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EP0013585A1 - Composition détergente liquide douce - Google Patents

Composition détergente liquide douce Download PDF

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Publication number
EP0013585A1
EP0013585A1 EP80200017A EP80200017A EP0013585A1 EP 0013585 A1 EP0013585 A1 EP 0013585A1 EP 80200017 A EP80200017 A EP 80200017A EP 80200017 A EP80200017 A EP 80200017A EP 0013585 A1 EP0013585 A1 EP 0013585A1
Authority
EP
European Patent Office
Prior art keywords
detergent composition
liquid detergent
composition according
carbon atoms
nonionic surfactant
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP80200017A
Other languages
German (de)
English (en)
Other versions
EP0013585B1 (fr
Inventor
Michael P. Aronson
Edilia A. Larrauri
Zahera J. Hussain
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Unilever PLC
Unilever NV
Original Assignee
Unilever PLC
Unilever NV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Unilever PLC, Unilever NV filed Critical Unilever PLC
Priority to AT80200017T priority Critical patent/ATE1864T1/de
Publication of EP0013585A1 publication Critical patent/EP0013585A1/fr
Application granted granted Critical
Publication of EP0013585B1 publication Critical patent/EP0013585B1/fr
Expired legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
    • C11D3/3776—Heterocyclic compounds, e.g. lactam
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/38—Products with no well-defined composition, e.g. natural products
    • C11D3/384—Animal products

