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WO2018001346A1 - Low alloy cast steel, and smelting method and heat treatment thereof, and railway locomotive part of same - Google Patents

Low alloy cast steel, and smelting method and heat treatment thereof, and railway locomotive part of same Download PDF

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WO2018001346A1
WO2018001346A1 PCT/CN2017/091007 CN2017091007W WO2018001346A1 WO 2018001346 A1 WO2018001346 A1 WO 2018001346A1 CN 2017091007 W CN2017091007 W CN 2017091007W WO 2018001346 A1 WO2018001346 A1 WO 2018001346A1
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alloy cast
cast steel
low alloy
weight percentage
low
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PCT/CN2017/091007
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French (fr)
Chinese (zh)
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张俊新
文超
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中车戚墅堰机车车辆工艺研究所有限公司
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Publication of WO2018001346A1 publication Critical patent/WO2018001346A1/en

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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/02Ferrous alloys, e.g. steel alloys containing silicon
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21CPROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
    • C21C5/00Manufacture of carbon-steel, e.g. plain mild steel, medium carbon steel or cast steel or stainless steel
    • C21C5/52Manufacture of steel in electric furnaces
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21CPROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
    • C21C7/00Treating molten ferrous alloys, e.g. steel, not covered by groups C21C1/00 - C21C5/00
    • C21C7/04Removing impurities by adding a treating agent
    • C21C7/068Decarburising
    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D1/00General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
    • C21D1/26Methods of annealing
    • C21D1/28Normalising
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/04Ferrous alloys, e.g. steel alloys containing manganese
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/06Ferrous alloys, e.g. steel alloys containing aluminium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/12Ferrous alloys, e.g. steel alloys containing tungsten, tantalum, molybdenum, vanadium, or niobium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/18Ferrous alloys, e.g. steel alloys containing chromium
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/20Recycling

Definitions

  • the invention belongs to the technical field of alloy steel, and relates to a low alloy cast steel, in particular to a low alloy cast steel containing tungsten ruthenium, a smelting method and a heat treatment method of the low alloy cast steel, a B+ grade steel obtained after heat treatment, and Mainly applied to the railway locomotive parts prepared by the B+ grade steel.
  • the alloy cast steel was graded and classified as A grade steel.
  • the American Railway Association (AAR) M-201-05 standard specifies B+ grade steel, which cannot be applied to the B+ grade performance by quenching and tempering heat treatment.
  • AAR American Railway Association
  • B+ grade steel in order to meet the mechanical performance requirements of B+ grade steel and not use quenching and tempering treatment, it is necessary to use chromium-nickel-molybdenum and chromium-nickel alloys and design blending alloy components, such as Chinese patent disclosure.
  • No. B+ grade steel disclosed in the related patents of CN1995429A and CN101701325A Therefore, in the current B+ grade steel, it is necessary to compound and add the more expensive alloying element nickel.
  • the present invention provides the following technical solutions.
  • a low alloy cast steel the components thereof and their weight percentage relative to the total weight of the low alloy cast steel are:
  • a heat treatment method for the above low alloy cast steel comprising the steps of:
  • the steel casting is subjected to normalizing treatment, wherein the normalizing treatment is: heating the steel casting to 900 ° C to 940 ° C for 3 to 6 hours, and then cooling the air to room temperature.
  • the normalizing treatment is: heating the steel casting to 900 ° C to 940 ° C for 3 to 6 hours, and then cooling the air to room temperature.
  • a B+ grade steel obtained by treating the above low alloy cast steel by the above heat treatment method.
  • a smelting method for the above low alloy cast steel wherein the smelting is carried out by an electric arc furnace oxidation method, comprising the steps of:
  • Loading step based on the component requirements, the corresponding charge is put into the electric arc furnace, wherein the furnace charge comprises ferromolybdenum and tungsten iron;
  • Oxidation period step when the bath temperature is greater than or equal to 1560 ° C, iron ore is added to the electric arc furnace to decarburize, and dephosphorization operation is performed;
  • the tapping water step and the pouring step are The tapping water step and the pouring step.
  • a railway locomotive component which is formed using the B+ grade steel described above.
  • the low alloy cast steel of the invention adds the alloying elements tungsten and niobium, and selects the appropriate ratio, thereby effectively suppressing austenite grain growth during the casting process, and refining the crystal. Granules, while strengthening the matrix.
  • the metallographic structure of the obtained low-alloy cast steel is mainly pearlite + ferrite, and the mechanical properties of the M-201 are AAR-
  • the requirements of B+ grade steel in the 05 standard the cost of B+ grade steel is greatly reduced.
  • in terms of hardness for example, it can fall within the range of 150 HBW to 180 HBW from the hardness index
  • it is particularly good from the viewpoint of carbon equivalent, the carbon equivalent of the low alloy cast steel is lowered, and the weldability is improved; the tensile strength is improved.
  • Performance indicators such as yield strength can also reflect the strengthening of the matrix of low alloy cast steel.
  • Fig. 1 is a photograph showing a metallographic structure of a low alloy cast steel obtained by a normalizing treatment in accordance with an embodiment of the present invention.
  • FIG. 2 is a picture of a metallographic structure obtained by magnifying 500 times of a low alloy cast steel after normalizing treatment according to an embodiment of the present invention.
  • low alloy cast steel refers to alloy steel with a alloying element content of less than 5% by weight in cast steel.
  • B+ grade steel was revised and released in 2005 according to the American Railroad Association (AAR). The steel grade defined by the 201-05 standard for alloy steel classification.
  • the inventors of the present application have found that with the increase in the cost of raw materials required for the production of B+ grade steel, the industry has put forward higher requirements for controlling the cost of B+ grade steel, and is working to reduce the cost of B+ grade steel, but simply saves it. Or the use of expensive nickel components can not be obtained to meet the mechanical performance requirements of B+ grade steel (in the case where quenching and tempering is not required); the inventors of the present application also noted that the introduction of tungsten can be used for low alloy cast steel. The pearlite and bainite transformation have a great influence, which is beneficial to reduce the overheat sensitivity and strength of the cast steel.
  • the measurement of mechanical properties is carried out in accordance with the relevant provisions of the M-201-05 standard of AAR, and the sample used for the measurement of mechanical properties is a Kiel test block.
  • the low-alloy cast steel according to any one of claims 1 to 11, wherein The carbon equivalent CE of the low alloy cast steel is between 0.45% and 0.62%, and the carbon equivalent CE is calculated according to the following formula:
  • C represents the weight percentage of carbon
  • Mn represents the weight percentage of manganese
  • Si represents the weight percentage of silicon
  • Cr represents the weight percentage of chromium
  • Mo represents the weight percentage of molybdenum
  • V represents the weight percentage of vanadium
  • Ni represents the weight percentage of nickel.
  • Cu represents the weight percentage of copper.
  • the steel casting is subjected to normalizing treatment, wherein the normalizing treatment is: heating the steel casting to 900 ° C to 940 ° C for 3 to 6 hours, and then cooling the air to room temperature.
  • the normalizing treatment is: heating the steel casting to 900 ° C to 940 ° C for 3 to 6 hours, and then cooling the air to room temperature.
  • the invention provides a B+ grade steel obtained by treating the low alloy cast steel according to any one of claims 16 to 18 by the heat treatment method according to any one of claims 16 to 18.
  • Loading step based on the component requirements, the corresponding charge is put into the electric arc furnace, wherein the furnace charge comprises ferromolybdenum and tungsten iron;
  • Oxidation period step when the bath temperature is greater than or equal to 1560 ° C, iron ore is added to the electric arc furnace to decarburize, and dephosphorization operation is performed;
  • the weight percentage of each chemical component of the cast steel is required to add at least the charge containing at least the strontium iron alloy to the electric arc furnace;
  • the tapping water step and the pouring step are The tapping water step and the pouring step.
  • the tungsten iron is of a grade of FeW75, wherein the weight percentage of W is 75%.
  • Ferroalloy including at least strontium iron alloy; of course, if it is not required, that is, if the sampling analysis indicates that a chemical component has satisfied the weight percentage requirement of the chemical composition of the low alloy cast steel, then it is not necessary to add The corresponding material containing the chemical composition.
  • the component contents are all based on their weight percentage.
  • the components and their weight percentages are as follows: carbon 0.24%, silicon 0.42%, manganese 1.13%, phosphorus 0.026%, sulfur 0.019%, chromium 0.26%, molybdenum 0.14%, aluminum 0.02%, tungsten 0.07%, ⁇ 0.03%, of which tungsten + bismuth is 0.10%, the balance is iron and other unavoidable elements.
  • the carbon equivalent in the low alloy cast steel of the embodiment 1 is specifically 0.58, which satisfies the carbon equivalent requirement of the B-grade steel of the M-201-05 standard of AAR, and therefore the weldability is good. .
  • the tungsten-rhenium-containing low alloy cast steel of Example 1 can be, but is not limited to, prepared by the smelting method exemplified below.
