WO2018123596A1 - Agent inhibiteur d'odeur désagréable - Google Patents
Agent inhibiteur d'odeur désagréable Download PDFInfo
- Publication number
- WO2018123596A1 WO2018123596A1 PCT/JP2017/044750 JP2017044750W WO2018123596A1 WO 2018123596 A1 WO2018123596 A1 WO 2018123596A1 JP 2017044750 W JP2017044750 W JP 2017044750W WO 2018123596 A1 WO2018123596 A1 WO 2018123596A1
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- WIPO (PCT)
- Prior art keywords
- mass
- fat
- oil
- oxidized
- odor
- Prior art date
Links
- 239000003638 chemical reducing agent Substances 0.000 title abstract 4
- 239000003921 oil Substances 0.000 claims abstract description 136
- 239000003925 fat Substances 0.000 claims abstract description 115
- 235000021243 milk fat Nutrition 0.000 claims abstract description 60
- 235000013305 food Nutrition 0.000 claims abstract description 48
- 238000000034 method Methods 0.000 claims abstract description 19
- 150000002978 peroxides Chemical class 0.000 claims abstract description 16
- 239000004480 active ingredient Substances 0.000 claims abstract description 6
- 239000000203 mixture Substances 0.000 claims description 49
- 108090000623 proteins and genes Proteins 0.000 claims description 48
- 102000004169 proteins and genes Human genes 0.000 claims description 48
- 244000046052 Phaseolus vulgaris Species 0.000 claims description 34
- 235000010627 Phaseolus vulgaris Nutrition 0.000 claims description 34
- 238000004519 manufacturing process Methods 0.000 claims description 24
- 241000251468 Actinopterygii Species 0.000 claims description 21
- 239000003112 inhibitor Substances 0.000 claims description 19
- 240000004808 Saccharomyces cerevisiae Species 0.000 claims description 18
- 235000014647 Lens culinaris subsp culinaris Nutrition 0.000 claims description 16
- 244000045195 Cicer arietinum Species 0.000 claims description 14
- 235000010523 Cicer arietinum Nutrition 0.000 claims description 14
- 235000010469 Glycine max Nutrition 0.000 claims description 13
- 244000068988 Glycine max Species 0.000 claims description 13
- 240000004713 Pisum sativum Species 0.000 claims description 13
- 235000010582 Pisum sativum Nutrition 0.000 claims description 13
- 239000002994 raw material Substances 0.000 claims description 11
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 9
- 239000001301 oxygen Substances 0.000 claims description 9
- 229910052760 oxygen Inorganic materials 0.000 claims description 9
- 238000010438 heat treatment Methods 0.000 claims description 5
- 230000003647 oxidation Effects 0.000 claims description 4
- 238000007254 oxidation reaction Methods 0.000 claims description 4
- 239000008157 edible vegetable oil Substances 0.000 claims description 2
- 244000043158 Lens esculenta Species 0.000 claims 3
- 235000019198 oils Nutrition 0.000 description 117
- 235000019197 fats Nutrition 0.000 description 94
- 235000019645 odor Nutrition 0.000 description 92
- 108010073771 Soybean Proteins Proteins 0.000 description 39
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- 238000002360 preparation method Methods 0.000 description 36
- 230000000694 effects Effects 0.000 description 31
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- 238000011156 evaluation Methods 0.000 description 16
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- -1 medium-chain fatty acid triglycerides Chemical class 0.000 description 10
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- 235000010724 Wisteria floribunda Nutrition 0.000 description 5
- 239000000654 additive Substances 0.000 description 5
- 235000014121 butter Nutrition 0.000 description 5
- 235000013336 milk Nutrition 0.000 description 5
- 239000008267 milk Substances 0.000 description 5
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- 240000008042 Zea mays Species 0.000 description 4
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- 229910052751 metal Inorganic materials 0.000 description 4
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- 239000012138 yeast extract Substances 0.000 description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- 241000219739 Lens Species 0.000 description 3
- 240000007594 Oryza sativa Species 0.000 description 3
- 235000007164 Oryza sativa Nutrition 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 239000005018 casein Substances 0.000 description 3
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 3
- 235000021240 caseins Nutrition 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 238000007796 conventional method Methods 0.000 description 3
- 235000005687 corn oil Nutrition 0.000 description 3
- 239000002285 corn oil Substances 0.000 description 3
- ZPWVASYFFYYZEW-UHFFFAOYSA-L dipotassium hydrogen phosphate Chemical compound [K+].[K+].OP([O-])([O-])=O ZPWVASYFFYYZEW-UHFFFAOYSA-L 0.000 description 3
- 235000011194 food seasoning agent Nutrition 0.000 description 3
- 235000011187 glycerol Nutrition 0.000 description 3
- 238000000227 grinding Methods 0.000 description 3
- 235000014593 oils and fats Nutrition 0.000 description 3
- 230000001590 oxidative effect Effects 0.000 description 3
- 239000003002 pH adjusting agent Substances 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 235000009566 rice Nutrition 0.000 description 3
