WO1990008165A1 - Polymeric aqueous composition for protective coatings - Google Patents
Polymeric aqueous composition for protective coatings Download PDFInfo
- Publication number
- WO1990008165A1 WO1990008165A1 PCT/US1990/000356 US9000356W WO9008165A1 WO 1990008165 A1 WO1990008165 A1 WO 1990008165A1 US 9000356 W US9000356 W US 9000356W WO 9008165 A1 WO9008165 A1 WO 9008165A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- aqueous composition
- protective coating
- polymeric aqueous
- polymeric
- coalescents
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 51
- 239000011253 protective coating Substances 0.000 title claims description 28
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 claims abstract description 14
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims abstract description 12
- -1 Vinyl Acrylics Chemical compound 0.000 claims abstract description 11
- 239000004014 plasticizer Substances 0.000 claims abstract description 11
- 239000006185 dispersion Substances 0.000 claims abstract description 10
- 239000001993 wax Substances 0.000 claims abstract description 10
- 239000002562 thickening agent Substances 0.000 claims abstract description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 9
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000011734 sodium Substances 0.000 claims abstract description 8
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 8
- 238000009736 wetting Methods 0.000 claims abstract description 8
- 229960002380 dibutyl phthalate Drugs 0.000 claims abstract description 7
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 6
- 235000011187 glycerol Nutrition 0.000 claims abstract description 6
- 239000004354 Hydroxyethyl cellulose Substances 0.000 claims abstract description 5
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 claims abstract description 5
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims abstract description 5
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 claims abstract description 5
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 4
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000010685 fatty oil Substances 0.000 claims abstract description 4
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 claims abstract description 4
- 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 claims abstract description 4
- KDYFGRWQOYBRFD-UHFFFAOYSA-L succinate(2-) Chemical compound [O-]C(=O)CCC([O-])=O KDYFGRWQOYBRFD-UHFFFAOYSA-L 0.000 claims abstract description 4
- 239000000463 material Substances 0.000 claims description 17
- 239000011248 coating agent Substances 0.000 claims description 5
- 238000000576 coating method Methods 0.000 claims description 5
- 230000001681 protective effect Effects 0.000 claims description 5
- 229920005989 resin Polymers 0.000 claims description 4
- 239000011347 resin Substances 0.000 claims description 4
- 229940074404 sodium succinate Drugs 0.000 claims 2
- APSBXTVYXVQYAB-UHFFFAOYSA-M sodium docusate Chemical group [Na+].CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC APSBXTVYXVQYAB-UHFFFAOYSA-M 0.000 claims 1
- 229920006397 acrylic thermoplastic Polymers 0.000 abstract description 8
- 229920003229 poly(methyl methacrylate) Polymers 0.000 abstract description 8
- 229920002554 vinyl polymer Polymers 0.000 abstract description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract description 4
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract description 3
- 239000005977 Ethylene Substances 0.000 abstract description 3
- 239000002518 antifoaming agent Substances 0.000 abstract description 3
- 239000000839 emulsion Substances 0.000 abstract description 3
- HDERJYVLTPVNRI-UHFFFAOYSA-N ethene;ethenyl acetate Chemical class C=C.CC(=O)OC=C HDERJYVLTPVNRI-UHFFFAOYSA-N 0.000 abstract description 3
- 150000002334 glycols Chemical class 0.000 abstract description 3
- 239000003208 petroleum Substances 0.000 abstract description 3
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 abstract description 3
- 229920002451 polyvinyl alcohol Polymers 0.000 abstract description 3
- 235000019422 polyvinyl alcohol Nutrition 0.000 abstract description 3
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 abstract description 3
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 abstract description 3
- 239000011521 glass Substances 0.000 description 11
- 238000010276 construction Methods 0.000 description 6
- 238000004140 cleaning Methods 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 239000004570 mortar (masonry) Substances 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 239000007788 liquid Substances 0.000 description 2
- 239000003973 paint Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 239000005060 rubber Substances 0.000 description 2
- ISXSCDLOGDJUNJ-UHFFFAOYSA-N tert-butyl prop-2-enoate Chemical compound CC(C)(C)OC(=O)C=C ISXSCDLOGDJUNJ-UHFFFAOYSA-N 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 241001251094 Formica Species 0.000 description 1
