WO2018108612A1 - Compositions herbicides contenant des isoxazolo[5,4-b]pyridines - Google Patents
Compositions herbicides contenant des isoxazolo[5,4-b]pyridines Download PDFInfo
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- WO2018108612A1 WO2018108612A1 PCT/EP2017/081426 EP2017081426W WO2018108612A1 WO 2018108612 A1 WO2018108612 A1 WO 2018108612A1 EP 2017081426 W EP2017081426 W EP 2017081426W WO 2018108612 A1 WO2018108612 A1 WO 2018108612A1
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- 239000000203 mixture Substances 0.000 title claims abstract description 238
- 230000002363 herbicidal effect Effects 0.000 title claims abstract description 100
- DITTYRBIXKVOTK-UHFFFAOYSA-N [1,2]oxazolo[5,4-b]pyridine Chemical class C1=CC=C2C=NOC2=N1 DITTYRBIXKVOTK-UHFFFAOYSA-N 0.000 title abstract description 20
- 239000004009 herbicide Substances 0.000 claims abstract description 108
- 150000003839 salts Chemical class 0.000 claims abstract description 57
- 150000001875 compounds Chemical class 0.000 claims abstract description 45
- 238000000034 method Methods 0.000 claims abstract description 25
- 150000001204 N-oxides Chemical class 0.000 claims abstract description 15
- 241000196324 Embryophyta Species 0.000 claims description 64
- -1 bicyclopyron Chemical compound 0.000 claims description 51
- 244000038559 crop plants Species 0.000 claims description 18
- 240000008042 Zea mays Species 0.000 claims description 15
- 229920000742 Cotton Polymers 0.000 claims description 13
- 241000219146 Gossypium Species 0.000 claims description 13
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 claims description 13
- 235000002017 Zea mays subsp mays Nutrition 0.000 claims description 13
- 235000005822 corn Nutrition 0.000 claims description 13
- 235000002595 Solanum tuberosum Nutrition 0.000 claims description 11
- 244000061456 Solanum tuberosum Species 0.000 claims description 11
- 239000012872 agrochemical composition Substances 0.000 claims description 11
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 9
- 235000006008 Brassica napus var napus Nutrition 0.000 claims description 8
- 235000010469 Glycine max Nutrition 0.000 claims description 8
- 244000068988 Glycine max Species 0.000 claims description 8
- 239000005504 Dicamba Substances 0.000 claims description 7
- IWEDIXLBFLAXBO-UHFFFAOYSA-N dicamba Chemical compound COC1=C(Cl)C=CC(Cl)=C1C(O)=O IWEDIXLBFLAXBO-UHFFFAOYSA-N 0.000 claims description 7
- 239000007787 solid Substances 0.000 claims description 7
- 239000005578 Mesotrione Substances 0.000 claims description 6
- 240000007594 Oryza sativa Species 0.000 claims description 6
- 235000007164 Oryza sativa Nutrition 0.000 claims description 6
- MXWJVTOOROXGIU-UHFFFAOYSA-N atrazine Chemical compound CCNC1=NC(Cl)=NC(NC(C)C)=N1 MXWJVTOOROXGIU-UHFFFAOYSA-N 0.000 claims description 6
- 125000001072 heteroaryl group Chemical group 0.000 claims description 6
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 6
- KPUREKXXPHOJQT-UHFFFAOYSA-N mesotrione Chemical compound [O-][N+](=O)C1=CC(S(=O)(=O)C)=CC=C1C(=O)C1C(=O)CCCC1=O KPUREKXXPHOJQT-UHFFFAOYSA-N 0.000 claims description 6
- 240000000111 Saccharum officinarum Species 0.000 claims description 5
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- IYMLUHWAJFXAQP-UHFFFAOYSA-N topramezone Chemical compound CC1=C(C(=O)C2=C(N(C)N=C2)O)C=CC(S(C)(=O)=O)=C1C1=NOCC1 IYMLUHWAJFXAQP-UHFFFAOYSA-N 0.000 claims description 5
- AIAYSXFWIUNXRC-PHIMTYICSA-N (1r,5s)-3-[hydroxy-[2-(2-methoxyethoxymethyl)-6-(trifluoromethyl)pyridin-3-yl]methylidene]bicyclo[3.2.1]octane-2,4-dione Chemical compound COCCOCC1=NC(C(F)(F)F)=CC=C1C(O)=C1C(=O)[C@@H](C2)CC[C@@H]2C1=O AIAYSXFWIUNXRC-PHIMTYICSA-N 0.000 claims description 4
- WVQBLGZPHOPPFO-LBPRGKRZSA-N (S)-metolachlor Chemical compound CCC1=CC=CC(C)=C1N([C@@H](C)COC)C(=O)CCl WVQBLGZPHOPPFO-LBPRGKRZSA-N 0.000 claims description 4
- CASLETQIYIQFTQ-UHFFFAOYSA-N 3-[[5-(difluoromethoxy)-1-methyl-3-(trifluoromethyl)pyrazol-4-yl]methylsulfonyl]-5,5-dimethyl-4h-1,2-oxazole Chemical compound CN1N=C(C(F)(F)F)C(CS(=O)(=O)C=2CC(C)(C)ON=2)=C1OC(F)F CASLETQIYIQFTQ-UHFFFAOYSA-N 0.000 claims description 4
- 239000005617 S-Metolachlor Substances 0.000 claims description 4
- ZOMSMJKLGFBRBS-UHFFFAOYSA-N bentazone Chemical compound C1=CC=C2NS(=O)(=O)N(C(C)C)C(=O)C2=C1 ZOMSMJKLGFBRBS-UHFFFAOYSA-N 0.000 claims description 4
- 239000000460 chlorine Substances 0.000 claims description 4
- 229910052801 chlorine Inorganic materials 0.000 claims description 4
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 claims description 4
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- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 claims description 4
- 235000009566 rice Nutrition 0.000 claims description 4
- WBDLZWMPSRTAJU-GHMZBOCLSA-N (4R,5R)-1-(5-tert-butyl-1,2-oxazol-3-yl)-4-ethoxy-5-hydroxy-3-methylimidazolidin-2-one Chemical compound C(C)(C)(C)C1=CC(=NO1)N1C(N([C@@H]([C@H]1O)OCC)C)=O WBDLZWMPSRTAJU-GHMZBOCLSA-N 0.000 claims description 3
- PHZSPMUIHAUXQQ-NXEZZACHSA-N (4R,5R)-5-ethoxy-4-hydroxy-1-methyl-3-[4-(trifluoromethyl)pyridin-2-yl]imidazolidin-2-one Chemical compound C(C)O[C@@H]1[C@H](N(C(N1C)=O)C1=NC=CC(=C1)C(F)(F)F)O PHZSPMUIHAUXQQ-NXEZZACHSA-N 0.000 claims description 3
- WBDLZWMPSRTAJU-WDEREUQCSA-N (4R,5S)-1-(5-tert-butyl-1,2-oxazol-3-yl)-4-ethoxy-5-hydroxy-3-methylimidazolidin-2-one Chemical compound C(C)(C)(C)C1=CC(=NO1)N1C(N([C@@H]([C@@H]1O)OCC)C)=O WBDLZWMPSRTAJU-WDEREUQCSA-N 0.000 claims description 3
- PHZSPMUIHAUXQQ-VHSXEESVSA-N (4S,5R)-5-ethoxy-4-hydroxy-1-methyl-3-[4-(trifluoromethyl)pyridin-2-yl]imidazolidin-2-one Chemical compound C(C)O[C@@H]1[C@@H](N(C(N1C)=O)C1=NC=CC(=C1)C(F)(F)F)O PHZSPMUIHAUXQQ-VHSXEESVSA-N 0.000 claims description 3
- 244000062793 Sorghum vulgare Species 0.000 claims description 3
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- 235000019713 millet Nutrition 0.000 claims description 3
- 235000012015 potatoes Nutrition 0.000 claims description 3
- HTSGKJQDMSTCGS-UHFFFAOYSA-N 1,4-bis(4-chlorophenyl)-2-(4-methylphenyl)sulfonylbutane-1,4-dione Chemical compound C1=CC(C)=CC=C1S(=O)(=O)C(C(=O)C=1C=CC(Cl)=CC=1)CC(=O)C1=CC=C(Cl)C=C1 HTSGKJQDMSTCGS-UHFFFAOYSA-N 0.000 claims description 2
- 239000005476 Bentazone Substances 0.000 claims description 2
- 240000002791 Brassica napus Species 0.000 claims description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical group [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 2
- 230000000996 additive effect Effects 0.000 claims description 2
- CNBGNNVCVSKAQZ-UHFFFAOYSA-N benzidamine Natural products C12=CC=CC=C2C(OCCCN(C)C)=NN1CC1=CC=CC=C1 CNBGNNVCVSKAQZ-UHFFFAOYSA-N 0.000 claims description 2
- 125000001309 chloro group Chemical group Cl* 0.000 claims description 2
- 235000021374 legumes Nutrition 0.000 claims description 2
- FZXISNSWEXTPMF-UHFFFAOYSA-N terbutylazine Chemical compound CCNC1=NC(Cl)=NC(NC(C)(C)C)=N1 FZXISNSWEXTPMF-UHFFFAOYSA-N 0.000 claims description 2
- 229910052799 carbon Inorganic materials 0.000 abstract description 3
- 239000003053 toxin Substances 0.000 description 23
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- 102000004169 proteins and genes Human genes 0.000 description 16
- 235000014113 dietary fatty acids Nutrition 0.000 description 15
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- 239000011734 sodium Substances 0.000 description 10
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- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 9
- 239000012895 dilution Substances 0.000 description 9
- 238000010790 dilution Methods 0.000 description 9
- IAJOBQBIJHVGMQ-UHFFFAOYSA-N 2-amino-4-[hydroxy(methyl)phosphoryl]butanoic acid Chemical compound CP(O)(=O)CCC(N)C(O)=O IAJOBQBIJHVGMQ-UHFFFAOYSA-N 0.000 description 8
- 238000007792 addition Methods 0.000 description 8
- XDDAORKBJWWYJS-UHFFFAOYSA-N glyphosate Chemical compound OC(=O)CNCP(O)(O)=O XDDAORKBJWWYJS-UHFFFAOYSA-N 0.000 description 8
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- NUPJIGQFXCQJBK-UHFFFAOYSA-N 2-(4-isopropyl-4-methyl-5-oxo-4,5-dihydro-1H-imidazol-2-yl)-5-(methoxymethyl)nicotinic acid Chemical compound OC(=O)C1=CC(COC)=CN=C1C1=NC(C)(C(C)C)C(=O)N1 NUPJIGQFXCQJBK-UHFFFAOYSA-N 0.000 description 4