Definitions

  • Spotting may be referred to as resulting from the break - up of a once continuous liquid film followed by the isolation of liquid patches that become stranded on the solid surface. Upon the drying of these isolated liquid patches, spots will form from the solid residue that was dissolved or suspended in the liquid.
  • One of the disadvantages associated with liquid dishwashing detergent compositions therefore, is the need to dry the washed objects or apparatus with a towel so that spot and film formation from the minerals in the rinse water can be avoided or minimized to a large extent.
  • a liquid detergent composition containing a relatively small amount of a copolymer of N-vinylpyrrolidone and dimethylamino-ethylmethacrylate, having specific molecular weight limitations, and a small amount of an alkali metal salt of casein, e.g., sodium caseinate, when added to an anionic surfactant, nonionic surfactant, or mixtures thereof, provides an excellent washing and cleaning composition with much improved drainage properties so as to render the cleaned objects virtually free from spotting and/or filming.
  • casein e.g., sodium caseinate
  • the liquid detergent composition will generally contain from about 2% to about 50% by weight, preferably from about 10% to about 30% by weight of the total composition of an anionic surfactant compound.
  • Suitable synthetic anionic surface active agents that may be present in the liquid dishwashing detergent composition are the water-soluble hydrocarbon sulfates having the general formula:
  • R 2 is chosen from the group consisting of a straight or branched, saturated or unsaturated, aliphatic hydrocarbon radical having from 8 to 24, preferably from 12 to 18 carbon atoms; and an alkylbenzene radical having from 8 to 18, preferably from 12 to 16 carbon atoms in the alkyl group; and M is a cation, preferably sodium, potassium, ammonium, magnesium or calcium.
  • the synthetic detergents which form a part of the preferred compositions of the present invention are the salts of an organic, sulfuric acid reaction product of a hydrocarbon of the methane series, including iso-, neo-, meso-, and n-paraffins, having 8 to 24 carbon atoms, preferably 11 to 18 carbon atoms, and double bonds, and a sulfonating agent, e.g. SO 3 , H 2 SO 4 , oleum, obtained according to known sulfonation methods, including bleaching and hydrolysis.
  • a sulfonating agent e.g. SO 3 , H 2 SO 4 , oleum
  • Preferred are sulfonated C 12-18 n-paraffins, alone or in combination with suifonated alpha olefilns containing an average of 14 caroon atoms.
  • alkylbenzene sulfonates in which the alkyl group contains from about 9 to about 18 carbon atoms are dodecyl-, tetradecyl-, and hexadecylbenzene sulfonates and those which are described in U.S. Patents Nos. 2,220,099 and 2,477,383.
  • the preferred anionic surface-active agent which can be included in the composition of the present invention, is the water-soluble hydrocarbon sulfate as represented hereinbefore by the general formula R 1 O(C 2 H 4 O) n SO 3 M, wherein R 1 is preferably a straight, saturated, aliphatic hydrocarbon radical, having from 8 to 20, desirably 12 to 16 carbon atoms; n is preferably from 3 to 9; and M is preferably sodium, potassium or ammonium.
  • Said preferred ethoxylated hydrocarbon sulfates can be present in amounts up to 50%, but are preferably present between 5 and 35% by weight, based on the total weight of the composition.
  • the weight ratio of said water-soluble salts of the organic, sulfuric acid reaction product to the ethoxylated hydrocarbon sulfate will usually be, dependent upon the concentration and type of the metal cations present in the wash solution (i.e. the ionic strength), from about 10:1 to about 1:10, preferably from about 3:1 to about 1:1.
  • compositions whereby the water-soluble ethoxylated hydrocarbon sulfates are C 12-16 alkyl - 0 - (C 2 H 4 O) 3-6 SO 3 M, and the water-soluble salts of the organic, sulfuric acid reaction products are C 11-18 paraffin sulfonates.
  • the levels of nonionic surface-active detergent in the liquid detergent composition of the present invention will preferably be from about 1% to about 30% by weight, most preferably from about 1% to about 10% by weight based on the total weight of the composition.
  • Suitable, water-soluble, nonionic surface-active agents to be used in the formulation of the liquid dishwashing detergent composition of the present invention are the water-soluble, nonionic, tertiary amine oxides as represented hereinafter by the general formula: whereby R 3 represents a high molecular, straight or branched, saturated or unsaturated, aliphatic hydrocarbon, hydroxyhydrocarbon, or alkyloxyhydrocarbon radical, preferably an alkyl radical having a total of 8 to 24, preferably 12 to 18; R 4 and R 5 which may be the same or different, represent each a methyl, ethyl, hydroxymethyl, and hydroxyethyl radical.
  • tertiary amine oxides are: dimethyl dodecyl amine oxide, diethyl tetradecyl amine oxide, bis-(2-hydroxyethyl)-dodecyl amine oxide, bis-(2-hydroxyethyl)-3-dodecoxy-l-hydroxypropyl amine oxide, dimethyl-2-hydroxydodecyl amine oxide, and diethyl eicosyl amine oxide.
  • nonionic surfactant compounds are the water-soluble, tertiary phosphine oxides, represented by the general formula: whereby R 3 , R 4 and R 5 have the same meaning as described hereinbefore. They can be prepared by alkylating an alkyl phosphine derivative and oxidizing the resulting reaction product.
  • tertiary phosphine oxides are: dimethyl dodecyl phosphine oxide, diethyl tetradecyl phosphine oxide, bis-(2-hydroxyethyl)- dodecyl phosphine oxide, tetradecyl ethyl 2-hydroxyethyl phosphine oxide, oleyl dimethyl phosphine oxide, and 2-hydroxydodecyl dimethyl phosphine oxide.
  • Still another group of nonionic surfactant compounds are the water-soluble amides represented by the general formula: wherein R 6 is a saturated or unsaturated, aliphatic hydrocarbon radical having from 7 to 21, preferably from 11 to 17 carbon atoms; R 7 represents a methylene or ethylene group; and m is 1, 2 or 3, preferably 1.
  • Specific examples of said amides are mono-ethanpl coconut fatty acid amide, diethanol dodecyl fatty acid amide, and dimethanol oleyl amide.
  • nonionic surfactant compounds are the water-soluble condensation products obtained by condensing from 3 to about 25 moles of an alkylene oxide, preferably ethylene or propylene oxide, with one mole of an organic hydrophobic compound, aliphatic or alkyl aromatic in nature and having 8 to 24 carbon atoms and at least one reactive hydrogen atom, preferably a reactive hydroxyl, amino, amido or carboxy group.
  • an alkylene oxide preferably ethylene or propylene oxide
  • organic hydrophobic compound aliphatic or alkyl aromatic in nature and having 8 to 24 carbon atoms and at least one reactive hydrogen atom, preferably a reactive hydroxyl, amino, amido or carboxy group.
