WO1997015530B1 - Carbonate de metal alcalino-terreux micronise - Google Patents
Carbonate de metal alcalino-terreux microniseInfo
- Publication number
- WO1997015530B1 WO1997015530B1 PCT/DE1996/002006 DE9602006W WO9715530B1 WO 1997015530 B1 WO1997015530 B1 WO 1997015530B1 DE 9602006 W DE9602006 W DE 9602006W WO 9715530 B1 WO9715530 B1 WO 9715530B1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- acid
- reaction mixture
- solution
- oxide
- surface area
- Prior art date
Links
- -1 alkaline earth metal carbonate Chemical class 0.000 title claims abstract 6
- 229910052784 alkaline earth metal Inorganic materials 0.000 title claims abstract 3
- 238000000034 method Methods 0.000 claims abstract 16
- 150000003863 ammonium salts Chemical class 0.000 claims abstract 6
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical class OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims abstract 6
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims abstract 6
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims abstract 5
- 239000013078 crystal Substances 0.000 claims abstract 5
- 239000011976 maleic acid Substances 0.000 claims abstract 5
- AYJRCSIUFZENHW-UHFFFAOYSA-L barium carbonate Chemical compound [Ba+2].[O-]C([O-])=O AYJRCSIUFZENHW-UHFFFAOYSA-L 0.000 claims abstract 4
- 239000003795 chemical substances by application Substances 0.000 claims abstract 4
- 229910000018 strontium carbonate Inorganic materials 0.000 claims abstract 4
- 239000003990 capacitor Substances 0.000 claims abstract 3
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims abstract 3
- 125000000896 monocarboxylic acid group Chemical group 0.000 claims abstract 3
- 238000002360 preparation method Methods 0.000 claims abstract 3
- 239000002887 superconductor Substances 0.000 claims abstract 3
- 125000005210 alkyl ammonium group Chemical group 0.000 claims abstract 2
- 150000001735 carboxylic acids Chemical class 0.000 claims abstract 2
- BDAGIHXWWSANSR-NJFSPNSNSA-N hydroxyformaldehyde Chemical compound O[14CH]=O BDAGIHXWWSANSR-NJFSPNSNSA-N 0.000 claims abstract 2
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims 11
- 239000011541 reaction mixture Substances 0.000 claims 9
- RGHNJXZEOKUKBD-SQOUGZDYSA-N D-gluconic acid Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=O RGHNJXZEOKUKBD-SQOUGZDYSA-N 0.000 claims 4
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 claims 4
- 238000004519 manufacturing process Methods 0.000 claims 4
- 150000001734 carboxylic acid salts Chemical class 0.000 claims 3
- 235000015165 citric acid Nutrition 0.000 claims 3
- 238000002156 mixing Methods 0.000 claims 3
- 239000002245 particle Substances 0.000 claims 3
- RGHNJXZEOKUKBD-UHFFFAOYSA-N D-gluconic acid Natural products OCC(O)C(O)C(O)C(O)C(O)=O RGHNJXZEOKUKBD-UHFFFAOYSA-N 0.000 claims 2
- AEMOLEFTQBMNLQ-AQKNRBDQSA-N D-glucopyranuronic acid Chemical compound OC1O[C@H](C(O)=O)[C@@H](O)[C@H](O)[C@H]1O AEMOLEFTQBMNLQ-AQKNRBDQSA-N 0.000 claims 2
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 claims 2
- IAJILQKETJEXLJ-UHFFFAOYSA-N Galacturonsaeure Natural products O=CC(O)C(O)C(O)C(O)C(O)=O IAJILQKETJEXLJ-UHFFFAOYSA-N 0.000 claims 2
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 claims 2
- 239000001361 adipic acid Substances 0.000 claims 2
- 235000011037 adipic acid Nutrition 0.000 claims 2
- 229910010293 ceramic material Inorganic materials 0.000 claims 2
- 239000000174 gluconic acid Substances 0.000 claims 2
- 235000012208 gluconic acid Nutrition 0.000 claims 2
- 229940097043 glucuronic acid Drugs 0.000 claims 2
- 238000001556 precipitation Methods 0.000 claims 2
- 239000011975 tartaric acid Substances 0.000 claims 2
