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WO2016006619A1 - Procédé permettant de produire un stratifié décoratif, et stratifié décoratif - Google Patents

Procédé permettant de produire un stratifié décoratif, et stratifié décoratif Download PDF

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Publication number
WO2016006619A1
WO2016006619A1 PCT/JP2015/069581 JP2015069581W WO2016006619A1 WO 2016006619 A1 WO2016006619 A1 WO 2016006619A1 JP 2015069581 W JP2015069581 W JP 2015069581W WO 2016006619 A1 WO2016006619 A1 WO 2016006619A1
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WO
WIPO (PCT)
Prior art keywords
primer layer
layer
substrate
uncured
ink
Prior art date
Application number
PCT/JP2015/069581
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English (en)
Japanese (ja)
Inventor
信隆 松永
Original Assignee
株式会社ミマキエンジニアリング
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 株式会社ミマキエンジニアリング filed Critical 株式会社ミマキエンジニアリング
Publication of WO2016006619A1 publication Critical patent/WO2016006619A1/fr

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
    • B05D3/06—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by exposure to radiation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/12—Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives

Definitions

  • the present invention relates to a method for manufacturing a decorative laminate and a decorative laminate.
  • Patent Document 1 describes a decorative laminated glass in which a printed glass side of a plate glass that has been ink-jet-printed on a plate glass via a primer layer is brought into contact with an intermediate film to form a laminated glass.
  • Patent Document 2 describes a laminated decorative member in which a film of lacquer paint is installed between two glass plates.
  • Patent Document 3 discloses a decorative laminated glass plate with a color pattern that is transparent when viewed from the inside and allows viewing of the outside scenery, and when viewed from the outside, only the color pattern design can be viewed. A process for producing a decorative laminated glass plate with a color pattern for the purpose of obtaining the above is described.
  • JP 2011-190133 A released September 29, 2011
  • JP 2011-514849 A released on May 12, 2011
  • Japanese Patent Laid-Open No. 7-291681 published on November 7, 1995
  • the present invention has been made in view of such problems, and provides a decorative laminate that can be more easily manufactured.
  • the method for producing a decorative laminate according to the present invention includes a first substrate having light permeability, an image layer disposed on the first substrate, and a primer layer disposed on the image layer. And a second substrate having light transmittance disposed on the primer layer, wherein the image layer and the primer layer are formed of an ink containing a photocurable compound.
  • a manufacturing method wherein a photocurable compound is formed on at least one of an image layer forming step of forming the image layer on the first substrate, and the image layer and the second substrate.
  • the other boards By irradiating light, including a lamination step of curing the uncured primer layer.
  • the primer can be cured by irradiation with light, the decorative laminate can be easily manufactured.
  • the adhesive agent like patent document 2 it also has an advantage of preventing deterioration of an image by invading materials such as glass and ink.
  • the surface tension of the uncured primer layer is affected by the second substrate repelling the uncured primer layer.
  • an uncured primer layer may be fooled, or irregularities may be formed on the surface of the uncured primer layer. If it is laminated with the first substrate as it is, there is a possibility that the image looks uneven. Therefore, before forming the uncured primer layer on the second substrate, the primer layer is formed and cured immediately. The second substrate can be prevented from repelling the uncured primer layer, and the influence of surface tension can be suppressed. This can prevent the uncured primer layer from being fooled.
  • the surface of the uncured primer layer is smoothed (leveled), and when mixed, foreign matter such as air and dust can be prevented, It becomes a higher quality decorative laminate.
  • a first substrate on which the ink containing a photocurable compound is applied and cured on a portion where the image layer is not formed on the first substrate It is more preferable to include an upper cured primer layer forming step before the uncured primer layer forming step.
  • the surface tension of the uncured primer layer is affected by repelling the primer layer in the uncured state.
  • an uncured primer layer may be fooled, or irregularities may be formed on the surface of the uncured primer layer. If it is laminated with the second substrate as it is, there is a possibility that the image looks uneven. Therefore, before forming the uncured primer layer at the location, the primer layer is formed and cured immediately. The first substrate can be prevented from repelling the uncured primer layer, and the influence of surface tension can be suppressed. This can prevent the uncured primer layer from being fooled.
  • the surface of the uncured primer layer is smoothed (leveled), and when mixed, foreign matter such as air and dust can be prevented, It becomes a higher quality decorative laminate.
  • the first primer-on-primer layer forming step of applying and curing an ink containing a photocurable compound on the image layer is the same as the uncured primer layer forming step. May be included before.
  • the effect of the gloss of the first substrate and the second substrate on the appearance of the decoration can be suppressed, and the surface can be textured like a mat.
  • the decorative laminate according to the present invention includes a first substrate having light transmittance, an image layer disposed on the first substrate, a primer layer disposed on the image layer, A light-transmitting second substrate disposed on the primer layer, wherein the image layer and the primer layer are formed of an ink containing a photocurable compound.