  • the maximum level of water-soluble, anionic and nonionic surface-active agents that can be included in the liquid detergent composition of the present invention will usually depend on the level of each of the surfactants present and also to a certain extent on the presence of the drainage modification agents herein.
  • the maximum amount of both nonionic and anionic surface-active agents which can be present in the composition of the present invention is about 50% by weight based on the total weight of the composition.
  • the copolymer used in the present liquid dishwashing detergent composition to provide enhanced drainage properties is a copolymer of N-vinyl pyrrolidone and dimethylamino-ethylmethacrylate whose monomer structure is represented by the following formula:
  • the molecular weight of this copolymer is preferably between 40,000 and 1.5 million, and may be present in the composition from about 0.1% to about 10% by weight of the total composition, preferably between 0.5% and 3.0% by weight.
  • a copolymer that is commercially available may be obtained from the GAF Corporation under the trade name of Gafquat 755, having a molecular weight of about 1 million, and Gafquat 734,having a molecular weight of about 100,000.
  • a third ingredient that is used in the dishwashing liquid composition of the invention is an alkali metal salt of the protein, casein, preferably sodium caseinate.
  • the caseinate can be present in an amount of from 0.5% to about 5% by weight based on the total weight of the composition, preferably from 1.0% to about 3.0% by weight.
  • a commercial grade of sodium caseinate is available from Western Dairy Products under the trade name of Savortone LF having the following analysis:
  • the invention pertains to a light duty, hand dishwashing liquid detergent composition
  • a light duty, hand dishwashing liquid detergent composition comprising:
  • the above liquid detergent composition provides excellent drainage of washed kitchen utensils and apparatus, and prevents water spotting and filming when the utensils are left to dry. Moreover, the utensils are left with a shiny clean appearance and eliminate the necessity for towel drying or wiping.
  • a preferred embodiment for the dishwashing liquid detergent composition according to the invention is one which contains (a) from about 10 to about 50% of an anionic surfactant compound, or a mixture of anionic surfactant compounds; (b) from about 1% to about 10% of a nonionic surfactant compound, or a mixture of nonionic surfactant compounds; (c) from about 0.5% to about 3.0% of a copolymer of N-vinylpyrrolidone and dimethylamino-ethylmethacrylate having a molecular weight between about 40,000 and 1.5 million, or mixtures thereof; and (d) from about 1.0% to about 3.0% of sodium caseinate; the percentages expressed being based on the total weight of the composition.
  • Additional ingredients that can be optionally included in the hand dishwashing liquid composition of the present invention are water-soluble, low molecular weight organic acid, or the water-soluble alkali metal, ammonium,or substituted ammonium salts thereof.
  • Organic acids or their salts are added to enhance the cleaning action of the liquid detergent composition of the present invention and can, in addition, be used as a source of ions to maintain the pH of the composition at a given pH value.
  • Suitable water-soluble, low molecular weight organic acids include, for example, acetic, citric, malic, gluconic, maleic, lactic, tartaric, propionic, butyric, malonic, polymaleic, polyitaconic, glutaric, citraconic, benzene pentacarboxylic, hexacarboxylic, succinic, ethylene diamine tetra-acetic and nitrilotriacetic acids. Partially and completely neutralized salts of the foregoing acids can also be used.
  • suitable, organic acid salts are mono-, di- and trisodium citrate, diammonium citrate, monopotassium tartrate, disodium succinate, and tetrasodium melletate.
  • the maximum level of the water-soluble organic acids or salts that can be added to the liquid detergent composition of the present invention should usually not exceed 15 percent by weight of the total weight of the composition, and should preferably be below about 10 percent by weight.
  • Some of the organic acid salts can be replaced by inorganic builder salts.
  • the amount of inorganic builder salts, e.g. sodium phosphates and carbonates, should preferably not exceed 5 percent by weight in the composition.
  • compositions of the present invention include perfume, dyes, fluorescers, tarnish inhibitors, such as benzotriozole or ethylene thio-urea; shine improvers, such as boric acid or its salts in amounts of up to 3 percent by weight; bactericides such as 2-bromo-2-nitro-1, 3-propanediol, substituted benziodolium compounds, diphenyl ethers substituted with C1, Br or -CF 3 , e.g.
  • organic solvents examples include the mono- and dialcohols containing 2 to 8 carbon atoms such as ethanol, butanol, methylpropanol-1 and -2, amylol (pentanol), 1,2-,1,3- and 1,4-butanediol, toluol, benzyl carbinol, ethyleneglycol monobutyl ether, propyleneglycol propyl ether and diethyleneglycol dimethyl ether.
  • hydrotropes examples include sodium,potassium or ammonium xylene sulfonate, and sodium, potassium or ammonium isethionate.
  • the substrates used to judge the effectiveness of the foregoing agents in the drainage modification in a liquid dishwashing detergent composition of all of the examples herein were either 310 ml drinking glasses, glass dinner plates (23 cm diameter), ceramic dinner plates (23 cm diameter), or plastic dinner plates (23 cm diameter), Boontonware.
  • the substrates were washed with various detergent compositions at a use level of 0.15% and 0.20% for 1 minute and 3 minutes at a temperature of 40-45°C. Edgewater, New Jersey tap water was used in all of the experiments.
  • the substrates were then rinsed either under running tap water or in a dishpan filled with clean tap water. In both cases, the temperature of the rinse water was approximately 45°C. The duration of the rinse was varied between 10 seconds and 2 minutes.
  • the substrate was placed on a rack to dry.
  • the time at which drainage began and the percentage of the surface area of the substrate that dried due to this drainage were recorded.
  • the degree of benefit arising from the agent is directly related to the time at which drainage begins and the percentage of the area dried by this drainage.
  • the benefit produced by drainage modification increases with increasing drainage rate and increasing percentage area dried by the enhanced drainage, provided that the rinse water film drains as a uniform sheet, and does not break up into water droplets which produce objectionable spotting.
  • the samples were examined on drinking glasses with respect to drain-dry performance and end result following rinsing.
  • the washing tests were carried out at 42°C using precleaned glasses for each test at 0.2% product concentration under various water hardness conditions. Wash and rinse times were prolonged to optimise drain-dry effect; the treated glasses which had been rinsed were drained in an inverted position following the normal procedure.

