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WO2015093264A1 - Composition - Google Patents

Composition Download PDF

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Publication number
WO2015093264A1
WO2015093264A1 PCT/JP2014/081667 JP2014081667W WO2015093264A1 WO 2015093264 A1 WO2015093264 A1 WO 2015093264A1 JP 2014081667 W JP2014081667 W JP 2014081667W WO 2015093264 A1 WO2015093264 A1 WO 2015093264A1
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WO
WIPO (PCT)
Prior art keywords
composition according
weight
alkyl
fatty
surfactant
Prior art date
Application number
PCT/JP2014/081667
Other languages
English (en)
Inventor
Saki Tsuzuki
Daisuke Misu
Original Assignee
L'oreal
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
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Publication of WO2015093264A1 publication Critical patent/WO2015093264A1/fr

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04—Dispersions; Emulsions
    • A61K8/046—Aerosols; Foams
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/08—Preparations for bleaching the hair

Definitions

  • the present invention relates to a composition, particularly a dyeing or a bleaching composition, for keratin fibers such as hair.
  • compositions based on ammonia as an alkaline agent has been proposed, with
  • compositions comprising a large amount of fatty materials. Such compositions usually contain a large quantity of fatty compounds, in combination with an oxidizing agent, with or without an oxidative dye. Such compositions provide high bleaching or dyeing ability. Such compositions are known, for example, in FR2940058A (OA08548), FR2940083A (OA08549), and FR2958161 A (OA10122). In order to enhance the usage quality of hair bleaching or dyeing products, foam textures have been recently recognized as strong improvements in the market, especially in terms of easier handling.
  • compositions in the form of a mousse from the compositions with a large amount of fatty compounds was not proposed because it was thought that a large amount of fatty materials may suppress or collapse the foam.
  • An objective of the invention is to develop a dyeing or bleaching composition with a good quality of foam and a reduced malodor.
  • composition comprising: (a) at least one first alkaline agent(s) selected from amino acid salt(s), (b) at least one second alkaline agent(s) which is different from the (a) first alkaline agent, (c) at least one fatty material(s) at an amount of equal to or higher than 20% by weight, relative to the total weight of the composition, and (d) at least one surfactant.
  • the composition according to the present invention contains a large amount of fatty compounds and still can have a good foamability and exhibit a good stability of the formed foam, as well as a good bleaching or dyeing ability.
  • the foam formed by the composition according to the present invention can show good consistency, as well as good applicability to the keratin fibers.
  • the mousse according the present invention is a mixture of gas, preferably air, with a composition, preferably in the form of a liquid, cream, or gel, and the mixture, expanded or aerated, can have at room temperature (preferably 25 °C) a density preferably less than 0.5, more preferably less than 0.3, and better less than 0.2.
  • the composition according to the present invention may be an aerated composition.
  • composition according to the present invention comprises at least one (a) first alkaline agent(s) selected from amino acid salt(s).
  • first alkaline agent(s) selected from amino acid salt(s).
  • a single type of amino acid salt or a combination of different types of amino acid salts may be used.
  • amino acid salt means a salt of an amino acid.
  • the salt may be a metal salt, such as sodium salt, potassium salt, calcium salt, magnesium salt, and the like. In another embodiment, the salt may be an ammonium salt.
  • amino acid means a compound having an amino radical and an acidic radical at the same time.
  • the amino acid includes alpha-amino acid, beta-amino acid, and gamma-amino acid, and alpha-amino acid is more preferable.
  • the amino acid may be natural or synthetic, and a natural amino acid is more preferable.
  • the amino acid may be, for example, glycine, alanine, valine, leucine, isoleucine, serine,
  • the amino acid may preferably be a neutral amino acid, such as glycine, alanine, valine, leucine, isoleucine, serine, phenylalanine, glutamine, asparagine, and the like.
  • salts of neutral amino acids selected from the group consisting of potassium glycinate, sodium glycinate, potassium alaninate, sodium alaninate, potassium valinate, sodium valinate, potassium leucinate, sodium leucinate, potassium isoleucinate, and sodium isoleucinate are still more preferable, and potassium glycinate and sodium glycinate are most preferable.
  • the amount of the first alkaline agent(s) may be from 0.01% to 20% by weight or from 0.1% to 20% by weight, preferably 0.5% to 15 % by weight, and more preferably from 0.5% to 10 % by weight, relative to the total weight of the composition according to the present invention.
  • composition according to the present invention comprises (b) at least one second alkaline agent(s) which is different from the (a) first alkaline agent.
  • a single type of second alkaline agent or a combination of different types of second alkaline agents may be used.
  • the second alkaline agent may be an inorganic alkaline agent. It is preferable that the inorganic alkaline agent be selected from the group consisting of: alkaline metal hydroxides; alkaline earth metal hydroxides; alkaline metal (hydrogeno)carbonates; alkaline earth metal(hydrogeno)carbonates; and alkaline metal metasilicates.
  • inorganic alkaline agents mention may be made of sodium hydroxide, potassium hydroxide, calcium hydroxide, magnesium hydroxide, sodium carbonate, potassium carbonate, sodium hydrogenocarbonate, potassium
  • the second alkaline agent may be an organic alkaline agent. It is preferable that the organic alkaline agent be selected from the group consisting of: monoamines and derivatives thereof, such as alkanolamines; diamines and derivatives thereof, such as alkanolamines, preferably monoethanolamine; polyamines and derivatives thereof; and guanidine and derivatives thereof.
  • alkanolamines such as mono-, di-, and tri-ethanolamine, comprising 1 to 3 hydroxyalkyl(C 1 -C 4 ) groups.
  • the alkanolamines may be selected from the group consisting of:
  • organic alkaline agents may also be selected from urea, guanidine and their derivatives; and diamines such as those described in the structure below:
  • W denotes an alkylene such as propylene optionally substituted by a hydroxyl or a C1-C4 alkyl radical
  • Ra, Rb, Rc, and Rd independently denote a hydrogen atom, an alkyl radical, or a C1-C4 hydroxyalkyl radical, which may be exemplified by
  • the organic alkaline agents may also be chosen from organic amines of heterocyclic type. Mention may be made in particular of pyridine, piperidine, imidazole, triazole, tetrazole, and benzimidazole.
  • the organic alkaline agent is monoethanolamine.
