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WO1996034078A1 - Composition aqueuse et utilisation d'un agent ameliorant le mouillage - Google Patents

Composition aqueuse et utilisation d'un agent ameliorant le mouillage Download PDF

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Publication number
WO1996034078A1
WO1996034078A1 PCT/SE1996/000498 SE9600498W WO9634078A1 WO 1996034078 A1 WO1996034078 A1 WO 1996034078A1 SE 9600498 W SE9600498 W SE 9600498W WO 9634078 A1 WO9634078 A1 WO 9634078A1
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WO
WIPO (PCT)
Prior art keywords
formula
carbon atoms
group
range
composition
Prior art date
Application number
PCT/SE1996/000498
Other languages
English (en)
Inventor
Ingegärd Johansson
Original Assignee
Akzo Nobel N.V.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Akzo Nobel N.V. filed Critical Akzo Nobel N.V.
Priority to AT96912365T priority Critical patent/ATE203763T1/de
Priority to DK96912365T priority patent/DK0822972T3/da
Priority to EP96912365A priority patent/EP0822972B1/fr
Priority to DE69614259T priority patent/DE69614259T2/de
Priority to US08/930,176 priority patent/US5928993A/en
Publication of WO1996034078A1 publication Critical patent/WO1996034078A1/fr
Priority to GR20010401780T priority patent/GR3036910T3/el

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88—Ampholytes; Electroneutral compounds
    • C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/30—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests characterised by the surfactants
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/662—Carbohydrates or derivatives
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88—Ampholytes; Electroneutral compounds

