WO2018183010A1 - Système dispersant pour formulations de lavage automatique de la vaisselle - Google Patents
Système dispersant pour formulations de lavage automatique de la vaisselle Download PDFInfo
- Publication number
- WO2018183010A1 WO2018183010A1 PCT/US2018/023089 US2018023089W WO2018183010A1 WO 2018183010 A1 WO2018183010 A1 WO 2018183010A1 US 2018023089 W US2018023089 W US 2018023089W WO 2018183010 A1 WO2018183010 A1 WO 2018183010A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- automatic dishwashing
- dishwashing composition
- acrylic acid
- present
- surfactant
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 155
- 238000004851 dishwashing Methods 0.000 title claims abstract description 121
- 239000002270 dispersing agent Substances 0.000 title claims abstract description 38
- 238000009472 formulation Methods 0.000 title description 8
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 43
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims abstract description 37
- 239000004094 surface-active agent Substances 0.000 claims abstract description 32
- 229920001577 copolymer Polymers 0.000 claims abstract description 26
- 229920002959 polymer blend Polymers 0.000 claims abstract description 25
- 239000000178 monomer Substances 0.000 claims abstract description 21
- 229920001519 homopolymer Polymers 0.000 claims abstract description 20
- 239000000654 additive Substances 0.000 claims abstract description 10
- 230000000996 additive effect Effects 0.000 claims abstract description 10
- 125000000217 alkyl group Chemical group 0.000 claims description 20
- 229920006395 saturated elastomer Polymers 0.000 claims description 19
- 238000000034 method Methods 0.000 claims description 12
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 11
- 150000001298 alcohols Chemical class 0.000 claims description 11
- KXDHJXZQYSOELW-UHFFFAOYSA-N Carbamic acid Chemical compound NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 claims description 9
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims description 9
- 239000007844 bleaching agent Substances 0.000 claims description 9
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 claims description 8
- 239000013522 chelant Substances 0.000 claims description 8
- 229910019142 PO4 Inorganic materials 0.000 claims description 7
- 125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 claims description 7
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 7
- 239000010452 phosphate Substances 0.000 claims description 7
- 238000004140 cleaning Methods 0.000 claims description 4
- 102000004190 Enzymes Human genes 0.000 claims description 3
- 108090000790 Enzymes Proteins 0.000 claims description 3
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 3
- 239000003054 catalyst Substances 0.000 claims description 3
- 239000011574 phosphorus Substances 0.000 claims description 3
- 229910052698 phosphorus Inorganic materials 0.000 claims description 3
- 239000012190 activator Substances 0.000 claims description 2
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical class OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 claims 1
- MWKFXSUHUHTGQN-UHFFFAOYSA-N decan-1-ol Chemical compound CCCCCCCCCCO MWKFXSUHUHTGQN-UHFFFAOYSA-N 0.000 description 24
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 21
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 17
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 15
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 15
- WQDUMFSSJAZKTM-UHFFFAOYSA-N Sodium methoxide Chemical compound [Na+].[O-]C WQDUMFSSJAZKTM-UHFFFAOYSA-N 0.000 description 14
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical class C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 13
- 238000006243 chemical reaction Methods 0.000 description 13
- 229910052757 nitrogen Inorganic materials 0.000 description 13
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 12
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical group C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 11
- 238000005227 gel permeation chromatography Methods 0.000 description 11
- 229920000642 polymer Polymers 0.000 description 11
- 239000011734 sodium Substances 0.000 description 11