- 235000019483 Peanut oil Nutrition 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 239000010425 asbestos Substances 0.000 description 1
- 238000009435 building construction Methods 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000012459 cleaning agent Substances 0.000 description 1
- 239000004567 concrete Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000011499 joint compound Substances 0.000 description 1
- 239000004579 marble Substances 0.000 description 1
- 239000000312 peanut oil Substances 0.000 description 1
- 229910052573 porcelain Inorganic materials 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 238000007634 remodeling Methods 0.000 description 1
- 229910052895 riebeckite Inorganic materials 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 238000007790 scraping Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/008—Temporary coatings
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2218/00—Methods for coating glass
- C03C2218/30—Aspects of methods for coating glass not covered above
- C03C2218/355—Temporary coating
Definitions
- This invention relates in general to protective coatings, and more particularly, to" a polymeric aqueous composition for forming temporary protective coatings when used on glass, metal, rubber, concrete-like surfaces and plastic, non-porous or painted surfaces unaffected by solvents, that may be easily peeled therefrom.
- Cleanups with new construction both residential and commercial can be a real problem even for those who are providing a commercial cleaning service cleaning new construction. There has been a pronounced need for something that would make window cleaning both easier and faster. Many substances have been tried, including even Crisco and peanut oil with, however, it being found that removal of some of these substances is more of a problem than direct scraping removal of paint, mortar, texture, and other substances that may have splashed, dropped or deposited on glass and/or metal surfaces. The new substance comes in a liquid form that may be sprayed to coat surfaces for protection.
- the material forms a protective film temporary coating on glass, metal, rubber, concrete like surfaces and plastic non-porous or painted surfaces generally unaffected by solvents, that may be easily peeled away taking with it paint, mortar, mud and dust or any other foreign materials that may have been deposited thereon during construction.
- This temporary protective coating greatly reduces the use of razor blades, and abrasive cleaning agents that can scratch glass and even break glass. By not allowing direct contact of sand, mortar and cement and other foreign material with glass during construction the costly service of replacing damaged glass with unscratched and unbroken glass and/or regla__ing glass is reduced. This provides great savings in reduced replacement costs and also in reduced cleaning rates in many instances.
- the material may be applied to formica, ceramic (bathtubs) , porcelain, marble, stainless steel, copper and aluminum, and as an aid in asbestos abatement.
- the material is useful also for applications other than temporary protective coatings in that it can be sprayed or dip applied to porous materials or even, in some.instances, to surfaces of materials that interact with solvents in the coating material. It provides a protective surface for wood with release characteristic of the temporary protective coating.
- Another object is to protect glass and other materials from damage during building construction or remodeling.
- a further object is to speed up cleanup after construction.
- Still another object is to lower cleanup costs after construction and make the cleanup job easier.
- aqueous composition for protective coatings a composition with defoamers in the range of 0.1% to 0.6%, wetting aids 0.1% to 0.6%, dispersing aids 0.1% to 0.8%, plasticizers and coalescents 0.1% to 2.5%, release aids 7% to 15%, resins 34% to 54%, thickeners 1% to 5% and the remainder, water.
- defoamers in the range of 0.1% to 0.6%, wetting aids 0.1% to 0.6%, dispersing aids 0.1% to 0.8%, plasticizers and coalescents 0.1% to 2.5%, release aids 7% to 15%, resins 34% to 54%, thickeners 1% to 5% and the remainder, water.
- the composition is an aqueous polymeris dispersion (emulsion) composed of a blend of Vinyl Acrylics, Poly Vinyl Alcohols, Ethylene Vinyl Acetates, Vinyl Acrylics and Acrylics, a part or all thereof blended with a dispersing aid such as Dioctyl Sodium Sulfa Succinate, and wetting aids such as Phenoxy Polethyenoeoxy Ethanol, Nonylphenol Polyelectrol, Glycol Ether, and Sodium Carboxylated Polyelectrol, and certain plasticizers and coalescents such as Oi Butyl Phthalate and 2, 2, 4 Trimethylpemtanediol - 1, 3 Monisobutyrate and Glycerin.