  • the smelting is performed by an electric arc furnace large slag oxidation method, which specifically includes the following steps:
  • the base component is required to be put into the corresponding charge. Among them, a suitable amount of ferromolybdenum and tungsten iron is added to the furnace charge.
  • the tungsten iron is specifically made of tungsten iron of the grade of FeW75, which represents the weight percentage of W. About 75%.
  • the furnace charge generally includes, for example, scrap steel, high quality pig iron, iron alloy, recycled material, and the like.
  • the furnace material melting and slag dephosphorization treatment can be carried out at the maximum power matched by the electric arc furnace. When the charge is melted by 25% to 45%, the oxygen can be blown and the furnace charge can be accelerated.
  • the pure aluminum block, the silicon, the ferromanganese alloy and the neodymium iron alloy are added in a controlled manner, at least including the neodymium iron alloy; If necessary, that is, if the sampling analysis indicates that a chemical component has satisfied the weight percentage requirement of each chemical component of the low alloy cast steel, it is not necessary to add a corresponding material containing the chemical component.
  • the addition of the strontium iron alloy in the reduction period step is avoided, the oxidation reaction of the bismuth in the molten steel is avoided earlier, the enthalpy loss is reduced, and the percentage content of the lanthanum element in the low alloy cast steel after formation is ensured. Corresponding effect.
  • V tapping When the temperature of the molten pool is in the range of 1620 ⁇ 1650°C, the chemical composition operation is carried out by sampling and analyzing; after the composition is qualified, when the temperature reaches the tapping water temperature, the molten steel and steel slag are mixed and desulfurized.
  • the steel can be heat-treated to obtain a B+ grade steel having better performance.
  • the heat treatment process is normalized, and Avoid quenching and tempering after normalizing. Specifically, the normalizing treatment process is heated to 920 ° C for 4 hours, and then discharged to air cooling.
  • the metallographic structure obtained is mainly ferrite + pearlite, and the specific metallographic structure is shown in FIG. 1 and FIG. And Figure 2 shows a typical ferritic + pearlite metallographic morphology (where the dark gray black part is pearlite and the light gray part is ferrite), which avoids the appearance of bainite; and, the grain size Significantly refined, the uniformity of the structure is very good, because the tungsten and niobium in the low alloy cast steel can be combined to increase the austenite grain growth during the casting process, which is beneficial to refining the cast steel.
  • the grain, the pearlite grains of the low alloy cast steel obtained after the normalizing treatment are also relatively fine.
  • the addition of tungsten and niobium in a certain weight percentage is beneficial to strengthening the matrix.
  • the low alloy cast steel of the above Example 1 is subjected to the normalizing heat treatment of the above example After that, it can be used as a B+ grade steel, and it performs well in terms of hardness, strength, and weldability; and, depending on the addition of nickel, the cost is greatly reduced.
  • Table 1 Composition (% by weight) and carbon equivalent of the low alloy cast steel of Examples 2 to 10
  • the role of the alloying element aluminum is mainly used for deoxidation, and at the same time can achieve a certain degree of grain refining effect.
  • the low-alloy cast steel containing tungsten ruthenium of Examples 2 to 10 can be, but is not limited to, prepared by the smelting method exemplified above to obtain a corresponding steel casting.
  • the heat treatment can be performed to obtain the B+ grade steel with better performance.
  • the heat treatment process is normalized; in particular, positive
  • the steel castings are usually heated to 900 ° C ⁇ 940 ° C for 3 to 6 hours, and then air cooled to room temperature. Further optimization of normalizing treatment, the steel castings can be heated to 920 ° C ⁇ 930 ° C for 4 to 5 hours.
  • the metallographic structure obtained is mainly pearlite + ferrite, and the specific metallographic structure is similar to that shown in Figs. 1 and 2.
  • the low alloy cast steel based on the above Examples 2 to 10 can obtain B+ grade steel satisfying the mechanical performance requirements of the B+ grade cast steel of the American Railway Association Standard M-201-05; and in terms of hardness (for example, from the hardness index) It can fall well in the range of 150HBW to 180HBW), especially in terms of carbon equivalent, the carbon equivalent of low alloy cast steel decreases, weldability is improved; performance indexes such as tensile strength and yield strength can also reflect low alloy casting.
  • the matrix of the steel is strengthened.
  • the low-alloy cast steels of the above Examples 1 to 10 can be used as B+ grade steel after the normalizing heat treatment of the above examples, and have superior weldability, good hardness and strength, and in particular, cost is large. reduce.
  • the low alloy cast steels of the above embodiments 1 to 10 can be used without being used.
  • Nickel is used as an alloying element to obtain good mechanical properties.
  • the alloying elements tungsten and rhenium are compounded and a suitable ratio (tungsten 0.02% to 0.10%, ⁇ 0.01% to 0.05%, and must be satisfied) 0.04% ⁇ tungsten + ⁇ ⁇ 0.12%), can effectively inhibit austenite grain growth during casting, refine grains, and strengthen the matrix; therefore, the low alloy cast steel in the embodiment of the present application After the normalized heat treatment process, the hardness of the low alloy cast steel is obviously improved compared with the traditional B+ grade steel, and the strength is high and the weldability is superior, and the overall mechanical performance requirements of the B+ grade steel are satisfied.
  • the low alloy cast steels of the above embodiments 1 to 10 can be used to prepare corresponding parts on a railway locomotive after normalizing, for example, key components in a bogie such as a bolster, a side frame, and the like. It should be understood that the specific application of the low alloy cast steel of the above embodiment is not limited to the above embodiment, and those skilled in the art can also use it for components on railway machines or other equipment having substantially the same mechanical performance requirements, such as wheels. core.

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Abstract

A low alloy cast steel, and a smelting method and heat treatment thereof, and a railway locomotive part of same. The low alloy cast steel comprises the following components in the respective weight percentages: 0.19-0.25% of carbon, 0.30-0.50% of silicon, 0.90-1.15% of manganese, ≤ 0.030% of phosphorus, ≤ 0.030% of sulfur, 0.19-0.29% of chromium, 0.13-0.19% of molybdenum, 0.02-0.06% of aluminum, 0.02-0.10% of tungsten, and 0.01-0.05% of niobium, wherein 0.04% ≤ tungsten + niobium ≤ 0.12%; and a remainder of iron and other unavoidable elements. After heat treatment, the steel can be used as a Grade B+ steel.

Description

低合金铸钢及其冶炼方法、热处理方法和铁路机车零部件Low alloy cast steel and its smelting method, heat treatment method and railway locomotive parts 技术领域Technical field
本发明属于合金钢技术领域,涉及一种低合金铸钢,特别涉及一种含钨铌的低合金铸钢、该低合金铸钢的冶炼方法和热处理方法、热处理后获得的B+级钢、以及主要应用该B+级钢制备的铁路机车零部件。The invention belongs to the technical field of alloy steel, and relates to a low alloy cast steel, in particular to a low alloy cast steel containing tungsten ruthenium, a smelting method and a heat treatment method of the low alloy cast steel, a B+ grade steel obtained after heat treatment, and Mainly applied to the railway locomotive parts prepared by the B+ grade steel.
背景技术Background technique
美国铁路协会(AAR)于2005年修订并发布了M-201-05标准,以满足诸如铁道行业铸造零部件的材质需求,其中对合金铸钢进行了分级定义,其被分为A级钢、B级钢、B+级钢、C级钢和E级钢,并且相应地定义它们的主要化学成分范围和机械性能等。The American Railway Association (AAR) revised and released the M-201-05 standard in 2005 to meet the material requirements of cast parts such as the railway industry. The alloy cast steel was graded and classified as A grade steel. Grade B steel, B+ grade steel, C grade steel and E grade steel, and define their main chemical composition range and mechanical properties.
美国铁路协会(AAR)M-201-05的标准中对B+级钢规定,其不能应用调质热处理工艺获得B+级性能。目前,广泛使用的B+级钢中,为满足B+级钢的机械性能要求且不使用调质处理,需要采用铬-镍-钼系和铬-镍系合金并设计调配合金成分,诸如中国专利公开号为CN1995429A、CN101701325A的相关专利中公开的B+级钢。因此,目前的B+级钢中都需要复合添加较昂贵的合金元素镍的。The American Railway Association (AAR) M-201-05 standard specifies B+ grade steel, which cannot be applied to the B+ grade performance by quenching and tempering heat treatment. At present, in the widely used B+ grade steel, in order to meet the mechanical performance requirements of B+ grade steel and not use quenching and tempering treatment, it is necessary to use chromium-nickel-molybdenum and chromium-nickel alloys and design blending alloy components, such as Chinese patent disclosure. No. B+ grade steel disclosed in the related patents of CN1995429A and CN101701325A. Therefore, in the current B+ grade steel, it is necessary to compound and add the more expensive alloying element nickel.
