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WO2014085594A3 - Systems and methods for producing hydrogen gas - Google Patents

Systems and methods for producing hydrogen gas Download PDF

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Publication number
WO2014085594A3
WO2014085594A3 PCT/US2013/072240 US2013072240W WO2014085594A3 WO 2014085594 A3 WO2014085594 A3 WO 2014085594A3 US 2013072240 W US2013072240 W US 2013072240W WO 2014085594 A3 WO2014085594 A3 WO 2014085594A3
Authority
WO
WIPO (PCT)
Prior art keywords
carrier gas
hydrocarbon feedstock
reaction chamber
systems
methods
Prior art date
Application number
PCT/US2013/072240
Other languages
French (fr)
Other versions
WO2014085594A2 (en
Inventor
Roderick A. Hyde
Lowell L. Wood, Jr.
Original Assignee
Elwha Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US13/691,585 external-priority patent/US20140154170A1/en
Priority claimed from US13/691,552 external-priority patent/US9434612B2/en
Priority claimed from US13/691,543 external-priority patent/US9156688B2/en
Application filed by Elwha Llc filed Critical Elwha Llc
Publication of WO2014085594A2 publication Critical patent/WO2014085594A2/en
Publication of WO2014085594A3 publication Critical patent/WO2014085594A3/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/22Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds
    • C01B3/24Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds of hydrocarbons
    • C01B3/26Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds of hydrocarbons using catalysts
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/50Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02Processes for making hydrogen or synthesis gas
    • C01B2203/0266Processes for making hydrogen or synthesis gas containing a decomposition step
    • C01B2203/0277Processes for making hydrogen or synthesis gas containing a decomposition step containing a catalytic decomposition step
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08Methods of heating or cooling
    • C01B2203/0805Methods of heating the process for making hydrogen or synthesis gas
    • C01B2203/0811Methods of heating the process for making hydrogen or synthesis gas by combustion of fuel
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08Methods of heating or cooling
    • C01B2203/0805Methods of heating the process for making hydrogen or synthesis gas
    • C01B2203/0811Methods of heating the process for making hydrogen or synthesis gas by combustion of fuel
    • C01B2203/0822Methods of heating the process for making hydrogen or synthesis gas by combustion of fuel the fuel containing hydrogen
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08Methods of heating or cooling
    • C01B2203/0805Methods of heating the process for making hydrogen or synthesis gas
    • C01B2203/0833Heating by indirect heat exchange with hot fluids, other than combustion gases, product gases or non-combustive exothermic reaction product gases
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08Methods of heating or cooling
    • C01B2203/0805Methods of heating the process for making hydrogen or synthesis gas
    • C01B2203/085Methods of heating the process for making hydrogen or synthesis gas by electric heating
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/10Process efficiency

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Fuel Cell (AREA)

Abstract

Systems and methods for thermally decomposing hydrocarbon feedstock may comprise a hydrocarbon feedstock, a non-oxidizing carrier gas, one or more heat exchangers, and a reaction chamber. The carrier gas may be used to transfer heat to the hydrocarbon feedstock. The heat exchanger(s) may be configured to heat the carrier gas. And the reaction chamber may be configured to receive hydrocarbon feedstock and heated carrier gas. Inside the reaction chamber, the hydrocarbon feedstock and the heated carrier gas may mix with one another causing the thermal decomposition reaction. The thermal decomposition reaction occurs in a substantially oxidant-free environment thereby eliminating or greatly reducing the production of carbon oxide byproducts. Hydrogen gas may be separated from a gaseous product stream that is thereafter collected from the reaction chamber. A portion of the gaseous product stream may be thermally coupled to the carrier gas and may thereafter be recycled through the system.
PCT/US2013/072240 2012-11-30 2013-11-27 Systems and methods for producing hydrogen gas WO2014085594A2 (en)

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
US13/691,543 2012-11-30
US13/691,585 US20140154170A1 (en) 2012-11-30 2012-11-30 Systems and methods for producing hydrogen gas
US13/691,552 US9434612B2 (en) 2012-11-30 2012-11-30 Systems and methods for producing hydrogen gas
US13/691,543 US9156688B2 (en) 2012-11-30 2012-11-30 Systems and methods for producing hydrogen gas
US13/691,552 2012-11-30
US13/691,585 2012-11-30

Publications (2)

Publication Number Publication Date
WO2014085594A2 WO2014085594A2 (en) 2014-06-05
WO2014085594A3 true WO2014085594A3 (en) 2014-07-17

Family

ID=50828464

Family Applications (2)

Application Number Title Priority Date Filing Date
PCT/US2013/072240 WO2014085594A2 (en) 2012-11-30 2013-11-27 Systems and methods for producing hydrogen gas
PCT/US2013/072248 WO2014085598A1 (en) 2012-11-30 2013-11-27 Systems and methods for producing hydrogen gas

Family Applications After (1)

Application Number Title Priority Date Filing Date
PCT/US2013/072248 WO2014085598A1 (en) 2012-11-30 2013-11-27 Systems and methods for producing hydrogen gas

Country Status (1)

Country Link
WO (2) WO2014085594A2 (en)

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1717354A (en) * 1927-08-22 1929-06-18 Alox Chemical Corp Production of hydrogen and carbon by thermal decomposition of hydrocarbons
EP0205598B1 (en) * 1984-12-31 1992-01-29 GONDOUIN, Oliver Michael Natural gas conversion process
US5997837A (en) * 1991-12-12 1999-12-07 Kvaerner Technology And Research Ltd. Method for decomposition of hydrocarbons
US6395197B1 (en) * 1999-12-21 2002-05-28 Bechtel Bwxt Idaho Llc Hydrogen and elemental carbon production from natural gas and other hydrocarbons
US20020160125A1 (en) * 1999-08-17 2002-10-31 Johnson Wayne L. Pulsed plasma processing method and apparatus
US20120048064A1 (en) * 2010-09-01 2012-03-01 Directa Plus S.r.I. Multi mode production complex for nano-particles of metal

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2791990A (en) * 1954-05-21 1957-05-14 Daniel A Grieb Ultrasonic mixing method and apparatus therefor
US4341598A (en) * 1979-08-14 1982-07-27 Occidental Research Corporation Fluidized coal pyrolysis apparatus
US6736535B2 (en) * 2002-06-03 2004-05-18 Richard W. Halsall Method for continuous internal agitation of fluid within hot water heaters or other fluid containing vessels
GB0711752D0 (en) * 2007-06-18 2007-07-25 Otter Controls Ltd Electrical appliances

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1717354A (en) * 1927-08-22 1929-06-18 Alox Chemical Corp Production of hydrogen and carbon by thermal decomposition of hydrocarbons
EP0205598B1 (en) * 1984-12-31 1992-01-29 GONDOUIN, Oliver Michael Natural gas conversion process
US5997837A (en) * 1991-12-12 1999-12-07 Kvaerner Technology And Research Ltd. Method for decomposition of hydrocarbons
US20020160125A1 (en) * 1999-08-17 2002-10-31 Johnson Wayne L. Pulsed plasma processing method and apparatus
US6395197B1 (en) * 1999-12-21 2002-05-28 Bechtel Bwxt Idaho Llc Hydrogen and elemental carbon production from natural gas and other hydrocarbons
US20120048064A1 (en) * 2010-09-01 2012-03-01 Directa Plus S.r.I. Multi mode production complex for nano-particles of metal

Also Published As

Publication number Publication date
WO2014085598A1 (en) 2014-06-05
WO2014085594A2 (en) 2014-06-05

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