Definitions

  • the present invention relates to an aqueous composition which, when applied to a surface, improves the wetting.
  • the composition contains an alkyl glycoside, which is soluble in the aqueous composition and in which the alkyl group is a branched alkyl chain having 6-12 carbon atoms, in combination with a low-foaming amphoteric compound, which is soluble in the aqueous composition, or a nonionic alkoxilate, which is soluble in the aqueous compo ⁇ sition, or a mixture thereof.
  • Surfactants are generally used for spreading an aqueous composition containing one or more active substances rapidly and evenly over a surface. As a result, the active substances in the composition are put to more efficient use.
  • alkyl polyglycosides are known from Statutory Invention H 303 and US 4,888,325.
  • EP 220 902 proposes that also a foam inhibitor, such as di ethylpolysiloxane, be added to compositions containing alkyl glycoside as wetting agent.
  • a foam inhibitor such as di ethylpolysiloxane
  • alkyl polyglycosides used as wetting agents may be mixed with respectively an acetylene diol and a fatty alcohol as foam-inhibiting and wetting-improving agent. Since the foam inhibitors proposed have low water solubility, their presence may result in unstable formulations necessita ⁇ ting the addition of a solubiliser.
  • One object of the present invention is, therefore, to provide a wetting agent of good wetting power not necessitating any extra additions of a foam inhibitor of limited solubility or of a solubiliser.
  • ROG x (I) wherein R is a branched alkyl group having 6-12 carbon atoms, G is a monosaccharide residue, x is a number in the range of 1-5, and has a foaming not exceeding 25 mm after 5 min at 50°C, as measured according to Ross-Miles, and a concentration of 0.05% by weight, in combination with an amphoteric compound which is soluble in the aqueous composition and contains an alkyl group having 6-12 carbon atoms, and/or a nonionic al- koxilate which is soluble in the aqueous composition and con ⁇ tains an alkyl group having 6-12 carbon atoms, or a mixture thereof, the amphoteric compound and the alkoxilate having a foaming not exceeding 25 mm after 5 min at 50°C, as measured according to Ross-Miles, and a content of 0.05% by weight.
  • the branched alkyl glycosides indicated above have a low tendency towards foaming and result, in combination with the lowfoaming amphoteric or nonionic surfactants indicated above, in ex ⁇ cellent wetting properties.
  • the amphoteric surfactant or the nonionic alkoxilate has been found to enhance the wetting power of the alkyl glycoside while keeping foaming at a low level.
  • the aqueous composition may advantageously be applied e.g. to hydrophobic surfaces, such as those of plant leaves, lacquered metal sheets, plastics, for instance polyethylene or PVC, and glass, as well as surfaces coated with hydrophobic dirt.
  • hydrophobic surfaces such as those of plant leaves, lacquered metal sheets, plastics, for instance polyethylene or PVC, and glass, as well as surfaces coated with hydrophobic dirt.
  • the weight ratio of the alkyl glycoside, on the one hand, to the amphoteric compound and/or the alkoxilate, on the other hand, usually ranges from 100:1 to 2:1, preferably from 50:1 to 6:1.
  • the total content of all three components may vary within wide limits depending on the field of application, but it normally constitutes 0.1-4% by weight, preferably 0.2-2% by weight. If the composition is in the form of a concentrate that is ready for use after being diluted with water, the content of these three components usually is 2-80% by weight.
  • the alkyl glycoside of formula I preferably consists of compounds having the general formula R x
  • R 2 wherein R : is an alkyl group having 2-5 carbon atoms, prefer ⁇ ably an alkyl group having 2-4 carbon atoms, R 2 is an alkyl group having 3-7 carbon atoms, preferably an alkyl group having 4-6 carbon atoms, the sum of carbon atoms in R x and R 2 being 5-12, preferably 6-10, G is a monosaccharide residue, and x is a number in the range of 1-5, preferably 1-4.
  • This alkyl glyco ⁇ side has good cleaning and wetting properties, as well as low foaming in relation to other straight alkyl glycosides of approximately the same chain length.
  • Especially preferred com ⁇ pounds of formula II are those in which R : is 3, R 2 is 5, and G is a glucose residue.
  • the glucosides have a neutral smell, are easily degraded and have low biotoxicity. In tests, one has not found any skin irritations caused by the alkyl glycosides.
  • SE-A-9300955-3 discloses alkyl glycosides of this type.
  • alkyl glycosides are those encompassed by the formula R 3 CH 2 0(G) x H (III) wherein R 3 is an alkyl group having a total of 6-12 carbon atoms and containing 1-4 groups of the formula -CH(CH 3 )- forming part of the carbon chain of the alkyl group, G is a monosaccharide residue, and x is a number in the range of 1-5, preferably 1-4. Preferably, the number of methyl groups is 2 or 3.
  • Alkyl glycosides of formula III not only have good cleaning and wetting properties but also exhibit low foaming in relation to glycosides based on straight alcohols having approximately the same chain length.
  • alkyl glycosides of formula III are easily degraded and have low biotoxicity. In tests, one has not found any skin irritations caused by these alkyl glycosides.
  • Especially preferred compounds are those in which R 3 contains 7-11 carbon atoms, since these compounds have a low tendency towards foaming and are relatively easy to produce.
  • SE-A-9300954-6 discloses alkyl glycosides of this type.
