+

US6503495B1 - Cosmetic compositions having improved wear and beauty - Google Patents

Cosmetic compositions having improved wear and beauty Download PDF

Info

Publication number
US6503495B1
US6503495B1 US08/951,285 US95128597A US6503495B1 US 6503495 B1 US6503495 B1 US 6503495B1 US 95128597 A US95128597 A US 95128597A US 6503495 B1 US6503495 B1 US 6503495B1
Authority
US
United States
Prior art keywords
water
vinyl
group
mascara composition
mixtures
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US08/951,285
Other languages
English (en)
Inventor
Ali Abdelaziz Alwattari
Edward Martin Bartholomey
Edward Dewey Smith, III
David Edmund Tarantino
David William Walling
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Noxell Corp
Galleria Co
Original Assignee
Procter and Gamble Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Procter and Gamble Co filed Critical Procter and Gamble Co
Priority to US08/951,285 priority Critical patent/US6503495B1/en
Assigned to PROCTER & GAMBLE COMPANY, THE reassignment PROCTER & GAMBLE COMPANY, THE ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: ALWATTARI, ALI A., BARTHOLOMEY, EDWARD M., SMITH, III. EDWARD D., TARANTINO, DAVID E., WALLING, DAVID W.
Application granted granted Critical
Publication of US6503495B1 publication Critical patent/US6503495B1/en
Assigned to JPMORGAN CHASE BANK, N.A. reassignment JPMORGAN CHASE BANK, N.A. IP SECURITY AGREEMENT Assignors: NOXELL CORPORATION
Assigned to GALLERIA CO. reassignment GALLERIA CO. ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: PROCTER AND GAMBLE COMPANY
Assigned to NOXELL CORPORATION reassignment NOXELL CORPORATION ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: GALLERIA CO.
Anticipated expiration legal-status Critical
Assigned to GALLERIA CO. reassignment GALLERIA CO. CORRECTIVE ASSIGNMENT TO CORRECT THE THE NAME OF ASSIGNOR PREVIOUSLY RECORDED ON REEL 040437 FRAME 0133. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT. Assignors: THE PROCTER AND GAMBLE COMPANY
Assigned to JPMORGAN CHASE BANK N.A. reassignment JPMORGAN CHASE BANK N.A. SECURITY INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: NOXELL CORPORATION
Assigned to NOXELL CORPORATION reassignment NOXELL CORPORATION RELEASE BY SECURED PARTY (SEE DOCUMENT FOR DETAILS). Assignors: JPMORGAN CHASE BANK, N.A.
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/41—Amines
    • A61K8/416—Quaternary ammonium compounds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/26—Aluminium; Compounds thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8129—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical; Compositions of hydrolysed polymers or esters of unsaturated alcohols with saturated carboxylic acids; Compositions of derivatives of such polymers, e.g. polyvinylmethylether
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • A61K8/8152—Homopolymers or copolymers of esters, e.g. (meth)acrylic acid esters; Compositions of derivatives of such polymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/02—Preparations containing skin colorants, e.g. pigments
    • A61Q1/10—Preparations containing skin colorants, e.g. pigments for eyes, e.g. eyeliner, mascara