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- CAAMSDWKXXPUJR-UHFFFAOYSA-N 3,5-dihydro-4H-imidazol-4-one Chemical class O=C1CNC=N1 CAAMSDWKXXPUJR-UHFFFAOYSA-N 0.000 description 4
- 241000335053 Beta vulgaris Species 0.000 description 4
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- CLQMBPJKHLGMQK-UHFFFAOYSA-N 2-(4-isopropyl-4-methyl-5-oxo-4,5-dihydro-1H-imidazol-2-yl)nicotinic acid Chemical compound N1C(=O)C(C(C)C)(C)N=C1C1=NC=CC=C1C(O)=O CLQMBPJKHLGMQK-UHFFFAOYSA-N 0.000 description 3
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- CABMTIJINOIHOD-UHFFFAOYSA-N 2-[4-methyl-5-oxo-4-(propan-2-yl)-4,5-dihydro-1H-imidazol-2-yl]quinoline-3-carboxylic acid Chemical compound N1C(=O)C(C(C)C)(C)N=C1C1=NC2=CC=CC=C2C=C1C(O)=O CABMTIJINOIHOD-UHFFFAOYSA-N 0.000 description 3
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- PPKIJAQKBAYNNL-UHFFFAOYSA-M sodium;4-(2,4-dichlorophenoxy)butanoate Chemical compound [Na+].[O-]C(=O)CCCOC1=CC=C(Cl)C=C1Cl PPKIJAQKBAYNNL-UHFFFAOYSA-M 0.000 description 1
- GABUSZPTCJGKGB-UHFFFAOYSA-M sodium;4-(4-chloro-2-methylphenoxy)butanoate Chemical group [Na+].CC1=CC(Cl)=CC=C1OCCCC([O-])=O GABUSZPTCJGKGB-UHFFFAOYSA-M 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000004550 soluble concentrate Substances 0.000 description 1
- 238000009331 sowing Methods 0.000 description 1
- 238000001694 spray drying Methods 0.000 description 1
- 230000037359 steroid metabolism Effects 0.000 description 1
- 108010076424 stilbene synthase Proteins 0.000 description 1
- 239000000021 stimulant Substances 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-O sulfonium Chemical compound [SH3+] RWSOTUBLDIXVET-UHFFFAOYSA-O 0.000 description 1
- 125000005537 sulfoxonium group Chemical group 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 235000012222 talc Nutrition 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- DZLFLBLQUQXARW-UHFFFAOYSA-N tetrabutylammonium Chemical compound CCCC[N+](CCCC)(CCCC)CCCC DZLFLBLQUQXARW-UHFFFAOYSA-N 0.000 description 1
- CBXCPBUEXACCNR-UHFFFAOYSA-N tetraethylammonium Chemical compound CC[N+](CC)(CC)CC CBXCPBUEXACCNR-UHFFFAOYSA-N 0.000 description 1
- CXWXQJXEFPUFDZ-UHFFFAOYSA-N tetralin Chemical compound C1=CC=C2CCCCC2=C1 CXWXQJXEFPUFDZ-UHFFFAOYSA-N 0.000 description 1
- QEMXHQIAXOOASZ-UHFFFAOYSA-N tetramethylammonium Chemical compound C[N+](C)(C)C QEMXHQIAXOOASZ-UHFFFAOYSA-N 0.000 description 1
- 125000000437 thiazol-2-yl group Chemical group [H]C1=C([H])N=C(*)S1 0.000 description 1
- 125000004495 thiazol-4-yl group Chemical group S1C=NC(=C1)* 0.000 description 1
- 125000004496 thiazol-5-yl group Chemical group S1C=NC=C1* 0.000 description 1
- 210000001519 tissue Anatomy 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- BQZXUHDXIARLEO-UHFFFAOYSA-N tribenuron Chemical compound COC1=NC(C)=NC(N(C)C(=O)NS(=O)(=O)C=2C(=CC=CC=2)C(O)=O)=N1 BQZXUHDXIARLEO-UHFFFAOYSA-N 0.000 description 1
- 125000003866 trichloromethyl group Chemical group ClC(Cl)(Cl)* 0.000 description 1
- MCVUKOYZUCWLQQ-UHFFFAOYSA-N tridecylbenzene Chemical class CCCCCCCCCCCCCC1=CC=CC=C1 MCVUKOYZUCWLQQ-UHFFFAOYSA-N 0.000 description 1
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 description 1
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 description 1
- NRZWQKGABZFFKE-UHFFFAOYSA-N trimethylsulfonium Chemical compound C[S+](C)C NRZWQKGABZFFKE-UHFFFAOYSA-N 0.000 description 1
- 239000002753 trypsin inhibitor Substances 0.000 description 1
- 150000003672 ureas Chemical class 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 229940117958 vinyl acetate Drugs 0.000 description 1
- 230000003612 virological effect Effects 0.000 description 1
- 239000004562 water dispersible granule Substances 0.000 description 1
- 239000003021 water soluble solvent Substances 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
Definitions
- compositions comprising isoxazolo[5,4-b]pyridines
- the present invention relates to herbicidal compositions comprising at least one isoxazolo[5,4- b]pyridine herbicide I .A, I.B or I.C, or an N-oxide, or an agriculturally useful salt thereof, and at least one further compound selected from herbicidally active compounds of the formula 11.1 and II.2, or an N-oxide, or an agriculturally useful salt thereof, and, if desired, a safener C or at least one further herbicide D.
- the present invention also relates to the use of such a composition for controlling unwanted vegetation and to a method for controlling unwanted vegetation, which comprises allowing a composition to act on plants, their seeds and/or their habitat.
- crop protection compositions it is desirable to increase the specific activity of an active compound and the reliability of the effect. It is particularly desirable for the crop protection composition to control the harmful plants effectively, but at the same time to be compatible with the useful plants in question. It is also desirable to provide a broad spectrum of activity allowing the simultaneous control of a variety of harmful plants. Frequently this cannot be achieved using a single herbicidally active compound. With many highly effective herbicides, there is the problem that their compatibility with useful plants, in particular dicotyledonous crop plants, such as cotton, oilseed rape and graminaceous plants, such as barley, millet, corn, rice, wheat and sugar cane, is not always satisfactory, i.e.
- Herbicidal isoxazolo[5,4-b]pyridines of formulae I .A, I.B and I.C and their synthesis are known from WO 2012/010633 A1. Routes for the synthesis of isoxazolo[5,4-b]pyridine compounds are known from Elbannany et al, Pharmazie (1988), 43(2), 128-129 and Volochnyuk et al, Journal of Combinatorial Chemistry (2010), 12(4), 510-517. The isoxazolo[5,4-b]pyridine of formula I .A was described in herbicidal compositions with other herbicides and/or safeners in WO
- compositions which are highly active against unwanted harmful plants, showing enhanced activity in the sense of a synergistic effect.
- the compositions should have good compatibility with useful plants.
- the compositions according to the invention should have a broad spectrum of activity.
- the present invention relates to herbicidal compositions comprising as component A) at least nsisting of
- R 1 is methyl or methoxy
- R 2 is hydrogen, methyl or ethoxy
- A is a heteroaryl group, which is unsubstituted or substituted with 1 , 2 or 3 radicals selected from the group consisiting of Ci-C6-alkyl or Ci-C6-haloalkyl;
- R 1 is chlorine, methyl or methoxy
- R 2 is hydrogen, chlorine, methyl or ethoxy
- A is a heteroaryl group, which is unsubstituted or substituted with 1 , 2 or 3 radicals selected from the group consisiting of Ci-C6-alkyl or Ci-C6-haloalkyl; and, if desired, as component C) safeners.
- C n -C m indicates the number of carbon atoms possible in each case in the substituent or substituent moiety in question.
- Ci-C6-alkyl refers to a straight-chained or branched saturated hydrocarbon group having 1 to 6 carbon atoms, for example methyl, ethyl, propyl, 1 -methylethyl, butyl,
- Ci-C6-haloalkyl refers to a straight-chained or branched alkyl group having 1 to 6 carbon atoms (as defined above), wherein some or all of the hydrogen atoms in these groups may be replaced by halogen atoms as mentioned above, for example chloromethyl,
- heteroaryl refers to 5- or 6-membered aromatic ring systems incuding besides carbon atoms, 1 , 2, 3 or 4 heteroatoms independently selected from the group consisting of N, O and S; for example, a 5-membered heteroaryl such as pyrrol-1 -yl, pyrrol-2-yl, pyrrol-3-yl, thien-2-yl, thien-3-yl, furan-2-yl, furan-3-yl, pyrazol-1 -yl, pyrazol-3-yl, pyrazol-4-yl, pyrazol-5-yl, imidazol-1 -yl, imidazol-2-yl, imidazol-4-yl, imidazol-5-yl, oxazol-2-yl, oxazol-4-yl, oxazol-5-yl, isoxazol-3-yl, isoxazol-4-yl, isoxazol-3-yl,
- a 6-membered heteroaryl such as pyridin-2-yl, pyridin-3-yl, pyridin-4-yl, pyridazin-3-yl, pyridazin-4-yl, pyrimidin-2-yl, pyrimidin-4-yl, pyrimidin-5-yl, pyrazin-2-yl and 1 ,3,5-triazin-2-yl and 1 ,2,4-triazin-3-yl.