- 238000012360 testing method Methods 0.000 description 11
- -1 disilicate Chemical class 0.000 description 10
- 150000003839 salts Chemical class 0.000 description 10
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- 238000001644 13C nuclear magnetic resonance spectroscopy Methods 0.000 description 8
- BBBUAWSVILPJLL-UHFFFAOYSA-N 2-(2-ethylhexoxymethyl)oxirane Chemical compound CCCCC(CC)COCC1CO1 BBBUAWSVILPJLL-UHFFFAOYSA-N 0.000 description 8
- XMVBHZBLHNOQON-UHFFFAOYSA-N 2-butyl-1-octanol Chemical compound CCCCCCC(CO)CCCC XMVBHZBLHNOQON-UHFFFAOYSA-N 0.000 description 8
- 230000000052 comparative effect Effects 0.000 description 8
- 239000011521 glass Substances 0.000 description 8
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 7
- 239000002736 nonionic surfactant Substances 0.000 description 7
- 238000010926 purge Methods 0.000 description 7
- 238000003756 stirring Methods 0.000 description 7
- 239000000126 substance Substances 0.000 description 7
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical class [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 6
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- 229910052700 potassium Inorganic materials 0.000 description 6
- 239000011591 potassium Chemical class 0.000 description 6
- 239000002689 soil Substances 0.000 description 6
- CIEZZGWIJBXOTE-UHFFFAOYSA-N 2-[bis(carboxymethyl)amino]propanoic acid Chemical compound OC(=O)C(C)N(CC(O)=O)CC(O)=O CIEZZGWIJBXOTE-UHFFFAOYSA-N 0.000 description 5
- 238000004458 analytical method Methods 0.000 description 5
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- 239000002904 solvent Substances 0.000 description 5
- YIWUKEYIRIRTPP-UHFFFAOYSA-N 2-ethylhexan-1-ol Chemical compound CCCCC(CC)CO YIWUKEYIRIRTPP-UHFFFAOYSA-N 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical class [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 4
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 4
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 4
- 229910052799 carbon Inorganic materials 0.000 description 4
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 4
- 239000011777 magnesium Substances 0.000 description 4
- 239000003264 margarine Substances 0.000 description 4
- 235000013310 margarine Nutrition 0.000 description 4
- 150000004760 silicates Chemical class 0.000 description 4
- 229910000029 sodium carbonate Inorganic materials 0.000 description 4
- HLZKNKRTKFSKGZ-UHFFFAOYSA-N tetradecan-1-ol Chemical compound CCCCCCCCCCCCCCO HLZKNKRTKFSKGZ-UHFFFAOYSA-N 0.000 description 4
- 239000005968 1-Decanol Substances 0.000 description 3
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical class OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 239000011575 calcium Substances 0.000 description 3
- 239000011203 carbon fibre reinforced carbon Substances 0.000 description 3
- 150000001860 citric acid derivatives Chemical class 0.000 description 3
- 239000003599 detergent Substances 0.000 description 3
- VTIIJXUACCWYHX-UHFFFAOYSA-L disodium;carboxylatooxy carbonate Chemical compound [Na+].[Na+].[O-]C(=O)OOC([O-])=O VTIIJXUACCWYHX-UHFFFAOYSA-L 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 239000000945 filler Substances 0.000 description 3
- 239000006260 foam Substances 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 229910052744 lithium Chemical class 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 229920001223 polyethylene glycol Polymers 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 229940045872 sodium percarbonate Drugs 0.000 description 3
- 238000003786 synthesis reaction Methods 0.000 description 3
- NJWSNNWLBMSXQR-UHFFFAOYSA-N 2-hexyloxirane Chemical compound CCCCCCC1CO1 NJWSNNWLBMSXQR-UHFFFAOYSA-N 0.000 description 2
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 2
- 239000005711 Benzoic acid Substances 0.000 description 2
- KZMGYPLQYOPHEL-UHFFFAOYSA-N Boron trifluoride etherate Chemical compound FB(F)F.CCOCC KZMGYPLQYOPHEL-UHFFFAOYSA-N 0.000 description 2
- 241000219198 Brassica Species 0.000 description 2
- 235000003351 Brassica cretica Nutrition 0.000 description 2
- 235000003343 Brassica rupestris Nutrition 0.000 description 2
- 125000006539 C12 alkyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