Definitions

  • the present invention relates to cosmetic compositions, particularly eye make-up compositions, most particularly mascaras, comprising water-insoluble polymeric material in the form of an aqueous emulsion and water-soluble, film-forming polymers.
  • cosmetic compositions particularly eye make-up compositions, most particularly mascaras, comprising water-insoluble polymeric material in the form of an aqueous emulsion and water-soluble, film-forming polymers.
  • the compositions herein utilize organophilic clays wherein the clays physically complex with the polymers. This serves to reinforce the film applied to the lashes such that smudging & smearing of the mascara is prevented.
  • Eye make-up compositions including mascara, are significant products in the cosmetics market. Mascara enhances the beauty of the wearer by coating the eye lashes, or in some instances eyebrows, with color.
  • Eye makeup compositions comprising polymeric emulsions in order to eliminate smudging are well known in the art and typically include water-insoluble polymers, also referred to as latexes.
  • water-insoluble polymers also referred to as latexes.
  • Such compositions including eye shadows as disclosed in U.S. Pat. No. 3,639,572, Henrich, issued Feb. 1, 1972; and mascaras as disclosed in U.S. Pat. No. 4,423,031, Murui et al., issued Dec. 27, 1983; and European Patent Application (EPA) 0568035, published Nov. 3, 1993.
  • These compositions include plasticizers or solvents to assist in forming films using said latexes.
  • These compositions are known to contain thickeners to adjust the viscosity of the composition. Said thickeners include water-soluble and water-swellable polymers, typically known for such use in the cosmetic art.
  • compositions known in the art that avoid combining plasticizers and insoluble-polymers are exemplified in EPO 0530084, published Mar. 3, 1993.
  • This application discloses compositions comprising a internal phase and a external phase, wherein the external phase contains at least one water-soluble polymer and the internal phase contains at least 50% wax.
  • Said composition may contain other materials routinely used in cosmetic compositions including water-insoluble polymers.
  • L'Oreals patent application discloses water-resistant composition for eyelashes containing at least one wax, at least one “consistency” agent, at least one volatile organic solvent and 1-35% (by weight of the composition) of an aqueous solution of at least one water-soluble, film-forming polymer.
  • the level of water-soluble, film-forming polymers is between 0.1% and 55%, and does not contain any emulsifying agents.
  • the processing instructions direct one to disperse the aqueous phase into the oil phase thereby making the composition a water-in-oil emulsion.
  • the “consistency agent” (referred to in the specification as a “stability agent”) is selected from the group of organically treated argyles.
  • Organophilic clays are known for use with organic solvent and oil based systems. The benefits derived from the use of organophilic clays in these systems is three-fold. Organophilic clays provide viscosity, flow control and stability to these solvent-based and oil-based systems. This is similar to the way hydrophilic clay thickeners are used water-based products.
  • organoclay reaction products of an organic quaternary amine with either hectorite or bentonite clay, are capable of swelling and gelling above mentioned organic-based systems to gel various hydrocarbon and natural oils, solvents and synthetic liquids; see “Controlling Cosmetic Rheology,” NL Industries (1985), p6.
  • organic solvent-based and oil solvent-based systems include those which are anhydrous or contain water as the dispersed phase as in water-in-oil emulsion systems. Regardless of which of the organic or oil based system are employed, it is understood that the organophilic clays are dispersed in the lipophilic phase to thicken the viscosity of the oils and the vehicle overall. In this manner, they may also be combined with oil-soluble polymeric or resin materials.
  • organophilic clays can benefit from the use of organophilic clays.
  • organophilic clays By experimentation and ingenuity, it has been surprisingly found incorporating organophilic clays into oil-in-water cosmetic compositions as disclosed herein provides additional wear and beauty benefits not realized in the art.
  • the present invention is for mascara compositions, removable with soap and water, that provide surprising beauty and wear benefits as compared to compositions known in the art.
  • These compositions comprise from about 3% to about 60% water-insoluble polymeric material, from about 2% to about 50% water-soluble, film-forming polymers, and from about 0.05% to about 20.0% organophilic clays.
  • compositions of the present invention can be fabricated in a multitude of forms, such as creams, pastes and solids. All percentages are by weight of the cosmetic composition unless otherwise indicated. All solutions are on a weight/weight concentration unless otherwise indicated.
  • the mascara composition of the present invention comprises water-insoluble polymeric materials in an aqueous emulsion.
  • Said water-insoluble polymeric materials disclosed in the art as latexes, are aqueous emulsions or dispersions of polymeric materials comprising polymers formed from monomers, said monomer derivatives, mixtures of said monomers, mixtures of said monomer derivatives, natural polymers and mixtures thereof.
  • Said polymeric material also include chemically modified versions of the above polymers.
  • These water-insoluble polymeric materials of the present invention comprise from about 3% to about 60%; preferably from about 4% to about 40% and most preferably from about 5% to about 30% by weight of the composition.
  • Water-insoluble polymeric material of the present invention comprise monomers selected from the group consisting of aromatic vinyls, dienes, vinyl cyanides, vinyl halides, vinylidene halides, vinyl esters, olefins and their isomers, vinyl pyrrolidone, unsaturated carboxylic acids, alkyl esters of unsaturated carboxylic acids, hydroxy derivatives of alkyl esters of unsaturated carboxylic acids, amides of unsaturated carboxylic acids, amine derivatives of unsaturated carboxylic acids, glycidyl derivatives of alkyl esters of unsaturated carboxylic acids, olefinic diamines and isomers, aromatic diamines, terephthaloyl halides, olefinic polyols and mixtures thereof.
  • Preferred monomers are selected from the group consisting of aromatic vinyls, dienes, vinyl esters, olefins and their isomers, unsaturated carboxylic acids, alkyl esters of unsaturated carboxylic acids, hydroxy derivatives of alkyl esters of unsaturated carboxylic acids, amides of unsaturated carboxylic acids and mixtures thereof.
  • Most preferred monomers are selected from the group consisting of aromatic vinyls, dienes, vinyl esters, alkyl esters of unsaturated carboxylic acids, hydroxy derivatives of alkyl esters of unsaturated carboxylic acids and mixtures thereof.
  • the polymerization process for making said polymeric material of the present invention is well known in the art. Such processes are disclosed in Kirk Othmer, Encyclopedia of Chemical Technology, Volume 14, “Latex Technology” 3rd Ed. 1981; incorporated herein by reference.
  • Specific polymeric material useful in the present invention include, but, are not necessarily limited to the Syntran Series (of latexes) from Interpolymer Corporation, for example Syntran 5170, Syntran EX33-1, Syntran EX30-1, and Syntran 5130 (acrylates copolymers formulated with added ammonia, propylene glycol, preservative and surfactant) and Syntran 5002 (styrene/acrylates/methacrylate copolymer formulated with added ammonia, propylene glycol, preservative and surfactant); the Primal Series (acrylic latexes) from Rohm & Hass; Appretan V (styrene/acrylic ester copolymer latexes) from Hoechst; Vinac (polyvinylacetate latex) from Air Products; UCAR latex resin 130 (polyvinylacetate latex) from Union Carbide; Rhodopas A Series (polyvinylacetate latexes) from Rhone Poulenc; App
  • the mascara composition of the present invention comprises water-soluble, film forming polymers.
  • Water-soluble, film-forming polymers are defined herein to mean polymers which are soluble in water, water-cosolvent mixtures, such as ethanol/water, pH adjusted water, and/or tempered solutions of the above to facilitate solubilization of the polymers.
  • Water-soluble, film forming polymers comprise from about 0.1% to about 50%, preferably from about 1% to about 30%, and most preferably from about 1.5% to about 10% of the composition.
  • the film forming, water-soluble polymers comprise polymers formed from monomers, said monomer derivatives, mixtures of said monomers, mixtures of said monomer derivatives, natural polymers and mixtures thereof.
  • the water-soluble, film forming polymers disclosed herein also include chemically modified versions of the above disclosed polymers.
  • Said monomers are selected from the group consisting of olefin oxides, vinyl pyrrolidone, vinyl esters, vinyl alcohols, vinyl cyanides, oxazoline, carboxylic acids and esters and mixtures thereof.
  • Preferred vinyl pyrrolidone polymers are selected from the group consisting of polyvinylpyrrolidone, vinyl acetate/vinyl pyrrolidone copolymer and mixtures thereof.
  • Preferred polyvinyl esters are selected form the group consisting of vinyl acetate/crotonic acid copolymer, vinyl acetate/crotonic acid/vinyl neodecanoate copolymer and mixtures thereof
  • Preferred vinyl alcohol polymers are selected from the group consisting of vinyl alcohol/vinyl acetate, vinyl alcohol/poly(alkyleneoxy)acrylate, vinyl alcohol/vinyl acetate/poly-(alkyleneoxy)acrylate and mixtures thereof.
  • Preferred olefin oxides are selected from the group consisting of polyethylene oxide, polypropylene oxide and mixtures thereof.
  • Preferred polycarboxylic acids and their esters are selected from the group consisting of acrylates, acrylates/otylacrylamide copolymers and mixtures thereof.
