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WO2019087953A1 - Composition d'agent nettoyant désinfectant - Google Patents

Composition d'agent nettoyant désinfectant Download PDF

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Publication number
WO2019087953A1
WO2019087953A1 PCT/JP2018/039816 JP2018039816W WO2019087953A1 WO 2019087953 A1 WO2019087953 A1 WO 2019087953A1 JP 2018039816 W JP2018039816 W JP 2018039816W WO 2019087953 A1 WO2019087953 A1 WO 2019087953A1
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Prior art keywords
component
mass
less
content
carbon atoms
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PCT/JP2018/039816
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English (en)
Japanese (ja)
Inventor
土屋隆夫
鈴木圭吾
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花王株式会社
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Application filed by 花王株式会社 filed Critical 花王株式会社
Priority to CN201880058316.2A priority Critical patent/CN111065721B/zh
Publication of WO2019087953A1 publication Critical patent/WO2019087953A1/fr

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Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N33/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
    • A01N33/02—Amines; Quaternary ammonium compounds
    • A01N33/12—Quaternary ammonium compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B08—CLEANING
    • B08B—CLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
    • B08B3/00—Cleaning by methods involving the use or presence of liquid or steam
    • B08B3/04—Cleaning involving contact with liquid
    • B08B3/08—Cleaning involving contact with liquid the liquid having chemical or dissolving effect
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/62—Quaternary ammonium compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/75—Amino oxides
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/835—Mixtures of non-ionic with cationic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions

Definitions

  • the present invention relates to germicidal cleaning compositions.
  • JP-A-2010-168428 discloses (a) at least one surfactant selected from nonionic surfactants and amphoteric surfactants, (b) cationic surfactants having bactericidal properties, (c) A liquid cleaner composition for hard surfaces is described, which contains specific polymer compounds as well as water. Further, a technique of using an amine oxide and a cationic surfactant in combination is disclosed in JP-A-2016-216543 and JP-A-2014-520137. Furthermore, Japanese Patent Application Laid-Open No. 2014-210739 discloses a water-based fungicide containing myristyl dimethyl amine oxide, a foaming component, and further a cationic antibacterial substance.
  • the present invention provides a bactericidal detergent composition which is excellent in both detergency and bactericidal activity against dirt such as oil stains.
  • the present invention is a cationic germicide [hereinafter referred to as component (a)], an amine oxide surfactant having one hydrocarbon group having 9 to 12 carbon atoms (hereinafter referred to as component (b)), and 13 carbon atoms. Or an amine oxide surfactant having one of 14 hydrocarbon groups [hereinafter referred to as component (c)];
  • component (a) an amine oxide surfactant having one hydrocarbon group having 9 to 12 carbon atoms
  • component (c) an amine oxide surfactant having one of 14 hydrocarbon groups
  • the mass ratio of [content of component (a)] / [content of component (b) + content of component (c)] is 0.2 or more and 5 or less,
  • the invention relates to a sterilizing cleaner composition.
  • a sterilizing and cleaning composition which is excellent in both detergency and sterilizing ability against dirt such as oil stains.
  • quaternary ammonium type surfactant is preferable.
  • the component (a) include at least one cationic bactericide selected from the cationic bactericide represented by the following general formula (a1) and the cationic bactericide represented by the following general formula (a2) .
  • R 1a , R 2a , R 3a and R 4a are an alkyl group or alkenyl group having 8 to 16 carbon atoms, or
  • each is an alkyl group having 1 or more and 3 or less carbon atoms, a benzyl group, or a formula-(CH 2 CH 2 O) m H (m is an average addition mole number, R 5a represents an alkyl group having 12 to 18 carbon atoms or an alkenyl group, and X - represents a counter ion. ]
  • R 1a , R 2a , R 3a and R 4a each is an alkyl group having 8 to 12 carbon atoms, and the remainder is the same or different and is a methyl group, an ethyl group, Or a group selected from a benzyl group.
