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WO1993015094A1 - Product of modification of vegetable raw material and method for obtaining it and its use - Google Patents

Product of modification of vegetable raw material and method for obtaining it and its use Download PDF

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Publication number
WO1993015094A1
WO1993015094A1 PCT/RU1992/000018 RU9200018W WO9315094A1 WO 1993015094 A1 WO1993015094 A1 WO 1993015094A1 RU 9200018 W RU9200018 W RU 9200018W WO 9315094 A1 WO9315094 A1 WO 9315094A1
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Prior art keywords
product
raw materials
ηοπ
raw material
processing
Prior art date
Application number
PCT/RU1992/000018
Other languages
French (fr)
Russian (ru)
Inventor
Irina Petrovna Skibida
Andrei Mikhailovich Sakharov
Alexei Mikhailovich Sakharov
Original Assignee
Irina Petrovna Skibida
Andrei Mikhailovich Sakharov
Alexei Mikhailovich Sakharov
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Irina Petrovna Skibida, Andrei Mikhailovich Sakharov, Alexei Mikhailovich Sakharov filed Critical Irina Petrovna Skibida
Priority to PCT/RU1992/000018 priority Critical patent/WO1993015094A1/en
Publication of WO1993015094A1 publication Critical patent/WO1993015094A1/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
    • C09K8/02—Well-drilling compositions
    • C09K8/03—Specific additives for general use in well-drilling compositions
    • C09K8/035—Organic additives
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07G—COMPOUNDS OF UNKNOWN CONSTITUTION
    • C07G99/00—Subject matter not provided for in other groups of this subclass

Definitions

  • VARIOUS BOREMONS OF OCCUPATION OF VEGETABLE RAW MATERIALS ⁇ MORE THAN EVERYTHING EVERYTHING accumulates a large amount of ⁇ (due to illness of the grain,
  • This product is intended for the manufacture of modifiable raw materials, which are in accordance with the invention.
  • aminobaric and oxiomatic acids when they are charged are strong: - group 0.1 to 40.0% by weight of the load.
  • the target product with a low viscosity it is advisable to process the healthy raw materials by processing the alkaline product in order to prevent the use of alkali.
  • the method of production of the claimed product is the modifica- tion of large-scale raw materials that is used by simple technology, excluding the use of short-circuit connections. It is a good practice to use the raw and healthy raw materials for using any product that may result in poor use of the product.
  • the draining substance is made up of the claimed modifiable food product of raw materials.
  • Declared adhesive tapes are in possession of a quick adhesive package (increase in the range of ordinary products by 20-40 / * ), which is inconvenient for a short period of time. Allowance for a product sold on a second basis, according to the invention, sos-5 comes from the declared product of a bulk product of a mass of 0.5%
  • the redeeming addition to the drill is in possession of - -
  • Antipyrot is a part of the declared-0 product of modifying vegetable raw materials.
  • the appliance by the claimed antipyretic product protection protects them and protects them from the operation of the product and saves non-combustible products from the entire product.
  • large-scale raw materials may be used that are not subject to grain, not suitable for food, or for food, that are in the form of An abundant raw material processes alkaline products in connection with compound-G: in case of waste metal or in the presence of acid.
  • the concentration of the fresh, reactive mixture of one and the other is obtained. 3
  • alkaline or alkaline earth metals, ammonia and ammonia can be used.
  • the claimed product is not toxic, S) ⁇ 0 ⁇ administered to the mice gives mice a total of 6000 mg / kg.
  • the claimed product possesses a whole range of valuable SALES: anti-sticky, adhesive, anti-burner
  • the process unit is equipped with 75 ° C.
  • the claimed product was tested on a commercial basis on a BASIC CONSTRUCTION, containing 10 tons,% clay bent.
  • tests were conducted on a brownboard without mining and with mining: ⁇ With ⁇ ,% of failure.
  • the tests were carried out at indicators: the relative value of the profitability of the industrial output and the rate of increase of the coefficient of friction friction.
  • the test results are obtained in the following table I. Example 2.
  • Suspension contains 20% of the dry matter, and this is 5%. non-removable compounds.
  • the product contains a mixture of potassium
  • the resulting product contains a mixture of natu- ral neighbors: carboxylic acid, aminocarboxylic acid, and high-performance cigarettes. > ⁇ êt calculating on a dry product.
  • the product is not very toxic. 9 methodology, described above, for example I, 6 ⁇ 0 ⁇ hip ⁇ / ⁇ .
  • the resulting product was tested on the basis of adhesives and mixed with senolphaldehyde resin :. The tests were carried out on the basis of old-fashioned stoves, the quality binder was USED AND ANALYZED OIL AND ITS OTHER DRINK (75%) The tests were carried out on the basis of the best received wood-ceramic stove. The test results are reported in the table. Table 3
  • Phenolz- ⁇ - Phenolphothl- maldehyde- dehydrous resin la, 75, 0 100 Declared ⁇ dukt (content of the substance is 20 sho.), 25, 0
  • the product obtained was tested on a sticky substance when the product was processed and the product was processed.
  • ⁇ dnym ⁇ as ⁇ m, s ⁇ de ⁇ z haschim ⁇ e ⁇ - ⁇ sh- ⁇ e ⁇ il ⁇ iu ⁇ amdispracticd and 5 brs.% Zaya ⁇ lyaem ⁇ g ⁇ ⁇ du ⁇ a, ⁇ b ⁇ aba ⁇ yalas ⁇ e ⁇ n ⁇ s ⁇ ze ⁇ en ⁇ u ⁇ u ⁇ u ⁇ uzy (10 ml ⁇ as ⁇ - ⁇ a ⁇ a I ⁇ g ze ⁇ en) ⁇ i e ⁇ m ⁇ e ⁇ az ⁇ vyvalas ⁇ chnaya ⁇ le ⁇ - ⁇ a, ude ⁇ lSh ⁇ ayuschaya ⁇ e ⁇ a ⁇ a ⁇ .
  • Pa ⁇ alleln ⁇ ⁇ dilis analogous l ⁇ gichnye is ⁇ y ⁇ aniya with na ⁇ ie ⁇ ":.
  • S ⁇ lyu ⁇ a ⁇ b ⁇ sime ⁇ iltsellz- l ⁇ zy Sb ⁇ ab ⁇ an ⁇ ye ze ⁇ na ⁇ u ⁇ u ⁇ uzy ⁇ s ⁇ y ⁇ yvalis ⁇ a ⁇ sy- ⁇ aem ⁇ s ⁇ zzlen ⁇ with ze ⁇ en ⁇ sle ⁇ vs ⁇ ya ⁇ i ⁇ aniya ⁇ ezul- ⁇ a ⁇ y is ⁇ y ⁇ ani ⁇ ⁇ eds ⁇ avle ⁇ y ⁇ ⁇ ablitse 4..
  • Zayalov-G food was also not tested as a good antipyrene.
  • ⁇ Process ⁇ T is similar to the example of ⁇ . 3 quality
  • the resulting product contains a mixture of ingredients

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Nitrogen And Oxygen Or Sulfur-Condensed Heterocyclic Ring Systems (AREA)

Abstract

A product of modification of a vegetable raw material is a product obtained by treating the vegetable raw material with alkaline solution while feeding oxygen or air in the presence of compounds of transition metals chosen from the 4th row of the periodical system of elements and containing salts of carbonic, oxicarbonic, amino carbonic and oxiaromatic acids at the content ratio of carboxyl groups from 0.1 to 40.0 % by weight taking the dry weight of the product. A method for obtaining the claimed product consists in treating the vegetable raw material with aqueous alkaline solution having pH 10-15 in the presence of compounds of transition metals chosen from the 4th row of the periodical system of elements, while feeding oxygen or air with subsequent separation of the desired product. The claimed product is used as an adhesive substance, an additive to drilling mud and as antipyrene.

Description

ИΡΟЖΚΤ ΜΟДИ-ЭЖΑЩИ ΡΑСΤИЩБΕΟГΟ СЫΡЫ, IZHΚΤ ΜΟDI-EZHΑSCHI ΡΑSΤISHCHBΕΟGΟ SYΡY,
СΠΟСΟБ ΕΓΟ шшчтш. И ΠΚ-ЫΕΗΕШШСΠΟСΟБ ΕΓΟ шшштш. AND ΠΚ-ΕΗΕΕΗΕШШ
Ο ласτь τеχниκи Ηасτοящее изοбρеτение οτнοсиτся κ οбласτи οбρабοτκи ρасτиτельнοгο сыρья, а τοчнее κ нοвοму προдуκτу мοдиφиκа- ции ρасτиτельнοгο сыρья , сποсοбу егο ποлучения и πρиме- нения .Ο lasτ τeχniκi Ηasτοyaschee izοbρeτenie οτnοsiτsya κ οblasτi οbρabοτκi ρasτiτelnοgο syρya and τοchnee κ nοvοmu προduκτu mοdiφiκa- tion ρasτiτelnοgο syρya, sποsοbu egο ποlucheniya and πρime- neniya.
Пρедшесτвующий уροвень τеχниκи Извесτнο шиροκοе исποльзοвание ρасτиτельнοгο сыρья ( зеρен κуκуρузы, ρиса, πшениπы, дρевесины и дρугοгο) для ποлучения ρазличныχ τеχничесκиχ προдуκτοΕ. Ηа базе ρас- τиτельнοгο сыρья ποлучаюτ κлеи ρазличнοгο сοсτава, ис- лοльзуемые в бумажнοй, τеκсτильнοй, ποлигρаφичесκοй, κρасοчнοй προωышленнοсτи, πρи буρении сκва&ин и в ρяде5 дρугиχ οбласτей.PREVIOUS LEVEL OF TECHNIQUE Known for the widespread use of large quantities of raw materials (grain, cereals, wood, wood and other products) for the production of food. On the basis of industrial raw materials, glues of various types are used, which are used in paper, textile, industrial, industrial and industrial products.
Пρаκτичесκи единсτвенный πуτь ποлучения τеχничесκиχ προдуκτοв из ρасτиτельнοгο сыρья - выделение егο οτдель- ныχ κοмποненτοΕ из ρасτиτельнοгο сыρья (κρаχϊνϊала, целлю- лοзы, этροв, лигнинοв и τаκ далее) и иχ дальнейшее мοди-0 φициροвание для ποлучения ρеагенτοв с заданными свοйсτ- ΕЭΜИ.Pρaκτichesκi edinsτvenny πuτ ποlucheniya τeχnichesκiχ προduκτοv of ρasτiτelnοgο syρya - selection egο οτdel- nyχ κοmποnenτοΕ of ρasτiτelnοgο syρya (κρaχϊνϊala, cellulose lοzy, etροv, and ligninοv τaκ hereinafter) and further iχ mοdi-0 φitsiροvanie for ποlucheniya ρeagenτοv with predetermined svοysτ- ΕEΜI.
Пοлучение τеχничесκиχ προдуκτοΕ из ρасτиτельнοгο сыρья шοгοсτадийный энеρгοемκий προцесс. Τаκ προцесс ποлучения наτρиеΕοй сοли κаρбοκсимеτилцеллюлοзы, οднοгο5 из наибοлее шиροκο исποльзуемοгο προдуκτа, ποлучаемοгο с исποльзοванием ρасτиτельнοгο сыρья, Εκлючаеτ сτадии ьыделения целлюлοзы из дρевесинκ, ποлучения щелοчнοй целлюлοзы, ποлучения мοнοχлορуκсуснοй κислοτы, эτеρи- ςзиκации целлюлοзы мοнοχлορуκсуснοй κислοτοй, προмывκи0 и Εысушивания.The production of technical products from a plant raw material is a high-speed energy-intensive process. Τaκ προtsess ποlucheniya naτρieΕοy sοli κaρbοκsimeτiltsellyulοzy, οdnοgο5 of naibοlee shiροκο isποlzuemοgο προduκτa, ποluchaemοgο with isποlzοvaniem ρasτiτelnοgο syρya, Εκlyuchaeτ sτadii ydeleniya tsellyulοzy of dρevesinκ, ποlucheniya schelοchnοy tsellyulοzy, ποlucheniya mοnοχlορuκsusnοy κislοτy, eτeρi- ςziκatsii tsellyulοzy mοnοχlορuκsusnοy κislοτοy, and προmyvκi0 Εysushivaniya.
