+

WO2018187621A1 - Lubrifiant en émulsion inverse multi-usage d'aérosol non inflammable - Google Patents

Lubrifiant en émulsion inverse multi-usage d'aérosol non inflammable Download PDF

Info

Publication number
WO2018187621A1
WO2018187621A1 PCT/US2018/026326 US2018026326W WO2018187621A1 WO 2018187621 A1 WO2018187621 A1 WO 2018187621A1 US 2018026326 W US2018026326 W US 2018026326W WO 2018187621 A1 WO2018187621 A1 WO 2018187621A1
Authority
WO
WIPO (PCT)
Prior art keywords
composition
water
aerosol
propellent
multiuse
Prior art date
Application number
PCT/US2018/026326
Other languages
English (en)
Inventor
Meghan LIEB
Chris Aiello
Original Assignee
Wd-40 Company
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Wd-40 Company filed Critical Wd-40 Company
Priority to CN201880035142.8A priority Critical patent/CN110678535A/zh
Priority to EP18781184.9A priority patent/EP3607034A1/fr
Priority to AU2018250302A priority patent/AU2018250302A1/en
Publication of WO2018187621A1 publication Critical patent/WO2018187621A1/fr

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M173/00—Lubricating compositions containing more than 10% water
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04—Mixtures of base-materials and additives
    • C10M169/045—Mixtures of base-materials and additives the additives being a mixture of compounds of unknown or incompletely defined constitution and non-macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M173/00—Lubricating compositions containing more than 10% water
    • C10M173/02—Lubricating compositions containing more than 10% water not containing mineral or fatty oils
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/02—Water
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/281—Esters of (cyclo)aliphatic monocarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/283—Esters of polyhydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2211/00—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions
    • C10M2211/02—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions containing carbon, hydrogen and halogen only
    • C10M2211/022—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions containing carbon, hydrogen and halogen only aliphatic
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2020/00—Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
    • C10N2020/09—Characteristics associated with water
    • C10N2020/091—Water solubility
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/08—Resistance to extreme temperature
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/12—Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/16—Antiseptic; (micro) biocidal or bactericidal
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/24—Emulsion properties
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/70—Soluble oils
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2050/00—Form in which the lubricant is applied to the material being lubricated
    • C10N2050/01—Emulsions, colloids, or micelles
    • C10N2050/013—Water-in-oil
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2050/00—Form in which the lubricant is applied to the material being lubricated
    • C10N2050/04—Aerosols