- the isoxazolo[5,4-b]pyridine compounds of formula I. A, I.B and I.C and the herbicides of the formula 11.1 and II.2 have ionizable functional groups. They can also be employed in the form of their agriculturally acceptable salts. Suitable are, in general, the salts of those cations and the acid addition salts of those acids whose cations and anions, respectively, have no adverse effect on the activity of the active compounds.
- Preferred cations are the ions of the alkali metals, preferably of lithium, sodium and potassium, of the alkaline earth metals, preferably of calcium and magnesium, and of the transition metals, preferably of manganese, copper, zinc and iron, further ammonium and substituted ammonium in which one to four hydrogen atoms are replaced by Ci-C4-alkyl, hydroxy-Ci-C4-alkyl, C1-C4- alkoxy-Ci-C4-alkyl, hydroxy-Ci-C4-alkoxy-Ci-C4-alkyl, phenyl or benzyl, preferably ammonium, methylammonium, isopropylammonium, dimethylammonium, diisopropylammonium, trimethylammonium, heptylammonium, dodecylammonium, tetradecylammonium,
- Anions of useful acid addition salts are primarily chloride, bromide, fluoride, iodide,
- the invention relates in particular to compositions in the form of herbicidally active agrochemical compositions comprising a herbicidally effective amount of an active compound combination comprising at least one isoxazolo[5,4-b]pyridine compound of formula I .A, I.B or I.C, or an N- oxide, or an agriculturally useful salt thereof, and at least one further herbicide selected from a herbicide of the formula 11.1 or II.2, or an N-oxide, or an agriculturally useful salt thereof, and, if desired, safeners C or at least one further herbicide D, and at least one liquid and/or solid carrier and/or one or more surfactants and, if desired, one or more further auxiliaries customary for agrochemical compositions.
- An agrochemical composition comprises a pesticidally effective amount of at least one composition according to the invention.
- the term "effective amount” denotes an amount of the active ingredients, which is sufficient for controlling unwanted plants, especially for controlling unwanted plants in cultivated plants and which does not result in a substantial damage to the treated plants. Such an amount can vary in a broad range and is dependent on various factors, such as the plants to be controlled, the treated cultivated plant or material, the climatic conditions and the specific composition according to the invention used.
- the invention furthermore relates to a method for controlling unwanted vegetation, in particular in fields where crop plants are cultivated.
- the invention also relates to a method for the desiccation or defoliation of plants.
- the time frame within which the desired herbicidal action can be achieved, may be expanded by the compositions according to the invention. This allows a more flexibly timed application of the compositons according to the present invention in comparison with the single compounds.
- compositions according to the invention have better herbicidal activity, i.e. better activity against harmful plants, than would have been expected based on the herbicidal activity observed for the individual components A or B, or a broader activity spectrum.
- the herbicidal activity to be expected for compositions based on the individual compound can be calculated using the method of S. R. Colby (1967) "Calculating synergistic and antagonistic responses of herbicide combinations", Weeds 15, p. 22 ff..
- the value E which represents the expected additive activity of the individual active compounds, was calculated using the formula
- X percent activity using active component A at an application rate a
- E expected activity (in %) by A + B at application rates a + b.
- compositions comprise as component A isoxazolo[5,4- b]pyridine of formula I .A or an agriculturally acceptable salt thereof.
- the isoxazolo[5,4-b]pyridine compounds of formula I .A. I.B or I.C or the herbicides of the formula 11.1 or II.2, the safeners C or the further herbicides D as described herein, are capable of forming geometrical isomers, it is possible to use both, the pure isomers and mixtures thereof, in the compositions according to the invention.
- compositions comprising as component B a herbicide selected from the group consisting of
- compositions wherein component A is the compound of the formula I.A and component B is selected from the group consisting of compounds of the formulae II.A, 5S-II.A, N-C, II. D, II. F, II.G, II.H and II.J; in particular component B is 5S-II.A or II. D.
- component A is the compound of the formula I.A and component B is selected from the group consisting of compounds of the formulae 4R,5S-II.A, 4S,5S-II.A, II. Ca, II. Cb, II.Fa and II.Fb, or component B is selected from mixtures of these stereoisomers.
- Compound ll.Ca is herein referred to as ⁇ 4S, 5R)-5-ethoxy-4-hydroxy-1 -methyl-3-[4- (trifluoromethyl)-2-pyridyl]imidazolidin-2-one.
- Compound ll.Cb is herein referred to as (4R, 5R)-5-ethoxy-4-hydroxy-1 -methyl-3-[4- (trifluoromethyl)-2-pyridyl]imidazolidin-2-one.
- Compound 11. Fa is herein referred to as (4R, 5S)-1 -(5-tert-butylisoxazol-3-yl)-4-ethoxy-5- hydroxy-3-methyl-imidazolidin-2-one.
- Compound II.Fb is herein referred to as (4R, 5R)-1 -(5-tert-butylisoxazol-3-yl)-4-ethoxy-5- hydroxy-3-methyl-imidazolidin-2-one.
- Compound 4R,5S-II.A is herein referred to as (4R,5SJ-4-hydroxy-1 -methoxy-5-methyl-3-[4- trifluoromethyl)-2-pyridyl]imidazolidin-2-one.
- 4S,5S-II.A is herein referred to as (4S,5SJ-4-hydroxy-1 -methoxy-5-methyl-3-[4- (trifluoromethyl)-2-pyridyl]imidazolidin-2-one.
- component A is the compound of the formula I.A and component B is selected from the stereoisomers of the compound of the formula II.C, ⁇ 4R, 5R)-5-ethoxy-4-hydroxy-1 - methyl-3-[4-(trifluoromethyl)-2-pyridyl]imidazolidin-2-one and (4S, 5R)-5-ethoxy-4-hydroxy-1 - methyl-3-[4-(trifluoromethyl)-2-pyridyl]imidazolidin-2-one, or mixtures of these stereoisomers.
- component A is the compound of the formula I.A and component B is selected from the stereoisomers of the compound of the formula II.
- F (4R, 5R)-1 -(5-tert- butylisoxazol-3-yl)-4-ethoxy-5-hydroxy-3-methyl-imidazolidin-2-one and (4R, 5S)-1 -(5-tert- butylisoxazol-3-yl)-4-ethoxy-5-hydroxy-3-methyl-imidazolidin-2-one, or mixtures of these stereoisomers.
- component A is the compound of the formula I.A and component B is selected from the stereoisomers of the compound of the formula 11.
- A (4R,5S,)-4-hydroxy-1 - methoxy-5-methyl-3-[4-trifluoromethyl)-2-pyridyl]imidazolidin-2-one and (4S,5S J-4-hydroxy-l - methoxy-5-methyl-3-[4-(trifluoromethyl)-2-pyridyl]imidazolidin-2-one, or mixtures of these stereoisomers.
- ternary compositions which correspond to the binary compositions mentioned above and additionally comprise a safener C.
- Particularly preferred safeners C namely C.1 to C.17, are listed below in table C.
- Safeners C are known from, for example, The Compendium of Pesticide Common Names (http://www.alanwood.net/pesticides/); Farm Chemicals Handbook 2000 volume 86, Meister Publishing Company, 2000; B. Hock, C. Fedtke, R. R. Schmidt, Herbizide [Herbicides], Georg Thieme Verlag, Stuttgart 1995; W. H. Ahrens, Herbicide Handbook, 7th edition, Weed Science Society of America, 1994; and K. K. Hatzios, Herbicide Handbook, Supplement for the 7th edition, Weed Science Society of America, 1998.
- compositions according to the invention may comprise further herbicides D selected from the group consisiting of pinoxaden, clethodim, clodinafop-propargyl, chlorsulfuron, florasulam, imazamox, imazapic, imazapyr, imazaquin, imazethapyr, mesosulfuron-methyl, metazosulfuron, metsulfuron-methyl, nicosulfuron, penoxsulam, pyroxsulam,thiencarbazone-methyl,
- compositions may comprise further herbicides D selected from the group consisting of atrazine, terbutylazine, mesotrione, bicyclopyron, S-metolachlor,
- topramezone dicamba, bentazone, DMTA-p, pyroxasulfone, pendimethylin, atrazine, mesotrione and bicyclopyrone.
- herbicides D and safeners C having a carboxyl group can be employed in the form of the acid or in the form of an agriculturally suitable salt as mentioned above or else in the form of an agriculturally acceptable derivative in the compositions according to the invention.
- suitable salts include those, where the counterion is an agriculturally acceptable cation.
- suitable salts of dicamba are dicamba-sodium, dicamba- potassium, dicamba-methylammonium, dicamba-dimethylammonium, dicamba- isopropylammonium, dicamba-diglycolamine, dicamba-olamine, dicamba-diolamine, dicamba- trolamine, dicamba-N,N-bis-(3-aminopropyl)methylamine and dicamba-diethylenetriamine.
- a suitable ester are dicamba-methyl and dicamba-butotyl.