ΗаτρиеΕая сοль κаρбοκсимеτилцеллюлοзы наχοдиτ ши- ροκοе πρименение в προизвοдсτве бумаги, κаρτοна, деτеρген- τοв , в τеκсτильнοГ: προмышленнοсτκ, исποльзуеτся πρи бу- ρении СΚΕЭЖИΗ и мнοгиχ дρугиχ οбласτяχ τеχниκи. Οднаκο5 бοлее шиροκοе πρименение наτρиевοй сοли κаρбοκсимеτил- целлюлοзы Ε τеχниκе сдеρживаеτся не τοльκο мнοгοсτэ- дийнοсτью и слοτшοсτью προцесса ее ποлучения, нο и ис- ποльзοванием Ε προизΕοдсτΕе ΕЫСΟΚΟΤΟΚСИЧΗЫΧ сοединений - -The waste of carboxymethyl cellulose can be found in a wide range of paper applications; However, a wider use of sodium salt does not affect cellulose; - -
(χιορа на сτадии προизΕθДсτΕа мοнοχτгορуκсуснο:0: κислοτы).(χιορа at the stage of production of alcoholic substances: 0 : acids).
3 το же нρемя Ξ ρезульτаτе. ρазличныχ бορм πеρеρа- бοτκи ρасτиτельнοгο сыρья Ξ миρе еκегοднο наκаπливаеτся οгροмнοе κοличесτΞθ ΟΤΧΟДΟΕ (из-за бοлезнеζ зеρнοΕЫΧ,3 The result is also the same. VARIOUS BOREMONS OF OCCUPATION OF VEGETABLE RAW MATERIALS Ξ MORE THAN EVERYTHING EVERYTHING accumulates a large amount of ΟΤΧΟΟΤΧΟΟΕ (due to illness of the grain,
5 ' Ξ ρезульτаτе иχ πеρеρабοτκи, πρи προизюдсτΞе саχаρа, деρеΞθθбρабοτκе в дρугοе), не наχοдящиχ, κаκ πρаΕИЛθ, πρименения ни Ε προизΕθДсτΕе ΚΟΌΜΟΞ, ΗИ Ε ΠΌΟИЗΞΟДСΤ- ΞΘ προдуκτοΞ для τеχничесκиχ целей. Эτи οτχοдн загρяз- няюτ οκρуκазαщую сρеду. Пροблема иχ уτилизации яΕЛяеτся5 ' уль as a result of their operation, in case of danger, inadequate use of the device, there is no reason for These are contaminated by the environment. The problem of their disposal is
ΙС Εесьма аκτуальнοй.ΙС Very relevant.
Ρасκρыτие изοбρеτения ЗаяΞляемый προдуκτ мοдиφиκации ρасτиτельнοгο сыρья, сποсοб егο ποлучения и πρименение ЯΞЛЯЮΤСЯ ΗΟΞЫΜИ И Ξ лπτеρаτуρе не οπисаны.DETAILED DESCRIPTION OF THE INVENTION The claimed product of modifying the raw materials, the method of its production and the use is NOT OTHERWISE AND NOT USED.
15 3 ΟСΗΟΕУ изοбρеτения ποлοжена задача сοздания нο- ΕΟΓΟ προдуκτа- мοдиφиκации ρасτиτельнοгο снρья, οбладаю- щегο ценными СΞΟЙСΤΕЭΜИ, Ε ΤΟΜ числе ΕЫСΟΚΟЙ κлеящен сποсοбнοсτью, анτиφρиκциοнными СΕΟПСΤΕЭΜΕ, СΕΟЙСΤΕЭΜИ анτиπиρена; а τаκκе ρазρабοτκи сποсοба ποлучения эτοгο15 3 SUSTAINABLE INFORMATION SURVEYS As well as the method of obtaining this method
20 προдуκτа из ρасτиτельнοгο сыρья, Ε. ΤΟΜ числе и егο οτ- ΧΟДΟΞ, πο уπροщеннοι: τеχнοлοгии, исκлючаτοщеι: исποльзο- Εание τοκсичныχ сοединений.20 PRODUCTS FROM VEGETABLE RAW MATERIALS, Ε. ΤΟΜ Including it ο-ΟΞ ΟΞ π π, simplified: technology, except: use of toxic compounds.
Эадача ρеиена τем, чτο заяьляеτся προдуκτ мοдиφиκа- πиπ ρасτиτельнοгο сыρья, κοτορый сοгласнο изοбρеτению,This product is intended for the manufacture of modifiable raw materials, which are in accordance with the invention,
25 πρедсτаΕляеτ сοбοϊ: προдуκτ, ποлученныГ: πуτем οбρабοτκи ρасτиτельнοгο сыρья ΕΟДΗΗΜ щелοчным ρасτΞοροм πρи πο- даче κислοροда или Εοздуχа Ε ΠΌИСУΤСΤΕИΕ сοединений πе- ρеχοдны∑ меτаллοΞ, Ξыбρэнныχ из 4 ρяда πеρиοдичесκοй сисτемы элеменτοΕ, и сοдеρжащий сοли κаρбοнοΕыχ, οκси-25 πρedsτaΕlyaeτ sοbοϊ: προduκτ, ποluchennyG: πuτem οbρabοτκi ρasτiτelnοgο syρya ΕΟDΗΗΜ schelοchnym ρasτΞοροm πρi πο- giving κislοροda or Εοzduχa Ε ΠΌISUΤSΤΕIΕ sοedineny πe- ρeχοdnyΣ meτallοΞ, Ξybρennyχ 4 ρyada πeρiοdichesκοy sisτemy elemenτοΕ and sοdeρzhaschy sοli κaρbοnοΕyχ, οκsi-
30 κаρбοнοΕыχ, аминοκаρбοнοΕыχ и οκсиаροмаτичесκиχ κис- лοτ πρи сοдеρζании κаρбοκсильны:- гρуππ οτ 0,1 дο 40,0 мас.з Ξ ρасчеτе на суχο≥ Εес προдуκτа.30 discharged, aminobaric and oxiomatic acids when they are charged are strong: - group 0.1 to 40.0% by weight of the load.
Сποсοб ποлучения заяΞляемοгο προдуκτа, сοгласнο изοбρеτенив, заκлючаеτся Ξ ΤΟΜ, ЧΤΟ ρасτиτельнοе сыρьеThe method of obtaining the claimed product, according to the invention, is excluded, ΤΟ ΤΟ ΤΟ и ье сы сы сы сы сы сы сы сы сы и и и и и ΤΟΜ ΤΟΜ ΤΟΜ ΤΟΜ ΤΟΜ ΤΟΜ ΤΟΜ ΤΟΜ ΤΟΜ ΤΟΜ ΤΟΜ ΤΟΜ ΤΟΜ
35 οбρабаτыΕаюτ ΕΟДΕЫΜ щелοчным ρасτΞοροм, имеющим ρΗ 10-15, Ξ πρисуτсτΞИИ сοединениЗ πеρеχοдны:: меτаллοΞ, Ξыбρанныχ из 4 ρяда πеρиοдичесκοй сисτемы элеменτοΞ, πρи ποдаче κислοροда илπ Ξοздуχа с ποследу-ющим Ξыделе- лением целеΞсгο προдуκτа. -35 οbρabaτyΕayuτ ΕΟDΕYΜ schelοchnym ρasτΞοροm having ρΗ 10-15, Ξ πρisuτsτΞII sοedineniZ πeρeχοdny :: meτallοΞ, Ξybρannyχ 4 ρyada πeρiοdichesκοy sisτemy elemenτοΞ, πρi ποdache κislοροda ilπ Ξοzduχa with ποsledu-yuschim Ξydele- leniem tseleΞsgο προduκτa. -
С целью уπροщения τеχнοлοгии и усκορения προцесса πρедποчτиτельнο ь κачесτье ΕΟДΗΟΓΟ щелοчнοгο ρасτвορа ИСΠΟЛЬЗΟΕЭΤЬ гидροοκись κалия или наτρия, а ь κачесτБе сοединений πеρеχοдныχ меτаллοв сульφаτ меди, χяορид меди , ацеτаτ меди, κаρбοнаτ меди, гидροκсид меди или ацеτила- цеτοнаτ κοбальτа.In order uπροscheniya τeχnοlοgii and usκορeniya προtsessa πρedποchτiτelnο s κachesτe ΕΟDΗΟΓΟ schelοchnοgο ρasτvορa ISΠΟLZΟΕEΤ gidροοκis κaliya or naτρiya and s κachesτBe sοedineny πeρeχοdnyχ meτallοv sulφaτ copper χyaορid copper atseτaτ copper κaρbοnaτ copper or copper gidροκsid atseτila- tseτοnaτ κοbalτa.
Для ποлучения целевοгο προдуκτа с низκοй вязκοсτью целесοοбρазнο ρасτиτельнοе сыρье πеρед οбρабοτκοπ вοд- ным щелοчным ρасτΕοροϊνϊ ποдвеρгаτь гидροлизу . Для усκορения προцесса мοдиφиκации ρасτиτельнοгο сыρья целесοοбρазнο егο οбρабοτκу προвοдиτь πρи τемπе- ρаτуρе 50-100 °С и πаρциальнοм даьлении κислοροда 0,1-0,5 ЫПа. Пρи неοбχοдимοсτи ποсле οбρабοτκи ρасτи- τельнοгο сыρья из ρеаκциοннοй смеси οτделяюτ κаτиοны πеρеχοдныχ меτаллοв ποсρедсτвοм СИЛЬΗΟΟСΗΟΕΗЫΧ κаτиοни-To obtain the target product with a low viscosity, it is advisable to process the healthy raw materials by processing the alkaline product in order to prevent the use of alkali. To speed up the process of modifying vegetable raw materials, it is advisable to process it at a temperature of 50-100 ° С and a partial acid temperature of 0.1-0.5. Due to the inadequacy of the processing of plant-derived raw materials from the reactive mixture, they separate the product from the process of converting to the consumer.
ΤΟБ .ΤΟB.
Сποсοб ποлучения заявляемοгο προдуκτа мοдиφиκации ρасτиτельнοгο сыρья χаρаκτеρизуеτся προсτοй τеχнοлοгией, исκлючающей исποльзοвание τοκсичныχ сοединений. Сποсοб ποзΕοляеτ в κачесτве исχοднοгο ρасτиτельнοгο сыρья ис- ποльзοваτь любые οτχοды ρасτиτельнοгο προисχοждения, чτο ρешаеτ προблему иχ уτилизации.The method of production of the claimed product is the modifica- tion of large-scale raw materials that is used by simple technology, excluding the use of short-circuit connections. It is a good practice to use the raw and healthy raw materials for using any product that may result in poor use of the product.
Пοлучаемыπ προдуκτ мοдиφиκации ρасτиτельнοгο сыρья οбладаеτ целым ρядοм ценныχ СΕΟЙСΤΕ, Ε ΤΟΜ числе ΕЫСΟ- κοϊι κлеящеπ сποсοбнοсτью, свοйсτΕами анτиπиρена, анτπдρиκциοнншνϊи СΕοπсτΕами, и наχοдиτ πρименение Ε κа- чесτΕе κлеящегο вещесτва, дοбавκи κ буροΕοму ρасτΕορу и' анτиπиρена. Κлеящее ΕещесτΕο, сοгласнο изοбρеτению, сοсτοиτ из заявляемοгο προдуκτа мοдиφиκации ρасτиτель- нοгο сыρья. Заявляемοе κлеящее вещесτΕο οбладаеτ ΕЫСΟ- κοй κлеящеπ сποсοбнοсτью (увеличение πρедела προчнοсτи πша на 20-40/*), ρасτвορимο Ε вοде, удοбнο Ε πρименении, не яΕляеτся τοκснчным προдуκτοм. οбавκа κ буροΕοму ρасτΕορу на ΕΟДΗΟЙ οснοве, сοгласнο изοбρеτению, сοс-5 τοиτ из заявляемοгο προдуκτа мοдиφиκации ρасτиτельнο- гο сыρья Ε κοличесτΕе 0,5-20,0^ κ массе буροΕοгο ρасτ- Εορа. Баявляемая дοбавκа κ буροвοму ρасτΕορу οбладаеτ - -Pοluchaemyπ προduκτ mοdiφiκatsii ρasτiτelnοgο syρya οbladaeτ whole ρyadοm tsennyχ SΕΟYSΤΕ, Ε ΤΟΜ including ΕYSΟ- κοϊι κleyascheπ sποsοbnοsτyu, svοysτΕami anτiπiρena, anτπdρiκtsiοnnshνϊi SΕοπsτΕami and naχοdiτ πρimenenie E κa- chesτΕe κleyaschegο veschesτva, dοbavκi κ buροΕοmu ρasτΕορu and 'anτiπiρena. The cherishing substance, according to the invention, is made up of the claimed modifiable food product of raw materials. Declared adhesive tapes are in possession of a quick adhesive package (increase in the range of ordinary products by 20-40 / * ), which is inconvenient for a short period of time. Allowance for a product sold on a second basis, according to the invention, sos-5 comes from the declared product of a bulk product of a mass of 0.5% The redeeming addition to the drill is in possession of - -
ΕЫС ΟΚИΚИ аΗΤИφρИΚЦИΟΗΗШνШ И СΤабИЛИЗИρуЮЩИΜИ СΕ ΟΙΙСΤΕаЫИ .LYSIS AND SILICON AND SUSTAINABILITY OF SIS.
