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WO2018129789A1 - Whole-process continuous gas-assisted magnetic separation system - Google Patents

Whole-process continuous gas-assisted magnetic separation system Download PDF

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Publication number
WO2018129789A1
WO2018129789A1 PCT/CN2017/074332 CN2017074332W WO2018129789A1 WO 2018129789 A1 WO2018129789 A1 WO 2018129789A1 CN 2017074332 W CN2017074332 W CN 2017074332W WO 2018129789 A1 WO2018129789 A1 WO 2018129789A1
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Prior art keywords
column
extraction
magnetic
desorption
storage tank
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PCT/CN2017/074332
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French (fr)
Chinese (zh)
Inventor
杨良嵘
董婷婷
邢慧芳
于杰淼
戎猛
刘会洲
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中国科学院过程工程研究所
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Priority to EP17891394.3A priority Critical patent/EP3424600B1/en
Publication of WO2018129789A1 publication Critical patent/WO2018129789A1/en

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03C—MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03C1/00—Magnetic separation
    • B03C1/02—Magnetic separation acting directly on the substance being separated
    • B03C1/10—Magnetic separation acting directly on the substance being separated with cylindrical material carriers
    • B03C1/14—Magnetic separation acting directly on the substance being separated with cylindrical material carriers with non-movable magnets
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03C—MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03C1/00—Magnetic separation
    • B03C1/32—Magnetic separation acting on the medium containing the substance being separated, e.g. magneto-gravimetric-, magnetohydrostatic-, or magnetohydrodynamic separation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03C—MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03C1/00—Magnetic separation
    • B03C1/005—Pretreatment specially adapted for magnetic separation
    • B03C1/01—Pretreatment specially adapted for magnetic separation by addition of magnetic adjuvants
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03C—MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03C1/00—Magnetic separation
    • B03C1/02—Magnetic separation acting directly on the substance being separated
    • B03C1/30—Combinations with other devices, not otherwise provided for
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
    • B03D1/00—Flotation
    • B03D1/02—Froth-flotation processes
    • B03D1/023—Carrier flotation; Flotation of a carrier material to which the target material attaches
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
    • B03D1/00—Flotation
    • B03D1/14—Flotation machines
    • B03D1/1443—Feed or discharge mechanisms for flotation tanks
    • B03D1/1462—Discharge mechanisms for the froth
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
    • B03D1/00—Flotation
    • B03D1/14—Flotation machines
    • B03D1/24—Pneumatic
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03C—MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03C2201/00—Details of magnetic or electrostatic separation
    • B03C2201/18—Magnetic separation whereby the particles are suspended in a liquid
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03C—MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03C2201/00—Details of magnetic or electrostatic separation
    • B03C2201/26—Details of magnetic or electrostatic separation for use in medical or biological applications

Definitions

  • the invention relates to the technical field of magnetic separation processing equipment, in particular to a full-process continuous gas-assisted magnetic separation system.
  • the magnetic carrier separation technique adsorbs a target component by an affinity ligand, a hydrophobic group, an ion exchange group, and the like coupled to the surface of the magnetic carrier, and then separates the magnetic carrier loaded with the target by a suitable magnetic separation device.
  • a new separation technique that comes out and is washed and eluted to directly and quickly separate the target.
  • the magnetic carrier separation technology has been developed since the 1970s and has been greatly developed. Because of its advantages of rapid and simple separation, high selectivity, rapid separation and direct application to the separation of complex systems, it has been proposed and widely studied for immunoassay, cell labeling and separation, nucleic acid separation, protein purification, wastewater treatment. , the separation of natural products and other fields.
  • the technique when the technique is used in the separation field, since the separation object is mostly a dilute solution or even a very dilute solution, a moderate increase in the processing scale faces a great challenge.
  • the existing magnetic separation device can not adapt to the requirement if the processing scale is too small, or the spatial magnetic field intensity and gradient in the device after amplification are insufficient, resulting in weak magnetic particles and ultrafine magnetic particles flowing in the space, especially the nano magnetic particles, and the magnetic force Too weak to be captured quickly and efficiently. How to effectively treat a large amount of dilute solution containing magnetic particles is a prominent problem in the application of magnetic carrier separation technology.
  • the object of the present invention is to provide a full-flow continuous gas-assisted magnetic separation system, which solves the problem that the magnetic field strength and the gradient are insufficient after the device existing in the prior art is increased, and the weak magnetic particles and ultra-fine magnetic particles in the space, especially It is a technical problem of nano magnetic particles that cannot be quickly and efficiently captured.
  • a full-flow continuous gas-assisted magnetic separation system comprising an adsorption tank, the adsorption tank is connected with an extraction tower, and the extraction tower is connected with a desorption tower;
  • the top of the adsorption tank is provided with a feed liquid inlet and a magnetic particle inlet, and the bottom is provided with a mixed liquid outlet, and the adsorption tank is provided with a stirring device;
  • the extraction column comprises a hollow air floating column, the air floating column is provided with a mixed liquid inlet and a raffinate outlet, and the mixed liquid inlet is connected with the mixed liquid outlet, and the top of the air floating column is provided a magnetic roller, one side of the magnetic roller is provided with a scraper, the end of the scraper is provided with a mixture storage tank, and the bottom of the air floating column is provided with a gas inlet;
  • the desorption column comprises a hollow air floating column, the air floating column is provided with a magnetic particle inlet and a product outlet, the magnetic particle inlet is connected with the mixture storage tank, and the top of the air floating column is provided with a magnetic roller
  • One side of the magnetic roller is provided with a scraper, the end of the scraper is provided with a magnetic particle storage tank, the magnetic particle storage tank is connected with the adsorption tower, and the bottom of the air floating column is provided with a gas inlet ;
  • the extraction tower and the air floatation column of the desorption tower are connected with a flushing device, and the flushing port of the flushing device is disposed opposite to the scraper.
  • a plurality of extraction columns are included, and a plurality of the extraction columns are connected in series through the mixed liquid inlet and the raffinate outlet;
  • the mixed liquid inlet of the extraction column at the head end is connected to the mixed liquid outlet, and the raffinate outlet of the extraction column at the end is connected to the raffinate storage tank.
  • a plurality of extraction columns are included, and the mixed liquid inlets of each of the extraction columns are respectively connected to the mixed liquid outlet, and the raffinate outlet of each of the extraction columns is connected to a raffinate storage tank.
  • a plurality of desorption columns are included, and a plurality of the desorption columns are connected in series through the magnetic particle inlet and the product outlet;
  • the magnetic particle inlet of the desorption column at the head end is connected to the mixture storage tank, and the product outlet of the desorption column at the end is connected to the product storage tank.