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Zoology (AREA)
  • Detergent Compositions (AREA)
EP80200017A 1979-01-12 1980-01-08 Composition détergente liquide douce Expired EP0013585B1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AT80200017T ATE1864T1 (de) 1979-01-12 1980-01-08 Milde fluessige reinigungsmittelzusammensetzung.

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US292479A 1979-01-12 1979-01-12
US2924 2001-11-15

Publications (2)

Publication Number Publication Date
EP0013585A1 true EP0013585A1 (fr) 1980-07-23
EP0013585B1 EP0013585B1 (fr) 1982-11-24

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ID=21703211

Family Applications (1)

Application Number Title Priority Date Filing Date
EP80200017A Expired EP0013585B1 (fr) 1979-01-12 1980-01-08 Composition détergente liquide douce

Country Status (11)

Country Link
EP (1) EP0013585B1 (fr)
JP (1) JPS5598298A (fr)
AR (1) AR221396A1 (fr)
AT (1) ATE1864T1 (fr)
AU (1) AU528923B2 (fr)
BR (1) BR8000109A (fr)
CA (1) CA1117843A (fr)
DE (1) DE3061116D1 (fr)
NZ (1) NZ192549A (fr)
PH (1) PH18064A (fr)
ZA (1) ZA80139B (fr)