  • the amount of the second alkaline agent(s) may be from 0.01% to 15% by weight, preferably from 0.1% to 10% by weight, and more preferably from 1% to 6% by weight, relative to the total weight of the composition according to the present invention.
  • composition according to the present invention comprises (c) at least one fatty material(s).
  • a single type of fatty material or a combination of different types of fatty materials may be used.
  • fatty material means an organic compound that is insoluble in water at ordinary temperature (25 °C) and at atmospheric pressure (760 mmHg) (solubility of less than 5%, preferably 1%, and even more preferably 0.1%).
  • the fatty material may contain, in its structure, a sequence of at least two siloxane groups or at least one hydrocarbon-based chain containing at least 6 carbon atoms.
  • the fatty substances may be soluble in organic solvents under the same temperature and pressure conditions, for instance, chloroform, ethanol, benzene, or
  • fatty material(s) do(es) not comprise any C 2 -C 3 oxyalkylene units or any glycerolated units.
  • the fatty material may be in the form of a liquid or a solid.
  • liquid and solid mean that the fatty material is in the form of a liquid or a paste (non-solid) or solid, respectively, at ambient temperature (25°C) under atmospheric pressure (760 mmHg or 105Pa). It is preferable that the fatty material be in the form of a liquid or a paste, more preferably in the form of a liquid, at ambient temperature and under atmospheric pressure.
  • the fatty material may be selected from the group consisting of oils of animal or plant origin, synthetic glycerides, esters of fatty alcohols and/or fatty acids other than animal or plant oils, fatty alcohols, fatty acids, silicone oils, and aliphatic hydrocarbons.
  • fatty materials may be volatile or non- volatile.
  • the fatty material(s) is(are) selected from aliphatic hydrocarbons, plant oils, fatty alcohols, esters of a fatty acid and/or of a fatty alcohol other than animal or plant oils and synthetic glycerides, or mixtures thereof.
  • aliphatic hydrocarbons examples include, for example, linear or branched hydrocarbons, such as mineral oil (e.g., liquid paraffin), paraffin, vaseline or petrolatum, naphthalenes, and the like; hydrogenated polyisobutene, isoeicosan, polydecenes, hydrogenated polyisobutenes such as Parleam, and decene/butene copolymer; and mixtures thereof.
  • aliphatic hydrocarbons mention may also be made of linear or branched, or possibly cyclic C 6 -C 16 lower alkanes. Examples that may be mentioned include hexane, undecane, dodecane, tridecane, and isoparaffins such as isohexadecane, isododecane, and isodecane.
  • caprylic/capric acid triglycerides for instance, those sold by the company Stearineries Dubois or those sold under the names Miglyol® 810, 812 and 818 by the company Dynamit Nobel.
  • silicone oils mention may be made of, for example, linear
  • organopolysiloxanes such as dimethylpolysiloxane, methylphenylpolysiloxane, methylhydrogenpolysiloxane, and the like; cyclic organopolysiloxanes such as octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane,
  • dodecamethylcyclohexasiloxane and the like; and mixtures thereof.
  • plant oils examples include, for example, linseed oil, camellia oil, macadamia nut oil, sunflower oil, apricot oil, soybean oil, arara oil, hazelnut oil, corn oil, mink oil, olive oil, avocado oil, sasanqua oil, castor oil, safflower oil, jojoba oil, sunflower oil, almond oil, grapeseed oil, sesame oil, peanut oil, and mixtures thereof.
  • animal oils mention may be made of, for example, squalene, perhydrosqualene, and squalane.
  • esters of a fatty acid and/or of a fatty alcohol which are examples of the esters of a fatty acid and/or of a fatty alcohol, which are
  • dihydroabietyl behenate octyldodecyl behenate; isocetyl behenate; cetyl lactate; C 12 -C 15 alkyl lactate; isostearyl lactate; lauryl lactate; linoleyl lactate; oleyl lactate; (iso)stearyl octanoate; isocetyl octanoate; octyl octanoate; cetyl octanoate; decyl oleate; isocetyl isostearate; isocetyl laurate; isocetyl stearate; isodecyl octanoate; isodecyl oleate; isononyl isononanoate; isostearyl palmitate; methylacetyl ricinoleate; myristyl stearate;
  • esters of C 4 -C 22 dicarboxylic or tricarboxylic acids and of C 1 -C 22 alcohols and esters of mono-, di-, or tricarboxylic acids and of C 2 -C 26 di-, tri-, tetra-, or pentahydroxy alcohols may also be used.
  • diethyl sebacate diisopropyl sebacate; diisopropyl adipate; di-n-propyl adipate; dioctyl adipate; diisostearyl adipate; dioctyl maleate; glyceryl undecylenate; octyldodecyl stearoyl stearate; pentaerythrityl monoricinoleate; pentaerythrityl tetraisononanoate; pentaerythrityl tetrapelargonate; pentaerythrityl tetraisostearate; pentaerythrityl tetraoctanoate; propylene glycol dicaprylate; propylene glycol dicaprate; tridecyl erucate; triisopropyl citrate;
  • triisostearyl citrate glyceryl trilactate; glyceryl trioctanoate; trioctyldodecyl citrate; trioleyl citrate; propylene glycol dioctanoate; neopentyl glycol diheptanoate; diethylene glycol diisononanoate; and polyethylene glycol distearates.
  • esters mentioned above it is preferred to use ethyl, isopropyl, myristyl, cetyl or stearyl palmitate, 2-ethylhexyl palmitate, 2-octyldecyl palmitate, alkyl myristates such as isopropyl, butyl, cetyl, or 2-octyldodecyl myristate, hexyl stearate, butyl stearate, isobutyl stearate, dioctyl malate, hexyl laurate, 2-hexyldecyl laurate, isononyl isononanoate, or cetyl octanoate.
  • alkyl myristates such as isopropyl, butyl, cetyl, or 2-octyldodecyl myristate, hexyl stearate, butyl stearate, isobutyl
  • composition may also comprise, as fatty esters, sugar esters and diesters of C 6 -C 3 o, and preferably C 12 -C2 2 fatty acids.
  • sugar esters means oxygen-bearing hydrocarbon-based compounds containing several alcohol functions, with or without aldehyde or ketone functions, and which contain at least 4 carbon atoms. These sugars may be monosaccharides, oligosaccharides, or polysaccharides.
  • suitable sugars include sucrose (or saccharose), glucose, galactose, ribose, fructose, maltose, mannose, arabinose, xylose, and lactose, and derivatives thereof, especially alkyl derivatives, such as methyl derivatives, for instance, methylglucose.