  • a plurality of desorption columns are included, the magnetic particle inlets of each of the desorption columns being respectively connected to the mixture storage tank, and the product outlet of each of the desorption columns is connected to a product storage tank.
  • liquid inlet, the magnetic particle inlet and the stirring device are all disposed on the can lid of the adsorption can, and the can lid of the adsorption can is connected with the lifting assembly.
  • a peristaltic pump is disposed between the adsorption tank and the extraction tower, between the extraction tower and the desorption tower, and between the flushing device and the scraper.
  • control device includes a controller, the controller is connected to the stirring device, the magnetic roller, the lifting assembly and the peristaltic pump, and the controller is provided with a control Button.
  • the utility model further comprises a gas supply pipeline, wherein the gas supply pipeline is respectively connected with the gas inlets of the extraction tower and the desorption tower, and a gas flow meter is arranged at the gas inlet of the extraction tower and the desorption tower.
  • the magnetic roller includes a magnetic arcuate region, and the arc of the magnetic arcuate region has an arc of 240°.
  • the invention provides a full-flow continuous gas-assisted magnetic separation system.
  • the extraction is carried out in an adsorption tower to complete the adsorption of the target object and the magnetic particles, and then enters the extraction tower, and the magnetic particles in the extraction tower are raised.
  • the magnetic particles are trapped by the rising bubbles, and are enriched to the liquid surface to form a magnetic particle solution enrichment zone, and pass through the magnetic roller at the magnetic particle solution enrichment zone.
  • the separation of the magnetic particles from the desorbent is completed, after which the magnetic particles are continuously sent to the adsorption tank for recycling.
  • the whole process continuous gas-assisted magnetic separation system couples the air-floating separation technology with the magnetic carrier separation technology, and has a high magnetic separation effect after the device scale is increased;
  • the canister, the extraction column and the desorption column are respectively used for the continuous magnetic separation of the adsorption, washing and desorption processes of the target, and the continuous realization of the three processes themselves is realized, and finally the continuous separation of the entire process of the target separation is achieved.
  • the system can not only achieve the whole process of the target separation, but also realize the continuous flow and direct recycling of the magnetic particle carrier.
  • FIG. 1 is a schematic flow chart of a full-process continuous gas-assisted magnetic separation system provided by the present invention
  • FIG. 2 is a front elevational view of the magnetic roller of the full flow continuous gas magnetic separation system provided by the present invention.
  • the embodiment provides a full-flow continuous gas-assisted magnetic separation system, which comprises an adsorption tank 1, an adsorption tank 1 is connected with an extraction tower 2, and an extraction tower 2 is connected with a desorption tower 3. ;
  • the top of the adsorption tank 1 is provided with a liquid inlet 4 and a magnetic particle inlet 5, the bottom is provided with a mixed liquid outlet, and the adsorption tank 1 is provided with a stirring device 6;
  • the extraction tower 2 comprises a hollow air floating column 7, and the air floating column 7 is provided with a mixed liquid inlet and a raffinate outlet, and the mixed liquid inlet and the mixed liquid outlet are connected.
  • the top of the air floating column 7 is provided with a magnetic roller 8 and a magnetic roller.
  • a scraper 9 is disposed on one side of the strip 8
  • a mixture storage tank 10 is disposed at the end of the scraper 9, and a gas inlet is provided at the bottom of the air float column 7;
  • the desorption column 3 comprises a hollow air floating column 7, on which the magnetic particle inlet and the product outlet are arranged, the magnetic particle inlet is connected to the mixture storage tank 10, and the top of the air floating column 7 is provided with a magnetic roller 8, and the magnetic roller 8 One side There is a squeegee 9, the end of the squeegee 9 is provided with a magnetic particle storage tank 11, the magnetic particle storage tank 11 is connected with the adsorption tower, and the bottom of the air floating column 7 is provided with a gas inlet;
  • the extraction column 2 and the air floating column 7 of the desorption column 3 are each connected with a flushing device, and the flushing port of the flushing device is disposed opposite to the scraper 9.
  • the adsorption tank 1 in the system has a large capacity, that is, a sufficient amount of the adsorption raw material liquid can be prepared for subsequent continuous use, and high-capacity storage is also provided for easy realization of closed loop.
  • a manhole and a liquid level observation hole of the glass are disposed on the adsorption tank 1 to facilitate observation of the material and liquid level inside the adsorption tank 1.
  • the rinsing device comprises a rinsing liquid storage tank 17 connected to the rinsing port, wherein the extraction column 2 and the desorption column 3 use the same rinsing liquid storage tank 17, or the extraction column 2 and the desorption column 3 are separately provided with rinsing liquid storage Both cans 17 can be used.
  • a plurality of extraction towers 2 and a desorption tower 3 may be respectively adopted, specifically including a plurality of extraction towers 2, and a plurality of extraction towers 2 pass through a mixed liquid inlet and a raffinate The liquid outlets are connected in series;
  • the mixed liquid inlet of the extraction column 2 at the head end is connected to the mixed liquid outlet, and the raffinate outlet of the end extraction column 2 is connected to the raffinate storage tank 12.
  • each of the extraction columns 2 is connected to the mixed liquid outlet, and the raffinate outlet of each of the extraction columns 2 is connected to the raffinate storage tank 12.
  • the above two forms are respectively a form in which a plurality of extraction towers 2 are connected in series and in parallel, wherein when the extraction towers 2 are connected in series, the multi-stage magnetic separation can make the separation of magnetic particles in the raffinate more fully; When connected in parallel, multiple extraction columns 2 can be used simultaneously, and the magnetic separation efficiency is higher.
  • the desorption column 3 can also be connected in series or in parallel, that is, including a plurality of desorption columns 3, and the plurality of desorption columns 3 are connected in series through the magnetic particle inlet and the product outlet;
  • the magnetic particle inlet of the desorption column 3 at the head end is connected to the mixture storage tank 10, and the product outlet of the desorbing column 3 at the end is connected to the product storage tank 13.
  • each desorption column 3 is included, the magnetic particle inlets of each desorption column 3 are respectively connected to the mixture storage tank 10, and the product outlet of each desorption column 3 is connected to the product storage tank 13.
  • the desorption column 3 connected in series is more sufficient for the recovery of the magnetic particles, reducing the circulation loss of the magnetic particles; and the desorption column 3 connected in parallel can improve the recovery efficiency of the magnetic particles.
  • the liquid inlet 4, the magnetic particle inlet 5 and the stirring device 6 are all disposed on the can lid of the adsorption tank 1, and the can lid of the adsorption tank 1 is connected with a lifting assembly.
  • the adsorption tank 1 can be lifted and lowered by setting the lifting assembly, which facilitates maintenance and inspection of the interior of the device later.
