+

WO2018191997A1 - High temperature resistant release agent and preparation method therefor - Google Patents

High temperature resistant release agent and preparation method therefor Download PDF

Info

Publication number
WO2018191997A1
WO2018191997A1 PCT/CN2017/081854 CN2017081854W WO2018191997A1 WO 2018191997 A1 WO2018191997 A1 WO 2018191997A1 CN 2017081854 W CN2017081854 W CN 2017081854W WO 2018191997 A1 WO2018191997 A1 WO 2018191997A1
Authority
WO
WIPO (PCT)
Prior art keywords
parts
release agent
add
high temperature
temperature resistant
Prior art date
Application number
PCT/CN2017/081854
Other languages
French (fr)
Chinese (zh)
Inventor
黄春华
Original Assignee
黄春华
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 黄春华 filed Critical 黄春华
Publication of WO2018191997A1 publication Critical patent/WO2018191997A1/en

Links

Classifications

    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L9/00Disinfection, sterilisation or deodorisation of air
    • A61L9/01Deodorant compositions
    • A61L9/014Deodorant compositions containing sorbent material, e.g. activated carbon
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L9/00Disinfection, sterilisation or deodorisation of air
    • A61L9/01Deodorant compositions
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L9/00Disinfection, sterilisation or deodorisation of air
    • A61L9/01Deodorant compositions
    • A61L9/013Deodorant compositions containing animal or plant extracts, or vegetable material
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L2209/00Aspects relating to disinfection, sterilisation or deodorisation of air
    • A61L2209/20Method-related aspects
    • A61L2209/21Use of chemical compounds for treating air or the like
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L2209/00Aspects relating to disinfection, sterilisation or deodorisation of air
    • A61L2209/20Method-related aspects
    • A61L2209/22Treatment by sorption, e.g. absorption, adsorption, chemisorption, scrubbing, wet cleaning