- 235000015067 sauces Nutrition 0.000 description 3
- 239000001509 sodium citrate Substances 0.000 description 3
- HRXKRNGNAMMEHJ-UHFFFAOYSA-K trisodium citrate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O HRXKRNGNAMMEHJ-UHFFFAOYSA-K 0.000 description 3
- 229940038773 trisodium citrate Drugs 0.000 description 3
- FYELSNVLZVIGTI-UHFFFAOYSA-N 2-[4-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]-5-ethylpyrazol-1-yl]-1-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethanone Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)C=1C=NN(C=1CC)CC(=O)N1CC2=C(CC1)NN=N2 FYELSNVLZVIGTI-UHFFFAOYSA-N 0.000 description 2
- 108010084695 Pea Proteins Proteins 0.000 description 2
- 241000269851 Sarda sarda Species 0.000 description 2
- 239000002671 adjuvant Substances 0.000 description 2
- JAZBEHYOTPTENJ-JLNKQSITSA-N all-cis-5,8,11,14,17-icosapentaenoic acid Chemical compound CC\C=C/C\C=C/C\C=C/C\C=C/C\C=C/CCCC(O)=O JAZBEHYOTPTENJ-JLNKQSITSA-N 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 235000020673 eicosapentaenoic acid Nutrition 0.000 description 2
- 229960005135 eicosapentaenoic acid Drugs 0.000 description 2
- JAZBEHYOTPTENJ-UHFFFAOYSA-N eicosapentaenoic acid Natural products CCC=CCC=CCC=CCC=CCC=CCCCC(O)=O JAZBEHYOTPTENJ-UHFFFAOYSA-N 0.000 description 2
- 239000010520 ghee Substances 0.000 description 2
- 235000021374 legumes Nutrition 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 235000019702 pea protein Nutrition 0.000 description 2
- 230000001953 sensory effect Effects 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 2
- 150000004670 unsaturated fatty acids Chemical class 0.000 description 2
- DVSZKTAMJJTWFG-SKCDLICFSA-N (2e,4e,6e,8e,10e,12e)-docosa-2,4,6,8,10,12-hexaenoic acid Chemical compound CCCCCCCCC\C=C\C=C\C=C\C=C\C=C\C=C\C(O)=O DVSZKTAMJJTWFG-SKCDLICFSA-N 0.000 description 1
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- IIZPXYDJLKNOIY-JXPKJXOSSA-N 1-palmitoyl-2-arachidonoyl-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCC\C=C/C\C=C/C\C=C/C\C=C/CCCCC IIZPXYDJLKNOIY-JXPKJXOSSA-N 0.000 description 1
- LPZOCVVDSHQFST-UHFFFAOYSA-N 2-[4-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]-3-ethylpyrazol-1-yl]-1-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethanone Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)C=1C(=NN(C=1)CC(=O)N1CC2=C(CC1)NN=N2)CC LPZOCVVDSHQFST-UHFFFAOYSA-N 0.000 description 1
- YJLUBHOZZTYQIP-UHFFFAOYSA-N 2-[5-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]-1,3,4-oxadiazol-2-yl]-1-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethanone Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)C1=NN=C(O1)CC(=O)N1CC2=C(CC1)NN=N2 YJLUBHOZZTYQIP-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- GZJLLYHBALOKEX-UHFFFAOYSA-N 6-Ketone, O18-Me-Ussuriedine Natural products CC=CCC=CCC=CCC=CCC=CCC=CCCCC(O)=O GZJLLYHBALOKEX-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- 235000017166 Bambusa arundinacea Nutrition 0.000 description 1
- 235000017491 Bambusa tulda Nutrition 0.000 description 1
- 241000238366 Cephalopoda Species 0.000 description 1
- 239000004278 EU approved seasoning Substances 0.000 description 1
- 235000007688 Lycopersicon esculentum Nutrition 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 244000082204 Phyllostachys viridis Species 0.000 description 1
- 235000015334 Phyllostachys viridis Nutrition 0.000 description 1
- 235000019485 Safflower oil Nutrition 0.000 description 1
- 240000003768 Solanum lycopersicum Species 0.000 description 1
- 235000019486 Sunflower oil Nutrition 0.000 description 1
- 244000299461 Theobroma cacao Species 0.000 description 1
- 235000005764 Theobroma cacao ssp. cacao Nutrition 0.000 description 1
- 235000005767 Theobroma cacao ssp. sphaerocarpum Nutrition 0.000 description 1
- DTOSIQBPPRVQHS-PDBXOOCHSA-N alpha-linolenic acid Chemical compound CC\C=C/C\C=C/C\C=C/CCCCCCCC(O)=O DTOSIQBPPRVQHS-PDBXOOCHSA-N 0.000 description 1
- 235000020661 alpha-linolenic acid Nutrition 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 239000011425 bamboo Substances 0.000 description 1
- 235000008429 bread Nutrition 0.000 description 1
- 235000001046 cacaotero Nutrition 0.000 description 1
- 239000003240 coconut oil Substances 0.000 description 1
- 235000019864 coconut oil Nutrition 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 235000009508 confectionery Nutrition 0.000 description 1
- 235000012343 cottonseed oil Nutrition 0.000 description 1
- 239000002385 cottonseed oil Substances 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 235000020669 docosahexaenoic acid Nutrition 0.000 description 1
- KAUVQQXNCKESLC-UHFFFAOYSA-N docosahexaenoic acid (DHA) Natural products COC(=O)C(C)NOCC1=CC=CC=C1 KAUVQQXNCKESLC-UHFFFAOYSA-N 0.000 description 1
- 239000000284 extract Substances 0.000 description 1
- 238000004108 freeze drying Methods 0.000 description 1
- 239000010649 ginger oil Substances 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 239000000543 intermediate Substances 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 239000000787 lecithin Substances 0.000 description 1
- 235000010445 lecithin Nutrition 0.000 description 1
- 229940067606 lecithin Drugs 0.000 description 1
- 229960004488 linolenic acid Drugs 0.000 description 1