- a dispersing aid such as Dioctyl Sodium Sulfa Succinate
- wetting aids such as Phenoxy Polethyenoeoxy Ethanol, Nonylphenol Polyelectrol, Glycol Ether, and Sodium Carboxylated Poly
- composition is then dispersed with a colloidal mixture of parafine waxes, polymeric waxes and selected fatty oils as release agents imposing a high resistance to water.
- the composition also includes selected thickening agents such as Hydroxyethyl Cellulose and an Acrylic aqueous dispersion, and Antifoam such as Silica dispersion in Petroleum oil, and Glycols such as Propylene and Ethylene.
- the mixture of the present invention comprises, by weight a mixture of nonvolatile materials in the range of 41% to 71% and volatile and evaporant materials in the range of 29% to 59%.
- the nonvolatile portion includes: release aids in the range of 7% to 15% and resins in the range of 34% to 54%, defoamers 0.1% to 0.6%, wetting aids 0.1% to 0.6%, dispersing aids 0.1 to 0.8% and thickeners 1% to 5%.
- the volatile and evaporant materials include plasticizers and coalescents in the range of 0.1% to 2.5%, and water in the range of 28.9% to 56.5%.
- the resins are a blend of Vinyl acrylics. Poly Vinyl alcohols, Ethylene Vinyl Acetates, Vinyl Acrylics and Acrylics. A part or all thereof is blended with a dispersing aid such as Dioctyl Sodium Sulfa Succinate, and wetting aids such as Phenoxy Polethyenoeoxy Ethanol, Nonylphenol Polyelectrol, Glycol Ether, and Sodium Carboxylated Polyelectrol.
- a dispersing aid such as Dioctyl Sodium Sulfa Succinate
- wetting aids such as Phenoxy Polethyenoeoxy Ethanol, Nonylphenol Polyelectrol, Glycol Ether, and Sodium Carboxylated Polyelectrol.
- Plasticizers and coalescents are also blended into the dispersion with Di Butyl Phthalate, a plasticizer, and 2 , 2, 4 Trimethylpemtanediol - l, 3 Monisobutyrate and Glycerin as coalescents.
- the composition is then dispersed with a colloidal mixture of parafine waxes, polymeric waxes and selected fatty oils as release agents imposing a high resistance to water.
- the composition also includes selected thickening agents such as hydroxyethyl Cellulose and an Acrylic aqueous dispersion, and antifoam defoamers such as Silica dispersion in Petroleum Oil and Glycols such as Propylene and Ethylene.
- volatile and evaporant materials include Di Butyl Phthalate a plasticizer; 2, 2, 4 Trimethylpemtanediol - 1, 3
- Monisobutyrate and Glycerin as coalescents and water as an evaporant.
- the overall mixture constituted as set forth is sprayed on surfaces to provide a peel-off protective film, on glass for example, it takes from several minutes to hours, depending on dryness of air and heat used, to substantially vaporize the volatile content and water from the mixture to form the protective film to peel-off form.
- the composition in liquid form may be applied by spraying, dip application or by being brushed on a surface to be protected with a peel-off film of material.
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
- Surface Treatment Of Glass (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
A composition aqueous polymeric dispersion (emulsion) composed of a blend of Vinyl Acrylics, Poly Vinyl Alcohols, Ethylene Vinyl Acetates, Vinyl Acrylics and Acrylics part or all thereof blended with a dispersing aid such as Dioctyl Sodium Sulfa Succinate, and wetting aids such as Phenoxy Polethyenoeoxy Ethanol, Nonylphenol Polyethlaylene Glycol Ether, and Sodium Carboxylated Polyelectrol, certain plasticizers and coalescents such as Di Butyl Phthalate and 2,2,4-Trimethylpemtanediol-1,3-Monisobutyrate and Glycerin. The composition is then dispersed with a colloidal mixture of parafine waxes, polymeric waxes and selected fatty oils as release agents imposing a high resistance to water. The composition also includes selected thickening agents such as Hydroxyethyl Cellulose and an Acrylic aqueous dispersion, an Antifoam such as Silica dispersion in Petroleum oil, and Glycols such as Propylene and Ethylene.
