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WO1990008165A1 - Composition aqueuse polymere pour revetements protecteurs - Google Patents

Composition aqueuse polymere pour revetements protecteurs Download PDF

Info

Publication number
WO1990008165A1
WO1990008165A1 PCT/US1990/000356 US9000356W WO9008165A1 WO 1990008165 A1 WO1990008165 A1 WO 1990008165A1 US 9000356 W US9000356 W US 9000356W WO 9008165 A1 WO9008165 A1 WO 9008165A1
Authority
WO
WIPO (PCT)
Prior art keywords
aqueous composition
protective coating
polymeric aqueous
polymeric
coalescents
Prior art date
Application number
PCT/US1990/000356
Other languages
English (en)
Inventor
George Wilbur Grogan
Robert Howard Boyd
Original Assignee
George Wilbur Grogan
Robert Howard Boyd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by George Wilbur Grogan, Robert Howard Boyd filed Critical George Wilbur Grogan
Publication of WO1990008165A1 publication Critical patent/WO1990008165A1/fr

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/008Temporary coatings
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2218/00Methods for coating glass
    • C03C2218/30Aspects of methods for coating glass not covered above
    • C03C2218/355Temporary coating

Definitions

  • This invention relates in general to protective coatings, and more particularly, to" a polymeric aqueous composition for forming temporary protective coatings when used on glass, metal, rubber, concrete-like surfaces and plastic, non-porous or painted surfaces unaffected by solvents, that may be easily peeled therefrom.
  • Cleanups with new construction both residential and commercial can be a real problem even for those who are providing a commercial cleaning service cleaning new construction. There has been a pronounced need for something that would make window cleaning both easier and faster. Many substances have been tried, including even Crisco and peanut oil with, however, it being found that removal of some of these substances is more of a problem than direct scraping removal of paint, mortar, texture, and other substances that may have splashed, dropped or deposited on glass and/or metal surfaces. The new substance comes in a liquid form that may be sprayed to coat surfaces for protection.
  • the material forms a protective film temporary coating on glass, metal, rubber, concrete like surfaces and plastic non-porous or painted surfaces generally unaffected by solvents, that may be easily peeled away taking with it paint, mortar, mud and dust or any other foreign materials that may have been deposited thereon during construction.
  • This temporary protective coating greatly reduces the use of razor blades, and abrasive cleaning agents that can scratch glass and even break glass. By not allowing direct contact of sand, mortar and cement and other foreign material with glass during construction the costly service of replacing damaged glass with unscratched and unbroken glass and/or regla__ing glass is reduced. This provides great savings in reduced replacement costs and also in reduced cleaning rates in many instances.
  • the material may be applied to formica, ceramic (bathtubs) , porcelain, marble, stainless steel, copper and aluminum, and as an aid in asbestos abatement.
  • the material is useful also for applications other than temporary protective coatings in that it can be sprayed or dip applied to porous materials or even, in some.instances, to surfaces of materials that interact with solvents in the coating material. It provides a protective surface for wood with release characteristic of the temporary protective coating.
  • Another object is to protect glass and other materials from damage during building construction or remodeling.
  • a further object is to speed up cleanup after construction.
  • Still another object is to lower cleanup costs after construction and make the cleanup job easier.
  • aqueous composition for protective coatings a composition with defoamers in the range of 0.1% to 0.6%, wetting aids 0.1% to 0.6%, dispersing aids 0.1% to 0.8%, plasticizers and coalescents 0.1% to 2.5%, release aids 7% to 15%, resins 34% to 54%, thickeners 1% to 5% and the remainder, water.
  • defoamers in the range of 0.1% to 0.6%, wetting aids 0.1% to 0.6%, dispersing aids 0.1% to 0.8%, plasticizers and coalescents 0.1% to 2.5%, release aids 7% to 15%, resins 34% to 54%, thickeners 1% to 5% and the remainder, water.