- 235000002906 tartaric acid Nutrition 0.000 claims 2
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 claims 1
- PXRKCOCTEMYUEG-UHFFFAOYSA-N 5-aminoisoindole-1,3-dione Chemical compound NC1=CC=C2C(=O)NC(=O)C2=C1 PXRKCOCTEMYUEG-UHFFFAOYSA-N 0.000 claims 1
- DSLZVSRJTYRBFB-LLEIAEIESA-N D-glucaric acid Chemical compound OC(=O)[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=O DSLZVSRJTYRBFB-LLEIAEIESA-N 0.000 claims 1
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 claims 1
- 229910052788 barium Inorganic materials 0.000 claims 1
- 238000006243 chemical reaction Methods 0.000 claims 1
- 239000003638 chemical reducing agent Substances 0.000 claims 1
- 238000001035 drying Methods 0.000 claims 1
- 239000001630 malic acid Substances 0.000 claims 1
- 235000011090 malic acid Nutrition 0.000 claims 1
- 239000000203 mixture Substances 0.000 claims 1
- 239000007787 solid Substances 0.000 claims 1
- 238000003746 solid phase reaction Methods 0.000 claims 1
- 238000010671 solid-state reaction Methods 0.000 claims 1
- 229910052712 strontium Inorganic materials 0.000 claims 1
- YWYZEGXAUVWDED-UHFFFAOYSA-N triammonium citrate Chemical compound [NH4+].[NH4+].[NH4+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O YWYZEGXAUVWDED-UHFFFAOYSA-N 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 1
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 abstract 2
- QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Chemical compound [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 abstract 2
- IATRAKWUXMZMIY-UHFFFAOYSA-N strontium oxide Chemical compound [O-2].[Sr+2] IATRAKWUXMZMIY-UHFFFAOYSA-N 0.000 abstract 2
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical class O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 abstract 1
- 229910000019 calcium carbonate Inorganic materials 0.000 abstract 1
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 abstract 1
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 abstract 1
- 239000000292 calcium oxide Substances 0.000 abstract 1
- 229910017604 nitric acid Chemical class 0.000 abstract 1
- 239000011224 oxide ceramic Substances 0.000 abstract 1
- 229910052574 oxide ceramic Inorganic materials 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
Abstract
L'invention concerne un carbonate de métal alcalino-terreux micronisé obtenu avec ou sans apport d'un agent inhibant la croissance cristalline, ainsi qu'un procédé permettant de le préparer et son utilisation. Le carbonate micronisé obtenu, que ce soit du carbonate de calcium, du carbonate de baryum à surface BET comprise entre 3 et 30 m2/g ou du carbonate de strontium à surface BET comprise entre 3 et 50 m2/g, s'utilise notamment pour produire des condensateurs, des thermistances et d'autres composants électriques en céramique oxydée contenant de l'oxyde de calcium, de l'oxyde de baryum ou de l'oxyde de strontium ainsi que des supraconducteurs pour hautes températures. Les agents inhibant la croissance cristalline utilisés sont des sels d'ammonium ou d'alkylammonium d'acides carboxyliques, qui comportent au total entre 3 et 12 atomes de C, ainsi qu'au moins deux groupes COOH ou au moins deux groupes OH, par ex. des sels d'acide maléique ou d'acide citrique.
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/065,067 US6479029B1 (en) | 1995-10-26 | 1996-10-22 | Micronized alkaline earth metal carbonate |
| EP96945521A EP0857160B1 (fr) | 1995-10-26 | 1996-10-22 | Carbonate de metal alcalino-terreux micronise |
| DE59602568T DE59602568D1 (de) | 1995-10-26 | 1996-10-22 | Mikronisiertes erdalkalimetallcarbonat |