  • the primer can be cured by irradiation with light, the decorative laminate can be easily manufactured.
  • FIG. 1 is a diagram schematically showing a configuration of a decorative laminate 10 which is an embodiment of a decorative laminate according to the present invention.
  • the decorative laminate 10 includes a plate glass 11 (first substrate), a color ink layer 12 (image layer), primer layers 13, 14, 15 and a plate glass 16 (second substrate).
  • the plate glass 11 and the plate glass 16 are light transmissive, the light can reach the primer layer 14 when irradiated with light after being laminated. Since the primer layer 14 is formed of an ink containing a photocurable compound, the primer layer 14 is cured by the irradiated light, and the plate glass 11 and the plate glass 16 can be easily bonded.
  • plate glass is used as the first substrate and the second substrate included in the decorative laminate according to the present invention, but the present invention is not limited to this, and any substrate having optical transparency may be used.
  • Various things can be adopted according to the usage of the decorative laminate. Examples thereof include a transparent glass plate, a transparent amorphous material such as a transparent resin such as an acrylic plate, and a transparent crystal.
  • the color ink layer 12 is a layer on which a desired image is printed.
  • the color ink layer is formed of an ink containing a photocurable compound. That is, it can be cured by applying light after applying the ink.
  • an ink containing an ultraviolet curable compound is preferable.
  • Examples of the ultraviolet curable compound include a curable monomer and a curable oligomer that are polymerized by irradiation with ultraviolet rays.
  • Examples of the curable monomer include low-viscosity acrylic monomers, vinyl ethers, oxetane monomers, and cycloaliphatic epoxy monomers.
  • Examples of the curable oligomer include acrylic oligomers.
  • the ink that forms the color ink layer 12 may be one containing a desired coloring component in order to form a desired image.
  • the coloring component include pigments and dyes.
  • each layer is formed using an ultraviolet curable ink containing an ultraviolet curable compound.
  • the primer layer 13 is formed on the color ink layer 12. In this embodiment, it is formed with clear ink. By forming the primer layer 13 with clear ink, the gloss of the plate glass can be suppressed, or the surface can be textured like a mat.
  • the primer layer 13 is formed of an ink containing a photocurable compound. Thereby, it can harden immediately after apply
  • FIG. 1 A photocurable compound
  • the description of the ink containing the photocurable compound is in accordance with the description in the color ink layer 12.
  • the ink forming the color ink layer 12 may contain a coloring component, but the primer layer 13 is preferably a transparent ink. This is to facilitate light transmission. Since the primer layer 13 easily transmits light, the primer layer 14 can be efficiently cured. Moreover, if it is a transparent ink, the influence on the color of the decoration of the color ink layer 12 can be reduced.
  • the ink for forming the primer layer 13 may be any ink that can be cured by irradiation with light.
  • LH100 manufactured by Mimaki Engineering Co., Ltd. can be preferably used.
  • the primer layer 14 is for adhering the plate glass 11 and the plate glass 16.
  • the primer layer 14 is formed of an ink containing a photocurable compound.
  • the description of the ink containing the photocurable compound follows the description of the color ink layer 12.
  • the ink forming the color ink layer 12 may contain a coloring component, but the primer layer 14 is preferably a transparent ink. This is to reduce the influence of the color ink layer 12 on the decoration hue.
  • the primer layer 14 is a primer layer previously provided on the primer layer 13 and the primer layer 15 in advance, and is obtained by overlapping and curing the uncured state (hereinafter, referred to as “the primer layer 14”).
  • An uncured primer layer is referred to as an “uncured primer layer”).
  • a single primer layer 14 is formed by forming an uncured primer layer with the same type of ink on the primer layer 13 and the primer layer 15 and then curing them by overlapping.
  • the decorative layered body according to the present invention has two primer layers 14 that serve to bond the first substrate and the second substrate. Can be.
  • the uncured primer layer for forming the primer layer 14 is provided on each of the primer layer 13 and the primer layer 15, but the present invention is not limited to this.
  • the uncured primer layer may be formed on at least one of the image layer and the second substrate, and between the uncured primer layer and the image layer or the second substrate. May be provided in advance with a primer layer (hereinafter, the cured primer layer is referred to as “cured primer layer”) that has been applied and cured with an ink containing a photocurable compound. Even if it is which structure, there exists an effect that it can adhere
  • the kind of ink forming the primer layer 14 may be any ink that can be cured by irradiation with light.
  • PR100 manufactured by Mimaki Engineering Co., Ltd. can be preferably used.
  • the primer layer 15 is a cured primer layer provided on the plate glass 16.
  • the plate glass 16 and the uncured primer layer repels the uncured primer layer due to the lack of wettability of the plate glass 16.
  • the uncured primer layer is repelled by the glass sheet 16, it is affected by the surface tension. As a result, for example, a surface (substance remaining as a lump) is formed or irregularities are formed on the surface.
  • the primer layer 15 is provided in advance. Since the primer layer 15 is the same material as the uncured primer layer, the uncured primer layer is easily wetted with the primer layer 15.
