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WO2018163587A1 - Chocolate-like food containing highly unsaturated fatty acid, said food configured to suppress generation of unfavorable flavors - Google Patents

Chocolate-like food containing highly unsaturated fatty acid, said food configured to suppress generation of unfavorable flavors Download PDF

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Publication number
WO2018163587A1
WO2018163587A1 PCT/JP2018/000144 JP2018000144W WO2018163587A1 WO 2018163587 A1 WO2018163587 A1 WO 2018163587A1 JP 2018000144 W JP2018000144 W JP 2018000144W WO 2018163587 A1 WO2018163587 A1 WO 2018163587A1
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Prior art keywords
chocolate
food
unsaturated fatty
highly unsaturated
fatty acid
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PCT/JP2018/000144
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French (fr)
Japanese (ja)
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暁之 石渡
美和子 盛川
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不二製油グループ本社株式会社
不二製油株式会社
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Priority to JP2018505747A priority Critical patent/JPWO2018163587A1/en
Publication of WO2018163587A1 publication Critical patent/WO2018163587A1/en

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    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23GCOCOA; COCOA PRODUCTS, e.g. CHOCOLATE; SUBSTITUTES FOR COCOA OR COCOA PRODUCTS; CONFECTIONERY; CHEWING GUM; ICE-CREAM; PREPARATION THEREOF
    • A23G1/00Cocoa; Cocoa products, e.g. chocolate; Substitutes therefor

Definitions

  • the present invention relates to a highly unsaturated fatty acid-containing chocolate-like food in which the occurrence of a different flavor is suppressed.
  • Chocolate-like foods represented by chocolate are foods preferred by children. Therefore, by blending the specific nutritional component into the chocolate-like food, the nutritional component can be easily taken by the child.
  • Polyunsaturated fatty acids represented by DHA and EPA are materials that are attracting attention for their physiological effects. However, polyunsaturated fatty acids are susceptible to oxidative degradation and are often difficult to formulate into general foods.
  • Patent Document 1 describes "a chocolate composition characterized by containing at least one of hydrogenated untreated fats and oils and catechins having eicosapentaenoic acid and / or docosahexaenoic acid.”
  • Patent Document 2 states that “a fat or oil containing a highly unsaturated fatty acid is coated with an edible film forming substance composed of a protein or a salt thereof, a lipid, or a combination thereof so as to be substantially blocked from the outside air. And a highly unsaturated fatty acid-containing food characterized in that it contains a filmed oil and fat in the form of particles having a diameter of 2 mm or less.
  • the present invention relates to a chocolate-like food containing a highly unsaturated fatty acid-containing oil and fat, and an object thereof is to provide a product in which a change in flavor over time is suppressed.
  • Patent Document 1 it is considered that the effect of suppressing changes over time is recognized to some extent, but since the shelf life of the chocolate-like food is relatively long, a stronger effect is required.
  • Patent Document 2 since the highly unsaturated fatty acid is added in the form of capsules, it has been difficult to apply to foods such as chocolate-like foods that emphasize the feeling of melting in the mouth.
  • the present invention (1) A chocolate-like food containing 0.02 to 10% by mass of a highly unsaturated fatty acid and 5 to 15% by mass of a dairy product, (2) The chocolate-like food according to (1), wherein the dairy product is one or more selected from whole milk powder, skim milk powder, whey powder, milk protein, (3) In a chocolate-like food containing 5 to 15% by mass of one or more dairy products selected from whole milk powder, skim milk powder, whey powder and milk protein, and 0.02 to 10% by mass of highly unsaturated fatty acid, A method of suppressing the occurrence of a different flavor, It is about.
  • the chocolate-like food referred to in the present invention is, for example, chocolate.
  • the present technology is applied to ice-coating chocolate, which is distributed at a low temperature, the effect is remarkable and preferable.
  • the highly unsaturated fatty acid-containing fats and oils referred to in the present invention are fats and oils containing one or more highly unsaturated fatty acids as constituent fatty acids.
  • the highly unsaturated fatty acid is also called a polyunsaturated fatty acid and is a general term for fatty acids containing many double bonds.
  • DHA docosahexaenoic acid
  • EPA eicosapentaenoic acid
  • highly unsaturated fatty acid containing fats and oils may be called PUFA oil.
  • the chocolate-like food according to the present invention needs to contain a highly unsaturated fatty acid-containing fat so that the total amount of DHA and EPA is 0.02 to 10% by weight. It is 2 to 8% by weight, and more preferably 1 to 6% by weight. The effect can be expected by containing an appropriate amount of highly unsaturated fatty acid-containing fats and oils.
  • Various types of fats and oils containing highly unsaturated fatty acids can be used.
  • fish oil can be raised.
  • highly unsaturated fatty acid-containing fats and oils that have undergone some antioxidant treatment.
  • an aqueous phase containing 2.5 to 65% by weight of a water-soluble antioxidant and further added with a saccharide so that the total amount of water-soluble solids in the aqueous phase is 18 to 79% by weight.
  • the dairy product in the chocolate-like food, it is necessary to contain 5 to 15% by mass of the dairy product in the chocolate-like food, and this amount is more desirably 7 to 14% by mass, and further desirably 8 to 13% by mass.
  • the effect can be expected by containing an appropriate amount of dairy products.
  • Specific examples of the dairy product mentioned here include whole milk powder, skim milk powder, whey powder and milk protein, more preferably skim milk powder and whey powder, and more preferably whey powder.
  • the milk protein as used in the field of this invention means the raw material which is not classified into whole milk powder (namely, whole milk powder), skim milk powder, and whey powder among the raw materials containing the protein component derived from milk.
  • Ice coating chocolate was prepared according to the formulation shown in Table 1. The preparation method followed “ ⁇ Preparation method of ice-coating chocolate”. The obtained sample was evaluated according to “Evaluation method of ice coating chocolate”. The results are shown in Table 2.
  • Formulation -Vegetable oils and fats include EPA and DHA so that "Palm Ace 10" manufactured by Fuji Oil Co., Ltd., which is Super Palm Olein, has a total amount of EPA and DHA of 2.8% by mass in ice-coating chocolate. A mixture of fats and oils was used.
  • An oil and fat composition containing EPA and DHA contains 19% by mass of an aqueous phase containing 58% by mass of vitamin C, catechin, and sugar finely dispersed in 81% by mass of an oil phase containing an oil-soluble emulsifier. The thing to which the thing was distributed was used.
  • Preparation method 1 of ice-coating chocolate According to the recipe, raw materials other than lecithin and part of vegetable oil were mixed. 2 Fine-grained with a roll refiner. 3 Kneaded while heating in Conche. 4 Lecithin and vegetable oil not added in 1 were added and mixed.