  • the preferred oxazoline is polyoxazoline.
  • Water-soluble, film forming polymers of the present invention comprise natural polymers selected from the group consisting of cellulose derivatives, algin and its derivatives, starch and its derivatives, guar and its derivatives, shellac polymers, and mixtures thereof.
  • Preferred cellulose derivatives are selected from the group consisting of hydroxyethylcellulose, hydroxypropylcellulose, hydroxypropyl methylcellulose, ethylhydroxyethyl cellulose and mixtures thereof.
  • Specific water-soluble, film-forming polymers used in the present invention include, but are not necessarily limited to Polyox WSR (polyethyleneoxide polymers) from Union Carbide; Natrosol 250 (hydroxyethylcellulose) from Aqualon; Cellosize (hydroxyethylcellulose) from Union Carbide; Airvol (polyvinylalcohol copolymer) from Air Products and Chemicals, preferably all commercially available grades like Airvol 103, Airvol 325, Airvol 540, Airvol 523S; Vinex from Air Products and Chemicals, preferably all commercially available grades such as Vinex 1003, Vinex 2034, Vinex 2144, Vinex 2019; PEOX (polyethyloxazoline) from Polymer Chemistry Innovations; PVP K Series (polyvinylpyrrolidone) from International Specialty Products; Luviskol K Series (polyvinylpyrrolidone) from BASF; PVP/VA (vinyl acetate/vinyl pyrrolidone copoly
  • orgaophilic clays are know for use in organic solvent-based and oil-based systems, including anhydrous and water-in-oil mascara compositions. While such a system is known for industrial use, it has not been previously applied to the cosmetic arts; see Tie Lan and Dr. T. J. Pinnavaia (Dept. of Chemistry), CMS Courier, Vol I Issue 8, July 1994; “Polymer-Clay Nanocomposite Materials”, pp.2-3 disclosing the addition of organophilic clays to nylon-6, improve the tensile strength, modulus, rheology and thermal capacity of plastics used in automobile production.
  • organophilic clays used in sufficient concentrations within an aqueous-based or oil-in-water emulsions results in providing mascara compositions with surprising results including the formation of a physical complex with the water-insoluble, film-forming polymers in the present invention.
  • This complexing of the clays and film-forming polymers yields a composite film that is reinforced by the organophilic clay and thereby preventing smudging or smearing of the product, especially in the case of mascaras.
  • the hydrophobic properties of organophilic clays are transferred to the aqueous-based emulsion, thereby imparting a degree of water-resistance to the product. Therefore, a new set of benefits is realized, different from conventional teachings in the cosmetic industry. And these benefits directly impact the overall stability of the cosmetic film on the substrate resulting in long-wear for the consumer.
  • the organophilic clays are used at levels from about 0.05% to about 20.0%, preferably 1% to about 10% and most preferably from about 2% to about 5% of the compositions of the present invention. Whether the clay is commercially available or not is not a limitation of the present invention. However, the commercially clays are logically preferred.
  • Clays are generally considered amorphous and crystalline. Among the amorphous clays are those that belong to the allophane group. Crystalline types of clays include two-layer type clays, three layer-type clays, regular mixed-layer type clays and chain structure type clays; see Grim, R. E. Mineralogy, Second Edition, McGraw-Hill, N.Y., 1968.
  • Two-layer type clays include those that are equi-dimensional and elongate.
  • Equi-dimensional clays include the kaolinite group of clays.
  • the elongate clays include the halloysite group of clays.
  • Three-layer type clays include expanding lattice clays including equi-dimensional and elongate clays as well as non-expanding lattice clays. Expanding lattice, equi-dimensional clays include smectite and vermiculite groups of clays. The smectite group of clays consists of montmorillonite, bentonite and sauconite.
  • Expanding lattice, elongate clays include the smectite group of clays consisting of nontronite hectorite and saponite.
  • the non-expanding lattice clays include illite.
  • the regular mixed-layer type clays include the chlorite group of clays.
  • the chain structure types of clays include attapulgite and sepiolite types of clay.
  • Organophilic clays are formed by modifying the above identified clays with compounds selected from the group consisting of quaternary amines, tertiary amines, amine acetates, imidazolines, amine soaps, fatty sulfates, alkyl aryl sulfonates, amine oxides, ethoxylated alkyl phenols and mixtures thereof. These materials are combined with the above clays under ion-exchange conditions renders the clays organophilic.
  • organophilic clays for used as the organophilic clays of the present invention are those selected from the group of montmorillonite, bentonite, hectorite, attapulgite, sepiolite and mixtures thereof.
  • organophilic clays for use in the present invention are the following commercially available ones including:
  • Bentone 34 (Rheox Corp.)—Quaternium-18 Bentonite
  • Tixogel VP United Catalysts—Quaternium-18 Bentonite
  • Bentone 38 (Rheox Corp.)—Quaternium-18 Hectorite
  • Bentone SD-3 (Rheox Corp.)—Dihydrogenated Tallow Benzylmonium Hectorite
  • Bentone 27 (Rheox Corp.)—Stearalkonium Hectorite
  • Tixogel LG (United Catalysts)—Stearalkonium Bentonite
  • Vistrol 1265 (Cimbar)—Organophilic Attapulgite.
  • organophilic clays can also be purchased as pre-dispersed organophilic clay in either an oil or an organic solvent.
  • the materials are in the form of a heavy paste that can be readily dispersed into the formulation. Such materials include Mastergels by Rheox, United Catalysts, and Southern Clay.
  • compositions of this invention contain an effective amount of “activator” for the organically modified hectorite and bentonite clays.
  • activators are known in the art, including for example, propylene carbonate, ethanol, and mixtures thereof.
  • the preferred activator for use is propylene carbonate.
  • the ratio of clay to activator is about 3:1.
  • Optional ingredients useful in the present invention are selected based on either the various forms or attributes the composition is to have.
  • the most preferred embodiments of the present invention are oil-in-water emulsions.
  • Some of the most common optional ingredients include oils and fats, emulsifiers, waxes, pigments and mixtures thereof.
  • Mascara compositions of the present invention include oil-in-water emulsion compositions. These compositions require a lipophilic material which forms the internal phase of the composition. Said lipophilic materials typically comprise oils and fats generally known for use in the cosmetic arts.
  • Oils typically used in cosmetics include those selected from the group consisting of polar oils, non-polar oils, volatile oils, non-volatile oils and mixtures thereof. These oils may be saturated or unsaturated, straight or branched chained, aliphatic or aromatic hydrocarbons.
  • Preferred oils include non-polar volatile hydrocarbons including isodecane (such as Permethyl-99A®, available from Presperse Inc.) and the C 7 -C 8 through C 12 -C 15 isoparaffins (such as the Isopar® Series available from Exxon Chemicals), as well as cyclomethicone (such as DC Fluids 244, 245, 344, 345).
  • isodecane such as Permethyl-99A®, available from Presperse Inc.
  • C 7 -C 8 through C 12 -C 15 isoparaffins such as the Isopar® Series available from Exxon Chemicals
  • cyclomethicone such as DC Fluids 244, 245, 344, 345.
  • Fats employed according to the invention are selected from the group consisting of fats derived from animals, vegetables, synthetically derived fats, and mixtures thereof wherein said fats have a melting point from about 55° C. to about 100° C. and a needle penetration, as measured according to the American standard ASTM D5, from about 3 to about 40 at 25° C.
  • the fats selected for use in the present invention are fatty acid esters which are solids at room temperature and exhibit crystalline structure.
  • fatty acid esters useful in the present invention include the glyceryl esters of higher fatty acids such as stearic and palmitic such as glyceryl monostearate, glyceryl distearate, glyceryl tristearate, palmitate esters of glycerol, C 18-36 triglycerides, glyceryl tribehenate and mixtures thereof.
  • a necessary components in the oil-in-water-emulsion compositions of the present invention are emulsifiers.
  • emulsifiers are typically used at levels from about 0.1% to about 40%, preferably from about 0.5% to about 30%.
  • HLB hydrophilic-lipophilic balance value
  • emulsifiers are selected from those known in the art and mixtures thereof including those in McCutcheon's Volume 1, Emulsifiers & Detergents, 1994, North American Edition, pp. 236-239; herein incorporated by reference.
  • Waxes are defined as lower-melting organic mixtures or compounds of high molecular weight, solid at room temperature and generally similar in composition to fats and oils except that they contain no glycerides. Some are hydrocarbons, others are esters of fatty acids and alcohols. Waxes useful in the present invention are selected from the group consisting of animal waxes, vegetable waxes, mineral waxes, various fractions of natural waxes, synthetic waxes, petroleum waxes, ethylenic polymers, hydrocarbon types such as Fischer-Tropsch waxes, silicone waxes, and mixtures thereof wherein the waxes have a melting point between 55° and 100° C. and a needle penetration, as measured according to the American standard ASTM D5, of 3 to 40 at 25° C.
  • the principle of the measurement of the needle penetration according to the standards ASTM D5 consists in measuring the depth, expressed in tenths of a millimeter, to which a standard needle (weighing 2.5 g and placed in a needle holder weighing 47.5 g, i.e. a total of 50 g) penetrates when placed on the wax for 5 seconds.
  • Waxes are used at levels in order to provide sufficient bulk material that resists drying out after application, providing thickness to the lashes.