  • any one of R 1a , R 2a , R 3a and R 4a is an alkyl group having 8 to 12 carbon atoms, and the remainder is the same or different and is a methyl group, an ethyl group or a benzyl group It is more preferable that In the general formula (a2), R 5a is an alkyl group having 8 or more carbon atoms, 14 or more carbon atoms, and 18 or less carbon atoms, preferably a cetyl group.
  • X - is a counterion, halogen ions, sulfate ion, alkyl sulfate ion, and the like carboxylate ion. X - is preferably a chloro ion or a monoalkyl sulfate ion having 1 or more and 3 or less carbon atoms.
  • component (a) examples include: dialkyldimethyl ammonium halide, benzalkonium chloride, benzethonium chloride or a cationic surfactant-based bactericidal agent in which the counter ion is converted to another anion, chlorhexidine, gluconic acid
  • biguanides such as chlorhexidine
  • amino acid-type fungicides such as alkyldiaminoethylglycine and alkylpolyaminoethylglycine.
  • the component (a) is more preferably a dialkyldimethyl ammonium salt having an alkyl group having 8 to 10 carbon atoms, or an alkyl dimethyl benzyl ammonium salt having an alkyl group having 8 to 12 carbon atoms, and still more preferably an alkyl group. It is alkyldimethyl benzyl ammonium chloride having 8 to 12 carbon atoms in the group.
  • the hydrocarbon group having 9 to 12 carbon atoms of the component (b) is preferably an alkyl group or an alkenyl group, and more preferably an alkyl group.
  • an amine oxide type surfactant which has one C9-C12 hydrocarbon group of (b) component the amine oxide type surfactant represented by following General formula (b1) is mentioned.
  • R 1b is an alkyl group or alkenyl group having 9 to 12 carbon atoms.
  • X 1 is a group selected from -COO-, -CONH-, -OCO-, and -NHCO-
  • R 2b is an alkylene group having 1 to 6 carbon atoms
  • p is a number of 0 or 1 .
  • R 3b and R 4b are each an alkyl group having 1 to 3 carbon atoms or a hydroxyalkyl group having 1 to 3 carbon atoms.
  • R 1b is an alkyl group or alkenyl group having 9 to 12 carbon atoms, preferably an alkyl group having 12 carbon atoms.
  • R 1b is preferably an alkyl group having 12 carbon atoms.
  • R 1b is preferably a residue obtained by removing a carboxyl group from lauric acid (an alkyl group having 11 carbon atoms).
  • X 1 is preferably -COO- or -CONH-, more preferably -CONH-.
  • the carbon number of R 2b is preferably 2 or 3.
  • Each of R 3b and R 4b is preferably a methyl group.
  • p is preferably 0.
  • component (b) one selected from N-lauryl-N, N-dimethylamine-N-oxide and N- (3-lauroylaminopropyl) -N, N-dimethylamine-N-oxide preferably Or two or more amine oxide surfactants, more preferably N-lauryl-N, N-dimethylamine-N-oxide.
  • the hydrocarbon group having 13 or 14 carbon atoms of the component (c) is preferably an alkyl group or an alkenyl group, and more preferably an alkyl group.
  • an amine oxide type surfactant which has one carbon number 13 or 14 hydrocarbon group of (c) component the amine oxide type surfactant represented by following General formula (c1) is mentioned.
  • R 1c is an alkyl group having 13 or 14 carbon atoms or an alkenyl group.
  • X 2 is a group selected from -COO-, -CONH-, -OCO-, and -NHCO-,
  • R 2c is an alkylene group having 1 to 6 carbon atoms, and
  • q is a number of 0 or 1 .
  • R 3c and R 4c are each an alkyl group having 1 to 3 carbon atoms or a hydroxyalkyl group having 1 to 3 carbon atoms.
  • R 1c is an alkyl group having 13 or 14 carbon atoms or an alkenyl group, preferably an alkyl group having 14 carbon atoms.
  • R 1c when q is 0, R 1c is preferably an alkyl group having 14 carbon atoms.