Definitions

  • the invention relates to an adhesive, in particular to a high temperature resistant release agent and a preparation method thereof.
  • An object of the present invention is to provide a high temperature resistant release agent and a method of preparing the same, which solves one or more of the above prior art problems.
  • a high temperature resistant release agent comprising 45-185 parts of low molecular weight polyisobutylene, 34-84 parts of oxalic acid, 18-49 parts of emulsifier, 14-22 parts of catalyst, deionized by weight. 400-900 parts of water, 1-8 parts of ethylenediaminetetraacetic acid, 25-75 parts of silicone rubber, 5-17 parts of antifreeze and 12-32 parts of polyalkylene glycol, and 33-88 parts of hydroxyphenylethyl ester.
  • the emulsifier is a fatty alcohol polyoxyethylene ether or a fatty acid glyceride.
  • the catalyst is dodecylbenzenesulfonic acid, aluminum sulfate, or sodium silicate.
  • the antifreeze is ethylene glycol or glycerol.
  • the invention also provides a preparation method of the above-mentioned high temperature resistant release agent, comprising the following steps:
  • Step 1 Add low molecular weight polyisobutylene, oxalic acid, polyalkylene glycol, ethylenediaminetetraacetic acid, silicone rubber and 1/2 deionized water to the homogenizer, and then add 1/2 of the catalyst to adjust the pH. Value to 5-7, then add 1/2 emulsifier, at a speed of 3000r / min, pressure of 40-80mPa, homogenization 20-80min, to make a homogeneous preform emulsion;
  • Step 2 Add the remaining deionized water, emulsifier and catalyst to the reaction kettle, heat to 70-80 ° C, then add antifreeze, hydroxyphenyl ethyl ester and homogeneous preform emulsion, add time 2h, heat preservation 3- 6h, and then cooled to 40 ° C, the finished product.
  • the release agent of the invention can prolong the service life of the template, is convenient for cleaning, has good surface smoothness and greatly reduces the cost.
  • the emulsifier is a fatty alcohol polyoxyethylene ether
  • the catalyst is dodecylbenzenesulfonic acid
  • the antifreeze is ethylene glycol
  • the preparation method of the high temperature resistant release agent of the invention comprises the following steps:
  • Step 1 Add low molecular weight polyisobutylene, oxalic acid, polyalkylene glycol, ethylenediaminetetraacetic acid, silicone rubber and 1/2 deionized water to the homogenizer, and then add 1/2 of the catalyst to adjust the pH. Value to 5-7, then add 1/2 emulsifier, at a speed of 3000r / min, pressure of 40-80mPa, homogenization 20-80min, to make a homogeneous preform emulsion;
  • Step 2 Add the remaining deionized water, emulsifier and catalyst to the reaction kettle, heat to 70-80 ° C, then add antifreeze, hydroxyphenyl ethyl ester and homogeneous preform emulsion, add time 2h, heat preservation 3- 6h, and then cooled to 40 ° C, the finished product.
  • the release agent is applied on the inside of the template, and the dosage per square meter is about 0.2 kg.
  • the concrete is poured according to the normal construction procedure and demolished by the age. Tap the template, the template is separated from the concrete, the concrete surface is smooth, dense, washed with water, and can be easily washed away.
  • the emulsifier is a fatty acid glyceride
  • the catalyst is aluminum sulfate
  • the antifreeze is glycerin.
  • the preparation method of the high temperature resistant release agent of the invention comprises the following steps:
  • Step 1 Add low molecular weight polyisobutylene, oxalic acid, polyalkylene glycol, ethylenediaminetetraacetic acid, silicone rubber and 1/2 deionized water to the homogenizer, and then add 1/2 of the catalyst to adjust the pH. Value to 5-7, then add 1/2 emulsifier, at a speed of 3000r / min, pressure of 40-80mPa, homogenization 20-80min, to make a homogeneous preform emulsion;
  • Step 2 Add the remaining deionized water, emulsifier and catalyst to the reaction kettle, heat to 70-80 ° C, then add antifreeze, hydroxyphenyl ethyl ester and homogeneous preform emulsion, add time 2h, heat preservation 3- 6h, and then cooled to 40 ° C, the finished product.
  • the release agent is applied on the inside of the template, and the dosage per square meter is about 0.2 kg.
  • the concrete is poured according to the normal construction procedure and demolished by the age. Tap the template, the template is separated from the concrete, the concrete surface is smooth, dense, washed with water, and can be easily washed away.
  • the emulsifier is a fatty acid glyceride
  • the catalyst is sodium silicate
  • the antifreeze is glycerin.
  • the preparation method of the high temperature resistant release agent of the invention comprises the following steps:
  • Step 1 Add low molecular weight polyisobutylene, oxalic acid, polyalkylene glycol, ethylenediaminetetraacetic acid, silicone rubber and 1/2 deionized water to the homogenizer, and then add 1/2 of the catalyst to adjust the pH. Value to 5-7, then add 1/2 emulsifier, at a speed of 3000r / min, pressure of 40-80mPa, homogenization 20-80min, to make a homogeneous preform emulsion;
  • Step 2 Add the remaining deionized water, emulsifier and catalyst to the reaction kettle, heat to 70-80 ° C, then add antifreeze, hydroxyphenyl ethyl ester and homogeneous preform emulsion, add time 2h, heat preservation 3- 6h, and then cooled to 40 ° C, the finished product.
  • the release agent is applied on the inside of the template, and the dosage per square meter is about 0.2 kg.
  • the concrete is poured according to the normal construction procedure and demolished by the age. Tap the template, the template is separated from the concrete, the concrete surface is smooth, dense, washed with water, and can be easily washed away.

Landscapes

  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Epidemiology (AREA)
  • General Health & Medical Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Botany (AREA)
  • Zoology (AREA)
  • Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Aftertreatments Of Artificial And Natural Stones (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)
  • Detergent Compositions (AREA)
  • Fertilizers (AREA)

Abstract

A high temperature resistant release agent and a preparation method therefor. The high temperature resistant release agent comprises, in parts by weight, 45-185 parts of a low molecular weight polyisobutylene, 34-84 parts of oxalic acid, 18-49 parts of an emulsifier, 14-22 parts of a catalyst, 400-900 parts of deionized water, 1-8 parts of ethylenediamine tetraacetic acid, 25-75 parts of a silicone rubber, 5-17 parts of an antifreezing agent, 12-32 parts of polyalkylene glycol, and 33-88 parts of hydroxyphenyl ethyl ester. In this way, a mold can have a prolonged service life, is easy to clean, and has good surface smoothness, greatly reducing the cost.