Cited By (31)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0077588A1 (fr) * 1981-10-16 1983-04-27 Unilever N.V. Composition pour lave-vaisselle
EP0125711A1 (fr) * 1983-04-19 1984-11-21 Unilever N.V. Composition de nettoyage à tout usage
EP0079646B1 (fr) * 1981-11-16 1986-05-21 Unilever N.V. Composition détergente liquide
EP0244647A3 (en) * 1982-07-30 1988-06-08 Denes Potschke Use of casein as a cleaning agent
US4954292A (en) * 1986-10-01 1990-09-04 Lever Brothers Co. Detergent composition containing PVP and process of using same
US4999129A (en) * 1986-07-30 1991-03-12 Michael Hull Process and composition for washing soiled polyester fabrics
BE1003561A3 (nl) * 1989-10-11 1992-04-21 Met Beperkte Aansprakelijkheid Vloeibare wasmiddelen.
EP0576778A1 (fr) * 1992-07-03 1994-01-05 The Procter & Gamble Company Compositions détergentes aqueuses liquides concentrées
WO1994010281A1 (fr) * 1992-10-23 1994-05-11 Basf Aktiengesellschaft Utilisation de copolymerisats de vinylpyrrolidone et de vinylimidazole comme produits d'addition aux detergents, ainsi que leur procede de preparation
EP0859046A1 (fr) * 1997-02-14 1998-08-19 The Procter & Gamble Company Compositions liquides de nettoyage pour surfaces dures
EP0892039A1 (fr) * 1997-07-18 1999-01-20 The Procter & Gamble Company Compositions de nettoyage liquides
WO1999023194A1 (fr) * 1997-10-31 1999-05-14 The Procter & Gamble Company Compositions acides liquides servant a eliminer des depots de calcaire, conditionnees dans un distributeur de type pulverisateur
WO1999027057A1 (fr) * 1997-11-21 1999-06-03 The Procter & Gamble Company Compositions detergentes liquides comprenant des activateurs polymeres de mousse
WO1999027058A1 (fr) * 1997-11-21 1999-06-03 The Procter & Gamble Company Compositions detergentes comprenant des activateurs polymeres de mousse, et leur utilisation
EP0982394A1 (fr) * 1998-08-27 2000-03-01 The Procter & Gamble Company Composition liquide neutre ou alcaline de nettoyage pour surfaces dures
WO2000071660A1 (fr) * 1999-05-26 2000-11-30 The Procter & Gamble Company Compositions de detergent liquide contenant des activateurs polymeres bloc de mousse
WO2000071659A1 (fr) * 1999-05-26 2000-11-30 The Procter & Gamble Company Compositions de detergent liquide contenant des activateurs polymeres bloc de mousse
WO2000071241A1 (fr) * 1999-05-26 2000-11-30 The Procter & Gamble Company Compositions et procedes d'utilisation d'activateurs polymeres de mousse
WO2000071658A1 (fr) * 1999-05-26 2000-11-30 The Procter & Gamble Company Compositions detergents comprenant des renforçateurs de savonnage polymeres offrant une plus grande douceur et une meilleure sensation au contact de la peau
US6333299B1 (en) 1997-10-31 2001-12-25 The Procter & Gamble Co. Liquid acidic limescale removal composition packaged in a spray-type dispenser
US6376631B1 (en) 2000-09-27 2002-04-23 Rhodia, Inc. Processes to control the residual monomer level of copolymers of tertiary amino monomer with a vinyl-functional monomer
WO2003002707A1 (fr) * 2001-06-26 2003-01-09 Johnsondiversey, Inc. Composition de rinçage contenant un bio-polypeptide
US6718992B1 (en) 1998-08-27 2004-04-13 Sergio Cardola Liquid neutral to alkaline hard-surface cleaning composition
US6827795B1 (en) 1999-05-26 2004-12-07 Procter & Gamble Company Detergent composition comprising polymeric suds enhancers which have improved mildness and skin feel
US6864314B1 (en) 1999-05-26 2005-03-08 Dominic Wai-Kwing Yeung Block polymers, compositions and methods of use for foams, laundry detergents, shower rinses and coagulants
US6903064B1 (en) * 1999-05-26 2005-06-07 Procter & Gamble Company Detergent composition comprising polymeric suds volume and suds duration enhancers
US7241729B2 (en) 1999-05-26 2007-07-10 Rhodia Inc. Compositions and methods for using polymeric suds enhancers
WO2010088165A1 (fr) * 2009-02-02 2010-08-05 The Procter & Gamble Company Composition de détergent liquide pour le lavage manuel de la vaisselle
US7939601B1 (en) 1999-05-26 2011-05-10 Rhodia Inc. Polymers, compositions and methods of use for foams, laundry detergents, shower rinses, and coagulants
US8361239B2 (en) 2009-02-02 2013-01-29 The Procter & Gamble Company Liquid hand diswashing detergent composition
US8575083B2 (en) 2009-02-02 2013-11-05 The Procter & Gamble Company Liquid hand diswashing detergent composition