- KQQKGWQCNNTQJW-UHFFFAOYSA-N linolenic acid Natural products CC=CCCC=CCC=CCCCCCCCC(O)=O KQQKGWQCNNTQJW-UHFFFAOYSA-N 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000000873 masking effect Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 235000021096 natural sweeteners Nutrition 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 239000003346 palm kernel oil Substances 0.000 description 1
- 235000019865 palm kernel oil Nutrition 0.000 description 1
- 239000006072 paste Substances 0.000 description 1
- 239000000546 pharmaceutical excipient Substances 0.000 description 1
- 230000001766 physiological effect Effects 0.000 description 1
- 235000020777 polyunsaturated fatty acids Nutrition 0.000 description 1
- 235000015277 pork Nutrition 0.000 description 1
- 235000012029 potato salad Nutrition 0.000 description 1
- 235000004252 protein component Nutrition 0.000 description 1
- 235000021251 pulses Nutrition 0.000 description 1
- 235000020185 raw untreated milk Nutrition 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 235000005713 safflower oil Nutrition 0.000 description 1
- 239000003813 safflower oil Substances 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 235000013580 sausages Nutrition 0.000 description 1
- 235000014102 seafood Nutrition 0.000 description 1
- 238000001694 spray drying Methods 0.000 description 1
- 239000002600 sunflower oil Substances 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 235000010436 thaumatin Nutrition 0.000 description 1
- 239000000892 thaumatin Substances 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23D—EDIBLE OILS OR FATS, e.g. MARGARINES, SHORTENINGS OR COOKING OILS
- A23D9/00—Other edible oils or fats, e.g. shortenings or cooking oils
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23J—PROTEIN COMPOSITIONS FOR FOODSTUFFS; WORKING-UP PROTEINS FOR FOODSTUFFS; PHOSPHATIDE COMPOSITIONS FOR FOODSTUFFS
- A23J3/00—Working-up of proteins for foodstuffs
- A23J3/14—Vegetable proteins
- A23J3/16—Vegetable proteins from soybean
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES, NOT OTHERWISE PROVIDED FOR; PREPARATION OR TREATMENT THEREOF
- A23L35/00—Foods or foodstuffs not provided for in groups A23L5/00 - A23L33/00; Preparation or treatment thereof
Definitions
- the present invention relates to an unpleasant odor inhibitor applied to foods having an unpleasant odor.
- Fisheries such as fish contain highly unsaturated fatty acids such as docosahexaenoic acid (DHA) and eicosapentaenoic acid (EPA). These polyunsaturated fatty acids are attracting attention because of their various physiological activities.
- marine products such as fish have a peculiar unpleasant odor (fish odor) that is considered to be derived from these highly unsaturated fatty acids and lower amines. For this reason, fish odor is a problem in foods containing fishery products such as fish.
- meat containing soy protein hamburger, meatballs, etc.
- unpleasant odors and flavors derived from soy protein are problematic.
- Patent Document 1 Japanese Patent Application Laid-Open No. 2001-131575 proposes masking of odor by adding ginger oil or ginger-flavoring to marine animal fats.
- Patent Document 2 Japanese Patent Application Laid-Open No. 2011-4699 discloses that the unpleasant taste of soy protein can be masked by adding thaumatin, which is a natural sweetener, to meat-containing foods containing soy protein.
- Patent Document 3 Japanese Patent Laid-Open No. 2016-67354. discloses that processed lecithin suppresses an unusual flavor such as soybean protein odor.
- Patent Document 4 Japanese Patent Application Laid-Open No. 2007-75070 describes that yeast extract has a kind of unpleasant odor called a so-called yeast odor, which is a cause of limited use. Has been. And in order to solve the subject, the manufacturing method which adds a seafood extract in a manufacturing process is disclosed.
- Patent Document 5 Patent No. 5976968 discloses that fats and oils including specific oxidized milk fat enhance the milk flavor. However, the effect of suppressing unpleasant odors such as soybean protein odor is not disclosed.
- an object of the present invention is to provide an unpleasant odor inhibitor and a method for suppressing unpleasant odors of foods, which can be added to foods with unpleasant odors to suppress the unpleasant odors. .
- oxidized fat containing a predetermined amount of milk fat has an effect of suppressing unpleasant odor of food, and completed the present invention.
- the present invention is an unpleasant odor suppressor having an active ingredient of oxidized fats and oils having a peroxide value of 15 to 180 and containing 10 to 100% by weight of milk fat.
- the inhibitor contains 0.001% by mass or more and 100% by mass or less of the oxidized oil or fat.
- the unpleasant odor is preferably one or more of fish odor, beans-derived protein odor and yeast odor.
- the beans are one kind or two or more kinds of soybeans, lentils, chickpeas and peas.
- the present invention is a method for producing an unpleasant odor inhibitor
- This production method comprises a step of heating a raw fat / oil containing 10% by mass or more and 100% by mass or less of milk fat while supplying oxygen to obtain an oxidized fat / oil having a peroxide value of 15 to 180.