- Suitable salts of 2,4-D are 2,4-D-ammonium, 2,4-D-dimethylammonium, 2,4-D- diethylammonium, 2,4-D-diethanolammonium (2,4-D-diolamine), 2,4-D-triethanolammonium, 2,4-D-isopropylammonium, 2,4-D-triisopropanolammonium, 2,4-D-heptylammonium, 2,4-D- dodecylammonium, 2,4-D-tetradecylammonium, 2,4-D-triethylammonium, 2,4-D-tris(2- hydroxypropyl)ammonium, 2,4-D-tris(isopropyl)ammonium, 2,4-D-trolamine, 2,4-D-lithium, 2,4- D-sodium.
- esters of 2,4-D are 2,4-D-butotyl, 2,4-D-2-butoxypropyl, 2,4-D- 3-butoxypropyl, 2,4-D-butyl, 2,4-D-ethyl, 2,4-D-ethylhexyl, 2,4-D-isobutyl, 2,4-D-isooctyl, 2,4-D- isopropyl, 2,4-D-meptyl, 2,4-D-methyl, 2,4-D-octyl, 2,4-D-pentyl, 2,4-D-propyl, 2,4-D-tefuryl and clacyfos.
- Suitable salts of 2,4-DB are for example 2,4-DB-sodium, 2,4-DB-potassium and 2,4-DB- dimethylammonium.
- Suitable esters of 2,4-DB are for example 2,4-DB-butyl and 2,4-DB-isoctyl.
- Suitable salts of dichlorprop are for example dichlorprop-sodium, dichlorprop-potassium and dichlorprop-dimethylammonium. Examples of suitable esters of dichlorprop are dichlorprop- butotyl and dichlorprop-isoctyl.
- Suitable salts and esters of MCPA include MCPA-butotyl, MCPA-butyl, MCPA-dimethyl- ammonium, MCPA-diolamine, MCPA-ethyl, MCPA-thioethyl, MCPA-2-ethylhexyl, MCPA- isobutyl, MCPA-isoctyl, MCPA-isopropyl, MCPA-isopropylammonium, MCPA-methyl, MCPA- olamine, MCPA-potassium, MCPA-sodium and MCPA-trolamine.
- a suitable salt of MCPB is MCPB sodium.
- a suitable ester of MCPB is MCPB-ethyl.
- Suitable salts of clopyralid are clopyralid-potassium, clopyralid-olamine and clopyralid-tris-(2- hydroxypropyl)ammonium.
- Example of suitable esters of clopyralid is clopyralid-methyl.
- Examples of a suitable ester of fluroxypyr are fluroxypyr-meptyl and fluroxypyr-2-butoxy-1 - methylethyl, wherein fluroxypyr-meptyl is preferred.
- Suitable salts of picloram are picloram-dimethylammonium, picloram-potassium, picloram- triisopropanolammonium, picloram-triisopropylammonium and picloram-trolamine.
- a suitable ester of picloram is picloram-isoctyl.
- a suitable salt of triclopyr is triclopyr-triethylammonium.
- Suitable esters of triclopyr are for example triclopyr-ethyl and triclopyr-butotyl.
- Suitable salts and esters of chloramben include chloramben-ammonium, chloramben-diolamine, chloramben-methyl, chloramben-methylammonium and chloramben-sodium.
- Suitable salts and esters of 2,3,6-TBA include 2,3,6-TBA-dimethylammonium, 2,3,6-TBA-lithium, 2,3,6-TBA- potassium and 2,3,6-TBA-sodium.
- Suitable salts and esters of aminopyralid include aminopyralid-potassium, aminopyralid- dimethylammonium, and aminopyralid-tris(2-hydroxypropyl)ammonium.
- Suitable salts of glyphosate are for example glyphosate-ammonium, glyphosate-diammonium, glyphoste-dimethylammonium, glyphosate-isopropylammonium, glyphosate-potassium, glyphosate-sodium, glyphosate-trimesium as well as the ethanolamine and diethanolamine salts, preferably glyphosate-diammonium, glyphosate-isopropylammonium and glyphosate- trimesium (sulfosate).
- a suitable salt of glufosinate is for example glufosinate-ammonium.
- a suitable salt of glufosinate-P is for example glufosinate-P-ammonium.
- Suitable salts and esters of bromoxynil are for example bromoxynil-butyrate, bromoxynil- heptanoate, bromoxynil-octanoate, bromoxynil-potassium and bromoxynil-sodium.
- Suitable salts and esters of ioxonil are for example ioxonil-octanoate, ioxonil-potassium and ioxonil-sodium.
- Suitable salts and esters of mecoprop include mecoprop-butotyl, mecoprop-dimethylammonium, mecoprop-diolamine, mecoprop-ethadyl, mecoprop-2-ethylhexyl, mecoprop-isoctyl, mecoprop- methyl, mecoprop-potassium, mecoprop-sodium and mecoprop-trolamine.
- Suitable salts of mecoprop-P are for example mecoprop-P-butotyl, mecoprop-P- dimethylammonium, mecoprop-P-2-ethylhexyl, mecoprop-P-isobutyl, mecoprop-P-potassium and mecoprop-P-sodium.
- a suitable salt of diflufenzopyr is for example diflufenzopyr-sodium.
- a suitable salt of naptalam is for example naptalam-sodium.
- Suitable salts and esters of aminocyclopyrachlor are for example aminocyclopyrachlor- dimethylammonium, aminocyclopyrachlor-methyl, aminocyclopyrachlor- triisopropanolammonium, aminocyclopyrachlor-sodium and aminocyclopyrachlor-potassium.
- a suitable salt of quinclorac is for example quinclorac-dimethylammonium.
- a suitable salt of quinmerac is for example quinmerac-dimethylammonium.
- a suitable salt of imazamox is for example imazamox-ammonium.
- Suitable salts of imazapic are for example imazapic-ammonium and imazapic- isopropylammonium.
- Suitable salts of imazapyr are for example imazapyr-ammonium and imazapyr- isopropylammonium.
- a suitable salt of imazaquin is for example imazaquin-ammonium.
- Suitable salts of imazethapyr are for example imazethapyr-ammonium and imazethapyr- isopropylammonium.
- a suitable salt of topramezone is for example topramezone-sodium.
- binary compositions refers to compositions comprising one or more isoxazolo[5,4- b]pyridines of the formula I .A, I.B or I.C (component A), and one or more herbicides of the formula 11.1 or II.2 or subformulae thereof as defined herein (component B).
- ternary compositions refers to compositions comprising one or more isoxazolo[5,4- b]pyridines of the formula I.A, I.B or I.C (component A), and one or more, herbicides of the formula 11.1 or II.2 or subformulae thereof as defined herein (component B), and a third component, which may be a further herbicide D as defined herein or one or more safeners C as defined herein.
- the weight ratio of the active components A:B is generally in the range of from 1 :500 to 500:1 , or in the range of from 1 :250 to 250:1 , or in the range of from 1 :125 to 125:1 , or in the range of from 1 :50 to 50: 1 , or in the range of from 1 :20 to 20: 1 , or in the range of from 1 :5 to 5:1 .
- the weight ratio of the active components I.A:B is in the range of from 1 :10 to 10:1 or more preferably from 1 :5 to 5:1 , in a specially preferred embodiment 1 :3 to 3:1 , for example 1 :1 , 1 .5:1 , 2:1 , 1 :1.5 or 1 :2.
- the relative proportions by weight of the components A:B are generally in the range of from 1 :500 to 500:1 , or in the range of from 1 :250 to 250:1 , or in the range of from 1 :125 to 125:1 , or the range of from 1 :50 to 50:1 , or in the range of from 1 :20 to 20:1 , or in the range of from 1 :5 to 5:1 ; and wherein the weight ratio of the components A:C or A:D is generally in the range of from 1 :500 to 500:1 , or in the range of from 1 :250 to 250:1 , or in the range of from 1 :125 to 125:1 , or the range of from 1 :50 to 50:1 , or in the range of from 1 :20 to 20:1 , or in the range of from 1 :5 to 5:1 ; and the weight ratio of the components B:C is generally in the range of from 1 :500 to 500:1 ,
- compositions mentioned below in table 1 wherein each
- composition comprises isoxazolo[5,4-b]pyridine of formula I.A, a component B and, if desired, the safener C as defined for each individual composition in one row of table 1 below
- compositions no. M1.1 to M1.270 are compositions no. M1.1 to M1.270.
- compositions M2.1 to M2.270 which differ from the corresponding
- compositions M1.1 to M1.270 in table 1 only in that they comprise as the active component A, instead of the isoxazolo[5,4-b]pyridine of formula I.A, the isoxazolo[5,4-b]pyridine of formula I.B. Also preferred are compositions M3.1 to M3.270, which differ from the corresponding
- compositions M1.1 to M1.270 in table 1 only in that they comprise as the active component A, instead of the isoxazolo[5,4-b]pyridine of formula I.A, the isoxazolo[5,4-b]pyridine of formula I.C.
- the specific number for each single composition is deductible as follows: for example, composition M1.18 comprises the compound of the formula I.A, the compound of the formula 4S,5S-II.A and the safener C.1 (benoxacor, as defined in table C).