  • amphoteric surfactant has the general formula
  • R 4 is an alkyl group having 6-12 carbon atoms
  • Z is the group CO, a group (B) n OCH 2 CH(OH)CH 2 , in which B is an oxyalkyl group having 2-4 carbon atoms, and n is a number in the range of 0-5, or the group CH(OH)CH 2 , z is 0 or 1,
  • R 5 is the group -C 2 H 4 - or the group -C 3 H 6 -
  • y is a group R 6 COOM
  • y is a number in the range of 0-3, y being 1-3 when z is 1 and Z is the group CO
  • R 6 is -CH 2 - or -C 2 H 4 -
  • M is hydrogen or a cation.
  • the amphoteric compound of formula IV has a surpris ⁇ ingly good solubilising power enabling the preparation of a concentrated aqueous composition.
  • Amphoteric compounds in which the number of R 6 COOM groups is at least 2 are preferred, M preferably being a mono- valent cation, such as an alkali ion or an organic ammonium ion.
  • the designation y preferably is a number in the range of 0-2.
  • the hydrocarbon group R 4 preferably is an aliphatic group having 6-15 carbon atoms. Specific examples of suitable R 4 groups are hexyl, 2-ethylhexyl, capryl and decyl groups, as well as alkyl groups corresponding to those indicated for formulae I, II and III. Examples of suitable amphoteric com-
  • R 4 , R 5 , R 6 , M and Y have the significations indicated for formula IV, and y : is a number in the range of 0-2, prefer ⁇ ably 0 or 1, the number of R 6 COOM groups being at least 2,
  • R 4 , R 5 , R 6 , Y and M have the significations indicated for formula IV, and y 2 is 0 or 1, the number of R 6 COOM groups being at least 2,
  • R 4 , R 5 , R 6 , Y and M have the significations indicated for formula IV, and y 3 is a number in the range of 0-2, prefer ⁇ ably 0 or 1, the number of R 6 COOM groups being at least 2, and
  • B is an oxyethylene group and n is 0 or 1.
  • the nonionic alkoxilate consists of com ⁇ pounds having the formula
  • R 7 (C 2 H 4 0) x (C 3 H 6 0) y H (IX) wherein R 7 is a branched or straight alkyl group having 6-13 carbon atoms, preferably 7-11 carbon atoms, x is a number in the range of 2-6, and y is a number in the range of 0-4, the groups C 2 H 4 0 and C 3 H 6 0 being randomly added or added in blocks.
  • alkyl groups are groups derived from straight alcohols or branched alcohols, such as oxoalcohols, alcohols having the formula
  • the aqueous composition applied to a surface contains active sub ⁇ stances, such as pesticides, herbicides, fertilisers, cleaning surfactants, and complexing agents, which may be present in solid state or in the form of emulsions, suspensions or solu ⁇ tions.
  • active sub ⁇ stances such as pesticides, herbicides, fertilisers, cleaning surfactants, and complexing agents, which may be present in solid state or in the form of emulsions, suspensions or solu ⁇ tions.
  • Wetting-agent combinations according to the invention have proved to possess a good stabilising and solubilising power with respect to a great number of active substances. As a result, it has been found easy to formulate stable dispersions, emulsions and solutions having a high content of active sub ⁇ stances.
  • the wetting-agent composition is especially suited for use when the formulation consists of solutions and microemul- sions having a high content of active substances.
  • compositions accord- ing to the invention are icronutrient solutions containing different micronutrients, such as iron, manganese, zinc, copper, boron and molybdenum, which are complexed, pre ⁇ ferably to amino carboxylates, such as EDTA, DTPA, MEDTA and EDDHA.
  • micronutrients such as iron, manganese, zinc, copper, boron and molybdenum
  • the formulation may advan- tageously contain macronutrients, such as potassium, nitrogen, phosphorus, magnesium and sulphur.
  • liquid detergents which, besides the alkyl glycoside indicated above, the amphoteric compound and/or the alkoxilate, may contain complexing agents, preferably of amino carboxylate type, such as EDTA, DTPA, HEDTA, NTA and EDDHA, and optionally further surfactants, which may be anionic, nonionic, cationic, amphoteric and/or zwitter- ionic.
  • complexing agents preferably of amino carboxylate type, such as EDTA, DTPA, HEDTA, NTA and EDDHA
  • surfactants which may be anionic, nonionic, cationic, amphoteric and/or zwitter- ionic.
  • the wetting-agent composition according to the invention is especially suited for use in detergents having a high content of alkaline agents, such as alkali hydroxides, complexing agents and silicates, and having a pH value above 11, preferably above 12.
  • the wetting agent according to the invention considerably improves the poor wetting power
  • Test procedure A water drop (about 4 ml) , which con ⁇ tained different wetting agents and optionally various active substances, such as cleaning surfactants, pesticides, herbi ⁇ cides and fertilisers, was applied to a paraffin-wax surface (Parafilm) .
  • the propagation (spreading) of the drop was mea ⁇ sured by determining the contact angle after 2 s and 100 s.
  • the foam height for the following components was mea ⁇ sured according to Ross-Miles at a content of 0.05% by weight and at a temperature of 50°C, both at once and after 5 min.
  • the following results were obtained. It is evident from these results that the alkyl gly ⁇ cosides according to the invention exhibit much lower foaming than equivalent straight-chained alkyl glycosides. It is especially remarkable that the limited amount of foam formed when use is made of the alkyl glycosides according to the in ⁇ vention collapses fairly rapidly, whereas the alkyl glycoside in the comparative tests A and B gives rise to high-stability foam.

