-10-23 | 2003-05-08 | Otsuka Chem Co Ltd | 樹脂組成物及び成形品 |
WO2003066740A1 (fr) * | 2002-02-06 | 2003-08-14 | Sekisui Chemical Co., Ltd. | Composition de resine |
JP2003292803A (ja) * | 2002-02-01 | 2003-10-15 | Sekisui Chem Co Ltd | 絶縁基板用材料、プリント基板、積層板、樹脂付き銅箔、銅張積層板、ポリイミドフィルム、tab用フィルム及びプリプレグ |
JP2004168962A (ja) * | 2002-11-22 | 2004-06-17 | Sumitomo Bakelite Co Ltd | Tab生産工程用スペーステープ |
JP2004182832A (ja) * | 2002-12-02 | 2004-07-02 | Sumitomo Bakelite Co Ltd | 芳香族系樹脂組成物、耐熱性シート及びフレキシブル回路基板補強用シート |
JP2004253723A (ja) * | 2003-02-21 | 2004-09-09 | Dainichi Kasei Kogyo Kk | チップ搬送体のスペーサのベース用フィルム |
JP2004349366A (ja) * | 2003-05-21 | 2004-12-09 | Mitsubishi Plastics Ind Ltd | 多層配線基板及びその製造方法 |
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JP2839704B2 (ja) * | 1990-11-27 | 1998-12-16 | 住友ベークライト株式会社 | Tab用スペーステープ |
JP2003282648A (ja) * | 2002-03-26 | 2003-10-03 | Sumitomo Bakelite Co Ltd | 構成体シート及びtab用スペーステープ |
-
2004
- 2004-11-17 JP JP2005515897A patent/JPWO2005054345A1/ja active Pending
- 2004-11-17 WO PCT/JP2004/017046 patent/WO2005054345A1/fr not_active Application Discontinuation
- 2004-11-17 CN CNA2004800346269A patent/CN1886448A/zh active Pending
- 2004-11-17 KR KR1020067013497A patent/KR101146967B1/ko not_active Expired - Fee Related
- 2004-11-17 CN CNA2008102134486A patent/CN101358035A/zh active Pending
- 2004-11-23 TW TW093136044A patent/TW200518932A/zh unknown
Patent Citations (11)
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JPS6348835A (ja) * | 1986-08-19 | 1988-03-01 | Sumitomo Bakelite Co Ltd | フイルムキヤリアテ−プ |
JPS6454792A (en) * | 1987-08-26 | 1989-03-02 | Sumitomo Bakelite Co | Film carrier tape |
WO2002018495A1 (fr) * | 2000-08-29 | 2002-03-07 | Otsuka Chemical Co., Ltd. | Composition de resine, objet moule fabrique a partir d'une telle composition et utilisation correspondante |
JP2002338823A (ja) * | 2001-05-21 | 2002-11-27 | Mitsubishi Plastics Ind Ltd | 基板用耐熱フィルムおよびこれを用いたプリント配線基板 |
JP2003128931A (ja) * | 2001-10-23 | 2003-05-08 | Otsuka Chem Co Ltd | 樹脂組成物及び成形品 |
JP2003292803A (ja) * | 2002-02-01 | 2003-10-15 | Sekisui Chem Co Ltd | 絶縁基板用材料、プリント基板、積層板、樹脂付き銅箔、銅張積層板、ポリイミドフィルム、tab用フィルム及びプリプレグ |
WO2003066740A1 (fr) * | 2002-02-06 | 2003-08-14 | Sekisui Chemical Co., Ltd. | Composition de resine |
JP2004168962A (ja) * | 2002-11-22 | 2004-06-17 | Sumitomo Bakelite Co Ltd | Tab生産工程用スペーステープ |
JP2004182832A (ja) * | 2002-12-02 | 2004-07-02 | Sumitomo Bakelite Co Ltd | 芳香族系樹脂組成物、耐熱性シート及びフレキシブル回路基板補強用シート |
JP2004253723A (ja) * | 2003-02-21 | 2004-09-09 | Dainichi Kasei Kogyo Kk | チップ搬送体のスペーサのベース用フィルム |
JP2004349366A (ja) * | 2003-05-21 | 2004-12-09 | Mitsubishi Plastics Ind Ltd | 多層配線基板及びその製造方法 |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2009144058A (ja) * | 2007-12-14 | 2009-07-02 | Toyobo Co Ltd | 自動車外板部材。 |
JP2016079335A (ja) * | 2014-10-21 | 2016-05-16 | 三菱樹脂株式会社 | フィルム |
Also Published As
Publication number | Publication date |
---|---|
KR101146967B1 (ko) | 2012-05-22 |
CN101358035A (zh) | 2009-02-04 |
TW200518932A (en) | 2005-06-16 |
KR20060126683A (ko) | 2006-12-08 |
CN1886448A (zh) | 2006-12-27 |
JPWO2005054345A1 (ja) | 2007-06-28 |
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