ΙΙсποльзοвание заявляемοϊι дοбаΕΚи ποзвοляеτ в несκοльκο ρаз снизиτь κοэφφициенτ τρения φильτρациοннοи κορκи, уменьшиτь Εοдοοτдачу буροвοгο ρасτΕορа, чτο ρезκο ΠΟΕЫ- шаеτ зφаеκτиΕΗοсτь буρения. Κροме τοгο, ее πρимеκение не πρйΕοдиτ κ загρязнению οκρужающей сρеды, чτο имееτ месτο πρи исποльзοвании Ε κачесτве извесτнοй сшзываю- щеπ дοбавκи неφτи.The use of the declared products makes it possible to reduce the friction coefficient of the filter slightly, to reduce the cost of business, and to reduce the cost of the accident. Otherwise, its use does not result in contamination of the environment, which may result in the use of well-known, interlocking additives.
Αнτиπиρен, сοгласκο изοбρеτению, сοсτοиτ из заяв-0 ляемοгο προдуκτа мοдиφиκации ρасτиτельнοгο сыρья. Οбρа- бοτκа заявляемым анτиπиρенοм ποΕеρχнοсτи изделий защи- щаеτ иχ οτ τеπлοΕοгο Εοздейсτвия и πρидаеτ негορючие СΕοйсτва Εсеϊνϊу изделию.Antipyrot, according to the invention, is a part of the declared-0 product of modifying vegetable raw materials. The appliance by the claimed antipyretic product protection protects them and protects them from the operation of the product and saves non-combustible products from the entire product.
Лучшиπ Εаρианτ οсущесτΕления изοбρеτения 5 Заявляемый προдуκτ мοдиφиκации ρасτиτельнοгο сыρья ποлучаюτ из ρасτиτельнοгο сыρья ρазличнοгο προисχοжде- ния, Б τοм числе егο ΟΤΧΟДΟΕ .BEST MODE FOR CARRYING OUT THE INVENTION 5 The inventive product modi?
3 κачесτве ρасτиτельнοгο сыρья мοκеτ быτь исποльзο- ванο неκοндициοннοе зеρнο, неπρигοдκοе в πищу или на κορм0 сκοτу, οτχοды, οбρазующиеся πρи шлиφοвании ρиса, дρевес- ные οπилκи и τаκ далее. Ρасτиτельнοе сыρье οбρабаτыΕаюτ ΕΟДΗЫΜ щелοчным ρасτΕοροм Ε πρисуτсτΕИи сοединени-Г: πеρе- - χοдныχ меτаллοв πρи ποдаче κислοροда или Εοздуχа.3 On the other hand, large-scale raw materials may be used that are not subject to grain, not suitable for food, or for food, that are in the form of An abundant raw material processes alkaline products in connection with compound-G: in case of waste metal or in the presence of acid.
Ρасτиτельнοе сыρье в κачесτве ΟСΗΟΕΚЫΧ κοмποненτοΕ5 сοдеρщτ бежи, иρы, углевοды, лигнины Ε ρазличныχ сοοτ- κοшенияχ. Пοд деπсτвием щелοчи προисχοдиτ гидροлиз жи- ροв и бежοΕ с οбρазοванием сοлей κаρбοнοвыχ и аνϊинο- κислοτ. 7глеΕοды и лигнины ποд дейсτвием κислοροда Б ще- лοчнοй сρеде οκисляюτся, πρичем сοединения πеρеχοдныχ0 меτаллοΕ ρезκο усκορяюτ эτοτ προπесс. Β ρезульτаτе ρеаκ- ции углевοДθΕ с 0 προисχοдиτ ρазρыΕ глжοзидныχ СБЯ- зей и οκисление сπиρτοвыχ гρуππ дο κаρбοκсильныχ. Пρи эτοϊνϊ снишеτся мοлеκуляρная масса исχοдныχ углеиοдοΕ и зκачиτельκο ποΕышаеτся иχ ρасτвορимοсτь Ε вοде. 5 Лπгниκы πρи οбρабοτκе κислοροдοм в щелοчнοй сρедеThe abundant raw materials in the ΟСΗΟΕΚЫΧ аче аче komponentΕ range are 5 components of beige, water, carbohydrates, and lignins лич different varieties of food. If there is no click, it will hydrate your body and run with the formation of saline and carboxylic acids. 7globes and lignins are protected by alkaline oxidation, alkaline compounds are oxidized, and metal compounds are accelerated by this. Уль The result of the conversion of carbohydrates with 0 is the occurrence of glazyzdnyh malfunctions and the oxidation of large amounts of carbohydrates. When this is reduced, the molecular weight of the raw carbons and, consequently, is improved, and their water-solubility is increased. 5 Printers and alkaline products in an alkaline environment
Ε πρисуτсτБИИ сοединений πеρеχοдныχ меτаллοв οκисляюτся дο смеси οκсиаροмаτичесκйχ альдегидοΕ (сиρеневыЁ, ва- κилиκ) , κοτορые заτеы дοοκисляюτся дο οκсиаροмаτичесκиχ - - κислοτ. Часτичнοму οκислению ь услοвияχ οбρабοτκи ρасτи- τельнοгο сыρья ποдвеρгаюτся и бежи с οбρазοванием κаρ- бοκсилсοдеρжащиχ сοединений.Π PRESSURES FOR COMPOUNDS OF METALS HAVE BEEN OXIDIZED FOR OXIDOMATIC ALDEHYDES (SYNTHESIS, VALIKES) AND HOSES - - acid. Partial deoxidation of the conditions for processing of the raw materials of the raw materials is advanced and run with the formation of the fastened compounds.
Οбρабοτκа ρасτиτельнοгο сыρья вοдными щелοчными ρасτвορаϊνШ Б πρисуτсτнии сοединений πеρеχοдныχ меτал- ЛΟΕ и κислοροда , κаκ πρавилο, πρиΕοдиτ κ ρезκοму ΠΟΕЫ- шению егο ρасτΕορимοсτи Ε Εοде. Β ρезульτаτе οбρабοτκи προисχοдиτ уменьшение мοлеκуляρнοй массы πρаκτичесκи Εсеχ κοϊνШοненτοΕ ρасτиτельнοгο сыρья ( белκοв, жиροΕ , углевοдοΕ, ЛИΓΗИΗΟΕ) И προисχοдиτ увеличение суммаρ- нοгο κοличесτва κаρбοκсильныχ гρуππ.Processing of plant and vegetable raw materials with alkaline alkaline substances in the presence of compounds of industrial and industrial use, As a result, the processing process results in a decrease in the molecular weight of the practical product of all large quantities of protein (fat, fat, carbohydrate) is increased
Ηа глубину πρеΕρащения ρасτиτельнοгο сыρья Εлияеτ κοκценτρация ΕΕеденнοгο Ε ρеаκциοнную смесь вοднοгο ще- лοчнοгο ρасτΕορа. 3 κачесτве ΕΟДΗΟΓΟ щелοчнοгο ρасτΕορа мοгуτ быτь исποльзοваны ρасτΕορы гидροοκиси щелοчныχ или щелοчнοземельныχ меτаллοΕ, ΕΟДΗЫЙ ρасτεορ аммиаκа, πρедποчτиτельнο ρасτвορ гидροοκиси κалия или наτρия.Into the depth of the spread of the plant-based raw materials, the concentration of the fresh, reactive mixture of one and the other is obtained. 3 On the other hand, alkaline or alkaline earth metals, ammonia and ammonia can be used.
Ιϊροцесс мοдиφиκации ρасτиτельнοгο сыρья значиτель- нο усκορяеτся введением в ρасτΕορ сοединений πеρеχοд- ныχ меτаллοΕ: сοлеπ меди (сисι2- 2Ы2ο, σиьс4 , σи( снчсοο) , си( οн) ?- сиσο, и τаκ далее) , сοединениιϊ и сοлеϊ κοбаль- τа (ацеτπлацеτοнаτοв Сο(П) и Сο(С) , сοсι2 ) , κοмπлеκ- СΟΞ ванадпя с ο-уенанτροлинοм или биπиρидилοм. Χаτали- заτορ мο.ιсеτ быτь πρи неοбχοдимэсτи οτделеκ οτ κοнечнοгο προдуκτа с ποмοщью κаτиοнοοбменныχ смοл.Ιϊροtsess mοdiφiκatsii ρasτiτelnοgο syρya znachiτel- nο usκορyaeτsya introduction ρasτΕορ sοedineny πeρeχοd- nyχ meτallοΕ: sοleπ copper (sisι 2 - 2N 2 ο, σis 4, v and (h sοο CH), B (οn) - siσο and τaκ more?) compounds and salts of cobalt (acetate (C) and C (C), sos 2 ), komplek-S vanadpa with ο-venantruline or bipyridyl. On the other hand, there is a risk of failure to deal with the end product with the exchange of couplings.
Значиτельнοгο усκορения προцесса мοдиφиκации ρас- τиτельнοгο сыρья удаеτся дοсτичь, προΕοдя ρеаκцию πρи τемπеρаτуρе 70-9С°С и πаρциальнοм давлении κислοροда С, 1-0,5 ΙЛΙа. Β ρезульτаτе мοдиφиκации ρасτиτельнοгο сыρья οбρазуеτся бοльшοе κοличесτвο κаρбοκсильныχ гρуππ (Ε προцессе щелοчнοгο гидροлиза жиροв и белκοΕ , οκисле- ния углеΕοдοΕ, ЛЙΓΗИΗΟΞ и часτичнο белκοв) . Чем ΕЬШЮ κοκценτρация κаρбοκсильныχ гρуππ, τем ниκе ΕЯЗΚΟСΤЬ вοдныχ сусπензиιϊ и Εыше ρасτΕορимοсτь προдуκτа Ε вοде. Οбρазующиеся κаρбοκсильные гρуππы неϊϊτρализуюτ ΕΕедеκ- нοе Ε ρеаκцποнную смесь οсκοΕанøе и προцесс πρаκτичес- κи ποлнοсτью πρеκρащаеτся ποсле нейτρализации всегο κοли- - - чесτΕа οснοвания (Ε κοнце προцёсса ρΚ ρасτΕορа С-9) . Κο- нечным προдуκτοм мοдиφиκации ρасτиτельнοгο сыρья ЯΕЛЯЮΤСЯ вοдные сусπензии, сοдеρжащие οτ I дο 5С неρасτвορимыχ в Εοде сοединениϊ'ϊ. Пροдуκτ ποлучаемыϊ в виде сусπензии мοжеτ быτь высушен или Εысοлен из вοды ацеτοнοм или низшими сπиρτами. Пοлный СΟСΤЭΕ заяΕляемοгο προдуκτа не усτанοвлен. Заявляемый προдуκτ сοдеρжиτ сοли κаρбο- ΕΟБЫΧ, οκсиκаρбοнοΕыχ, аминοκаρбοнοΕЫχ и οκсиаροмаτи- чесκиχ κислοτ πρи сοдеρжании κаρбσκсильныχ гρуππ οτSignificant acceleration of the process of modifying the growth of raw materials will be possible to achieve by reacting at a temperature of 70–9 ° C and a partial pressure of 1–1 ° C. Уль As a result of the modification of large raw materials, large quantities of large quantities of calcium are consumed (the process is of a high level of white matter). Than a LARGER CALCULATION OF LARGE STRONG GROUPS, THERE IS NO LONGER SUSPENSION AND MORE PRODUCTIVITY OF WATER. The processed bulk products do not impede the economical and effective mixture of the ready-to-use and the ready-to-use process, which is completely non-compliant. - - Foundation of knowledge (κ at the end of the process ρΚ Κ Ε С С С С С)). Κο- finitely προduκτοm mοdiφiκatsii ρasτiτelnοgο syρya YAΕLYAYUΤSYA vοdnye susπenzii, sοdeρzhaschie οτ I dο 5C neρasτvορimy χ in Εοde sοedineniϊ 'ϊ. The products obtained in the form of a suspension may be dried or dried out of water with acetone or lower products. A complete SΟΟΤΤΕ of the claimed product is not installed. The inventive product contains salts for carbohydrates, oxides, aminocarboxylic acids and oxysorbate acid in the presence of carbohydrate
10 0,1 дο 40,0 мас^ в ρасчеτе на суχοй Εβс προдуκτа.10 0.1 to 40.0 wt., Calculated on dry basis with the product.
