WO2013179497A1 - Low yield ratio high-strength cold-rolled steel sheet with excellent elongation and stretch flange formability, and manufacturing method thereof - Google Patents
Low yield ratio high-strength cold-rolled steel sheet with excellent elongation and stretch flange formability, and manufacturing method thereof Download PDFInfo
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- WO2013179497A1 WO2013179497A1 PCT/JP2012/064735 JP2012064735W WO2013179497A1 WO 2013179497 A1 WO2013179497 A1 WO 2013179497A1 JP 2012064735 W JP2012064735 W JP 2012064735W WO 2013179497 A1 WO2013179497 A1 WO 2013179497A1
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- martensite
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- 239000010960 cold rolled steel Substances 0.000 title claims abstract description 20
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 10
- 229910000831 Steel Inorganic materials 0.000 claims abstract description 57
- 239000010959 steel Substances 0.000 claims abstract description 57
- 229910000734 martensite Inorganic materials 0.000 claims abstract description 48
- 229910001562 pearlite Inorganic materials 0.000 claims abstract description 36
- 229910000859 α-Fe Inorganic materials 0.000 claims abstract description 33
- 239000000126 substance Substances 0.000 claims abstract description 10
- 239000002131 composite material Substances 0.000 claims abstract description 8
- 239000012535 impurity Substances 0.000 claims abstract description 6
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 3
- 229910052748 manganese Inorganic materials 0.000 claims abstract description 3
- 229910052757 nitrogen Inorganic materials 0.000 claims abstract description 3
- 229910052698 phosphorus Inorganic materials 0.000 claims abstract description 3
- 238000001816 cooling Methods 0.000 claims description 44
- 239000000203 mixture Substances 0.000 claims description 7
- 230000000694 effects Effects 0.000 description 21
- 238000005096 rolling process Methods 0.000 description 18
- 238000000034 method Methods 0.000 description 15
- 238000000137 annealing Methods 0.000 description 14
- 229910001566 austenite Inorganic materials 0.000 description 14
- 238000002791 soaking Methods 0.000 description 13
- 238000010438 heat treatment Methods 0.000 description 12
- 238000005728 strengthening Methods 0.000 description 11
- 229910001563 bainite Inorganic materials 0.000 description 8
- 238000005098 hot rolling Methods 0.000 description 8
- 238000005097 cold rolling Methods 0.000 description 7
- 239000006104 solid solution Substances 0.000 description 7
- 239000013078 crystal Substances 0.000 description 6
- 230000000717 retained effect Effects 0.000 description 6
- 229910001567 cementite Inorganic materials 0.000 description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 5
- KSOKAHYVTMZFBJ-UHFFFAOYSA-N iron;methane Chemical compound C.[Fe].[Fe].[Fe] KSOKAHYVTMZFBJ-UHFFFAOYSA-N 0.000 description 5
- 238000005554 pickling Methods 0.000 description 5
- 229920006395 saturated elastomer Polymers 0.000 description 5
- 238000002441 X-ray diffraction Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 238000001953 recrystallisation Methods 0.000 description 3
- 229910052684 Cerium Inorganic materials 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 230000005540 biological transmission Effects 0.000 description 2
- 238000005266 casting Methods 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 229910052746 lanthanum Inorganic materials 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 238000005204 segregation Methods 0.000 description 2
- 239000002344 surface layer Substances 0.000 description 2
- 238000009864 tensile test Methods 0.000 description 2
- 229910052718 tin Inorganic materials 0.000 description 2
- 238000003466 welding Methods 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- 229910000885 Dual-phase steel Inorganic materials 0.000 description 1
- 229910001335 Galvanized steel Inorganic materials 0.000 description 1
- -1 MnS are generated Chemical class 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- 229910001035 Soft ferrite Inorganic materials 0.000 description 1
- 230000001133 acceleration Effects 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 238000009749 continuous casting Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 239000008397 galvanized steel Substances 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 150000001247 metal acetylides Chemical class 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 150000004767 nitrides Chemical class 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229910001568 polygonal ferrite Inorganic materials 0.000 description 1
- 238000004080 punching Methods 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 229910052761 rare earth metal Inorganic materials 0.000 description 1
- 238000009628 steelmaking Methods 0.000 description 1
- 238000005482 strain hardening Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/0247—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/46—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for sheet metals
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/001—Ferrous alloys, e.g. steel alloys containing N
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/06—Ferrous alloys, e.g. steel alloys containing aluminium
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D2211/00—Microstructure comprising significant phases
- C21D2211/005—Ferrite
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D2211/00—Microstructure comprising significant phases
- C21D2211/008—Martensite
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D2211/00—Microstructure comprising significant phases
- C21D2211/009—Pearlite
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
Definitions
- the present invention relates to a high-strength cold-rolled steel sheet having a low yield ratio and excellent elongation and stretch flangeability, which is suitable as a member for automobile undercarriage parts and structural parts used by being pressed.