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  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Plant Pathology (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Molecular Biology (AREA)
  • Toxicology (AREA)
  • Dentistry (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Detergent Compositions (AREA)
  • Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)

Abstract

Composition aqueuse qui contient un glycoside d'alkyle peu moussant de formule (I) ROGx dans laquelle R est un groupe alkyle ramifié possédant de 6 à 12 atomes de carbone, G est un reste de monosaccharide et x est un nombre de 1 à 5. Ladite composition, lorsqu'elle est combinée à un composé amphotère peu moussant et/ou à un alcoxylate non ionique peu moussant, se révèle avoir un effet mouillant étonnamment élevé. En plus de la composition tensioactive, ladite composition peut contenir des substances actives telles que des pesticides, des herbicides, des engrais, des tensioactifs de nettoyage et des agents alcalins.
PCT/SE1996/000498 1995-04-28 1996-04-18 Composition aqueuse et utilisation d'un agent ameliorant le mouillage WO1996034078A1 (fr)

Priority Applications (6)

Application Number Priority Date Filing Date Title
AT96912365T ATE203763T1 (de) 1995-04-28 1996-04-18 Wässerige zusammensetzung und verwendung eines netzmittels
DK96912365T DK0822972T3 (da) 1995-04-28 1996-04-18 Vandig sammensætning og anvendelsen af et befugtningsforbedrende middel
EP96912365A EP0822972B1 (fr) 1995-04-28 1996-04-18 Composition aqueuse et utilisation d'un agent ameliorant le mouillage
DE69614259T DE69614259T2 (de) 1995-04-28 1996-04-18 Wässerige zusammensetzung und verwendung eines netzmittels
US08/930,176 US5928993A (en) 1995-04-28 1996-04-18 Aqueous composition, and the use of a wetting-improving agent
GR20010401780T GR3036910T3 (en) 1995-04-28 2001-10-17 Aqueous composition, and the use of a wetting-improving agent

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
SE9501581-4 1995-04-28
SE9501581A SE506265C2 (sv) 1995-04-28 1995-04-28 Vattenhaltig komposition innehållande en alkylglykosid och användning därav som vätmedel

Publications (1)

Publication Number Publication Date
WO1996034078A1 true WO1996034078A1 (fr) 1996-10-31

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PCT/SE1996/000498 WO1996034078A1 (fr) 1995-04-28 1996-04-18 Composition aqueuse et utilisation d'un agent ameliorant le mouillage

Country Status (11)

Country Link
US (1) US5928993A (fr)
EP (1) EP0822972B1 (fr)
AT (1) ATE203763T1 (fr)
CA (1) CA2217241A1 (fr)
DE (1) DE69614259T2 (fr)
DK (1) DK0822972T3 (fr)
ES (1) ES2162050T3 (fr)
GR (1) GR3036910T3 (fr)
PT (1) PT822972E (fr)
SE (1) SE506265C2 (fr)
WO (1) WO1996034078A1 (fr)

Cited By (13)