  • the lifting assembly is a telescopic cylinder, a hydraulic cylinder, an electric hoist, and the like.
  • a peristaltic pump 14 is provided between the adsorption tank 1 and the extraction column 2, between the extraction column 2 and the desorption column 3, and between the rinsing device and the squeegee 9.
  • the flow rate of the peristaltic pump 14 is adjusted from 3 to 6800 mL/min.
  • the embodiment further includes a control device including a controller connected to the stirring device 6, the magnetic roller 8, the lifting assembly and the peristaltic pump 14, and the controller is provided with a control button.
  • the control device is arranged at the lower part of the system for easy operation, and the control device is provided with corresponding control buttons for convenient operation by the operator.
  • the present embodiment further includes a gas supply line connected to the gas inlets of the extraction column 2 and the desorption column 3, respectively, and a gas flow meter 15 at the gas inlet of the extraction column 2 and the desorption column 3.
  • the extraction column 2 and the desorption column 3 are subjected to a uniform gas supply operation through the gas supply line, wherein a corresponding gas flow meter 15 is provided at the gas inlet, and the range of the gas flow meter 15 is set to 6 to 60 L/h.
  • the magnet roller 8 includes a magnetic arcuate region 16 having an arc of 240°.
  • the surface of the magnetic arc-shaped region 16 of the magnetic roller 8 has a relatively uniform trapping force on the magnetic particles, and in the design of the magnetic circuit system, a certain amount is small
  • the type of NdFeB rare earth permanent magnets are arranged in a ring shape at a certain interval along the surface of the cylinder to enable uniform magnetic field strength on the surface of the sleeve.
  • the whole process continuous gas assisted magnetic separation system, the mixture storage tank 10, the magnetic particle storage tank 11, the raffinate storage tank 12, the product storage tank 13 and the flushing liquid storage tank 17 are all made of stainless steel, generally Set its shape to a cuboid shape.
  • a plurality of spare storage tanks can be provided for arranging and storing the washing supernatant and the desorbent.
  • the magnetic carrier ie, magnetic particles
  • the solution containing the target separation are mixed in the adsorption tank 1, and fully stirred by the stirring device 6, accelerating the extraction process of the magnetic particles to the target and promoting the sufficient suspension of the magnetic particles.
  • the extraction column 2 taking two extraction columns 2 as an example, one can be used at the same time, or can be used alternately or in series
  • the magnetic particles are fully supported by the magnetic roller 8 with the aid of the air floating column 7.
  • the suspension is pumped into the desorption column 3, and the desorbing column 3 has a desorbing liquid.
  • the target is desorbed from the magnetic particles and enters the product storage tank 13.
  • the desorbed magnetic particles are captured by the magnetic roller 8 and washed by the washing liquid to enter the magnetic field.
  • the magnetic particles can be refluxed into the adsorption tower for recycling, and form a continuous closed circuit cycle.

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  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Biotechnology (AREA)
  • Physics & Mathematics (AREA)
  • Fluid Mechanics (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Treatment Of Liquids With Adsorbents In General (AREA)
  • Water Treatment By Sorption (AREA)

Abstract

Disclosed is a whole-process continuous gas-assisted magnetic separation system, comprising an adsorption tank (1), an extraction column (2) connected to the adsorption tank (1), and a desorption column (3) connected to the extraction column (2). The extraction column (2) and the desorption column (3) each comprises a hollow gas floatation column (7). A magnetic roller (8) is provided on the top of each gas floatation column (7), a scraper (9) is provided on one side of the magnetic roller (8), and a gas inlet is provided at the bottom of each gas floatation column (7). Each of the gas floatation columns (7) of the extraction column (2) and the desorption column (3) is connected to a rinsing device, a rinsing opening of which is arranged opposite the scraper (9).

Description

一种全流程连续化气助磁分离系统Full process continuous gas-assisted magnetic separation system 技术领域Technical field
本发明涉及磁分离处理设备技术领域，尤其涉及一种全流程连续化气助磁分离系统。The invention relates to the technical field of magnetic separation processing equipment, in particular to a full-process continuous gas-assisted magnetic separation system.
背景技术Background technique
磁性载体分离技术是通过偶联在磁性载体表面的亲和配基、疏水基团、离子交换基团等对目标组分进行吸附，然后利用合适的磁分离装置将负载了目标物的磁性载体分离出来，并经过清洗、洗脱来直接快速的分离目标物的新型分离技术。磁性载体分离技术从20世纪70年代起开始发展起来，并获得了很大发展。由于该技术具有分离快速简单，选择性高，分离迅速和可直接适用于复杂体系的分离等优点，因此被提出和广泛研究应用于免疫检测、细胞标记和分离、核酸分离、蛋白质纯化、废水处理、天然产物分离等领域。The magnetic carrier separation technique adsorbs a target component by an affinity ligand, a hydrophobic group, an ion exchange group, and the like coupled to the surface of the magnetic carrier, and then separates the magnetic carrier loaded with the target by a suitable magnetic separation device. A new separation technique that comes out and is washed and eluted to directly and quickly separate the target. The magnetic carrier separation technology has been developed since the 1970s and has been greatly developed. Because of its advantages of rapid and simple separation, high selectivity, rapid separation and direct application to the separation of complex systems, it has been proposed and widely studied for immunoassay, cell labeling and separation, nucleic acid separation, protein purification, wastewater treatment. , the separation of natural products and other fields.
但是，该技术用于分离领域时，由于分离对象大多数时候是稀溶液甚至极稀溶液，适度增大处理规模就面临着巨大挑战。现有的磁分离装置要么处理规模太小无法适应要求，要么放大后装置内空间磁场强度及梯度不够，导致空间内流动的弱磁性颗粒和超细磁性颗粒，尤其是纳米磁性颗粒，所受磁力太弱而不能被快速有效捕集。如何有效的处理大量含磁颗粒的稀溶液是磁性载体分离技术应用中的一个突出问题。However, when the technique is used in the separation field, since the separation object is mostly a dilute solution or even a very dilute solution, a moderate increase in the processing scale faces a great challenge. The existing magnetic separation device can not adapt to the requirement if the processing scale is too small, or the spatial magnetic field intensity and gradient in the device after amplification are insufficient, resulting in weak magnetic particles and ultrafine magnetic particles flowing in the space, especially the nano magnetic particles, and the magnetic force Too weak to be captured quickly and efficiently. How to effectively treat a large amount of dilute solution containing magnetic particles is a prominent problem in the application of magnetic carrier separation technology.