- the steel sheet having a TS of 590 MPa or more is required to have excellent elongation and stretch flangeability (hole expanding property) from the viewpoint of formability. Furthermore, since it is assembled by arc welding, spot welding or the like after press working and modularized, high dimensional accuracy is required at the time of assembly. For this reason, it is necessary to make it difficult for a springback or the like to occur after processing, and a low yield ratio is required before processing.
- Patent Document 1 discloses a high-strength steel sheet for automobiles that achieves both collision safety and formability by controlling the space factor and the average crystal grain size of the entire structure of ferrite and martensite.
- Patent Document 2 discloses a high-strength steel sheet having improved elongation and stretch flangeability by controlling the space factor of the fine ferrite having an average grain size of 3 ⁇ m or less and the martensite having an average grain size of 6 ⁇ m or less with respect to the entire structure. It is disclosed.
- Patent Document 3 discloses a DP steel sheet in which fine inclusions are dispersed in the steel sheet by containing Ce or La in the steel sheet component to improve stretch flangeability.
- Patent Document 4 a composite structure composed of ferrite, residual austenite, the balance being bainite and martensite, the aspect ratio and average particle size of martensite and residual austenite are defined, and martensite and residual per unit area By defining the number of austenite, a composite structure cold-rolled steel sheet having excellent elongation and stretch flangeability is disclosed.
- Non-Patent Document 1 will be described in an example.
- Patent Document 1 defines the average crystal grain size of ferrite and martensite, it does not ensure sufficient hole expansion property for press molding.
- Patent Document 2 since the volume fraction of martensite is remarkably large, the elongation is insufficient.
- Patent Document 3 is low in production cost because Ce and La are added, and the manufacturing cost is high, and the material variation is large in order to control the size of inclusions.
- Patent Document 4 a steel sheet containing bainite or retained austenite requires a high cooling rate using special equipment to obtain its structure, so that the manufacturing cost is high and the material variation is large. Furthermore, as a characteristic, a high strength steel plate having a steel structure having retained austenite and bainite has a higher YR than DP steel, so it is difficult to stably set the YR to 70% or less.
- an object of the present invention is to provide a high-strength cold-rolled steel sheet that has solved the above-mentioned problems of the prior art, has excellent elongation and stretch flangeability, and has a low yield ratio and a method for manufacturing the same.
- the inventors have added a suitable amount of Si and controlled the volume fraction of ferrite, martensite and pearlite, and are excellent in elongation and stretch flangeability that ensure high strength at low YR. It was found that a cold-rolled steel sheet can be obtained.
- Si is added in an amount of 0.6 to 1.2%
- the main phase ferrite is 80% or more in terms of volume fraction
- martensite is 3 to 15%
- pearlite is 0.5 to 10%.
- the present invention provides the following (1) and (2).
- the chemical composition of the steel sheet is mass%, C: 0.05 to 0.13%, Si: 0.6 to 1.2%, Mn: 1.6 to 2.4%, P: 0.00. 10% or less, S: 0.0050% or less, Al: 0.01 to 0.10%, N: less than 0.0050%, the balance is made of Fe and inevitable impurities, and the microstructure of the steel sheet is It has a composite structure containing 80% or more of ferrite, 3 to 15% of martensite, and 0.5 to 10% of pearlite in volume fraction, yield ratio is 70% or less, and tensile strength is 590 MPa or more. Low yield ratio high strength cold-rolled steel sheet with excellent elongation and stretch flangeability.
- the volume fraction includes ferrite of 80% or more, martensite of 3 to 15%, and pearlite of 0.5 to 10%.
- High-strength cold-rolled steel sheet with a low yield ratio that has a composite structure has a tensile strength of 590 MPa or more, a yield ratio of 70% or less, an elongation of 29.0% or more, and an elongation and stretch flangeability of 65% or more. Can be obtained.
- C 0.05 to 0.13% C is an element effective for increasing the strength of a steel sheet, and contributes to increasing the strength by forming a second phase of pearlite and martensite.