Definitions

  • the present invention relates to non-flammable multiuse aerosol lubricants.
  • This invention relates to an improved aerosol non-flammable composition in the form of a substantially stable water-in-oil emulsion for use in protecting metal from rust and corrosion, penetrating stuck parts, displacing moisture and lubricating almost anything. More particularly, such improved aerosol non-flammable composition consists of water, an oil base, an invert emulsifier, and a preservative.
  • the aerosol delivery system consists of a standard aerosol mechanism with increased stem orifice radius sufficient to create larger than standard droplets in the aerosol to reduce the fiammability profile of the aerosol mist.
  • Multiuse aerosol lubricants are widely known. Generally, such compositions employ hydrocarbons and are flammable. The most widely known and successful of these compounds is marketed under the trademark WD-40 ® . For over 50 years, consumers have used WD-40 ® Multi-Use Product (hereinafter "WD-40 ® ”) to protect metal from rust and corrosion and for penetrating lubrication. WD-40 ® protects and lubricates effectively, in part, because it so effectively displaces water. The formulation for WD-40 ® is a trade secret but is generally understood to consist of hydrocarbons and other proprietary ingredients. It does not contain water. There has long been a need for non-flammable multiuse aerosol lubricants.
  • WD-40 ® Multi-Use Product
  • This invention has found surprisingly that when an invert emulsion made with a synthetic ester base oil and a compatible invert emulsifier is delivered through an aerosol apparatus that creates certain larger than standard droplets it creates a non-flammable multiuse lubricant aerosol.
  • a preservative is included in the composition to prevent the growth of bacteria, yeast, and molds that would interfere with the creation and stability of the emulsion.
  • the improved water-in-oil aerosol non-flammable multiuse lubricating composition appears to be an improvement over the prior art lubricating compositions because of its improved combination of lubrication, corrosion and rust prevention, water displacement, and fire resistance.
  • the improved multiuse composition is in the form of a substantially stable water-in-oil emulsion consisting of 10% to 20% by weight of a liquified, normally gaseous, propellant and 80% to 90% of a base consisting essentially of by weight:
  • Aerosol apparatus for delivering the formulation in a stable non-flammable form. Aerosols of the current invention created using a standard stem sizes, however, are flammable.
  • the current invention uses stems and actuators with increased radiuses or other components to create larger droplets in the aerosol, which in turn creates a non-flammable aerosol.
  • a stem orifice of 0.013" to 0.025" is preferable.
  • a multiuse composition in the form of a substantially stable water-in-oil emulsion consists of 13% Honeywell's Solstice (HFO-1234ze) propellent by weight and 87% to a base consisting essentially of by weight:
  • the aerosol apparatus for delivering the formulation in a stable non-flammable form consists of standard aerosol components with a stem with increased orifice of 0.020" and two entry ways for uptake of the base liquid.
  • Hypermer 2524 is an oligomeric ester emulsifier for use in the manufacture of inverse polymer emulsions. It is compatible with synthetic esters such as Priolube LL- 564 as an inverse emulsifier. It is a proprietary product manufactured and sold by Croda International Pic.
  • Priolube LL-564 is a low viscosity synthetic ester. It is a proprietary product manufactured and sold by Croda International Pic.
  • Reputain B-30 is a preservative that contains 2-bromo-2-nitropropane-l,3-diol (30%), Propylene glycol (57.5 - 62.5%), and Water (7-10%).
  • the above composition has shown surprisingly good lubricating and anticorrosion properties while maintaining non-flammability in both the liquid and aerosol form.
  • the invert emulsion was the only formulation that had lubricating and anticorrosion properties similar to the market leader WD-40 ® , while remaining nonflammable in both liquid and aerosol form.
  • Synthetic Emulsion - This is a proprietary synthetic metal working fluid formulation provided by Croda International Pic.
  • GPL and PFPE - This is a formulation of chlorinated hydrocarbons
  • PFPE perfluoropolyether
  • Vertel XF (1,1,1,2,2,3,4,5,5,5- Decafluoropentane) is a proprietary hydrofluorocarbon fluid used as a solvent and vapor degreasing equipment for cleaning, rinsing, and drying. Vertel XF is supplied by Chemours.
  • GPL-105 is a clear, colorless perfluoropolyether oil that is nonflammable and long-lasting. On a weight basis, GPL-105 contains 21.6% carbon, 9.4% oxygen, and 69.0% Fluorine. It is sourced from Chemours.
  • KDP and PFPE - This is also a formulation of chlorinated hydrocarbons and
  • PFPE perfluoropolyether
  • Phosphate Ester - This is a product sold by Exxon under the name Hyjet V. It is marketed as a fire-resistant hydraulic fluid based on phosphate esters. Its chemical composition is commercially described as 70-80% tributyl phosphate, 10-20% phenol, isopropylated, phosphate, 5-7% aliphatic epoxide, and 0.1-1% 2,6-Di-Tert-Butyl-P- Cresol.