  • R 1c when q is 1, R 1c is preferably a residue obtained by removing a carboxyl group from myristic acid (an alkyl group having 13 carbon atoms).
  • X 2 is preferably -COO- or -CONH-, more preferably -CONH-.
  • the carbon number of R 2c is preferably 2 or 3.
  • Each of R 3c and R 4c is preferably a methyl group. q is preferably 0.
  • the component (c) is preferably selected from N-myristyl-N, N-dimethylamine-N-oxide and N- (3-myristoyl aminopropyl) -N, N-dimethylamine-N-oxide
  • One or more amine oxide type surfactants more preferably N-myristyl-N, N-dimethylamine-N-oxide.
  • the germicidal detergent composition of the present invention can contain an amine oxide surfactant [hereinafter referred to as component (c ') component] other than the components (b) and (c).
  • component (c ') component an amine oxide surfactant
  • amine oxide surfactants having one hydrocarbon group having 15 or more carbon atoms amine oxide-type surfactant is more in the general formula (c1) R 1c is more than 15 carbon atoms alkyl or alkenyl group, It is preferable that the content thereof is small because the bactericidal effect of the present invention tends to be reduced.
  • the proportion of the amine oxide surfactant which is an alkyl group or an alkenyl group is preferably 20% by mass or less, more preferably 10% by mass or less, based on the total content of the components (b) and (c). Preferably it is 5 mass% or less, More preferably, it is 1 mass% or less.
  • the component (a) is generally known as a bactericidal agent, but when it is used as a cleaning agent, not only the expected bactericidal effect can not be obtained particularly in the presence of oil stains, but also the washing effect such as oil stains It turned out that it might be damaged.
  • the bactericidal effect of the detergent using the component (a) is enhanced by using in combination two amine oxide compounds having different chain lengths of the hydrocarbon groups of the components (b) and (c), and an oil The surprising effect is obtained that the soil detergency can be synergistically increased.
  • the mass ratio of [content of component (a)] / [content of component (b) + content of component (c)] in the disinfectant cleaner composition of the present invention is from the viewpoint of detergency and bactericidal power 0.2 or more, preferably 0.3 or more, more preferably 0.4 or more, further preferably 0.5 or more, more preferably 0.6 or more, and 5 or less, preferably 4 or less, more preferably It is 2.5 or less, more preferably 2 or less, and further preferably 1 or less.
  • the mass ratio of [content of component (b)] / [content of component (c)] is preferably 0.1 or more, from the viewpoint of detergency and bactericidal activity, of the disinfectant cleaner composition of the present invention. More preferably, it is 0.4 or more, more preferably 0.8 or more, and preferably 10 or less, more preferably 5 or less, still more preferably 3 or less.
  • the sterilizing cleaner composition of the present invention preferably contains 0.1% by mass or more, more preferably 0.5% by mass or more, still more preferably 1% by mass or more, and preferably 10% by mass of the component (a).
  • the content is more preferably 7% by mass or less, still more preferably 5% by mass or less.
  • the sterilizing / cleaning agent composition of the present invention preferably contains 0.1% by mass or more, more preferably 0.5% by mass or more, still more preferably 1% by mass or more, still more preferably 2% by mass or more of the component (b). And preferably 10% by mass or less, more preferably 7% by mass or less, still more preferably 5% by mass or less, still more preferably 4% by mass or less.
  • the sterilizing cleaner composition of the present invention preferably contains 0.1% by mass or more, more preferably 0.5% by mass or more, still more preferably 0.8% by mass or more, and still more preferably 1% by mass of the component (c) % Or more, preferably 10% by mass or less, more preferably 7% by mass or less, still more preferably 5% by mass or less, still more preferably 3% by mass or less.
  • the germicidal detergent composition of the present invention preferably further contains a surfactant other than the components (a), (b) and (c) as the component (d).
  • the component (d) is preferably a nonionic surfactant. That is, it is preferable that the microbicide composition of this invention contains a nonionic surfactant as (d) component.
  • the nonionic surfactant include one or more nonionic surfactants selected from alkyl glycoside type nonionic surfactants and alkoxylated nonionic surfactants.
