WO1996003644B1 - Determination de la biodegradabilite de derives d'acide aspartique, chelates degradables et leurs utilisations et compositions - Google Patents
Determination de la biodegradabilite de derives d'acide aspartique, chelates degradables et leurs utilisations et compositionsInfo
- Publication number
- WO1996003644B1 WO1996003644B1 PCT/US1995/008809 US9508809W WO9603644B1 WO 1996003644 B1 WO1996003644 B1 WO 1996003644B1 US 9508809 W US9508809 W US 9508809W WO 9603644 B1 WO9603644 B1 WO 9603644B1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- distance
- chelate
- formula
- compound
- contacting
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title claims 4
- 150000001509 aspartic acid derivatives Chemical class 0.000 title 1
- 238000000034 method Methods 0.000 claims abstract 26
- 239000013522 chelant Substances 0.000 claims abstract 22
- 150000001875 compounds Chemical class 0.000 claims abstract 17
- 229910021645 metal ion Inorganic materials 0.000 claims abstract 7
- 238000004061 bleaching Methods 0.000 claims abstract 4
- 229910052751 metal Inorganic materials 0.000 claims abstract 4
- 239000002184 metal Substances 0.000 claims abstract 4
- 238000005406 washing Methods 0.000 claims abstract 4
- 239000002253 acid Substances 0.000 claims abstract 3
- 238000004140 cleaning Methods 0.000 claims abstract 3
- 230000008021 deposition Effects 0.000 claims abstract 3
- 238000007747 plating Methods 0.000 claims abstract 3
- 102000004190 Enzymes Human genes 0.000 claims abstract 2
- 108090000790 Enzymes Proteins 0.000 claims abstract 2
- 229910019142 PO4 Inorganic materials 0.000 claims abstract 2
- 238000006065 biodegradation reaction Methods 0.000 claims abstract 2
- 239000003054 catalyst Substances 0.000 claims abstract 2
- 230000006866 deterioration Effects 0.000 claims abstract 2
- 238000002845 discoloration Methods 0.000 claims abstract 2
- 238000005553 drilling Methods 0.000 claims abstract 2
- 239000007789 gas Substances 0.000 claims abstract 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims abstract 2
- 238000004519 manufacturing process Methods 0.000 claims abstract 2
- 235000015097 nutrients Nutrition 0.000 claims abstract 2
- 230000003647 oxidation Effects 0.000 claims abstract 2
- 238000007254 oxidation reaction Methods 0.000 claims abstract 2
- 239000003208 petroleum Substances 0.000 claims abstract 2
- 235000021317 phosphate Nutrition 0.000 claims abstract 2
- 150000003013 phosphoric acid derivatives Chemical class 0.000 claims abstract 2
- 229920000642 polymer Polymers 0.000 claims abstract 2
- 238000011084 recovery Methods 0.000 claims abstract 2
- 230000006641 stabilisation Effects 0.000 claims abstract 2
- 238000011105 stabilization Methods 0.000 claims abstract 2
- 239000004753 textile Substances 0.000 claims abstract 2
- 239000003599 detergent Substances 0.000 claims 7
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims 6
- 229910052802 copper Inorganic materials 0.000 claims 6
- 239000010949 copper Substances 0.000 claims 6
- 238000004768 lowest unoccupied molecular orbital Methods 0.000 claims 6
- 239000012530 fluid Substances 0.000 claims 4
- JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 claims 3
- 239000007864 aqueous solution Substances 0.000 claims 3
- 229910052799 carbon Inorganic materials 0.000 claims 3
- 239000000243 solution Substances 0.000 claims 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 3
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims 2
- 125000002877 alkyl aryl group Chemical group 0.000 claims 2
- 125000000217 alkyl group Chemical group 0.000 claims 2
- 125000003710 aryl alkyl group Chemical group 0.000 claims 2
- 125000003118 aryl group Chemical group 0.000 claims 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims 2