然而,随着镍在不锈钢和耐热钢领域的广泛使用,使得镍资源日趋匮乏,使得B+级钢的成本也日趋增加。However, with the widespread use of nickel in the fields of stainless steel and heat-resistant steel, nickel resources are becoming increasingly scarce, and the cost of B+ grade steel is also increasing.
发明内容Summary of the invention
本发明的目的在于,降低低合金铸钢的成本且使其能够对应至少满足B+级钢的机械性能要求。It is an object of the present invention to reduce the cost of low alloy cast steel and to enable it to at least meet the mechanical performance requirements of B+ grade steel.
为实现以上目的或者其他目的,本发明提供以下技术方案。To achieve the above object or other objects, the present invention provides the following technical solutions.
按照本发明的第一方面,提供一种低合金铸钢,其各组分及其相对于所述低合金铸钢总重的重量百分比为:According to a first aspect of the invention, there is provided a low alloy cast steel, the components thereof and their weight percentage relative to the total weight of the low alloy cast steel are:
碳0.19%~0.25%、硅0.30%~0.50%、锰0.90%~1.15%、磷≤0.030%、硫≤0.030%、铬0.19%~0.29%、钼0.13%~0.19%、铝0.02%~0.06%、以及钨0.02%~0.10%、铌0.01%~0.05%,且必须满足0.04%≤钨+铌≤0.12%;以及余量为铁和其他不可避免的元素。 Carbon 0.19% to 0.25%, silicon 0.30% to 0.50%, manganese 0.90% to 1.15%, phosphorus ≤0.030%, sulfur ≤0.030%, chromium 0.19% to 0.29%, molybdenum 0.13% to 0.19%, aluminum 0.02% to 0.06 %, and 0.02% to 0.10% of tungsten, 铌0.01% to 0.05%, and must satisfy 0.04% ≤ tungsten + 铌 ≤ 0.12%; and the balance is iron and other unavoidable elements.
按照本发明的第二方面,提供一种上述低合金铸钢的热处理方法,其包括步骤:According to a second aspect of the present invention, there is provided a heat treatment method for the above low alloy cast steel, comprising the steps of:
提供所述低合金铸钢的铸钢件;以及Providing a steel casting of the low alloy cast steel;
对所述铸钢件进行正火处理,其中,所述正火处理为:将铸钢件加热到900℃~940℃保温3~6小时,然后出炉空冷到室温。The steel casting is subjected to normalizing treatment, wherein the normalizing treatment is: heating the steel casting to 900 ° C to 940 ° C for 3 to 6 hours, and then cooling the air to room temperature.
按照本发明的第三方面,提供一种上述低合金铸钢通过上述热处理方法处理后获得的B+级钢。According to a third aspect of the present invention, there is provided a B+ grade steel obtained by treating the above low alloy cast steel by the above heat treatment method.
按照本发明的第四方面,提供一种上述低合金铸钢的冶炼方法,其中采用电弧炉氧化法进行冶炼,包括以下步骤:According to a fourth aspect of the present invention, there is provided a smelting method for the above low alloy cast steel, wherein the smelting is carried out by an electric arc furnace oxidation method, comprising the steps of:
装料步骤:基于组分要求,将相应的炉料投入所述电弧炉内,其中入炉炉料包括钼铁和钨铁;Loading step: based on the component requirements, the corresponding charge is put into the electric arc furnace, wherein the furnace charge comprises ferromolybdenum and tungsten iron;
对炉料进行熔化的熔化期步骤;a melting step of melting the charge;
氧化期步骤:在熔池温度大于或等于1560℃时,向所述电弧炉内加入铁矿石以脱碳,并进行脱磷操作;Oxidation period step: when the bath temperature is greater than or equal to 1560 ° C, iron ore is added to the electric arc furnace to decarburize, and dephosphorization operation is performed;
还原期步骤:向所述电弧炉内加入铬铁合金,并且根据取样分析化学成分的检测结果,将该结果与所述低合金铸钢的各化学成分的重量百分比进行比对,向所述电弧炉内至少加入铌铁合金;以及a reduction period step of: adding a ferrochrome alloy to the electric arc furnace, and comparing the result with a weight percentage of each chemical component of the low alloy cast steel according to the detection result of the sampling analysis chemical composition, to the electric arc furnace At least iron-iron alloy is added to the inside;
出钢水步骤和浇注步骤。The tapping water step and the pouring step.
按照本发明的第五方面,提供一种铁路机车零部件,其采用以上所述的B+级钢制备形成。According to a fifth aspect of the invention, there is provided a railway locomotive component which is formed using the B+ grade steel described above.
本发明的低合金铸钢为了避免或节约使用镍,复合添加了合金元素钨和铌,并选择其合适的配比,则能有效地抑制铸造过程中奥氏体晶粒长大,细化晶粒,同时强化基体。In order to avoid or save the use of nickel, the low alloy cast steel of the invention adds the alloying elements tungsten and niobium, and selects the appropriate ratio, thereby effectively suppressing austenite grain growth during the casting process, and refining the crystal. Granules, while strengthening the matrix.
并且,本发明的低合金铸钢经过本发明的正火热处理工艺以后,所获得低合金铸钢的金相组织主要为珠光体+铁素体,且其机械性能指标满AAR的M-201-05标准中B+级钢的要求,B+级钢的成本得到大大降低。另外,在硬度方面(例如从硬度指标来看其能够落入150HBW至180HBW的范围)尤其表现良好;从碳当量来看,低合金铸钢的碳当量下降,可焊性得到提升;抗拉强度和屈服强度等性能指标也可以反映低合金铸钢的基体得到强化。Moreover, after the low-alloy cast steel of the present invention is subjected to the normalizing heat treatment process of the present invention, the metallographic structure of the obtained low-alloy cast steel is mainly pearlite + ferrite, and the mechanical properties of the M-201 are AAR- The requirements of B+ grade steel in the 05 standard, the cost of B+ grade steel is greatly reduced. In addition, in terms of hardness (for example, it can fall within the range of 150 HBW to 180 HBW from the hardness index), it is particularly good; from the viewpoint of carbon equivalent, the carbon equivalent of the low alloy cast steel is lowered, and the weldability is improved; the tensile strength is improved. Performance indicators such as yield strength can also reflect the strengthening of the matrix of low alloy cast steel.
附图说明 DRAWINGS
图1是按照本发明一实施例的低合金铸钢经正火处理后获得放大100倍的金相组织图片。BRIEF DESCRIPTION OF THE DRAWINGS Fig. 1 is a photograph showing a metallographic structure of a low alloy cast steel obtained by a normalizing treatment in accordance with an embodiment of the present invention.
图2是按照本发明一实施例的低合金铸钢经正火处理后获得放大500倍的金相组织图片。2 is a picture of a metallographic structure obtained by magnifying 500 times of a low alloy cast steel after normalizing treatment according to an embodiment of the present invention.
具体实施方式detailed description
下面介绍的是本发明的多个可能实施例中的一些,旨在提供对本发明的基本了解,并不旨在确认本发明的关键或决定性的要素或限定所要保护的范围。容易理解,根据本发明的技术方案,在不变更本发明的实质精神下,本领域的一般技术人员可以提出可相互替换的其他实现方式。因此,以下具体实施方式以及附图仅是对本发明的技术方案的示例性说明,而不应当视为本发明的全部或者视为对本发明技术方案的限定或限制。The following is a description of some of the various possible embodiments of the invention, which are intended to provide a basic understanding of the invention and are not intended to identify key or critical elements of the invention or the scope of the invention. It is to be understood that, in accordance with the technical aspects of the present invention, those skilled in the art can suggest other alternatives that are interchangeable without departing from the spirit of the invention. Therefore, the following detailed description and the accompanying drawings are merely illustrative of the embodiments of the invention, and are not intended to
在本申请中,“低合金铸钢”是指铸钢中合金元素含量小于5%(重量百分比)的合金钢,B+级钢是按照美国铁路协会(AAR)于2005年修订并发布了M-201-05标准对合金钢分级定义的钢种。In the present application, "low alloy cast steel" refers to alloy steel with a alloying element content of less than 5% by weight in cast steel. B+ grade steel was revised and released in 2005 according to the American Railroad Association (AAR). The steel grade defined by the 201-05 standard for alloy steel classification.
本申请发明人发现,目前随着生产B+级钢所需原材料成本的提高,行业对控制B+级钢的成本提出了更高要求,并致力于降低B+级钢的成本,但是,简单地省去或节约昂贵的镍组分的使用量并不能获得满足B+级钢机械性能要求(在要求不进行调质处理的情况下);本申请发明人还注意到,钨的引入可以对低合金铸钢的珠光体和贝氏体相变产生很大的影响,有利于降低铸钢的过热敏感性、提高强度。The inventors of the present application have found that with the increase in the cost of raw materials required for the production of B+ grade steel, the industry has put forward higher requirements for controlling the cost of B+ grade steel, and is working to reduce the cost of B+ grade steel, but simply saves it. Or the use of expensive nickel components can not be obtained to meet the mechanical performance requirements of B+ grade steel (in the case where quenching and tempering is not required); the inventors of the present application also noted that the introduction of tungsten can be used for low alloy cast steel. The pearlite and bainite transformation have a great influence, which is beneficial to reduce the overheat sensitivity and strength of the cast steel.