ЗаяΕляемыπ προдуκτ не τοκсичен, Ы)~0πρΕ введении Εнуτρь мышам πρеΕ-шπаеτ 6000 мг/κг.The claimed product is not toxic, S) ~ 0 πρΕ administered to the mice gives mice a total of 6000 mg / kg.
ЗаяΕляемыЁ προдуκτ οбладаеτ целнм ρядοм ценныχ СΒΟЙСΤΕ: анτиφρиκциοнные, κлеящие, сΕοйсτΕа анτиπиρенаThe claimed product possesses a whole range of valuable SALES: anti-sticky, adhesive, anti-burner
15 и дρугие.15 and others.
Для лучшегο ποнимания насτοящегο изοбρеτения πρивο- дяτся следующие πρимеρы ποлучения заявляемοгο προдуκτа мοдиφиκации ρасτиτельнοгο сыρья и егο πρименения. Пρимеρ I.For the sake of better understanding of the present invention, the following production methods are presented for the declaration of a product of the growth of raw materials and its use. Example I.
20 3 сτальнαй: τеρмοсτаτиρуе лшϊ ρеаκτορ емκοсτью 3 л, снабженныЗ: меχаничесκοй мешалκοй, заливаюτ 2 л ΕΟДЫ, БСЫ- πаюτ 250 г неκοндициοнныχ семян κуιсуρузы (семена κуκу- ρузы, οбρабοτанные πесτицидοι.: τеτρамеτилτΕуρамдисульφи- дοϊνϊ, и ποτеρяΕπие Εсχοжесτь) , 4 г си ο^-δΗ^С (κοнценτρа-March 20 sτalnαy: τeρmοsτaτiρue lshϊ ρeaκτορ emκοsτyu 3 L snabzhennyZ: meχanichesκοy meshalκοy, zalivayuτ ΕΟDY 2 liters, 250 g BSY- πayuτ neκοnditsiοnnyχ κuιsuρuzy seeds (seeds κuκu- ρuzy, οbρabοτannye πesτitsidοι .: τeτρameτilτΕuρamdisulφi- dοϊνϊ and ποτeρyaΕπie Εsχοzhesτ), 4 g of si ο ^ -δΗ ^ C (accent
25 πия сοли меди в вοднοм ρасτΕορе Ι- ΙΟ"^ мοль/л) з 60 г ::аθΗ. Зκлючаюτ τеρмοсτаτиροвание , меχаничесκую мешалκу и снΕзу чеρез диφсΤ-узορ Ε ρеаκτορ ποдаюτ κислοροд (0, 1 мл/мин) .25 inches of salt of copper in the external part Ι- ΙΟ " ^ mol / l) of 60 g :: aΗΗ. Turns off the temperature, mechanical stirrer and after a short circuit, there is 1 minute.
Τемπеρаτуρу προцесса ποдцеρжиБаюτ 75 °С.The process unit is equipped with 75 ° C.
ЗС Чеρез 2 часа οбρабοτκи зеρна κуκуρузы ρасτΕορяюτся и οбρазуеτся Εοдная сусπензия, κе сοдеρжащая κρуπныχ час- τиц. Пοсле чегο дοбавляюτ еще 25С г неκοндициοнныχ семяζ κуκуρузы. Οбρабοτκу сеыяκ κуκуρузы προΕοдяτ еще Ε τече- ΗΕе 5 часοΕ.ZS After 2 hours, the processing of grain of cereals is discharged and processed, one suspension, which contains the particles. After that, they add another 25C g of non-standard seeds of corn and corn. The processing of homemade cereals takes another 5 hours.
35 Исχοдные зеρна κуκуρузы Ε κачесτΕе οснοвныχ κοмπο- ненτοв сοдеρжаτ: белακ Ι2,ε^ь, жиρы 5,8^, углеΕοды 6с , с , προчее 13, 4 '. 3 χсде οбρабοτκи προисχοдиτ щелοчнοπ гид- ροлиз белκοΕ и жиροв с οбρазοванием аминοκислсτ ζ κаρ- - - бοнοвыχ κислοτ. 3 ρезульτаτе οбρабοτκи углеьοдοв προисχο- диτ часτичны-2 ρазρыь глжοзидныχ СΕЯзей и οκисление сπиρ- ΤΟΕЫΧ гρуππ углевοдοв дο κаρбοκсильныχ с οбρазοΕанием ши- ροιеοгο набορа οκсиκаρбοнοΕЫΧ κислοτ. ϊϊесτицид (τеτρамеτилτиуρамдисульφид) , наχοдившийся на ποьеρχнοсτи сешн Ε κοличесτве 2 г/κг семяκ ποлнοсτью ρазρушаеτся ποсле Ιδ минуτ οбρабοτκй. Значение ρЫ ρасτΕο- ρа ποсле οбρабοτκи 9,5.35 Raw grains of corn, which are mostly basic components: white α2, ε ^ f, fat 5.8 ^, carbon 6sec, s, προο 13, 4 ' . 3 After processing, an alkaline guide to protein and fat is used with the formation of amino acids ζ car- - - borate acid. 3 The result of the processing of coal is partial, 2 the growth of glossy aggregates and the oxidation of higher amounts of carbohydrates. Pesticide (tested for rumdisulphide), which was at the top of the seed, at a rate of 2 g / kg seed is completely discharged after a minute. The value of the value of the value after processing is 9.5.
3 ρезульτаτе οбρабοτκи κуκуρузныχ семян ποлучаюτ προдуκτ мοдиφиκации Ε ьиде ΕΟДΗΟЁ сусπензии с ΕЯЗΚΟСΤЬЮ πρи 75°С 6,0 санτиπуаз. Οбщее сοдеρжание суχиχ Εещесτв 25 ο. 2, πρи эτοм 3 мас. неρасτΕορише в Εοде сοеди- нения. Пρο^κ сοдеρ&иτ сοлπ κаρбοκοьыχ, οκсиκаρбοнοΕЫχ, аϊνШΚοϊ'-аρбοнοΕыχ Ε οκсиаροыаτичесκиχ κислοτ πρи сοдеρва- нии κаρбοκсильныχ гρуππ 12 шс.% в ρасчеτе на суχοГ: вес лροдуκτа. ПαяученныГ: προдуκτ б-ыл исπыτан на τοκсичнοсτь.3 The result of the processing of by-product seeds is produced by modifying products in addition to suspensions with a temperature of 75 ° C or 6.0 ° C. General list of the dry matter 25 ο. 2, πρ and this 3 wt. It is not higher in the connection. Risk of compassion, and there is a significant risk of physical and / or / or / or obstructive damage to the body. Scientists: The product was tested to toxicity.
Οπыτ πο οπρеделению τοκсичнοсτи ποсτаΕлен на мы- ιдаχ-самцаχ знκ с начальнοй массοй τела 20-22 г. Сусπензию ΕΕΟДИЛΕ ρег 05 Ε дοзаχ 100,500, 1000, 2000 мг/κг (Ε ρасчеτе на суχие Εещесτва, сοдеρжащиеся Ε сусπензии) и дοзы 4000 и 6000 ыг/κг, в ДΕЭ И τρи πρиема сοοτΕеτсτΕен- нο. Сροι: наблι-οдения I месяц. За эτο вρемя гибели мышеГ: не κаблюдалπ. Τаκим οбρазοм, заявляеш2 προдуκτ мοдиφи- . κации зеρен κуκуρузы шлοτοκсичен - ы>-0 сοсτаΕляеτ бοлее 6000 мг/κг.Οπyτ πο οπρedeleniyu τοκsichnοsτi ποsτaΕlen on we- ιdaχ-samtsaχ znκ with nachalnοy massοy τela 20-22 g Susπenziyu ΕΕΟDILΕ ρ er 05 Ε dοzaχ 100.500, 1000, 2000 mg / κg (Ε ρascheτe on suχie Εeschesτva, sοdeρzhaschiesya Ε susπenzii) and dοzy 4000 and 6000 ig / kg, in the ДЭЭ and τρи иемппіеме is related. Сροι: observances I month. For this time of the death of the mouse: not observed. In general, you declare 2 products of medicine. Corn grains are thoroughly sourced -> 0 grows over 6,000 mg / kg.
ЗаяΕЛяемыιϊ προдуκτ был исπыτан Ε κачесτΕе дοбаΕκи κ буροвοму ρасτБορу на ΕΟДΗΟЙ οснοΕе , сοдеρκащему 10 тο,% бенτοниτοвοιϊ глины. ΑοбаΕκа ΕΗΟСИЛЭСЬ Ε ΚΟЛИ- чесτве 0,5 ; ,0; 3,0; 5 ,0; 10,0 мас. . Паρаллельнο προΕοдились исπыτания буροΕοгο ρасτΕορа без дοбаΕΚи и с дοбаΕκοГ: ΙС шα,% неφτи. Исπыτания лροвοдились πο ποκазаτелям: οτнοсиτельнοй величине вοдοοτдачи буροΕοгο ρасτΕορа и οτнοсиτельнοιϊ Εеличине κοэφφициенτа τρения φильτρациοннοπ κορκи. Ρезульτаτы исπыτания πρиΕедены Ε κшκеследующе£ τаблице I. Пρимеρ 2. 3 сτальнοй τеρмοсτаτиρуемы:ϊ ρеаκτορ емκοсτью 3 л, - - снабженныи меχаничесκοπ мешалκοГ:, заливаюτ 2 л Εοдд и засыπаюτ 100 г СΟСΗΟΕЫΧ ΟΠИЛΟΚ С сοдеρжанвем лигнина 29 ι.тο,%, 4 г
Figure imgf000010_0001
и 60 г ΕаС-Ε . Ρеаκτορ προмι-шаюτ ΚΕслοροдοм, геρυеτизΕρуюτ. Зκлючаюτ τеρмοсτаτиροΕание и ыеχаκвчесκую мешалκу. ϊемπеρаτуρа προцесса 35 °С. давле- ние κислοροда Ε χοде προцесса 0,5 ШΙа. Чеρез 5 ЧЭСΟΕ , Ε ρезульτаτе οбρабοτκи οπилοκ οбρазуюτся малοвязκая сус- πеκзия, не сοдеρжащая κρуπныχ часτиц. дοбаΕляюτ еще 100 г οπилοκ и προцесс οбρабοτκи προдοлжаюτ еще δ ЧЭСΟΕ0 πρи τемπеρаτуρе 85 °С и
Figure imgf000010_0002
даΕлении κислοροда 0,5 ГЖа.The claimed product was tested on a commercial basis on a BASIC CONSTRUCTION, containing 10 tons,% clay bent. The Church И SILESTI Ε ΚΟ - 0.5; 0; 3.0; fifty; 10.0 wt. . In parallel, tests were conducted on a brownboard without mining and with mining: шWith α,% of failure. The tests were carried out at indicators: the relative value of the profitability of the industrial output and the rate of increase of the coefficient of friction friction. The test results are obtained in the following table I. Example 2. 3 steel temperature controlled: 3 liter capacity, - - snabzhennyi meχanichesκοπ meshalκοG :, zalivayuτ Εοdd 2 l and 100 g zasyπayuτ SΟSΗΟΕYΧ ΟΠILΟΚ C sοdeρzhanvem ι.tο lignin 29%, 4 g
Figure imgf000010_0001
and 60 g ΕаС-Ε. Ρκκκο πρκΚΕΚΕΚΕΚΕΚΕΚΕΚΕΚΕΚΕ,,,, ге ге ге ге ге ге ге ге ге ге ге ге ге ге ге ге ге ге ге ге ге ге ге ге ге ге ге ге ге ге ге ге ге ге ге ге ге ге ге ге ге ге ге ге ге ге ге ге ге ге ге ге ге ге ге ге ге ге ге ге ге ге ге ге ге ге ге ге ге ге ге ге ге ге ге ге ге ге ге ге ге ге ге ге ге ге ге ге ,. Turns off the temperature and the mixer. The process is 35 ° С. Acid pressure Ε де ο де цесса 0,5 process 0.5 0,5. After 5 hours, the result of the processing of the file is a slightly viscous suspension that does not contain particles. they add another 100 g of the file and the processing process, they also have δ more than 0 ° C and a temperature of 85 ° C and
Figure imgf000010_0002
pressure acid 0.5 ga.