  • the sugar esters of fatty acids may be chosen especially from the group comprising the esters or mixtures of esters of sugars described previously and of linear or branched, saturated or unsaturated C 6 -C 3 o, and preferably Ci2-C 22 fatty acids. If they are unsaturated, these compounds may comprise one to three conjugated or non-conjugated carbon-carbon double bonds.
  • esters according to this variant may also be chosen from mono-, di-, tri-, tetraesters, and polyesters, and mixtures thereof.
  • esters may be chosen, for example, from oleates, laurates, palmitates, myristates, behenates, cocoates, stearates, linoleates, linolenates, caprates and arachidonates, or mixtures thereof such as, especially, oleo-palmitate, oleo-stearate, and palmito-stearate mixed esters.
  • monoesters and diesters and especially sucrose, glucose, or methylglucose mono- or dioleates, stearates, behenates, oleopalmitates, linoleates, linolenates, and oleostearates.
  • Glucate® DO is a methylglucose dioleate.
  • esters or mixtures of esters of sugar and of fatty acid examples include:
  • sucrose palmitostearates formed from 73% monoester and 27% diester and triester, from 61% monoester and 39% diester, triester and tetraester, from 52% monoester and 48% diester, triester, and tetraester, from 45% monoester and 55% diester, triester, and tetraester, from 39% monoester and 61% diester, triester, and tetraester, and sucrose monolaurate;
  • Ryoto Sugar Esters for example, referenced B370 and corresponding to sucrose behenate formed from 20% monoester and 80% di- triester-polyester;
  • sucrose mono-dipalmito-stearate sold by the company Goldschmidt under the name Tegosoft® PSE.
  • the fatty material may be at least one fatty alcohol.
  • fatty alcohol here means any saturated or unsaturated, linear or branched C 8 -C 30 fatty alcohol, which is optionally substituted, in particular with one or more hydroxyl groups (in particular, 1 to 4). If they are unsaturated, these compounds may comprise one to three conjugated or non-conjugated carbon-carbon double bonds.
  • C 12 -C 2 2 fatty alcohols for example, are used.
  • lauryl alcohol cetyl alcohol, stearyl alcohol, isostearyl alcohol, oleyl alcohol, behenyl alcohol, linoleyl alcohol, undecylenyl alcohol, palmitoleyl alcohol, linolenyl alcohol, myristyl alcohol, arachidonyl alcohol, and erucyl alcohol, and mixtures thereof.
  • cetyl alcohol, stearyl alcohol, or a mixture thereof (e.g., cetearyl alcohol), as well as myristyl alcohol can be used as a solid fatty material.
  • isostearyl alcohol can be used as a liquid fatty material.
  • the fatty material may be a wax.
  • wax means that the fatty material is substantially in the form of a solid at room temperature (25°C) under atmospheric pressure (760 mmHg), and has a melting point generally of 35°C or more.
  • waxes generally used in cosmetics can be used alone or in combination thereof.
  • the wax may be chosen from carnauba wax, microcrystalline waxes, ozokerites, hydrogenated jojoba oil, polyethylene waxes such as the wax sold under the name "Performalene 400 Polyethylene” by the company New Phase Technologies, silicone waxes, for instance poly(C 24 - C28)alkylmethyldimethylsiloxane, such as the product sold under the name "Abil Wax 9810” by the company Goldschmidt, palm butter, the C 20 -C 40 alkyl stearate sold under the name "Kester Wax K82H” by the company Kester Keunen, stearyl benzoate, shellac wax, and mixtures thereof.
  • polyethylene waxes such as the wax sold under the name "Performalene 400 Polyethylene” by the company New Phase Technologies
  • silicone waxes for instance poly(C 24 - C28)alkylmethyldimethylsiloxane, such as the product sold under the name "Abil Wax 9810” by the company Goldsch
  • a wax chosen from carnauba wax, candelilla wax, ozokerites, hydrogenated jojoba oil, and polyethylene waxes is used.
  • the wax is preferably chosen from candelilla wax and ozokerite, and mixtures thereof.
  • mineral oils are preferable.
  • the amount of the (c) fatty material(s) is 20% by weight or more, preferably 30% by weight or more, more preferably 35% by weight or more, and further more preferably 40% by weight or more, relative to the total weight of the composition according to the present invention.
  • the composition according to the present invention without an oxidizing agent contains 40% by weight or more of fatty material, and after mixing with an oxidizing agent, the amount of the (c) fatty material is 20% by weight or more, and preferably 25% by weight or more, relative to the amount of the composition.
  • composition according to the present invention comprises at least one (d) surfactant(s).
  • the surfactant used in the present invention may be selected from the group consisting of anionic surfactants, amphoteric surfactants, cationic surfactants, and nonionic surfactants. A single type of surfactant or a combination of different types of surfactants may be used. In one embodiment, the "surfactant" is capable of forming foam with water without additives.
  • the surfactant may more preferably be a combination of at least one anionic surfactant(s), at least one amphoteric surfactant(s), and at least one nonionic surfactant(s).
  • the total amount of the (d) surfactant(s) is from 0.1% to 25% by weight, preferably from 0.5% to 20% by weight, and more preferably from 1% to 15% by weight, relative to the total weight of the composition.
  • the type of anionic surfactant is not limited. It is preferable that the anionic surfactant be selected from the group consisting of
  • the anionic surfactants are i the form of salts such as salts of alkali metals, for instance, sodium; salts of alkaline-earth metals, for instance, magnesium; ammonium salts; amine salts; and amino alcohol salts. Depending on the conditions, they may also be in acid form.
  • the anionic surfactant be selected from salts of (C 6 -C3 0 )alkyl sulfate.
  • the amount of the anionic surfactant may be from 0.01% to 20% by weight, preferably from 0.1%) to 15% by weight, and more preferably from 0.3% to 8% by weight, relative to the total weight of the composition.
  • amphoteric surfactant is not limited.
  • the amphoteric (or zwitterionic) surfactants can be, for example, amine derivatives such as aliphatic secondary or tertiary amine, and optionally quaternized amine derivatives, in which the aliphatic radical is a linear or branched chain comprising 8 to 22 carbon atoms and containing at least one water-solubilizing anionic group (for example, carboxylate, sulphonate, sulphate, phosphate, or phosphonate).
  • amphoteric surfactant may preferably be selected from the group consisting of betaines and amidoaminecarboxylated derivatives.