Description

一种耐高温脱模剂及其制备方法High temperature resistant release agent and preparation method thereof 技术领域Technical field
本发明涉及胶黏剂,尤其涉及一种耐高温脱模剂及其制备方法。The invention relates to an adhesive, in particular to a high temperature resistant release agent and a preparation method thereof.
背景技术Background technique
在混凝土浇注中,制品如果与模板相粘,不仅损坏制品表面光度,而且造成拆模困难,费时费力,加大建筑成本。因此脱模剂的使用在混凝土施工中至关重要。In the concrete pouring, if the product is adhered to the template, it not only damages the surface luminosity of the product, but also causes difficulty in demoulding, time-consuming and laborious, and increases construction cost. Therefore, the use of release agents is crucial in concrete construction.
为了满足装配式钢筋混凝土浇注的需要和外露构件及装饰面对混凝土外表的要求,应用脱模剂是比较普遍的,多采用化工原料配制,存在成本高,脱模效果差,不易清洗。In order to meet the requirements of prefabricated reinforced concrete pouring and the requirements of exposed components and decorative surfaces facing concrete, the application of release agents is more common, and more chemical raw materials are used for preparation, which has high cost, poor demolding effect and is difficult to clean.
发明内容Summary of the invention
本发明的目的提供一种耐高温脱模剂及其制备方法,解决上述现有技术问题中的一个或者多个。SUMMARY OF THE INVENTION An object of the present invention is to provide a high temperature resistant release agent and a method of preparing the same, which solves one or more of the above prior art problems.
根据本发明的一个方面,提供一种耐高温脱模剂,按重量份包括低分子聚异丁烯45-185份、草酸34-84份、乳化剂18-49份、催化剂14-22份、去离子水400-900份、乙二胺四乙酸1-8份、硅橡胶25-75份、防冻剂5-17份和聚亚烷基二醇12-32份,羟苯乙酯33-88份。According to one aspect of the present invention, there is provided a high temperature resistant release agent comprising 45-185 parts of low molecular weight polyisobutylene, 34-84 parts of oxalic acid, 18-49 parts of emulsifier, 14-22 parts of catalyst, deionized by weight. 400-900 parts of water, 1-8 parts of ethylenediaminetetraacetic acid, 25-75 parts of silicone rubber, 5-17 parts of antifreeze and 12-32 parts of polyalkylene glycol, and 33-88 parts of hydroxyphenylethyl ester.
在一些实施方式中:乳化剂为脂肪醇聚氧乙烯醚或脂肪酸甘油酯。In some embodiments: the emulsifier is a fatty alcohol polyoxyethylene ether or a fatty acid glyceride.
在一些实施方式中:催化剂为十二烷基苯磺酸、硫酸铝或硅酸钠。In some embodiments: the catalyst is dodecylbenzenesulfonic acid, aluminum sulfate, or sodium silicate.
在一些实施方式中:防冻剂为乙二醇或甘油。In some embodiments: the antifreeze is ethylene glycol or glycerol.
本发明还提供了上述的一种耐高温脱模剂的制备方法,包括以下步骤:The invention also provides a preparation method of the above-mentioned high temperature resistant release agent, comprising the following steps:
步骤一:在均质机中加入低分子聚异丁烯、草酸、聚亚烷基二醇、乙二胺四乙酸、硅橡胶和1/2的去离子水,再投入1/2的催化剂,调节pH值至5-7,然后加入1/2的乳化剂,在速度为3000r/min,压力为40-80mPa的条件下,均质20-80min,制成均质预制体乳液;Step 1: Add low molecular weight polyisobutylene, oxalic acid, polyalkylene glycol, ethylenediaminetetraacetic acid, silicone rubber and 1/2 deionized water to the homogenizer, and then add 1/2 of the catalyst to adjust the pH. Value to 5-7, then add 1/2 emulsifier, at a speed of 3000r / min, pressure of 40-80mPa, homogenization 20-80min, to make a homogeneous preform emulsion;
步骤二:在反应釜中加入剩余的去离子水、乳化剂和催化剂,升温至70-80℃,再加入防冻剂、羟苯乙酯和均质预制体乳液,加入时间为2h,保温3-6h,再冷却至40℃,即得成品。Step 2: Add the remaining deionized water, emulsifier and catalyst to the reaction kettle, heat to 70-80 ° C, then add antifreeze, hydroxyphenyl ethyl ester and homogeneous preform emulsion, add time 2h, heat preservation 3- 6h, and then cooled to 40 ° C, the finished product.