- M1.12 I.A+II.H; M1.13: I.A+II.J; M1.14: I.A+II.K; M1.15: I.A+II.L; M1.16: I.A+II.A+C.1; M1.17: I.A+4R,5S-II.A+C1; M1.18: I.A+4S,5S-II.A+C1; M1.19: I.A+II.B+C.1; M1.20: I.A+II.Ca+C.1; M1.21: I.A+II.Cb+C.1; M1.22: I.A+II.D+C.1; M1.23: I.A+II.E+C.1; M1.24: I.A+II.Fa+C.1; M1.25: I.A+II.Fb+C.1; M1.26: I.A+II.G+C.1; M1.2
- M1.159 I.A+II.Fa+C.10
- M1.160 I.A+II.Fb+C.10
- M1.161 I.A+II.G+C.10
- M1.162 I.A+II.G+C.10
- M1.173 I.A+II.E+C.11 ; M1.174: I.A+II.Fa+C.11 ; M1.175: I.A+II.Fb+C.11 ; M1.176:
- M1.191 I.A+II.G+C.12; M1.192: I.A+II.H+C.12; M1.193: I.A+II.J+C.12; M1.194: I.A+II.K+C.12; M1.195: I.A+II.L+C.12; M1.196: I.A+II.A+C.13; M1.197: I.A+4R,5S-II.A+C13; M1.198:
- M1.220 I.A+II.Fb+C.14; M1.221: I.A+II.G+C.14; M1.222: I.A+II.H+C.14; M1.223: I.A+II.J+C.14; M1.224: I.A+II.K+C.14; M1.225: I.A+II.L+C.14; M1.226: I.A+II.A+C.15; M1.227: I.A+4R,5S- II.A+C.15; M1.228: I.A+4S,5S-II.A+C15; M1.229: I.A+II.B+C.15; M1.230: I.A+II.Ca+C.15; M1.231: I.A+II.Cb+C.15; M1.232: I.A+II.D+C.15; M1.233: I.A+II.E+C.15; M1.234:
- M1.238 I.A+II.J+C.15; M1.239: I.A+II.K+C.15; M1.240: I.A+II.L+C.15; M1.241: I.A+II.A+C.16; M1.242: I.A+4R,5S-II.A+C16; M1.243: I.A+4S,5S-II.A+C16; M1.244: I.A+II.B+C.16; M1.245: I.A+II.Ca+C.16; M1.246: I.A+II.Cb+C.16; M1.247: I.A+II.D+C.16; M1.248: I.A+II.E+C.16;
- M1.249 I .A+l I .Fa+C.16; M1.250: I.A+II.Fb+C.16; M1.251: I.A+II.G+C.16; M1.252:
- M1 .263 I.A+II.E+C.17
- M1.264 I.A+II.Fa+C.17
- M1.265 I.A+II.Fb+C.17
- M1.266
- compositions M4.1 to M4.270 which differ from the corresponding compositions M1 .1 to M1 .270 only in that they additionally comprise pinoxaden as further herbicide D.
- compositions M5.1 to M5.270 which differ from the corresponding compositions M1 .1 to M1 .270 only in that they additionally comprise clethodim as further herbicide D.
- compositions M6.1 to M6.270 which differ from the corresponding compositions M1 .1 to M1 .270 only in that they additionally comprise clodinafop-propargyl as further herbicide D.
- compositions M7.1 to M7.270 which differ from the corresponding compositions M1 .1 to M1 .270 only in that they additionally comprise chlorsulfuron as further herbicide D.
- compositions M8.1 to M8.270 which differ from the corresponding compositions M1 .1 to M1 .270 only in that they additionally comprise florasulam as further herbicide D.
- compositions M9.1 to M9.270 which differ from the corresponding compositions M1 .1 to M1 .270 only in that they additionally comprise imazamox as further herbicide D.
- compositions M10.1 to M10.270 which differ from the
- compositions M1 .1 to M1 .270 only in that they additionally comprise imazapic as further herbicide D.
- compositions M1 1.1 to M1 1 .270 which differ from the
- compositions M1.1 to M1 .270 only in that they additionally comprise imazapyr as further herbicide D.
- compositions M12.1 to M12.270 which differ from the
- compositions M1 .1 to M1 .270 only in that they additionally comprise imazaquin as further herbicide D.
- compositions M13.1 to M13.270 which differ from the
- compositions M1 .1 to M1 .270 only in that they additionally comprise imazethapyr as further herbicide D.
- compositions M14.1 to M14.270 which differ from the
- compositions M1 .1 to M1 .270 only in that they additionally comprise
- compositions M15.1 to M15.270 which differ from the
- compositions M1 .1 to M1 .270 only in that they additionally comprise
- metazosulfuron as further herbicide D.
- compositions M16.1 to M16.270 which differ from the
- compositions M1 .1 to M1 .270 only in that they additionally comprise metsulfuron- methyl as further herbicide D.
- compositions M17.1 to M17.270 which differ from the
- compositions M1 .1 to M1 .270 only in that they additionally comprise nicosulfuron as further herbicide D.
- compositions M18.1 to M18.270 which differ from the
- compositions M1 .1 to M1 .270 only in that they additionally comprise penoxsulam as further herbicide D.
- compositions M19.1 to M19.270 which differ from the
- compositions M1 .1 to M1 .270 only in that they additionally comprise pyroxsulam as further herbicide D.
- compositions M20.1 to M20.270 which differ from the
- compositions M1 .1 to M1 .270 only in that they additionally comprise
- compositions M21.1 to M21 .270 which differ from the
- compositions M1 .1 to M1 .270 only in that they additionally comprise
- compositions M22.1 to M22.270 which differ from the
- compositions M1 .1 to M1 .270 only in that they additionally comprise tribenuron- methyl as further herbicide D.
- compositions M23.1 to M23.270 which differ from the
- compositions M1 .1 to M1 .270 only in that they additionally comprise atrazine as further herbicide D.
- compositions M5.1 to M5.270 which differ from the corresponding compositions M1 .1 to M1 .270 only in that they additionally comprise bentazon as further herbicide D.
- compositions M24.1 to M24.270 which differ from the
- compositions M1 .1 to M1 .270 only in that they additionally comprise bromoxynil as further herbicide D.
- compositions M25.1 to M25.270 which differ from the
- compositions M1 .1 to M1 .270 only in that they additionally comprise metribuzin as further herbicide D.
- compositions M26.1 to M26.270 which differ from the
- compositions M1 .1 to M1 .270 only in that they additionally comprise paraquat- dichloride as further herbicide D.
- compositions M27.1 to M27.270 which differ from the
- compositions M1 .1 to M1 .270 only in that they additionally comprise acifluorfen as further herbicide D.
- compositions M28.1 to M28.270 which differ from the
- compositions M1 .1 to M1 .270 only in that they additionally comprise
- compositions M29.1 to M29.270 which differ from the
- compositions M1 .1 to M1 .270 only in that they additionally comprise flumioxazin as further herbicide D.
- compositions M30.1 to M30.270 which differ from the corresponding compositions M1 .1 to M1 .270 only in that they additionally comprise fomesafen as further herbicide D.
- compositions M31.1 to M31 .270 which differ from the
- compositions M1 .1 to M1 .270 only in that they additionally comprise oxadiargyl as further herbicide D.
- compositions M32.1 to M32.270 which differ from the
- compositions M1 .1 to M1 .270 only in that they additionally comprise oxyfluorfen as further herbicide D.
- compositions M33.1 to M33.270 which differ from the
- compositions M1 .1 to M1 .270 only in that they additionally comprise saflufenacil as further herbicide D.
- compositions M34.1 to M34.270 which differ from the
- compositions M1 .1 to M1 .270 only in that they additionally comprise
- compositions M35.1 to M35.270 which differ from the
- compositions M1 .1 to M1 .270 only in that they additionally comprise isoxaflutole as further herbicide D.
- compositions M36.1 to M36.270 which differ from the
- compositions M1 .1 to M1 .270 only in that they additionally comprise mesotrione as further herbicide D.
- compositions M37.1 to M37.270 which differ from the
- compositions M1 .1 to M1 .270 only in that they additionally comprise tembotrione as further herbicide D.
- compositions M38.1 to M38.270 which differ from the
- compositions M1.1 to M1 .270 only in that they additionally comprise
- topramezone as further herbicide D.
- compositions M39.1 to M39.270 which differ from the
- compositions M1 .1 to M1 .270 only in that they additionally comprise
- compositions M40.1 to M40.270 which differ from the
- compositions M1 .1 to M1 .270 only in that they additionally comprise
- compositions M41.1 to M41 .270 which differ from the
- compositions M1 .1 to M1 .270 only in that they additionally comprise
- compositions M42.1 to M42.270 which differ from the
- compositions M1 .1 to M1 .270 only in that they additionally comprise glyphosate as further herbicide D.
- compositions M43.1 to M43.270 which differ from the
- compositions M1 .1 to M1 .270 only in that they additionally comprise glufosinate as further herbicide D.
- compositions M44.1 to M44.270 which differ from the corresponding compositions M1 .1 to M1 .270 only in that they additionally comprise acetochlor as further herbicide D.
- compositions M45.1 to M45.270 which differ from the
- compositions M1 .1 to M1 .270 only in that they additionally comprise
- compositions M46.1 to M46.270 which differ from the
- compositions M1 .1 to M1 .270 only in that they additionally comprise metolachlor as further herbicide D.
- compositions M47.1 to M47.270 which differ from the
- compositions M1 .1 to M1 .270 only in that they additionally comprise S- metolachlor as further herbicide D.
- compositions M48.1 to M48.270 which differ from the
- compositions M1 .1 to M1 .270 only in that they additionally comprise
- compositions M49.1 to M49.270 which differ from the
- compositions M1.1 to M1 .270 only in that they additionally comprise
- compositions M50.1 to M50.270 which differ from the
- compositions M1 .1 to M1 .270 only in that they additionally comprise dicamba as further herbicide D.
- compositions M51.1 to M51 .270 which differ from the
- compositions M1 .1 to M1 .270 only in that they additionally comprise fluroxypyr as further herbicide D.
- compositions M52.1 to M52.270 which differ from the
- compositions M1 .1 to M1 .270 only in that they additionally comprise 2,4-D as further herbicide D.