- 239000002202 Polyethylene glycol Substances 0.000 description 2
- 229920002125 Sokalan® Polymers 0.000 description 2
- 238000001994 activation Methods 0.000 description 2
- 230000004913 activation Effects 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 239000003242 anti bacterial agent Substances 0.000 description 2
- 235000010233 benzoic acid Nutrition 0.000 description 2
- QKSKPIVNLNLAAV-UHFFFAOYSA-N bis(2-chloroethyl) sulfide Chemical compound ClCCSCCCl QKSKPIVNLNLAAV-UHFFFAOYSA-N 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical class C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 description 2
- 235000013345 egg yolk Nutrition 0.000 description 2
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- WMFOQBRAJBCJND-UHFFFAOYSA-M lithium hydroxide Inorganic materials [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 description 2
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- 239000002243 precursor Substances 0.000 description 2
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- RFDGKSUFGFLBOX-UHFFFAOYSA-N 2-methyloxirane;oxirane;oxolane Chemical compound C1CO1.CC1CO1.C1CCOC1 RFDGKSUFGFLBOX-UHFFFAOYSA-N 0.000 description 1
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- JRKICGRDRMAZLK-UHFFFAOYSA-L persulfate group Chemical group S(=O)(=O)([O-])OOS(=O)(=O)[O-] JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 1
- UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 description 1
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- 229910000027 potassium carbonate Inorganic materials 0.000 description 1
- 159000000001 potassium salts Chemical class 0.000 description 1
- OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 description 1
- 229910052939 potassium sulfate Inorganic materials 0.000 description 1
- 235000011151 potassium sulphates Nutrition 0.000 description 1
- 238000004886 process control Methods 0.000 description 1
- 235000013772 propylene glycol Nutrition 0.000 description 1
- 235000019419 proteases Nutrition 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 238000001448 refractive index detection Methods 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 238000001542 size-exclusion chromatography Methods 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000001509 sodium citrate Substances 0.000 description 1
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
- HRZFUMHJMZEROT-UHFFFAOYSA-L sodium disulfite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])(=O)=O HRZFUMHJMZEROT-UHFFFAOYSA-L 0.000 description 1
- 229940001584 sodium metabisulfite Drugs 0.000 description 1
- 235000010262 sodium metabisulphite Nutrition 0.000 description 1
- 229960001922 sodium perborate Drugs 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- MWNQXXOSWHCCOZ-UHFFFAOYSA-L sodium;oxido carbonate Chemical class [Na+].[O-]OC([O-])=O MWNQXXOSWHCCOZ-UHFFFAOYSA-L 0.000 description 1
- YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 238000007725 thermal activation Methods 0.000 description 1
- 238000004448 titration Methods 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- NLVXSWCKKBEXTG-UHFFFAOYSA-N vinylsulfonic acid Chemical compound OS(=O)(=O)C=C NLVXSWCKKBEXTG-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/378—(Co)polymerised monomers containing sulfur, e.g. sulfonate
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
- C11D1/721—End blocked ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
Definitions
- the present invention also provides a method of cleaning an article in an automatic dishwashing machine, the method comprising: applying to the article the automatic dishwashing composition of the present invention.
- the builder used in the automatic dishwashing composition of the present invention comprises one or more carbonates, citrates and silicates.
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
L'invention concerne une composition de lavage de vaisselle automatique, comprenant : un mélange polymère dispersant, comprenant un homopolymère d'acide acrylique ; et un copolymère d'acide acrylique et d'un monomère sulfoné ; le mélange polymère dispersant ayant un rapport de mélange de l'homopolymère d'acide acrylique au copolymère de 3 : 1 à 1 : 3 ; un tensioactif ; un adjuvant ; et éventuellement, un additif.