- the raw oil / fat preferably contains 50% by mass to 100% by mass of milk fat.
- the heating is preferably performed at 65 ° C. or higher and 150 ° C. or lower for 1 hour or longer and 72 hours or shorter.
- the supply of oxygen is 0.001 to 2 L / min per 1 kg of the raw material fat.
- the milk fat is preferably anhydrous milk fat.
- the fat content of the raw material fat is preferably 90% by mass or more and 100% by mass or less.
- the said manufacturing method it is preferable to further include the process of adding the said oxidized fats and oils to edible fats and oils.
- the said oxidation fats and oils 0.001 to 50 mass% with respect to the said edible fats and oils.
- the present invention also relates to a food containing an unpleasant odor suppressant having a peroxide value of 15 to 180 and comprising an oxidized fat containing 10% by mass or more and 100% by mass or less of milk fat, the inhibitor This food has an unpleasant odor suppressed by the addition of.
- the inhibitor is contained so that milk fat contained in the oxidized fat / oil is 0.005 to 50,000 ppm.
- the present invention also relates to a method for suppressing an unpleasant odor of food, characterized by adding an oxidized fat containing 15 to 180% of a peroxide value and containing 10% to 100% by weight of milk fat to the food. is there.
- the unpleasant odor is preferably one or more of a fish odor, a bean-derived protein odor and a yeast odor.
- the said beans are any 1 type, or 2 or more types of a soybean, a lentil, a chickpea, and a pea.
- the present invention is a protein-containing composition
- a protein-containing composition comprising powdered fats and oils containing oxidized fats and oils and beans-derived protein
- the oxidized oil / fat is a protein-containing composition having a peroxide value of 15 to 180 and containing 10% by mass to 100% by mass of milk fat.
- the oxidized oil / fat is preferably 0.0005 parts by mass or more and 5 parts by mass or less with respect to 100 parts by mass of the beans-derived protein.
- the beans are one kind or two or more kinds of soybeans, lentils, chickpeas and peas.
- the content of the oxidized fat / oil in the powdered fat / oil is preferably 0.01% by mass or more and 30% by mass or less.
- a food or the like in which an unpleasant odor is suppressed can be obtained by adding an oxidized fat containing a predetermined amount of milk fat to a food or the like having an unpleasant odor.
- oxidized fats and oils having a peroxide value of 15 to 180 and containing 10% by mass or more and 100% by mass or less of milk fat are used as active ingredients for suppressing unpleasant odor.
- Milk fat means a fat or oil content obtained from raw milk, milk or special milk that is 95% by mass or more and 100% by mass or less.
- Examples include anhydrous milk fat and clarified butter.
- Anhydrous milk fat is obtained by removing almost all components other than milk fat from milk and the like, and is sometimes described as AMF (Anhydrous Milk Fat, butter oil).
- Clear butter is a fraction of butter fat.
- the milk fat used in the present invention is preferably anhydrous milk fat or clarified butter, more preferably anhydrous milk fat.
- the fat content of milk fat is preferably 98% by mass or more and 100% by mass or less, and more preferably 99% by mass or more and 100% by mass or less.
- the milk fat content of the oxidized fat used in the present invention is 10% by mass to 100% by mass, preferably 20% by mass to 100% by mass, and more preferably 50% by mass to 100% by mass. It is preferably 60% by mass or more and 100% by mass or less, more preferably 65% by mass or more and 100% by mass or less, particularly preferably 95% by mass or more and 100% by mass or less, and 100% by mass. % (Ie milk fat alone) is most preferred.
- the fat content of the oxidized fat is preferably 90% by mass or more and 100% by mass or less, more preferably 95% by mass or more and 100% by mass or less, and more preferably 98% by mass or more and 100% by mass or less. More preferably, it is 99 mass% or more and 100 mass% or less.
- the oxidized fats and oils may contain edible fats and oils other than milk fats.
- Edible fats and oils other than milk fat are not particularly limited, but any one or more of medium chain fatty acid triglyceride, soybean oil, rapeseed oil, corn oil, palm oil and palm fractionated oil are preferable, medium chain fatty acid triglyceride, soybean oil And one or more of rapeseed oil are more preferred, and any one or two of medium-chain fatty acid triglycerides and soybean oil are more preferred.
- the oxidized fats and oils may contain auxiliary agents that can be added to the fats and oils as long as the effects of the present invention are not impaired.
- the oxidized oil and fat has a peroxide value (hereinafter also referred to as “POV”) of 15 to 180, preferably 30 to 150, more preferably 35 to 140, and 40 to 40. 140 is more preferable, and 40 to 120 is particularly preferable.
- POV peroxide value
- the oxidized oil / fat can be oxidized to a predetermined range of POV, but the oxidation method is not particularly limited.
- the heating temperature is preferably 65 ° C or higher and 150 ° C or lower, more preferably 70 ° C or higher and 140 ° C or lower, and further preferably 75 ° C or higher and 140 ° C or lower.
- the oxidation time is not particularly limited, but is preferably 1 hour or more and 72 hours or less, more preferably 3 hours or more and 72 hours or less, and further preferably 5 hours or more and 72 hours or less.
- the oxygen supply source may be oxygen alone or may contain oxygen such as air, preferably air.