Description
POLYMERIC AQUEOUS COMPOSITION FOR PROTECTIVE COATINGS This invention relates in general to protective coatings, and more particularly, to" a polymeric aqueous composition for forming temporary protective coatings when used on glass, metal, rubber, concrete-like surfaces and plastic, non-porous or painted surfaces unaffected by solvents, that may be easily peeled therefrom.
Cleanups with new construction, both residential and commercial can be a real problem even for those who are providing a commercial cleaning service cleaning new construction. There has been a pronounced need for something that would make window cleaning both easier and faster. Many substances have been tried, including even Crisco and peanut oil with, however, it being found that removal of some of these substances is more of a problem than direct scraping removal of paint, mortar, texture, and other substances that may have splashed, dropped or deposited on glass and/or metal surfaces. The new substance comes in a liquid form that may be sprayed to coat surfaces for protection. The material forms a protective film temporary coating on glass, metal, rubber, concrete like surfaces and plastic non-porous or painted surfaces generally unaffected by solvents, that may be easily peeled away taking with it paint, mortar, mud and dust or any other foreign materials that may have been deposited thereon during construction. This temporary
protective coating greatly reduces the use of razor blades, and abrasive cleaning agents that can scratch glass and even break glass. By not allowing direct contact of sand, mortar and cement and other foreign material with glass during construction the costly service of replacing damaged glass with unscratched and unbroken glass and/or regla__ing glass is reduced. This provides great savings in reduced replacement costs and also in reduced cleaning rates in many instances. As an easy peel-off temporary coating the material may be applied to formica, ceramic (bathtubs) , porcelain, marble, stainless steel, copper and aluminum, and as an aid in asbestos abatement.
The material is useful also for applications other than temporary protective coatings in that it can be sprayed or dip applied to porous materials or even, in some.instances, to surfaces of materials that interact with solvents in the coating material. It provides a protective surface for wood with release characteristic of the temporary protective coating.
It is therefore a principal object of this invention to provide a polymeric aqueous composition coating material having a surface with desired release characteristics from material surfaces it would otherwise adhere to.
Another object is to protect glass and other materials from damage during building construction or remodeling.
A further object is to speed up cleanup after construction.
Still another object is to lower cleanup costs after construction and make the cleanup job easier.
Features of the invention useful in accomplishing the above objects include, in a polymeric aqueous composition for protective coatings, a composition with defoamers in the range of 0.1% to 0.6%, wetting aids 0.1% to 0.6%, dispersing aids 0.1% to 0.8%,
plasticizers and coalescents 0.1% to 2.5%, release aids 7% to 15%, resins 34% to 54%, thickeners 1% to 5% and the remainder, water. These ingredients are blended together at various times while the dispersion is being conducted for providing desirable temporary protective coatings. The composition is an aqueous polymeris dispersion (emulsion) composed of a blend of Vinyl Acrylics, Poly Vinyl Alcohols, Ethylene Vinyl Acetates, Vinyl Acrylics and Acrylics, a part or all thereof blended with a dispersing aid such as Dioctyl Sodium Sulfa Succinate, and wetting aids such as Phenoxy Polethyenoeoxy Ethanol, Nonylphenol Polyelectrol, Glycol Ether, and Sodium Carboxylated Polyelectrol, and certain plasticizers and coalescents such as Oi Butyl Phthalate and 2, 2, 4 Trimethylpemtanediol - 1, 3 Monisobutyrate and Glycerin. The composition is then dispersed with a colloidal mixture of parafine waxes, polymeric waxes and selected fatty oils as release agents imposing a high resistance to water. The composition also includes selected thickening agents such as Hydroxyethyl Cellulose and an Acrylic aqueous dispersion, and Antifoam such as Silica dispersion in Petroleum oil, and Glycols such as Propylene and Ethylene.