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA1170949A (fr) * 1980-02-05 1984-07-17 John B. Welch Detergent liquide
JPS59115398A (ja) * 1982-12-21 1984-07-03 ライオン株式会社 洗浄剤組成物
US5723425A (en) * 1992-07-03 1998-03-03 Cauwberghs; Serge Gabriel Pierre Concentrated aqueous liquid detergent comprising polyvinylpyrrolidone
AU5294600A (en) * 1999-05-26 2000-12-12 Procter & Gamble Company, The Detergent compositions comprising polymeric suds volume and suds duration enhancers and methods for washing with same
JP3405970B2 (ja) * 2000-11-17 2003-05-12 花王株式会社 硬質表面用洗浄剤組成物

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CH389141A (de) * 1959-12-22 1965-03-15 Colgate Palmolive Co Flüssiges Reinigungsmittel
CH488007A (de) * 1966-01-15 1970-03-31 Henkel & Cie Gmbh Schaumarmes Spül- und Reinigungsmittel
US3979339A (en) * 1975-03-18 1976-09-07 The Procter & Gamble Company Hard surface cleaning compositions
DE2607656A1 (de) * 1975-03-03 1976-09-16 Unilever Nv Wasch- und reinigungsmittel
US4048301A (en) * 1975-05-28 1977-09-13 L'oreal Shampoo composition containing a detergent and a graft cationic copolymer

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CH389141A (de) * 1959-12-22 1965-03-15 Colgate Palmolive Co Flüssiges Reinigungsmittel
CH488007A (de) * 1966-01-15 1970-03-31 Henkel & Cie Gmbh Schaumarmes Spül- und Reinigungsmittel
DE2607656A1 (de) * 1975-03-03 1976-09-16 Unilever Nv Wasch- und reinigungsmittel
US3979339A (en) * 1975-03-18 1976-09-07 The Procter & Gamble Company Hard surface cleaning compositions
US4048301A (en) * 1975-05-28 1977-09-13 L'oreal Shampoo composition containing a detergent and a graft cationic copolymer