  • the betaine-type amphoteric surfactant is preferably selected from the group consisting of alkylbetaines, alkylamidoalkylbetaines, sulfobetaines, phosphobetaines, and alkylamidoalkylsulfobetaines, in particular, (C 8 -C 2 4)alkylbetaines,
  • amphoteric surfactants of betaine type are chosen from (C 8 -C 24 )alkylbetaines,
  • Non-limiting examples that may be mentioned include the compounds classified in the CTFA dictionary, 9th edition, 2002, under the names cocobetaine, laurylbetaine, cetylbetaine, coco/oleamidopropylbetaine, cocamidopropylbetaine,
  • palmitamidopropylbetaine palmitamidopropylbetaine, stearamidopropylbetaine, cocamidoethylbetaine,
  • cocamidopropylhydroxysultaine cocamidopropylhydroxysultaine, oleamidopropylhydroxysultaine, cocohydroxysultaine, laurylhydroxysultaine, and cocosultaine, alone or as mixtures.
  • the betaine-type amphoteric surfactant is preferably an alkylbetaine and an
  • alkylamidoalkylbetaine in particular, cocobetaine and cocamidopropylbetaine.
  • amidoaminecarboxylated derivatives mention may be made of the products sold under the name Miranol, as described in U.S. Pat. Nos. 2,528,378 and 2,781,354 and classified in the CTFA dictionary, 3rd edition, 1982 (the disclosures of which are incorporated herein by reference), under the names Amphocarboxyglycinates and Amphocarboxypropionates.
  • the amphoteric surfactant may be selected from (C 8 -C2 4 )-alkyl amphomonoacetates, (C 8 -C 24 )alkyl amphodiacetates, (C8-C 24 )alkyl amphomonopropionates, and
  • cocoamphodiacetate sold under the trade name MiranolR C2M concentrate by the company Rhodia Chimie.
  • the amount of the amphoteric surfactant(s) may be from 0.01% to 20% by weight, preferably from 0.1% to 15% by weight, and more preferably from 1% to 10% by weight, relative to the total weight of the composition according to the present invention.
  • the type of cationic surfactant is not limited.
  • the cationic surfactant may be selected from the group consisting of optionally
  • quaternary ammonium salts examples include, alkyl quarternary ammonium salt, for example, chloride and methyl sulfate, of
  • diacyloxyethyl-dimethylammonium of diacyloxyethylhydroxyethyl-methylammonium, of monoacyloxyethyldihydroxyethyl- methylammonium, of
  • the acyl radicals may comprise from 14 to 18 carbon atoms, and may be derived, for example, from a plant oil, for instance palm oil and sunflower oil. When the compound comprises several acyl radicals, these radicals may be identical or different.
  • These products may be obtained, for example, by direct esterification of optionally oxyalkylenated triethanolamine, triisopropanolamine, alkyldiethanolamine, or alkyldiisopropanolamine onto fatty acids or onto mixtures of fatty acids of plant or animal origin, or by transesterification of the methyl esters thereof.
  • This esterification may be followed by a quaternization using an alkylating agent chosen from alkyl halides, for example, methyl and ethyl halides; dialkyl sulfates, for example, dimethyl and diethyl sulfates; methyl methanesulfonate; methyl para-toluenesulfonate; glycol chlorohydrin; and glycerol chlorohydrin.
  • alkylating agent chosen from alkyl halides, for example, methyl and ethyl halides; dialkyl sulfates, for example, dimethyl and diethyl sulfates; methyl methanesulfonate; methyl para-toluenesulfonate; glycol chlorohydrin; and glycerol chlorohydrin.
  • Such compounds are sold, for example, under the names Dehyquart® by the company Cognis, Stepanquat® by the company Stepan, Noxamium® by the company Ceca, and "Rewoquat® WE 18" by the company Rewo-Goldschmidt.
  • compositions according to the present invention may comprise, for example, a mixture of quaternary ammonium mono-, di-, and tri-ester salts with a weight majority of diester salts.
  • compositions according to the present invention include, but are not limited to, those corresponding to formula (I), for example, tetraalkylammonium chlorides, for instance, dialkyldimethylammonium and alkyltrimethylammonium chlorides in which the alkyl radical comprises from about 12 to 22 carbon atoms, such as
  • the cationic surfactant that may be used in the
  • compositions of the present invention is chosen from quaternary ammonium salts, for example, from behenyltrimethylammonium chloride, cetyltrimethylammonium chloride, Quaternium-83, Quaternium-87, Quaternium-22,
  • the amount of the cationic surfactant(s) may be, if present, from 0.01% to 20% by weight, preferably from 0.1% to 15% by weight, and more preferably from 0.3% to 8% by weight, relative to the total weight of the composition according to the present invention.
  • nonionic surfactant is not limited.
  • the nonionic surfactants are compounds well known in themselves (see, e.g., in this regard, "Handbook of Surfactants” by M. R. Porter, Blackie & Son publishers (Glasgow and London), 1991 , pp. 116-178). Thus, they can, for example, be chosen from alcohols, alpha-diols, alkylphenols, and esters of fatty acids that are polyethoxylated,
  • polypropoxylated, or polyglycerolated and have at least one fatty chain comprising, for example, from 8 to 18 carbon atoms, it being possible for the number of ethylene oxide or propylene oxide groups to range from 2 to 50, and for the number of glycerol groups to range from 2 to 30.
  • Maltose derivatives may also be mentioned.
  • Non-limiting mention may also be made of copolymers of ethylene oxide and/or of propylene oxide; condensates of ethylene oxide and/or of propylene oxide with fatty alcohols;
  • polyethoxylated fatty amides comprising, for example, from 2 to 30 mol of ethylene oxide; polyglycerolated fatty amides comprising, for example, from 1 to 5 glycerol groups, such as from 1.5 to 4; ethoxylated fatty acid esters of sorbitan comprising from 2 to 30 mol of ethylene oxide; ethoxylated oils of plant origin; fatty acid esters of sucrose; fatty acid esters of polyethylene glycol; fatty acid mono or diesters of glycerol; (C 6 -C 24 )alkylpolyglycosides; N-(C 6 -C 24 )alkylglucamine derivatives, amine oxides such as (C 10 -C 1 4)alkylamine oxides or N- (C 10 -Ci 4 )acylaminopropylmorpholine oxides; and mixtures thereof.