- 0.05% or more must be added.
- it is 0.08% or more.
- the upper limit is made 0.13%.
- Si 0.6-1.2%
- Si is an element that contributes to high strength, and since it has a high work-hardening ability, it has a relatively small decrease in elongation with respect to an increase in strength, and is an element that also contributes to an improvement in strength-elongation balance. Furthermore, the solid solution strengthening of the ferrite phase reduces the hardness difference from the hard second phase, thereby contributing to the improvement of stretch flangeability.
- the addition of an appropriate amount of Si can suppress the generation of voids from the interface between the ferrite phase and the pearlite phase, but in order to obtain the effect, it is necessary to contain 0.6% or more.
- the upper limit is not particularly defined from the viewpoint of elongation and stretch flangeability, but if it exceeds 1.2%, the chemical conversion treatment property is lowered, so the content is made 1.2% or less. Preferably it is 1.0% or less.
- Mn 1.6 to 2.4% Mn is an element that contributes to strengthening by forming solid solution strengthening and martensite. To obtain this effect, it is necessary to contain 1.6% or more. On the other hand, when the content is excessive, the moldability is significantly lowered. Therefore, the content is set to 2.4% or less. Preferably it is 2.2% or less.
- P 0.10% or less P contributes to high strength by solid solution strengthening, but when excessively added, segregation to the grain boundary becomes remarkable and the grain boundary becomes brittle, and weldability. Therefore, the content is made 0.10% or less. Preferably it is 0.05% or less.
- S 0.0050% or less
- the content of S is large, a large amount of sulfides such as MnS are generated, and the local elongation represented by stretch flangeability is reduced, so the upper limit of the content is 0.0050%. To do. Preferably, it is 0.0030% or less. Although a minimum is not specifically limited, Since ultra-low S raises steelmaking cost, it is preferable to contain 0.0005% or more.
- Al 0.01 to 0.10%
- Al is an element necessary for deoxidation. In order to obtain this effect, it is necessary to contain 0.01% or more, but even if it exceeds 0.10%, the effect is saturated.
- the content is 0.10% or less. Preferably it is 0.05% or less.
- N Less than 0.0050% Since N forms coarse nitrides and deteriorates stretch flangeability, it is necessary to suppress the content. When N is 0.0050% or more, this tendency becomes remarkable, so the N content is less than 0.0050%.
- V 0.10% or less
- V can contribute to an increase in strength by forming fine carbonitrides. In order to exhibit such an effect, it is preferable to contain the addition amount of V 0.01% or more. On the other hand, even if added over 0.10%, the effect of increasing the strength is small, and on the contrary, the cost of the alloy is increased, so the content is preferably 0.10% or less.
- Ti 0.10% or less Ti, like V, can contribute to an increase in strength by forming fine carbonitride, and can be added as necessary. In order to exert such an effect, the Ti content is preferably 0.005% or more. On the other hand, when a large amount of Ti is added, YR increases remarkably, so the content is preferably 0.10% or less.
- Nb 0.10% or less
- Nb can contribute to an increase in strength by forming fine carbonitrides, and can be added as necessary.
- the Nb content is preferably 0.005% or more.
- the content is preferably 0.10% or less.
- Cr 0.50% or less Cr is an element that contributes to increasing the strength by improving the hardenability and generating the second phase, and can be added as necessary. In order to exhibit this effect, it is preferable to make it contain 0.10% or more. On the other hand, since the effect is saturated even if the content exceeds 0.50%, the content is preferably 0.50% or less.
- Mo 0.50% or less Mo is an element that improves hardenability and contributes to high strength by generating the second phase, and further contributes to high strength by generating some carbides. Can be added accordingly. In order to exhibit these effects, it is preferable to make it contain 0.05% or more. Since the effect is saturated even if the content exceeds 0.50%, the content is preferably 0.50% or less.
- Cu 0.50% or less
- Cu is an element that contributes to high strength by solid solution strengthening, improves hardenability, and contributes to high strength by generating a second phase. Can be added. In order to exhibit these effects, it is preferable to make it contain 0.05% or more. On the other hand, even if the content exceeds 0.50%, the effect is saturated and surface defects due to Cu are likely to occur. Therefore, the content is preferably 0.50% or less.