Priority Applications (6)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AU2018245984A AU2018245984B2 (en) | 2017-03-30 | 2018-03-19 | Dispersant system for automatic dish washing formulations |
| JP2019548457A JP7162002B2 (ja) | 2017-03-30 | 2018-03-19 | 自動食器洗浄配合物用分散剤系 |
| CN201880017116.2A CN110382678B (zh) | 2017-03-30 | 2018-03-19 | 用于自动餐具洗涤制剂的分散剂系统 |
| BR112019018379-5A BR112019018379B1 (pt) | 2017-03-30 | 2018-03-19 | Composição de lavagem de louça automática, e, método de limpeza de um artigo em uma máquina de lavar louças automática |
| EP18712491.2A EP3601511B1 (fr) | 2017-03-30 | 2018-03-19 | Système dispersant pour formulations de lave-vaisselle |
| PL18712491T PL3601511T3 (pl) | 2017-03-30 | 2018-03-19 | Układ środków dyspergujących dla preparatów do automatycznego mycia naczyń |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP17290049 | 2017-03-30 | ||
| EP17290049.0 | 2017-03-30 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO2018183010A1 true WO2018183010A1 (fr) | 2018-10-04 |
Family
ID=58547460
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/US2018/023089 WO2018183010A1 (fr) | 2017-03-30 | 2018-03-19 | Système dispersant pour formulations de lavage automatique de la vaisselle |
Country Status (7)
| Country | Link |
|---|---|
| EP (1) | EP3601511B1 (fr) |
| JP (1) | JP7162002B2 (fr) |
| CN (1) | CN110382678B (fr) |
| AU (1) | AU2018245984B2 (fr) |
| BR (1) | BR112019018379B1 (fr) |
| PL (1) | PL3601511T3 (fr) |
| WO (1) | WO2018183010A1 (fr) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113795569A (zh) * | 2019-06-05 | 2021-12-14 | 陶氏环球技术有限责任公司 | 自动餐具洗涤组合物和清洁物品的方法 |
| US11920110B2 (en) | 2018-10-22 | 2024-03-05 | Dow Global Technologies Llc | Automatic dishwashing composition with dispersant polymer |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP7664596B2 (ja) | 2020-06-25 | 2025-04-18 | シーバイエス株式会社 | 自動食器洗浄方法 |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5294365A (en) | 1991-12-12 | 1994-03-15 | Basf Corporation | Hydroxypolyethers as low-foam surfactants |
| JPH11121586A (ja) * | 1997-10-20 | 1999-04-30 | Kokusai Electric Co Ltd | ウェーハボート管理システム |
| US6365785B1 (en) * | 1997-08-02 | 2002-04-02 | Therprocter & Gamble Company | Process for preparing ether-capped poly(oxyalkylated) alcohol surfactants |
| US20040127377A1 (en) * | 2000-03-29 | 2004-07-01 | Rodrigues Klein A. | Polymers that inhibit calcium phosphate and calcium carbonate scale in autodish applications |
| WO2016153668A1 (fr) * | 2015-03-20 | 2016-09-29 | Rohm And Haas Company | Détergent pour lavage automatique de vaisselle |
| WO2017013158A1 (fr) * | 2015-07-23 | 2017-01-26 | Henkel Ag & Co. Kgaa | Lessive lave-vaisselle contenant des agents de blanchiment et des polymères |
| WO2017172394A1 (fr) * | 2016-03-31 | 2017-10-05 | Rohm And Haas Company | Tensioactifs destinés à la prévention des taches dans les compositions de lave-vaisselle automatique |
| WO2017218222A1 (fr) * | 2016-06-16 | 2017-12-21 | Dow Global Technologies Llc | Composition pour lave-vaisselle présentant un tensioactif de prévention de taches |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH1121586A (ja) * | 1997-07-07 | 1999-01-26 | Asahi Denka Kogyo Kk | 洗浄剤組成物 |
| US6482994B2 (en) * | 1997-08-02 | 2002-11-19 | The Procter & Gamble Company | Ether-capped poly(oxyalkylated) alcohol surfactants |
| CA2297829A1 (fr) * | 1997-08-02 | 1999-02-11 | The Procter & Gamble Company | Compositions renfermant des tensioactifs a base d'alcools poly(oxyalkyles) coiffes par un ether |
| JP4303155B2 (ja) * | 2003-10-31 | 2009-07-29 | ディバーシー・アイピー・インターナショナル・ビー・ヴイ | 自動食器洗浄機用洗浄剤組成物 |