本发明一实施例中,机械性能的测定依据的是AAR的M-201-05标准的相关规定进行的,机械性能的测定所用的试样为基尔试块。其中碳当量CE的计算公式为:CE=C+(Mn+Si)/6+(Cr+Mo+V)/5+(Ni+Cu)/15,其中,以上公式中的某些合金元素,有可能是不可避免的余量元素。In one embodiment of the present invention, the measurement of mechanical properties is carried out in accordance with the relevant provisions of the M-201-05 standard of AAR, and the sample used for the measurement of mechanical properties is a Kiel test block. The calculation formula of carbon equivalent CE is: CE=C+(Mn+Si)/6+(Cr+Mo+V)/5+(Ni+Cu)/15, among which some alloy elements in the above formula have May be an inevitable margin element.
本申请提供以下技术方案:The application provides the following technical solutions:
技术方案1,一种低合金铸钢,其中,各组分及其相对于所述低合金铸钢总重的重量百分比为:Technical Solution 1, a low alloy cast steel, wherein each component and its weight percentage relative to the total weight of the low alloy cast steel are:
碳0.19%~0.25%、硅0.30%~0.50%、锰0.90%~1.15%、磷≤0.030%、硫≤0.030%、铬0.19%~0.29%、钼0.13%~0.19%、铝0.02%~ 0.06%、以及钨0.02%~0.10%、铌0.01%~0.05%,且必须满足0.04%≤钨+铌≤0.12%;以及余量为铁和其他不可避免的元素。Carbon 0.19% to 0.25%, silicon 0.30% to 0.50%, manganese 0.90% to 1.15%, phosphorus ≤0.030%, sulfur ≤0.030%, chromium 0.19% to 0.29%, molybdenum 0.13% to 0.19%, aluminum 0.02% 0.06%, and 0.02% to 0.10% of tungsten, 铌0.01% to 0.05%, and must satisfy 0.04% ≤ tungsten + 铌 ≤ 0.12%; and the balance is iron and other unavoidable elements.
技术方案2,如技术方案1所述的低合金铸钢,其中,相对于所述低合金铸钢总重,碳的重量百分比为0.20%~0.24%,0.21%~0.24%,或者0.20%~0.25%。The low-alloy cast steel according to claim 1, wherein the weight percentage of carbon is 0.20% to 0.24%, 0.21% to 0.24%, or 0.20% by weight relative to the total weight of the low alloy cast steel. 0.25%.
技术方案3,如技术方案1-2任一所述的低合金铸钢,其中,相对于所述低合金铸钢总重,硅的重量百分比为0.33%~0.39%,或者0.36%~0.47%,或者0.33%~0.45%,或者0.36%~0.42%。The low alloy cast steel according to any one of claims 1-2, wherein the weight percentage of silicon is 0.33% to 0.39%, or 0.36% to 0.47%, relative to the total weight of the low alloy cast steel. , or 0.33% to 0.45%, or 0.36% to 0.42%.
技术方案4,如技术方案1-3任一所述的低合金铸钢,其中,相对于所述低合金铸钢总重,锰的重量百分比为0.91%~1.14%,或者0.98%~1.15%,或者0.98%~1.13%。The low-alloy cast steel according to any one of claims 1 to 3, wherein the weight percentage of manganese is 0.91% to 1.14%, or 0.98% to 1.15%, relative to the total weight of the low alloy cast steel. , or 0.98% to 1.13%.
技术方案5,如技术方案1-4任一所述的低合金铸钢,其中,相对于所述低合金铸钢总重,磷的重量百分比≤0.025%,或者≤0.020%。The low alloy cast steel according to any one of claims 1 to 4, wherein the weight percentage of phosphorus is ≤0.025% or ≤0.020% with respect to the total weight of the low alloy cast steel.
技术方案6,如技术方案1-5任一所述的低合金铸钢,其中,相对于所述低合金铸钢总重,硫的重量百分比≤0.025%,或者≤0.020%,或者≤0.015%。The low-alloy cast steel according to any one of claims 1 to 5, wherein the weight percentage of sulfur is ≤0.025%, or ≤0.020%, or ≤0.015%, relative to the total weight of the low alloy cast steel. .
技术方案7,如技术方案1-6任一所述的低合金铸钢,其中,相对于所述低合金铸钢总重,铬的重量百分比为0.20%~0.29%,或者0.23%~0.29%,或者0.24%~0.28%,或者0.24%~0.29%。The low alloy cast steel according to any one of claims 1 to 6, wherein the weight percentage of chromium is 0.20% to 0.29%, or 0.23% to 0.29%, relative to the total weight of the low alloy cast steel. , or 0.24% to 0.28%, or 0.24% to 0.29%.
技术方案8,如技术方案1-7任一所述的低合金铸钢,其中,相对于所述低合金铸钢总重,钼的重量百分比为0.13%~0.18%,或者0.14%~0.18%,或者0.15%~0.18%。The low-alloy cast steel according to any one of claims 1 to 7, wherein the weight percentage of molybdenum is 0.13% to 0.18%, or 0.14% to 0.18%, relative to the total weight of the low alloy cast steel. , or 0.15% to 0.18%.
技术方案9,如技术方案1-8任一所述的低合金铸钢,其中,相对于所述低合金铸钢总重,铝的重量百分比为0.02%~0.04%,或者0.03%~0.05%。The low alloy cast steel according to any one of claims 1 to 8, wherein the weight percentage of aluminum is 0.02% to 0.04%, or 0.03% to 0.05%, based on the total weight of the low alloy cast steel. .
技术方案10,如技术方案1-9任一所述的低合金铸钢,其中,相对于所述低合金铸钢总重,铌的重量百分比为0.02%~0.04%,或者0.03%~0.05%。The low-alloy cast steel according to any one of claims 1-9, wherein the weight percentage of bismuth is 0.02% to 0.04%, or 0.03% to 0.05%, relative to the total weight of the low alloy cast steel. .
技术方案11,如技术方案1-10任一所述的低合金铸钢,其中,相对于所述低合金铸钢总重,钨的重量百分比为0.02%~0.09%,或者0.05%~0.09%。The low-alloy cast steel according to any one of claims 1 to 10, wherein the weight percentage of tungsten is 0.02% to 0.09%, or 0.05% to 0.09%, relative to the total weight of the low alloy cast steel. .
技术方案12,如技术方案1-11任一所述的低合金铸钢,其中, 所述低合金铸钢的碳当量CE在0.45%~0.62%之间,所述碳当量CE按照以下公式计算:The low-alloy cast steel according to any one of claims 1 to 11, wherein The carbon equivalent CE of the low alloy cast steel is between 0.45% and 0.62%, and the carbon equivalent CE is calculated according to the following formula:
CE=C+(Mn+Si)/6+(Cr+Mo+V)/5+(Ni+Cu)/15CE=C+(Mn+Si)/6+(Cr+Mo+V)/5+(Ni+Cu)/15
其中,C表示碳的重量百分比,Mn表示锰的重量百分比,Si表示硅的重量百分比,Cr表示铬的重量百分比,Mo表示钼的重量百分比,V表示钒的重量百分比,Ni表示镍的重量百分比,Cu表示铜的重量百分比。Wherein C represents the weight percentage of carbon, Mn represents the weight percentage of manganese, Si represents the weight percentage of silicon, Cr represents the weight percentage of chromium, Mo represents the weight percentage of molybdenum, V represents the weight percentage of vanadium, and Ni represents the weight percentage of nickel. , Cu represents the weight percentage of copper.
技术方案13,如技术方案1-12任一所述的低合金铸钢,其中,所述低合金铸钢为经过正火处理得到的B+级钢。The low alloy cast steel according to any one of claims 1 to 12, wherein the low alloy cast steel is a B+ grade steel obtained by normalizing.
技术方案14,如技术方案13所述的低合金铸钢,其中,所述正火处理为:将铸钢件加热到900℃~940℃保温3~6小时,然后出炉空冷到室温。The low-alloy cast steel according to claim 13, wherein the normalizing treatment is: heating the steel casting to 900 ° C to 940 ° C for 3 to 6 hours, and then cooling the air to room temperature.
技术方案15,如技术方案14所述的低合金铸钢,其中,其硬度范围为150HBW至180HBW。The low-alloy cast steel according to claim 14, wherein the hardness ranges from 150 HBW to 180 HBW.