本发明的脱模剂能够延长模板的使用寿命,方便清洗,其表面光洁度好,较大的降低了成本。 The release agent of the invention can prolong the service life of the template, is convenient for cleaning, has good surface smoothness and greatly reduces the cost.
具体实施方式detailed description
下面通过实施例对本发明作进一步详细说明。The invention will now be further described in detail by way of examples.
实施例1:Example 1:
按重量份包括低分子聚异丁烯45份、草酸34份、乳化剂18份、催化剂14份、去离子水400份、乙二胺四乙酸1份、硅橡胶25份、防冻剂5份和聚亚烷基二醇12份,羟苯乙酯33份。In parts by weight, including 45 parts of low molecular weight polyisobutylene, 34 parts of oxalic acid, 18 parts of emulsifier, 14 parts of catalyst, 400 parts of deionized water, 1 part of ethylenediaminetetraacetic acid, 25 parts of silicone rubber, 5 parts of antifreeze and poly Asia 12 parts of alkyl diol and 33 parts of hydroxyphenyl ester.
其中,乳化剂为脂肪醇聚氧乙烯醚,催化剂为十二烷基苯磺酸,防冻剂为乙二醇。Wherein, the emulsifier is a fatty alcohol polyoxyethylene ether, the catalyst is dodecylbenzenesulfonic acid, and the antifreeze is ethylene glycol.
本发明耐高温脱模剂的制备方法:包括以下步骤:The preparation method of the high temperature resistant release agent of the invention comprises the following steps:
步骤一:在均质机中加入低分子聚异丁烯、草酸、聚亚烷基二醇、乙二胺四乙酸、硅橡胶和1/2的去离子水,再投入1/2的催化剂,调节pH值至5-7,然后加入1/2的乳化剂,在速度为3000r/min,压力为40-80mPa的条件下,均质20-80min,制成均质预制体乳液;Step 1: Add low molecular weight polyisobutylene, oxalic acid, polyalkylene glycol, ethylenediaminetetraacetic acid, silicone rubber and 1/2 deionized water to the homogenizer, and then add 1/2 of the catalyst to adjust the pH. Value to 5-7, then add 1/2 emulsifier, at a speed of 3000r / min, pressure of 40-80mPa, homogenization 20-80min, to make a homogeneous preform emulsion;
步骤二:在反应釜中加入剩余的去离子水、乳化剂和催化剂,升温至70-80℃,再加入防冻剂、羟苯乙酯和均质预制体乳液,加入时间为2h,保温3-6h,再冷却至40℃,即得成品。Step 2: Add the remaining deionized water, emulsifier and catalyst to the reaction kettle, heat to 70-80 ° C, then add antifreeze, hydroxyphenyl ethyl ester and homogeneous preform emulsion, add time 2h, heat preservation 3- 6h, and then cooled to 40 ° C, the finished product.
混凝土工程施工,在支好模板后,在模板内侧涂刷本脱模剂,每平方米用量约为0.2kg。按正常施工程序浇注混凝土,到龄期拆模。轻敲模板,模板即与混凝土脱离,混凝土表面光滑、密实,用水清洗,能够轻易洗去。For concrete construction, after the template is supported, the release agent is applied on the inside of the template, and the dosage per square meter is about 0.2 kg. The concrete is poured according to the normal construction procedure and demolished by the age. Tap the template, the template is separated from the concrete, the concrete surface is smooth, dense, washed with water, and can be easily washed away.
实施例2:Example 2:
按重量份包括低分子聚异丁烯85份、草酸64份、乳化剂28份、催化剂17份、去离子水700份、乙二胺四乙酸5份、硅橡胶55份、防冻剂12份和聚亚烷基二醇24份,羟苯乙52份。In parts by weight, 85 parts of low molecular weight polyisobutylene, 64 parts of oxalic acid, 28 parts of emulsifier, 17 parts of catalyst, 700 parts of deionized water, 5 parts of ethylenediaminetetraacetic acid, 55 parts of silicone rubber, 12 parts of antifreeze and poly Asia 24 parts of alkyl diol and 52 parts of hydroxybenzene.
其中,乳化剂为脂肪酸甘油酯,催化剂为硫酸铝,防冻剂为甘油。Wherein, the emulsifier is a fatty acid glyceride, the catalyst is aluminum sulfate, and the antifreeze is glycerin.
本发明耐高温脱模剂的制备方法:包括以下步骤:The preparation method of the high temperature resistant release agent of the invention comprises the following steps:
步骤一:在均质机中加入低分子聚异丁烯、草酸、聚亚烷基二醇、乙二胺四乙酸、硅橡胶和1/2的去离子水,再投入1/2的催化剂,调节pH值至5-7,然后加入1/2的乳化剂,在速度为3000r/min,压力为40-80mPa的条件下,均质20-80min,制成均质预制体乳液;Step 1: Add low molecular weight polyisobutylene, oxalic acid, polyalkylene glycol, ethylenediaminetetraacetic acid, silicone rubber and 1/2 deionized water to the homogenizer, and then add 1/2 of the catalyst to adjust the pH. Value to 5-7, then add 1/2 emulsifier, at a speed of 3000r / min, pressure of 40-80mPa, homogenization 20-80min, to make a homogeneous preform emulsion;