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  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Food Science & Technology (AREA)
  • Polymers & Plastics (AREA)
  • Confectionery (AREA)

Abstract

The present invention relates to a chocolate-like food containing a highly unsaturated fatty acid-containing fat, and addresses the problem of providing such food which is configured to suppress temporal changes in flavor. Provided is a chocolate-like food that contains a highly unsaturated fatty acid at 0.02 to 10 mass%, wherein a fish-like smell derived from the highly unsaturated fatty acid can be suppressed as a result of the food containing a milk product at 5 to 15 mass%. The milk product is preferably a whey powder.

Description

異風味の発生が抑制された、高度不飽和脂肪酸含有チョコレート様食品Polyunsaturated fatty acid-containing chocolate-like foods with reduced off-flavors
本発明は異風味の発生が抑制された、高度不飽和脂肪酸含有チョコレート様食品に関する。 The present invention relates to a highly unsaturated fatty acid-containing chocolate-like food in which the occurrence of a different flavor is suppressed.
  チョコレートに代表されるチョコレート様食品は、子供にも好まれる食品である。そのため、特定栄養成分をチョコレート様食品に配合する事により、当該栄養成分を子供に無理なく摂取させることが出来る。
 DHAやEPAに代表される高度不飽和脂肪酸は、その生理的効果が注目されている素材である。しかし、高度不飽和脂肪酸は酸化劣化しやすく、一般の食品への配合は困難な場合が多い。
 特許文献1では、「エイコサペンタエン酸及び/又はドコサヘキサエン酸を有する水素添加未処理の油脂及びカテキン類の少なくとも一種を含有することを特徴とするチョコレート組成物。」について記載がある。
Chocolate-like foods represented by chocolate are foods preferred by children. Therefore, by blending the specific nutritional component into the chocolate-like food, the nutritional component can be easily taken by the child.
Polyunsaturated fatty acids represented by DHA and EPA are materials that are attracting attention for their physiological effects. However, polyunsaturated fatty acids are susceptible to oxidative degradation and are often difficult to formulate into general foods.
Patent Document 1 describes "a chocolate composition characterized by containing at least one of hydrogenated untreated fats and oils and catechins having eicosapentaenoic acid and / or docosahexaenoic acid."
 特許文献2には、「高度不飽和脂肪酸を含有する油脂を、蛋白質若しくはこれらの塩、脂質、又はこれらの組み合わせからなる可食性皮膜形成物質により実質的に外気と遮断するように被覆してなり、且つ直径が2mm以下の粒子状である皮膜化油脂を含有することを特徴とする高度不飽和脂肪酸含有食品。」について記載されている。 Patent Document 2 states that “a fat or oil containing a highly unsaturated fatty acid is coated with an edible film forming substance composed of a protein or a salt thereof, a lipid, or a combination thereof so as to be substantially blocked from the outside air. And a highly unsaturated fatty acid-containing food characterized in that it contains a filmed oil and fat in the form of particles having a diameter of 2 mm or less.
特開平5-292885号公報JP-A-5-292858 特開昭59-17949号公報JP 59-17949 A
 本発明は、高度不飽和脂肪酸含有油脂を含有するチョコレート様食品に関するものであって、経時的な風味変化が抑制されたものを提供することを課題とする。 The present invention relates to a chocolate-like food containing a highly unsaturated fatty acid-containing oil and fat, and an object thereof is to provide a product in which a change in flavor over time is suppressed.
 本発明者は、課題の解決に向け鋭意検討を行った。
 特許文献1に記載される方法では、一定程度、経時的な変化を抑制する効果も認められると考えられるが、チョコレート様食品の賞味期間は比較的長い為、より強力な効果が求められる。