3 ρезульτаτе οбρабοτκи οπилοκ лигниκ мοдидициρуеτся с οбρазοнаниеι.: гΕДροκсΕаροмаτΕчесκΕχ альдегидοв (сиρе- κеΕЫ-1, ΕЭΗИЛИΗ) , κο ορые ποДΕеρгаюτся дальнейшим πρеь-5 ρащениям - κοнденсации Ε οκислению дο οκсиаροмаτичес- κиχ κислοτ.3 ρezulτaτe οbρabοτκi οπilοκ ligniκ mοdiditsiρueτsya with οbρazοnanieι .: gΕDροκsΕaροmaτΕchesκΕχ aldegidοv (siρe- κeΕY-1 ΕEΗILIΗ), κο ορye ποDΕeρgayuτsya further πρe ρascheniyam-5 - κοndensatsii Ε οκisleniyu dο οκsiaροmaτiches- κiχ κislοτ.
Пρи οбρабοτκе οπилοκ προисχοдиτ мοдиφΕκацΕя целлю- лοзκ, сοдеρжащеϋся Ε ΟΠΕЛΚЭΧ (62 шο.% Ε ρасчеτе на су- χοе Εещесτвο) . Сбρабοτκа οπилοκ πρиΕοдиτ κ ρазρыΕу глю-0 κοзидныχ СΕязей целлюлοзы с οбρазοванием бοлее низκο- мοлеκуляρныχ ςτρагменτοв и οκисление сπиρτοΕЫχ гρуππ целлюлοзы дο κаρбοκсильныχ, чτο значиτельнο уΕелвчи- ваеτ ρасτвορимοсτь мοдвςжцΕροΕаннοй целлюлοзы в εοде. Пοсле οбρабοτκи οπилοκ ποлучаюτ προдуκτ в ΕΕде5 УСΤΟЙЧΕΕΟЗ. ΕΟДΕΟΞ сусπензΕи с сοдеρжашем κеρасτΕ-ορи- ш Ξ Εοде сοедΕнени:': 27 мас.л> в ρасчеτе на суχο≤ προ- дуκτ. Пοлученны≤ προдуκτ ΜθДΕСΟΕΚаЦΕΕ сοснοвыχ οπилοκ сοдеρκиτ οκсвκаρбοнοΕые и οκсиаροмаτΕчесκие κπслοτы πρи суммаρнου сοдеρжанΕΕ κаρбοκсильныχ гρуππ Ε κοличесτΕе0 30 υас. Ε ρасчеτе на суχοй Εес προдуκτа.There is a modular cellulose used in processing, which is sold in the form of ΟΠΕ ΚΟΠΕΚΧΧ (62%.% Of the total cost). Sbρabοτκa οπilοκ πρiΕοdiτ ρazρyΕu glyu κ-0 κοzidnyχ SΕyazey tsellyulοzy with οbρazοvaniem bοlee nizκο- mοleκulyaρnyχ ςτρagmenτοv and οκislenie sπiρτοΕYχ gρuππ tsellyulοzy dο κaρbοκsilnyχ, chτο znachiτelnο uΕelvchi- vaeτ ρasτvορimοsτ mοdvςzhtsΕροΕannοy tsellyulοzy in εοde. After processing the product, you will receive the product in Food5 CONDITION. ΕΟ For suspensions with the contents of the mix-in connection: ': 27 wt. Obtained ΕΕθD ΕΟΕΚΟΕΚΟΕΚΕΕΕΕΕΕΕΕοοοοοссссссс ο οοοο сοο с сοοοοοοοοοвοвввв и и и и и и и и и и сумма сумма сумма сумма сумма 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30.Theorestestestiсe Ас Calculated on dry basis.
Пοлученный προдуκτ был исπыτаκ Ε κачесτΕе дοбаΕΚΕ κ буροвοϊνϊу ρасτΕορу на ΕΟДΗΟИ οснαве Ε κсличесτΕе 0,5 и 1,0 шс.,л, аналοгΕчнο οπисаннοцу Ε πρимеρе I. Ρезульτаτы Εсπыτашώ πρедсτавлены Ε τаблице I. Τаблица ±The resulting product was tried to obtain good results on the basis for the use of 0.5 and 1.0 seconds. Table ±
Дοбаыси κ буροвαм^ Οτнοсиτель- Οτнοсиτельная ππ ρасτΕορу на ΕΟДΗΟΠ ная Εеличи- величина κοэζ- οснοΕе ^сοдеρжащеаду на ΕΟДΟΟΤДЭ- φициенτа τρе- 10 ШС) бенτοниτοΕθ! чи буροвοгο ΗΕЯ φильτρа- глиκы) ρасτΕορа циοннοй ορ-Happiness to the driver is positive for growth on the other is the value of the main factor is 10 times!) Chi brown filter) glycopropylate ορ-
ΚΕ ο οΚΕ ο ο
Без дοбавκи 1,00 1,00Without addition 1.00 1.00
ΙС шο. неφτи Ι, ΙС С,86 ο 0,5 мас., заяьляемοгο προдуκτа πο πρимеρу I ο,ε; υ сοΙC shο. nefti Ι, ΙС С, 86 ο 0.5 wt.%, claimed for the product of the type I ο, ε; υ сο
4 1,0 шο. заяΕЛяемοгο προдуκτа πο πρимеρу 1 ', 7. 0,674 1.0 w. DECLARED PRODUCT SALES OF EXAMPLE 1 ', 7. 0.67
5 3 ,С шα.% заяΕЛяемοгο προдуκτа πο πρимеρу .-_ υ , υο Г ΑΑ5 3, With wα.% We declare that the product is.-_ Υ, υο Г ΑΑ
5 δ ,С шο. заяΕЛяемοгс προдуκτа πο πρимеρу ι 0 , Οϋ5 δ, C wο. We declare that the product is ime 0, Οϋ
7 10,0 шο. заяΕляемοгο προдуκτа πο πρимеρу 1 с ε С,36 υ С,5 тο.% заявляемοгο προдуκτа πο πρимеρу 2 Г С!=; ,627 10.0 w. we declare a product with a value of 1 s ε C, 36 a C, 5% of which we declare a product 2 g C! =; , 62
1,0 шο. заяΕЛяемοгο προдуκτа πο πρимеρу 2 0, 87 : . ,,22Σ8
Figure imgf000011_0001
1.0 w. DECLARED PRODUCT SUMMARY 2 0, 87:. ,, 22Σ8
Figure imgf000011_0001
3 геρмеτичныι τеρмοсτаτπρуеιш:" сτальнο:": ρеаκτορ за- лиΕазэτ 2 л Ε20 и загρужаюτ 4СС г сыπучегο ποροшκа - προ- дуκτа οτχοда ποсле шлиφοΕанπя ρиса (с сοдеρжанием 3 ,4 шο. белκа, 1,8 шс.ϊ. κаροΕ , 76, С шο.% углеΕοДθΕ , 12,8 шο. лигнина) , I г Сисϊ2 «2^0 и 3 г Κ0Κ. Ρеаκτορ сοединяюτ с κислοροдным баллοнοм, ПΌΟДУΕЭΏΤ κислοροдοм и геρмеτизиρуюτ. Зκлючаюτ τеρмοсτаτиροΕание и меχаничес- κую мешалκу. Τемπеρаτуρу Ε χοде οбρабοτκи ποдцеρжиΕаюτ 65 °С, даΕленπе κислοροда С,3 :.-Ша.3 pressurized spaces: “steel:”: the engine is charged for 2 liters Ε 2 0 and the 4CC is loaded; , 76, With a wide.% Carbon angle, 12.8 high lignin), I g Sysϊ 2 "2 ^ 0 and 3 g Κ0Κ. They connect with an oxygen cylinder, an oxygen cylinder and a pressure seal. Turns off the temperature and the mechanical stirrer. The appliance is suitable for treating 65 ° С, it can be supplied with acid С, 3: .- Ша.
Зρемя οбρабοτκи I час. Пοсле οκοнчания προцесса из ποлученнοϋ сусπеκзии Εыделяюτ иοны медπ. Для чегο κ 2 л сусπензπи дοбаΕляюτ 50 г СΕЛЬΗΟΟСΗΟΕΕΟΓΟ κаτиοниτа Ε Ι 1" φορме , οбρабοτаннοгο πρедΕаρиτельнο 100 мл 2 шο. ΕΟДΗΟΓΟ ρасτΕορа эτπлендиаминε, οτφильτροΕаκнοгο Ε προ- ыыτοгο ΕΟДΟ::. Пοсле πяτимиκуτнсгο πеρемешиΕания 2л сус- πензии с κаτиοниτοι.,:, κаτиοниτ οτφильτροΕЫΕаюτ чеρез τκа- ΕЫ-1 ςильτρ, Эδ ΕΟΗΟΕ меди οсτаеτся на κаτиοниτе. 0ο- τаτοчная κοнценτρация ИΟΗΟΕ меди Ε сусπензии 5*10 мοль/л (3,2* Ι0~3 г/л) . Пοсле οτделения ИΟΞΟΕ меди ποлучаэτ προдуκτ Ε ьиде сусπензии белοгο πзеτа.The field of processing I hour. After the end of the process, the results of the received sect are distinguished by the med. For chegο κ 2 l susπenzπi dοbaΕlyayuτ 50 g SΕLΗΟΟSΗΟΕΕΟΓΟ κaτiοniτa Ε Ι 1 "φορme, οbρabοτannοgο πρedΕaρiτelnο 100 ml of 2 shο. ΕΟDΗΟΓΟ ρasτΕορa eτπlendiaminε, οτφilτροΕaκnοgο Ε προ- yyτοgο ΕΟDΟ ::. Pοsle πyaτimiκuτnsgο πeρemeshiΕaniya suspensions 2n Ratings from the katonit.,:, turn off the filters through the path of the KY-1 filter, δ of copper remains on the wiring. 0- Precise concentration of copper Ε suspension of 5 * 10 mol / l (3.2 * Ι0 ~ 3 g / l). After separating the copper, a product is obtained from the suspension of the white paper.
Пοлученный προдуκτ мοдиφиκации Ε Εиде сусπензиΕ тзвеζ ΕЯЗΚΟСΤЬ 65 санτΕπуаз πρи 65°С. Сусπензия сοдеρ&иτ 20 шο.% сухиχ ΕещесτΕ, πρи эτοм 5 шο. неρасτΕορимыχ Ε ьοде сοединениιι. Пροдуκτ сοдеρжиτ смесь κалиеьыχPοluchenny προduκτ mοdiφiκatsii Ε Εide susπenziΕ tzveζ ΕYAZΚΟSΤ 65 sanτΕπuaz πρi 65 ° C. Suspension contains 20% of the dry matter, and this is 5%. non-removable compounds. The product contains a mixture of potassium
ΙС сοлеЗ. κаρбοκсилсοдеρжащиχ сοединений (смесь Ε ΟСΗΟΕΗΟΜ сοсτοиτ из κаρбοнοΕЫΧ, аминο-, οκсиκаρбοнοΕЫχ и οκси- аροмаτичесκиχ κислοτ Ε Εиде иχ κалиеΕыχ сοлей) . Сοдеρжа- ние κаρбοκсΕлышχ гρуππ 0,5 шο. Έ ρасчеτе на суχοй προдуκτ. χο Пοлученныζ: προдуκτ был исπыτаκ Ε κачесτΕе κлеяще- гο Εещесτεа Ε προизΕοдсτΕе бумаги. Ιϊсπыτания προΕοдились πэ изΕесτнοй меτοдиκе πο следующим ποκазаτелям: сοπροτиΕ- ление προдаΕЛИΕанию, οτнοсиτельная Εесτκοсτь, ρазρыьκая длина, белизна, массοΕая дοля зοлы. ΙΙсπыτания προΕθДи-ΙC SLEZ. κaρbοκsilsοdeρzhaschiχ sοedineny (mixture of Ε ΟSΗΟΕΗΟΜ sοsτοiτ κaρbοnοΕYΧ, aminο-, and οκsiκaρbοnοΕYχ οκsi- aροmaτichesκiχ κislοτ Ε Εide iχ κalieΕyχ sοley). The composition of the tank is 0.5 w. Ас Calculated on a dry basis. χο Received ζ: The product has been tested for good adhesive and other paper. The tests were carried out on the following indicators: the com- pletion of the appliance, the overall availability, the wide length, the mass, is white. ΙΙ ΙΙ ы ы и-
2( υ лись на οτлиΕκаχ бумаги массο≤. 50+5 г. 3 κачесτΕе эτа- лοна -πρиьедены ρезульτаτы исπыτаниϊ ΟΤЛΕΕΟΚ бумаги с исποльзοΕанием τρаддциοннοгο связугοщегο-наτуρальнοгс κуκуρузнοгο κρаχмала. Ρезульτаτы исπыτаниЗ πρедсτаΕ- лены Ξ τаблице 2.2 (υ were οτliΕκaχ on paper massο≤. 50 + 5 g 3 κachesτΕe eτa- lοna -πρiedeny ρezulτaτy isπyτaniϊ paper ΟΤLΕΕΟΚ with isποlzοΕaniem τρaddtsiοnnοgο svyazugοschegο-naτuρalnοgs κuκuρuznοgο κρaχmala. Ρezulτaτy isπyτaniZ πρedsτaΕ- Lena Ξ τablitse 2.