发明内容Summary of the invention
本发明的目的在于提出一种全流程连续化气助磁分离系统，以解决现有技术中存在的装置增大后，磁场强度及梯度不够，空间内的弱磁性颗粒和超细磁性颗粒，尤其是纳米磁性颗粒，不能被快速有效捕集的技术问题。 The object of the present invention is to provide a full-flow continuous gas-assisted magnetic separation system, which solves the problem that the magnetic field strength and the gradient are insufficient after the device existing in the prior art is increased, and the weak magnetic particles and ultra-fine magnetic particles in the space, especially It is a technical problem of nano magnetic particles that cannot be quickly and efficiently captured.
为达此目的，本发明采用以下技术方案：To this end, the present invention employs the following technical solutions:
一种全流程连续化气助磁分离系统，包括吸附罐，所述吸附罐连接有萃取塔，所述萃取塔连接有解吸塔；A full-flow continuous gas-assisted magnetic separation system, comprising an adsorption tank, the adsorption tank is connected with an extraction tower, and the extraction tower is connected with a desorption tower;
所述吸附罐顶部设有料液进口和磁颗粒进口，底部设有混合液出口，所述吸附罐内设有搅拌装置；The top of the adsorption tank is provided with a feed liquid inlet and a magnetic particle inlet, and the bottom is provided with a mixed liquid outlet, and the adsorption tank is provided with a stirring device;
所述萃取塔包括中空的气浮柱，所述气浮柱上设有混合液入口和萃余液出口，所述混合液入口和所述混合液出口连接，所述气浮柱的顶部设有磁辊，所述磁辊的一侧设有刮板，所述刮板的末端设有混合物储罐，所述气浮柱的底部设有气体入口；The extraction column comprises a hollow air floating column, the air floating column is provided with a mixed liquid inlet and a raffinate outlet, and the mixed liquid inlet is connected with the mixed liquid outlet, and the top of the air floating column is provided a magnetic roller, one side of the magnetic roller is provided with a scraper, the end of the scraper is provided with a mixture storage tank, and the bottom of the air floating column is provided with a gas inlet;
所述解吸塔包括中空的气浮柱，所述气浮柱上设有磁颗粒入口和产品出口，所述磁颗粒入口与所述混合物储罐连接，所述气浮柱的顶部设有磁辊，所述磁辊的一侧设有刮板，所述刮板的末端设有磁颗粒储罐，所述磁颗粒储罐与所述吸附塔连接，所述气浮柱的底部设有气体入口；The desorption column comprises a hollow air floating column, the air floating column is provided with a magnetic particle inlet and a product outlet, the magnetic particle inlet is connected with the mixture storage tank, and the top of the air floating column is provided with a magnetic roller One side of the magnetic roller is provided with a scraper, the end of the scraper is provided with a magnetic particle storage tank, the magnetic particle storage tank is connected with the adsorption tower, and the bottom of the air floating column is provided with a gas inlet ;
所述萃取塔和所述解吸塔的所述气浮柱均连接有冲洗装置，所述冲洗装置的冲洗口与所述刮板相对设置。The extraction tower and the air floatation column of the desorption tower are connected with a flushing device, and the flushing port of the flushing device is disposed opposite to the scraper.
进一步的，包括多个萃取塔，多个所述萃取塔之间通过所述混合液入口和所述萃余液出口串联连接；Further, a plurality of extraction columns are included, and a plurality of the extraction columns are connected in series through the mixed liquid inlet and the raffinate outlet;
其中，位于首端的所述萃取塔的所述混合液入口和所述混合液出口连接，末端的所述萃取塔的萃余液出口连接萃余液储罐。Wherein the mixed liquid inlet of the extraction column at the head end is connected to the mixed liquid outlet, and the raffinate outlet of the extraction column at the end is connected to the raffinate storage tank.
进一步的，包括多个萃取塔，每个所述萃取塔的所述混合液入口分别与所述混合液出口连接，每个所述萃取塔的萃余液出口连接萃余液储罐。Further, a plurality of extraction columns are included, and the mixed liquid inlets of each of the extraction columns are respectively connected to the mixed liquid outlet, and the raffinate outlet of each of the extraction columns is connected to a raffinate storage tank.
进一步的，包括多个解吸塔，多个所述解吸塔之间通过所述磁颗粒入口和所述产品出口串联连接； Further, a plurality of desorption columns are included, and a plurality of the desorption columns are connected in series through the magnetic particle inlet and the product outlet;
其中，位于首端的所述解吸塔的所述磁颗粒入口与所述混合物储罐连接，末端的所述解吸塔的产品出口连接产品储罐。Wherein the magnetic particle inlet of the desorption column at the head end is connected to the mixture storage tank, and the product outlet of the desorption column at the end is connected to the product storage tank.
进一步的，包括多个解吸塔，每个所述解吸塔的所述磁颗粒入口分别与所述混合物储罐连接，每个所述解吸塔的所述产品出口与产品储罐连接。Further, a plurality of desorption columns are included, the magnetic particle inlets of each of the desorption columns being respectively connected to the mixture storage tank, and the product outlet of each of the desorption columns is connected to a product storage tank.
进一步的，所述料液进口、所述磁颗粒进口及所述搅拌装置均设于所述吸附罐的罐盖上，所述吸附罐的罐盖连接有升降组件。Further, the liquid inlet, the magnetic particle inlet and the stirring device are all disposed on the can lid of the adsorption can, and the can lid of the adsorption can is connected with the lifting assembly.
进一步的，所述吸附罐与所述萃取塔之间、所述萃取塔与所述解吸塔之间以及所述冲洗装置与所述刮板之间均设有蠕动泵。Further, a peristaltic pump is disposed between the adsorption tank and the extraction tower, between the extraction tower and the desorption tower, and between the flushing device and the scraper.
进一步的，还包括控制装置，所述控制装置包括控制器，所述控制器与所述搅拌装置、所述磁辊、所述升降组件和所述蠕动泵连接，所述控制器上设有控制按钮。Further, a control device is further included, the control device includes a controller, the controller is connected to the stirring device, the magnetic roller, the lifting assembly and the peristaltic pump, and the controller is provided with a control Button.
进一步的，还包括供气管路，所述供气管路分别与所述萃取塔和所述解吸塔的气体入口连接，所述萃取塔和所述解吸塔的气体入口处设有气体流量计。Further, the utility model further comprises a gas supply pipeline, wherein the gas supply pipeline is respectively connected with the gas inlets of the extraction tower and the desorption tower, and a gas flow meter is arranged at the gas inlet of the extraction tower and the desorption tower.
进一步的，所述磁辊包括磁弧形区，所述磁弧形区的弧度为240°。Further, the magnetic roller includes a magnetic arcuate region, and the arc of the magnetic arcuate region has an arc of 240°.