  • the composition is an aqueous polymeris dispersion (emulsion) composed of a blend of Vinyl Acrylics, Poly Vinyl Alcohols, Ethylene Vinyl Acetates, Vinyl Acrylics and Acrylics, a part or all thereof blended with a dispersing aid such as Dioctyl Sodium Sulfa Succinate, and wetting aids such as Phenoxy Polethyenoeoxy Ethanol, Nonylphenol Polyelectrol, Glycol Ether, and Sodium Carboxylated Polyelectrol, and certain plasticizers and coalescents such as Oi Butyl Phthalate and 2, 2, 4 Trimethylpemtanediol - 1, 3 Monisobutyrate and Glycerin.
  • a dispersing aid such as Dioctyl Sodium Sulfa Succinate
  • wetting aids such as Phenoxy Polethyenoeoxy Ethanol, Nonylphenol Polyelectrol, Glycol Ether, and Sodium Carboxylated Poly
  • composition is then dispersed with a colloidal mixture of parafine waxes, polymeric waxes and selected fatty oils as release agents imposing a high resistance to water.
  • the composition also includes selected thickening agents such as Hydroxyethyl Cellulose and an Acrylic aqueous dispersion, and Antifoam such as Silica dispersion in Petroleum oil, and Glycols such as Propylene and Ethylene.
  • the mixture of the present invention comprises, by weight a mixture of nonvolatile materials in the range of 41% to 71% and volatile and evaporant materials in the range of 29% to 59%.
  • the nonvolatile portion includes: release aids in the range of 7% to 15% and resins in the range of 34% to 54%, defoamers 0.1% to 0.6%, wetting aids 0.1% to 0.6%, dispersing aids 0.1 to 0.8% and thickeners 1% to 5%.
  • the volatile and evaporant materials include plasticizers and coalescents in the range of 0.1% to 2.5%, and water in the range of 28.9% to 56.5%.
  • the resins are a blend of Vinyl acrylics. Poly Vinyl alcohols, Ethylene Vinyl Acetates, Vinyl Acrylics and Acrylics. A part or all thereof is blended with a dispersing aid such as Dioctyl Sodium Sulfa Succinate, and wetting aids such as Phenoxy Polethyenoeoxy Ethanol, Nonylphenol Polyelectrol, Glycol Ether, and Sodium Carboxylated Polyelectrol.
  • a dispersing aid such as Dioctyl Sodium Sulfa Succinate
  • wetting aids such as Phenoxy Polethyenoeoxy Ethanol, Nonylphenol Polyelectrol, Glycol Ether, and Sodium Carboxylated Polyelectrol.
  • Plasticizers and coalescents are also blended into the dispersion with Di Butyl Phthalate, a plasticizer, and 2 , 2, 4 Trimethylpemtanediol - l, 3 Monisobutyrate and Glycerin as coalescents.
  • the composition is then dispersed with a colloidal mixture of parafine waxes, polymeric waxes and selected fatty oils as release agents imposing a high resistance to water.
  • the composition also includes selected thickening agents such as hydroxyethyl Cellulose and an Acrylic aqueous dispersion, and antifoam defoamers such as Silica dispersion in Petroleum Oil and Glycols such as Propylene and Ethylene.
  • volatile and evaporant materials include Di Butyl Phthalate a plasticizer; 2, 2, 4 Trimethylpemtanediol - 1, 3
  • Monisobutyrate and Glycerin as coalescents and water as an evaporant.
  • the overall mixture constituted as set forth is sprayed on surfaces to provide a peel-off protective film, on glass for example, it takes from several minutes to hours, depending on dryness of air and heat used, to substantially vaporize the volatile content and water from the mixture to form the protective film to peel-off form.
  • the composition in liquid form may be applied by spraying, dip application or by being brushed on a surface to be protected with a peel-off film of material.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Paints Or Removers (AREA)
  • Surface Treatment Of Glass (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

Une dispersion (émulsion) polymère aqueuse est composée d'un mélange d'acryliques de vinyle, d'alcools de polyvinyle, d'acétates d'éthylène vinyle, d'acryliques de vinylacryliques et d'acryliques entièrement ou partiellement mélangés avec un dispersant tel que le diotylsodiumsulfasuccinate, et des agents mouillants tels que l'éthanol de phénoxypolyéthyènoeoxyle, du nonylphénol polyéthlaylène glycoléther, et du polyélectrol carboxylé de sodium, certains plastifiants et coalesceurs tels que le dibutylphthalate et le 2, 2, 4 triméthylpemtanédiol-1, 3 monisobutyrate et glycérine. On disperse ensuite cette composition dans un mélange colloïdal de cires de paraffine, de cires polymères et d'huiles grasses sélectionnées en tant qu'agents de libération qui offrent un résistance élevée à l'eau. La composition comprend également des épaississants sélectionnés tels que l'hydroxyéthylcellulose et une dispersion aqueuse acrylique, un agent anti-moussant tel qu'une dispersion de silice dans du pétrole et des glycols tels que le propylène et l'éthylène.
PCT/US1990/000356 1989-01-23 1990-01-18 Composition aqueuse polymere pour revetements protecteurs WO1990008165A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US29963289A 1989-01-23 1989-01-23
US299,632 1989-01-23