In a preferred embodiment, the mixture of the present invention comprises, by weight a mixture of nonvolatile materials in the range of 41% to 71% and volatile and evaporant materials in the range of 29% to 59%. The nonvolatile portion includes: release aids in the range of 7% to 15% and resins in the range of 34% to 54%, defoamers 0.1% to 0.6%, wetting aids 0.1% to 0.6%, dispersing aids 0.1 to 0.8% and thickeners 1% to 5%. The volatile and evaporant materials include plasticizers and coalescents in the range of 0.1% to 2.5%, and water in the range of 28.9% to 56.5%. In the nonvolatile portion of the aqueous polymeric dispersion (emulsion) , the resins are a blend of Vinyl acrylics. Poly Vinyl alcohols, Ethylene Vinyl
Acetates, Vinyl Acrylics and Acrylics. A part or all thereof is blended with a dispersing aid such as Dioctyl Sodium Sulfa Succinate, and wetting aids such as Phenoxy Polethyenoeoxy Ethanol, Nonylphenol Polyelectrol, Glycol Ether, and Sodium Carboxylated Polyelectrol.
Plasticizers and coalescents are also blended into the dispersion with Di Butyl Phthalate, a plasticizer, and 2 , 2, 4 Trimethylpemtanediol - l, 3 Monisobutyrate and Glycerin as coalescents. The composition is then dispersed with a colloidal mixture of parafine waxes, polymeric waxes and selected fatty oils as release agents imposing a high resistance to water. The composition also includes selected thickening agents such as hydroxyethyl Cellulose and an Acrylic aqueous dispersion, and antifoam defoamers such as Silica dispersion in Petroleum Oil and Glycols such as Propylene and Ethylene.
Please note again that the volatile and evaporant materials include Di Butyl Phthalate a plasticizer; 2, 2, 4 Trimethylpemtanediol - 1, 3
Monisobutyrate and Glycerin as coalescents and water as an evaporant. When the overall mixture, constituted as set forth is sprayed on surfaces to provide a peel-off protective film, on glass for example, it takes from several minutes to hours, depending on dryness of air and heat used, to substantially vaporize the volatile content and water from the mixture to form the protective film to peel-off form. The composition in liquid form may be applied by spraying, dip application or by being brushed on a surface to be protected with a peel-off film of material.
Whereas this invention has been described with respect to a range of composition mixture variations thereof, it should be realized that various changes may be made without departures from the essential contributions to the art made by the teachings hereof.
Claims
1. A polymeric aqueous composition for protective coatings comprising: a mixture of non-volatile and evaporant materials with the non-volatile materials including defoamers in the range of 0.1% to 0.6%; wetting aids in the range of 0.1% to 0.6%; dispersing aids in the range of 0.1% to 0.8%; plasticizers and coalescents in the range of 0.1% to 2.5%; release aids in the range of 7% to 15%; resins in the range of 34% to 54%; thickeners in the range of 1% to 5%; and water in the range of 28.9% to 56.5%.
2. The polymeric aqueous composition for protective coating of claim 1, wherein said wetting aids include Sodium Carboxylated Polyelectrol.
3. The polymeric aqueous composition for protective coating of claim 2, wherein said wetting aids also include: Phenoxy Polethyenoeoxy Ethanol, and Nonylphenol Polyethlene Glycol Ether.
4. The polymeric aqueous composition for protective coating of claim 3, wherein said composition is a combination solution and a colloidal mixture of waxes and fatty oils as release agents imposing a high resistance to water.
5. The polymeric aqueous composition for protective . coating of claim 4, wherein said waxes include: parafine waxes, and polymeric waxes.
6. The polymeric aqueous composition for protective coating of claim 5, wherein said thickeners include Hydroxyethyl Cellulose.
7. The polymeric aqueous composition for protective coating of claim 5, wherein said thickeners include an Acrylic aqueous dispersion.