本发明提供的一种全流程连续化气助磁分离系统，使用时，在吸附塔内进行萃取，完成目标物与磁颗粒的吸附，之后，进入到萃取塔，萃取塔内磁颗粒被上升气泡捕获，并被富集到液面形成磁颗粒溶液富集区，在磁颗粒溶液富集区处通过磁辊完成磁颗粒与萃余液的分离，之后，磁颗粒进入解吸塔，解吸塔内设有解吸液，解吸液将目标物与磁颗粒分离，同理，磁颗粒被上升气泡捕获，并被富集到液面形成磁颗粒溶液富集区，在磁颗粒溶液富集区处通过磁辊完成磁颗粒与解吸液的分离，之后，磁颗粒继续送至吸附罐内循环使用。The invention provides a full-flow continuous gas-assisted magnetic separation system. When used, the extraction is carried out in an adsorption tower to complete the adsorption of the target object and the magnetic particles, and then enters the extraction tower, and the magnetic particles in the extraction tower are raised. Captured and enriched into the liquid surface to form a magnetic particle solution enrichment zone, and the magnetic particle and the raffinate are separated by a magnetic roller at the magnetic particle solution enrichment zone, after which the magnetic particles enter the desorption column, and the desorption tower is provided There is a desorption liquid, and the desorbing liquid separates the target object from the magnetic particles. Similarly, the magnetic particles are trapped by the rising bubbles, and are enriched to the liquid surface to form a magnetic particle solution enrichment zone, and pass through the magnetic roller at the magnetic particle solution enrichment zone. The separation of the magnetic particles from the desorbent is completed, after which the magnetic particles are continuously sent to the adsorption tank for recycling.
该全流程连续化气助磁分离系统，将气浮分离技术与磁性载体分离技术相耦合，在装置规模增大后，仍然具有较高的磁分离效果；同时，串联设置的吸 附罐、萃取塔和解吸塔分别用于目标物的吸附、洗涤和解吸过程的连续磁分离，结合三个过程本身的连续化实现，最终实现目标分离物全流程的连续化分离。同时，该系统不仅能够实现目标分离物的全流程连续化，而且能够实现磁颗粒载体的全流程连续化和可直接循环利用性。The whole process continuous gas-assisted magnetic separation system couples the air-floating separation technology with the magnetic carrier separation technology, and has a high magnetic separation effect after the device scale is increased; The canister, the extraction column and the desorption column are respectively used for the continuous magnetic separation of the adsorption, washing and desorption processes of the target, and the continuous realization of the three processes themselves is realized, and finally the continuous separation of the entire process of the target separation is achieved. At the same time, the system can not only achieve the whole process of the target separation, but also realize the continuous flow and direct recycling of the magnetic particle carrier.
附图说明DRAWINGS
图1是本发明提供的全流程连续化气助磁分离系统的流程示意图；1 is a schematic flow chart of a full-process continuous gas-assisted magnetic separation system provided by the present invention;
图2是本发明提供的全流程连续化气助磁分离系统的磁辊处的主视图。2 is a front elevational view of the magnetic roller of the full flow continuous gas magnetic separation system provided by the present invention.
图中：In the picture:
1、吸附罐；2、萃取塔；3、解吸塔；4、料液进口；5、磁颗粒进口；6、搅拌装置；7、气浮柱；8、磁辊；9、刮板；10、混合物储罐；11、磁颗粒储罐；12、萃余液储罐；13、产品储罐；14、蠕动泵；15、气体流量计；16、磁弧形区；17、冲洗液储罐。1, adsorption tank; 2, extraction tower; 3, desorption tower; 4, feed liquid inlet; 5, magnetic particle import; 6, stirring device; 7, air floating column; 8, magnetic roller; 9, scraper; Mixture storage tank; 11, magnetic particle storage tank; 12, raffinate storage tank; 13, product storage tank; 14, peristaltic pump; 15, gas flow meter; 16, magnetic arc-shaped area; 17, flushing liquid storage tank.
具体实施方式detailed description
下面结合附图并通过具体实施方式来进一步说明本发明的技术方案。The technical solution of the present invention will be further described below with reference to the accompanying drawings and specific embodiments.
如图1和图2所示，本实施例提供了一种全流程连续化气助磁分离系统，该系统包括吸附罐1，吸附罐1连接有萃取塔2，萃取塔2连接有解吸塔3；As shown in FIG. 1 and FIG. 2, the embodiment provides a full-flow continuous gas-assisted magnetic separation system, which comprises an adsorption tank 1, an adsorption tank 1 is connected with an extraction tower 2, and an extraction tower 2 is connected with a desorption tower 3. ;
吸附罐1顶部设有料液进口4和磁颗粒进口5，底部设有混合液出口，吸附罐1内设有搅拌装置6；The top of the adsorption tank 1 is provided with a liquid inlet 4 and a magnetic particle inlet 5, the bottom is provided with a mixed liquid outlet, and the adsorption tank 1 is provided with a stirring device 6;
萃取塔2包括中空的气浮柱7，气浮柱7上设有混合液入口和萃余液出口，混合液入口和混合液出口连接，气浮柱7的顶部设有磁辊8，磁辊8的一侧设有刮板9，刮板9的末端设有混合物储罐10，气浮柱7的底部设有气体入口；The extraction tower 2 comprises a hollow air floating column 7, and the air floating column 7 is provided with a mixed liquid inlet and a raffinate outlet, and the mixed liquid inlet and the mixed liquid outlet are connected. The top of the air floating column 7 is provided with a magnetic roller 8 and a magnetic roller. a scraper 9 is disposed on one side of the strip 8, a mixture storage tank 10 is disposed at the end of the scraper 9, and a gas inlet is provided at the bottom of the air float column 7;
解吸塔3包括中空的气浮柱7，气浮柱7上设有磁颗粒入口和产品出口，磁颗粒入口与混合物储罐10连接，气浮柱7的顶部设有磁辊8，磁辊8的一侧设 有刮板9，刮板9的末端设有磁颗粒储罐11，磁颗粒储罐11与吸附塔连接，气浮柱7的底部设有气体入口；The desorption column 3 comprises a hollow air floating column 7, on which the magnetic particle inlet and the product outlet are arranged, the magnetic particle inlet is connected to the mixture storage tank 10, and the top of the air floating column 7 is provided with a magnetic roller 8, and the magnetic roller 8 One side There is a squeegee 9, the end of the squeegee 9 is provided with a magnetic particle storage tank 11, the magnetic particle storage tank 11 is connected with the adsorption tower, and the bottom of the air floating column 7 is provided with a gas inlet;
萃取塔2和解吸塔3的气浮柱7均连接有冲洗装置，冲洗装置的冲洗口与刮板9相对设置。The extraction column 2 and the air floating column 7 of the desorption column 3 are each connected with a flushing device, and the flushing port of the flushing device is disposed opposite to the scraper 9.