Publications (1)

Publication Number Publication Date
WO1990008165A1 true WO1990008165A1 (fr) 1990-07-26

Family

ID=23155625

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US1990/000356 WO1990008165A1 (fr) 1989-01-23 1990-01-18 Composition aqueuse polymere pour revetements protecteurs

Country Status (5)

Country Link
JP (1) JPH04504433A (fr)
AU (1) AU5107390A (fr)
IE (1) IE900239L (fr)
PT (1) PT92933A (fr)
WO (1) WO1990008165A1 (fr)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1997024407A1 (fr) * 1995-12-28 1997-07-10 Eastman Chemical Company Composition de revetement amovible et procede pour proteger des surfaces
DE19649263C1 (de) * 1996-11-28 1998-01-15 Herberts Gmbh Wäßrige Schutzüberzugsmittel und deren Verwendung
EP0750949A4 (fr) * 1994-12-01 1998-08-26 Kansai Paint Co Ltd Procede de protection temporaire d'une couche de peinture appliquee sur une carrosserie d'automobile
US5945462A (en) * 1997-10-02 1999-08-31 Loctite Corporation Temporary protective coatings for precision surfaces
US6250512B1 (en) 1997-10-02 2001-06-26 Loctite Corporation Temporary protective coatings for precision surfaces
WO2008153622A1 (fr) * 2007-06-06 2008-12-18 Centre Luxembourgeois De Recherches Pour Le Verre Et La Ceramique S.A. (C.R.V.C.) Procédé de production d'un article de verre revêtu, et produit intermédiaire utilisé dans celui-ci

Families Citing this family (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3521282B2 (ja) * 1992-03-31 2004-04-19 ユーエスエー ビデオ,インコーポレイテッド ビデオ通信方法及びシステム
US7606492B2 (en) 2000-10-04 2009-10-20 Enablence Usa Fttx Networks Inc. System and method for communicating optical signals upstream and downstream between a data service provider and subscribers
MXPA03003655A (es) 2000-10-26 2005-01-25 Wave7 Optics Inc Metodo y sistema para procesar paquetes corriente arriba de una red optica.
US7146104B2 (en) 2001-07-05 2006-12-05 Wave7 Optics, Inc. Method and system for providing a return data path for legacy terminals by using existing electrical waveguides of a structure
US7333726B2 (en) 2001-07-05 2008-02-19 Wave7 Optics, Inc. Method and system for supporting multiple service providers within a single optical network
US7218855B2 (en) 2001-07-05 2007-05-15 Wave7 Optics, Inc. System and method for communicating optical signals to multiple subscribers having various bandwidth demands connected to the same optical waveguide
US7529485B2 (en) 2001-07-05 2009-05-05 Enablence Usa Fttx Networks, Inc. Method and system for supporting multiple services with a subscriber optical interface located outside a subscriber's premises
US7269350B2 (en) 2001-07-05 2007-09-11 Wave7 Optics, Inc. System and method for communicating optical signals between a data service provider and subscribers
WO2003005612A1 (fr) 2001-07-05 2003-01-16 Wave7 Optics, Inc. Procedes et systemes offrant un trajet de retour a des signaux generes par des terminaux classiques dans un reseau optique
US7593639B2 (en) 2001-08-03 2009-09-22 Enablence Usa Fttx Networks Inc. Method and system for providing a return path for signals generated by legacy terminals in an optical network
US7038910B1 (en) 2002-01-07 2006-05-02 Wave7 Optics, Inc. System and method for removing heat from a subscriber optical interface
US7583897B2 (en) 2002-01-08 2009-09-01 Enablence Usa Fttx Networks Inc. Optical network system and method for supporting upstream signals propagated according to a cable modem protocol
US7623786B2 (en) 2002-05-20 2009-11-24 Enablence Usa Fttx Networks, Inc. System and method for communicating optical signals to multiple subscribers having various bandwidth demands connected to the same optical waveguide
US7058260B2 (en) 2002-10-15 2006-06-06 Wave7 Optics, Inc. Reflection suppression for an optical fiber
US7454141B2 (en) 2003-03-14 2008-11-18 Enablence Usa Fttx Networks Inc. Method and system for providing a return path for signals generated by legacy terminals in an optical network
US7340180B2 (en) 2004-08-10 2008-03-04 Wave7 Optics, Inc. Countermeasures for idle pattern SRS interference in ethernet optical network systems
US7599622B2 (en) 2004-08-19 2009-10-06 Enablence Usa Fttx Networks Inc. System and method for communicating optical signals between a data service provider and subscribers
US7616901B2 (en) 2005-08-10 2009-11-10 Enablence Usa Fttx Networks Inc. Countermeasures for idle pattern SRS interference in ethernet optical network systems
US10000049B2 (en) * 2014-06-23 2018-06-19 Exel Industries Methods and apparatus for applying protective films
JP7271759B1 (ja) * 2021-08-30 2023-05-11 積水化学工業株式会社 積層体