  • the nonionic surfactant is preferably an alkyl glycoside type nonionic surfactant from the viewpoint of detergency and bactericidal activity.
  • alkyl glycoside type surfactant examples include alkyl glycoside type surfactants represented by the following general formula (d1).
  • R 1d- (O-R 2d ) n G m (d1) [Wherein, R 1d is a linear alkyl group having 8 to 16 carbon atoms, and R 2d is an alkylene group having 2 to 4 carbon atoms. G represents a group derived from reducing sugar. n is an average added mole number and represents a number of 0 or more and 5 or less, m is an average degree of condensation and represents a number of 1 or more and 3 or less. ]
  • R 1d is preferably a linear alkyl group having 12 to 14 carbon atoms.
  • n is 0 or more, and preferably 3 or less, more preferably 2 or less, and still more preferably 0.
  • R 2d is preferably an ethylene group.
  • G is a group derived from a reducing sugar, and more specifically, a glycosidic group can be mentioned.
  • the reducing sugar as a raw material may be any of aldose and ketose, and may be triose, tetrose, pentose or hexose having 3 to 6 carbon atoms.
  • aldoses include apiose, arabinose, galactose, glucose, lyxose, mannose, gallose, aldose, idose, talose and xylose, and ketose can include fructose.
  • aldopentose having 5 or 6 carbon atoms or aldohexose is preferred, and glucose is more preferred.
  • m represents the average degree of condensation of sugars and is a number of 1 or more, and preferably 2 or less, more preferably 1.5 or less.
  • the compound of the general formula (d1) can be easily synthesized by an acetalization reaction or a ketalization reaction of the above-mentioned sugar with R 1d- (O-R 2d ) n -OH using an acid catalyst. Moreover, in the case of an acetalization reaction, a hemiacetal structure may be sufficient and a normal acetal structure may be sufficient.
  • the alkoxylate type nonionic surfactant includes polyoxyalkylene alkyl or alkenyl ether.
  • the oxyalkylene group which a polyoxyalkylene alkyl or alkenyl ether has is preferably an oxyethylene group or an oxyalkylene group selected from an oxypropylene group, and preferably contains an oxyethylene group.
  • the average addition mole number of the oxyalkylene group is preferably 2 or more, more preferably 3 or more, and preferably 20 or less, more preferably 18 or less.
  • the carbon number of the alkyl group or alkenyl group which the polyoxyalkylene alkyl or alkenyl ether has is preferably 8 or more, more preferably 10 or more, and preferably 20 or less, preferably 18 or less.
  • the proportion of the anionic surfactant is preferably 50% by mass or less, more preferably 20% by mass with respect to the content of the component (d) including the anionic surfactant. % Or less. Further, in the bactericidal detergent composition of the present invention, the proportion of the anionic surfactant is preferably 50% by mass or less, more preferably 20% by mass or less, based on the content of the component (a).
  • the sterilizing detergent composition of the present invention contains the component (d), [the content of the component (a) + the content of the component (b) + the content of the component (c)] / [the component (d)]
  • the mass ratio of the content] is preferably 0.3 or more, more preferably 0.5 or more, and preferably 3 or less, more preferably 2 or less, still more preferably 1.5 or less.
  • the content of the component (d) in the composition is preferably 1% by mass or more, more preferably 5% by mass or more, and preferably The content is 20% by mass or less, more preferably 15% by mass or less.
  • the germicidal detergent composition of the present invention preferably contains water.
  • the germicidal detergent composition of the present invention is preferably a liquid composition.
  • the pH (measured by the glass electrode method) of the sterilizing / cleaning agent composition of the present invention is preferably 6.0 or more, more preferably 6.5 or more, and preferably 7.9 or less, more preferably 20 ° C. It is 7.8 or less.
  • the disinfectant cleaner composition of the present invention is preferably for hard surfaces. Specifically, it is preferable to use an article having a hard surface.