  • the plate glass 16 can be prevented from repelling the uncured primer layer, and the influence of the surface tension can be suppressed. This can prevent the uncured primer layer from being fooled.
  • the surface of the uncured primer layer is smoothed (leveled) to prevent the entry of foreign matters such as air and dust when laminated, resulting in higher quality A decorative laminate.
  • the primer layer 15 is formed of ink containing a photocurable compound.
  • the description of the ink containing the photocurable compound follows the description of the color ink layer 12.
  • the ink forming the color ink layer 12 may contain a coloring component, but the primer layer 15 is preferably a transparent ink. This is to facilitate light transmission. Since the primer layer 15 easily transmits light, the primer layer 14 can be efficiently cured. Moreover, if it is a transparent ink, the influence on the color of the decoration of the color ink layer 12 can be reduced.
  • the ink for forming the primer layer 15 may be any ink that can be cured by irradiation with light.
  • LH100 manufactured by Mimaki Engineering Co., Ltd. can be preferably used.
  • the ink forming the primer layer 13 and the primer layer 15 may be of the same type or different types.
  • FIG. 2 is a diagram schematically showing a configuration of a decorative laminate 20 which is an embodiment of the decorative laminate according to the present invention.
  • members having the same functions are denoted by the same reference numerals, and description thereof will be omitted.
  • the decorative laminate 20 is different from the decorative laminate 10 in that there is a place where the color ink layer 12 is not formed on the plate glass 11.
  • An ink for forming the primer layer 13 is applied to a portion on the surface of the plate glass 11 where the color ink layer 12 is not formed.
  • the primer layer 13 is provided in advance at the location. Since the primer layer 13 is the same material as the uncured primer layer, the uncured primer layer 13 is easily wetted with the primer layer 13. Accordingly, it is possible to prevent the plate glass 11 from repelling the uncured primer layer. Further, when an uncured primer layer is provided on the cured primer layer, the surface of the uncured primer layer can be smoothed.
  • the primer layer 14 and a sub-primer layer 14 'described later are formed, or the primer layer 14 is formed on the opposing primer layer 15 and laminated. Or you may.
  • FIG. 3 is a diagram schematically showing a method of manufacturing the decorative laminate 10 which is an embodiment of the decorative laminate according to the present invention.
  • a color glass layer 12, a primer layer 13, and a sub-primer layer 14 'that becomes a part of the primer layer 14 are formed on the surface of the plate glass 11, and a primer on the surface of the plate glass 16.
  • a layer 15 and a layer formed with a sub-primer layer 14 ′′ to be a part of the primer layer 14 are prepared.
  • the color ink layer 12 is formed on the surface of the plate glass 11 (image forming step).
  • the ultraviolet curable ink for forming the color ink layer 12 is printed by inkjet.
  • means for applying ink for forming the color ink layer 12, the primer layers 13, 14, and 15 in the image forming step and the subsequent steps are not particularly limited, but all More preferably, the ink is applied by an ink jet having a function of irradiating light for curing the ink.
  • the first substrate and the second substrate can be bonded to each other with a single ink jet apparatus, and the bonding can be easily performed, so that the decorative laminate can be manufactured very easily.
  • the color ink layer 12 is cured by irradiating with ultraviolet rays after applying the ink.
  • irradiating ultraviolet rays for example, when ink is ejected by inkjet, printing may be performed while irradiating ultraviolet rays with an ultraviolet irradiator provided adjacent to the head. Further, after all the ink for forming the color ink layer 12 is discharged, the entire surface of the plate glass 11 may be irradiated with ultraviolet rays. Alternatively, temporary curing may be performed by an ultraviolet irradiator provided adjacent to the head, and then the entire surface of the plate glass 11 may be irradiated with ultraviolet rays to perform main curing.
  • the primer layer 13 is formed by applying and curing an ultraviolet curable ink on the color ink layer 12.
  • a UV curable ink is applied to the substrate and cured.
  • the ink may be applied using inverted data obtained by inverting the image data of the color ink layer 12. .
  • the first on-substrate cured primer layer forming step is performed by ink jet as in the image forming step. After the ink for forming the primer layer 13 is applied, it is cured by irradiation with ultraviolet rays.
  • the method of irradiating with ultraviolet rays conforms to the explanation in the image forming process.
  • the primer layer 15 is formed on the plate glass 16 by applying and curing an ultraviolet curable ink (second substrate cured primer layer forming step). Thereby, as above-mentioned, it can prevent that the plate glass 11 repels an unhardened primer layer, and can suppress the influence of surface tension.
  • the second primer-cured primer layer forming step is performed by ink jet as in the image forming step. After the ink for forming the primer layer 15 is applied, it is cured by irradiation with ultraviolet rays.
  • the method of irradiating with ultraviolet rays conforms to the explanation in the image forming process.
  • an ultraviolet curable ink for forming the primer layer 14 is applied on the primer layer 13 and the primer layer 15.
  • the ink application is performed by inkjet in the same manner as in the image forming step, the first substrate cured primer layer forming step, and the second substrate cured primer layer forming step.