 特許文献2に記載される方法では、高度不飽和脂肪酸をカプセル状にして添加するため、チョコレート様食品のような、口溶け感を重視する食品においては、適用が困難であった。
The present inventor has intensively studied to solve the problem.
In the method described in Patent Document 1, it is considered that the effect of suppressing changes over time is recognized to some extent, but since the shelf life of the chocolate-like food is relatively long, a stronger effect is required.
In the method described in Patent Document 2, since the highly unsaturated fatty acid is added in the form of capsules, it has been difficult to apply to foods such as chocolate-like foods that emphasize the feeling of melting in the mouth.
 本発明者が鋭意検討を行なったところ、5~15質量%の乳製品を配合することで、高度不飽和脂肪酸含有油脂を含有するチョコレート様食品において、高度不飽和脂肪酸に由来する異風味を低減できることを見出し、本発明を完成させた。 As a result of intensive studies by the present inventor, by blending 5 to 15% by mass of dairy product, in the chocolate-like food containing highly unsaturated fatty acid-containing fats and oils, the unusual flavor derived from highly unsaturated fatty acids is reduced. The present invention has been completed by finding out what can be done.
すなわち、本発明は、
(1)高度不飽和脂肪酸を0.02~10質量%含有し、かつ、乳製品を5~15質量%含有する、チョコレート様食品、
(2)乳製品が、全粉乳、脱脂粉乳、ホエイパウダー、乳タンパクから選ばれる1以上である、(1)記載の、チョコレート様食品、
(3) 全粉乳、脱脂粉乳、ホエイパウダー、乳タンパクから選ばれる1以上の乳製品を5~15質量%含有させる、高度不飽和脂肪酸を0.02~10質量%含有するチョコレート様食品における、異風味発生の抑制方法、
に関するものである。
That is, the present invention
(1) A chocolate-like food containing 0.02 to 10% by mass of a highly unsaturated fatty acid and 5 to 15% by mass of a dairy product,
(2) The chocolate-like food according to (1), wherein the dairy product is one or more selected from whole milk powder, skim milk powder, whey powder, milk protein,
(3) In a chocolate-like food containing 5 to 15% by mass of one or more dairy products selected from whole milk powder, skim milk powder, whey powder and milk protein, and 0.02 to 10% by mass of highly unsaturated fatty acid, A method of suppressing the occurrence of a different flavor,
It is about.
 本発明によれば、高度不飽和脂肪酸含有油脂を含有するチョコレート様食品に関するものであって、経時的な風味変化が抑制されたものを得ることができる。 According to the present invention, it is possible to obtain a chocolate-like food containing a highly unsaturated fatty acid-containing oil and fat, in which a change in flavor over time is suppressed.
 本発明でいうチョコレート様食品とは、一例を挙げると、チョコレート類が該当する。 特に、低温で流通されることになる、アイスコーチングチョコへ本技術を適用すれば、その効果が顕著に現れ、好ましい。  The chocolate-like food referred to in the present invention is, for example, chocolate. In particular, if the present technology is applied to ice-coating chocolate, which is distributed at a low temperature, the effect is remarkable and preferable. *
 本発明で言う高度不飽和脂肪酸含有油脂とは、その構成脂肪酸として高度不飽和脂肪酸を1以上含む油脂である。ここで高度不飽和脂肪酸とは、多価不飽和脂肪酸とも呼ばれ、二重結合を多く含む脂肪酸の総称である。具体的には、DHA(ドコサヘキサエン酸)やEPA(エイコサペンタエン酸)を列挙できる。なお、高度不飽和脂肪酸含有油脂を、PUFA油と称することもある。 The highly unsaturated fatty acid-containing fats and oils referred to in the present invention are fats and oils containing one or more highly unsaturated fatty acids as constituent fatty acids. Here, the highly unsaturated fatty acid is also called a polyunsaturated fatty acid and is a general term for fatty acids containing many double bonds. Specifically, DHA (docosahexaenoic acid) and EPA (eicosapentaenoic acid) can be listed. In addition, highly unsaturated fatty acid containing fats and oils may be called PUFA oil.