- -1 carboxyl hydroxy groups Chemical group 0.000 claims 2
- 150000001879 copper Chemical class 0.000 claims 2
- 229910001431 copper ion Inorganic materials 0.000 claims 2
- 239000001257 hydrogen Substances 0.000 claims 2
- 229910052739 hydrogen Inorganic materials 0.000 claims 2
- 239000000463 material Substances 0.000 claims 2
- 125000004430 oxygen atom Chemical group O* 0.000 claims 2
- VTLYFUHAOXGGBS-UHFFFAOYSA-N Fe3+ Chemical compound [Fe+3] VTLYFUHAOXGGBS-UHFFFAOYSA-N 0.000 claims 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 1
- 238000000367 ab initio method Methods 0.000 claims 1
- 229910052783 alkali metal Inorganic materials 0.000 claims 1
- 125000005210 alkyl ammonium group Chemical group 0.000 claims 1
- 125000003277 amino group Chemical group 0.000 claims 1
- 150000003863 ammonium salts Chemical class 0.000 claims 1
- CKLJMWTZIZZHCS-REOHCLBHSA-N aspartic acid group Chemical group N[C@@H](CC(=O)O)C(=O)O CKLJMWTZIZZHCS-REOHCLBHSA-N 0.000 claims 1
- 239000007844 bleaching agent Substances 0.000 claims 1
- 238000009835 boiling Methods 0.000 claims 1
- MMCOUVMKNAHQOY-UHFFFAOYSA-N carbonoperoxoic acid Chemical group OOC(O)=O MMCOUVMKNAHQOY-UHFFFAOYSA-N 0.000 claims 1
- 125000002091 cationic group Chemical group 0.000 claims 1
- 239000008139 complexing agent Substances 0.000 claims 1
- 229910001447 ferric ion Inorganic materials 0.000 claims 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims 1
- 150000003949 imides Chemical class 0.000 claims 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 1
- 239000003960 organic solvent Substances 0.000 claims 1
- LFGREXWGYUGZLY-UHFFFAOYSA-N phosphoryl Chemical group [P]=O LFGREXWGYUGZLY-UHFFFAOYSA-N 0.000 claims 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims 1
- 150000003839 salts Chemical class 0.000 claims 1
- 125000000472 sulfonyl group Chemical group *S(*)(=O)=O 0.000 claims 1
- 239000004094 surface-active agent Substances 0.000 claims 1
- 238000004458 analytical method Methods 0.000 abstract 1
Abstract
Des chélates représentés par la formule (Ib) sont jugés biodégradables quand une distance A varie entre 3,8 x 10-10 et 4,6 x 10-10m, une distance B varie entre 5,1 x 10-10 et 5,9 x 10-10m, et une distance C varie entre 4,3 et 6,7 x 10-10m. Des composés correspondant à ces critères sont qualifiés de composés de formule 2. Outre des procédés d'analyse et des systèmes informatiques nécessaires, l'invention concerne un procédé permettant la chélation d'un ion métal pour former un chélate et la biodégradation de ce chélate. Ce procédé consiste a) à mettre l'ion métal en contact avec au moins un composé de formule 2 pour former un chélate et b) à mettre le chélate résultant en contact avec des microbes du type précisé dans ASTM 2667-89 ou ISO 5815 ou avec leurs enzymes efficaces, dans des conditions et pendant une durée suffisante pour une biodégradation, de façon que 1) le chélate formé à l'étape a) le soit dans le cadre d'un processus d'élimination de dépôts, de tartre, ou de rouille; de nettoyage ou de lavage; de lutte contre une oxydation ou une détérioration commencée ou catalysée par un métal, y compris une dégradation, une décoloration ou un rancissement; dans un traitement pour textiles; la fabrication du papier; la stabilisation de polymères ou de phosphates; ou le forage, la production ou la récupération concernant le pétrole; ou bien de façon que 2) le chélate formé à l'étape a) soit utilisé avant l'étape b) comme catalyseur d'oxydo-réduction; dans un processus de blanchiment, blanchiment-fixage ou développement photographique; dans les dépôts ou placages chimiques; dans l'élimination de gaz contenant des acides ou des oxydes, y compris H¿2?S, NOx, SOx, CO et CO2; ou dans l'obtention de substances nutritives destinées à l'agriculture.