该系统中的吸附罐1具有较大的容量，即可一次性制备足够量吸附原料液供应后续连续化使用，同时也为易于实现闭路循环提供高容量储存。在吸附罐1上设置玻璃的人孔和液位观察孔，以便于对吸附罐1里面的物料和液位进行观察。The adsorption tank 1 in the system has a large capacity, that is, a sufficient amount of the adsorption raw material liquid can be prepared for subsequent continuous use, and high-capacity storage is also provided for easy realization of closed loop. A manhole and a liquid level observation hole of the glass are disposed on the adsorption tank 1 to facilitate observation of the material and liquid level inside the adsorption tank 1.
冲洗装置包括冲洗液储罐17，冲洗液储罐17与冲洗口连接，其中，萃取塔2和解吸塔3使用同一个冲洗液储罐17，或者萃取塔2和解吸塔3单独设置冲洗液储罐17均可。The rinsing device comprises a rinsing liquid storage tank 17 connected to the rinsing port, wherein the extraction column 2 and the desorption column 3 use the same rinsing liquid storage tank 17, or the extraction column 2 and the desorption column 3 are separately provided with rinsing liquid storage Both cans 17 can be used.
该全流程连续化气助磁分离系统中，分别可采用多个萃取塔2和解吸塔3的形式，具体的包括多个萃取塔2，多个萃取塔2之间通过混合液入口和萃余液出口串联连接；In the whole process continuous gas-assisted magnetic separation system, a plurality of extraction towers 2 and a desorption tower 3 may be respectively adopted, specifically including a plurality of extraction towers 2, and a plurality of extraction towers 2 pass through a mixed liquid inlet and a raffinate The liquid outlets are connected in series;
其中，位于首端的萃取塔2的混合液入口和混合液出口连接，末端的萃取塔2的萃余液出口连接萃余液储罐12。Among them, the mixed liquid inlet of the extraction column 2 at the head end is connected to the mixed liquid outlet, and the raffinate outlet of the end extraction column 2 is connected to the raffinate storage tank 12.
或者包括多个萃取塔2，每个萃取塔2的混合液入口分别与混合液出口连接，每个萃取塔2的萃余液出口连接萃余液储罐12。Or a plurality of extraction columns 2 are included, the mixed liquid inlets of each of the extraction columns 2 are respectively connected to the mixed liquid outlet, and the raffinate outlet of each of the extraction columns 2 is connected to the raffinate storage tank 12.
上述的两种形式分别是多个萃取塔2串联连接和并联连接的形式，其中，萃取塔2串联连接时，为多级磁分离，可使萃余液中磁颗粒物分离的更充分；而采用并联连接时，可同时使用多个萃取塔2，其磁分离效率更高。The above two forms are respectively a form in which a plurality of extraction towers 2 are connected in series and in parallel, wherein when the extraction towers 2 are connected in series, the multi-stage magnetic separation can make the separation of magnetic particles in the raffinate more fully; When connected in parallel, multiple extraction columns 2 can be used simultaneously, and the magnetic separation efficiency is higher.
同理，解吸塔3也可以为串联连接或并联连接，即包括多个解吸塔3，多个解吸塔3之间通过磁颗粒入口和产品出口串联连接； Similarly, the desorption column 3 can also be connected in series or in parallel, that is, including a plurality of desorption columns 3, and the plurality of desorption columns 3 are connected in series through the magnetic particle inlet and the product outlet;
其中，位于首端的解吸塔3的磁颗粒入口与混合物储罐10连接，末端的解吸塔3的产品出口连接产品储罐13。Among them, the magnetic particle inlet of the desorption column 3 at the head end is connected to the mixture storage tank 10, and the product outlet of the desorbing column 3 at the end is connected to the product storage tank 13.
或者，包括多个解吸塔3，每个解吸塔3的磁颗粒入口分别与混合物储罐10连接，每个解吸塔3的产品出口与产品储罐13连接。Alternatively, a plurality of desorption columns 3 are included, the magnetic particle inlets of each desorption column 3 are respectively connected to the mixture storage tank 10, and the product outlet of each desorption column 3 is connected to the product storage tank 13.
串联连接的解吸塔3，对于磁颗粒回收更加充分，降低磁颗粒的循环损失；而并联连接的解吸塔3可提高磁颗粒的回收效率。The desorption column 3 connected in series is more sufficient for the recovery of the magnetic particles, reducing the circulation loss of the magnetic particles; and the desorption column 3 connected in parallel can improve the recovery efficiency of the magnetic particles.
料液进口4、磁颗粒进口5及搅拌装置6均设于吸附罐1的罐盖上，吸附罐1的罐盖连接有升降组件。The liquid inlet 4, the magnetic particle inlet 5 and the stirring device 6 are all disposed on the can lid of the adsorption tank 1, and the can lid of the adsorption tank 1 is connected with a lifting assembly.
通过设置升降组件可将吸附罐1进行升降操作，便于后期对装置内部进行维护和检修。其中，升降组件为伸缩气缸，液压缸，电葫芦等等均可。The adsorption tank 1 can be lifted and lowered by setting the lifting assembly, which facilitates maintenance and inspection of the interior of the device later. Among them, the lifting assembly is a telescopic cylinder, a hydraulic cylinder, an electric hoist, and the like.
优选的，吸附罐1与萃取塔2之间、萃取塔2与解吸塔3之间以及冲洗装置与刮板9之间均设有蠕动泵14。其中，蠕动泵14的流量的调节范围为3～6800mL/min。Preferably, a peristaltic pump 14 is provided between the adsorption tank 1 and the extraction column 2, between the extraction column 2 and the desorption column 3, and between the rinsing device and the squeegee 9. The flow rate of the peristaltic pump 14 is adjusted from 3 to 6800 mL/min.
本实施例中还包括控制装置，控制装置包括控制器，控制器与搅拌装置6、磁辊8、升降组件和蠕动泵14连接，控制器上设有控制按钮。控制装置设置在该系统的下部，便于操作，控制装置上设有相应的控制按钮，便于操作者的统一操控。The embodiment further includes a control device including a controller connected to the stirring device 6, the magnetic roller 8, the lifting assembly and the peristaltic pump 14, and the controller is provided with a control button. The control device is arranged at the lower part of the system for easy operation, and the control device is provided with corresponding control buttons for convenient operation by the operator.