  • Reolube 46B is sold by Chemours and marketed as a fire-resistant hydraulic fluid. It is essentially 100% Phenol, isobutylenated, phosphate, with less than 25% of phenols triphenyl phosphates.
  • the invert emulsion was generally comparable or better than most of the other potential non-flammable multiuse lubricators. Three tests were performed on the formulations to determine their relative abilities to lubricate under varying conditions. Those tests and results are described below.
  • This test is commonly known as the Four Ball Wear and measures the wear protection of a test fluid.
  • Three steel balls are clamped together and covered with the lubricant to be evaluated.
  • a fourth steel ball is pressed with force into the top cavity formed by the three lower balls.
  • the temperature of the test lubricant can be regulated and then the top ball is rotated at 1200 rpm for 60 minutes.
  • Lubricants are compared by the average of the measure (in mm) of the scar worn into the three lower balls. Good results are less than 1.0 mm with excellent results being around 0.5 mm.
  • Anti-wear fluids will reduce the amount of metal lose due to friction during a metalworking process or metal to metal contact.
  • ASTM D-3233 Measurement of Extreme Pressure Properties of Fluid Lubricants (Falex Pin and Vee Block Methods " ).
  • This test measures the load-carrying properties of a lubricant by rotating a steel pin at 290 rpm against two stationary V-blocks immersed in the lubricant sample. Load, in 250 foot pound increments, is applied to the V-blocks by a ratchet mechanism. The load is increased every minute until failure occurs as indicated by breakage of the shear pin or test pin, or inability to increase or maintain the load on the ratchet wheel. Results are reported as pounds with 4,500 being the maximum that can be detected. An extreme pressure fluid will maintain its lubricating properties as pressure and temperature increases.
  • ASTM D-5620 Evaluating Thin Film Fluid Lubricants in a Drain and Dry Mode.
  • test fluid is deposited on the pin and V-blocks and allowed to drain for 1 to 4 minutes.
  • the steel pin is rotated at 290 rpm against two stationary V-blocks and a load of 300 foot pounds is applied. If after 60 minutes, there is no failure, the load is increased to 500 foot pounds. Failure is when the steady state torque is interrupted by a sharp increase or spike in the torque, breakage of the shear pin, or failure to maintain the load. Results are reported in minutes at load pounds.
  • invert emulsion was markedly better than most of the other potential nonflammable multiuse lubricators. Two tests were performed on the formulations to determine their relative abilities to prevent corrosion and rust. Those tests and results are described below.
  • ASTM B-l 17 Salt Spray iFog ⁇ Apparatus.
  • This test is used to measure the level of corrosion protection provided by a test fluid.
  • Cold rolled steel panels, with surface prepared by sand blasting, are treated with the fluid by dipping or spray, allowed to drain for 2 hours, then placed in the salt spray cabinet that contains a fog of 5% salt (NaCl) water solution at 35°C (95°F). Panels are left in the closed cabinet for the entire test period; we typically use a 72 hour period.
  • FTM-3007 Water Displacement.
  • This test is used to measure the ability of a fluid to displace water on a metal surface and then provide corrosion protection.
  • Cold rolled steel panels, with surface prepared by sand blasting are immersed in deionized water and then immersed in the test fluid just prior to being place in a static humidity chamber (25°C and 50% humidity) for one hour. The procedure is repeated but using the test fluid after a 10% level of water has been added and mixed with it. Results are reported as % visible corrosion for both the as is and the contaminated fluid.
  • the invert emulsion was the only potential non-flammable multiuse lubricant with superior lubrication and anticorrosion properties that was also non-flammable in an aerosol form.
  • the Invert Emulsion was tested for flammability using a straw connected the actuator and without. Three tests were performed on the formulations to determine their relative flammability profile. Using the larger stem orifice radius reduced the flammability profile of the invert emulsion. Those tests and results are described below.
  • a spray can is placed in a holding device 15cm from an open flame source set at a height of 5 cm.
  • the spray can is discharged for 5 seconds and the flame extension is measured.
  • the operator can then determine if a flashback exists by observing if a flame travels backwards toward the spray can.
  • a spray can is discharged towards an open flame starting at a distance of 60 cm. The distance is shortened incrementally until a sustained ignition is observed.
  • a spray can is discharged into a test vessel (55 gallon drum) containing a burning candle.
  • a timer is started at the time the can was discharged in order to determine the time elapsed before ignition, if any.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)