  • Levels of wax commonly found in the art are from about 1% to about 40%.
  • the specific waxes useful in the present invention are selected from the group consisting of beeswax, lanolin wax, shellac wax (animal waxes); carnauba, candelilla, bayberry (vegetable waxes); ozokerite, ceresin, (mineral waxes); paraffin, microcrystalline waxes (petroleum waxes); polyethylene, (ethylenic polymers); polyethylene homopolymers (Fischer-Tropsch waxes); C 24-45 alkyl methicones (silicone waxes); and mixtures thereof Most preferred are beeswax, lanolin wax, carnauba, candelilla, ozokerite, ceresin, paraffins, microcrystalline waxes, polyethylene, C 24-45 alkyl methicones, and mixtures thereof.
  • the solids component of the mascara compositions of the present invention contain cosmetically acceptable pigments selected from the group consisting of inorganic pigments, organic pigments, and pearlescent pigments. When employed, the pigments are present in proportions depending on the color and the intensity of the color which it is intended to produce.
  • the level of pigments in the solid portion of the mascara composition of present invention is from about 3% to about 30%, preferably from about 5% to about 20%.
  • Pigments are selected from the group consisting of inorganic pigments, organic lake pigments, pearlesent pigments, and mixtures thereof. Said pigments may optionally be surface-treated within the scope of the present invention but are not limited to treatments such as silicones, perfluorinated compounds, lecithin, and amino acids.
  • Inorganic pigments useful in the present invention include those selected from the group consisting of rutile or anatase titanium dioxide, coded in the Color Index under the reference CI 77,891; black, yellow, red and brown iron oxides, coded under references CI 77,499, 77, 492 and, 77,491; manganese violet (CI 77,742); ultramarine blue (CI 77,007); chromium oxide (CI 77,288); chromium hydrate (CI 77,289); and ferric blue (CI 77,510) and mixtures thereof.
  • the organic pigments and lakes useful in the present invention include those selected from the group consisting of D&C Red No. 19 (CI 45,170), D&C Red No. 9 (CI 15,585), D&C Red NO. 21 (CI 45,380), D&C Orange No. 4 (CI 15,510), D&C Orange No. 5 (CI 45,370), D&C Red No. 27 (CI 45,410), D&C Red No. 13 (CI 15,630), D&C Red No. 7 (CI 15,850), D&C Red No. 6 (CI 15,850), D&C Yellow No. 5 (CI 19,140), D&C Red No. 36 (CI 12,085), D&C Orange No. 10 (CI 45,425), D&C Yellow No. 6 (CI 15,985), D&C Red No. 30 (CI 73,360), D&C Red No. 3 (CI 45,430) and the dye or lakes based on Cochineal Carmine (CI 75,570) and mixtures thereof.
  • D&C Red No. 19 CI 45,170
  • the pearlescent pigments useful in the present invention include those selected from the group consisting of the white pearlescent pigments such as mica coated with titanium oxide, bismuth oxychloride, colored pearlescent pigments such as titanium mica with iron oxides, titanium mica with ferric blue, chromium oxide and the like, titanium mica with an organic pigment of the above-mentioned type as well as those based on bismuth oxychloride and mixtures thereof.
  • the mascara composition of the present invention contain a preservative system to inhibit microbiological growth and maintain the integrity of the product.
  • the preservative system does not have a detrimental effect on the composition.
  • optional ingredients are cosmetic fillers including, but not limited to, mica, talc, nylon, polyethylene, silica, polymethacrylate, kaolin, teflon; cosmetic preservatives including, but not limited to, methylparaben, propylparaben, butylparaben, ethylparaben, potassium sorbate, trisodium EDTA, phenoxyethanol, ethyl alcohol, diazolidinyl urea, benzyl alcohol, imidazolidinyl urea, quaternium-15. Also, additives such as tall oil glycerides are easily incorporated into emulsion forms of the mascara.
  • Example #1 Ingredient W/W % Deionized Water 49.96 Synthetic Wax 7.00 Glycerol Monostearate 3.00 Carnauba Wax 2.00 Black Iron Oxide 7.25 Quaternium-18 Hectorite 1 4.00 Propylene Carbonate 1.33 Stearic Acid 2.75 Oleic Acid 0.75 Triethanolamine 1.75 Trisodium EDTA 0.10 Polyvinyl Alcohol 3.00 Propylene Glycol 2.00 Simethicone 2 0.20 Ammonium Acrylates Copolymer 3 12.20 Ethyl Alcohol 4 1.00 Benzyl Alcohol 0.65 Phenoxyethanol 0.28 Propylparaben 0.10 Methylparaben 0.20 Ethylparaben 0.20 Panthenol 5 0.28 1 available as Bentone 38 from Rheox. 2 available as Antifoam from Dow Corning. 3 available as Syntran EX33-1 (41% Stock Solution) from Interpolymer Corporation. 4 available as SD Alcohol 40-B from Warner Graham Company. 5 available as dl-Panthenol from Roche.
  • Example #2 Ingredient W/W % Deionized Water 40.18 Synthetic Wax 1.50 Glycerol Monostearate 7.25 Carnauba Wax 2.00 Black Iron Oxide 7.25 Quaternium-18 Hectorite 1 3.75 Propylene Carbonate 1.25 Stearic Acid 2.75 Oleic Acid 1.00 Triethanolamine 1.75 Xanthan Gum 0.10 Trisodium EDTA 0.10 Polyvinyl Alcohol 1.50 Acrylates Copolymer 2 5.17 Propylene Glycol 2.00 Simethicone 3 0.20 Ammonium Acrylates Copolymer 18.29 Lecithin 1.25 Ethyl Alcohol 5 1.00 Benzyl Alcohol 0.65 Phenoxyethanol 0.28 Propylparaben 0.10 Methylparaben 0.20 Ethylparaben 0.20 Panthenol 6 0.28 1 available as Bentone 38 from Rheox.
  • Example #3 Ingredient W/W % Deionized Water 41.95 Synthetic Wax 3.00 Glycerol Monostearate 6.00 Carnauba Wax 4.50 Black Iron Oxide 7.25 Quaternium-18 Hectorite 1 2.25 Propylene Carbonate 0.75 Stearic Acid 2.75 Oleic Acid 0.75 Triethanolamine 1.75 Trisodium EDTA 0.10 Polyvinyl Alcohol 4.00 Acrylates Copolymer 2 1.72 Propylene Glycol 2.00 Simethicone 3 0.20 Ammonium Acrylates Copolymer 4 17.07 Lecithin 1.25 Ethyl Alcohol 5 1.00 Benzyl Alcohol 0.65 Phenoxyethanol 0.28 Propylparaben 0.10 Methylparaben 0.20 Ethylparaben 0.20 Panthenol 6 0.28 1 available as Bentone 38 from Rheox.
  • Example #4 Ingredient W/W % Deionized Water 41.15 Synthetic Wax 4.00 Glycerol Monostearate 6.00 Carnauba Wax 3.75 Black Iron Oxide 9.00 Quaternium-18 Hectorite 1 4.00 Propylene Carbonate 1.33 Stearic Acid 2.75 Oleic Acid 1.00 Triethanolamine 1.75 Trisodium EDTA 0.10 Propylene Glycol 1.00 Simethicone 2 0.20 Ammonium Acrylates Copolymer 3 19.51 Lecithin 1.75 Ethyl Alcohol 4 1.00 Benzyl Alcohol 0.65 Phenoxyethanol 0.28 Propylparaben 0.10 Methylparaben 0.20 Ethylparaben 0.20 Panthenol 5 0.28 1 available as Bentone 38 from Rheox. 2 available as Antifoam from Dow Corning. 3 available as Syntran EX33-1 (41% Stock Solution) from Interpolymer Corporation. 4 available as SD Alcohol 40-B from Warner Graham Company. 5 available as dl-Panthenol from Roche.
  • Example #5 Ingredient W/W % Deionized Water 37.43 Synthetic Wax 3.00 Glycerol Monostearate 7.00 Carnauba Wax 1.00 Black Iron Oxide 7.25 Quaternium-18 Hectorite 1 3.75 Propylene Carbonate 1.25 Stearic Acid 2.75 Oleic Acid 0.75 Triethanolamine 1.75 Xanthan Gum 0.40 Trisodium EDTA 0.10 Polyvinyl Alcohol 1.00 Acrylates Copolymer 2 6.90 Propylene Glycol 2.00 Simethicone 3 0.20 Ammonium Acrylates Copolymer 4 19.51 Lecithin 1.25 Ethyl Alcohol 5 1.00 Benzyl Alcohol 0.65 Phenoxyethanol 0.28 Propylparaben 0.10 Methylparaben 0.20 Ethylparaben 0.20 Panthenol 6 0.28 1 available as Bentone 38 from Rheox.
  • Example #6 Ingredient W/W % Deionized Water 40.42 Synthetic Wax 3.00 Glycerol Monostearate 5.00 Carnauba Wax 1.00 Micronized Black 6.50 Quaternium-18 Hectorite 1 6.00 Propylene Carbonate 2.00 Stearic Acid 2.75 Oleic Acid 1.00 Triethanolamine 1.75 Xanthan Gum 0.10 Trisodium EDTA 0.10 Polyvinyl Alcohol 1.00 Acrylates Copolymer 2 6.90 Propylene Glycol 1.00 Semithicone 3 0.20 Ammonium Acrylates Copolymer 4 17.07 Lecithin 1.50 Ethyl Alcohol 5 1.00 Benzyl Alcohol 0.65 Phenoxyethanol 0.28 Propylparaben 0.10 Methylparaben 0.20 Ethylparaben 0.20 Panthenol 6 0.28 1 available as Bentone 38 from Rheox.
  • Example #7 Ingredient W/W % Deionized Water 41.22 Synthetic Wax 5.00 Glycerol Monostearate 7.50 Carnauba Wax 2.75 Black Iron Oxide 7.50 Quaternium-18 Hectorite 1 1.00 Propylene Carbonate 0.33 Stearic Acid 2.75 Oleic Acid 1.00 Triethanolamine 1.75 Xanthan Gum 0.40 Trisodium EDTA 0.10 Polyvinyl Alcohol 4.00 Acrylates Copolymer 2 1.72 Propylene Glycol 2.00 Antifoam 0.20 Ammonium Acrylates Copolymer 3 17.07 Lecithin 1.00 Ethyl Alcohol 4 1.00 Benzyl Alcohol 0.65 Phenoxyethanol 0.28 Propylparaben 0.10 Methylparaben 0.20 Ethylparaben 0.20 Panthenol 5 0.28 1 available as Bentone 38 from Rheox. 2 available as Antifoam from Dow Corning. 3 available as Syntran EX33-1 (41% Stock Solution) from Interpolymer Corporation. 4 available as SD Alcohol
  • Example #8 Ingredient W/W % Deionized Water 41.18 Synthetic Wax 1.50 Glycerol Monostearate 6.50 Carnauba Wax 2.75 Black Iron Oxide 7.25 Quaternium-18 Hectorite 1 4.00 Propylene Carbonate 1.33 Stearic Acid 2.75 Oleic Acid 1.00 Triethanolamine 1.75 Trisodium EDTA 0.10 Polyvinyl Alcohol 2.50 Acrylates Copolymer 2 1.72 Propylene Glycol 2.00 Semithicone 3 0.20 Ammonium Acrylates Copolymer 4 19.51 Lecithin 1.25 Ethyl Alcohol 5 1.00 Benzyl Alcohol 0.65 Phenoxyethanol 0.28 Propylparaben 0.10 Methylparaben 0.20 Ethylparaben 0.20 Panthenol 6 0.28 1 available as Bentone 38 from Rheox.
  • Example #9 Ingredient W/W % Deionized Water 41.88 Synthetic Wax 2.00 Glycerol Monostearate 5.25 Carnauba Wax 3.00 Black Iron Oxide 7.25 Quaternium-18 Hectorite 1 4.00 Propylene Carbonate 1.33 Stearic Acid 2.75 Oleic Acid 0.80 Triethanolamine 1.75 Trisodium EDTA 0.10 Polyvinyl Alcohol 2.50 Acrylates Copolymer 2 1.72 Propylene Glycol 2.00 Semithicone 3 0.20 Ammonium Acrylates Copolymer 4 19.51 Lecithin 1.25 Ethyl Alcohol 5 1.00 Benzyl Alcohol 0.65 Phenoxyethanol 0.28 Propylparaben 0.10 Methylparaben 0.20 Ethylparaben 0.20 Panthenol 6 0.28 1 available as Bentone 38 from Rheox.
  • a second vessel equipped with mixing and heating, add water followed by the water-soluble, film-forming polymers, and the remainder of the water-dispersible components.
  • the mixture of water and water-soluble film forming polymers can be made up ahead of the processing of the mascara composition. Mix with heating until this aqueous mixture is about 90-95° C. Q.S. for any water loss from said aqueous mixture.