步骤二:在反应釜中加入剩余的去离子水、乳化剂和催化剂,升温至70-80℃,再加入防冻剂、羟苯乙酯和均质预制体乳液,加入时间为2h,保温3-6h,再冷却至40℃,即得成品。Step 2: Add the remaining deionized water, emulsifier and catalyst to the reaction kettle, heat to 70-80 ° C, then add antifreeze, hydroxyphenyl ethyl ester and homogeneous preform emulsion, add time 2h, heat preservation 3- 6h, and then cooled to 40 ° C, the finished product.
混凝土工程施工,在支好模板后,在模板内侧涂刷本脱模剂,每平方米用量约为0.2kg。按正常施工程序浇注混凝土,到龄期拆模。轻敲模板,模板即与混凝土脱离,混凝土表面光滑、密实,用水清洗,能够轻易洗去。 For concrete construction, after the template is supported, the release agent is applied on the inside of the template, and the dosage per square meter is about 0.2 kg. The concrete is poured according to the normal construction procedure and demolished by the age. Tap the template, the template is separated from the concrete, the concrete surface is smooth, dense, washed with water, and can be easily washed away.
实施例3:Example 3:
按重量份包括低分子聚异丁烯185份、草酸84份、乳化剂49份、催化剂22份、去离子水900份、乙二胺四乙酸8份、硅橡胶75份、防冻剂17份和聚亚烷基二醇32份,羟苯乙酯88份。In parts by weight, 185 parts of low molecular weight polyisobutylene, 84 parts of oxalic acid, 49 parts of emulsifier, 22 parts of catalyst, 900 parts of deionized water, 8 parts of ethylenediaminetetraacetic acid, 75 parts of silicone rubber, 17 parts of antifreeze and poly Asia 32 parts of alkyl diol and 88 parts of hydroxyphenylethyl ester.
其中,乳化剂为脂肪酸甘油酯,催化剂为硅酸钠,防冻剂为甘油。Wherein, the emulsifier is a fatty acid glyceride, the catalyst is sodium silicate, and the antifreeze is glycerin.
本发明耐高温脱模剂的制备方法:包括以下步骤:The preparation method of the high temperature resistant release agent of the invention comprises the following steps:
步骤一:在均质机中加入低分子聚异丁烯、草酸、聚亚烷基二醇、乙二胺四乙酸、硅橡胶和1/2的去离子水,再投入1/2的催化剂,调节pH值至5-7,然后加入1/2的乳化剂,在速度为3000r/min,压力为40-80mPa的条件下,均质20-80min,制成均质预制体乳液;Step 1: Add low molecular weight polyisobutylene, oxalic acid, polyalkylene glycol, ethylenediaminetetraacetic acid, silicone rubber and 1/2 deionized water to the homogenizer, and then add 1/2 of the catalyst to adjust the pH. Value to 5-7, then add 1/2 emulsifier, at a speed of 3000r / min, pressure of 40-80mPa, homogenization 20-80min, to make a homogeneous preform emulsion;
步骤二:在反应釜中加入剩余的去离子水、乳化剂和催化剂,升温至70-80℃,再加入防冻剂、羟苯乙酯和均质预制体乳液,加入时间为2h,保温3-6h,再冷却至40℃,即得成品。Step 2: Add the remaining deionized water, emulsifier and catalyst to the reaction kettle, heat to 70-80 ° C, then add antifreeze, hydroxyphenyl ethyl ester and homogeneous preform emulsion, add time 2h, heat preservation 3- 6h, and then cooled to 40 ° C, the finished product.
混凝土工程施工,在支好模板后,在模板内侧涂刷本脱模剂,每平方米用量约为0.2kg。按正常施工程序浇注混凝土,到龄期拆模。轻敲模板,模板即与混凝土脱离,混凝土表面光滑、密实,用水清洗,能够轻易洗去。For concrete construction, after the template is supported, the release agent is applied on the inside of the template, and the dosage per square meter is about 0.2 kg. The concrete is poured according to the normal construction procedure and demolished by the age. Tap the template, the template is separated from the concrete, the concrete surface is smooth, dense, washed with water, and can be easily washed away.
以上所述仅是本发明的一种实施方式,应当指出,对于本领域普通技术人员来说,在不脱离本发明创造构思的前提下,还可以做出若干相似的变形和改进,这些也应视为本发明的保护范围之内。 The above is only one embodiment of the present invention, and it should be noted that some similar variations and modifications may be made by those skilled in the art without departing from the inventive concept. It is considered to be within the scope of protection of the present invention.