技术方案16,一种如技术方案1至15中任一项所述低合金铸钢的热处理方法,其中,包括步骤:The method of heat treatment of a low alloy cast steel according to any one of claims 1 to 15, wherein the method comprises the steps of:
提供所述低合金铸钢的铸钢件;以及Providing a steel casting of the low alloy cast steel;
对所述铸钢件进行正火处理,其中,所述正火处理为:将铸钢件加热到900℃~940℃保温3~6小时,然后出炉空冷到室温。The steel casting is subjected to normalizing treatment, wherein the normalizing treatment is: heating the steel casting to 900 ° C to 940 ° C for 3 to 6 hours, and then cooling the air to room temperature.
技术方案17,如技术方案16所述的热处理方法,其中,在所述热处理后,所述低合金铸钢的金相组织主要为珠光体和铁素体。The heat treatment method according to claim 16, wherein after the heat treatment, the metallographic structure of the low alloy cast steel is mainly pearlite and ferrite.
技术方案18,如技术方案16所述的热处理方法,其中,所述正火处理步骤中,将铸钢件加热到920℃~930℃保温4~5小时,然后出炉空冷到室温。The heat treatment method according to claim 16, wherein in the normalizing treatment step, the steel casting is heated to 920 ° C to 930 ° C for 4 to 5 hours, and then air-cooled to room temperature.
技术方案19,一种如技术方案1-12任一所述的低合金铸钢通过如技术方案16至18中任一项所述的热处理方法处理后获得的B+级钢。The invention provides a B+ grade steel obtained by treating the low alloy cast steel according to any one of claims 16 to 18 by the heat treatment method according to any one of claims 16 to 18.
技术方案20,一种如技术方案1至12中任一项所述低合金铸钢的冶炼方法,其中采用电弧炉氧化法进行冶炼,其中,包括以下步骤:The smelting method of the low-alloy cast steel according to any one of claims 1 to 12, wherein the smelting is performed by an electric arc furnace oxidation method, wherein the following steps are included:
装料步骤:基于组分要求,将相应炉料投入所述电弧炉内,其中入炉炉料包括钼铁和钨铁;Loading step: based on the component requirements, the corresponding charge is put into the electric arc furnace, wherein the furnace charge comprises ferromolybdenum and tungsten iron;
对炉料进行熔化的熔化期步骤; a melting step of melting the charge;
氧化期步骤:在熔池温度大于或等于1560℃时,向所述电弧炉内加入铁矿石以脱碳,并进行脱磷操作;Oxidation period step: when the bath temperature is greater than or equal to 1560 ° C, iron ore is added to the electric arc furnace to decarburize, and dephosphorization operation is performed;
还原期步骤:向所述电弧炉内加入铬铁合金,并且根据取样分析化学成分的检测结果,将该结果与所述低合金铸钢的化学成分的重量百分比进行比对,并按照所述低合金铸钢各化学成分的重量百分比要求,向所述电弧炉内至少加入至少包括铌铁合金的的炉料;以及a reduction period step of: adding a ferrochrome alloy to the electric arc furnace, and comparing the result to a weight percentage of a chemical composition of the low alloy cast steel according to a result of sampling and analyzing chemical composition, and following the low alloy The weight percentage of each chemical component of the cast steel is required to add at least the charge containing at least the strontium iron alloy to the electric arc furnace;
出钢水步骤和浇注步骤。The tapping water step and the pouring step.
技术方案21,如技术方案20所述的冶炼方法,其中,在所述装料步骤中,所述钨铁的牌号为FeW75,其中,W的重量百分比含量为75%。The smelting method according to claim 20, wherein in the charging step, the tungsten iron is of a grade of FeW75, wherein the weight percentage of W is 75%.
技术方案22,如技术方案20所述的冶炼方法,其中,在所述熔化期步骤中,进行炉料熔化及造渣先期脱磷处理,其中,当炉料熔化25%~45%以上时,进行吹氧助熔以加速炉料熔化。The smelting method according to claim 20, wherein in the melting step, the furnace material is melted and the slag is dephosphorized in advance, wherein when the charge is melted by 25% to 45%, the blowing is performed. Oxygen assists to accelerate the melting of the charge.
技术方案23,如技术方案20或22所述的冶炼方法,其中,在所述氧化期步骤中,在所述脱碳后,进行大渣量流渣脱磷操作。The smelting method according to claim 20 or 22, wherein, in the oxidizing period, after the decarburization, a large slag amount slag dephosphorization operation is performed.
技术方案24,如技术方案23所述的冶炼方法,其中,在所述还原期步骤中,在稀薄渣形成后加入所述铬铁合金,然后在渣面加入碳粉或碳化硅,造还原渣,在所述还原渣变白色后,搅拌、进行所述取样分析化学成分操作。The smelting method according to claim 23, wherein in the reducing step, the ferrochrome alloy is added after the formation of the thin slag, and then carbon powder or silicon carbide is added to the slag surface to form a reducing slag. After the reducing slag turns white, the sampling and analysis chemical composition operations are performed by stirring.
技术方案25,如技术方案24所述的冶炼方法,其中,所述还原期步骤中,基于取样分析结果和比对结果,在需要的情况下,依次加入铝块、硅铁合金、锰铁合金和所述铌铁合金,其中至少包括铌铁合金;当然,在不需要的情况下,即,如果取样分析结果表明某化学成分已满足所述低合金铸钢各化学成分的重量百分比要求,则就无须再加入含有该化学成分的相应物料。The smelting method according to claim 24, wherein in the reducing period step, based on the sampling analysis result and the comparison result, an aluminum block, a ferrosilicon alloy, a ferromanganese alloy, and the like are sequentially added as needed. Ferroalloy, including at least strontium iron alloy; of course, if it is not required, that is, if the sampling analysis indicates that a chemical component has satisfied the weight percentage requirement of the chemical composition of the low alloy cast steel, then it is not necessary to add The corresponding material containing the chemical composition.
技术方案26,如技术方案20所述的冶炼方法,其中,在所述出钢步骤中,当熔池温度在1620~1650℃范围时,进一步取样分析化学成分,在成分合格后,进行出钢水、钢渣混冲脱硫操作。The smelting method according to claim 20, wherein in the tapping step, when the bath temperature is in the range of 1620 to 1650 ° C, the chemical components are further sampled and analyzed, and after the components are qualified, the tapping water is performed. , steel slag mixed desulfurization operation.
技术方案27,一种铁路机车零部件,其中,其采用如技术方案1-5和19任一项所述的B+级钢制备形成。Technical Solution 27, a railway locomotive component, wherein the B+ grade steel according to any one of claims 1-5 and 19 is prepared.
技术方案28,如技术方案27所述的铁路机车零部件,其中,所述铁路机车零部件为转向架的摇枕或侧架,或具有同等机械性能要求 的其他零部件。The railway locomotive component according to claim 27, wherein the railway locomotive component is a bolster or a side frame of the bogie, or has the same mechanical performance requirement. Other parts.
以下实施例中,组分含量均以其重量百分比含量计。In the following examples, the component contents are all based on their weight percentage.
实施例1Example 1
该实施例1的含钨铌的低合金铸钢中,其各组分及其重量百分比如下:碳0.24%、硅0.42%、锰1.13%、磷0.026%、硫0.019%、铬0.26%、钼0.14%、铝0.02%、钨0.07%、铌0.03%,其中钨+铌为0.10%,余量为铁及其他不可避免的元素。其中,碳当量CE的计算公式为:CE=C+(Mn+Si)/6+(Cr+Mo+V)/5+(Ni+Cu)/15,其中公式中的某些合金元素,有可能是不可避免的余量元素。In the tungsten-rhenium-containing low alloy cast steel of Example 1, the components and their weight percentages are as follows: carbon 0.24%, silicon 0.42%, manganese 1.13%, phosphorus 0.026%, sulfur 0.019%, chromium 0.26%, molybdenum 0.14%, aluminum 0.02%, tungsten 0.07%, 铌0.03%, of which tungsten + bismuth is 0.10%, the balance is iron and other unavoidable elements. Among them, the calculation formula of carbon equivalent CE is: CE=C+(Mn+Si)/6+(Cr+Mo+V)/5+(Ni+Cu)/15, in which some alloying elements in the formula are possible It is an inevitable margin element.
基于以上碳当量的计算公式,确定在该实施例1的低合金铸钢中的碳当量具体为0.58,满足AAR的M-201-05标准关于B+级钢的碳当量要求,因此可焊性好。Based on the calculation formula of the above carbon equivalent, it is determined that the carbon equivalent in the low alloy cast steel of the embodiment 1 is specifically 0.58, which satisfies the carbon equivalent requirement of the B-grade steel of the M-201-05 standard of AAR, and therefore the weldability is good. .
实施例1的含钨铌的低合金铸钢可以但不限于通过以下示例的冶炼方法制备得到。The tungsten-rhenium-containing low alloy cast steel of Example 1 can be, but is not limited to, prepared by the smelting method exemplified below.