  • the material of the article having a hard surface includes plastic (including silicone resin and the like), metal, pottery, wood, and a combination thereof.
  • Articles having a hard surface include food processing equipment, cookware, rigid articles around the kitchen, dishes and the like. More preferably, the sterilizing and cleaning composition of the present invention is for food processing equipment or cooking utensils. Examples of food processing equipment to which the present invention is applied include large-scale equipment such as meat slicers, noodle makers, fryers, and rice cookers. Moreover, as a cooking appliance to which the present invention is applied, a cutting board, a kitchen knife, a colander and the like can be mentioned.
  • the present invention relates to an article having a hard surface, preferably a food processing plant, which brings a treatment liquid containing the germicidal detergent composition of the present invention into contact with an article having a hard surface, preferably a food processing plant and / or a cooker. And / or provide a method of sterilizing and cleaning the cookware.
  • the matters described in the sterilization cleaner composition of the present invention can be appropriately applied to this sterilization cleaning method.
  • the treatment liquid preferably contains 0.001% by mass or more, more preferably 0.005% by mass or more, still more preferably 0.01% by mass or more, and still more preferably 0.1% by mass or more of the component (a). More preferably, it is 0.5% by mass or more, more preferably 1% by mass or more, and preferably 10% by mass or less, more preferably 7% by mass or less, still more preferably 5% by mass or less, still more preferably 3% by mass or less contains.
  • the treatment liquid preferably contains 0.001% by mass or more, more preferably 0.005% by mass or more, still more preferably 0.01% by mass or more, and still more preferably 0.1% by mass of the component (b).
  • the treatment liquid preferably contains 0.001% by mass or more, more preferably 0.005% by mass or more, still more preferably 0.01% by mass or more, and still more preferably 0.1% by mass of the component (c).
  • the said process liquid can contain (d) component.
  • the treatment liquid contains the component (d)
  • the treatment liquid preferably contains the component (d) in an amount of preferably 0.002% by mass or more, more preferably 0.01% by mass or more, still more preferably 0.02% by mass.
  • the sterilizing cleaner composition of the present invention can be used as it is. That is, the sterilizing and cleaning agent composition of the present invention may be the treatment liquid. In addition, the sterilizing and cleaning agent composition of the present invention can be diluted with water to form the treatment solution.
  • the dilution ratio is preferably 100 times or less, more preferably 50 times or less, and still more preferably 10 times or less, from the viewpoints of economy, ease of storage and storage stability of the germicidal detergent composition.
  • the temperature of the treatment liquid is preferably 5 ° C. or more and 60 ° C. or less.
  • the contact time of the treatment liquid is preferably 1 minute or more and 120 minutes or less.
  • the pH (measured by the glass electrode method) of the treatment liquid is preferably 6.0 or more, more preferably 6.5 or more, and preferably 7.9 or less, more preferably 7.8 or less.
  • This pH may be the pH at the washing temperature. Also, the pH may be at 20 ° C.
  • the mass ratio of [content of component (a)] / [content of component (b) + content of component (c)], [content of component (b)] / [( c) mass ratio of component content] and [mass ratio of (a) component content + (b) component content + (c) component content] / [(d) component content] Each can select the same numerical value as the sterilizing cleaning composition of the present invention.
  • the present invention is a process for producing a bactericidal cleaner composition according to the present invention, wherein the content of the (a) component / the content of the (b) component + the (c) component in the bactericidal cleaner composition.
  • the method for producing a sterilizing / cleansing composition which comprises mixing the (a) component, the (b) component, and the (c) component such that the mass ratio of the content is 0.2 or more and 5 or less. That is, the mass ratio of [content of component (a)] / [content of component (b) + content of component (c)] of (a) component, (b) component, and (c) component is Provided is a method for producing a sterilizing cleaner composition, which is mixed to be 0.2 or more and 5 or less.
  • the matters described in the sterilizing and cleaning agent composition of the present invention can be appropriately applied to this production method.