 本発明に係るチョコレート様食品においては、DHAとEPAの合計で0.02~10重量%となるように高度不飽和脂肪酸含有油脂を含有している必要があり、この量は、望ましくは0.2~8重量%であり、さらに望ましくは1~6重量%である。適当な量の高度不飽和脂肪酸含有油脂が含有されていることで、その効果が期待できる。 The chocolate-like food according to the present invention needs to contain a highly unsaturated fatty acid-containing fat so that the total amount of DHA and EPA is 0.02 to 10% by weight. It is 2 to 8% by weight, and more preferably 1 to 6% by weight. The effect can be expected by containing an appropriate amount of highly unsaturated fatty acid-containing fats and oils.
 高度不飽和脂肪酸を含有する油脂としては、各種のものを使用することができる。代表的には魚油を上げることができる。
 また、使用に際しては、何らかの抗酸化処理を施した高度不飽和脂肪酸含有油脂を使用することが望ましい。たとえば、水溶性抗酸化剤を水相中2.5~65重量%含有し、さらに糖質を、水相中の水溶性固形分が合計18~79重量%となるように添加された水相1~38重量%が、油相中に分散されている、水分0.5~18重量%を含有する抗酸化油脂組成物が配合された高度不飽和脂肪酸含有油脂を使用することが望ましい。
Various types of fats and oils containing highly unsaturated fatty acids can be used. Typically, fish oil can be raised.
In use, it is desirable to use highly unsaturated fatty acid-containing fats and oils that have undergone some antioxidant treatment. For example, an aqueous phase containing 2.5 to 65% by weight of a water-soluble antioxidant and further added with a saccharide so that the total amount of water-soluble solids in the aqueous phase is 18 to 79% by weight. It is desirable to use highly unsaturated fatty acid-containing fats and oils formulated with an antioxidant fat and oil composition containing 0.5 to 18% by weight of water, in which 1 to 38% by weight is dispersed in the oil phase.
 本発明においては、チョコレート様食品中に乳製品を5~15質量%含有する必要があり、この量はより望ましくは7~14質量%であり、更に望ましくは8~13質量%である。適当な量の乳製品が含有されていることで、その効果が期待できる。
 なお、ここで言う乳製品としては、具体的には全粉乳、脱脂粉乳、ホエイパウダー、乳タンパクを挙げることができ、より望ましくは脱脂粉乳、ホエイパウダーであり、更に望ましくはホエイパウダーである。望ましいとされる乳製品を1以上使用することで、経時的な風味変化が抑制されたチョコレート様食品を得ることができる。 
 なお、本発明でいう乳タンパクとは、乳に由来する蛋白質成分を含む素材のうち、全粉乳(即ち全脂粉乳)、脱脂粉乳、及びホエイパウダーに分類されない素材をいう。
In the present invention, it is necessary to contain 5 to 15% by mass of the dairy product in the chocolate-like food, and this amount is more desirably 7 to 14% by mass, and further desirably 8 to 13% by mass. The effect can be expected by containing an appropriate amount of dairy products.
Specific examples of the dairy product mentioned here include whole milk powder, skim milk powder, whey powder and milk protein, more preferably skim milk powder and whey powder, and more preferably whey powder. By using one or more desirable dairy products, it is possible to obtain a chocolate-like food in which a change in flavor over time is suppressed.
In addition, the milk protein as used in the field of this invention means the raw material which is not classified into whole milk powder (namely, whole milk powder), skim milk powder, and whey powder among the raw materials containing the protein component derived from milk.
 本発明に係るチョコレート様食品においては、上記の他、チョコレート様食品の製造に一般的に使用される各種の原材料を、本発明の効果に影響を与えない範囲で適宜使用することができる。 
以下、実施例を記載する。