Claims (5)

  1. 一种耐高温脱模剂,其特征在于:按重量份包括低分子聚异丁烯45-185份、草酸34-84份、乳化剂18-49份、催化剂14-22份、去离子水400-900份、乙二胺四乙酸1-8份、硅橡胶25-75份、防冻剂5-17份和聚亚烷基二醇12-32份,羟苯乙酯33-88份。A high temperature resistant mold release agent characterized by comprising 45-185 parts of low molecular weight polyisobutylene, 34-84 parts of oxalic acid, 18-49 parts of emulsifier, 14-22 parts of catalyst, and 400-900 of deionized water in parts by weight. Parts, 1-8 parts of ethylenediaminetetraacetic acid, 25-75 parts of silicone rubber, 5-17 parts of antifreeze and 12-32 parts of polyalkylene glycol, and 33-88 parts of hydroxyphenylethyl ester.
  2. 根据权利要求1所述的一种耐高温脱模剂,其特征在于:所述乳化剂为脂肪醇聚氧乙烯醚或脂肪酸甘油酯。A high temperature resistant release agent according to claim 1, wherein the emulsifier is a fatty alcohol polyoxyethylene ether or a fatty acid glyceride.
  3. 根据权利要求1所述的一种耐高温脱模剂,其特征在于:所述催化剂为十二烷基苯磺酸、硫酸铝或硅酸钠。A high temperature resistant release agent according to claim 1, wherein the catalyst is dodecylbenzenesulfonic acid, aluminum sulfate or sodium silicate.
  4. 根据权利要求1所述的一种耐高温脱模剂,其特征在于:所述防冻剂为乙二醇或甘油。A high temperature resistant release agent according to claim 1, wherein the antifreeze agent is ethylene glycol or glycerin.
  5. 一种制备权利要求1-4任一项所述耐高温脱模剂的方法,其特征在于,包括以下步骤:A method for preparing the high temperature release agent according to any one of claims 1 to 4, comprising the steps of:
    步骤一:在均质机中加入低分子聚异丁烯、草酸、聚亚烷基二醇、乙二胺四乙酸、硅橡胶和1/2的去离子水,再投入1/2的催化剂,调节pH值至5-7,然后加入1/2的乳化剂,在速度为3000r/min,压力为40-80mPa的条件下,均质20-80min,制成均质预制体乳液;Step 1: Add low molecular weight polyisobutylene, oxalic acid, polyalkylene glycol, ethylenediaminetetraacetic acid, silicone rubber and 1/2 deionized water to the homogenizer, and then add 1/2 of the catalyst to adjust the pH. Value to 5-7, then add 1/2 emulsifier, at a speed of 3000r / min, pressure of 40-80mPa, homogenization 20-80min, to make a homogeneous preform emulsion;
    步骤二:在反应釜中加入剩余的去离子水、乳化剂和催化剂,升温至70-80℃,再加入防冻剂、羟苯乙酯和均质预制体乳液,加入时间为2h,保温3-6h,再冷却至40℃,即得成品。 Step 2: Add the remaining deionized water, emulsifier and catalyst to the reaction kettle, heat to 70-80 ° C, then add antifreeze, hydroxyphenyl ethyl ester and homogeneous preform emulsion, add time 2h, heat preservation 3- 6h, and then cooled to 40 ° C, the finished product.
PCT/CN2017/081854 2017-04-18 2017-04-25 High temperature resistant release agent and preparation method therefor WO2018191997A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN201710253315.0 2017-04-18
CN201710253315.0A CN107050497A (en) 2017-04-18 2017-04-18 It is a kind of to prevent the deodorant of refrigerator peculiar smell