  • it is not necessary to irradiate ultraviolet rays, or it may be temporarily cured by irradiating ultraviolet rays with an illuminance that does not completely cure.
  • the glass plates 11 and 16 can be easily bonded.
  • the subprimer layer 14 ′ and the subprimer layer 14 ′′ are provided on each of the primer layer 13 and the primer layer 15 in this embodiment, but the present invention is not limited to this.
  • the uncured primer layer may be formed on at least one of the image layer and the second substrate, and the uncured primer layer and the image layer or the second layer may be formed.
  • a primer layer in which an ink containing a photocurable compound is applied and cured may be provided between the substrate and the substrate in advance. In any configuration, the first substrate and the second substrate can be easily bonded.
  • the plate glass 11 and the plate glass 16 are overlapped so that the sub-primer layers 14 ′ and 14 ′′ are in contact with each other.
  • the cured primer layer 14 is formed by curing the sub-primer layers 14 ′ and 14 ′′ in an uncured state by irradiating ultraviolet rays.
  • the method of irradiating ultraviolet rays is not particularly limited, for example, the ultraviolet rays may be irradiated from one side or both sides of the decorative laminate 10 after overlapping.
  • subprimer layers 14 ′ and 14 ′′ after superimposing the subprimer layers 14 ′ and 14 ′′, they may be moved in the horizontal direction before being irradiated with ultraviolet rays. By sliding or the like, air becomes easier to escape, and mixing of air can be further suppressed.
  • one embodiment of the method for producing a decorative laminate according to the present invention includes the plate glass 11, the color ink layer 12 disposed on the plate glass 11, and the primer layer disposed on the color ink layer 12. 13, 14, 15 and a plate glass 16 disposed on the primer layer 15, and the color ink layer 12 and the primer layers 13, 14, 15 are formed of an ink containing a photocurable compound.
  • An uncured primer layer forming step in which the ink containing the ink is applied and left in an uncured state, and the uncured primer layer forming step is in an uncured state.
  • Bed primer layer 14 ', 14' ' is superimposed so as to be interposed flat glass 11 and flat glass 16 is irradiated with light, comprising a laminating step of curing the primer layer that is in the state of the uncured, the.
  • the primer can be cured by irradiating with light, it can be easily manufactured.
  • the adhesive agent like patent document 2
  • it also has an advantage of preventing deterioration of an image by invading materials such as glass and ink.
  • the second substrate-cured primer layer forming step of applying and curing an ink containing a photocurable compound on the plate glass 16 is performed as an uncured primer layer. Included before the forming step.
  • the plate glass 16 may repel the uncured primer layer, which may affect the surface tension of the uncured primer layer.
  • the uncured primer layer may be fooled, or irregularities may occur on the surface of the uncured primer layer. If it is laminated with the plate glass 11 as it is, there is a possibility that the image looks uneven. Therefore, before the uncured primer layer is formed on the plate glass 16, the primer layer 15 is formed and cured immediately, thereby preventing the plate glass 16 from repelling the uncured primer layer, and the influence of surface tension. Can be suppressed. This can prevent the uncured primer layer from being fooled. In addition, when an uncured primer layer is provided on the primer layer 15, the surface of the uncured primer layer is smoothed (leveled) to prevent the entry of foreign matters such as air and dust when laminated, thereby improving the quality. A decorative laminate.
  • the ink containing the photocurable compound is applied and cured on the plate glass 11 where the color ink layer 12 is not formed.
  • a one-substrate cured primer layer forming step is included before the uncured primer layer forming step.
  • the portion may repel the uncured primer layer, which may affect the surface tension of the uncured primer layer.
  • the uncured primer layer may be fooled, or irregularities may occur on the surface of the uncured primer layer. If it is laminated with the plate glass 16 as it is, there is a possibility that the image looks uneven. Therefore, by forming the primer layer and curing it immediately before forming the uncured primer layer at that location, the plate glass 11 is prevented from repelling the uncured primer layer, and the influence of surface tension is suppressed. be able to. This can prevent the uncured primer layer from being fooled.
  • the surface of the uncured primer layer is smoothed (leveled) to prevent the entry of foreign matters such as air and dust when laminated, thereby improving the quality.
  • a decorative laminate when an uncured primer layer is provided on the primer layer 13, the surface of the uncured primer layer is smoothed (leveled) to prevent the entry of foreign matters such as air and dust when laminated, thereby improving the quality.
  • the uncured primer layer forming step on the first substrate is performed by applying and curing an ink containing a photocurable compound on the color ink layer 12. It is included before the primer layer forming step.
  • the surface gloss of the plate glass 11 and the plate glass 16 can be suppressed from affecting the appearance of the decoration, and the surface can be made to feel like a mat.
  • the decorative laminate 10 includes a plate glass 11, a color ink layer 12 disposed on the plate glass 11, primer layers 13, 14, and 15 disposed on the color ink layer 12, and a primer layer 15.
  • the color ink layer 12 and the primer layers 13, 14, and 15 are formed of ink containing a photocurable compound.
  • the primer can be cured by irradiating with light, it can be easily manufactured.
  • the present invention can be used for decorations that can be used for, for example, nameplates, nameplates, and objects.