  • the present invention contains (a) component, (b) component, and (c) component, [content of component (a)] / [content of component (b) + content of component (c)]
  • the composition has a weight ratio of 0.2 or more and 5 or less, and provides the use or use as a sterilizing and cleaning agent composition.
  • the matters described in the germicidal detergent composition of the present invention can be appropriately applied to this use or use.
  • component (a) Cationic germicide [hereinafter referred to as component (a)], amine oxide surfactant having one hydrocarbon group having 9 to 12 carbon atoms (hereinafter referred to as component (b)), and carbonization having 13 or 14 carbon atoms It contains an amine oxide surfactant having one hydrogen group [hereinafter referred to as component (c)].
  • the mass ratio of [content of component (a)] / [content of component (b) + content of component (c)] is 0.2 or more and 5 or less, Germicidal detergent composition.
  • ⁇ 3> Cationic surfactant bactericides in which the component (a) is a dialkyldimethyl ammonium halide, benzalkonium chloride, benzethonium chloride or their counter ions are converted to other anions, biguanides such as chlorhexidine, chlorhexidine gluconate, etc.
  • the germicidal cleaning agent composition as described in ⁇ 1> which is a cationic germicide selected from amino acid type
  • Component (b) is one or two selected from N-lauryl-N, N-dimethylamine-N-oxide and N- (3-lauroylaminopropyl) -N, N-dimethylamine-N-oxide
  • ⁇ 5> (C) One or more selected from the group consisting of N-myristyl-N, N-dimethylamine-N-oxide and N- (3-myristoyl aminopropyl) -N, N-dimethylamine-N-oxide
  • Composition Composition.
  • the mass ratio of [content of component (a)] / [content of component (b) + content of component (c)] is 0.2 or more, preferably 0.3 or more, more preferably 0.4 Or more, more preferably 0.5 or more, further preferably 0.6 or more, and 5 or less, preferably 4 or less, more preferably 2.5 or less, still more preferably 2 or less, further preferably 1 or less.
  • the germicidal detergent composition according to any one of ⁇ 1> to ⁇ 5>.
  • the mass ratio of [content of component (b)] / [content of component (c)] is preferably 0.1 or more, more preferably 0.4 or more, still more preferably 0.8 or more, and preferably The germicidal detergent composition according to any one of ⁇ 1> to ⁇ 6>, wherein is not more than 10, more preferably not more than 5, further preferably not more than 3.
  • the component (a) is preferably 0.1% by mass or more, more preferably 0.5% by mass or more, still more preferably 1% by mass or more, and preferably 10% by mass or less, more preferably 7% by mass or less.
  • the sterilizing / cleansing composition according to any one of ⁇ 1> to ⁇ 7>, more preferably containing 5% by mass or less.
  • the component (b) is preferably 0.1% by mass or more, more preferably 0.5% by mass or more, still more preferably 1% by mass or more, still more preferably 2% by mass or more, and preferably 10% by mass or less.
  • the component (c) is preferably 0.1% by mass or more, more preferably 0.5% by mass or more, still more preferably 0.8% by mass or more, still more preferably 1% by mass or more, and preferably 10% by mass
  • the germicidal detergent composition as described in any one of ⁇ 1>- ⁇ 10> which contains surfactant other than (a) component, (b) component, and (c) component as (d) component. object.
  • the nonionic surfactant is one or more nonionic surfactants selected from alkyl glycoside type nonionic surfactants and alkoxylate type nonionic surfactants, preferably alkyl glycoside type nonionic surfactants.
  • the germicidal cleaning agent composition as described in ⁇ 12>.
  • alkyl glycoside type surfactant is an alkyl glycoside type surfactant represented by the following general formula (d1).
  • R 1d- (O-R 2d ) n G m (d1) [Wherein, R 1d is a linear alkyl group having 8 to 16 carbon atoms, and R 2d is an alkylene group having 2 to 4 carbon atoms. G represents a group derived from reducing sugar.
  • n is an average added mole number and represents a number of 0 or more and 5 or less
  • m is an average degree of condensation and represents a number of 1 or more and 3 or less.