Cited By (47)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0077588A1 (fr) * 1981-10-16 1983-04-27 Unilever N.V. Composition pour lave-vaisselle
EP0079646B1 (fr) * 1981-11-16 1986-05-21 Unilever N.V. Composition détergente liquide
EP0244647A3 (en) * 1982-07-30 1988-06-08 Denes Potschke Use of casein as a cleaning agent
EP0125711A1 (fr) * 1983-04-19 1984-11-21 Unilever N.V. Composition de nettoyage à tout usage
TR22299A (tr) * 1983-04-19 1987-01-08 Unilever Nv Genel kullanimh temizleme bilesimi
US4999129A (en) * 1986-07-30 1991-03-12 Michael Hull Process and composition for washing soiled polyester fabrics
US4954292A (en) * 1986-10-01 1990-09-04 Lever Brothers Co. Detergent composition containing PVP and process of using same
BE1003561A3 (nl) * 1989-10-11 1992-04-21 Met Beperkte Aansprakelijkheid Vloeibare wasmiddelen.
EP0576778A1 (fr) * 1992-07-03 1994-01-05 The Procter & Gamble Company Compositions détergentes aqueuses liquides concentrées
WO1994010281A1 (fr) * 1992-10-23 1994-05-11 Basf Aktiengesellschaft Utilisation de copolymerisats de vinylpyrrolidone et de vinylimidazole comme produits d'addition aux detergents, ainsi que leur procede de preparation
EP0859046A1 (fr) * 1997-02-14 1998-08-19 The Procter & Gamble Company Compositions liquides de nettoyage pour surfaces dures
WO1999003957A1 (fr) * 1997-07-18 1999-01-28 The Procter & Gamble Company Compositions de nettoyage liquides
EP0892039A1 (fr) * 1997-07-18 1999-01-20 The Procter & Gamble Company Compositions de nettoyage liquides
WO1999023194A1 (fr) * 1997-10-31 1999-05-14 The Procter & Gamble Company Compositions acides liquides servant a eliminer des depots de calcaire, conditionnees dans un distributeur de type pulverisateur
EP0919610A1 (fr) * 1997-10-31 1999-06-02 The Procter & Gamble Company Compositions liquides acides pour enlever le tartre emballées dans un atomiseur
US6333299B1 (en) 1997-10-31 2001-12-25 The Procter & Gamble Co. Liquid acidic limescale removal composition packaged in a spray-type dispenser
US6372708B1 (en) 1997-11-21 2002-04-16 The Procter & Gamble Company Liquid detergent compositions comprising polymeric suds enhancers
KR100404534B1 (ko) * 1997-11-21 2003-11-05 더 프록터 앤드 갬블 캄파니 중합체성 거품 증진제를 포함하는 세제 조성물 및 이를 사용한 거품 용적과 거품 보유율의 증진방법
US6369012B1 (en) 1997-11-21 2002-04-09 The Procter & Gamble Company Detergent compositions comprising polymeric suds volume and suds enhancers and methods of washing with same
WO1999027058A1 (fr) * 1997-11-21 1999-06-03 The Procter & Gamble Company Compositions detergentes comprenant des activateurs polymeres de mousse, et leur utilisation
US6207631B1 (en) 1997-11-21 2001-03-27 The Procter & Gamble Company Detergent compositions comprising polymeric suds volume and suds duration enhancers and methods for washing with same
WO1999027057A1 (fr) * 1997-11-21 1999-06-03 The Procter & Gamble Company Compositions detergentes liquides comprenant des activateurs polymeres de mousse
EP0982394A1 (fr) * 1998-08-27 2000-03-01 The Procter & Gamble Company Composition liquide neutre ou alcaline de nettoyage pour surfaces dures
WO2000012661A1 (fr) * 1998-08-27 2000-03-09 The Procter & Gamble Company Composition de liquide nettoyant neutre a alcalin pour surfaces dures
US6718992B1 (en) 1998-08-27 2004-04-13 Sergio Cardola Liquid neutral to alkaline hard-surface cleaning composition
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BR8000109A (pt) 1980-09-23
JPS6111280B2 (fr) 1986-04-02
ATE1864T1 (de) 1982-12-15
AU5452980A (en) 1980-07-17
AU528923B2 (en) 1983-05-19
PH18064A (en) 1985-03-18
ZA80139B (en) 1981-08-26
DE3061116D1 (en) 1982-12-30
NZ192549A (en) 1981-11-19
AR221396A1 (es) 1981-01-30
EP0013585B1 (fr) 1982-11-24
CA1117843A (fr) 1982-02-09
JPS5598298A (en) 1980-07-26

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