在一示例中,采用电弧炉大渣量氧化法进行冶炼,具体包括以下步骤:In an example, the smelting is performed by an electric arc furnace large slag oxidation method, which specifically includes the following steps:
I装料:基组分要求,投入相应的炉料,其中,入炉炉料加入了合适量的钼铁和钨铁,其中,钨铁具体采用牌号为FeW75的钨铁,其表示W的重量百分比为75%左右。入炉炉料例如一般包括废钢、优质生铁、铁合金、回炉料等。I Charge: The base component is required to be put into the corresponding charge. Among them, a suitable amount of ferromolybdenum and tungsten iron is added to the furnace charge. The tungsten iron is specifically made of tungsten iron of the grade of FeW75, which represents the weight percentage of W. About 75%. The furnace charge generally includes, for example, scrap steel, high quality pig iron, iron alloy, recycled material, and the like.
II熔化期:以电弧炉能匹配的最大功率进行炉料熔化及造渣先期脱磷处理,当炉料熔化25%~45%以上时,可吹氧助熔,加速炉内炉料熔化。II Melting period: The furnace material melting and slag dephosphorization treatment can be carried out at the maximum power matched by the electric arc furnace. When the charge is melted by 25% to 45%, the oxygen can be blown and the furnace charge can be accelerated.
III氧化期:当熔池温度大于或等于1560℃时,加铁矿石脱碳,在该温度条件下,铁矿石相对容易发生脱碳反应;并进行大渣量流渣脱磷操作。III oxidation period: When the temperature of the molten pool is greater than or equal to 1560 ° C, the iron ore is decarburized. Under this temperature condition, the iron ore is relatively easy to decarburize; and the large slag slag dephosphorization operation is carried out.
IV还原期:在稀薄渣形成后,加入铬铁合金,然后在渣面上加入碳粉或加碳化硅,造还原渣;当还原渣基本变为白色后,搅拌、进行取样分析化学成分操作,并且根据化验报告结果,比对以上实施例1的低合金铸钢的化学成分重量百分比要求,依次有控制地加入纯铝块、硅、锰铁合金和铌铁合金,其中至少包括铌铁合金;当然,在不 需要的情况下,即,如果取样分析结果表明某化学成分已满足所述低合金铸钢各化学成分的重量百分比要求,则就无须再加入含有该化学成分的相应物料。本实施例选择在还原期步骤加入铌铁合金,避免了铌在钢液中较早地发生氧化反应,减少了铌的损失,有利于保证形成后的低合金铸钢中的铌元素的百分比含量和相应作用。IV reduction period: after the formation of the thin slag, adding the ferrochrome alloy, then adding carbon powder or adding silicon carbide on the surface of the slag to form the reducing slag; when the reducing slag is substantially turned into white, stirring, sampling and analyzing the chemical composition operation, and According to the results of the test report, in comparison with the chemical composition weight percentage requirement of the low alloy cast steel of the above Example 1, the pure aluminum block, the silicon, the ferromanganese alloy and the neodymium iron alloy are added in a controlled manner, at least including the neodymium iron alloy; If necessary, that is, if the sampling analysis indicates that a chemical component has satisfied the weight percentage requirement of each chemical component of the low alloy cast steel, it is not necessary to add a corresponding material containing the chemical component. In this embodiment, the addition of the strontium iron alloy in the reduction period step is avoided, the oxidation reaction of the bismuth in the molten steel is avoided earlier, the enthalpy loss is reduced, and the percentage content of the lanthanum element in the low alloy cast steel after formation is ensured. Corresponding effect.
V出钢:当熔池温度在1620~1650℃范围时,进行取样分析化学成分操作;在成分合格后,当温度达到出钢水温度时,进行出钢水、钢渣混冲脱硫操作。V tapping: When the temperature of the molten pool is in the range of 1620~1650°C, the chemical composition operation is carried out by sampling and analyzing; after the composition is qualified, when the temperature reaches the tapping water temperature, the molten steel and steel slag are mixed and desulfurized.
VI浇注:钢水在钢包内完成规定的镇静时间后,进行铸件成型浇注操作。VI casting: After the molten steel has completed the specified sedation time in the ladle, the casting is cast and cast.
以上实施例1的低合金铸钢经以上示例的冶炼方法冶炼铸造成型获得铸钢件后,可以进行热处理获得性能较好的B+级钢,在该实施例中,热处理过程采用正火处理,并且在正火处理后避免采用调质处理。具体地,正火处理工艺为加热到920℃保温4小时,然后出炉进行空冷。After the smelting and casting of the low-alloy cast steel of the above Example 1 is obtained by the smelting method of the above example, the steel can be heat-treated to obtain a B+ grade steel having better performance. In this embodiment, the heat treatment process is normalized, and Avoid quenching and tempering after normalizing. Specifically, the normalizing treatment process is heated to 920 ° C for 4 hours, and then discharged to air cooling.
以上实施例1的低合金铸钢经过以上示例的正火处理以后,所获得的金相组织主要为铁素体+珠光体,具体金相组织图样如图1和图2所示,由图1和图2可以看到典型的铁素体+珠光体金相形貌(其中深灰黑色部分为珠光体、浅灰色部分为铁素体),其中避免了贝氏体出现;并且,晶粒尺寸明显细化,组织均匀性非常良好,这是由于低合金铸钢中钨和铌按一定重量百分比复合添加时,能有效抑制铸造过程中奥氏体晶粒长大,有利于细化铸钢的晶粒,在正火处理后得到的低合金铸钢的珠光体晶粒也相对较细。并且,钨和铌按一定重量百分比的复合添加,同时有利于强化基体。After the normalized fire treatment of the low alloy cast steel of the above embodiment 1, the metallographic structure obtained is mainly ferrite + pearlite, and the specific metallographic structure is shown in FIG. 1 and FIG. And Figure 2 shows a typical ferritic + pearlite metallographic morphology (where the dark gray black part is pearlite and the light gray part is ferrite), which avoids the appearance of bainite; and, the grain size Significantly refined, the uniformity of the structure is very good, because the tungsten and niobium in the low alloy cast steel can be combined to increase the austenite grain growth during the casting process, which is beneficial to refining the cast steel. The grain, the pearlite grains of the low alloy cast steel obtained after the normalizing treatment are also relatively fine. Moreover, the addition of tungsten and niobium in a certain weight percentage is beneficial to strengthening the matrix.
对以上实施例1的低合金铸钢(经过上述正火热处理后)进行机械性能测定,获得以下测试结果:抗拉强度597MPa,屈服强度386MPa,伸长率33%,断面收缩率49.5%,-7℃的夏比V型冲击功(平均值)38J,硬度169HBW。The mechanical properties of the low alloy cast steel of the above Example 1 (after the above normalizing heat treatment) were measured, and the following test results were obtained: tensile strength 597 MPa, yield strength 386 MPa, elongation 33%, and section shrinkage 49.5%, - Charpy V-type impact energy at 7 ° C (average value) 38 J, hardness 169 HBW.
基于AAR的M-201-05标准可以看到,基于以上实施例1的低合金铸钢能够获得满足美国铁道协会标准M-201-05的B+级钢机械性能要求,并且硬度和强度方面尤其表现良好。It can be seen from the AAR-based M-201-05 standard that the low alloy cast steel based on the above Example 1 can obtain the mechanical performance requirements of the B+ grade steel meeting the American Railway Association standard M-201-05, and is particularly manifested in terms of hardness and strength. good.
因此,以上实施例1的低合金铸钢在经过以上示例的正火热处理 后,可以作为B+级钢使用,而且硬度、强度和可焊性方面表现良好;并且,不依赖于镍元素的添加使用,成本大大降低。Therefore, the low alloy cast steel of the above Example 1 is subjected to the normalizing heat treatment of the above example After that, it can be used as a B+ grade steel, and it performs well in terms of hardness, strength, and weldability; and, depending on the addition of nickel, the cost is greatly reduced.
实施例2~10Examples 2 to 10
与实施例1基本相同,实施例2~10的低合金铸钢中的各具体组分及含量、碳当量见表1。相对应的机械性能如下表2所示:Basically, in the same manner as in the first embodiment, the specific components and contents and carbon equivalents in the low-alloy cast steels of Examples 2 to 10 are shown in Table 1. The corresponding mechanical properties are shown in Table 2 below:
表1实施例2~10的低合金铸钢的组成(重量百分比%)及碳当量Table 1 Composition (% by weight) and carbon equivalent of the low alloy cast steel of Examples 2 to 10
Figure PCTCN2017091007-appb-000001
Figure PCTCN2017091007-appb-000001
其中,合金元素铝的作用主要用于脱氧,同时能一定程度起到的细化晶粒的效果。Among them, the role of the alloying element aluminum is mainly used for deoxidation, and at the same time can achieve a certain degree of grain refining effect.
实施例2~10的含钨铌的低合金铸钢可以但不限于通过以上示例的冶炼方法制备得到相应的铸钢件。The low-alloy cast steel containing tungsten ruthenium of Examples 2 to 10 can be, but is not limited to, prepared by the smelting method exemplified above to obtain a corresponding steel casting.