  • polyglycerolated fatty amides comprising, for example, from 1 to 5
  • the nonionic surfactants may preferably be chosen from monooxyalkylenated or polyoxyalkylenated, monoglycerolated, or polyglycerolated nonionic surfactants.
  • the oxyalkylene units are more particularly oxyethylene or oxypropylene units, or a combination thereof, preferably oxyethylene units.
  • oxyalkylenated nonionic surfactants examples include:
  • oxyalkylenated (C8-C 24 )alkylphenols saturated or unsaturated, linear or branched, oxyalkylenated C8-C30 alcohols; saturated or unsaturated, linear or branched, oxyalkylenated C 8 - C 30 amides; esters of saturated or unsaturated, linear or branched, C8-C30 acids and of polyethylene glycols; poly oxyalkylenated esters of saturated or unsaturated, linear or branched, C 8 -C 3 o acids and of sorbitol; saturated or unsaturated, oxyalkylenated plant oils; condensates of ethylene oxide and/or of propylene oxide, inter alia, alone or as mixtures.
  • the surfactants contain a number of moles of ethylene oxide and/or of propylene oxide of between 1 and 100 and preferably between 2 and 50.
  • the nonionic surfactants do not comprise any oxypropylene units.
  • oxyalkylenated nonionic surfactants are chosen from oxyethylenated C8-C30 alcohols or ethoxylated fatty esters.
  • ethoxylated (or oxyethylenated) fatty alcohols examples include the adducts of ethylene oxide with lauryl alcohol, especially those containing from 9 to 50 oxyethylene groups, and more particularly those containing from 10 to 12 oxyethylene groups (Laureth-10 to Laureth-12, as the CTFA names); the adducts of ethylene oxide with behenyl alcohol, especially those containing from 9 to 50 oxyethylene groups (Beheneth-9 to Beheneth-50, as the CTFA names); the adducts of ethylene oxide with cetearyl alcohol (mixture of cetyl alcohol and stearyl alcohol), especially those containing from 10 to 30 oxyethylene groups (Ceteareth-10 to Ceteareth-30, as the CTFA names); the adducts of ethylene oxide with cetyl alcohol, especially those containing from 10 to 30 oxyethylene groups (Ceteth-10 to Ceteth-30, as the CTFA names); the adducts of ethylene oxide with cety
  • ethoxylated fatty esters examples include the adducts of ethylene oxide with esters of lauric acid, palmitic acid, stearic acid, or behenic acid, and mixtures thereof, especially those containing from 9 to 50 oxyethylene groups, such as PEG-9 to PEG-50 laurate (as the CTFA names: PEG-9 laurate to PEG-50 laurate); PEG-9 to PEG-50 palmitate (as the CTFA names: PEG-9 palmitate to PEG-50 palmitate); PEG-9 to PEG-50 stearate (as the CTFA names: PEG-9 stearate to PEG-50 stearate); PEG-9 to PEG-50 palmitostearate; PEG-9 to PEG-50 behenate (as the CTFA names: PEG-9 behenate to PEG-50 behenate); and mixtures thereof.
  • PEG-9 to PEG-50 laurate as the CTFA names: PEG-9 laurate to PEG-50 laurate
  • the composition according to the present invention comprises at least one ethoxylated fatty alcohol.
  • monoglycerolated or polyglycerolated C 8 -C4 0 alcohols are preferably used.
  • the monoglycerolated or polyglycerolated Cg-C 4 o alcohols correspond to the following formula:
  • Polyglyceryl-4 Lauryl Ether lauryl alcohol containing 1.5 mol of glycerol, oleyl alcohol containing 4 mol of glycerol (INCI name: Polyglyceryl-4 Oleyl Ether), oleyl alcohol containing 2 mol of glycerol (INCI name: Polyglyceryl-2 Oleyl Ether), cetearyl alcohol containing 2 mol of glycerol, cetearyl alcohol containing 6 mol of glycerol, oleocetyl alcohol containing 6 mol of glycerol, and octadecanol containing 6 mol of glycerol.
  • the alcohol may represent a mixture of alcohols in the same way that the value of m represents a statistical value, which means that, in a commercial product, several species of polyglycerolated fatty alcohol may coexist in the form of a mixture.
  • the monoglycerolated or polyglycerolated alcohols it is more particularly preferred to use the Cs/Qo alcohol containing 1 mol of glycerol, the C 10 /C 12 alcohol containing 1 mol of glycerol, and the C 12 alcohol containing 1.5 mol of glycerol.
  • the nonionic surfactant may be a nonionic surfactant with an HLB from 8 to 18.
  • the HLB is the ratio between the hydrophilic part and the lipophilic part in the molecule. This term HLB is well known to those skilled in the art and is described in "The HLB system. A time-saving guide to emulsifier selection" (published by ICI Americas Inc., 1984).
  • the amount of the nonionic surfactant(s) may be from 0.01% to 20% by weight, preferably from 0.05% to 15% by weight, and more preferably from 0.1% to 10% by weight, relative to the total weight of the composition according to the present invention.
  • the composition according to the present invention contains at least one anionic surfactant(s), at least one amphoteric surfactant(s), and at least one nonionic surfactant(s).
  • the composition according to the present invention contains the anionic surfactant(s) in an amount ranging from 0.01% to 20% by weight, preferably from 0.1% to 15% by weight, and more preferably from 0.3% to 8%; the amphoteric surfactant(s) in an amount ranging from 0.01% to 20% by weight, preferably from 0.1% to 15% by weight, and more preferably from 1% to 10% by weight; and the nonionic surfactant(s) in an amount ranging from 0.01% to 20% by weight, preferably from 0.05% to 15% by weight, and more preferably from 0.1% to 10% by weight, relative to the total weight of the composition according to the present invention.
  • the composition according to the present invention can comprise at least one (e) dye(s).
  • e e.g., A single type of dye or a combination of different types of dyes may be used.
  • the dye may be an oxidation dye.
  • the oxidation dye can be selected from oxidation bases, oxidation couplers, and the acid addition salts thereof.
  • the oxidation base can be selected from those conventionally known in oxidation dyeing, preferably from the group consisting of ortho- and para-phenylenediamines, double bases, ortho- and para-aminophenols, heterocyclic bases, and the acid addition salts thereof.
  • the oxidation dye may be an oxidation coupler which can be selected from those conventionally known in oxidation dyeing, preferably from the group consisting of meta-phenylenediamines, meta-aminophenols, meta-diphenols, naphthols, heterocyclic couplers, and the acid addition salts thereof.