- Ni 0.50% or less
- Ni is an element that contributes to strengthening by solid solution strengthening, improves hardenability, and generates a second phase to contribute to strengthening. It can be added as necessary. In order to exhibit these effects, it is preferable to make it contain 0.05% or more. Moreover, since it has the effect of suppressing the surface defect resulting from Cu when it adds simultaneously with Cu, it is effective at the time of Cu addition. On the other hand, since the effect is saturated even if the content exceeds 0.50%, the content is preferably 0.50% or less.
- Inevitable impurities include, for example, Sb, Sn, Zn, Co, etc.
- the allowable ranges of these contents are Sb: 0.01% or less, Sn: 0.1% or less, Zn: 0. 01% or less, Co: 0.1% or less.
- this invention even if it contains Ta, Mg, Ca, Zr, and REM within the range of a normal steel composition, the effect is not impaired.
- the microstructure of the high-strength cold-rolled steel sheet has a main phase of ferrite with a volume fraction of 80% or more, martensite with a volume fraction of 3-15%, and pearlite with a volume fraction of 0.5-10%.
- the volume fraction is the volume fraction with respect to the entire steel sheet.
- the volume fraction of the ferrite phase is 80% or more. Preferably, it is 83% or more.
- the volume fraction of martensite is less than 3%, the effect of increasing the strength is small, sufficient elongation cannot be obtained, and YR exceeds 70%. Therefore, the volume fraction of martensite is 3% or more.
- the volume fraction of martensite exceeds 15%, the stretch flangeability is remarkably lowered. Therefore, the volume fraction of martensite is made 15% or less. Preferably it is 12% or less.
- the pearlite volume fraction When the pearlite volume fraction is less than 0.5%, the effect of increasing the strength is small. Therefore, in order to achieve a good balance between strength and formability, the pearlite volume fraction needs to be 0.5% or more. On the other hand, when the pearlite volume fraction exceeds 10%, YR becomes remarkably high, so the pearlite volume fraction is 10% or less. Preferably it is 8% or less.
- the remaining structure other than ferrite, martensite and pearlite may be a structure containing one or more of bainite, residual ⁇ , spherical cementite, etc., but from the viewpoint of stretch flangeability, other than ferrite, martensite and pearlite.
- the volume fraction of the remaining tissue is preferably 5% or less.
- the average crystal grain size of martensite and pearlite is not particularly limited, but if the average crystal grain size is fine, the connection of the generated voids is suppressed and the stretch flangeability is improved. Therefore, the average crystal grain size of martensite is preferably 10 ⁇ m or less, and the average crystal grain size of pearlite is preferably 5 ⁇ m or less.
- the steel slab having the above component composition (chemical component) is hot-rolled and pickled, then cold-rolled, and then annealed. This will be described in detail below.
- the steel slab is preferably manufactured by a continuous casting method in order to prevent macro segregation of components, but can also be manufactured by an ingot forming method or a thin slab casting method.
- the steel slab is subjected to rough rolling and finish rolling to obtain hot rolled sheets. It is preferable to heat the slab before rolling.
- the slab heating temperature is preferably 1100 to 1300 ° C.
- the slab once cooled to room temperature may be reheated in a heating furnace, or the steel slab may be charged into the heating furnace as it is without being cooled to room temperature and reheated.
- energy saving processes such as direct feed rolling and direct rolling which carry out hot rolling immediately after heat-retaining steel slab, or hot-rolling as it is after casting, without performing slab heating.
- the finish rolling end temperature is preferably 830 ° C. or higher.
- the finish rolling finish temperature is preferably 830 to 950 ° C.
- the subsequent cooling method is not particularly limited.
- the coiling temperature is not limited, but when the coiling temperature exceeds 700 ° C., coarse pearlite is remarkably formed, which affects the formability of the steel sheet after annealing. preferable. More preferably, it is 650 degrees C or less.
- the lower limit of the coiling temperature is not particularly limited, but if the coiling temperature becomes too low, hard bainite and martensite are excessively generated and the cold rolling load increases, so 400 ° C or higher is preferable.
- the pickling process After the hot rolling step, it is preferable to carry out an acidic step and remove the scale of the hot rolled sheet surface layer.
- the pickling step is not particularly limited, and may be performed according to a conventional method.
- Cold rolling process The hot-rolled sheet after pickling is subjected to a cold rolling process for rolling into a cold-rolled sheet having a predetermined thickness.
- a cold rolling process is not specifically limited, What is necessary is just to implement by a conventional method.