以上实施例2~10的低合金铸钢经冶炼铸造成型获得铸钢件后,可以进行热处理获得性能较好的B+级钢,在该实施例中,热处理过程采用正火处理;具体地,正火处理即通常将铸钢件加热到900℃~940℃保温3~6小时,然后出炉空冷到室温。进一步优化正火处理,铸钢件可加热到920℃~930℃保温4~5小时。After obtaining the steel castings by the smelting and casting of the low alloy cast steels of the above embodiments 2 to 10, the heat treatment can be performed to obtain the B+ grade steel with better performance. In this embodiment, the heat treatment process is normalized; in particular, positive In the fire treatment, the steel castings are usually heated to 900 ° C ~ 940 ° C for 3 to 6 hours, and then air cooled to room temperature. Further optimization of normalizing treatment, the steel castings can be heated to 920 ° C ~ 930 ° C for 4 to 5 hours.
以上实施例2~10的低合金铸钢经过以上示例的正火处理以后,所获得的金相组织主要为珠光体+铁素体,具体金相组织图样类似如图1和图2所示。After the normalizing treatment of the low alloy cast steels of the above Examples 2 to 10, the metallographic structure obtained is mainly pearlite + ferrite, and the specific metallographic structure is similar to that shown in Figs. 1 and 2.
对以上实施例2~10的低合金铸钢(经过上述热处理后)进行机 械性能测定,获得以下表2所示的测试结果:The low alloy cast steel of the above Examples 2 to 10 (after the above heat treatment) was machined The mechanical properties were measured and the test results shown in Table 2 below were obtained:
表2实施例2~10的低合金铸钢的机械性能Table 2 Mechanical properties of low alloy cast steel of Examples 2 to 10
Figure PCTCN2017091007-appb-000002
Figure PCTCN2017091007-appb-000002
从以上表2的机械性能数据可以看出,能实现如下机械性能指标:抗拉强度≥552MPa,屈服强度≥345MPa,伸长率≥24%,断面收缩率≥36%,-7℃的夏比V型冲击功≥21J,硬度范围为137HBW~228HBW;尤其地,硬度范围在150HBW~180HBW之间。It can be seen from the mechanical performance data of Table 2 above that the following mechanical performance indexes can be achieved: tensile strength ≥ 552 MPa, yield strength ≥ 345 MPa, elongation ≥ 24%, reduction in area ≥ 36%, and Charpy to -7 °C. The V-type impact energy is ≥21J, and the hardness ranges from 137HBW to 228HBW; in particular, the hardness ranges from 150HBW to 180HBW.
因此,基于以上实施例2~10的低合金铸钢能够获得满足美国铁道协会标准M-201-05的B+级铸钢机械性能要求的B+级钢;且在硬度方面(例如从硬度指标来看其能够落入150HBW至180HBW的范围)尤其表现良好;从碳当量来看,低合金铸钢的碳当量下降,可焊性得到提升;抗拉强度和屈服强度等性能指标也可以反映低合金铸钢的基体得到强化。Therefore, the low alloy cast steel based on the above Examples 2 to 10 can obtain B+ grade steel satisfying the mechanical performance requirements of the B+ grade cast steel of the American Railway Association Standard M-201-05; and in terms of hardness (for example, from the hardness index) It can fall well in the range of 150HBW to 180HBW), especially in terms of carbon equivalent, the carbon equivalent of low alloy cast steel decreases, weldability is improved; performance indexes such as tensile strength and yield strength can also reflect low alloy casting. The matrix of the steel is strengthened.
因此,以上实施例1~10的低合金铸钢在经过以上示例的正火热处理后,可以作为B+级钢使用,并且,具有优越的可焊性、良好的硬度和强度,尤其地,成本大大降低。Therefore, the low-alloy cast steels of the above Examples 1 to 10 can be used as B+ grade steel after the normalizing heat treatment of the above examples, and have superior weldability, good hardness and strength, and in particular, cost is large. reduce.
需要说明的是,以上实施例1~10的低合金铸钢可以在不使用 镍作为合金元素的情况下获得良好的机械性能,主要原因在于,复合添加合金元素钨和铌,并选择了合适的配比(钨0.02%~0.10%、铌0.01%~0.05%,且必须满足0.04%≤钨+铌≤0.12%),能有效地抑制铸造过程中奥氏体晶粒长大,细化晶粒,同时强化基体;因此,在经过本申请实施例的为该低合金铸钢设计的正火热处理工艺后,低合金铸钢硬度相对传统的B+级钢得到明显提升,并且强度高、可焊性优越,整体满足B+级钢的机械性能要求。It should be noted that the low alloy cast steels of the above embodiments 1 to 10 can be used without being used. Nickel is used as an alloying element to obtain good mechanical properties. The main reason is that the alloying elements tungsten and rhenium are compounded and a suitable ratio (tungsten 0.02% to 0.10%, 铌0.01% to 0.05%, and must be satisfied) 0.04% ≤ tungsten + 铌 ≤ 0.12%), can effectively inhibit austenite grain growth during casting, refine grains, and strengthen the matrix; therefore, the low alloy cast steel in the embodiment of the present application After the normalized heat treatment process, the hardness of the low alloy cast steel is obviously improved compared with the traditional B+ grade steel, and the strength is high and the weldability is superior, and the overall mechanical performance requirements of the B+ grade steel are satisfied.
以上实施例1至10的低合金铸钢在经过正火处理后,可以用来制备铁路机车上的相应零部件,例如,转向架中的关键零部件,如摇枕、侧架等。应当理解到,以上实施例的低合金铸钢具体应用并不限于以上实施例,本领域技术人员也可以将其用于具有基本同等机械性能要求的铁路机上或其他设备上的零部件,例如轮芯。The low alloy cast steels of the above embodiments 1 to 10 can be used to prepare corresponding parts on a railway locomotive after normalizing, for example, key components in a bogie such as a bolster, a side frame, and the like. It should be understood that the specific application of the low alloy cast steel of the above embodiment is not limited to the above embodiment, and those skilled in the art can also use it for components on railway machines or other equipment having substantially the same mechanical performance requirements, such as wheels. core.
以上例子主要说明了本发明的低合金铸钢及各种冶炼方法和热处理方法、热处理后得到的B+级钢及其应用。尽管只对其中一些本发明的实施方式进行了描述,但是本领域普通技术人员应当了解,本发明可以在不偏离其主旨与范围内以许多其他的形式实施。因此,所展示的例子与实施方式被视为示意性的而非限制性的,在不脱离如所附各权利要求所定义的本发明精神及范围的情况下,本发明可能涵盖各种的修改与替换。 The above examples mainly illustrate the low alloy cast steel of the present invention, various smelting methods and heat treatment methods, B+ grade steel obtained after heat treatment, and applications thereof. Although only a few of the embodiments of the present invention have been described, it will be understood by those skilled in the art that the invention may be practiced in many other forms without departing from the spirit and scope of the invention. Accordingly, the present invention is to be construed as illustrative and not restrictive, and the invention may cover various modifications without departing from the spirit and scope of the invention as defined by the appended claims With replacement.

Claims (22)

  1. 一种低合金铸钢,其特征在于,各组分及其相对于所述低合金铸钢总重的重量百分比为:A low alloy cast steel characterized in that the weight percentage of each component and its total weight relative to the low alloy cast steel is:
    碳0.19%~0.25%、硅0.30%~0.50%、锰0.90%~1.15%、磷≤0.030%、硫≤0.030%、铬0.19%~0.29%、钼0.13%~0.19%、铝0.02%~0.06%、以及钨0.02%~0.10%、铌0.01%~0.05%,且必须满足0.04%≤钨+铌≤0.12%;以及余量为铁和其他不可避免的元素。Carbon 0.19% to 0.25%, silicon 0.30% to 0.50%, manganese 0.90% to 1.15%, phosphorus ≤0.030%, sulfur ≤0.030%, chromium 0.19% to 0.29%, molybdenum 0.13% to 0.19%, aluminum 0.02% to 0.06 %, and 0.02% to 0.10% of tungsten, 铌0.01% to 0.05%, and must satisfy 0.04% ≤ tungsten + 铌 ≤ 0.12%; and the balance is iron and other unavoidable elements.
  2. 如权利要求1所述的低合金铸钢,其特征在于,相对于所述低合金铸钢总重,碳的重量百分比为0.21%~0.24%。The low alloy cast steel according to claim 1, wherein the weight percentage of carbon is from 0.21% to 0.24% based on the total weight of the low alloy cast steel.
  3. 如权利要求1所述的低合金铸钢,其特征在于,相对于所述低合金铸钢总重,硅的重量百分比为0.33%~0.39%。The low alloy cast steel according to claim 1, wherein the weight percentage of silicon is from 0.33% to 0.39% with respect to the total weight of the low alloy cast steel.