  • the heterocyclic couplers may be selected from the group consisting of indole derivatives, indoline derivatives, sesamol and its derivatives, pyridine derivatives, pyrazolotriazole derivatives, pyrazolones, indazoles, benzimidazoles, benzothiazoles, benzoxazoles, 1,3-benzodioxoles, quinolines, and addition salts thereof with an acid.
  • the addition acid salts of the oxidation bases and couplers are chosen in particular from hydrochlorides, hydrobromides, sulphates, tartrates, lactates, and acetates.
  • the oxidation dye(s) more particularly represent from 0.0001% to 20% by weight, preferably from 0.005% to 15% by weight, and more preferably from 0.005% to 10% by weight, relative to the total weight of the composition.
  • the dye may be a direct dye.
  • the direct dye can be selected from ionic and nonionic species, preferably cationic or nonionic species.
  • Suitable direct dyes include the following direct dyes: azo dyes; methine dyes; carbonyl dyes; azine dyes; nitro (hetero)aryl dyes;
  • tri(hetero)arylmethane dyes include porphyrin dyes; phthalocyanin dyes, and natural direct dyes, alone or as mixtures.
  • the direct dye(s) more particularly represent from 0.0001%) to 10%) by weight, and preferably from 0.005% to 5% by weight, relative to the total weight of the composition.
  • composition according to the present invention may further comprise at least one
  • (f) oxidizing agent (f) oxidizing agent.
  • a single type of oxidizing agent or a combination of different types of oxidizing agents may be used.
  • the oxidizing agent may be chosen from hydrogen peroxide, peroxygenated salts, and compounds capable of producing hydrogen peroxide by hydrolysis.
  • the oxidizing agent can be chosen from aqueous hydrogen peroxide solution, urea peroxide, alkali metal bromates, and ferricyanides, and persalts such as perborates and
  • the oxidizing agent be hydrogen peroxide.
  • the amount of the oxidizing agent may be, if present, from 0.1% to 15% by weight, preferably from 0.5% to 10% by weight, and more preferably from 1% to 5% by weight, relative to the total weight of the composition according to the present invention.
  • the oxidizing agent may be present in a separate composition (oxidizing composition).
  • composition according to the present invention may further comprise at least one (g) foam stabilizer(s).
  • foam stabilizer(s) A single type of foam stabilizer or a combination of different types of foam stabilizers may be used.
  • any substance which can stabilize foam formed by the composition according to the present invention may be used as the foam stabilizer.
  • the foam stabilizer may be a rheology modifier selected from hydrophilic or lipophilic, organic or inorganic polymers and nonpolymers.
  • rheology modifier for example, mention may be made of: partly or totally crosslinked elastomeric organopolysiloxanes, of three-dimensional structure, such as those sold under the names KSG6, KSG16, and KSG18 by Shin-Etsu, Trefil E-505C or Trefil E23 506C by Dow Corning, Gransil SR-CYC, SR DMF10, SR-DC556, SR 5 CYC gel, SR DMF 10 gel, and SR DC 556 gel by Grant Industries, and SF 1204 and JK 113 by General Electric; and copolymers of a C 36 diacid condensed with
  • ethylenediamine with a weight-average molecular mass of approximately 6,000, such as the compounds sold by Arizona Chemical under the names Uniclear 80 and Uniclear 100; and silicone gums, such as PDMS, having a viscosity of equal to or more than 100,000 centistokes.
  • the rheology modifier may preferably be chosen from organophilic clays; fumed silicas; fatty acid amides; thickening polymers such as cellulose polymers,
  • galactomannans and derivatives thereof, gums of microbial origin, acrylic acid or acrylamidopropanesulfonic acid crosslinked homopolymers; associative polymers; and mixture thereof.
  • organophilic clays and fumed silicas for example, mention may be made of: optionally modified clays, such as hectorites modified with a C 10 -C 22 fatty acid ammonium chloride, such as hectorite modified with distearyldimethylammonium chloride; and pyrogenic silica, optionally having received a hydrophobic surface treatment, whose particle size is less than 1 ⁇ .
  • optionally modified clays such as hectorites modified with a C 10 -C 22 fatty acid ammonium chloride, such as hectorite modified with distearyldimethylammonium chloride
  • pyrogenic silica optionally having received a hydrophobic surface treatment, whose particle size is less than 1 ⁇ .
  • any amide comprising in its structure at least one
  • the fatty acid amides may be chosen from compounds derived from an amide of alkanolamine and of a saturated or unsaturated, linear or branched C 8 -C 3 o fatty acid, the alkanolamine and/or the fatty acid being optionally oxyalkenylated and more particularly
  • the fatty acid amides are preferably chosen from amides of a C 2 - C 10 alkanolamine and of a C 14 -C 30 fatty acid, and more preferably chosen from amides of a C 2 -C 10 alkanolamine and of a C 1 -C 22 fatty acid.
  • cellulose polymers for example, mention may be made of:
  • ethylhydroxyethylcelluloses ethylhydroxyethylcelluloses, carboxymethylcelluloses, and quaternized cellulose derivatives.
  • non-ionic guar gum specifically modified non-ionic guar gums and unmodified non-ionic guar gums.
  • the unmodified non-ionic guar gums are, for example, the products sold under the name Vidogum GH 175 by the company Unipectine and under the names Meypro-Guar 50 and Jaguar C by the company Rhodia Chimie.
  • modified non-ionic guar gums are in particular modified with C1-C6 hydroxyalkyl groups.
  • hydroxyalkylated guar gums are well known in the prior art and can be prepared, for example, by reacting corresponding alkene oxides such as, for example, propylene oxides, with the guar gum so as to obtain a guar gum modified with hydroxypropyl groups.
  • the degree of hydroxyalkylation which corresponds to the number of alkylene oxide molecules consumed by the number of free hydroxyl functions present on the guar gum, preferably ranges from 0.4 to 1.2.
  • non-ionic guar gums optionally modified with hydroxyalkyl groups are sold, for example, under the trade names Jaguar HP8, Jaguar HP60, Jaguar HP 120,
  • non-ionic guar gums modified with hydroxyalkyl groups, more especially hydroxypropyl groups, modified with groups comprising at least one C6-C30 fatty chain.