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  • Physics & Mathematics (AREA)
  • Engineering & Computer Science (AREA)
  • Plasma & Fusion (AREA)
  • Laminated Bodies (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)

Abstract

La présente invention concerne un stratifié décoratif qui peut être produit plus facilement et pour lequel une contamination par des substances étrangères, telles que de l'air, est empêchée. Le stratifié décoratif (10) est caractérisé par le fait qu'il comprend un premier substrat (11) ayant une transparence optique, une couche d'image (12) qui est disposée sur le premier substrat (11), une couche d'apprêt (13) qui est disposée sur la couche d'image (12), et un second substrat (16) qui est disposé au-dessus de la couche d'apprêt (13) et présente une transparence optique. L'invention est en outre caractérisée en ce que la couche d'image (12) et la couche d'apprêt (13) sont formées par une encre contenant un composé durcissable à la lumière.
PCT/JP2015/069581 2014-07-08 2015-07-08 Procédé permettant de produire un stratifié décoratif, et stratifié décoratif WO2016006619A1 (fr)

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JP2014-140853 2014-07-08
JP2014140853A JP6374243B2 (ja) 2014-07-08 2014-07-08 装飾積層体の製造方法

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5874546A (ja) * 1981-10-29 1983-05-06 ゼネラル・エレクトリツク・カンパニイ 積層安全ガラスとその製法
JPS63135207A (ja) * 1986-11-28 1988-06-07 Dainippon Ink & Chem Inc 接合方法
WO2008038413A1 (fr) * 2006-09-28 2008-04-03 Shibaura Mechatronics Corporation Procédé et appareil de liaison
JP2011190133A (ja) * 2010-03-12 2011-09-29 Central Glass Co Ltd 装飾合わせガラス

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5213825B2 (ja) * 2009-09-28 2013-06-19 大日本印刷株式会社 低誘虫シート及びこれを用いた照明器具
JP5286211B2 (ja) * 2009-09-28 2013-09-11 大日本印刷株式会社 低誘虫シート及びこれを用いた照明器具

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5874546A (ja) * 1981-10-29 1983-05-06 ゼネラル・エレクトリツク・カンパニイ 積層安全ガラスとその製法
JPS63135207A (ja) * 1986-11-28 1988-06-07 Dainippon Ink & Chem Inc 接合方法
WO2008038413A1 (fr) * 2006-09-28 2008-04-03 Shibaura Mechatronics Corporation Procédé et appareil de liaison
JP2011190133A (ja) * 2010-03-12 2011-09-29 Central Glass Co Ltd 装飾合わせガラス

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