Publications (1)

Publication Number Publication Date
WO2018191997A1 true WO2018191997A1 (en) 2018-10-25

Family

ID=59600706

Family Applications (4)

Application Number Title Priority Date Filing Date
PCT/CN2017/081606 WO2018191993A1 (en) 2017-04-18 2017-04-24 Deodorizer for preventing odors in refrigerator
PCT/CN2017/081854 WO2018191997A1 (en) 2017-04-18 2017-04-25 High temperature resistant release agent and preparation method therefor
PCT/CN2017/082214 WO2018192003A1 (en) 2017-04-18 2017-04-27 Resin cleaning agent
PCT/CN2017/082212 WO2018192002A1 (en) 2017-04-18 2017-04-27 Cooked food yield-increasing fertilizer

Family Applications Before (1)

Application Number Title Priority Date Filing Date
PCT/CN2017/081606 WO2018191993A1 (en) 2017-04-18 2017-04-24 Deodorizer for preventing odors in refrigerator

Family Applications After (2)

Application Number Title Priority Date Filing Date
PCT/CN2017/082214 WO2018192003A1 (en) 2017-04-18 2017-04-27 Resin cleaning agent
PCT/CN2017/082212 WO2018192002A1 (en) 2017-04-18 2017-04-27 Cooked food yield-increasing fertilizer

Country Status (2)

Country Link
CN (1) CN107050497A (en)
WO (4) WO2018191993A1 (en)

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1900702A1 (en) * 2006-09-15 2008-03-19 Sika Technology AG Mould Release Composition
CN101838581A (en) * 2009-03-19 2010-09-22 张伟 Mould release agent
CN103567375A (en) * 2013-10-09 2014-02-12 东莞市鹏润化工产品有限公司 Non-silicone magnesium alloy pressure casting mould release agent
CN105038916A (en) * 2015-06-08 2015-11-11 梁胜光 Concrete mold release agent
CN105969487A (en) * 2016-07-01 2016-09-28 陈凌燕 Compound type releasing agent

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH01155857A (en) * 1987-12-14 1989-06-19 Daicel Chem Ind Ltd Deodorizing composition
JPH08299420A (en) * 1995-04-28 1996-11-19 Mitsui Mining & Smelting Co Ltd Deodorizing, anti-fungous and purifying material
US6221823B1 (en) * 1995-10-25 2001-04-24 Reckitt Benckiser Inc. Germicidal, acidic hard surface cleaning compositions
JP2002361273A (en) * 2001-06-12 2002-12-17 Hitoshi Tofun Environment purifying material and producing method therefor
EP1776442B1 (en) * 2004-08-11 2010-05-26 The Procter and Gamble Company A highly water-soluble solid laundry detergent composition that forms a clear wash liquor upon dissolution in water
US9375501B2 (en) * 2006-03-22 2016-06-28 Takasago International Corporation Deodorant composition
CN101372649B (en) * 2008-09-24 2010-12-22 北京洛娃日化有限公司 Acidic bathroom detergent
CN104645388A (en) * 2013-11-19 2015-05-27 青岛水世界环保科技有限公司 Deodorant used for slaughter houses
CN105311663A (en) * 2014-07-31 2016-02-10 李尧 Deodorant solution and preparation method thereof
CN105330381A (en) * 2014-08-14 2016-02-17 郑州市沃田配肥站 Organic/inorganic broad bean bulk blending fertilizer formula
CN104446826A (en) * 2014-11-12 2015-03-25 张爱丽 Special chemical fertilizer for broad beans and preparation method thereof
CN104844304B (en) * 2015-06-05 2018-04-06 孙雨桢 A kind of organic composite fertilizer of suitable broad bean growth
CN106554858A (en) * 2015-09-24 2017-04-05 重庆亿阳机械有限公司 A kind of automobile inner decorative piece surface blot cleaning agent
CN105294241A (en) * 2015-10-22 2016-02-03 马鞍山月季园蔬菜种植有限公司 Broad bean planting soil miscellaneous fertilizer and preparation method thereof
CN105347991A (en) * 2015-11-12 2016-02-24 南京惠图农业科技有限公司 Broad bean yield-increase biological fertilizer and preparation method thereof
CN105670829A (en) * 2016-03-28 2016-06-15 无锡锡能锅炉有限公司 Cleaning agent for pollutants on inner walls of biomass boilers
CN106167745A (en) * 2016-07-23 2016-11-30 扬中市创想驿站工业设计有限公司 Resin abluent