  • An alkoxylate type nonionic surfactant is Polyoxyalkylene alkyl or alkenyl ether, Furthermore, an oxyethylene group selected from an oxyethylene group and an oxypropylene group, particularly a polyoxyalkylene alkyl or alkenyl ether containing an oxyethylene group, Furthermore, the polyoxyalkylene alkyl or alkenyl ether, wherein the average addition mole number of the oxyalkylene group is preferably 2 or more, more preferably 3 or more, and preferably 20 or less, more preferably 18 or less.
  • the polyoxyalkylene alkyl or alkenyl ether wherein the carbon number of the alkyl group or the alkenyl group is preferably 8 or more, more preferably 10 or more, and preferably 20 or less, preferably 18 or less.
  • the germicidal cleaning agent composition as described in ⁇ 13> which is an oxyalkylene alkyl or alkenyl ether.
  • the mass ratio of [content of component (a) + content of component (b) + content of component (c)] / [content of component (d)] is preferably 0.3 or more, more preferably
  • the sterilizing cleaner composition as described in any one of ⁇ 11>- ⁇ 15> which is 0.5 or more, preferably 3 or less, more preferably 2 or less, further preferably 1.5 or less.
  • the content of the component (d) in the composition is preferably 1% by mass or more, more preferably 5% by mass or more, and preferably 20% by mass or less, more preferably 15% by mass or less ⁇ 11>
  • ⁇ 19> It has a hard surface which makes the processing liquid containing the sterilizing detergent composition according to any one of ⁇ 1> to ⁇ 18> come into contact with an article having a hard surface, preferably food processing equipment and / or cooking utensils. Method for sterilizing articles, preferably food processing equipment and / or cookware.
  • the treatment liquid preferably contains 0.001% by mass or more, more preferably 0.005% by mass or more, still more preferably 0.01% by mass or more, and still more preferably 0.1% by mass or more of the component (a). More preferably, it is 0.5% by mass or more, more preferably 1% by mass or more, and preferably 10% by mass or less, more preferably 7% by mass or less, still more preferably 5% by mass or less, still more preferably 3% by mass or less.
  • the treatment liquid preferably contains 0.001% by mass or more, more preferably 0.005% by mass or more, still more preferably 0.01% by mass or more, and still more preferably 0.1% by mass or more of the component (b). More preferably 0.5% by mass or more, further preferably 1% by mass or more, further preferably 2% by mass or more, and preferably 10% by mass or less, more preferably 7% by mass or less, still more preferably 5% by mass or less.
  • the treatment liquid preferably contains 0.001% by mass or more, more preferably 0.005% by mass or more, still more preferably 0.01% by mass or more, and still more preferably 0.1% by mass or more of the component (c). More preferably, it is 0.5 mass% or more, more preferably, 0.8 mass% or more, further preferably, 1 mass% or more, and preferably, 10 mass% or less, more preferably, 7 mass% or less, still more preferably 5 mass%.
  • the sterilization cleaning method according to any one of ⁇ 19> to ⁇ 21>, which contains at most%, more preferably at most 3 mass%.
  • the treatment liquid preferably contains component (d) in an amount of 0.002% by mass or more, more preferably 0.01% by mass or more, still more preferably 0.02% by mass or more, still more preferably 1% by mass or more, Preferably it is 20 mass% or less, more preferably 15 mass% or less, still more preferably 5 mass% or less, still more preferably 3 mass% or less, further preferably 2 mass% or less, any of ⁇ 19> to ⁇ 22>
  • the sterilization cleaning method according to any one of the preceding claims.
  • component (a) Cationic germicide [hereinafter referred to as component (a)], amine oxide surfactant having one hydrocarbon group having 9 to 12 carbon atoms (hereinafter referred to as component (b)), and carbonization having 13 or 14 carbon atoms
  • Amine oxide type surfactant having one hydrogen group (hereinafter referred to as component (c)] is represented as [content of component (a)] / [content of component (b) + content of component (c)]
  • the manufacturing method of the germicidal detergent composition which mixes so that mass ratio may be set to 0.2 or more and 5 or less.