8. The polymeric aqueous composition for protective coating of claim 5, wherein said thickeners is a mixture of Hydroxyethyl Cellulose and an Acrylic aqueous dispersion.
9. The polymeric aqueous composition for protective coating of claim 8, wherein said dispersing aid is Dioctyl Sodium Sulfa Succinate.
10. The polymeric aqueous composition for protective coating of claim 5, wherein said dispersing aid is Dioctyl Sodium Succinate.
11. The polymeric aqueous composition for protective coating of claim 1, wherein said dispersing aid is Dioctyl Sodium Succinate.
12. The polymeric aqueous composition for protective coating of claim 9, wherein said plasticizers include Di Butyl Phthalate.
13. The polymeric aqueous composition for protective coating of claim 5, wherein said plasticizers include Di Butyl Phthalate.
14. The polymeric aqueous composition for protective coating of claim 1, wherein said plasticizers include Di Butyl Phthalate.
15. The polymeric aqueous composition for protective coating of claim 12, wherein said coalescents include 2, 2, 4 Trimethylpemtanediol -l.
16. The polymeric aqueous composition for protective coating of claim 5, wherein said coalescents include 2, 2, 4 Trimethylpemtanediol -1.
17. The polymeric aqueous composition for protective coating of claim 1, wherein said coalescents include 2, 2, 4 Trimethylpemtanediol -1.
18. The polymeric aqueous composition for protective coating of claim 15, wherein said coalescents also include 3 Monisobutyrate.
19. The polymeric aqueous composition for protective coating of claim 18, wherein said coalescents also include Glycerin.
20. The polymeric aqueous composition for protective coating of claim 15, wherein said coalescents also include Glycerin.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US29963289A | 1989-01-23 | 1989-01-23 | |
| US299,632 | 1989-01-23 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO1990008165A1 true WO1990008165A1 (en) | 1990-07-26 |
Family
ID=23155625
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/US1990/000356 WO1990008165A1 (en) | 1989-01-23 | 1990-01-18 | Polymeric aqueous composition for protective coatings |
Country Status (5)
| Country | Link |
|---|---|
| JP (1) | JPH04504433A (en) |
| AU (1) | AU5107390A (en) |
| IE (1) | IE900239L (en) |
| PT (1) | PT92933A (en) |
| WO (1) | WO1990008165A1 (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1997024407A1 (en) * | 1995-12-28 | 1997-07-10 | Eastman Chemical Company | Removable coating composition and process for protecting surfaces |
| DE19649263C1 (en) * | 1996-11-28 | 1998-01-15 | Herberts Gmbh | Aqueous coating composition for giving peelable protective film |
| EP0750949A4 (en) * | 1994-12-01 | 1998-08-26 | Kansai Paint Co Ltd | Method of temporarily protecting film of coating on shell plate of automobile |
| US5945462A (en) * | 1997-10-02 | 1999-08-31 | Loctite Corporation | Temporary protective coatings for precision surfaces |
| US6250512B1 (en) | 1997-10-02 | 2001-06-26 | Loctite Corporation | Temporary protective coatings for precision surfaces |
| WO2008153622A1 (en) * | 2007-06-06 | 2008-12-18 | Centre Luxembourgeois De Recherches Pour Le Verre Et La Ceramique S.A. (C.R.V.C.) | Method of making coated glass article, and intermediate product used in same |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3521282B2 (en) * | 1992-03-31 | 2004-04-19 | ユーエスエー ビデオ，インコーポレイテッド | Video communication method and system |
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| MXPA03003655A (en) | 2000-10-26 | 2005-01-25 | Wave7 Optics Inc | Method and system for processing upstream packets of an optical network. |
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| US7454141B2 (en) | 2003-03-14 | 2008-11-18 | Enablence Usa Fttx Networks Inc. | Method and system for providing a return path for signals generated by legacy terminals in an optical network |