- compositions M53.1 to M53.270 which differ from the
- compositions M1 .1 to M1 .270 only in that they additionally comprise MCPA as further herbicide D.
- compositions M54.1 to M54.270 which differ from the
- compositions M1.1 to M1 .270 only in that they additionally comprise quinclorac as further herbicide D.
- compositions M55.1 to M55.270 which differ from the
- compositions M1 .1 to M1 .270 only in that they additionally comprise
- compositions M56.1 to M56.270 which differ from the
- compositions M1.1 to M1 . 34 only in that they additionally comprise pyridate as further herbicide D.
- compositions M57.1 to M57.270 which differ from the
- compositions M1 .1 to M1 .270 only in that they additionally comprise halauxifen as further herbicide D.
- compositions M58.1 to M58.270 which differ from the
- compositions M1 .1 to M1 .270 only in that they additionally comprise trifludimoxazin as further herbicide D.
- agrochemical compositions e.g. solutions, emulsions, suspensions, dusts, powders, pastes, granules, pressings, capsules, and mixtures thereof.
- agrochemical composition types are suspensions (e.g. SC, OD, FS), emulsifiable concentrates (e.g. EC), emulsions (e.g. EW, EO, ES, ME), capsules (e.g. CS, ZC), pastes, pastilles, wettable powders or dusts (e.g.
- WP WP
- SP WS
- DP DS
- pressings e.g. BR, TB, DT
- granules e.g. WG, SG, GR, FG, GG, MG
- insecticidal articles e.g. LN
- gel formulations for the treatment of plant propagation materials such as seeds (e.g. GF).
- agrochemical compositions are prepared in a known manner, such as described by Mollet and Grubemann, Formulation technology, Wiley VCH, Weinheim, 2001 ; or Knowles, New developments in crop protection product formulation, Agrow Reports DS243, T&F Informa, London, 2005.
- auxiliaries are solvents, liquid carriers, solid carriers or fillers, surfactants, dispersants, emulsifiers, wetters, adjuvants, solubilizers, penetration enhancers, protective colloids, adhesion agents, thickeners, humectants, repellents, attractants, feeding stimulants,
- compatibilizers for bactericides, anti-freezing agents, anti-foaming agents, colorants, tackifiers and binders.
- Suitable solvents and liquid carriers are water and organic solvents, such as mineral oil fractions of medium to high boiling point, e.g. kerosene, diesel oil; oils of vegetable or animal origin; aliphatic, cyclic and aromatic hydrocarbons, e. g. toluene, paraffin,
- tetrahydronaphthalene alkylated naphthalenes
- alcohols e.g. ethanol, propanol, butanol, benzylalcohol, cyclohexanol
- glycols DMSO
- ketones e.g. cyclohexanone
- esters e.g. lactates, carbonates, fatty acid esters, gamma-butyrolactone
- fatty acids phosphonates
- amines amides, e.g. N-methylpyrrolidone, fatty acid dimethylamides; and mixtures thereof.
- Suitable solid carriers or fillers are mineral earths, e.g. silicates, silica gels, talc, kaolins, limestone, lime, chalk, clays, dolomite, diatomaceous earth, bentonite, calcium sulfate, magnesium sulfate, magnesium oxide; polysaccharides, e.g. cellulose, starch; fertilizers, e.g. ammonium sulfate, ammonium phosphate, ammonium nitrate, ureas; products of vegetable origin, e.g. cereal meal, tree bark meal, wood meal, nutshell meal, and mixtures thereof.
- mineral earths e.g. silicates, silica gels, talc, kaolins, limestone, lime, chalk, clays, dolomite, diatomaceous earth, bentonite, calcium sulfate, magnesium sulfate, magnesium oxide
- polysaccharides e.g. cellulose, starch
- fertilizers
- Suitable surfactants are surface-active compounds, such as anionic, cationic, nonionic and amphoteric surfactants, block polymers, polyelectrolytes, and mixtures thereof. Such surfactants can be used as emulsifier, dispersant, solubilizer, wetter, penetration enhancer, protective colloid, or adjuvant. Examples of surfactants are listed in McCutcheon's, Vol.1 : Emulsifiers & Detergents, McCutcheon's Directories, Glen Rock, USA, 2008 (International Ed. or North American Ed.).
- Suitable anionic surfactants are alkali, alkaline earth or ammonium salts of sulfonates, sulfates, phosphates, carboxylates, and mixtures thereof.
- sulfonates are alkylarylsulfonates, diphenylsulfonates, alpha-olefin sulfonates, lignine sulfonates, sulfonates of fatty acids and oils, sulfonates of ethoxylated alkylphenols, sulfonates of alkoxylated arylphenols, sulfonates of condensed naphthalenes, sulfonates of dodecyl- and tridecylbenzenes, sulfonates of naphthalenes and alkylnaphthalenes, sulfosuccinates or sulfosuccinamates.
- Examples of sulfates are sulfates of fatty acids and oils, of ethoxylated alkylphenols, of alcohols, of ethoxylated alcohols, or of fatty acid esters.
- Examples of phosphates are phosphate esters.
- Examples of carboxylates are alkyl carboxylates, and carboxylated alcohol or alkylphenol ethoxylates.
- Suitable nonionic surfactants are alkoxylates, N-substituted fatty acid amides, amine oxides, esters, sugar-based surfactants, polymeric surfactants, and mixtures thereof.
- alkoxylates are compounds such as alcohols, alkylphenols, amines, amides, arylphenols, fatty acids or fatty acid esters which have been alkoxylated with 1 to 50 equivalents.
- Ethylene oxide and/or propylene oxide may be employed for the alkoxylation, preferably ethylene oxide.
- N-substituted fatty acid amides are fatty acid glucamides or fatty acid
- esters are fatty acid esters, glycerol esters or monoglycerides.
- sugar-based surfactants are sorbitans, ethoxylated sorbitans, sucrose and glucose esters or alkylpolyglucosides.
- polymeric surfactants are home- or copolymers of vinylpyrrolidone, vinylalcohols, or vinylacetate.
- Suitable cationic surfactants are quaternary surfactants, for example quaternary ammonium compounds with one or two hydrophobic groups, or salts of long-chain primary amines.
- Suitable amphoteric surfactants are alkylbetains and imidazolines.
- Suitable block polymers are block polymers of the A-B or A-B-A type comprising blocks of polyethylene oxide and polypropylene oxide, or of the A-B-C type comprising alkanol, polyethylene oxide and polypropylene oxide.
- Suitable polyelectrolytes are polyacids or polybases. Examples of polyacids are alkali salts of polyacrylic acid or polyacid comb polymers. Examples of polybases are polyvinylamines or polyethyleneamines.
- Suitable adjuvants are compounds, which have a neglectable or even no pesticidal activity themselves, and which improve the biological performance of the compound I on the target.
- examples are surfactants, mineral or vegetable oils, and other auxiliaries. Further examples are listed by Knowles, Adjuvants and additives, Agrow Reports DS256, T&F Informa UK, 2006, chapter 5.
- Suitable thickeners are polysaccharides (e.g. xanthan gum, carboxymethylcellulose), inorganic clays (organically modified or unmodified), polycarboxylates, and silicates.
- Suitable bactericides are bronopol and isothiazolinone derivatives such as alkylisothiazolinones and benzisothiazolinones.
- Suitable anti-freezing agents are ethylene glycol, propylene glycol, urea and glycerin.
- Suitable anti-foaming agents are silicones, long chain alcohols, and salts of fatty acids.
- Suitable colorants are pigments of low water solubility and water- soluble dyes.
- examples are inorganic colorants (e.g. iron oxide, titan oxide, iron
- tackifiers or binders are polyvinylpyrrolidone, polyvinylacetates, polyvinyl alcohols, polyacrylates, biological or synthetic waxes, and cellulose ethers.
- Water-soluble concentrates (SL, LS) 10-60 wt% of a compostion according to the invention and 5-15 wt% wetting agent (e.g. alcohol alkoxylates) are dissolved in water and/or in a water-soluble solvent (e.g. alcohols) ad 100 wt%.
- the active substance dissolves upon dilution with water.
- composition according to the invention 5-25 wt% of a composition according to the invention and 1 -10 wt% dispersant (e. g.
- polyvinylpyrrolidone are dissolved in organic solvent (e.g. cyclohexanone) ad 100 wt%. Dilution with water gives a dispersion.
- organic solvent e.g. cyclohexanone
- emulsifiers e.g. calcium dodecylbenzenesulfonate and castor oil ethoxylate
- water-insoluble organic solvent e.g. aromatic hydrocarbon
- Emulsions (EW, EO, ES)
- emulsifiers e.g. calcium dodecylbenzenesulfonate and castor oil ethoxylate
- water-insoluble organic solvent e.g. aromatic hydrocarbon
- a composition according to the invention In an agitated ball mill, 20-60 wt% of a composition according to the invention are comminuted with addition of 2-10 wt% dispersants and wetting agents (e.g. sodium lignosulfonate and alcohol ethoxylate), 0,1 -2 wt% thickener (e.g. xanthan gum) and water ad 100 wt% to give a fine active substance suspension. Dilution with water gives a stable suspension of the active substance.
- dispersants and wetting agents e.g. sodium lignosulfonate and alcohol ethoxylate
- 0,1 -2 wt% thickener e.g. xanthan gum
- compositions according to the invention are ground finely with addition of dispersants and wetting agents (e.g. sodium lignosulfonate and alcohol ethoxylate) ad 100 wt% and prepared as water-dispersible or water-soluble granules by means of technical appliances (e. g. extrusion, spray tower, fluidized bed). Dilution with water gives a stable dispersion or solution of the active substance.