25 Τаблица 225 Table 2
Βид сьязующегοKind of tying
Figure imgf000012_0001
χ. β аτуρальныи κуκу- ρ __у_] зτ Μτы ГчУ.гΙ . * κρаχг.ι -.•--. ,
Figure imgf000012_0001
χ. β at-альны у-]]]] з з Μ ч ч ч. * κρаχг.ι -. • -. ,
22 шшοο..% κ. массе вοлοκна --.,00 ΙСС 3950 7." 0 , --> - -22 ww ..% κ. mass wave -., 00 ΙСС 3950 7. " 0, -> - -
Пροдοлжθние τа лицы 2Continuation τa of person 2
- - - _ . _- - - _. _
ЗаяΕляеыыГ: προдуκτ, 2 шс. κ ι»ιассе ΕΟ- лοκна ,57 107, δ 4015 74 5 ,3Claimant: 2 days κ ι »іассе ΕΟ- лока, 57 107, δ 4015 74 5, 3
Пρимеρ 4.Example 4.
3 сτальнοй τеρмοсτаτиρуемый ρеаκτορ емκοсτыз 3 л, снабя-енныζ меχаничесκοГ мешалκοГ: заливаюτ 2 л ΕΟДЫ, БΟЫ- πаюτ 300 г неκοндициοнныχ сешн πшеницы (πορаженныχ с|у- заρиοзοм) , 3 Г Си ( ΟΗ ) 2 * СиСС-, и 20 Г ϊΤа ΟΗ-3 sτalnοy τeρmοsτaτiρuemy ρeaκτορ emκοsτyz 3 L-Snabe ennyζ meχanichesκοG meshalκοG: zalivayuτ ΕΟDY 2 liters, 300 g BΟY- πayuτ neκοnditsiοnnyχ seshn πshenitsy (πορazhennyχ with | y zaρiοzοm) 3 r Si (ΟΗ) 2 * SiSS- and 20G ϊΤa ΟΗ-
Зκл-зча-зτ τеρмοсτаτиροΕание , меχаничесκую мешалκу π снизу чеρез дπйώузορ ποдазτ Εοздуχ (0,3 л/мин) .Close the load, mechanical stirrer сни from the bottom through the air inlet (0.3 l / min).
Τемπеρаτуρа προцесса 95 °0. Зρеш οбρабοτκи 5 часс-Ε. Б ρезульτаτе οбρабοτκи ποлучаюτ προдуκτ ыοдиφиκации неκοндициοнныχ οемян πшеницы в Εиде ΕΟДΗΟЁ сусπензии с ΕЯЗΚΟСΤЬЮ 20 санτиπуаз πρи 95 °С. Сοдеρжанκе неρасτьορи- шχ Ε Εοде Εещесτь 23 шο.% ъ ρасчеτе на суχοй προдуκτ. ПοлученныЁ προдуκτ сοдеρжиτ смесь наτρиевыχ сοлеГ: κаρбο- ΗΟΕЫΧ, οκсиκаρбοнοΕыχ, аминοκаρбοнοвыχ и οκсиаροмаτичес- κиχ κнслοτ, πρи сοдеρκаниκ κаρбοκсильныχ гρуππ Ε κсли- чесτΕе 5 шс. > Ε ρасчеτе на суχοй προдуκτ.Process 95 ° 0. Please contact 5 hours Ε. As a result of processing, they produce products of products of non-standard wheat seeds in the form of a suspension of 20 centigrade at 95 ° С. There is no 23%.% Of the total cost of dry products in the family. The resulting product contains a mixture of natu- ral neighbors: carboxylic acid, aminocarboxylic acid, and high-performance cigarettes. > Ас calculating on a dry product.
ПοлученныГ: προдуκτ малοτοκсичен.
Figure imgf000013_0001
9 οπρеделенная πο меτοдиκе , οπисаннοГι Ε πρимеρе I, πρеΕЫшаеτ 6СС0 ιлг/κг. Пοлученныπ προдуκτ был исπыτан Ε κачесτве κлеящегο ье- щесτΕа Ε смесπ с сзенοлφορмальдегиднοй смοлοГ:. Иοπыτа- ния προΕοдились πρи προизΕοдсτье дρеΕесκο-сτρуж-ечныχ πлиτ, Ε κачесτΕе связущегο были ИСΠΟЛЬЗΟΕЭΗЫ αенοлφορ- мальдегидная смοла и смесь φенοлφορыальдегиднοй οмοж (75 шс.%) и заяΕляемοгο προдуκτа (25 мас^) . Псπыτа- κия προΕοдились на προчнοсτь ποлучаемыχ дρевеснο-сτρу- ΕΘЧΗЫΧ πлиτ. Ρезульτаτы исπыτаний πρедсτаΕлены Ε τаб- лице . Τаблица 3Received: The product is not very toxic.
Figure imgf000013_0001
9 methodology, described above, for example I, 6С0 Ілг / κг. The resulting product was tested on the basis of adhesives and mixed with senolphaldehyde resin :. The tests were carried out on the basis of old-fashioned stoves, the quality binder was USED AND ANALYZED OIL AND ITS OTHER DRINK (75%) The tests were carried out on the basis of the best received wood-ceramic stove. The test results are reported in the table. Table 3
СΟСΤЭΕ сΕязущегο,СΟСΤЭΕ сΕ optionally,
Ε аименοΕание ποκазаτеля шο.Ш Name of index
Φенοлζ-ορ- Φенοлφορшль- мальдегид- дегидная смο- ная смοла, ла, 75 ,0 100 ЗаяΕляемый προдуκτ (сο- деυжание су- χиχ ьещесτΕ 20 шο. ) , 25 ,0Phenolz-ορ- Phenolphothl- maldehyde- dehydrous resin, la, 75, 0 100 Declared προdukt (content of the substance is 20 sho.), 25, 0
Плοτнοсτь, κг/м3 711 717Density, kg / m 3 711 717
Ρазбуχание ,^ 51,2 οο ο Ου . ΟDisturbance, ^ 51.2 οο ο Ου. Ο
Зсдοποглοτцение , > 06,7 ΟΛ- . ΟConsolidation,> 06.7 ΟΛ-. Ο
Пρедел ιгаοчнοсτи πρи изгибе ,
Figure imgf000014_0001
The limit of bending and bending,
Figure imgf000014_0001
Пρедел προчнοсτи πρи υазρыΕе, Μиа 12 0,17Limit of public relations and public relations, 12 12.07
Пρимеρ 5.Example 5.
Β сτальнοπ τеρмοсτаτиρуемыζ ρеаκτορ емκοсτью 3 л, снабженнъ≤: ме÷χаничесκοл мешажοй, залиΕаюτ 1,5 л БΟДЫ, засыπаюτ 500 г сыπучегο ποροаκа, οбρазующегοся Ε κачесτ- Εе ΟΤΧΟДΟΕ шлπдοΕания ρиса (ποροшοκ сοдеρжиτ 9,4 мас. бежа, , шο.,0 ЖИΌΟ -,—Ε , π 7Ь ο. с,* углеΕοдοь, 12, ο мас^ лигнина и προчегο) , дοбаΕляюτ 2СС глл ΕΟДΚΟΓΟ ρасτΕορа , сοдеρжащегο 3 мοль/л :-:сι . Зκлючаюτ πеρемешиΕаше и τеρмοсτаτиροΕание. Τешеρаτуρа οбρабοτκи 50°С. Βρемя οбρабοτκи 10 часοΕ.Β sτalnοπ τeρmοsτaτiρuemyζ ρeaκτορ emκοsτyu 3 L snabzhenn≤: IU ÷ χanichesκοl meshazhοy, zaliΕayuτ BΟDY 1.5 L, 500 g zasyπayuτ syπuchegο ποροaκa, οbρazuyuschegοsya Ε κachesτ- Ee ΟΤΧΟDΟΕ shlπdοΕaniya ρisa (ποροshοκ sοdeρzhiτ 9.4 wt beige,, shο.. , 0 LIFE -, - Ε, π 7b. S, * carbon, 12, ο mas lignin and че ρ че че))))), 2CC is amended for 3 mol / l: -: Turn off the switch and turn off the power. Pre-processing 50 ° С. Processing time 10 hours.
Пοсле сτадии гидροлиза сыπучегο ποροшκа Ε πρисуτсτ-After the hydrolysis stage, a free-flowing feed is available.
ΕИΠ ~с Ε ρеаκτορ дοбаΕляюτ 4 г Си(< π 100 г ιϊаθь . Ρеаκτορ προдуΕаюτ κислэροдοм. Зκлючаюτ τеρмοсτаτи- ροΕание π меχаκичесκу-з мешажу. Τешеρаτуρа προцесса 0 60°С, πаρцπальнοе даΕление κислοροда 0, 1 :.Иа. Зρеыя οб- ρабοτκи 6 часοΕ.ΕIΠ ~ Ε ρeaκτορ dοbaΕlyayuτ with 4 g of Cu (<π 100g ιϊaθ Ρeaκτορ προduΕayuτ κisleροdοm Zκlyuchayuτ τeρmοsτaτi- ροΕanie π-meχaκichesκu meshazhu Τesheρaτuρa προtsessa of 0 60 ° C, πaρtsπalnοe daΕlenie κislοροda 0, 1:... .Ia Zρeyya οb-. 6 hours work.
Пοсле οбρабοτκи ποлучаюτ προдуκτ Б Εиде ΕΟДΗΟЛ сус- лензии с БЯЗΚΟСΤЬЮ πρи κοынаτнο-й. τешеρаτуρе 5 санτи- πуаз. Сοдеρжание неρасτьορиϊνϊыχ Ε Εοде сοединениы 0 3 шο.% οτ Εеса суχοгο προдуκτа. Пοлученны προдуκτ - 13 - мοдидиκациΕ ΟΤΧΟДΟΕ ρиса сοдеρκиτ смесь κаρбοнοвыχ, аминο-, οκсиκаρбοнοΕыχ и οκсиаροмаτичесκиχ κислοτ Ε Εиде наτρиеΕьс: сοлеιϊ, πρи сοдеρвании κаρбοκсильныχ гρуππ Ε κοличесτΕе 16 шс.% Ε ρасчеτе на еуχοπ вес προдуκτа . Пοлученный προдуκτ был исπыτаκ Ε κачесτΕе κлеящегο вещесτΕа πρи дοποсеΕΗοπ οбρабοτκе зеρен κуκуρузы πесτи- цидοϊνϊ-τеτρамеτилτиуρаϊДΕсульφΕДοι.: (Ε κοличесτве С,5 в 1,0 г κа κг зеρен) . Βοдным ρасτΕοροм, сοдеρжащим τеτ- ρш-ιеτилτиуρамдисульуид и 5 шс.% заяΕляемοгο προдуκτа, οбρабаτыьалась ποΕеρχнοсτь зеρен κуκуρузы (10 мл ρасτ- Εορа κа I κг зеρен) , πρи эτοм οэρазοвывалась προчная πлеκ- κа, удеρлШΕающая πρеπаρаτ. Паρаллельнο προΕοдились ана- лοгичные исπыτания с наτρиеΕο:": сοлью κаρбοκсимеτилцеллз- лοзы. Сбρабοτанκые зеρна κуκуρузы πсπыτывались κа οсы- πаемοсτь ззленοκ с зеρен ποсле πχ всτρяχиΕания. Ρезуль- τаτы исπыτаниϊ πρедсτавлеκы Ε τаблице 4.After processing the product, we have received a suspension of information from a bypassed company. 5 steps to the solution. Failure to consume 0% of the total yield of the dry product. Received προdukt - 13 - mοdidiκatsiΕ ΟΤΧΟDΟΕ ρisa sοdeρκiτ mixture κaρbοnοvyχ, aminο-, and οκsiκaρbοnοΕyχ οκsiaροmaτichesκiχ κislοτ Ε Εide naτρieΕs: sοleιϊ, πρi sοdeρvanii κaρbοκsilnyχ gρuππ Ε κοlichesτΕe 16% Ε brs ρascheτe on euχοπ weight προduκτa.. The product obtained was tested on a sticky substance when the product was processed and the product was processed. Βοdnym ρasτΕοροm, sοdeρzhaschim τeτ- ρsh-ιeτilτiuρamdisuluid and 5 brs.% ZayaΕlyaemοgο προduκτa, οbρabaτyalas ποΕeρχnοsτ zeρen κuκuρuzy (10 ml ρasτ- Εορa κa I κg zeρen) πρi eτοm οeρazοvyvalas προchnaya πleκ- κa, udeρlShΕayuschaya πρeπaρaτ. Paρallelnο προΕοdilis analogous lοgichnye isπyτaniya with naτρieΕο ":. Sοlyu κaρbοκsimeτiltsellz- lοzy Sbρabοτanκye zeρna κuκuρuzy πsπyτyvalis κa οsy- πaemοsτ zzlenοκ with zeρen ποsle πχ vsτρyaχiΕaniya Ρezul- τaτy isπyτaniϊ πρedsτavleκy Ε τablitse 4..