| JP51619497A JP4528370B2 (ja) | 1995-10-26 | 1996-10-22 | 微粒子状のアルカリ土類金属炭酸塩の製造方法、該方法により得られるアルカリ土類金属炭酸塩および酸化物含有セラミック材料の製造方法 |
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19539813 | 1995-10-26 | ||
| DE19539813.0 | 1995-10-26 | ||
| DE19548131.3 | 1995-12-21 | ||
| DE19548131 | 1995-12-21 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| WO1997015530A2 WO1997015530A2 (fr) | 1997-05-01 |
| WO1997015530A3 WO1997015530A3 (fr) | 1997-06-05 |
| WO1997015530B1 true WO1997015530B1 (fr) | 1997-07-03 |
Family
ID=26019793
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/DE1996/002006 WO1997015530A2 (fr) | 1995-10-26 | 1996-10-22 | Carbonate de metal alcalino-terreux micronise |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US6479029B1 (fr) |
| EP (1) | EP0857160B1 (fr) |
| JP (2) | JP4528370B2 (fr) |
| KR (1) | KR100424536B1 (fr) |
| AT (1) | ATE182559T1 (fr) |
| DE (2) | DE59602568D1 (fr) |
| TW (1) | TW369511B (fr) |
| WO (1) | WO1997015530A2 (fr) |
Families Citing this family (29)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| AU6834298A (en) * | 1998-04-07 | 1999-10-25 | Fp-Pigments Oy | Process and apparatus for producing precipitated calcium carbonate |
| GB9815289D0 (en) * | 1998-07-14 | 1998-09-09 | Unilever Plc | Speroidal calcitic calcium carbonate |
| DE19964060B4 (de) * | 1999-12-30 | 2008-01-31 | Solvay Infra Bad Hönningen GmbH | Hochreaktives Bariumcarbonat |
| JP2005306640A (ja) * | 2004-04-20 | 2005-11-04 | Fuji Photo Film Co Ltd | アルカリ土類金属の炭酸塩結晶の製造方法およびアルカリ土類金属の炭酸塩結晶 |
| DE102005025717A1 (de) * | 2004-08-14 | 2006-02-23 | Solvay Barium Strontium Gmbh | Strontiumcarbonat-Dispersion und daraus erhältliches redispergierbares Pulver |
| KR20070040418A (ko) * | 2004-08-25 | 2007-04-16 | 후지필름 가부시키가이샤 | 탄산염 제조 방법 |
| JP4273066B2 (ja) * | 2004-10-26 | 2009-06-03 | 宇部マテリアルズ株式会社 | 針状炭酸ストロンチウム粒子 |
| JP4249115B2 (ja) * | 2004-10-26 | 2009-04-02 | 宇部マテリアルズ株式会社 | 炭酸ストロンチウム微粒子の製造方法 |
| WO2006137344A1 (fr) | 2005-06-24 | 2006-12-28 | Fujifilm Corporation | Composition de résine optique et procédé de production de celle-ci |
| EP1746073A1 (fr) * | 2005-07-20 | 2007-01-24 | SOLVAY (Société Anonyme) | Procédé de préparation de solides par précipitation, dispersions et solides obtenues et leur utilisation comme additif |
| JP2007099614A (ja) * | 2005-09-12 | 2007-04-19 | Ube Material Industries Ltd | 炭酸ストロンチウム微粉末 |
| DE102006014565A1 (de) * | 2005-11-05 | 2007-05-10 | Voith Patent Gmbh | Verfahren und Anordnung zur Herstellung von Streichfarbe zum Bestreichen einer Faserstoffbahn |
| JP2007176789A (ja) * | 2005-12-01 | 2007-07-12 | Ube Material Industries Ltd | 炭酸バリウム粉末及びその製造方法 |
| CN100450932C (zh) * | 2006-11-24 | 2009-01-14 | 清华大学 | 一种纳米碳酸钙的碳化工艺方法 |
| JP5543198B2 (ja) * | 2007-03-13 | 2014-07-09 | 宇部マテリアルズ株式会社 | 高分散性アルカリ土類金属炭酸塩微粉末 |
| JP5474310B2 (ja) * | 2007-03-28 | 2014-04-16 | 宇部マテリアルズ株式会社 | 粒状炭酸バリウム組成物粉末 |
| AT506658B1 (de) * | 2008-03-31 | 2015-02-15 | Erema | Verfahren zur herstellung eines gefüllten polymermaterials |
| JP4920666B2 (ja) * | 2008-12-02 | 2012-04-18 | 宇部マテリアルズ株式会社 | 針状炭酸ストロンチウム粒子の製造方法 |
| SG175039A1 (en) * | 2009-04-03 | 2011-11-28 | Sakai Chemical Industry Co | Generally spherical barium carbonate particles, and method for producing generally spherical barium carbonate particles |
| JP2010254533A (ja) * | 2009-04-28 | 2010-11-11 | Nippon Chem Ind Co Ltd | 炭酸ストロンチウム粒子粉末の製造方法 |
| JP6058250B2 (ja) * | 2010-04-12 | 2017-01-11 | 日東電工株式会社 | 粒子分散樹脂組成物、粒子分散樹脂成形体およびそれらの製造方法 |
| TWI516448B (zh) * | 2011-02-15 | 2016-01-11 | 宇部材料股份有限公司 | Preparation of needle - like strontium carbonate particles |
| DE102011014348A1 (de) * | 2011-03-18 | 2014-06-18 | Ecoloop Gmbh | Verfahren zur kontinuierlichen Herstellung von gefälltem Calciumcarbonat |