- dispersants and wetting agents e.g. sodium lignosulfonate and alcohol ethoxylate
- wt% of a composition according to the invention are ground in a rotor-stator mill with addition of 1 -5 wt% dispersants (e.g. sodium lignosulfonate), 1 -3 wt% wetting agents (e.g. alcohol ethoxylate) and solid carrier (e.g. silica gel) ad 100 wt%. Dilution with water gives a stable dispersion or solution of the active substance.
- dispersants e.g. sodium lignosulfonate
- wetting agents e.g. alcohol ethoxylate
- solid carrier e.g. silica gel
- a composition according to the invention In an agitated ball mill, 5-25 wt% of a composition according to the invention are comminuted with addition of 3-10 wt% dispersants (e.g. sodium lignosulfonate), 1 -5 wt% thickener (e.g. carboxymethylcellulose) and water ad 100 wt% to give a fine suspension of the active substance. Dilution with water gives a stable suspension of the active substance.
- dispersants e.g. sodium lignosulfonate
- 1 -5 wt% thickener e.g. carboxymethylcellulose
- wt% of a composition according to the invention are added to 5-30 wt% organic solvent blend (e.g. fatty acid dimethylamide and cyclohexanone), 10-25 wt% surfactant blend (e.g. alcohol ethoxylate and arylphenol ethoxylate), and water ad 100 %. This mixture is stirred for 1 h to produce spontaneously a thermodynamically stable microemulsion.
- organic solvent blend e.g. fatty acid dimethylamide and cyclohexanone
- surfactant blend e.g. alcohol ethoxylate and arylphenol ethoxylate
- An oil phase comprising 5-50 wt% of a composition according to the invention, 0-40 wt% water insoluble organic solvent (e.g. aromatic hydrocarbon), 2-15 wt% acrylic monomers (e.g.
- methylmethacrylate, methacrylic acid and a di- or triacrylate are dispersed into an aqueous solution of a protective colloid (e.g. polyvinyl alcohol). Radical polymerization initiated by a radical initiator results in the formation of poly(meth)acrylate microcapsules.
- a protective colloid e.g. polyvinyl alcohol.
- Radical polymerization initiated by a radical initiator results in the formation of poly(meth)acrylate microcapsules.
- an oil phase comprising 5-50 wt% of a compound I according to the invention, 0-40 wt% water insoluble organic solvent (e.g. aromatic hydrocarbon), and an isocyanate monomer (e.g.
- diphenylmethene-4,4'-diisocyanate are dispersed into an aqueous solution of a protective colloid (e.g. polyvinyl alcohol).
- a protective colloid e.g. polyvinyl alcohol.
- the addition of a polyamine results in the formation of polyurea microcapsules.
- the monomers amount to 1 -10 wt%.
- the wt% relate to the total CS composition.
- Dustable powders (DP, DS)
- compositions according to the invention are ground finely and mixed intimately with solid carrier (e.g. finely divided kaolin) ad 100 wt%.
- solid carrier e.g. finely divided kaolin
- a composition according to the invention is ground finely and associated with solid carrier (e.g. silicate) ad 100 wt%.
- Granulation is achieved by extrusion, spray-drying or the fluidized bed.
- compositions according to the invention are dissolved in organic solvent (e.g. aromatic hydrocarbon) ad 100 wt%.
- organic solvent e.g. aromatic hydrocarbon
- the agrochemical composition types i) to xiii) may optionally comprise further auxiliaries, such as 0,1 -1 wt% bactericides, 5-15 wt% anti-freezing agents, 0,1 -1 wt% anti-foaming agents, and 0,1 -1 wt% colorants.
- the agrochemical compositions generally comprise between 0.01 and 95%, preferably between 0.1 and 90%, and in particular between 0.5 and 75%, by weight of active substance.
- the active substances are employed in a purity of from 90% to 100%, preferably from 95% to 100% (according to NMR spectrum).
- Solutions for seed treatment (LS), suspoemulsions (SE), flowable concentrates (FS), powders for dry treatment (DS), water-dispersible powders for slurry treatment (WS), water-soluble powders (SS), emulsions (ES), emulsifiable concentrates (EC) and gels (GF) are usually employed for the purposes of treatment of plant propagation materials, particularly seeds.
- the compositions in question give, after two-to-tenfold dilution, active substance concentrations of from 0.01 to 60% by weight, preferably from 0.1 to 40% by weight, in the ready-to-use preparations. Application can be carried out before or during sowing.
- compositions according to the invention onto plant propagation material especially seeds include dressing, coating, pelleting, dusting, soaking and in-furrow application methods of the propagation material.
- they are applied on to the plant propagation material by a method such that germination is not induced, e. g. by seed dressing, pelleting, coating and dusting.
- compositions comprising them as premix or, if appropriate not until immediately prior to use (tank mix).
- These agents can be admixed with the compositions according to the invention in a weight ratio of 1 :100 to 100:1 , preferably 1 :10 to 10:1.
- the user applies the agrochemical composition according to the invention usually from a predosage device, a knapsack sprayer, a spray tank, a spray plane, or an irrigation system.
- the agrochemical composition is made up with water, buffer, and/or further auxiliaries to the desired application concentration and the ready-to-use spray liquor or the agrochemical composition according to the invention is thus obtained.
- 20 to 2000 liters, preferably 50 to 400 liters, of the ready-to-use spray liquor are applied per hectare of agricultural useful area.
- either individual components of the agrochemical composition according to the invention or partially premixed components may be mixed by the user in a spray tank and further auxiliaries and additives may be added, if appropriate.
- individual components of the agrochemical composition according to the invention such as parts of a kit or parts of a binary or ternary mixture may be mixed by the user himself in a spray tank and further auxiliaries may be added, if appropriate.
- the isoxazolo[5,4-b]pyridines of the formulae I. A, I.B or I.C (component A) and the at least one further herbicide of the formulae 11.1 or II.2 (component B) can be formulated and applied jointly or separately, simultaneously or in succession, before, during or after the emergence of the plants. In case of separate application, the order of the application of the components A and B is of minor importance. It is important that the at least one isoxazolo[5,4-b]pyridine of the formula I.A, I.B or I.C and the at least one further herbicide of the formulae 11.1 or II.2 are present simultaneously at the site of action, i.e. are at the same time in contact with or taken up by the plant to be controlled.
- compositions according to the invention are suitable as herbicides. They are suitable as such or as an appropriately formulated composition (agrochemical composition).
- compositions control vegetation on non-crop areas very efficiently, especially at high rates of application. They act against broad-leafed weeds and grass weeds in crops such as wheat, rice, corn, soybeans and cotton without causing any significant damage to the crop plants. This effect is mainly observed at low rates of application.
- the compositions according to the invention are applied to the plants mainly by spraying the leaves.
- the application can be carried out using, for example, water as carrier by customary spraying techniques using spray liquor amounts of from about 100 to 1000 l/ha (for example from 300 to 400 l/ha).
- the herbicidal compositions may also be applied by the low-volume or the ultra-low-volume method, or in the form of microgranules.
- herbicidal compositions according to the present invention can be done before, during and/or after, preferably during and/or after, the emergence of the undesirable plants.
- the herbicidal compositions according to the present invention can be applied pre- or post-emergence. If the active components A and B, and, if appropriate, C and/or D, are less well tolerated by certain crop plants, application techniques may be used in which the herbicidal compositions are sprayed, with the aid of the spraying equipment, in such a way that as far as possible they do not come into contact with the leaves of the sensitive crop plants, while the active compounds reach the leaves of undesirable plants growing underneath, or the bare soil surface (post-directed, lay-by).
- compositions of the present invention on their own or jointly in combination with other crop protection agents, for example with agents for controlling pests or phytopathogenic fungi or bacteria or with groups of active compounds which regulate growth.
- other crop protection agents for example with agents for controlling pests or phytopathogenic fungi or bacteria or with groups of active compounds which regulate growth.
- miscibility with mineral salt solutions which are employed for treating nutritional and trace element deficiencies.
- Non-phytotoxic oils and oil concentrates can also be added.
- the amounts of active substances applied i.e. components A and B, and, if appropriate, safeners C and/or further herbicides D, without formulation auxiliaries, are, depending on the kind of effect desired, from 0.001 to 3 kg/ha, preferably from 0.005 to 2.5 kg/ha and in particular from 0.01 to 2 kg/ha of active substance (a.s.).
- the application rates of the isoxazolo[5,4- b]pyridine of formula I .A, I.B or I.C are in the range from 0.1 g/ha to 5000 g/ha and preferably in the range from 1 g/ha to 2500 g/ha, from 5 g/ha to 2000 g/ha, from 10 to 750 g/ha, more preferably from 50 to 500 g/ha.
- the required application rates of herbicides B are generally in the range of from 0.5 to 2500 g/ha and preferably in the range of from 5 to 2000 g/ha, from 100 to 1500 g/h, most preferably from 100 to 500 g/ha of a.s..
- the required application rates of safeners C are generally in the range of from 0.5 to 2500 g/ha and preferably in the range of from 5 to 2000 g/ha or 10 to 1000 g/ha of a.s..
- compositions can be employed in a number of crop plants for eliminating undesirable plants.
- suitable crops are the following: Allium cepa, Ananas comosus, Arachis hypogaea, Asparagus officinalis, Avena sativa, Beta vulgaris spec, altissima, Beta vulgaris spec, rapa, Brassica napus var. napus, Brassica napus var. napobrassica, Brassica rapa var.