In the chocolate-like food according to the present invention, in addition to the above, various raw materials generally used for the production of chocolate-like food can be appropriately used as long as the effects of the present invention are not affected.
Examples will be described below.
表1の配合に従いアイスコーチングチョコを調製した。調製法は「○アイスコーチングチョコの調製法」に従った。
得られたサンプルは、「○アイスコーチングチョコの評価法」に従い評価を行なった。
結果を表2に示した。
Ice coating chocolate was prepared according to the formulation shown in Table 1. The preparation method followed “○ Preparation method of ice-coating chocolate”.
The obtained sample was evaluated according to “Evaluation method of ice coating chocolate”.
The results are shown in Table 2.
表1 配合
Figure JPOXMLDOC01-appb-I000001
・植物油脂には、スーパーパームオレインである不二製油株式会社製「パームエース10」に、EPAとDHAの合計がアイスコーチングチョコ中に2.8質量%となるように、EPAとDHAを含む油脂を混合したものを使用した。
・EPAとDHAを含む油脂には、ビタミンC,カテキン、砂糖が合計58質量%含有する水相19質量%が、油溶性乳化剤を含む油相81質量%中に微分散された抗酸化油脂組成物を加配されたものを使用した。
Table 1 Formulation
Figure JPOXMLDOC01-appb-I000001
-Vegetable oils and fats include EPA and DHA so that "Palm Ace 10" manufactured by Fuji Oil Co., Ltd., which is Super Palm Olein, has a total amount of EPA and DHA of 2.8% by mass in ice-coating chocolate. A mixture of fats and oils was used.
・ An oil and fat composition containing EPA and DHA contains 19% by mass of an aqueous phase containing 58% by mass of vitamin C, catechin, and sugar finely dispersed in 81% by mass of an oil phase containing an oil-soluble emulsifier. The thing to which the thing was distributed was used.
○アイスコーチングチョコの調製法
1 配合表に従い、レシチン及び植物油脂の一部以外の原材料を混合した。
2 ロールリファイナーで微粒子化した。
3 コンチェにて加温しながら練った。
4 レシチン及び1で添加しなかった植物油脂を添加し、混合した。
○ Preparation method 1 of ice-coating chocolate According to the recipe, raw materials other than lecithin and part of vegetable oil were mixed.
2 Fine-grained with a roll refiner.
3 Kneaded while heating in Conche.
4 Lecithin and vegetable oil not added in 1 were added and mixed.
○アイスコーチングチョコの評価法
1.各検討サンプル1000gを、1000ml容の茶色のプラスチック瓶に入れ、蓋をした。
2.40℃にて保管した。
3.6日目、14日目、21日目に、風味評価を行なった。評価は、熟練したパネラー3名の合議により、以下の基準にて行なった。
 5点 魚臭さを感じないもの。
 4点 わずかながら、チョコとは異なる風味を感じるもの。
 3点 魚臭と認識できる風味を感じるもの。
 2点 強い魚臭を感じるもの。
 1点 より強い魚臭を感じるもの。
14日目の段階で4点以上を合格とした。
○ Evaluation method for ice-coating chocolate 1000 g of each study sample was placed in a 1000 ml brown plastic bottle and capped.
2. Stored at 40 ° C.
3. Flavor evaluation was performed on the 6th, 14th and 21st days. The evaluation was made according to the following criteria by the consensus of three skilled panelists.
5 points No fishy odor.
4 Slightly different flavor than chocolate.
3 A taste that can be recognized as a fishy odor.
Two points with a strong fishy odor.
1 point Feels a stronger fish odor.
On the 14th day, 4 or more points were accepted.
表2 結果
Figure JPOXMLDOC01-appb-I000002
Table 2 Results
Figure JPOXMLDOC01-appb-I000002
考察
結果に示すように、各種乳製品を使用することで、高度不飽和脂肪酸に由来する魚臭を抑制する効果が確認された。特に、ホエイパウダーを使用した場合に、その効果が顕著に高かった。
As shown in the discussion results, the effect of suppressing fishy odor derived from highly unsaturated fatty acids was confirmed by using various dairy products. In particular, when whey powder was used, the effect was remarkably high.