本实施例中还包括供气管路，供气管路分别与萃取塔2和解吸塔3的气体入口连接，萃取塔2和解吸塔3的气体入口处设有气体流量计15。The present embodiment further includes a gas supply line connected to the gas inlets of the extraction column 2 and the desorption column 3, respectively, and a gas flow meter 15 at the gas inlet of the extraction column 2 and the desorption column 3.
萃取塔2和解吸塔3通过供气管路进行统一的供气操作，其中，在气体入口处设置相应的气体流量计15，气体流量计15的的量程设置为6～60L/h。The extraction column 2 and the desorption column 3 are subjected to a uniform gas supply operation through the gas supply line, wherein a corresponding gas flow meter 15 is provided at the gas inlet, and the range of the gas flow meter 15 is set to 6 to 60 L/h.
磁辊8包括磁弧形区16，磁弧形区16的弧度为240°。使磁辊8的磁弧形区16域表面对磁颗粒有着较均匀的捕集力，在磁路系统设计中，通过一定量小 型的铷铁硼稀土永磁铁沿筒表面以一定间距排列成环形，使其能在套筒表面产生均匀磁场强度。The magnet roller 8 includes a magnetic arcuate region 16 having an arc of 240°. The surface of the magnetic arc-shaped region 16 of the magnetic roller 8 has a relatively uniform trapping force on the magnetic particles, and in the design of the magnetic circuit system, a certain amount is small The type of NdFeB rare earth permanent magnets are arranged in a ring shape at a certain interval along the surface of the cylinder to enable uniform magnetic field strength on the surface of the sleeve.
其中，该全流程连续化气助磁分离系统，所用的混合物储罐10、磁颗粒储罐11、萃余液储罐12、产品储罐13以及冲洗液储罐17均为不锈钢材质，一般情况下将其形状设置为长方体形。同时，可设置多个备用储罐，用于配置和储存洗涤清液和解吸液等。Wherein, the whole process continuous gas assisted magnetic separation system, the mixture storage tank 10, the magnetic particle storage tank 11, the raffinate storage tank 12, the product storage tank 13 and the flushing liquid storage tank 17 are all made of stainless steel, generally Set its shape to a cuboid shape. At the same time, a plurality of spare storage tanks can be provided for arranging and storing the washing supernatant and the desorbent.
具体使用时，将磁性载体(即磁颗粒)与含有目标分离物的溶液在吸附罐1内进行混合，通过搅拌装置6充分搅拌，加速磁颗粒对目标物的萃取过程和促进磁颗粒的充分悬浮，然后泵入萃取塔2(以两个萃取塔2为例，可以只用一个、可以同时用、也可以交替用或串联使用)，磁颗粒在气浮柱7的协助下被磁辊8充分捕获，从冲洗液储罐17中泵出冲洗液将磁辊8上的磁颗粒洗涤下来，并收集进入混合物储罐10，萃余液收集进入萃余液储罐12，混合物储罐10内的悬浮液泵入解吸塔3，解吸塔3内有解吸液，目标物从磁颗粒上解吸下来，进入产品储罐13，解吸后的磁颗粒被磁辊8捕获，通过冲洗液洗涤下来，进入磁颗粒储罐11，磁颗粒可回流到吸附塔内进行循环利用，并形成连续闭路循环。In specific use, the magnetic carrier (ie, magnetic particles) and the solution containing the target separation are mixed in the adsorption tank 1, and fully stirred by the stirring device 6, accelerating the extraction process of the magnetic particles to the target and promoting the sufficient suspension of the magnetic particles. And then pumped into the extraction column 2 (taking two extraction columns 2 as an example, one can be used at the same time, or can be used alternately or in series), and the magnetic particles are fully supported by the magnetic roller 8 with the aid of the air floating column 7. Capture, pumping the rinsing liquid from the rinsing fluid storage tank 17 to wash the magnetic particles on the magnetic roller 8 and collecting them into the mixture storage tank 10, and collecting the raffinate into the raffinate storage tank 12, in the mixture storage tank 10. The suspension is pumped into the desorption column 3, and the desorbing column 3 has a desorbing liquid. The target is desorbed from the magnetic particles and enters the product storage tank 13. The desorbed magnetic particles are captured by the magnetic roller 8 and washed by the washing liquid to enter the magnetic field. In the particle storage tank 11, the magnetic particles can be refluxed into the adsorption tower for recycling, and form a continuous closed circuit cycle.
以上结合具体实施例描述了本发明的技术原理。这些描述只是为了解释本发明的原理，而不能以任何方式解释为对本发明保护范围的限制。基于此处的解释，本领域的技术人员不需要付出创造性的劳动即可联想到本发明的其它具体实施方式，这些方式都将落入本发明的保护范围之内。 The technical principles of the present invention have been described above in connection with specific embodiments. The descriptions are merely illustrative of the principles of the invention and are not to be construed as limiting the scope of the invention. Based on the explanation herein, those skilled in the art can devise various other embodiments of the present invention without departing from the scope of the invention.

Claims (10)

  1. 一种全流程连续化气助磁分离系统，其特征在于，包括吸附罐(1)，所述吸附罐(1)连接有萃取塔(2)，所述萃取塔(2)连接有解吸塔(3)；A full-process continuous gas-assisted magnetic separation system, comprising: an adsorption tank (1) connected to an extraction tower (2), and the extraction tower (2) is connected with a desorption tower ( 3);
    所述吸附罐(1)顶部设有料液进口(4)和磁颗粒进口(5)，底部设有混合液出口，所述吸附罐(1)内设有搅拌装置(6)；The top of the adsorption tank (1) is provided with a liquid inlet (4) and a magnetic particle inlet (5), and a bottom is provided with a mixed liquid outlet, and the adsorption tank (1) is provided with a stirring device (6);
    所述萃取塔(2)包括中空的气浮柱(7)，所述气浮柱(7)上设有混合液入口和萃余液出口，所述混合液入口和所述混合液出口连接，所述气浮柱(7)的顶部设有磁辊(8)，所述磁辊(8)的一侧设有刮板(9)，所述刮板(9)的末端设有混合物储罐(10)，所述气浮柱(7)的底部设有气体入口；The extraction column (2) comprises a hollow air floating column (7), and the air floating column (7) is provided with a mixed liquid inlet and a raffinate outlet, and the mixed liquid inlet and the mixed liquid outlet are connected. The top of the air floating column (7) is provided with a magnetic roller (8), one side of the magnetic roller (8) is provided with a squeegee (9), and the end of the squeegee (9) is provided with a mixture storage tank (10) a gas inlet is provided at a bottom of the air floating column (7);
    所述解吸塔(3)包括中空的气浮柱(7)，所述气浮柱(7)上设有磁颗粒入口和产品出口，所述磁颗粒入口与所述混合物储罐(10)连接，所述气浮柱(7)的顶部设有磁辊(8)，所述磁辊(8)的一侧设有刮板(9)，所述刮板(9)的末端设有磁颗粒储罐(11)，所述磁颗粒储罐(11)与所述吸附塔连接，所述气浮柱(7)的底部设有气体入口；The desorption column (3) comprises a hollow air flotation column (7) having a magnetic particle inlet and a product outlet, the magnetic particle inlet being connected to the mixture storage tank (10) The top of the air floating column (7) is provided with a magnetic roller (8), one side of the magnetic roller (8) is provided with a squeegee (9), and the end of the squeegee (9) is provided with magnetic particles a storage tank (11), the magnetic particle storage tank (11) is connected to the adsorption tower, and a gas inlet is arranged at a bottom of the air floating column (7);
    所述萃取塔(2)和所述解吸塔(3)的所述气浮柱(7)均连接有冲洗装置，所述冲洗装置的冲洗口与所述刮板(9)相对设置。The extraction tower (2) and the air floatation column (7) of the desorption column (3) are each connected with a flushing device, and the flushing port of the flushing device is disposed opposite to the scraper (9).