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1900702A1 (en) * 2006-09-15 2008-03-19 Sika Technology AG Mould Release Composition
CN101838581A (en) * 2009-03-19 2010-09-22 张伟 Mould release agent
CN103567375A (en) * 2013-10-09 2014-02-12 东莞市鹏润化工产品有限公司 Non-silicone magnesium alloy pressure casting mould release agent
CN105038916A (en) * 2015-06-08 2015-11-11 梁胜光 Concrete mold release agent
CN105969487A (en) * 2016-07-01 2016-09-28 陈凌燕 Compound type releasing agent

Also Published As

Publication number Publication date
WO2018192003A1 (en) 2018-10-25
CN107050497A (en) 2017-08-18
WO2018192002A1 (en) 2018-10-25
WO2018191993A1 (en) 2018-10-25

Similar Documents

Publication Publication Date Title
WO2018035850A1 (en) Water-soluble greasy mould release agent for concrete and preparation method therefor
CN105623828B (en) A kind of releasing agent for high-adhesiveness resin-based materials and preparation method thereof
CN102054578B (en) Pouring method of full-resin transformer coil
CN104005039B (en) A kind of aluminum alloy mould cleaning agent and preparation method thereof
CN101812362A (en) Emulsified paraffin release agent and manufacturing method thereof
CN113025173B (en) Concrete water-based demoulding protective emulsion and application thereof
CN106553297A (en) A kind of palm wax and silicones Compositional type high-rebound polyurethane foaming product releasing agent
TW201211158A (en) Method of forming a cured coating film of siloxane resin composition
CN106746759B (en) The heat-insulated of nano-silicon gallium, implosion guard and preparation method thereof
WO2018032523A1 (en) Microemulsion mold release agent and preparation method thereof
WO2018191997A1 (en) High temperature resistant release agent and preparation method therefor
WO2018018423A1 (en) Fair-faced concrete release agent and preparation method therefor
CN106520281A (en) Film-forming auxiliary agent prepared by utilizing organosilicon polymer and used for construction metal formwork release agent
CN109703131B (en) Recyclable film-coated aluminum alloy template and preparation method thereof
CN109233945A (en) A kind of plastic building template release agent and preparation method thereof
CN104974325A (en) Preparation method of high-hydrophily sponge
CN107031069A (en) The hard and soft assembling die and its manufacture method of a kind of airborne blade antenna cover
CN104387962A (en) Stain-resistant organic silicon surface treating agent
CN107828074A (en) A kind of anti-oxidant sheet plastic of antistatic and its production technology
CN204143937U (en) A kind of aluminum foil composite high-temperature heat insulation sleeve pipe
CN108339929B (en) A kind of forming and fixing agent and its preparation process and application
CN204357009U (en) A kind of heat insulation and decoration integrated composite tile
CN205056948U (en) An electric dewaxing pool
CN103396696A (en) Biodegradable and environmentally friendly paint remover
CN107747124A (en) A kind of anti-sticking crucible method of polycrystalline cast ingot

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 17906506

Country of ref document: EP

Kind code of ref document: A1

NENP Non-entry into the national phase

Ref country code: DE

122 Ep: pct application non-entry in european phase

Ref document number: 17906506

Country of ref document: EP

Kind code of ref document: A1

点击 这是indexloc提供的php浏览器服务,不要输入任何密码和下载