Claims (3)

  1. 高度不飽和脂肪酸を0.02~10質量%含有し、かつ、乳製品を5~15質量%含有する、チョコレート様食品。 A chocolate-like food containing 0.02 to 10% by mass of a highly unsaturated fatty acid and 5 to 15% by mass of a dairy product.
  2. 乳製品が、全粉乳、脱脂粉乳、ホエイパウダー、乳タンパクから選ばれる1以上である、請求項1記載の、チョコレート様食品。 2. The chocolate-like food according to claim 1, wherein the dairy product is one or more selected from whole milk powder, skim milk powder, whey powder, and milk protein.
  3. 全粉乳、脱脂粉乳、ホエイパウダー、乳タンパクから選ばれる1以上の乳製品を5~15質量%含有させる、高度不飽和脂肪酸を0.02~10質量%含有するチョコレート様食品における、異風味発生の抑制方法。  Occurrence of unusual flavor in chocolate-like foods containing 5 to 15% by mass of one or more dairy products selected from whole milk powder, skim milk powder, whey powder and milk protein, and 0.02 to 10% by mass of highly unsaturated fatty acids Suppression method.
PCT/JP2018/000144 2017-03-09 2018-01-09 Chocolate-like food containing highly unsaturated fatty acid, said food configured to suppress generation of unfavorable flavors WO2018163587A1 (en)

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WO2019069636A1 (en) * 2017-10-05 2019-04-11 不二製油グループ本社株式会社 White chocolate-like food containing highly unsaturated fatty acid
JP2020141631A (en) * 2019-03-08 2020-09-10 不二製油株式会社 Frozen desserts containing highly unsaturated fatty acids

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JP6969618B2 (en) * 2019-03-08 2021-11-24 不二製油株式会社 Ice cream containing polyunsaturated fatty acids

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JPH05292885A (en) * 1992-04-22 1993-11-09 Asahi Denka Kogyo Kk Chocolate composition
JP2000355538A (en) * 1999-04-15 2000-12-26 Kanegafuchi Chem Ind Co Ltd Peroxisome activator-responsive receptor agonist
KR20050007718A (en) * 2003-07-11 2005-01-21 네오메가(주) A composition containing docosahexaenoic acid
JP2013506423A (en) * 2009-09-30 2013-02-28 ソレイ リミテッド ライアビリティ カンパニー ω3 fatty acid enriched shortening and nut butter

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JPH05292885A (en) * 1992-04-22 1993-11-09 Asahi Denka Kogyo Kk Chocolate composition
JP2000355538A (en) * 1999-04-15 2000-12-26 Kanegafuchi Chem Ind Co Ltd Peroxisome activator-responsive receptor agonist
KR20050007718A (en) * 2003-07-11 2005-01-21 네오메가(주) A composition containing docosahexaenoic acid
JP2013506423A (en) * 2009-09-30 2013-02-28 ソレイ リミテッド ライアビリティ カンパニー ω3 fatty acid enriched shortening and nut butter

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2019069636A1 (en) * 2017-10-05 2019-04-11 不二製油グループ本社株式会社 White chocolate-like food containing highly unsaturated fatty acid
JP2020141631A (en) * 2019-03-08 2020-09-10 不二製油株式会社 Frozen desserts containing highly unsaturated fatty acids

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