Priority Applications (7)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NZ290516A NZ290516A (en) | 1994-07-27 | 1995-07-14 | An analytical process using computer software for determining the biodegradability of aspartic acid derivatives; chelating a metal ion then biodegrading the chelate |
| JP50578596A JP3504668B2 (ja) | 1994-07-27 | 1995-07-14 | アスパラギン酸誘導体の生分解性の決定、生分解性キラント、それらの使用及び組成物 |
| CA002194184A CA2194184C (fr) | 1994-07-27 | 1995-07-14 | Determination de la biodegradabilite de derives d'acide aspartique, chelates degradables et leurs utilisations et compositions |
| DE69515671T DE69515671T3 (de) | 1994-07-27 | 1995-07-14 | Bestimmung der biodegradabilität von asparaginsäurederivaten, abbaubare chelatbildner, verwendungen und zusammensetzungen davon |
| EP95927158A EP0772771B2 (fr) | 1994-07-27 | 1995-07-14 | Determination de la biodegradabilite de derives d'acide aspartique, chelates degradables et leurs utilisations et compositions |
| AU31270/95A AU697099C (en) | 1994-07-27 | 1995-07-14 | Determining biodegradability of aspartic acid derivatives, degradable chelants, uses and compositions thereof |
| MX9700622A MX9700622A (es) | 1994-07-27 | 1995-07-14 | Determinacion de la bidegradabilidad de derivados de acido aspartico, quelantes degradables, usos y composiciones de los mismos. |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US28106094A | 1994-07-27 | 1994-07-27 | |
| US08/281,060 | 1994-07-27 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| WO1996003644A1 WO1996003644A1 (fr) | 1996-02-08 |
| WO1996003644B1 true WO1996003644B1 (fr) | 1996-02-29 |
Family
ID=23075779
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/US1995/008809 WO1996003644A1 (fr) | 1994-07-27 | 1995-07-14 | Determination de la biodegradabilite de derives d'acide aspartique, chelates degradables et leurs utilisations et compositions |
Country Status (8)
| Country | Link |
|---|---|
| US (2) | US5776763A (fr) |
| EP (2) | EP0772771B2 (fr) |
| JP (1) | JP3504668B2 (fr) |
| DE (1) | DE69515671T3 (fr) |
| ES (1) | ES2143060T5 (fr) |
| MX (1) | MX9700622A (fr) |
| NZ (1) | NZ290516A (fr) |
| WO (1) | WO1996003644A1 (fr) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0968658A1 (fr) * | 1998-07-02 | 2000-01-05 | Akzo Nobel N.V. | Additifs alimentaires pour animaux contenant l'acide éthylènediamine-disuccinique comme agent de chélation |
| WO2002010741A2 (fr) * | 2000-07-28 | 2002-02-07 | Lion Bioscience Ag | Modele de permeabilite de la region des intestins |
| AU2001278056A1 (en) * | 2000-07-28 | 2002-02-13 | Lion Bioscience Ag | System and method for predicting adme/tox characteristics of a compound |
| EP2013324A2 (fr) * | 2006-04-21 | 2009-01-14 | Dow Global Technologies Inc. | Formulations à efficacité de nettoyage inattendue contenant un chélateur biodégradable |
| MX324478B (es) | 2008-04-28 | 2014-10-14 | Dow Global Technologies Inc | Composicion lubricante de polialquilenglicol. |
| RU2687174C1 (ru) * | 2018-06-13 | 2019-05-07 | Федеральное государственное бюджетное образовательное учреждение высшего образования "Санкт-Петербургский государственный технологический институт (технический университет)" | Способ определения устойчивости органических полимеров к деградации, индуцируемой различными факторами |