- the amount of oxygen supplied is preferably 0.001 to 2 L / min per kg of raw oil and fat, more preferably 0.005 to 2 L / min, and 0.02 to 2 L / min. It is further preferable that For example, in the case of air, the amount is preferably 0.005 to 10 L / min per 1 kg of the raw oil and fat, more preferably 0.025 to 10 L / min, and further preferably 0.1 to 10 L / min. Preferably, it is still more preferably 0.3 to 5 L / min.
- the milk fat content of the raw oil and fat is 10% by mass or more and 100% by mass or less, preferably 20% by mass or more and 100% by mass or less, more preferably 50% by mass or more and 100% by mass or less, and 60% by mass. % To 100% by mass, still more preferably 65% to 100% by mass, particularly preferably 95% to 100% by mass, and 100% by mass (ie, Most preferred is milk fat alone. Further, the fat content of the raw material fat is preferably 90% by mass or more and 100% by mass or less, more preferably 95% by mass or more and 100% by mass or less, and more preferably 98% by mass or more and 100% by mass or less. More preferably, it is 99 mass% or more and 100 mass% or less.
- the said raw material fats and oils may contain edible fats and oils other than milk fat.
- Edible fats and oils other than milk fat are not particularly limited, but any one or more of medium chain fatty acid triglyceride, soybean oil, rapeseed oil, corn oil, palm oil and palm fractionated oil are preferable, medium chain fatty acid triglyceride, soybean oil And one or more of rapeseed oil are more preferred, and any one or two of medium-chain fatty acid triglycerides and soybean oil are more preferred.
- content of the water of the said raw material fats and oils is less than 1 mass%, for example.
- the application method of the present invention is not particularly limited as long as it is a method of adding the oxidized fat to foods and the like.
- the oxidized fats and oils may be added to raw materials such as foods and intermediates in manufacturing processes.
- the timing to add is not specifically limited, either process of manufacture of a foodstuff etc. may be sufficient. Alternatively, it may be added after production and before eating.
- Whether unpleasant odors are suppressed in foods to which the present invention is applied is determined by sensory evaluation tests, preferably those prepared by adding the oxidized oil and fat, and those prepared in the same manner without addition.
- An objective evaluation is possible by using a sensory evaluation test or the like by a plurality of panelists selected so that there is no preference bias.
- the food to which the present invention is applied is not particularly limited, and includes not only human food and drink but also animal food and feed.
- it is a food including fish, etc., marine animals, beans-derived protein, yeast and other foods that are likely to cause unpleasant odors.
- the beans include soybeans, lentils, chickpeas, and peas.
- foods containing marine animals such as fish include canned fish and squid; seasonings such as bonito soup, grilled fish, boiled fish, steamed fish, fried fish, and foods containing them.
- Foods containing legume-derived proteins include hamburger, pork cutlet, grilled rice, dumplings, ham, sausage, rice cakes, bamboo rings, nuggets, meat dumplings, tsumire, soboro, Chinese buns, spring rolls, sprinkles, fillings, confectionery, bread, meat sauce, Demigrass sauce, tomato sauce, potato salad, tuna salad, soy milk.
- Examples of the food containing yeast include foods containing yeast extract, yeast fermented seasoning, yeast extract and the like.
- it is a food containing any one or more of marine animals, beans-derived protein and yeast, more preferably a food containing any one or more of fish, beans-derived protein and yeast, Preferably, it is a food containing any one or two of beans-derived protein and yeast, and even more preferably a food containing beans-derived protein, and the beans are any one of soybean, lentil, chickpea and pea Or 2 or more types are preferable and soybean is more preferable.
- the target unpleasant odor is not particularly limited, but is preferably one or more of fish odor, beans-derived protein odor and yeast odor, more preferably any one of beans-derived protein odor and yeast odor or Two, more preferably a bean-derived protein odor, wherein the beans are preferably one or more of soybeans, lentils, chickpeas and peas, and any one or two of soybeans and lentils Is more preferable, and soybean is more preferable.
- the content of the oxidized fats and oils in the foods may be adjusted according to the effect.
- the fats and oils contained in the oxidized fats and oils are, for example, 0. 005 to 50000 ppm, preferably 0.005 to 20000 ppm, more preferably 0.01 to 10000 ppm, still more preferably 0.05 to 5000 ppm, still more preferably 0.08 to 3000 ppm, and particularly preferably 0.08 to 2000 ppm.
- 0. 005 to 50000 ppm preferably 0.005 to 20000 ppm, more preferably 0.01 to 10000 ppm, still more preferably 0.05 to 5000 ppm, still more preferably 0.08 to 3000 ppm, and particularly preferably 0.08 to 2000 ppm.
- the application method of the present invention may be a method of adding the oxidized oil to food or the like.
- you may make it add to a foodstuff or its raw material in the form of an edible composition, ie, the form of an additive, for example.
- the content of the oxidized oil or fat in the edible composition is not particularly limited as long as it exhibits the effect of suppressing unpleasant odors.
- the oxidized fat is preferably 0.001% by mass to 100% by mass, more preferably 0.01% by mass to 100% by mass, and still more preferably 0.01% by mass to 50% by mass. Even more preferably, it is 0.01 mass% or more and 10 mass% or less.