  • acrylic acid or acrylamidopropanesulfonic acid crosslinked homopolymers for example, mention may be made of: acrylic acid homopolymers crosslinked with an allylic alcohol ether of the sugar series, for example, the products sold under the names CARBOPOL 980, 981, 954, 2984, and 5984 by the company Goodrich and the products sold under the names SYNTHALEN M and SYNTHALEN K by the company 3 VSA; crosslinked acrylamidomethanesulfonic acid homopolymers, crosslinked acrylamidoethanesulfonic acid homopolymers, crosslinked acrylamidopropanesulfonic acid homopolymers, crosslinked 2-acrylamido-2-methylpropanesulfonic acid
  • any amphiphilic polymer comprising, in its structure, at least one fatty chain and at least one hydrophilic portion, may be used.
  • the associative polymers in accordance with the present disclosure may be chosen from anionic, cationic, nonionic, and amphoteric polymers.
  • Anionic amphiphilic polymers are described and prepared, for example, according to an emulsion polymerization process described in document EP-0 216 479.
  • Associative anionic polymers of which non-limiting mention may be made include anionic polymers comprising at least one hydrophilic unit of olefinic unsaturated carboxylic acid type, and at least one hydrophobic unit exclusively of (C 10 -C 30 )alkyl ester of unsaturated carboxylic acid type.
  • Cationic associative polymers of which non-limiting mention may be made include quaternized cellulose derivatives and polyacrylates comprising at least one amine side group.
  • the nonionic associative polymers may be chosen from at least one of:
  • celluloses modified with groups comprising at least one fatty chain for example hydroxyethylcelluloses modified with groups comprising at least one fatty chain, such as alkyl groups, for example.
  • alkyl groups for example.
  • C 8 -C 20 , arylalkyl and alkylaryl groups for example,
  • guars for example, hydroxypropyl guar, modified with groups comprising at least one fatty chain, for example, an alkyl chain, copolymers of vinylpyrrolidone and of fatty-chain hydrophobic monomeric residues,
  • copolymers of at least one monomeric residue chosen from Q-Q alkyl methacrylates and acrylates and of amphiphilic monomeric residues comprising at least one fatty chain copolymers of monomeric residues chosen from hydrophilic methacrylates and acrylates and of hydrophobic monomeric residues comprising at least one fatty chain, for example, the polyethylene glycol methacrylate/lauryl methacrylate copolymer, associative polyurethanes,
  • the associative polymers may be chosen from associative polyurethanes.
  • the associative polyurethanes may be chosen from nonionic block copolymers comprising in the chain both hydrophilic blocks usually of polyoxyethylene nature, and hydrophobic blocks that may be chosen from aliphatic sequences, cycloaliphatic sequences, and aromatic sequences.
  • the polymers that may be used include those described in the article by G. Fonnum, J. Bakke and Fk. Hansen-Colloid Polym. Sci 271, 380-389 (1993).
  • xanthane gums may be used.
  • the foam stabilizer may more preferably be selected from the group consisting of cellulose polymers, guars, especially, non-ionic guar gums optionally modified with hydroxyalkyl groups, and xanthane gums.
  • the amount of the foam stabilizer(s) may be, if present, from 0.05% to 20% by weight, preferably from 0.1% to 15% by weight, and more preferably from 0.5% to 10% by weight, relative to the total weight of the composition according to the present invention.
  • the composition according to the present invention may comprise an aqueous medium.
  • the aqueous medium in the composition according to the present invention may comprise water.
  • the amount of water may be less than 80% by weight, preferably from 3% to 75% by weight, more preferably from 5% to 70% by weight, and further more preferably from 10% to 50% by weight, relative to the total weight of the composition.
  • the composition according to the present invention without an oxidizing agent contains from 10% to 50% by weight or more, and after mixing with an oxidizing agent, the amount of water is from 20% to 70% by weight, relative to the amount of the composition.
  • the aqueous medium may further comprise at least one organic solvent.
  • the organic solvent is preferably water-miscible.
  • the organic solvent there may be mentioned, for example, C1-C4 alkanols, such as ethanol and isopropanol; polyols and polyolethers such as glycerol, 2-butoxyethanol, propylene glycol, monomethyl ether of propylene glycol, and monoethyl ether and monomethyl ether of diethylene glycol; and aromatic alcohols such as benzyl alcohol and phenoxy ethanol; analogous products; and mixtures thereof.
  • C1-C4 alkanols such as ethanol and isopropanol
  • polyols and polyolethers such as glycerol, 2-butoxyethanol, propylene glycol, monomethyl ether of propylene glycol, and monoethyl ether and monomethyl ether of diethylene glycol
  • aromatic alcohols such as benzyl alcohol and phenoxy ethanol
  • the organic solvent(s) may be present in an amount ranging from 0.5% to 40% by weight, preferably from 1% to 30% by weight, and more preferably from 5% to 20% by weight, relative to the total weight of the composition.
  • composition according to the present invention may also comprise an effective amount of other agents, known previously elsewhere in oxidation dyeing, such as various common adjuvants, for instance, ammonia, sequestering agents such as EDTA and etidronic acid, UV screening agents, silicones other than those mentioned before such as organomodified silicones (such as with amine groups), preserving agents, ceramides, pseudoceramides, vitamins or provitamins, for instance, panthenol, opacifiers, and so on.
  • agents known previously elsewhere in oxidation dyeing, such as various common adjuvants, for instance, ammonia, sequestering agents such as EDTA and etidronic acid, UV screening agents, silicones other than those mentioned before such as organomodified silicones (such as with amine groups), preserving agents, ceramides, pseudoceramides, vitamins or provitamins, for instance, panthenol, opacifiers, and so on.
  • the form of the composition according to the present invention is not particularly limited, and may take various forms such as an O/W emulsion, a W/O emulsion, a multiple emulsion, or the like.
  • the form of an O/W emulsion is preferable.
  • the pH value of the composition according to the present invention applied to the keratin fibers may generally be, for example, from 4 to 12. It can range from 6 to 12, and preferably 7 to 11, and may be adjusted to the desired value using at least one acidifying agent that is well known in the prior art.
  • the acidifying agents can be, for example, mineral or organic acids, for instance, hydrochloric acid, orthophosphoric acid, carboxylic acids, for instance, tartaric acid, citric acid, and lactic acid, or sulphonic acids.
  • the composition according to the present invention may be formulated into a kit comprising at least a first compartment and a second compartment.