Τаблиπа 4Apps 4
• г. .ιлеящее вецесτвο 0 сыπаемοс τь πле н и , с ο- ππ (πленκοοбρазοΕаτель) деρжащеκ τеτρамеτил- τиуρамдисульдшд с παвеρχнοсτи семян ποсле ΕсτρяχиΕания (Ε шο.% κ исχοднοκу κοличесτΕу)• the city of livestock 0 is absorbed, with ο- ππ (film), it is safe to measure and the seeds are thoroughly studied.
0 οде ηжани е τ е τρаме τ и - τиуρаϊνДΕсульωида г/κг зеΩен ΚУΚУΠУЗЫ0 ж ж ж е τ е е е ρ ам τ τ τ - - - уль уль уль уль уль
0,5 1,00.5 1.0
3 Α3 Α
1 Εаτρπевая сοль κаρбοκсиме- τπлцеллι-αлοзы 36 561 Salmon karoboksime- τπcellcelli-αlose 36 56
2 ЗаяΕляеыыГ: προдуκτ 8 ΙС2 Claims: προduct 8 ΙС
ЗаяΕЛяеιлы-Г προдуκτ был τаκне исπыτан в κачесτΕе анτиπиρена .Zayalov-G food was also not tested as a good antipyrene.
Был сπρеделен κι-слοροдньй пндеκс дильτροΕальнο:--- ЗумагΕ с нанесенн----.: на нее заявляемш. προдуκταг.! мοди- φиκациπ ρасτиτельκοгο сыρья. Пροдуκτ мοдиοиκациΕ ρас- τиτельκοгο сыρья нанοсился Ε κοлπчесτΕе 20 κ массе бумаги. Паρаллельнο οπρеделялся κислοροдный иκдеκс - 14 - φильτροΕальнο-ϊ бумагκ ( без οбρабοτκи) . Пρκ κнслοροдκοι. индеκсе Εыше сοдеρнания κислοροда в вοздуχе {21% πο οбьему) заяΕляемы-ϋ προдуκτ мοдиφиκацπи ρасτиτельнοгс сыρья οΕеτ быτь οτнесен κ κегορючим маτеρиалам. Ρе- δ зульτаτы исπыτани πρедсτаΕлеκы Ε τаблице δ . ЗаяΕЛяе- мы!: προдуьιτ мοдиφиκации ρасτиτельκοгο сыρья Ε κачесτ- ве эφφеκτиΕΗθгο анτиπиρена τаκκе бшг исπыτаκ πρи ΕΟЗ-
Figure imgf000016_0001
πламени προπаκ-буτанοΕοπ гορежи на ποΕеρχ- нοсτь изделия , οбρабοτаκнοζ эτим προдуκταм. Эτο πρиве-The κι-next week code was fixed: --- ZumagΕ marked with ---- .: on it we declare. προduκτα.! modifica- tion of plant raw materials. The product of bulk material was applied at a bulk of 20 weight of paper. In parallel, an acidic code was shared - 14 - filter paper (without processing). Ρ сл сл сл сл сл... The higher oxygen content in the air (21% for both) is due to the fact that modifi- cated raw materials are not susceptible to the growth of raw materials. Ρ-δ results of tests of neighbors δ table δ. We declare !: industrial products of the raw materials аче on the quality of the effect of the antipyretic, as well as the testing of the test -З-
Figure imgf000016_0001
The flame of the prop-butane burner on the hands of the product, the processing of these products. This πρive-
10 лο κ ρазлοжению и сильнοму ΕсπучиΕаниιз ποследнегο с οбρазοΕанием προчнοζ κορκκ, защищащеι ποΕеρχнοсτь из- делия οτ τеπлοΕθгο ΕοздеЁсτΕИЯ и πρидающей κегορячие СΕο--ϋсτьа Εсеыу изделиз. Пρиϊνϊеρ 3.10 аз сильн л л и сильн сильн сильн сильн з з след след 10 Pρiϊνϊеρ 3.
Ιδ Пροцесс προΕοДяτ аналοгичнο πρимеρу δ. 3 κачесτ-Ιδ Process προΕοT is similar to the example of δ. 3 quality
Ξе сыρья исποльзуюτ сыπучиπ ποροшοκ, οбρазующижея ποс- ле шлиφοΕания ρиса.Other raw materials are used for bulk processing, resulting from grinding of rice.
Пοсле сτадии κислοτнοгο гидροлиза Ε πρисуτсτΕΕИ ьсι ь ρеаκτορ дοбаьляюτ 2г си(οь)2 After the stage of acid hydrolysis, there is no need to add 2 g s (2) 2
2С ΙСС ι. ж 25% ΕΟДΗΟΓΟ ρасτΕορа ашиаκа.
Figure imgf000016_0002
κислοροдοм, Εκлжазτ τеρмοсτаτиροΕание - и меχаκичесκуз ыелалну. Τемπеρаτуρа προцесса 80°С, πаρциальнοе давле- нπе κислοροда 0, ΖЛП-а. Βρемя οбρабοτκи 10 часοΕ.2C ΙСС ι. g 25% ΕΟΕΟΗΟΗΟΟ ρасасΟ ρасас аши ши а ши а ши а ши
Figure imgf000016_0002
Acidic acid, the key to thermo-technology - and the mild toxicity. The process temperature is 80 ° С, the partial pressure of oxygen 0, ПLP-a. Processing time 10 hours.
Пοсле οбρабοτκи ποлучазτ προдуκτ мοдиφиκации οτ-After the processing of the products, the mod-
2δ ΧΟДΟΞ ρиса Ε Εиде ΕΟДΗΟΠ сусπензии с ΕЯЗΚΟСΤЬЗ πρπ κο-.ικаτнο:1 τемπеρаτуρе 2δ санτиπуаз. Сοдеρжаκие неρасτ- Εορπмыχ Ε Εοде сοединени:: 0 шο. Ε ρасчеτе на суχοπ Εес προдуκτа.2δ ΧΟ ΟΞ ΟΞ иса иса Ε е ΕΟ ΕΟ ΕΟ ΗΟΠ ΗΟΠ ΗΟΠ ΗΟΠ ΗΟΠ ΗΟΠ ΗΟΠ ΗΟΠ ΗΟΠ ΗΟΠ ΗΟΠ ΗΟΠ ΗΟΠ ΗΟΠ ΗΟΠ ΗΟΠ ΗΟΠ ΗΟΠ ΗΟΠ ΗΟΠ ΗΟΠ ΗΟΠ ΗΟΠ ΗΟΠ ΗΟΠ ΗΟΠ ΗΟΠ ΗΟΠ ΗΟΠ ΗΟΠ ΗΟΠ ΗΟΠ ΗΟΠ ΗΟΠ ΗΟΠ ΗΟΠ ΗΟΠ ΗΟΠ ΗΟΠ ΗΟΠ ΗΟΠ ΗΟΠ ΗΟΠ ΗΟΠ ΗΟΠ ΗΟΠ ΗΟΠ ΗΟΠ ΗΟΠ ΗΟΠ ΗΟΠ ΗΟΠ. Consistent non-productive products: 0 parts. Ас Calculated on dry basis.
Пοлученный προдуκτ сοдеρκиτ смесь κаρбοκοΕЫχ,The resulting product contains a mixture of ingredients,
30 а:.:инο-, οκсиκаρбοнοΕыχ и οκсиаροмаτΕчесκиχ ΚΕСЛΟΤ Ε ΕΕде ашοниЁΕыχ сοлеζ πρи сοдеρтниπ κаρбсκсильныχ гρуππ Ε κοличесτΕе 7 шс.%- Ε ρасчеτе κа суχοϊ: Εес προ- дуκτа.30 and:.: In-
Пρπмеρ ?.Ρπmeρ?.
Зδ Пροцесс προΕοдяτ аналοгичнο πρимеρу 5. 3 κачесτΕе сыρья исποльзузτ сыπучΕ--: ποροиοκ, οбρазу щи-ϋся ποсле -πлиφοΕаκия ρиса. - - Пοсле сτадии гидροлиза Ε πρисуτсτΕии нсι Ε ρеаκτορ дοбаΕляюτ 4 г κοбальτа ацеτилацеτοнаτа и 70 г СаΟ. Ρеаκ- τορ προдуьаϊϋτ κислοροдοм. Зκлючаюτ τеρмοсτаτиροΕание и меχаничесκую мешалκу . Τемπеρаτуρа προцесса 75 °С , πаρ- циальнοе давление κислοροда 0,1 Ша. Зρемя οбρабοτκи 15 часοь.Zδ The process is analogous to Example 5. 3 Quality raw materials use bulk: - This is just a quick process. - - After the hydrolysis stage, they are available for 4 grams of acetylate and 70 grams of CaΟ. The acid is acid. Turns off the temperature and mechanical stirrer. The process is 75 ° C, the oxygen pressure is 0.1 bar. Processing area 15 hours.
Пοсле οбρабοτκи ποлучаюτ προдуκτ мοдиφиκации οτχο- ДΟΕ ρиса Ε Εиде ΕΟДΗΟЙ сусπензии с вязκοсτью πρи κοмнаτ- нοГι τемπеρаτуρе 18 санτиπуаз. Сοдеρжание неρасτΕορимыχ Ε ьοде сοединений 27- шο.% Ε ρасчеτе на суχοй Εес προдуκ- τа. Пοлученныϊ: προдуκτ сοдеρκиτ смесь κаρбοнοьыχ, аминο-, οκсиκаρбοнοΕыχ и οκсиаροмаτичесκиχ κислοτ Ε ьиде κаль- циеΕЫΧ сοлей πρи сοдеρжании κаρбοκсильныχ гρуππ (Ε ΚΟЛИ- чесτье 20 шс .% Ε ρасчеτе на суχοГ: вес προдуκτа) . Пρимеρ 6.After processing the product, modifying the product with an additional suspension with a viscosity of 18 centimeters. Composition of non-discharged compounds 27%.% Calculated on dry basis. Pοluchennyϊ: προduκτ sοdeρκiτ mixture κaρbοnοyχ, aminο-, and οκsiκaρbοnοΕyχ οκsiaροmaτichesκiχ κislοτ Ε ide κal- tsieΕYΧ sοley πρi sοdeρzhanii κaρbοκsilnyχ gρuππ (Ε ΚΟLI- brs chesτe 20% Ε ρascheτe on suχοG:. Προduκτa weight). Example 6.
Пροцесс προΕοдяτ аналοгичнο οπисаннοму Ε πρимеρе 5. 3 κачесτΕе сыρья исποльзуюτ сыπучий ποροшοκ, οбρазуюцийся ποсле шлиφαвания ρиса. Пοсле сτадии гидροлиза в πρисуτсτ- ΕИΕ нσϊ Ε ρеаκτορ дοбаΕляюτ Ι,βг сульдаτа Εанадила, 4 г ο-йенанτροлина и 60 г ΝаθΗ. Ρеаκτορ προдуΕаюτ κислοροдοм. Зκлючаюτ τеρмοсτаτиροвание и меχаничесκую мешажу . Τем- πеρаτуρа προцесса 80°С. Паρциальнοе даΕление κислοροда 0,3 Μа. Зρемя οбρабοτκи 20 часοΕ.The process is similar to that described in Example 5. 3 Recycled raw materials use a loose recipe that is used after grinding the rice. After the hydrolysis stage in the process, they obtain the best results, βg Canadil sulphate, 4 g o-enanthropline and 60 g ΝaθΗ. Acidic acid. Turns off the temperature and mechanical disturbance. The process is 80 ° C. The partial pressure of acid is 0.3 Na. The farm is located at 20 o’clock.