- the edible composition may use an edible oil or fat for diluting the oxidized fat or oil.
- the oxidized fat or oil is used for the edible fat or oil.
- the mass should be not more than%.
- Edible fats and oils are not particularly limited, for example, palm kernel oil, palm oil, coconut oil, corn oil, cottonseed oil, soybean oil, rapeseed oil, rice oil, sunflower oil, safflower oil, cacao butter and other vegetable oils, lard, etc.
- Animal fats and oils, medium chain fatty acid triglycerides and the like can be mentioned.
- processed oils and fats such as these fractionated oils (mid melting point of palm oil, fractionated soft oil of palm oil, fractionated hard oil of palm oil, etc.), transesterified oil, hydrogenated oil and the like can be used.
- these edible fats and oils can use 1 type (s) or 2 or more types.
- the adjuvant etc. which can be normally added to edible fats and oils may be used, and corn syrup etc. for making it into a powder form etc. may be used.
- the form may be any form suitable for use as, for example, an additive.
- powder, paste, liquid, etc. It may be in the form of a shape. In this case, it can also be prepared by powdering the oxidized oil and fat and mixing raw materials such as various additives.
- various known adjuvants such as excipients can be added.
- an emulsifier may be added to emulsify.
- the powdering method can be performed by any method known to those skilled in the art, such as spray drying and freeze drying.
- a protein-containing composition comprising powdered fats and oils containing the oxidized fats and oils and the beans-derived protein. Since this protein-containing composition contains powdered fats and oils, it is easy to mix with other materials, and since the oxidized fats and oils are contained, the protein-derived protein odor is suppressed. Therefore, it is suitably used as a food material for imparting a protein component to food or the like.
- the oxidized oil / fat is preferably 0.0005 parts by mass or more and 5 parts by mass or less, more preferably 0.001 parts by mass or more and 5 parts by mass or less, with respect to 100 parts by mass of the beans-derived protein.
- the amount is more preferably no less than 5 parts by mass and no greater than 5 parts by mass, and still more preferably no less than 0.01 parts by mass and no greater than 3 parts by mass.
- the bean-derived protein contained in the protein-containing composition is preferably 70% by mass or more, preferably 80% by mass or more, and more preferably 90% by mass or more. Although an upper limit is not specifically limited, The sum total of the said beans origin protein and the said powder fats and oils is 100 mass% or less.
- the content of the oxidized oil / fat in the powdered oil / fat is preferably 0.01% by mass to 30% by mass, more preferably 0.01% by mass to 20% by mass, and still more preferably 0.05% by mass to 20% by mass. % Or less, and more preferably 0.1% by mass or more and 20% by mass or less.
- Anhydrous milk fat (Product name: Butter Oil CML, manufactured by Maruwa Oil & Fat Co., Ltd., Oil content: 99.8% by mass) Soybean oil (manufactured by J-Oil Mills) Rapeseed oil (manufactured by J-Oil Mills Co., Ltd.) Medium-chain fatty acid triglyceride (MCT) (Product name: MCT Actor M-107FR, manufactured by Riken Vitamin Co., Ltd.) High oleic acid low linolenic acid rapeseed oil (HOLL rapeseed oil) (manufactured by J-Oil Mills Co., Ltd.)
- Oxidized fats and oils were prepared as follows.
- the peroxide value (POV) of the obtained oxidized oil / fat was measured according to “Standard oil analysis test method 2.5.2 Peroxide value”. The results are shown in Table 1.
- Preparation Examples 5 to 8 were prepared by adding Preparation Example 2 to rapeseed oil at 0.01% by mass, 0.1% by mass, 1% by mass, and 10% by mass.
- Examples 4-1 to 4 it was found that by adding the unpleasant odor suppressing agent according to the present invention, the soybean protein odor can be suppressed, and the effect is particularly obtained when the content of oxidized oils and fats during eating is 10 ppm or more. Was remarkable. Further, in the hamburgers of Examples 4-1 to 4, the rich feeling was improved. In addition, with respect to 100 parts by mass of soybean protein, oxidized oils and fats are 0.0016 parts by mass or more and 1.6 parts by mass or less, and the soybean protein odor suppressing effect can be confirmed, and 0.016 parts by mass or more and 1.6 parts by mass or less. The effect was remarkable.
- Preparation Examples 9 to 13 Anhydrous milk fat (not oxidized) or any one of Preparation Examples 1 to 4 was added to rapeseed oil so as to be 1% by mass to prepare Preparation Examples 9 to 13.
- oxidized fats and oils which are active ingredients of the unpleasant odor suppressing agent according to the present invention, have an effect of suppressing unpleasant odor when POV is 34 or more. In particular, the effect was remarkable at POV 51 or higher. On the other hand, the effect of suppressing unpleasant odors could not be confirmed with non-oxidized milk fat (POV 0).
- oxidized fats and oils including edible fats and oils other than milk fat and milk fat 80 parts by mass of HOLL rapeseed oil was mixed with 20 parts by mass of anhydrous milk fat to prepare an oil containing 20% by mass of milk fat. 200 g of the prepared oil and fat was put into a stainless beaker, stirred while keeping the temperature at 100 ° C., and air (200 ml / min) was supplied. Reaction was performed for 30 hours to obtain an oxidized oil of POV 105.