Abstract

L'invention concerne des émulsions eau dans l'huile stables destinées à être utilisées en tant que lubrifiants multi-usage d'aérosols résistants au feu. L'émulsion eau dans l'huile selon l'invention comprend une huile de base d'esters synthétiques, un émulsifiant inverse compatible, de l'eau et un conservateur. L'appareil d'aérosol selon l'invention met en oeuvre un orifice de tige plus grand qu'un orifice standard pour produire un aérosol non inflammable.
PCT/US2018/026326 2017-04-06 2018-04-05 Lubrifiant en émulsion inverse multi-usage d'aérosol non inflammable WO2018187621A1 (fr)

Priority Applications (3)

Application Number Priority Date Filing Date Title
CN201880035142.8A CN110678535A (zh) 2017-04-06 2018-04-05 不可燃气溶胶多用途反相乳液润滑剂
EP18781184.9A EP3607034A1 (fr) 2017-04-06 2018-04-05 Lubrifiant en émulsion inverse multi-usage d'aérosol non inflammable
AU2018250302A AU2018250302A1 (en) 2017-04-06 2018-04-05 Non-flammable aerosol multiuse invert emulsion lubricant

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
US201762482305P 2017-04-06 2017-04-06
US62/482,305 2017-04-06
US201862623610P 2018-01-30 2018-01-30
US62/623,610 2018-01-30
US15/946,611 US20180298306A1 (en) 2017-04-06 2018-04-05 Non-flammable aerosol multiuse invert emulsion lubricant
US15/946,611 2018-04-05

Publications (1)

Publication Number Publication Date
WO2018187621A1 true WO2018187621A1 (fr) 2018-10-11

Family

ID=63712700

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2018/026326 WO2018187621A1 (fr) 2017-04-06 2018-04-05 Lubrifiant en émulsion inverse multi-usage d'aérosol non inflammable

Country Status (3)

Country Link
US (2) US20180298306A1 (fr)
AU (1) AU2018250302A1 (fr)
WO (1) WO2018187621A1 (fr)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2021247027A1 (fr) * 2020-06-04 2021-12-09 Wd-40 Company Lubrifiant en émulsion inverse multi-usage à base d'aérosol ignifuge

Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3281356A (en) * 1963-05-17 1966-10-25 Lubrizol Corp Thermally stable water-in-oil emulsions
US4073412A (en) * 1976-06-03 1978-02-14 Blue Cross Laboratories, Inc. Emulsified cookware lubricant having freeze-thaw stability
US5712359A (en) * 1994-07-04 1998-01-27 Roehm Gmbh Chemische Fabrik Co-oligomers and copolymers having dispersant activity
JP2000319643A (ja) * 1999-05-06 2000-11-21 Toyo Aerosol Ind Co Ltd エアゾール組成物およびエアゾール製品
US6358893B1 (en) * 2000-06-20 2002-03-19 Stoner, Inc. Aerosol composition containing silicone-based fluid and improved spray system
US20030013618A1 (en) * 1993-03-19 2003-01-16 Horst Abramowski Non-flammable liquid penetrating lubricant
US20040235684A1 (en) * 2001-06-29 2004-11-25 Cook Stephen J. Lubricant from water in oil emulsion with suspended solid base
US20080176778A1 (en) * 2006-09-13 2008-07-24 Stefan Seemeyer Conveyor lubricants including emulsion of a lipophilic compound and an emulsifier and/or an anionic surfactant and methods employing them
US20120149616A1 (en) * 2009-09-01 2012-06-14 Klueber Lubrication Muenchen Kg Water-based lubricants
US20140332710A9 (en) * 2003-10-27 2014-11-13 Honeywell International, Inc. Compositions containing fluorine substituted olefins

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4439343A (en) * 1979-07-23 1984-03-27 United Industries Corporation Aerosol preparation
US4439342A (en) * 1979-07-23 1984-03-27 United Industries Corporation Aerosol preparation
US20080017677A1 (en) * 2006-07-21 2008-01-24 Hondroulis Sandra L Hanger
US8586518B2 (en) * 2011-08-26 2013-11-19 State Industrial Products Corporation Biobased penetrating oil