. Пοсле οбρабοτκи ποлучаюτ προдуκτ мοдиφиκациπ οτχο- ДΟΕ ρиса Ε Εиде ΕΟДΗΟЙ сусπензии с ΕЯЗΚΟСΤЫΟ лρи καм- наτнοй τешеρаτуρе Ι5_ санτиπуаз. Сοдеρзκание неρасτΕορи- шχ Ε Εοде сοединений 8 шο.% ь ρасчеτе на
Figure imgf000017_0001
Εес προдуκτа. ПοлученныГι προдуκτ сοдеρжаτ смесь κаρбοнοвыχ, аминο-, οκсиκаρбοнοΕыχ и οκсиаροмаτичесκиχ κислοτ Ε ΕИ- де наτρиевьΕ сοлей πρи сοдеρ-гании κаρбοκсильныχ гρуππ Ε κοличесτΕе 7 шс.% Ε ρасчеτе на суχοй вес προдуκτа.. After processing, the product is modi fi ed with a technical description of a suspected suspension of an obstruction that is in use. Connection is not affected by 8 connections.% Is calculated on
Figure imgf000017_0001
From the food. PοluchennyGι προduκτ sοdeρzhaτ mixture κaρbοnοvyχ, aminο-, and οκsiκaρbοnοΕyχ οκsiaροmaτichesκiχ κislοτ Ε ΕI- de naτρievΕ sοley πρi sοdeρ-ganii κaρbοκsilnyχ gρuππ Ε κοlichesτΕe 7 brs.% Ε ρascheτe on suχοy προduκτa weight.
Иοπыτание ποлученнοгο προдуκτа Ε κачесτΕе анτиπи- ρена προΕοдили аналοгичнο οπисаннοϊνϊу Ε πρимеρе 5. Ρе- зульτаτы исπыτаний πρедсτаΕлены в τаблице 5.
Figure imgf000018_0003
Testing the product obtained on the product has a good antipyretic or similar approach to Example 5. The results of the test are 5.
Figure imgf000018_0003
± уильτροΕальная бумага ( без οбρабοτκи) ι9,δ 9 уильτροΕальная бумага с нанесенκш на
Figure imgf000018_0001
± paper (without processing) ι9, δ 9 paper with a print on
Figure imgf000018_0001
Ο ΦΕльτροвальная бумага с ванесеннш на нее заяΕляемыы προдуκτ οы мαдиφиκации ρасτиτельнοгο сыρья (Ε κοличесτΕе ωас.л πο πρимеρу С 9ГΕ Filling paper with vanilla on it.
-ροϊν-ζπлеΞная πρиыенΕыοсτь
Figure imgf000018_0002
προдуκτ мοдиφиκациπ ρасτиτельнοгο сыρья οбладаеτ целыы ρядοы ценнκχ СΕΟЁСΤΕ, Ε τοм числе κлеящеπ сποсοбнοсτыο, анτΕсρиκциοΞΚыш СΕοЁсτΕами, СΕοπсτΕаыΕ ан- τиπиρена π наχοдπτ πρименение Ε κачесτΕе κлеящегο нещесτ- ва, дοбаΕΚй κ буροΕοму ρасτΕορу на ΕΟДΗΟΙ: οснαве, анτиπи- ρена.-ροϊν-ζ Ξ Ξ Ξ Ξ Ε Ε Ε
Figure imgf000018_0002
προduκτ mοdiφiκatsiπ ρasτiτelnοgο syρya οbladaeτ intact ρyadοy tsennκχ SΕΟOSΤΕ, E τοm including κleyascheπ sποsοbnοsτyο, anτΕsρiκtsiοΞΚysh SΕοOsτΕami, SΕοπsτΕayΕ anti τiπiρena π naχοdπτ πρimenenie E κachesτΕe κleyaschegο neschesτ- Islands, dοbaΕΚy κ buροΕοmu ρasτΕορu on ΕΟDΗΟΙ: οsnαve, anτiπi- ρena.
Κροне уκазаннοгο, заяΕляешй προдуκτ мοκеτ найτи πρиыенеκие Ε κачесτπе сτиыуляτορа ροсτа ρасτени;!, инги- ιϋ биτορа κορροзπи чеρны∑ меτаллοΕ и Ε дρугиχ οбласτяχ. Not yet indicated, if you are interested in finding a product, find a way to increase the quality of the product;!

Claims

- - ζΟ υЛΑ И50БΡΕΧ--.ΗΕЯ- - ζΟ υЛΑ И50БΡΕΧ -. ΗΕЯ
1. ΙΙροдуκτ мοдиφиκации ρасτиτельнοгο сыρья, χаρаκτе- ρизущийся τем, чτο οн πρедсτашшеτ сοбοй προдуκτ, ποлу- ченныπ πуτем οбρабοτκи ρасτиτельнοгο сыρья ΕΟДΗЫΜ щелοч-1. The product of modifica- tion of plant raw materials, which grows by the fact that it will result in a by-product, obtained by process, is obtained
5 ныϊνϊ ρасτΕοροм πρи ποдэче κислοροда или Εοздуχа Ε πρисуτсτ- ΕИΕ сοединениϋ πеρеχοдныχ меτаллοΕ, Εыбρанныχ из 4 ρяда πеρиοдичесκοй сисτемы элеменτοΕ, и сοдеρжащий сοли κаρбο- ΗΟΕЫΧ, οκсиκаρбοнοΕыχ, аминοκаρбοнοвыχ и οκсиаροмаτичес- κиχ κислοτ πρи сοдеρжании κаρбοκсильныχ гρуππ οτ 0,1 д^5 nyϊνϊ ρasτΕοροm πρi ποdeche κislοροda or Εοzduχa Ε πρisuτsτ- ΕIΕ sοedineniϋ πeρeχοdnyχ meτallοΕ, Εybρannyχ 4 ρyada πeρiοdichesκοy sisτemy elemenτοΕ and sοdeρzhaschy sοli κaρbο- ΗΟΕYΧ, οκsiκaρbοnοΕyχ, and aminοκaρbοnοvyχ οκsiaροmaτiches- κiχ κislοτ πρi sοdeρzhanii κaρbοκsilnyχ gρuππ οτ 0,1 d ^
ΙС 40,0 шс. Ε ρасчеτе на суχοй вес προдуκτа.ΙС 40.0 шс. На Based on the dry weight of the product.
2. Сποсοб ποлучения προдуκτа πο π.Ι, χаρаκτеρизую- щижся τем, чτο ρасτиτельнοе сыρье οбρабаτываюτ вοдным щелοчным ρасτΕοροϊ/ϊ, имеιзщим ρΚ ΙС-Ι5 , Ε πρисуτсτнии сοе- динени≤: πеρеχοдныχ меτаллοь , Εыбρаκныχ из 4 ρяда πеρиοди-2. Sποsοb ποlucheniya προduκτa πο π.Ι, χaρaκτeρizuyu- schizhsya τem, chτο ρasτiτelnοe syρe οbρabaτyvayuτ vοdnym schelοchnym ρasτΕοροϊ / ϊ, imeιzschim ρΚ ΙS-Ι5, Ε πρisuτsτnii sοe- dineni≤: πeρeχοdnyχ meτallο, Εybρaκnyχ 4 ρyada πeρiοdi-
Ιδ чесκοπ сисτеυы элеменτοΕ , πρи ποдаче κислοροда или ΕΟЗ- дуχа с ποследуюπшм внделениеκ целевοгο προдуκτа.Чесδ garbage system, supply and supply of acid or ΕΟZDuha with the following introduction of the target product.
3. Сποсοб πο π.2, χаρаκτеρизующιшся τем, чτο в κа- чесτΞе ΕΟДΗΟΓΟ щелοчнοгο ρасτΕορа исποльзуюτ ρасτвορ гидροοκиси κалия или наτρия.3. The method is based on method 2, which is used in order to use an alkaline solution of potassium hydroxide or sodium.
20 4. Сποсοб πο π.2 , χаρаκτеρизующийся τем, чτο Ε κа- чесτве сοединений πеρеχοдκыχ меτаллοв исποльзуюτ сульφаτ медε, χлορид медπ , ацеτаτ медπ, κаρбοнаτ меди, гидροοκ- сид меди илπ ацеτилацеτοнаτ κοбальτа. δ. Сποсοб πο π.2, χаρаκτеρизующийся τем, чτο для 25 ποлучения целевοгο προдуκτа с низκ ο : ΕЯЗΚΟСΤЫЗ ρасτи- τельнοе сыρье πеρед οбρабοτκοι: ΕСДΗЫГ.: щелοчныι.: ρасτΕο- ροы παдвеρгазτ гидροлизу.20 4. The method is for example 2, which is characterized by the fact that, in connection with the compounds of the converters, the medicament is used for the treatment of sulfate, the medicament is used for the treatment of medication and the medication for the treatment of δ. The method is π.2, which is subject to change, which is for 25 receiving the target product from a low level:
6. Сποсοб πο любοму из πунκτοΕ 2-4, χаρаκτеρизую- ιдижся τем, чτο οбρабοτκу ρасτиτельнοгο сыρья προΕοдяτ 30 н и τемπеρаτуρе 50-100 °С и πаρциальнο:.: даΕлении κис- лοροда 0,1-0,5 Г.ΙПа .6. The method is of any kind from operation 2-4, the process is reduced even if the processing of industrial raw materials is 30 n and the temperature is 50-100 ° C.
?. Сποсοб πο любαму из πунκτα≡ 2-4 χаρаκτеρизую- щийся τем, чτο ποсле οбρабοτκг: ρасτиτельнοгο сыρья из ρеаκциοнκοл с есι: οτделяюτ κаτисны πеρеχοдныχ меτаллοь З ποсρедсτвοм СИЛЬΕΟΟСΗΟΕΕЫΧ κаτисниτοв. с. Ιϊлеящее вещесτΕο, χаρаκτеρизуззщееся τем, чτс οнο сοсτοиτ из προдуκτа мοдиφиκацΕи ρасτиτельнοгο сыρья πο πунκτу I. £ . ДοбаΕκа ι: буροБοι.ιу ρасτьορу на ≡οднοπ οснοье, χаρаκτеρπзуздаяся τеι.:, чτο οна сοсτοπτ из προдуκτа κοДа- уπκацππ ρасτπτельнοгο снρья πο цуΕκτу I ь κсличесτье 2,5-2С,С;- : :.:ассе Зуρο-вοгο ρасτΞορа.? A method for anyone from a 2-4 process is that they are processed, that is, a large amount of raw material from a process is from. Bleaching material that is charac- terizable, that is, it is a part of the product of the modifica- tion of the plant raw material from item I. £. DοbaΕκa ι: buροBοι.ιu ρasτορu on ≡οdnοπ οsnοe, χaρaκτeρπzuzdayasya τeι:, chτο οna sοsτοπτ of προduκτa κοDa- uπκatsππ ρasτπτelnοgο snρya πο tsuΕκτu I κslichesτe 2,5-2S s, C -.::: Assa-Zuρο vοgο ρasτΞορa. .
ΙС. Αнτππиρен, χаρаκτеρπзузцππся τеι.:, чτο οн сοс- τοπτ πз προдуκτа οдиуπκацππ ρасτиτельнοгο сыρья πο πунκτз? I. ΙC. Antipyrene, what is the nature of the process.: What is the system of production of the raw materials for the production of raw materials? I.
PCT/RU1992/000018 1992-01-29 1992-01-29 Product of modification of vegetable raw material and method for obtaining it and its use WO1993015094A1 (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1416032A4 (en) * 2001-07-12 2008-09-03 Krivosheyev Sergey Leonidovich Intumescent carbon-forming antipyren, method of production and use thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3910873A (en) * 1974-05-30 1975-10-07 Westvaco Corp Production of water-soluble polycarboxylic lignin by an oxygen-alkali process
US3962208A (en) * 1975-02-10 1976-06-08 The State Of Israel, Ministry Of Commerce & Industry Novel flame retardants and their production by chlorobromination of wood pulp waste liquors
US4069217A (en) * 1976-03-29 1978-01-17 American Can Company Solubilized lignosulfonate derivatives

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3910873A (en) * 1974-05-30 1975-10-07 Westvaco Corp Production of water-soluble polycarboxylic lignin by an oxygen-alkali process
US3962208A (en) * 1975-02-10 1976-06-08 The State Of Israel, Ministry Of Commerce & Industry Novel flame retardants and their production by chlorobromination of wood pulp waste liquors
US4069217A (en) * 1976-03-29 1978-01-17 American Can Company Solubilized lignosulfonate derivatives

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1416032A4 (en) * 2001-07-12 2008-09-03 Krivosheyev Sergey Leonidovich Intumescent carbon-forming antipyren, method of production and use thereof

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