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Publication number Priority date Publication date Assignee Title
WO1997023131A1 (fr) * 1995-12-22 1997-07-03 Zeneca Limited Composition herbicide
WO1998039273A1 (fr) * 1997-03-07 1998-09-11 Aquatrols Corporation Of America Inc. Engrais hydrosoluble pleinement compatible impregne de tensioactifs, son concentre, et son procede d'utilisation
WO1999008517A1 (fr) * 1997-08-18 1999-02-25 Cognis Deutschland Gmbh Microemulsions
US6107249A (en) * 1996-10-07 2000-08-22 Zeneca Limited Glyphosate formulations
US6460290B1 (en) 1997-03-07 2002-10-08 Robert A. Moore Fully compatible surfactant-impregnated water-soluble fertilizer; concentrate; and use
EP1273756A1 (fr) 2001-06-12 2003-01-08 Services Petroliers Schlumberger Compositions surfactantes pour le nettoyage de puits
US6826866B2 (en) 1997-03-07 2004-12-07 Aquatrols Corp. Of America, Inc. Fully compatible water-soluble fertilizer and use
US6972274B1 (en) 1999-09-24 2005-12-06 Akzo Nobel N.V. Method of improving the permeability of an underground petroleum-containing formation
US7358215B1 (en) 1999-09-07 2008-04-15 Akzo Nobel Surface Chemistry Llc Quaternary ammonium salts as thickening agents for aqueous systems
WO2015000792A1 (fr) * 2013-07-03 2015-01-08 Basf Se Mélanges de composés, leur préparation, et utilisations
EP2998311A1 (fr) * 2014-09-17 2016-03-23 Basf Se Mélange d'alkylglycoside, sa fabrication et son utilisation
US10196567B2 (en) 2013-05-08 2019-02-05 Croda International Plc Soil treatment
US12268764B2 (en) 2019-10-30 2025-04-08 L'oreal Color- and clarity-stable natural micellar water

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FR2733246B1 (fr) * 1995-04-21 1997-05-23 Seppic Sa Composition anti-mousse comprenant un tensioactif non ionique et un alkylpolyglycoside
DE19701127A1 (de) * 1997-01-15 1998-07-16 Henkel Kgaa Schaumarme Tensidkonzentrate für den Einsatz im Bereich der Förderung des Pflanzenwachstums
US6565860B1 (en) * 1999-05-14 2003-05-20 Jay-Mar, Inc. Surfactant coated products and methods for their use in promoting plant growth and soil remediation
US6723688B1 (en) 1999-09-27 2004-04-20 Shaklee Corporation Cleanser that is gentle to human skin
US6358293B1 (en) * 1999-11-23 2002-03-19 The Hampshire Chemical Corporation Methods for rendering high concentrations of manganese safe for plant growth and formulations for same
US6537960B1 (en) 2001-08-27 2003-03-25 Ecolab Inc. Surfactant blend for use in highly alkaline compositions
US6645914B1 (en) * 2002-05-01 2003-11-11 Ndsu-Research Foundation Surfactant-ammonium sulfate adjuvant composition for enhancing efficacy of herbicides
US7199090B2 (en) 2003-09-29 2007-04-03 Ethena Healthcare Inc. High alcohol content gel-like and foaming compositions comprising an alcohol and fluorosurfactant
DE102004062775A1 (de) 2004-12-21 2006-06-29 Stockhausen Gmbh Alkoholischer Pumpschaum
US8263098B2 (en) * 2005-03-07 2012-09-11 Deb Worldwide Healthcare Inc. High alcohol content foaming compositions with silicone-based surfactants
US7651990B2 (en) * 2005-06-13 2010-01-26 3M Innovative Properties Company Foamable alcohol compositions comprising alcohol and a silicone surfactant, systems and methods of use
US20070148101A1 (en) * 2005-12-28 2007-06-28 Marcia Snyder Foamable alcoholic composition
WO2008156625A1 (fr) * 2007-06-14 2008-12-24 Mason Chemical Company Composition d'agent tensio-actif ester phosphate fluoré et d'alcool fluoré
WO2010002836A2 (fr) 2008-07-03 2010-01-07 Mosanto Technology Llc Combinaisons de tensioactifs de saccharides dérivés et de tensioactifs d’oxyde d’étheramine comme adjuvants herbicides
US8420529B2 (en) * 2008-09-19 2013-04-16 Mitsubishi Gas Chemical Company, Inc. Copper wiring surface protective liquid and method for manufacturing semiconductor circuit
EP3266859A1 (fr) * 2016-07-05 2018-01-10 Basf Se Composition appropriée comme agent d'élimination de dégraissage et/ou de dépôts de type huile grasse
CN114794099B (zh) * 2021-01-19 2024-10-25 诺力昂化学品国际有限公司 用于农业的含氮表面活性剂