  • ⁇ 25> The manufacturing method of ⁇ 24> which is a manufacturing method of the sterilizing detergent composition in any one of ⁇ 1>- ⁇ 18>.
  • component (a) Cationic germicide [hereinafter referred to as component (a)], amine oxide surfactant having one hydrocarbon group having 9 to 12 carbon atoms (hereinafter referred to as component (b)), and carbonization having 13 or 14 carbon atoms It contains an amine oxide surfactant having one hydrogen group [hereinafter referred to as component (c)].
  • component (c) The mass ratio of [content of component (a)] / [content of component (b) + content of component (c)] is 0.2 or more and 5 or less, Use of the composition as a germicidal cleaning composition.
  • composition according to any one of ⁇ 1> to ⁇ 18> as a germicidal detergent composition.
  • Example 1 The bactericidal detergent composition of Table 1 was prepared and subjected to the following evaluation. The results are shown in Table 1.
  • Test piece (SUS304, 1 mm x 25 mm x 70 mm, manufactured by Engineering Test Service Co., Ltd.) (mass x) weighing approximately 1 mg of rapeseed oil (manufactured by Wako Pure Chemical Industries, Ltd.) beforehand weighed using an electronic balance with lower 4 digits After the application / cm 2 application, it was weighed using a lower 4 digit balance (mass y). Each test piece after oil application was sprayed with 2 ml of a bactericidal detergent composition in a foam form using a pump former (for Biole hand wash, manufactured by Kao Corporation) and allowed to stand still for 20 minutes.
  • a pump former for Biole hand wash, manufactured by Kao Corporation
  • the test piece after washing for 20 minutes was rinsed with tap water at 25 ° C. for 1 minute (water volume: 700 ml, rotational speed of rotor: 300 rpm), using a reet tester. After rinsing, it was air-dried overnight under an environment of temperature 20 ° C./humidity 40%, and the weight of the test piece after washing was weighed by a lower 4-digit electronic balance (mass z).
  • Benzalkonium chloride Sanizole B-50 (Kao Corporation) ⁇ N-lauryl-N, N-dimethylamine-N-oxide: Anthyr 20N (Kao Corporation) ⁇ N-myristyl-N, N-dimethylamine-N-oxide: Anthyr 40N (Kao Corporation) ⁇ Alkyl glycoside: AG-124 (Kao Co., Ltd.), alkyl (C12-16 carbon) polyglucose (average sugar condensation degree 1-2) ⁇ Polyoxyethylene lauryl ether: Emulgen 105 (Kao Corporation)

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  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Agronomy & Crop Science (AREA)
  • General Chemical & Material Sciences (AREA)
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  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Zoology (AREA)
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  • Detergent Compositions (AREA)
  • Cleaning By Liquid Or Steam (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

L'invention concerne une composition d'agent nettoyant désinfectant qui comprend : un agent désinfectant cationique [ci-après composant (a)] ; un agent tensio-actif type oxyde d'amine possédant un groupe hydrocarbure de nombre d'atomes de carbone supérieur ou égal à 9 ou inférieur ou égal à 12 [ci-après composant (b)] ; et un agent tensio-actif type oxyde d'amine possédant un groupe hydrocarbure de 13 ou 14 atomes de carbone [ci-après composant (c)]. Le rapport massique [teneur en composant (a)]/ [teneur en composant (b)+teneur en composant (c)] est supérieur ou égal à 0,2 et inférieur ou égal à 5.
PCT/JP2018/039816 2017-10-30 2018-10-26 Composition d'agent nettoyant désinfectant WO2019087953A1 (fr)

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JP2017057345A (ja) * 2015-09-18 2017-03-23 株式会社Adeka 発泡洗浄剤組成物および洗浄方法

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TW201923060A (zh) 2019-06-16
CN111065721A (zh) 2020-04-24
JP2019081891A (ja) 2019-05-30
TWI811256B (zh) 2023-08-11
JP7657537B2 (ja) 2025-04-07

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