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Cosmetics (AREA)
US08/951,285 1996-10-31 1997-10-16 Cosmetic compositions having improved wear and beauty Expired - Lifetime US6503495B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
US08/951,285 US6503495B1 (en) 1996-10-31 1997-10-16 Cosmetic compositions having improved wear and beauty

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US74057896A 1996-10-31 1996-10-31
US08/951,285 US6503495B1 (en) 1996-10-31 1997-10-16 Cosmetic compositions having improved wear and beauty

Related Parent Applications (1)

Application Number Title Priority Date Filing Date
US74057896A Continuation 1996-10-31 1996-10-31

Publications (1)

Publication Number Publication Date
US6503495B1 true US6503495B1 (en) 2003-01-07

Family

ID=24977149

Family Applications (1)

Application Number Title Priority Date Filing Date
US08/951,285 Expired - Lifetime US6503495B1 (en) 1996-10-31 1997-10-16 Cosmetic compositions having improved wear and beauty

Country Status (12)

Country Link
US (1) US6503495B1 (fr)
EP (1) EP0946130B1 (fr)
JP (2) JP2001503063A (fr)
CN (1) CN1190181C (fr)
AT (1) ATE239440T1 (fr)
AU (1) AU732059B2 (fr)
CA (1) CA2269990C (fr)
CO (1) CO4920199A1 (fr)
CZ (1) CZ288877B6 (fr)
DE (1) DE69721813T2 (fr)
ES (1) ES2199380T3 (fr)
WO (1) WO1998018431A2 (fr)

Cited By (40)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20040126332A1 (en) * 2002-12-30 2004-07-01 Colgate-Palmolive Company Dentifrice containing functional film flakes
US20040191197A1 (en) * 2003-03-04 2004-09-30 Intercos S.P.A. Cosmetic composition containing polyisoprene
US20050112080A1 (en) * 2003-11-26 2005-05-26 Hongjie Cao Use of acrylates copolymer as waterproofing agent in personal care applications
US20050244355A1 (en) * 2004-04-30 2005-11-03 Sabino Michael C Long-wearing cosmetic compositions with improved shine
US20060024338A1 (en) * 2004-07-27 2006-02-02 Hegedus Charles R Cosmetic compositions incorporating vinyl acetate-ethylene polymers
US20060051309A1 (en) * 2002-11-13 2006-03-09 Maike Patzer Cosmetic dressing containing a waxy cmponent, a film-forming agent and a gel-forming substance
KR100716312B1 (ko) 2005-04-29 2007-05-08 (주)아모레퍼시픽 생크림과 유사한 제형의 화장료 조성물
US20070148213A1 (en) * 2005-12-22 2007-06-28 Sayed Ibrahim Film containing compositions
US20080199415A1 (en) * 2007-02-20 2008-08-21 L'oreal S.A. Compositions containing a bimodal film former and cross-linked starch
US20080242582A1 (en) * 2006-01-12 2008-10-02 Amcol International Corporation Compositions containing benefit agent composites pre-emulsified using colloidal cationic particles
US20080286367A1 (en) * 2007-05-14 2008-11-20 Amcol International Corporation Compositions containing benefit agent composites pre-emulsified using colloidal cationic particles
US20090035335A1 (en) * 2007-07-30 2009-02-05 Marotta Paul H Cosmetic Composition Containing a Polymer Blend
US20090148392A1 (en) * 2005-01-12 2009-06-11 Amcol International Corporation Compositions containing benefit agents pre-emulsified using colloidal cationic particles
EP2105122A1 (fr) 2003-12-16 2009-09-30 Colgate-Palmolive Company Compositions de soins personnels et oraux et procédés
US20100272821A1 (en) * 2007-09-14 2010-10-28 Juan Luis Gonzalez Segura Cosmetic Composition for External Administration in Spray Form
US20100279256A1 (en) * 2008-05-05 2010-11-04 Elizabeth Bilyeu Twohy Array of cosmetic product clusters
US20110033401A1 (en) * 2003-05-19 2011-02-10 Christopher Todd Morrissey Cosmetic Compositions Comprising a Polymer and a Colorant
US20110166370A1 (en) * 2010-01-12 2011-07-07 Charles Winston Saunders Scattered Branched-Chain Fatty Acids And Biological Production Thereof
WO2011123732A1 (fr) 2010-04-01 2011-10-06 The Procter & Gamble Company Composition comprenant des composés d'organosilicium modifiés
US20110300092A1 (en) * 2010-06-04 2011-12-08 L'oreal Mascaras obtained via multi-phase product
US20110300087A1 (en) * 2008-12-16 2011-12-08 L'oreal S.A. Transfer-resistant and long wear foundation in emulsion form containing oil absorbing powders
WO2013048919A1 (fr) * 2011-09-30 2013-04-04 L'oreal S.A. Compositions cosmétiques comprenant des substances permettant de former des films en latex
US8562960B2 (en) 2007-07-30 2013-10-22 Elc Management, Llc Cosmetic composition containing a polymer blend
EP2687590A2 (fr) 2010-04-28 2014-01-22 The Procter and Gamble Company Particules d'administration
EP2687287A2 (fr) 2010-04-28 2014-01-22 The Procter and Gamble Company Particules d'administration
WO2014138141A1 (fr) 2013-03-05 2014-09-12 The Procter & Gamble Company Compositions de sucre mélangées
WO2014149869A1 (fr) * 2013-03-15 2014-09-25 Elc Management Llc Procédé et compositions pour améliorer l'usure de produits cosmétiques colorés
US8927026B2 (en) 2011-04-07 2015-01-06 The Procter & Gamble Company Shampoo compositions with increased deposition of polyacrylate microcapsules
US8980292B2 (en) 2011-04-07 2015-03-17 The Procter & Gamble Company Conditioner compositions with increased deposition of polyacrylate microcapsules
US20150148425A1 (en) * 2013-11-25 2015-05-28 The Dial Corporation Antimicrobial composition exhibiting increased efficacy
US9162085B2 (en) 2011-04-07 2015-10-20 The Procter & Gamble Company Personal cleansing compositions with increased deposition of polyacrylate microcapsules
US9186642B2 (en) 2010-04-28 2015-11-17 The Procter & Gamble Company Delivery particle
US9308397B2 (en) 2004-04-30 2016-04-12 The Procter & Gamble Company Long-wearing cosmetic compositions
US9408785B2 (en) 2012-10-15 2016-08-09 L'oreal Hair styling compositions containing aqueous wax dispersions
US10232381B2 (en) 2014-12-19 2019-03-19 Halliburton Energy Services, Inc. Purification of organically modified surface active minerals by air classification
US20190269585A1 (en) * 2016-06-13 2019-09-05 Coty Inc. Thickening and elongation of keratinous fibers
US10413496B2 (en) 2012-10-15 2019-09-17 L'oreal Aqueous wax dispersions
US10561596B2 (en) 2014-04-11 2020-02-18 L'oreal Compositions and dispersions containing particles comprising a polymer
US10626294B2 (en) 2012-10-15 2020-04-21 L'oreal Aqueous wax dispersions containing volatile solvents
US12227720B2 (en) 2020-10-16 2025-02-18 The Procter & Gamble Company Consumer product compositions with at least two encapsulate populations