- Preparation Examples 18 to 21 Any of Preparation Examples 14 to 17 was added to rapeseed oil so as to be 1% by mass to prepare Preparation Examples 18 to 21.
- a hamburger was prepared by the same operation as the evaluation 2 in hamburger except that the additive components listed in Table 7 were used, and the inhibitory effect on soybean protein odor was evaluated.
- milk fat contained in oxidized fats and oils, which are active ingredients of the unpleasant odor suppressing agent according to the present invention has an effect of suppressing unpleasant odor at 20% by mass or more.
- the effect was particularly high at 50% by mass or more.
- Palm kernel polar hard oil 35 parts by weight, corn syrup (water content 25% by weight) 63.36 parts by weight, pH adjuster mix (dipotassium hydrogen phosphate, trisodium citrate) 2.10 parts by weight and emulsifier mix (acid casein) , Sodium hydroxide, sorbitan fatty acid ester, and glycerin fatty acid ester mixture) 5.38 parts by mass, Preparation Example 22 10 parts by mass were mixed and mixed. Furthermore, 84.16 parts by mass of water was added and emulsified and sprayed according to a conventional method to obtain an unpleasant odor suppressant in the form of powdered oil.
- Preparation 1-1 Preparation of Bean-derived Protein Composition Three kinds of pulse-derived protein compositions were prepared as follows. 1-1-1. Lentil-derived protein composition Lentil (lentil (no skin), Tomizawa Shoten) was pulverized with a mixer. 150 parts by mass of water was mixed with 50 parts by mass of the pulverized lentils. 1-1-2. Chickpea-derived protein composition Chickpeas (Garvanso, Tomizawa Shoten) were pulverized with a mixer. 150 parts by mass of water was mixed with 50 parts by mass of crushed chickpeas. 1-1-3.
- Pea-derived protein composition 150 parts by mass of water was mixed with 50 parts by mass of powdered pea protein (Organic Pea Protein pure isolate, Sun Bright Co., Ltd.). 1-2. Sautéed onion, chopped onion, sprinkled rapeseed oil in a frying pan, stir-fried until onion became soft and chilled. 2. Mixing and molding 2-1. The ingredients listed in Table 8 were added to the balls and mixed well so that the ingredients were uniformly mixed to prepare a hamburger mix. 2-2. 99 g of hamburger mix, and 1 g of either rapeseed oil (control) or Preparation Example 7 was added as an additive, and kneaded well so that the oil was evenly mixed.
- Molded fabric was produced by molding to a thickness of about 2-3.50 g and 1.5 cm. 3. Firing 3-1. The hot plate was heated to 230 ° C. and an appropriate amount of salad oil was added. The salad oil was lightly wiped off with kitchen paper, and the above-mentioned dough was put on a hot plate and baked. 3-2. I turned it over when it was baked. 3-3. Further, when the baked color was obtained, the temperature was lowered to 140 ° C., the lid was covered and steamed for 5 minutes. It was transferred to a metal vat, cooled, and a hamburger was prepared. 4). Evaluation The obtained hamburger was used to evaluate the effect of suppressing the bean-derived protein odor based on the following criteria (determined by the consensus of three evaluators). The results are shown in Table 9.
- Palm kernel polar hard oil 45 parts by weight, corn syrup (water content 25% by weight) 63.36 parts by weight, pH adjuster mix (dipotassium hydrogen phosphate, trisodium citrate) 2.10 parts by weight and emulsifier mix (acid casein) , Sodium hydroxide, sorbitan fatty acid ester, and glycerin fatty acid ester mixture) 5.38 parts by mass were mixed and mixed. Furthermore, 84.16 parts by mass of water was added and emulsified and sprayed according to a conventional method to obtain a powdered oil.
- Granular soy protein composition 5 247.5 parts by mass of water was added to and mixed with 82.5 parts by mass of granular soybean protein (product name: New Fujinic 52, manufactured by Fuji Oil Co., Ltd.). 1-4. Sautéed onion, chopped onion, sprinkled rapeseed oil in a frying pan, stir-fried until onion became soft and chilled. 2. Mixing and molding 2-1. The ingredients listed in Table 10 were added to the balls and mixed well so that the ingredients were uniformly mixed to prepare a hamburger mix. 2-2. As described in Table 11, hamburg mix and the like were mixed and kneaded well. Molded fabric was produced by molding to a thickness of about 2-3.50 g and 1.5 cm. 3. Firing 3-1. The hot plate was heated to 230 ° C.
- Example 11-1 and Example 11-2 the effect of the unpleasant odor suppressant according to the present invention was confirmed even in the form of powdered fats and oils.
- the unpleasant odor suppressant according to the present invention was prepared in the form of powdered oil and fat, mixed with soy protein, and further mixed with water to prepare soy protein.
- the effect of suppressing unpleasant odor was more remarkable.
- Unpleasant Odor Suppressor 200 g of anhydrous milk fat was placed in a stainless beaker, stirred while being kept at 100 ° C., and air (5 mL / min) was supplied. When the peroxide value reached 47, the supply of air was stopped and the mixture was cooled to obtain oxidized fats and oils. The obtained oxidized fat was used as an unpleasant odor inhibitor.