| KR101280942B1 (ko) | 2011-09-09 | 2013-07-02 | 주식회사 포스코 | 부산물 회수 방법 |
| EP3530805A1 (fr) * | 2018-02-21 | 2019-08-28 | Imertech Sas | Suspensions de carbonate de calcium précipité bimodales convenant à des applications de papier et de carton, leurs procédés de fabrication et leurs utilisations |
| JP6658792B2 (ja) * | 2018-04-26 | 2020-03-04 | 堺化学工業株式会社 | 炭酸バリウムの製造方法 |
| US11530232B2 (en) * | 2019-11-14 | 2022-12-20 | Alliance For Sustainable Energy, Llc | Reversibly soluble bases for lignin oxidative depolymerization |
| CN116443911B (zh) * | 2023-05-06 | 2023-12-29 | 湖北展鹏电子材料有限公司 | 一种高纯度球形纳米碳酸钡的制备方法 |
| CN116654967B (zh) * | 2023-06-01 | 2024-01-30 | 湖北展鹏电子材料有限公司 | 一种易于固液分离的球形纳米碳酸钡的制备方法 |
Family Cites Families (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2058503A (en) * | 1933-01-04 | 1936-10-27 | Raffold Process Corp | Colloidal calcium carbonate |
| US2188663A (en) * | 1938-04-04 | 1940-01-30 | Diamond Alkali Co | Process of making fine particle alkaline earth metal carbonates |
| US2964382A (en) * | 1958-04-04 | 1960-12-13 | Wyandotte Chemicals Corp | Production of precipitated calcium carbonate |
| US3920800A (en) * | 1973-10-12 | 1975-11-18 | Cyprus Mines Corp | Production of purified calcium carbonate |
| GB1447566A (en) * | 1974-02-14 | 1976-08-25 | Ici Ltd | Production of calcium carbonate |
| JPS5450499A (en) * | 1977-09-30 | 1979-04-20 | Okutama Kogyo Kk | Method of manufacturing aragonite columnar calcium carbonate |
| JPS56160322A (en) * | 1980-05-06 | 1981-12-10 | Shiraishi Chuo Kenkyusho:Kk | Manufacture of calcium carbonate with superior dispersibility |
| JPS59223225A (ja) * | 1983-05-27 | 1984-12-15 | Shiraishi Chuo Kenkyusho:Kk | アラゴナイト質炭酸カルシウムの製造方法 |
| JPS60189832A (ja) * | 1984-03-09 | 1985-09-27 | Toshiba Corp | アルカリ土類炭酸塩の製造方法 |
| DE3717058A1 (de) * | 1987-05-21 | 1988-12-08 | Bayer Ag | Mischer zum vermischen mindestens zweier fliessfaehiger stoffe, insbesondere unter durchfuehrung bzw. einleitung einer reaktion waehrend der vermischung |
| JP2605446B2 (ja) * | 1990-03-09 | 1997-04-30 | 住友金属工業株式会社 | 磁器材料の製造方法 |
| US5059407A (en) * | 1990-03-28 | 1991-10-22 | Liquid Carbonic Corporation | Liquid carbon dioxide injection in exothermic chemical reactions |
| JP3321823B2 (ja) * | 1992-03-04 | 2002-09-09 | 株式会社村田製作所 | 非還元性誘電体磁器組成物 |
| DE4207923A1 (de) * | 1992-03-13 | 1993-09-16 | Solvay Barium Strontium Gmbh | Herstellung von granuliertem erdalkalimetallcarbonat |
| JP3243912B2 (ja) * | 1992-12-25 | 2002-01-07 | 住友化学工業株式会社 | 水酸化アルミニウムの連続製造方法 |
| JP3407333B2 (ja) * | 1993-05-24 | 2003-05-19 | 松下電器産業株式会社 | 電子管陰極用炭酸塩の製造方法 |
| JP3232794B2 (ja) * | 1993-07-12 | 2001-11-26 | 堺化学工業株式会社 | チタン酸バリウム製造用微細炭酸バリウムの製造方法 |
| JP3269910B2 (ja) * | 1994-03-30 | 2002-04-02 | 太陽誘電株式会社 | 磁器コンデンサ及びその製造方法 |
-
1996
- 1996-10-22 US US09/065,067 patent/US6479029B1/en not_active Expired - Lifetime
- 1996-10-22 EP EP96945521A patent/EP0857160B1/fr not_active Expired - Lifetime
- 1996-10-22 JP JP51619497A patent/JP4528370B2/ja not_active Expired - Lifetime
- 1996-10-22 KR KR10-1998-0702750A patent/KR100424536B1/ko not_active Expired - Lifetime
- 1996-10-22 DE DE59602568T patent/DE59602568D1/de not_active Expired - Lifetime
- 1996-10-22 DE DE19643657A patent/DE19643657A1/de not_active Withdrawn
- 1996-10-22 AT AT96945521T patent/ATE182559T1/de active
- 1996-10-22 WO PCT/DE1996/002006 patent/WO1997015530A2/fr active IP Right Grant
- 1996-12-06 TW TW085115060A patent/TW369511B/zh not_active IP Right Cessation
-
2010
- 2010-02-12 JP JP2010028518A patent/JP5393518B2/ja not_active Expired - Lifetime
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