  2. 根据权利要求1所述的全流程连续化气助磁分离系统，其特征在于，包括多个萃取塔(2)，多个所述萃取塔(2)之间通过所述混合液入口和所述萃余液出口串联连接；A full-flow continuous gas assisted magnetic separation system according to claim 1, comprising a plurality of extraction columns (2) through which said plurality of extraction columns (2) pass and said mixed liquid inlet The raffinate outlets are connected in series;
    其中，位于首端的所述萃取塔(2)的所述混合液入口和所述混合液出口连接，末端的所述萃取塔(2)的萃余液出口连接萃余液储罐(12)。Wherein the mixed liquid inlet of the extraction column (2) at the head end is connected to the mixed liquid outlet, and the raffinate outlet of the extraction column (2) at the end is connected to the raffinate storage tank (12).
  3. 根据权利要求1所述的全流程连续化气助磁分离系统，其特征在于，包括多个萃取塔(2)，每个所述萃取塔(2)的所述混合液入口分别与所述混合液出口连接，每个所述萃取塔(2)的萃余液出口连接萃余液储罐(12)。 A full-flow continuous gas-assisted magnetic separation system according to claim 1, comprising a plurality of extraction columns (2), said mixed liquid inlets of said extraction columns (2) being separately mixed with said The liquid outlet is connected, and the raffinate outlet of each of the extraction columns (2) is connected to a raffinate storage tank (12).
  4. 根据权利要求1所述的全流程连续化气助磁分离系统，其特征在于，包括多个解吸塔(3)，多个所述解吸塔(3)之间通过所述磁颗粒入口和所述产品出口串联连接；A full-flow continuous gas-assisted magnetic separation system according to claim 1, comprising a plurality of desorption columns (3) through which said plurality of desorption columns (3) pass and said magnetic particle inlet Product outlets are connected in series;
    其中，位于首端的所述解吸塔(3)的所述磁颗粒入口与所述混合物储罐(10)连接，末端的所述解吸塔(3)的产品出口连接产品储罐(13)。Wherein the magnetic particle inlet of the desorption column (3) at the head end is connected to the mixture storage tank (10), and the product outlet of the desorbing column (3) at the end is connected to the product storage tank (13).
  5. 根据权利要求1所述的全流程连续化气助磁分离系统，其特征在于，包括多个解吸塔(3)，每个所述解吸塔(3)的所述磁颗粒入口分别与所述混合物储罐(10)连接，每个所述解吸塔(3)的所述产品出口与产品储罐(13)连接。The full-flow continuous gas-assisted magnetic separation system according to claim 1, comprising a plurality of desorption columns (3), said magnetic particle inlets of each of said desorption columns (3) and said mixture The storage tanks (10) are connected, and the product outlet of each of the desorption columns (3) is connected to a product storage tank (13).
  6. 根据权利要求1所述的全流程连续化气助磁分离系统，其特征在于，所述料液进口(4)、所述磁颗粒进口(5)及所述搅拌装置(6)均设于所述吸附罐(1)的罐盖上，所述吸附罐(1)的罐盖连接有升降组件。The full-flow continuous gas-assisted magnetic separation system according to claim 1, wherein said liquid inlet (4), said magnetic particle inlet (5) and said stirring device (6) are disposed at the same On the can lid of the canister (1), the can lid of the canister (1) is connected with a lifting assembly.
  7. 根据权利要求6所述的全流程连续化气助磁分离系统，其特征在于，所述吸附罐(1)与所述萃取塔(2)之间、所述萃取塔(2)与所述解吸塔(3)之间以及所述冲洗装置与所述刮板(4)之间均设有蠕动泵(14)。The full-flow continuous gas-assisted magnetic separation system according to claim 6, wherein said adsorption tank (1) and said extraction column (2), said extraction column (2) and said desorption A peristaltic pump (14) is provided between the towers (3) and between the flushing device and the scraper (4).
  8. 根据权利要求7所述的全流程连续化气助磁分离系统，其特征在于，还包括控制装置，所述控制装置包括控制器，所述控制器与所述搅拌装置(6)、所述磁辊(8)、所述升降组件和所述蠕动泵(14)连接，所述控制器上设有控制按钮。A full-process continuous gas-assisted magnetic separation system according to claim 7, further comprising control means, said control means comprising a controller, said controller and said stirring means (6), said magnetic A roller (8), the lifting assembly and the peristaltic pump (14) are connected, and a control button is arranged on the controller.
  9. 根据权利要求1所述的全流程连续化气助磁分离系统，其特征在于，还包括供气管路，所述供气管路分别与所述萃取塔(2)和所述解吸塔(3)的气体入口连接，所述萃取塔(2)和所述解吸塔(3)的气体入口处设有气体流量计(15)。A full-flow continuous gas-assisted magnetic separation system according to claim 1, further comprising a gas supply line, said gas supply line and said extraction column (2) and said desorption column (3) A gas inlet is connected, and a gas flow meter (15) is provided at the gas inlet of the extraction column (2) and the desorption column (3).
  10. 根据权利要求1所述的全流程连续化气助磁分离系统，其特征在于， 所述磁辊(8)包括磁弧形区(16)，所述磁弧形区(16)的弧度为240°。 The full-flow continuous gas-assisted magnetic separation system according to claim 1, wherein The magnet roller (8) includes a magnetic arcuate region (16) having an arc of 240°.
PCT/CN2017/074332 2017-01-11 2017-02-22 Whole-process continuous gas-assisted magnetic separation system WO2018129789A1 (en)

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