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JPH05201815A (ja) * 1991-08-02 1993-08-10 Monsanto Co 除草剤組成物、その製造方法およびその使用方法
US5258359A (en) * 1991-08-02 1993-11-02 Monsanto Company Glyphosant-containing herbicidal compositions comprising acetylenic diol rainfastness enhancing agents
US5385750A (en) * 1992-05-14 1995-01-31 Henkel Corporation Alkyl glycoside compositions with improved wetting properties
US5663117A (en) * 1993-12-17 1997-09-02 Monsanto Company Alkoxylated primary alcohol surfactants providing enhanced efficacy and/or rainfastness to glyphosate formulations

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Publication number Priority date Publication date Assignee Title
WO1988009369A1 (fr) * 1987-05-18 1988-12-01 Staley Continental, Inc. Composition de detergents peu moussante
WO1993020171A1 (fr) * 1992-04-02 1993-10-14 Henkel Kommanditgesellschaft Auf Aktien Melanges detergents aqueux peu moussants
WO1994021655A1 (fr) * 1993-03-23 1994-09-29 Berol Nobel Ab Glucoside d'alkyle et son utilisation
WO1994021769A1 (fr) * 1993-03-23 1994-09-29 Berol Nobel Ab Glucoside d'alkyle, son utilisation a des fins de nettoyage, et composition de nettoyage
WO1995004592A1 (fr) * 1993-08-06 1995-02-16 Societe D'exploitation De Produits Pour Les Industries Chimiques, S.E.P.P.I.C. Compositions aqueuses concentrees d'alkylpolyglycosides et leurs utilisations

Cited By (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6010979A (en) * 1995-12-22 2000-01-04 Zeneca Limited Herbicidal composition
WO1997023131A1 (fr) * 1995-12-22 1997-07-03 Zeneca Limited Composition herbicide
US6107249A (en) * 1996-10-07 2000-08-22 Zeneca Limited Glyphosate formulations
US6460290B1 (en) 1997-03-07 2002-10-08 Robert A. Moore Fully compatible surfactant-impregnated water-soluble fertilizer; concentrate; and use
WO1998039273A1 (fr) * 1997-03-07 1998-09-11 Aquatrols Corporation Of America Inc. Engrais hydrosoluble pleinement compatible impregne de tensioactifs, son concentre, et son procede d'utilisation
US6826866B2 (en) 1997-03-07 2004-12-07 Aquatrols Corp. Of America, Inc. Fully compatible water-soluble fertilizer and use
WO1999008517A1 (fr) * 1997-08-18 1999-02-25 Cognis Deutschland Gmbh Microemulsions
US6255253B1 (en) 1997-08-18 2001-07-03 Cognis Deutschland Gmbh Microemulsions
US7358215B1 (en) 1999-09-07 2008-04-15 Akzo Nobel Surface Chemistry Llc Quaternary ammonium salts as thickening agents for aqueous systems
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CN107074901B (zh) * 2014-09-17 2022-09-27 巴斯夫欧洲公司 烷基葡糖苷和烷基木糖苷的混合物、其制备和用途
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ES2162050T3 (es) 2001-12-16
EP0822972B1 (fr) 2001-08-01
DE69614259D1 (de) 2001-09-06
DK0822972T3 (da) 2001-11-26
DE69614259T2 (de) 2002-05-02
US5928993A (en) 1999-07-27
CA2217241A1 (fr) 1996-10-31
ATE203763T1 (de) 2001-08-15
GR3036910T3 (en) 2002-01-31
SE9501581D0 (sv) 1995-04-28
SE506265C2 (sv) 1997-11-24
PT822972E (pt) 2001-12-28
EP0822972A1 (fr) 1998-02-11
SE9501581L (sv) 1996-10-29

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