| US11525086B2 (en) | 2019-05-06 | 2022-12-13 | Gpcp Ip Holdings Llc | Paper sheet mulches and methods of making the same |
Family Cites Families (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3158635A (en) * | 1959-03-18 | 1964-11-24 | Stauffer Chemical Co | Bis-adduction products and methods of preparing same |
| DK17885D0 (da) * | 1985-01-14 | 1985-01-14 | Karlsson Karl Anders | Antiviralt middel |
| US4704233A (en) † | 1986-11-10 | 1987-11-03 | The Procter & Gamble Company | Detergent compositions containing ethylenediamine-N,N'-disuccinic acid |
| US4855931A (en) * | 1988-03-25 | 1989-08-08 | Yale University | Stochastic method for finding molecular conformations |
| JPH02151650A (ja) * | 1988-12-02 | 1990-06-11 | Polyplastics Co | 熱可塑性ポリエステル樹脂組成物 |
| EP0431189A4 (en) * | 1989-06-30 | 1992-04-22 | Hitachi, Ltd. | Method of assisting material design and apparatus therefor |
| CA2002536C (fr) * | 1989-11-08 | 1996-02-20 | Peter H. Buist | Modele moleculaire dynamique |
| HUT65361A (en) * | 1989-12-29 | 1994-05-02 | Univ Technologies Int | Method for modelling tertiary structures of biologically active ligands including agonists and antagonists thereto and novel synthetic antagonists based on angiotensin |
| US5220055A (en) * | 1990-10-23 | 1993-06-15 | Nippon Shokubai Co., Ltd. | Process for producing aminocarboxylic acid salts |
| CZ90793A3 (en) † | 1990-11-14 | 1994-06-15 | Procter & Gamble | Preparations free of phosphates and with oxygen-containing bleaching systems for automatic dish washers, and process for preparing thereof |
| US5362412A (en) * | 1991-04-17 | 1994-11-08 | Hampshire Chemical Corp. | Biodegradable bleach stabilizers for detergents |
| US5208369A (en) * | 1991-05-31 | 1993-05-04 | The Dow Chemical Company | Degradable chelants having sulfonate groups, uses and compositions thereof |
| JP3086979B2 (ja) † | 1992-02-17 | 2000-09-11 | コニカ株式会社 | 漂白液または漂白定着液およびこれら処理液を用いてのハロゲン化銀カラー写真感光材料の処理方法 |
| DE4211713A1 (de) † | 1992-04-08 | 1993-10-14 | Basf Ag | Verfahren zur Herstellung von Aminodicarbonsäure-N,N-diessigsäuren |
| GB9216408D0 (en) † | 1992-08-01 | 1992-09-16 | Procter & Gamble | Stabilized bleaching compositions |
-
1995
- 1995-07-14 EP EP95927158A patent/EP0772771B2/fr not_active Expired - Lifetime
- 1995-07-14 DE DE69515671T patent/DE69515671T3/de not_active Expired - Lifetime
- 1995-07-14 MX MX9700622A patent/MX9700622A/es unknown
- 1995-07-14 ES ES95927158T patent/ES2143060T5/es not_active Expired - Lifetime
- 1995-07-14 EP EP99115425A patent/EP0959352A1/fr not_active Ceased
- 1995-07-14 NZ NZ290516A patent/NZ290516A/en not_active IP Right Cessation
- 1995-07-14 JP JP50578596A patent/JP3504668B2/ja not_active Expired - Lifetime
- 1995-07-14 WO PCT/US1995/008809 patent/WO1996003644A1/fr active IP Right Grant
-
1996
- 1996-03-04 US US08/607,253 patent/US5776763A/en not_active Expired - Lifetime
-
1997
- 1997-09-18 US US08/932,972 patent/US5854060A/en not_active Expired - Lifetime
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