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2978372A (en) * 1961-04-04 Method for the manufacture of vinyl
US4139514A (en) * 1977-06-29 1979-02-13 Union Carbide Corporation Aqueous vehicles
US4562226A (en) * 1983-01-12 1985-12-31 Imperial Chemical Industries Plc Coating compositions
US4632847A (en) * 1985-02-06 1986-12-30 Isotek Corporation In situ polymeric membrane for isolating hazardous materials
US4731402A (en) * 1985-11-02 1988-03-15 Basf Aktiengesellschaft Floor covering adhesive based on aqueous polymer dispersions

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2978372A (en) * 1961-04-04 Method for the manufacture of vinyl
US4139514A (en) * 1977-06-29 1979-02-13 Union Carbide Corporation Aqueous vehicles
US4562226A (en) * 1983-01-12 1985-12-31 Imperial Chemical Industries Plc Coating compositions
US4632847A (en) * 1985-02-06 1986-12-30 Isotek Corporation In situ polymeric membrane for isolating hazardous materials
US4731402A (en) * 1985-11-02 1988-03-15 Basf Aktiengesellschaft Floor covering adhesive based on aqueous polymer dispersions

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0750949A4 (fr) * 1994-12-01 1998-08-26 Kansai Paint Co Ltd Procede de protection temporaire d'une couche de peinture appliquee sur une carrosserie d'automobile
WO1997024407A1 (fr) * 1995-12-28 1997-07-10 Eastman Chemical Company Composition de revetement amovible et procede pour proteger des surfaces
US5750269A (en) * 1995-12-28 1998-05-12 Eastman Chemical Company Removable coating composition and process for protecting surfaces
DE19649263C1 (de) * 1996-11-28 1998-01-15 Herberts Gmbh Wäßrige Schutzüberzugsmittel und deren Verwendung
US6149970A (en) * 1996-11-28 2000-11-21 Herberts Gmbh & Co. Kg Aqueous protective coating agent
US5945462A (en) * 1997-10-02 1999-08-31 Loctite Corporation Temporary protective coatings for precision surfaces
US6250512B1 (en) 1997-10-02 2001-06-26 Loctite Corporation Temporary protective coatings for precision surfaces
WO2008153622A1 (fr) * 2007-06-06 2008-12-18 Centre Luxembourgeois De Recherches Pour Le Verre Et La Ceramique S.A. (C.R.V.C.) Procédé de production d'un article de verre revêtu, et produit intermédiaire utilisé dans celui-ci
US8236116B2 (en) 2007-06-06 2012-08-07 Centre Luxembourgeois De Recherches Pour Le Verre Et Al Ceramique S.A. (C.R.V.C.) Method of making coated glass article, and intermediate product used in same
US8506737B2 (en) 2007-06-06 2013-08-13 Centre Luxembourgeois De Recherches Pour Le Verre Et Al Ceramique S.A. (C.R.V.C.) Method of making coated glass article, and intermediate product used in same

Also Published As

Publication number Publication date
AU5107390A (en) 1990-08-13
PT92933A (pt) 1990-07-31
JPH04504433A (ja) 1992-08-06
IE900239L (en) 1990-07-23

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