Families Citing this family (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE69718667T3 (de) * 1996-11-27 2008-02-21 The Procter & Gamble Company, Cincinnati Maskarazusammensetzungen mit verbesserten verschliess - und schönheitseigenschaften
DE19746468A1 (de) * 1997-10-21 1999-04-22 Henkel Kgaa Haar-Masara
US20010055600A1 (en) * 1999-02-09 2001-12-27 Amit R. Shah Long-wearing cosmetic compositions
MXPA02009634A (es) * 2000-03-31 2003-03-12 Procter & Gamble Composiciones cosmeticas, para aplicarse sin enjuagar, para aumentar el volumen del cabello.
FR2814674A1 (fr) * 2000-09-29 2002-04-05 Oreal Composition cosmetique filmogene aqueuse
FR2815850B1 (fr) * 2000-10-27 2003-02-14 Oreal Composition cosmetique filmogene
US6716419B2 (en) 2001-06-05 2004-04-06 The Procter & Gamble Company Pseudoplastic, film forming cosmetic compositions
DE10136883B4 (de) * 2001-07-24 2008-08-21 Coty B.V. Wasser- und abriebfestes Kosmetikum für Haare und dekorative Kosmetik
FR2852238B1 (fr) * 2003-03-11 2006-07-28 Oreal Compositions cosmetiques comprenant un copolymere d'acide methacrylique, des particules minerales insolubles et un polymere cationique et leurs utilisations
US7708981B2 (en) 2003-03-11 2010-05-04 L'oreal S.A. Cosmetic compositions comprising at least one crosslinked copolymer, at least one insoluble mineral particle and at least one polymer, and uses thereof
WO2005070374A1 (fr) * 2004-01-21 2005-08-04 Unilever Plc Composition de soins capillaires
US8211415B2 (en) * 2004-10-13 2012-07-03 L'oreal Easily removable waterproof cosmetic care and/or makeup composition comprising at least one latex or pseudolatex
JP4880912B2 (ja) * 2005-03-18 2012-02-22 株式会社コーセー 易水洗型睫用化粧料
CN101977582A (zh) 2005-09-26 2011-02-16 莱雅公司 组合物以及使用至少两种不混溶的化妆品组合物处理角蛋白被处理物的方法
US20080260836A1 (en) * 2007-04-18 2008-10-23 Thomas James Boyd Films Comprising a Plurality of Polymers
DE102009019006A1 (de) * 2009-04-17 2010-10-21 Beiersdorf Ag Maskara mit verbesserten rheologischen Eigenschaften
DE102009044637A1 (de) * 2009-11-24 2011-06-01 Bcm Kosmetik Gmbh Wimperntusche-Zubereitung mit Acrylat-Copolymeren
KR101993188B1 (ko) * 2012-01-04 2019-09-30 모멘티브 퍼포먼스 머티리얼즈 인크. 말단-관능화된 이온성 실리콘을 함유하는 퍼스널 케어 조성물
US9895307B2 (en) 2012-01-04 2018-02-20 Momentive Performance Materials Inc. Personal care compositions containing ionic silicone and film-forming agent
JP2015509919A (ja) 2012-01-19 2015-04-02 ザ プロクター アンド ギャンブルカンパニー しわ及びきめの粗い肌をなめらかにするための方法
CN104470496A (zh) 2012-05-30 2015-03-25 宝洁公司 用于减少毛发外观的美容产品
CN103805147A (zh) * 2012-11-12 2014-05-21 长江大学 一种油基钻井液有机土激活剂
CN105377219A (zh) 2013-07-15 2016-03-02 宝洁公司 用于平滑皱纹和皮肤肌理缺陷的施用的膜
JP2016532482A (ja) 2013-07-15 2016-10-20 ザ プロクター アンド ギャンブル カンパニー 皺及び肌のきめの欠点を滑らかにする組成物を適用するアプリケータ
CN105848634B (zh) * 2013-12-27 2020-06-30 株式会社高丝 皮肤用水包油型乳化化妆品
WO2016049392A1 (fr) 2014-09-26 2016-03-31 The Procter & Gamble Company Procédés de lissage de rides et d'imperfections de texture de peau
KR102096009B1 (ko) * 2018-07-27 2020-04-02 주식회사 코리아나화장품 스틱 타입의 클레이팩 화장료 조성물 및 이의 제조방법

Citations (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3639572A (en) 1967-02-27 1972-02-01 Pfizer & Co C Eyeliner composition
GB2021411A (en) 1978-03-17 1979-12-05 Shiseido Co Ltd A gel composition
US4423031A (en) 1979-11-08 1983-12-27 Shiseido Company, Ltd. Eye makeup preparation
US4917883A (en) 1989-03-16 1990-04-17 Amway Corporation Oil in water emulsion sunscreen composition
GB2238242A (en) 1989-11-20 1991-05-29 Maybe Holding Co Mascara composition containing microspheres
WO1991012793A1 (fr) 1990-03-01 1991-09-05 L'oreal COMPOSITION RESISTANTE A l'EAU POUR LE REVETEMENT DES CILS, ET SON PROCEDE DE PREPARATION
WO1992019215A1 (fr) 1991-04-26 1992-11-12 The Procter & Gamble Company Composition rendant des cosmetiques impermeables a l'eau
EP0530084A1 (fr) 1991-08-30 1993-03-03 L'oreal Composition pour le maquillage et le soin des cils et/ou sourcils et son procédé de préparation
EP0557196A1 (fr) 1992-02-21 1993-08-25 L'oreal Composition cosmétique pour le maquillage des yeux, comprenant une microdispersion de cire
WO1993016684A1 (fr) 1992-02-27 1993-09-02 L'oreal Composition cosmetique ou dermatologique sous la forme d'une dispersion huile-dans-l'eau susceptible de former des films composites
EP0568035A2 (fr) 1992-05-01 1993-11-03 Kao Corporation Composition cosmétique formulée avec un émulsion de polymères aqueuse
US5356627A (en) 1993-02-01 1994-10-18 Estee Lauder, Inc. Waterproof cosmetic compositions
US5389363A (en) 1993-04-23 1995-02-14 Revlon Consumer Products Corporation Cosmetic compositions for lengthening, coloring and curling eyelashes
US5420218A (en) * 1992-06-16 1995-05-30 Nippon Shokubai Co., Ltd. Resinous particles, method for production thereof, and uses therefor
JPH07267817A (ja) 1994-03-31 1995-10-17 Shiseido Co Ltd 水中油型メーキャップ化粧料
JPH07267828A (ja) 1994-03-31 1995-10-17 Shiseido Co Ltd 水中油型まつ毛用化粧料
US5480632A (en) * 1987-09-16 1996-01-02 Maybelline, Inc. Non-aqueous cosmetic compositions with high solids content
WO1996033690A1 (fr) 1995-04-28 1996-10-31 The Procter & Gamble Company Compositions de mascara comprenant un materiau polymere insoluble dans l'eau et des polymeres filmogenes solubles dans l'eau
WO1996036308A1 (fr) 1995-05-20 1996-11-21 The Procter & Gamble Company Compositions cosmetiques de maquillage
US5620693A (en) 1993-11-24 1997-04-15 L'oreal Mascara containing wax(es) and carboxyl-functional film-forming polymer aqueous dispersion

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
LU84210A1 (fr) * 1982-06-17 1984-03-07 Oreal Composition a base de polymeres cationiques,de polymeres anioniques et de cires destinee a etre utilisee en cosmetique
JP3020738B2 (ja) * 1992-06-24 2000-03-15 鐘紡株式会社 マスカラ
JP3405588B2 (ja) * 1994-03-31 2003-05-12 株式会社資生堂 水中油型まつ毛用化粧料
JPH0884921A (ja) * 1994-09-16 1996-04-02 Mikimoto Pharmaceut Co Ltd Ｏ／ｗ型エマルジョン用原料
JPH08217619A (ja) * 1995-02-20 1996-08-27 Shiseido Co Ltd 油中水型乳化化粧料
GB9510230D0 (en) * 1995-05-20 1995-07-19 Procter & Gamble Cosmetic make-up compositions
GB9510231D0 (en) * 1995-05-20 1995-07-19 Procter & Gamble Cosmetic make-up compositions
US5772345A (en) * 1995-06-06 1998-06-30 Simonds; James A. Shielded writing system

Patent Citations (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3639572A (en) 1967-02-27 1972-02-01 Pfizer & Co C Eyeliner composition
GB2021411A (en) 1978-03-17 1979-12-05 Shiseido Co Ltd A gel composition
US4423031A (en) 1979-11-08 1983-12-27 Shiseido Company, Ltd. Eye makeup preparation
US5480632A (en) * 1987-09-16 1996-01-02 Maybelline, Inc. Non-aqueous cosmetic compositions with high solids content
US4917883A (en) 1989-03-16 1990-04-17 Amway Corporation Oil in water emulsion sunscreen composition
GB2238242A (en) 1989-11-20 1991-05-29 Maybe Holding Co Mascara composition containing microspheres
WO1991012793A1 (fr) 1990-03-01 1991-09-05 L'oreal COMPOSITION RESISTANTE A l'EAU POUR LE REVETEMENT DES CILS, ET SON PROCEDE DE PREPARATION
WO1992019215A1 (fr) 1991-04-26 1992-11-12 The Procter & Gamble Company Composition rendant des cosmetiques impermeables a l'eau
EP0530084A1 (fr) 1991-08-30 1993-03-03 L'oreal Composition pour le maquillage et le soin des cils et/ou sourcils et son procédé de préparation
EP0557196A1 (fr) 1992-02-21 1993-08-25 L'oreal Composition cosmétique pour le maquillage des yeux, comprenant une microdispersion de cire
WO1993016684A1 (fr) 1992-02-27 1993-09-02 L'oreal Composition cosmetique ou dermatologique sous la forme d'une dispersion huile-dans-l'eau susceptible de former des films composites
EP0568035A2 (fr) 1992-05-01 1993-11-03 Kao Corporation Composition cosmétique formulée avec un émulsion de polymères aqueuse
US5420218A (en) * 1992-06-16 1995-05-30 Nippon Shokubai Co., Ltd. Resinous particles, method for production thereof, and uses therefor
US5356627A (en) 1993-02-01 1994-10-18 Estee Lauder, Inc. Waterproof cosmetic compositions
US5389363A (en) 1993-04-23 1995-02-14 Revlon Consumer Products Corporation Cosmetic compositions for lengthening, coloring and curling eyelashes
US5620693A (en) 1993-11-24 1997-04-15 L'oreal Mascara containing wax(es) and carboxyl-functional film-forming polymer aqueous dispersion
JPH07267817A (ja) 1994-03-31 1995-10-17 Shiseido Co Ltd 水中油型メーキャップ化粧料
JPH07267828A (ja) 1994-03-31 1995-10-17 Shiseido Co Ltd 水中油型まつ毛用化粧料
WO1996033690A1 (fr) 1995-04-28 1996-10-31 The Procter & Gamble Company Compositions de mascara comprenant un materiau polymere insoluble dans l'eau et des polymeres filmogenes solubles dans l'eau
WO1996036308A1 (fr) 1995-05-20 1996-11-21 The Procter & Gamble Company Compositions cosmetiques de maquillage