- silvestris Brassica oleracea, Brassica nigra, Camellia sinensis, Carthamus tinctorius, Carya illinoinensis, Citrus limon, Citrus sinensis, Coffea arabica (Coffea canephora, Coffea liberica), Cucumis sativus, Cynodon dactylon, Daucus carota, Elaeis guineensis, Fragaria vesca, Glycine max, Gossypium hirsutum,
- Hevea brasiliensis Hordeum vulgare, Humulus lupulus, Ipomoea batatas, Juglans regia, Lens culinaris, Linum usitatissimum, Lycopersicon lycopersicum, Malus spec, Manihot esculenta, Medicago sativa, Musa spec, Nicotiana tabacum (N.rustica), Olea europaea, Oryza sativa, Phaseolus lunatus, Phaseolus vulgaris, Picea abies, Pinus spec, Pistacia vera, Pisum sativum, Prunus avium, Prunus persica, Pyrus communis, Prunus armeniaca, Prunus cerasus, Prunus dulcis and prunus domestica, Ribes sylvestre, Ricinus communis, Saccharum officinarum, Secale cereale, Sinapis alba, Solanum tuberosum, S
- Preferred crops are Arachis hypogaea, Beta vulgaris spec, altissima, Brassica napus var.
- Especially preferred crops are crops of cereals, corn, soybeans, rice, millets, oilseed rape, cotton, sugarcane, potatoes, legumes, turf or permanent crops.
- compositions according to the invention can also be used in genetically modified plants.
- genetically modified plants is to be understood as plants whose genetic material has been modified by the use of recombinant DNA techniques to include an inserted sequence of DNA that is not native to that plant species' genome or to exhibit a deletion of DNA that was native to that species' genome, wherein the modification(s) cannot readily be obtained by cross breeding, mutagenesis or natural recombination alone.
- a particular genetically modified plant will be one that has obtained its genetic modification(s) by inheritance through a natural breeding or propagation process from an ancestral plant whose genome was the one directly treated by use of a recombinant DNA technique.
- one or more genes have been integrated into the genetic material of a genetically modified plant in order to improve certain properties of the plant.
- Such genetic modifications also include but are not limited to targeted post-translational modification of protein(s), oligo- or polypeptides, e. g., by inclusion therein of amino acid mutation(s) that permit, decrease, or promote glycosylation or polymer additions such as prenylation, acetylation farnesylation, or PEG moiety attachment.
- auxinic herbicides such as
- herbicides as a result of conventional methods of breeding or genetic engineering; furthermore, plants have been made resistant to multiple classes of herbicides through multiple genetic modifications, such as resistance to both glyphosate and glufosinate or to both glyphosate and a herbicide from another class such as ALS inhibitors, HPPD inhibitors, auxinic herbicides, or ACCase inhibitors.
- RoundupReady® (glyphosate tolerant, Monsanto, USA), Cultivance® (imidazolinone tolerant, BASF SE, Germany) and LibertyLink® (glufosinate tolerant, Bayer CropScience, Germany).
- plants are also covered that are by the use of recombinant DNA techniques capable to synthesize one or more insecticidal proteins, especially those known from the bacterial genus Bacillus, particularly from Bacillus thuringiensis, such as delta-endotoxins, e.
- VIP vegetative insecticidal proteins
- VIP1 e.g., VIP1 , VIP2, VIP3 or VIP3A
- insecticidal proteins of bacteria colonizing nematodes e. g., Photorhabdus spp.
- toxins produced by animals such as scorpion toxins, arachnid toxins, wasp toxins, or other insect-specific neurotoxins
- toxins produced by fungi such as Streptomycetes toxins, plant lectins, such as pea or barley lectins; agglutinins
- proteinase inhibitors such as trypsin inhibitors, serine protease inhibitors, patatin, cystatin or papain inhibitors
- ribosome-inactivating proteins (RIP) such as ricin, maize-RIP, abrin, luffin, saporin or bryodin
- steroid metabolism enzymes such as 3- hydroxy-steroid oxidase, ecdysteroid-IDP-glycosyl-transferase, cholesterol oxidases, ecdysone inhibitors or HMG-CoA-reductase
- ion channel blockers such as blockers of sodium
- these insecticidal proteins or toxins are to be understood expressly also as including pre-toxins, hybrid proteins, truncated or otherwise modified proteins.
- Hybrid proteins are characterized by a new combination of protein domains, (see, e. g., WO 02/015701 ).
- Further examples of such toxins or genetically modified plants capable of synthesizing such toxins are disclosed, e. g., in EP-A 374 753, WO 93/007278, WO 95/34656, EP-A 427 529, EP-A 451 878, WO 03/18810 und WO 03/52073.
- Plants capable to synthesize one or more insecticidal proteins are, e. g., described in the publications mentioned above, and some of which are commercially available such as YieldGard® (corn cultivars producing the CrylAb toxin), YieldGard® Plus (corn cultivars producing CrylAb and Cry3Bb1 toxins),
- Starlink® corn cultivars producing the Cry9c toxin
- Herculex® RW corn cultivars producing Cry34Ab1 , Cry35Ab1 and the enzyme Phosphinothricin-N-Acetyltransferase [PAT]
- NuCOTN® 33B cotton cultivars producing the CrylAc toxin
- Bollgard® I cotton cultivars producing the CrylAc toxin
- Bollgard® II cotton cultivars producing CrylAc and Cry2Ab2 toxins
- VIPCOT® cotton cultivars producing a VIP-toxin
- NewLeaf® potato cultivars producing the Cry3A toxin
- Bt-Xtra® NatureGard®, KnockOut®, BiteGard®, Protecta®, Bt1 1 (e.
- plants are also covered that are by the use of recombinant DNA techniques capable to synthesize one or more proteins to increase the resistance or tolerance of those plants to bacterial, viral or fungal pathogens. Examples of such proteins are the so-called
- pathogenesis-related proteins PR proteins, see, e.g., EP-A 392 225
- plant disease resistance genes e. g., potato culti-vars, which express resistance genes acting against Phytophthora infestans derived from the Mexican wild potato, Solanum bulbocastanum
- T4-lyso-zym e.g., potato cultivars capable of synthesizing these proteins with increased resistance against bacteria such as Erwinia amylovora.
- the methods for producing such genetically modified plants are generally known to the person skilled in the art and are described, e.g., in the publications mentioned above.
- plants are also covered that are by the use of recombinant DNA techniques capable to synthesize one or more proteins to increase the productivity (e.g., bio-mass production, grain yield, starch content, oil content or protein content), tolerance to drought, salinity or other growth-limiting environmental factors or tolerance to pests and fungal, bacterial or viral pathogens of those plants.
- productivity e.g., bio-mass production, grain yield, starch content, oil content or protein content
- tolerance to drought e.g., salinity or other growth-limiting environmental factors or tolerance to pests and fungal, bacterial or viral pathogens of those plants.
- plants are also covered that contain by the use of recombinant DNA techniques a modified amount of ingredients or new ingredients, specifically to improve human or animal nutrition, e. g., oil crops that produce health-promoting long-chain omega-3 fatty acids or unsaturated omega-9 fatty acids (e. g., Nexera® rape, Dow AgroSciences, Canada).
- a modified amount of ingredients or new ingredients specifically to improve human or animal nutrition, e. g., oil crops that produce health-promoting long-chain omega-3 fatty acids or unsaturated omega-9 fatty acids (e. g., Nexera® rape, Dow AgroSciences, Canada).
- plants are also covered that contain by the use of recombinant DNA techniques a modified amount of ingredients or new ingredients, specifically to improve raw material production, e.g., potatoes that produce increased amounts of amylopectin (e.g. Amflora® potato, BASF SE, Germany).
- a modified amount of ingredients or new ingredients specifically to improve raw material production, e.g., potatoes that produce increased amounts of amylopectin (e.g. Amflora® potato, BASF SE, Germany).
- compositions according to the invention are also suitable for the defoliation and/or desiccation of plant parts, for which crop plants such as cotton, potato, oilseed rape, sunflower, soybean or field beans, in particular cotton, are suitable.
- crop plants such as cotton, potato, oilseed rape, sunflower, soybean or field beans, in particular cotton
- compositions have been found for the desiccation and/or defoliation of plants, processes for preparing these compositions, and methods for desiccating and/or defoliating plants using the compositions according to the invention.
- compositions according to the invention are suitable in particular for desiccating the above-ground parts of crop plants such as potato, oilseed rape, sunflower and soybean, but also cereals. This makes possible the fully mechanical harvesting of these important crop plants.
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Abstract
La présente invention concerne des compositions herbicides comprenant au moins un herbicide de type isoxazolo [5,4-b]pyridine I.A, I.B ou I.C, ou un N-oxyde, ou un sel utile en agriculture de celui-ci, et au moins un autre composé choisi parmi des composés présentant une activité herbicide de formule II.1 et II.2, ou un N-oxyde, ou un sel utile en agriculture de celui-ci, et, si souhaité, un phytoprotecteur C ou au moins un autre herbicide D. La présente invention concerne également l'utilisation d'une telle composition pour lutter contre la végétation indésirable et un procédé de lutte contre la végétation indésirable, qui consiste à permettre à une composition d'agir sur des plantes, leurs graines et/ou leur habitat.
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
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US11185075B2 (en) | 2016-12-16 | 2021-11-30 | Basf Se | Herbicidal phenyltriazolinones |
WO2021240489A3 (fr) * | 2020-05-29 | 2022-01-06 | Best Agrolife Limited | Composition herbicide synergique |
US12133529B2 (en) | 2017-11-23 | 2024-11-05 | Basf Se | Herbicidal phenylethers |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US11185075B2 (en) | 2016-12-16 | 2021-11-30 | Basf Se | Herbicidal phenyltriazolinones |
US12133529B2 (en) | 2017-11-23 | 2024-11-05 | Basf Se | Herbicidal phenylethers |
WO2021240489A3 (fr) * | 2020-05-29 | 2022-01-06 | Best Agrolife Limited | Composition herbicide synergique |
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