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3281356A (en) * 1963-05-17 1966-10-25 Lubrizol Corp Thermally stable water-in-oil emulsions
US4073412A (en) * 1976-06-03 1978-02-14 Blue Cross Laboratories, Inc. Emulsified cookware lubricant having freeze-thaw stability
US20030013618A1 (en) * 1993-03-19 2003-01-16 Horst Abramowski Non-flammable liquid penetrating lubricant
US5712359A (en) * 1994-07-04 1998-01-27 Roehm Gmbh Chemische Fabrik Co-oligomers and copolymers having dispersant activity
JP2000319643A (ja) * 1999-05-06 2000-11-21 Toyo Aerosol Ind Co Ltd エアゾール組成物およびエアゾール製品
US6358893B1 (en) * 2000-06-20 2002-03-19 Stoner, Inc. Aerosol composition containing silicone-based fluid and improved spray system
US20040235684A1 (en) * 2001-06-29 2004-11-25 Cook Stephen J. Lubricant from water in oil emulsion with suspended solid base
US20140332710A9 (en) * 2003-10-27 2014-11-13 Honeywell International, Inc. Compositions containing fluorine substituted olefins
US20080176778A1 (en) * 2006-09-13 2008-07-24 Stefan Seemeyer Conveyor lubricants including emulsion of a lipophilic compound and an emulsifier and/or an anionic surfactant and methods employing them
US20120149616A1 (en) * 2009-09-01 2012-06-14 Klueber Lubrication Muenchen Kg Water-based lubricants

Also Published As

Publication number Publication date
US20180298306A1 (en) 2018-10-18
US20200080020A1 (en) 2020-03-12
AU2018250302A1 (en) 2019-11-28

Similar Documents

Publication Publication Date Title
US2631979A (en) Rust inhibiting composition
EP0830420A2 (fr) Procede et dispositif de reduction en copeaux du caoutchouc constituant des pneus de vehicules
JPH08209181A (ja) Ｆｄａ認可された添加剤を含有する食用トリグリセリドに由来の環境に優しい食品等級潤滑剤
JPS5978295A (ja) 保護潤滑剤組成物
US4428851A (en) Volatile oil compositions for metal working
US20200080020A1 (en) Non-flammable aerosol multiuse invert emulsion lubricant
EP3607034A1 (fr) Lubrifiant en émulsion inverse multi-usage d'aérosol non inflammable
US3970570A (en) Antiwear additive mixture
ES2928076T3 (es) Fluido de trabajo de metales
CA2843340C (fr) Lubrifiant inhibiteur de corrosion et procedes associes
WO1996041851A1 (fr) Additifs pour pressions extremes, modificateur du coefficient de friction et fluides fonctionnels
US20170267942A1 (en) Fluids for Extreme Pressure and Wear Applications
US2862886A (en) Compositions for use as hydraulic fluids
Brophy et al. Aqueous nonflammable hydraulic fluids
US3591506A (en) Functional fluids containing halocarbons for preventing cavitation damage
US20200299608A1 (en) Non-flammable aerosol multiuse invert emulsion lubricant
JP6674996B1 (ja) 水溶性潤滑防錆剤
WO2021247027A1 (fr) Lubrifiant en émulsion inverse multi-usage à base d'aérosol ignifuge
US3657128A (en) Synergistic functional fluid compositions
DE2805604A1 (de) Kaelte- oder waermepumpe mit stabiler verschleisshemmender arbeitsfluessigkeit
US20180148662A1 (en) Environmentally friendly high pressure lubricant additive
JP6730838B2 (ja) 難燃性半固体状潤滑剤組成物、並びにそれを封入してなる軸受及び歯車
Fowle Paper 19: Lubricants for Fluid Film and Hertzian Contact Conditions
JP7538498B2 (ja) 水－グリコール系作動液組成物及びその追加補充添加剤
WO2020217213A1 (fr) Compositions d'huile lubrifiante

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 18781184

Country of ref document: EP

Kind code of ref document: A1

DPE1 Request for preliminary examination filed after expiration of 19th month from priority date (pct application filed from 20040101)
NENP Non-entry into the national phase

Ref country code: DE

ENP Entry into the national phase

Ref document number: 2018781184

Country of ref document: EP

Effective date: 20191106

ENP Entry into the national phase

Ref document number: 2018250302

Country of ref document: AU

Date of ref document: 20180405

Kind code of ref document: A

点击 这是indexloc提供的php浏览器服务，不要输入任何密码和下载