Non-Patent Citations (14)

* Cited by examiner, † Cited by third party
Title
Abstract: J5 5130-906, published Oct. 11, 1980 Derwent Publications Ltd.
Abstract: JP 08 084921 A, published Apr. 2, 1996 Patent Abstracts of Japan.
Abstract: JP 08 217619 A, published Aug. 27, 1996 Patent Abstracts of Japan.
C.T.F.A. Cosmetic Ingredient Handbook, pp. 587-592, 1992. 1997.
Derwent Abstract NO. 96-224461/23 (JP08084921-A), published Apr. 2, 1996.
Derwent Abstract No. 96-439418/44 (JP08217619-A), published Aug. 27, 1996.
Grim, "Organically Modified Clay Mastergels-A New Approach to Cosmetic Formulating", Mineralogy, 2nd Ed., McGraw-Hill, N.Y., p. 31-35, 1968.
Lan et al., "Polymer-Clay Nanocomposite Materials", CMS Courier, vol. 1, Issue 8, pp. -3, 1994.
McCutcheion's, vol. 1, Emulsifiers & Detergents, N. Amer. Ed., pp. 236-239, 1994.
NL Industries, Inc., "Controlling Cosmetic Pheology", p. 6, 1985.
Othmer, "Latex Technology", Encyclopedia of Chem. Tech. vol. 14, 3rd Ed., 1981.
Remington's Pharmaceutical Sciences, 15th Ed., pp. 335-337, 1975.
Schick et al., Surfactant Science Series, vol. 2, Solvent Properties Surfactant Solutions, p. 607. 1966.
Wilkinson et al., Harry's Cosmeticology, 7th Ed., p. 738, 1982.

Cited By (78)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20060051309A1 (en) * 2002-11-13 2006-03-09 Maike Patzer Cosmetic dressing containing a waxy cmponent, a film-forming agent and a gel-forming substance
US20090196843A1 (en) * 2002-11-13 2009-08-06 Schwan-Stabilo Cosmetics Gmbh & Co. Kg Cosmetic dressings containing a waxy component, a film-forming agent and a gel-forming substance
US8475771B2 (en) 2002-12-30 2013-07-02 Colgate-Palmolive Company Dentifrice containing functional film flakes
US20080160056A1 (en) * 2002-12-30 2008-07-03 Boyd Thomas J Oral and Personal Care Compositions and Methods
US7763235B2 (en) 2002-12-30 2010-07-27 Colgate-Palmolive Company Dentifrice containing functional film flakes
US9827172B2 (en) 2002-12-30 2017-11-28 Colgate-Palmolive Company Dentifrice containing functional film flakes
US20050106112A1 (en) * 2002-12-30 2005-05-19 Boyd Thomas J. Oral and personal care compositions and methods
US9498410B2 (en) 2002-12-30 2016-11-22 Colgate-Palmolive Company Oral and personal care compositions and methods
US9918909B2 (en) 2002-12-30 2018-03-20 Colgate-Palmolive Company Oral and personal care compositions and methods
US20040126332A1 (en) * 2002-12-30 2004-07-01 Colgate-Palmolive Company Dentifrice containing functional film flakes
US20080138369A1 (en) * 2002-12-30 2008-06-12 Boyd Thomas J Dentifrice Containing Functional Film Flakes
US20040191197A1 (en) * 2003-03-04 2004-09-30 Intercos S.P.A. Cosmetic composition containing polyisoprene
US7998222B2 (en) 2003-05-19 2011-08-16 The Proctor & Gamble Company Cosmetic compositions comprising a polymer and a colorant
US20110033401A1 (en) * 2003-05-19 2011-02-10 Christopher Todd Morrissey Cosmetic Compositions Comprising a Polymer and a Colorant
US20050112080A1 (en) * 2003-11-26 2005-05-26 Hongjie Cao Use of acrylates copolymer as waterproofing agent in personal care applications
US8545859B2 (en) 2003-11-26 2013-10-01 Akzo Nobel N.V. Use of acrylates copolymer as waterproofing agent in personal care applications
EP2116219A1 (fr) 2003-12-16 2009-11-11 Colgate-Palmolive Company Compositions de soins personnels et oraux et procédés
EP2105122A1 (fr) 2003-12-16 2009-09-30 Colgate-Palmolive Company Compositions de soins personnels et oraux et procédés
EP2119426A1 (fr) 2003-12-16 2009-11-18 Colgate-Palmolive Company Compositions de soins personnels et oraux et procédés
US8318187B2 (en) 2004-04-30 2012-11-27 The Procter & Gamble Company Long-wearing cosmetic compositions with improved shine
US9308397B2 (en) 2004-04-30 2016-04-12 The Procter & Gamble Company Long-wearing cosmetic compositions
US20050244355A1 (en) * 2004-04-30 2005-11-03 Sabino Michael C Long-wearing cosmetic compositions with improved shine
US20060024338A1 (en) * 2004-07-27 2006-02-02 Hegedus Charles R Cosmetic compositions incorporating vinyl acetate-ethylene polymers
US20090148392A1 (en) * 2005-01-12 2009-06-11 Amcol International Corporation Compositions containing benefit agents pre-emulsified using colloidal cationic particles
US7871972B2 (en) * 2005-01-12 2011-01-18 Amcol International Corporation Compositions containing benefit agents pre-emulsified using colloidal cationic particles
KR100716312B1 (ko) 2005-04-29 2007-05-08 (주)아모레퍼시픽 생크림과 유사한 제형의 화장료 조성물
WO2007076466A2 (fr) 2005-12-22 2007-07-05 Colgate-Palmolive Company Compositions contenant un film
US20070148213A1 (en) * 2005-12-22 2007-06-28 Sayed Ibrahim Film containing compositions
US7915214B2 (en) * 2006-01-12 2011-03-29 Amcol International Corporation Compositions containing benefit agent composites pre-emulsified using colloidal cationic particles
US20080242582A1 (en) * 2006-01-12 2008-10-02 Amcol International Corporation Compositions containing benefit agent composites pre-emulsified using colloidal cationic particles
US20080199415A1 (en) * 2007-02-20 2008-08-21 L'oreal S.A. Compositions containing a bimodal film former and cross-linked starch
US8124060B2 (en) 2007-02-20 2012-02-28 L'oreal S.A. Compositions containing a bimodal film former and cross-linked starch
US7888306B2 (en) * 2007-05-14 2011-02-15 Amcol International Corporation Compositions containing benefit agent composites pre-emulsified using colloidal cationic particles
US20080286367A1 (en) * 2007-05-14 2008-11-20 Amcol International Corporation Compositions containing benefit agent composites pre-emulsified using colloidal cationic particles
US20090035335A1 (en) * 2007-07-30 2009-02-05 Marotta Paul H Cosmetic Composition Containing a Polymer Blend
US8562960B2 (en) 2007-07-30 2013-10-22 Elc Management, Llc Cosmetic composition containing a polymer blend
US20100272821A1 (en) * 2007-09-14 2010-10-28 Juan Luis Gonzalez Segura Cosmetic Composition for External Administration in Spray Form
US20100279256A1 (en) * 2008-05-05 2010-11-04 Elizabeth Bilyeu Twohy Array of cosmetic product clusters
US20110300087A1 (en) * 2008-12-16 2011-12-08 L'oreal S.A. Transfer-resistant and long wear foundation in emulsion form containing oil absorbing powders
US9308396B2 (en) * 2008-12-16 2016-04-12 L'oreal Transfer-resistant and long wear foundation in emulsion form containing oil absorbing powders
US8933131B2 (en) 2010-01-12 2015-01-13 The Procter & Gamble Company Intermediates and surfactants useful in household cleaning and personal care compositions, and methods of making the same
US20110166370A1 (en) * 2010-01-12 2011-07-07 Charles Winston Saunders Scattered Branched-Chain Fatty Acids And Biological Production Thereof
US20110171155A1 (en) * 2010-01-12 2011-07-14 Thomas Walter Federle Intermediates And Surfactants useful In Household Cleaning And Personal Care Compositions, And Methods Of Making The Same
WO2011088089A1 (fr) 2010-01-12 2011-07-21 The Procter & Gamble Company Intermédiaires et tensioactifs utiles dans des compositions de nettoyage ménager et d'hygiène personnelle, et leurs procédés de fabrication
WO2011123734A1 (fr) 2010-04-01 2011-10-06 The Procter & Gamble Company Polymères de soin
WO2011123739A1 (fr) 2010-04-01 2011-10-06 The Procter & Gamble Company Compositions contenant des organosilicones
WO2011123736A1 (fr) 2010-04-01 2011-10-06 The Procter & Gamble Company Compositions comprenant des polymères d'alkylsiloxane
WO2011123727A2 (fr) 2010-04-01 2011-10-06 The Procter & Gamble Company Organosilicones
WO2011123732A1 (fr) 2010-04-01 2011-10-06 The Procter & Gamble Company Composition comprenant des composés d'organosilicium modifiés
US9993793B2 (en) 2010-04-28 2018-06-12 The Procter & Gamble Company Delivery particles
EP3733827A1 (fr) 2010-04-28 2020-11-04 The Procter & Gamble Company Particules d'administration
US12133906B2 (en) 2010-04-28 2024-11-05 The Procter & Gamble Company Delivery particle
US9186642B2 (en) 2010-04-28 2015-11-17 The Procter & Gamble Company Delivery particle
US11096875B2 (en) 2010-04-28 2021-08-24 The Procter & Gamble Company Delivery particle
EP2687590A2 (fr) 2010-04-28 2014-01-22 The Procter and Gamble Company Particules d'administration
EP2687287A2 (fr) 2010-04-28 2014-01-22 The Procter and Gamble Company Particules d'administration
US20110300092A1 (en) * 2010-06-04 2011-12-08 L'oreal Mascaras obtained via multi-phase product
US8980292B2 (en) 2011-04-07 2015-03-17 The Procter & Gamble Company Conditioner compositions with increased deposition of polyacrylate microcapsules
US10143632B2 (en) 2011-04-07 2018-12-04 The Procter And Gamble Company Shampoo compositions with increased deposition of polyacrylate microcapsules
US9162085B2 (en) 2011-04-07 2015-10-20 The Procter & Gamble Company Personal cleansing compositions with increased deposition of polyacrylate microcapsules
US8927026B2 (en) 2011-04-07 2015-01-06 The Procter & Gamble Company Shampoo compositions with increased deposition of polyacrylate microcapsules
US9561169B2 (en) 2011-04-07 2017-02-07 The Procter & Gamble Company Conditioner compositions with increased deposition of polyacrylate microcapsules
US9402800B2 (en) 2011-09-30 2016-08-02 L'oreal Cosmetic compositions comprising latex film formers
WO2013048919A1 (fr) * 2011-09-30 2013-04-04 L'oreal S.A. Compositions cosmétiques comprenant des substances permettant de former des films en latex
EP2760424A4 (fr) * 2011-09-30 2015-07-15 Oréal L Compositions cosmétiques comprenant des agents formant film de latex
US10888504B2 (en) 2012-10-15 2021-01-12 L'oreal Hair styling compositions containing aqueous wax dispersions
US9408785B2 (en) 2012-10-15 2016-08-09 L'oreal Hair styling compositions containing aqueous wax dispersions
US10413496B2 (en) 2012-10-15 2019-09-17 L'oreal Aqueous wax dispersions
US10626294B2 (en) 2012-10-15 2020-04-21 L'oreal Aqueous wax dispersions containing volatile solvents
WO2014138141A1 (fr) 2013-03-05 2014-09-12 The Procter & Gamble Company Compositions de sucre mélangées
KR101738802B1 (ko) 2013-03-15 2017-05-22 이엘씨 매니지먼트 엘엘씨 색조 화장품의 지속성을 개선하기 위한 방법 및 조성물
US9579275B2 (en) 2013-03-15 2017-02-28 Elc Management, Llc Method and compositions for improving wear of color cosmetics
WO2014149869A1 (fr) * 2013-03-15 2014-09-25 Elc Management Llc Procédé et compositions pour améliorer l'usure de produits cosmétiques colorés
US20150148425A1 (en) * 2013-11-25 2015-05-28 The Dial Corporation Antimicrobial composition exhibiting increased efficacy
US10561596B2 (en) 2014-04-11 2020-02-18 L'oreal Compositions and dispersions containing particles comprising a polymer
US10232381B2 (en) 2014-12-19 2019-03-19 Halliburton Energy Services, Inc. Purification of organically modified surface active minerals by air classification
US20190269585A1 (en) * 2016-06-13 2019-09-05 Coty Inc. Thickening and elongation of keratinous fibers
US12227720B2 (en) 2020-10-16 2025-02-18 The Procter & Gamble Company Consumer product compositions with at least two encapsulate populations