| US7340180B2 (en) | 2004-08-10 | 2008-03-04 | Wave7 Optics, Inc. | Countermeasures for idle pattern SRS interference in ethernet optical network systems |
| US7599622B2 (en) | 2004-08-19 | 2009-10-06 | Enablence Usa Fttx Networks Inc. | System and method for communicating optical signals between a data service provider and subscribers |
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| US10000049B2 (en) * | 2014-06-23 | 2018-06-19 | Exel Industries | Methods and apparatus for applying protective films |
| JP7271759B1 (en) * | 2021-08-30 | 2023-05-11 | 積水化学工業株式会社 | laminate |
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| US4562226A (en) * | 1983-01-12 | 1985-12-31 | Imperial Chemical Industries Plc | Coating compositions |
| US4632847A (en) * | 1985-02-06 | 1986-12-30 | Isotek Corporation | In situ polymeric membrane for isolating hazardous materials |
| US4731402A (en) * | 1985-11-02 | 1988-03-15 | Basf Aktiengesellschaft | Floor covering adhesive based on aqueous polymer dispersions |
-
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- 1990-01-18 WO PCT/US1990/000356 patent/WO1990008165A1/en unknown
- 1990-01-18 AU AU51073/90A patent/AU5107390A/en not_active Abandoned
- 1990-01-18 JP JP2503691A patent/JPH04504433A/en active Pending
- 1990-01-22 IE IE23990A patent/IE900239L/en unknown
- 1990-01-23 PT PT9293390A patent/PT92933A/en not_active Application Discontinuation
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|---|---|---|---|---|
| US2978372A (en) * | 1961-04-04 | Method for the manufacture of vinyl | ||
| US4139514A (en) * | 1977-06-29 | 1979-02-13 | Union Carbide Corporation | Aqueous vehicles |
| US4562226A (en) * | 1983-01-12 | 1985-12-31 | Imperial Chemical Industries Plc | Coating compositions |
| US4632847A (en) * | 1985-02-06 | 1986-12-30 | Isotek Corporation | In situ polymeric membrane for isolating hazardous materials |
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Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0750949A4 (en) * | 1994-12-01 | 1998-08-26 | Kansai Paint Co Ltd | Method of temporarily protecting film of coating on shell plate of automobile |
| WO1997024407A1 (en) * | 1995-12-28 | 1997-07-10 | Eastman Chemical Company | Removable coating composition and process for protecting surfaces |
| US5750269A (en) * | 1995-12-28 | 1998-05-12 | Eastman Chemical Company | Removable coating composition and process for protecting surfaces |
| DE19649263C1 (en) * | 1996-11-28 | 1998-01-15 | Herberts Gmbh | Aqueous coating composition for giving peelable protective film |
| US6149970A (en) * | 1996-11-28 | 2000-11-21 | Herberts Gmbh & Co. Kg | Aqueous protective coating agent |
| US5945462A (en) * | 1997-10-02 | 1999-08-31 | Loctite Corporation | Temporary protective coatings for precision surfaces |
| US6250512B1 (en) | 1997-10-02 | 2001-06-26 | Loctite Corporation | Temporary protective coatings for precision surfaces |
| WO2008153622A1 (en) * | 2007-06-06 | 2008-12-18 | Centre Luxembourgeois De Recherches Pour Le Verre Et La Ceramique S.A. (C.R.V.C.) | Method of making coated glass article, and intermediate product used in same |
| US8236116B2 (en) | 2007-06-06 | 2012-08-07 | Centre Luxembourgeois De Recherches Pour Le Verre Et Al Ceramique S.A. (C.R.V.C.) | Method of making coated glass article, and intermediate product used in same |
| US8506737B2 (en) | 2007-06-06 | 2013-08-13 | Centre Luxembourgeois De Recherches Pour Le Verre Et Al Ceramique S.A. (C.R.V.C.) | Method of making coated glass article, and intermediate product used in same |
Also Published As
| Publication number | Publication date |
|---|---|
| AU5107390A (en) | 1990-08-13 |
| PT92933A (en) | 1990-07-31 |
| JPH04504433A (en) | 1992-08-06 |
| IE900239L (en) | 1990-07-23 |
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