  4. 如权利要求1所述的低合金铸钢,其特征在于,相对于所述低合金铸钢总重,锰的重量百分比为0.91%~1.14%。The low alloy cast steel according to claim 1, wherein the weight percentage of manganese is from 0.91% to 1.14% with respect to the total weight of the low alloy cast steel.
  5. 如权利要求1所述的低合金铸钢,其特征在于,相对于所述低合金铸钢总重,铬的重量百分比为0.23%~0.29%。The low alloy cast steel according to claim 1, wherein the weight percentage of chromium is from 0.23% to 0.29% with respect to the total weight of the low alloy cast steel.
  6. 如权利要求1所述的低合金铸钢,其特征在于,相对于所述低合金铸钢总重,钼的重量百分比为0.14%~0.18%。The low alloy cast steel according to claim 1, wherein the weight percentage of molybdenum is from 0.14% to 0.18% with respect to the total weight of the low alloy cast steel.
  7. 如权利要求1所述的低合金铸钢,其特征在于,相对于所述低合金铸钢总重,铝的重量百分比为0.03%~0.05%。The low alloy cast steel according to claim 1, wherein the weight percentage of aluminum is from 0.03% to 0.05% with respect to the total weight of the low alloy cast steel.
  8. 如权利要求1所述的低合金铸钢,其特征在于,相对于所述低合金铸钢总重,铌的重量百分比为0.02%~0.04%。The low alloy cast steel according to claim 1, wherein the weight percentage of niobium is from 0.02% to 0.04% based on the total weight of the low alloy cast steel.
  9. 如权利要求1所述的低合金铸钢,其特征在于,相对于所述低合金铸钢总重,钨的重量百分比为0.05%~0.09%。The low alloy cast steel according to claim 1, wherein the weight percentage of tungsten is 0.05% to 0.09% with respect to the total weight of the low alloy cast steel.
  10. 如权利要求1所述的低合金铸钢,其特征在于,所述低合金铸钢的碳当量CE在0.45%~0.62%之间,所述碳当量CE按照以下公式计算:The low alloy cast steel according to claim 1, wherein said low alloy cast steel has a carbon equivalent CE of between 0.45% and 0.62%, and said carbon equivalent CE is calculated according to the following formula:
    CE=C+(Mn+Si)/6+(Cr+Mo+V)/5+(Ni+Cu)/15CE=C+(Mn+Si)/6+(Cr+Mo+V)/5+(Ni+Cu)/15
    其中,C表示碳的重量百分比,Mn表示锰的重量百分比,Si表示硅的重量百分比,Cr表示铬的重量百分比,Mo表示钼的重量百分比,V表示钒的重量百分比,Ni表示镍的重量百分比,Cu表示铜的重量百分比。 Wherein C represents the weight percentage of carbon, Mn represents the weight percentage of manganese, Si represents the weight percentage of silicon, Cr represents the weight percentage of chromium, Mo represents the weight percentage of molybdenum, V represents the weight percentage of vanadium, and Ni represents the weight percentage of nickel. , Cu represents the weight percentage of copper.
  11. 如权利要求1所述的低合金铸钢,其特征在于,所述低合金铸钢为经过正火处理得到的B+级钢。The low-alloy cast steel according to claim 1, wherein the low-alloy cast steel is a B+ grade steel obtained by normalizing.
  12. 如权利要求11所述的低合金铸钢,其特征在于,所述正火处理为:将铸钢件加热到900℃~940℃保温3~6小时,然后出炉空冷到室温。The low-alloy cast steel according to claim 11, wherein the normalizing treatment is: heating the steel casting to 900 ° C to 940 ° C for 3 to 6 hours, and then cooling to room temperature.
  13. 如权利要求12所述的低合金铸钢,其特征在于,其具有以下机械性能的至少一个方面:抗拉强度≥552MPa,屈服强度≥345MPa,硬度范围为137HBW~228HBW。The low alloy cast steel according to claim 12, which has at least one of the following mechanical properties: tensile strength ≥ 552 MPa, yield strength ≥ 345 MPa, and hardness ranging from 137 HBW to 228 HBW.
  14. 如权利要求13所述的低合金铸钢,其特征在于,其还具有以下机械性能的至少一个方面:伸长率≥24%,断面收缩率≥36%,-7℃的夏比V型冲击功≥21J,The low-alloy cast steel according to claim 13, which further has at least one of the following mechanical properties: elongation ≥ 24%, reduction in area ≥ 36%, and Charpy V-type impact at -7 ° C. Power ≥ 21J,
  15. 如权利要求12所述的低合金铸钢,其特征在于,其具有以下机械性能:硬度范围为150HBW至180HBW。The low alloy cast steel according to claim 12, which has the following mechanical properties: a hardness ranging from 150 HBW to 180 HBW.
  16. 一种如权利要求1至15中任一项所述低合金铸钢的热处理方法,其特征在于,包括步骤:A method of heat-treating a low-alloy cast steel according to any one of claims 1 to 15, comprising the steps of:
    提供所述低合金铸钢的铸钢件;以及Providing a steel casting of the low alloy cast steel;
    对所述铸钢件进行正火处理,其中,所述正火处理为:将铸钢件加热到900℃~940℃保温3~6小时,然后出炉空冷到室温。The steel casting is subjected to normalizing treatment, wherein the normalizing treatment is: heating the steel casting to 900 ° C to 940 ° C for 3 to 6 hours, and then cooling the air to room temperature.
  17. 如权利要求16所述的热处理方法,其特征在于,在所述热处理后,所述低合金铸钢的金相组织主要为珠光体和铁素体。The heat treatment method according to claim 16, wherein after said heat treatment, said metallographic structure of said low alloy cast steel is mainly pearlite and ferrite.
  18. 如权利要求16所述的热处理方法,其特征在于,所述正火处理步骤中,将铸钢件加热到920℃~930℃保温4~5小时,然后出炉空冷到室温。The heat treatment method according to claim 16, wherein in the normalizing treatment step, the steel casting member is heated to 920 ° C to 930 ° C for 4 to 5 hours, and then air-cooled to room temperature.
  19. 一种如权利要求1至10中任一项所述的低合金铸钢通过如权利要求16至18中任一项所述的热处理方法处理后获得的B+级钢。A B+ grade steel obtained by treating the low alloy cast steel according to any one of claims 1 to 10 by the heat treatment method according to any one of claims 16 to 18.
  20. 一种如权利要求1至10中任一项所述低合金铸钢的冶炼方法,其中采用电弧炉氧化法进行冶炼,其特征在于,包括以下步骤:A smelting method for a low-alloy cast steel according to any one of claims 1 to 10, wherein the smelting is carried out by an electric arc furnace oxidation method, characterized in that it comprises the following steps:
    装料步骤:基于组分要求,将相应的炉料投入所述电弧炉内,其中入炉炉料包括钼铁和钨铁;Loading step: based on the component requirements, the corresponding charge is put into the electric arc furnace, wherein the furnace charge comprises ferromolybdenum and tungsten iron;
    对炉料进行熔化的熔化期步骤;a melting step of melting the charge;
    氧化期步骤:在熔池温度大于或等于1560℃时,向所述电弧炉内加入铁矿石以脱碳,并进行脱磷操作; Oxidation period step: when the bath temperature is greater than or equal to 1560 ° C, iron ore is added to the electric arc furnace to decarburize, and dephosphorization operation is performed;
    还原期步骤:向所述电弧炉内加入铬铁合金,并且根据取样分析化学成分操作的结果,基于取样分析的结果,将该结果与所述低合金铸钢各化学成分的重量百分比进行比对,并按照所述低合金铸钢各化学成分的重量百分比要求,向所述电弧炉内加入至少包括铌铁合金的炉料;以及a reduction period step of: adding a ferrochrome alloy to the electric arc furnace, and comparing the result with a weight percentage of each chemical component of the low alloy cast steel based on a result of sampling analysis according to a result of sampling analysis chemical composition operation, And adding a charge comprising at least a neodymium iron alloy to the electric arc furnace according to the weight percentage requirement of each chemical component of the low alloy cast steel;
    出钢水步骤和浇注步骤。The tapping water step and the pouring step.
  21. 一种铁路机车零部件,其特征在于,其采用如权利要求19所述的B+级钢制备形成。A railway locomotive component, characterized in that it is formed by using B+ grade steel according to claim 19.
  22. 如权利要求21所述的铁路机车零部件,其特征在于,所述铁路机车零部件为转向架的摇枕或侧架,或具有同等机械性能要求的其他零部件。 A railway locomotive component according to claim 21, wherein said railway locomotive component is a bolster or side frame of a bogie or other component having equivalent mechanical performance requirements.
PCT/CN2017/091007 2016-06-30 2017-06-30 Low alloy cast steel, and smelting method and heat treatment thereof, and railway locomotive part of same WO2018001346A1 (en)

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