Also Published As

Publication number Publication date
AU6907698A (en) 1998-05-22
DE69721813T2 (de) 2004-04-01
CA2269990A1 (fr) 1998-05-07
ES2199380T3 (es) 2004-02-16
EP0946130B1 (fr) 2003-05-07
DE69721813D1 (de) 2003-06-12
JP2006028190A (ja) 2006-02-02
CN1190181C (zh) 2005-02-23
ATE239440T1 (de) 2003-05-15
CN1253491A (zh) 2000-05-17
CZ288877B6 (cs) 2001-09-12
JP2001503063A (ja) 2001-03-06
AU732059B2 (en) 2001-04-12
CA2269990C (fr) 2002-10-29
CO4920199A1 (es) 2000-05-29
WO1998018431A2 (fr) 1998-05-07
WO1998018431A3 (fr) 1998-07-23
CZ150899A3 (cs) 1999-09-15
EP0946130A2 (fr) 1999-10-06

Similar Documents

Publication Publication Date Title
US6503495B1 (en) Cosmetic compositions having improved wear and beauty
EP0824339B1 (fr) Compositions de mascara comprenant un materiau polymere insoluble dans l'eau et des polymeres filmogenes solubles dans l'eau
AU726314B2 (en) Mascara compositions having improved wear and beauty benefits
US6248336B1 (en) Cosmetic make-up compositions
US5985258A (en) Mascara compositions comprising water-insoluble polymeric material and water-soluble, film-forming polymers
WO1996036308A1 (fr) Compositions cosmetiques de maquillage
WO1996036323A1 (fr) Compositions cosmetiques de maquillage
EP0827389A1 (fr) Compositions cosmetiques de maquillage
MXPA99004127A (en) Cosmetic compositions comprising an insoluble polymer, a film-forming polymer and an organophilic clay
MXPA97008280A (en) Compositions of rimel comprising polymeric insoluble material in water and hydrosoluble polymers pelic formators
MXPA99005007A (en) Mascara compositions having improved wear and beauty benefits

Legal Events

Date Code Title Description
AS Assignment

Owner name: PROCTER & GAMBLE COMPANY, THE, OHIO

Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:ALWATTARI, ALI A.;BARTHOLOMEY, EDWARD M.;SMITH, III. EDWARD D.;AND OTHERS;REEL/FRAME:009043/0192

Effective date: 19980303

STCF Information on status: patent grant

Free format text: PATENTED CASE

CC Certificate of correction
FPAY Fee payment

Year of fee payment: 4

FPAY Fee payment

Year of fee payment: 8

FPAY Fee payment

Year of fee payment: 12

AS Assignment

Owner name: JPMORGAN CHASE BANK, N.A., DELAWARE

Free format text: IP SECURITY AGREEMENT;ASSIGNOR:NOXELL CORPORATION;REEL/FRAME:040224/0630

Effective date: 20160929

AS Assignment

Owner name: NOXELL CORPORATION, MARYLAND

Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNOR:GALLERIA CO.;REEL/FRAME:040436/0438

Effective date: 20160923

Owner name: GALLERIA CO., OHIO

Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNOR:PROCTER AND GAMBLE COMPANY;REEL/FRAME:040437/0133

Effective date: 20160926

AS Assignment

Owner name: GALLERIA CO., OHIO

Free format text: CORRECTIVE ASSIGNMENT TO CORRECT THE THE NAME OF ASSIGNOR PREVIOUSLY RECORDED ON REEL 040437 FRAME 0133. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT;ASSIGNOR:THE PROCTER AND GAMBLE COMPANY;REEL/FRAME:040941/0637

Effective date: 20160926

AS Assignment

Owner name: JPMORGAN CHASE BANK N.A., DELAWARE

Free format text: SECURITY INTEREST;ASSIGNOR:NOXELL CORPORATION;REEL/FRAME:043340/0685

Effective date: 20161001

AS Assignment

Owner name: NOXELL CORPORATION, MARYLAND

Free format text: RELEASE BY SECURED PARTY;ASSIGNOR:JPMORGAN CHASE BANK, N.A.;REEL/FRAME:045950/0161

Effective date: 20180405

点击 这是indexloc提供的php浏览器服务，不要输入任何密码和下载