| JP5324207B2 (ja) * | 2008-12-19 | 2013-10-23 | ディバーシー株式会社 | 自動食器洗浄機用固形洗浄剤の製法およびそれによって得られる自動食器洗浄機用固形洗浄剤 |
| US20100197545A1 (en) * | 2009-01-30 | 2010-08-05 | Ecolab USA | High alkaline detergent composition with enhanced scale control |
| WO2015034766A2 (fr) * | 2013-09-05 | 2015-03-12 | Rohm And Haas Company | Détergent pour lave-vaisselle automatique capable d'inhibition de tartre synergique |
| EP2896637A1 (fr) * | 2014-01-21 | 2015-07-22 | Rhodia Operations | Copolymère comprenant des unités de dérivation de type A à partir de monomères d'acide carboxylique et unités de dérivation de type B de monomères d'acide sulfonique |
| GB201409631D0 (en) * | 2014-05-30 | 2014-07-16 | Reckitt Benckiser Brands Ltd | Improved PEI composition |
| CN104893870B (zh) * | 2015-04-24 | 2018-10-02 | 广州立白企业集团有限公司 | 一种具有除菌功效的家用洗碗机洗涤剂及其制备方法 |
-
2018
- 2018-03-19 JP JP2019548457A patent/JP7162002B2/ja active Active
- 2018-03-19 BR BR112019018379-5A patent/BR112019018379B1/pt not_active IP Right Cessation
- 2018-03-19 WO PCT/US2018/023089 patent/WO2018183010A1/fr unknown
- 2018-03-19 AU AU2018245984A patent/AU2018245984B2/en active Active
- 2018-03-19 PL PL18712491T patent/PL3601511T3/pl unknown
- 2018-03-19 CN CN201880017116.2A patent/CN110382678B/zh active Active
- 2018-03-19 EP EP18712491.2A patent/EP3601511B1/fr active Active
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5294365A (en) | 1991-12-12 | 1994-03-15 | Basf Corporation | Hydroxypolyethers as low-foam surfactants |
| US6365785B1 (en) * | 1997-08-02 | 2002-04-02 | Therprocter & Gamble Company | Process for preparing ether-capped poly(oxyalkylated) alcohol surfactants |
| JPH11121586A (ja) * | 1997-10-20 | 1999-04-30 | Kokusai Electric Co Ltd | ウェーハボート管理システム |
| US20040127377A1 (en) * | 2000-03-29 | 2004-07-01 | Rodrigues Klein A. | Polymers that inhibit calcium phosphate and calcium carbonate scale in autodish applications |
| WO2016153668A1 (fr) * | 2015-03-20 | 2016-09-29 | Rohm And Haas Company | Détergent pour lavage automatique de vaisselle |
| WO2017013158A1 (fr) * | 2015-07-23 | 2017-01-26 | Henkel Ag & Co. Kgaa | Lessive lave-vaisselle contenant des agents de blanchiment et des polymères |
| WO2017172394A1 (fr) * | 2016-03-31 | 2017-10-05 | Rohm And Haas Company | Tensioactifs destinés à la prévention des taches dans les compositions de lave-vaisselle automatique |
| WO2017218222A1 (fr) * | 2016-06-16 | 2017-12-21 | Dow Global Technologies Llc | Composition pour lave-vaisselle présentant un tensioactif de prévention de taches |
Non-Patent Citations (2)
| Title |
|---|
| J. P. SIBILIA: "A Guide to Materials Characterization and Chemical Analysis", 1988, VCH, pages: 81 - 84 |
| W. W. YAU; J. J. KIRKLAND; D. D. BLY: "Modem Size Exclusion Chromatography", 1979, WILEY-INTERSCIENCE |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US11920110B2 (en) | 2018-10-22 | 2024-03-05 | Dow Global Technologies Llc | Automatic dishwashing composition with dispersant polymer |
| CN113795569A (zh) * | 2019-06-05 | 2021-12-14 | 陶氏环球技术有限责任公司 | 自动餐具洗涤组合物和清洁物品的方法 |
| CN113795569B (zh) * | 2019-06-05 | 2023-10-13 | 陶氏环球技术有限责任公司 | 自动餐具洗涤组合物和清洁物品的方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| CN110382678B (zh) | 2021-06-18 |
| JP2020515664A (ja) | 2020-05-28 |
| AU2018245984A1 (en) | 2019-11-14 |
| EP3601511A1 (fr) | 2020-02-05 |
| BR112019018379A2 (pt) | 2020-04-07 |
| AU2018245984B2 (en) | 2022-11-24 |
| PL3601511T3 (pl) | 2021-06-14 |
| CN110382678A (zh) | 2019-10-25 |
| EP3601511B1 (fr) | 2021-01-06 |
| BR112019018379B1 (pt) | 2023-01-31 |
| JP7162002B2 (ja) | 2022-10-27 |
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