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- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
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- Oil, Petroleum & Natural Gas (AREA)
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Abstract
L'invention fournit un agent inhibiteur d'odeur désagréable additionné à un aliment, ou similaire, à l'odeur désagréable, et permettant ainsi d'inhiber l'odeur désagréable de celui-ci, et un procédé destiné à inhiber une odeur désagréable d'un aliment. Plus précisément, l'invention concerne un agent inhibiteur d'odeur désagréable dont l'indice de peroxyde est compris entre 15 et 180, et qui présente en tant que principe actif une matière grasse oxydée contenant 10% en masse ou plus à 100% en masse ou moins d'une matière grasse de lait. En outre, l'invention concerne un aliment dont l'odeur désagréable est inhibée par addition de cet inhibiteur d'odeur désagréable. Enfin, l'invention concerne un procédé destiné à inhiber une odeur désagréable d'un aliment par addition d'une matière grasse oxydée d'indice de peroxyde compris entre 15 et 180, et contenant 10% en masse ou plus à 100% en masse ou moins d'une matière grasse de lait.
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CN201780077303.5A CN110072400A (zh) | 2016-12-27 | 2017-12-13 | 难闻气味抑制剂 |
JP2018559020A JP7051713B2 (ja) | 2016-12-27 | 2017-12-13 | 不快臭抑制剤 |
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PCT/JP2017/044750 WO2018123596A1 (fr) | 2016-12-27 | 2017-12-13 | Agent inhibiteur d'odeur désagréable |
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JP (1) | JP7051713B2 (fr) |
CN (1) | CN110072400A (fr) |
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Cited By (4)
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WO2019073811A1 (fr) * | 2017-10-13 | 2019-04-18 | 株式会社J-オイルミルズ | Activateur de sensation de matière grasse destiné à des aliments, et aliment contenant ledit activateur |
WO2023053972A1 (fr) * | 2021-09-29 | 2023-04-06 | 株式会社J-オイルミルズ | Exhausteur de goût, composition d'huile ou de matière grasse améliorant le goût, procédé d'amélioration du goût, procédé de production d'exhausteur de goût et aliment améliorant le goût |
WO2023176454A1 (fr) * | 2022-03-15 | 2023-09-21 | 株式会社J-オイルミルズ | Agent de suppression d'odeur de protéine végétale, composition d'huile et de matière grasse pour suppression d'odeur de protéine végétale, et utilisation associée |
WO2023176455A1 (fr) * | 2022-03-15 | 2023-09-21 | 株式会社J-オイルミルズ | Agent de suppression d'odeur de protéine végétale, composition d'huile/matière grasse pour supprimer une odeur de protéine végétale, et utilisation associée |
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CN111109549A (zh) * | 2020-02-11 | 2020-05-08 | 荣成泰祥食品股份有限公司 | 一种油炸鱼肉馅料即食食品的制作方法 |
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KR102098155B1 (ko) * | 2012-11-14 | 2020-04-07 | 제이-오일 밀스, 인코포레이티드 | 감미 및/또는 우유 풍미 증강제 |
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2017
- 2017-12-13 WO PCT/JP2017/044750 patent/WO2018123596A1/fr active Application Filing
- 2017-12-13 JP JP2018559020A patent/JP7051713B2/ja active Active
- 2017-12-13 CN CN201780077303.5A patent/CN110072400A/zh active Pending
- 2017-12-14 TW TW106143983A patent/TWI746733B/zh not_active IP Right Cessation
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JP2005328754A (ja) * | 2004-05-20 | 2005-12-02 | Minoru Hishinuma | インスタント加工米食品及びその製造法 |
JP2008182934A (ja) * | 2007-01-29 | 2008-08-14 | Mitsui Norin Co Ltd | 飲食品組成物 |
WO2012160851A1 (fr) * | 2011-05-23 | 2012-11-29 | 株式会社J-オイルミルズ | Composition d'huile ou graisse |
JP2015053880A (ja) * | 2013-09-11 | 2015-03-23 | 株式会社カネカ | 乳風味呈味材 |
WO2016084788A1 (fr) * | 2014-11-26 | 2016-06-02 | 不二製油グループ本社株式会社 | Procédé de production d'huile permettant de rehausser un goût salé |
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2019073811A1 (fr) * | 2017-10-13 | 2019-04-18 | 株式会社J-オイルミルズ | Activateur de sensation de matière grasse destiné à des aliments, et aliment contenant ledit activateur |
WO2023053972A1 (fr) * | 2021-09-29 | 2023-04-06 | 株式会社J-オイルミルズ | Exhausteur de goût, composition d'huile ou de matière grasse améliorant le goût, procédé d'amélioration du goût, procédé de production d'exhausteur de goût et aliment améliorant le goût |
WO2023176454A1 (fr) * | 2022-03-15 | 2023-09-21 | 株式会社J-オイルミルズ | Agent de suppression d'odeur de protéine végétale, composition d'huile et de matière grasse pour suppression d'odeur de protéine végétale, et utilisation associée |
WO2023176455A1 (fr) * | 2022-03-15 | 2023-09-21 | 株式会社J-オイルミルズ | Agent de suppression d'odeur de protéine végétale, composition d'huile/matière grasse pour supprimer une odeur de protéine végétale, et utilisation associée |
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JP7051713B2 (ja) | 2022-04-11 |
TWI746733B (zh) | 2021-11-21 |
CN110072400A (zh) | 2019-07-30 |
JPWO2018123596A1 (ja) | 2019-10-31 |
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