  • the first compartment comprises (a) at least one first alkaline agent(s) selected from amino acid salt(s), (b) at least one second alkaline agent(s) which is (are) different from the (a) first alkaline agent, (c) at least one fatty material(s) at an amount of 20% by weight or more, relative to the total amount of the first compartment, (d) at least one surfactant(s), and optionally (e) at least one dye.
  • the second compartment comprises (f) at least one oxidizing agent(s).
  • the second compartment after mixing the first compartment, wherein the amount of (c) fatty material(s) is 30% by weight of more, with the second compartment, wherein the amount of the (c) fatty material(s) is 20% by weight or more, relative to the total weight of the composition obtained by mixing the first compartment and the second compartment.
  • composition according to the present invention can be formed as a mousse from air, inert gas, or a mixture thereof with the previously described composition.
  • the composition can be packaged in a foam dispenser. It can involve either products referred to as "aerosols" dispensed from a pressurized container by means of a propellant gas and thus forming a foam at the time of their dispensing, or compositions dispensed from a container by means of a mechanical pump connected to a dispensing head where the passage of the composition through the dispensing head transforms it into a foam in the area of the outlet orifice of such a head at the latest.
  • aerosols dispensed from a pressurized container by means of a propellant gas and thus forming a foam at the time of their dispensing
  • compositions dispensed from a container by means of a mechanical pump connected to a dispensing head where the passage of the composition through the dispensing head transforms it into a foam in the area of the outlet orifice of such a head at the latest.
  • the dispenser can be an aerosol furthermore containing the composition according to the present invention, generally divided into two parts: one with the oxidizing agent(s) and the other with the alkaline agent(s) and optionally the coloring substance(s) and a propellant gas.
  • the two parts are stored separately, each in a pressurized container.
  • the propellant gases selected for each of the containers can be adapted to the part of the composition with which it is mixed.
  • the purpose of the present invention is a non-aerosol device comprising the composition from the present invention.
  • the present invention also relates to a process for keratin fibers such as hair, comprising: a step of mixing or shaking the composition according to the present invention and an oxidizing agent to prepare a mixture (ready-to-use mixture), and a step of applying the mixture to the keratin fibers.
  • the mixing can be performed using any means such as a spoon and a whisk.
  • the mixing or shaking is performed using a device dispensing a mousse, aerosol, or non aerosol, such as described before.
  • composition according to the present invention can be used in treating (e.g., dyeing or bleaching) keratin fibers such as hair, comprising, for example, the steps:
  • composition which is either prepared by mixing or shaking, just before the application to the keratin fibers, one or more of the components (a) to (d) and the other components in the composition according to the present invention;
  • composition to act for an exposure time, ranging, for example, from 1 to 60 minutes, or from 5 to 45 minutes;
  • composition according to the present invention may be realized at room temperature or with the use of a warming device which is able to produce a temperature ranging from 40 to 220°C, and preferably ranging from 40 to 80°C.
  • compositions according to Examples 1-5 and Reference Examples 1-4 were prepared by mixing the components shown in Table 1 or 2.
  • the numerical values for the amounts of the components shown in the tables are all based on "% by weight" as active raw materials.
  • PEG-40 Hydrogenated castor oil, coco-betaine, sodium laureth sulfate, sodium metabisulfite, chelating agent (EDTA and/or pentasodium pentetate), and glycinate salt (potassium glycinate or sodium glycinate) or other alkaline agents shown in Table 2 were mixed in water. Then to the mixture was added mineral oil at 40° C with agitation at 40°C. Then to the mixture was added guar gum 2-hydroxypropyl ether or hydroxyethyl cellulose. The mixture was cooled to room temperature. To the mixture were added ascorbic acid (pre-dissolved in water) and the dyes (for Ex. 5 only), and then monoethanolamine was further added into the mixture with agitation.
  • Coco-betaine (30% AM) 10 10 10 10 10
  • compositions differ from the composition according to the present invention by the type of the first alkali agent.
  • the alkali-containing composition as shown in Tables 1 and 2 was put into a centrifuge and the centrifuge was spun at 3000 rpm for 60 min.
  • alkali-containing composition was taken out from the centrifuge. The appearance of the composition was checked visually for stability.
  • Each alkali-containing composition was mixed thoroughly with a developer (oxidizing agent) as shown in Table 3 at the weight ratio as shown in Table 4.
  • the mixture was applied immediately after the preparation thereof onto a swatch of Japanese black hair in a weight ratio 3:1 (dye composition : hair swatch).
  • the applied hair swatch was left for 30 minutes at 30°C. Then, the applied hair swatch was washed out by shampoo and dried.
  • the color of the hair was determined by using the L*a*b* system, with a Minolta CM-508d spectrophotometer. According to this system, L indicates the lightness. The lower the value of L, the more intense the color of the hair.
  • ⁇ which is the color variation between an uncolored lock and a colored lock, is obtained from the following formula:
  • Foam Uniformity foam uniformity was evaluated by appearance and measuring pH values of the foam at several points of different depth in the container.
  • Ref. Ex. 1 alkaline agent corresponding to glycinate salt was not used
  • Ref. Ex. 2 potassium carbonate was used
  • Ref. Ex. 3 potassium hydroxide was used
  • Ref. Ex. 4 containing a low amount of fatty material showed high stability and foam volume, but was not satisfactory in terms of lightening ability, foam thickness, and foam uniformity.
  • composition according to Example 5 has the same ingredients as the composition according to Example 3 except for oxidation dye precursors and couplers, the composition according to Example 3 is believed to have satisfactory properties, in terms of all of bleaching ability, foaming property, and cosmetic property, which are equivalent to those for Example 1.

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Abstract

La présente invention concerne une composition comprenant : (a) au moins un premier agent alcalin choisi parmi un ou plusieurs sels d'acide aminé, (b) au moins un second agent alcalin qui est différent du premier agent alcalin (a), (c) au moins un matériau gras en une quantité supérieure ou égale à 20 % en poids, par rapport au poids total de la composition, et (d) au moins un tensioactif. L'invention est utile, car la composition selon la présente invention peut avoir un bon pouvoir moussant ainsi qu'une bonne capacité de blanchiment ou de coloration de fibres de kératine comme le système pileux.
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WO2017021511A1 (fr) * 2015-08-04 2017-02-09 L'oreal Kit de coloration et/ou décoloration des fibres de kératine comprenant un agent alcalin, un agent oxydant et un récipient étanche à l'air ouvrable et refermable

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