- the annealing process is carried out in order to advance recrystallization and to form a second phase structure of martensite and pearlite for high strength.
- the annealing step is performed by heating to a temperature range of Ac 1 to Ac 3 points (also referred to as a soaking temperature or holding temperature) and then holding the temperature from the soaking temperature to a temperature of 500 to 550 ° C. at 1 ° C./s. Cool at an average cooling rate of ⁇ 25 ° C./s, and then cool at an average cooling rate of 5 ° C./s or less.
- Soaking temperature (holding temperature): Ac 1 to Ac 3 points Since austenite is not generated when the soaking temperature is less than Ac 1 point, then martensite cannot be obtained, and if it exceeds Ac 3 points, coarse austenite is obtained. Therefore, the predetermined martensite and pearlite volume fraction cannot be obtained thereafter. Therefore, the soaking temperature is in the range of Ac 1 to Ac 3 points. Ac 3 points-100 ° C. to Ac 3 points are preferred. If the heating rate up to the soaking temperature is too high, recrystallization will not proceed easily. If the heating rate is too low, the ferrite grains will become coarse and the strength will decrease, so the average heating rate up to the soaking temperature will be 3-30 ° C. / S is preferable. Further, the soaking time is preferably set to 30 s to 300 s (seconds) in order to sufficiently advance the recrystallization and partially austenite transformation.
- Cooling from a soaking temperature to a temperature of 500 to 550 ° C at an average cooling rate of 1 ° C / s to 25 ° C / s (primary cooling)
- the microstructure of the steel sheet finally obtained after the annealing process is controlled so that the volume fraction of ferrite is 80% or more, the volume fraction of martensite is 3 to 15%, and the volume fraction of pearlite is 0.5 to 10%. Therefore, primary cooling is performed by cooling from the soaking temperature to a temperature of 500 to 550 ° C. as a primary cooling temperature at an average cooling rate of 1 ° C./s to 25 ° C./s.
- the primary cooling temperature exceeds 550 ° C, martensite is not sufficiently formed, and when it is less than 500 ° C, pearlite is not sufficiently formed.
- both martensite and pearlite can be formed and the volume fraction thereof can be adjusted.
- the average cooling rate to the temperature range of 500 to 550 ° C is less than 1 ° C / s, martensite does not form 3% or more in volume fraction, and when the average cooling rate exceeds 25 ° C / s, pearlite has volume fraction. And not 0.5% or more. Therefore, the average cooling rate from the soaking temperature to the temperature range of 500 to 550 ° C. needs to be 1 ° C./s to 25 ° C./s.
- a preferable average cooling rate is 15 ° C./s or less.
- Cool from the primary cooling temperature at an average cooling rate of 5 ° C / s or less (secondary cooling) After cooling to the primary cooling temperature (500 to 550 ° C.), secondary cooling is performed at an average cooling rate of 5 ° C./s or less.
- the average cooling rate of the secondary cooling exceeds 5 ° C./s, the volume fraction of martensite increases and the predetermined martensite and pearlite volume fraction cannot be obtained, so the average cooling rate from the primary cooling temperature Is 5 ° C./s or less.
- it is 3 degrees C / s or less.
- temper rolling may be performed after annealing.
- a preferable range of the elongation rate is 0.3% to 2.0%.
- hot dip galvanization may be performed after the primary cooling to obtain a hot dip galvanized steel sheet. It may be a steel plate.
- the present invention is not originally limited by the following examples, and can be implemented with appropriate modifications within a range that can be adapted to the gist of the present invention. Included in the scope.
- the cooling rate 1 in Table 2 indicates the average cooling rate from the soaking temperature during annealing to the primary cooling temperature, and the cooling rate 2 indicates the average cooling rate from the primary cooling temperature to room temperature.
- the average heating rate up to the soaking temperature was 10 ° C./s.
- a JIS No. 5 tensile test piece was sampled so that the direction perpendicular to the rolling direction was the longitudinal direction (tensile direction), and was subjected to a tensile test (JIS Z2241 (1998)) to yield strength (YS), tensile strength (TS), total elongation (EL), and yield ratio (YR) were measured.
- Yield strength (YS) yield strength
- TS tensile strength
- EL total elongation
- YR yield ratio
- Stretch flangeability is based on the Japan Iron and Steel Federation standard (JFS T1001 (1996)), after punching a hole with a diameter of 10mm ⁇ at a clearance of 12.5%, and setting the burr on the die side after setting
- JFS T1001 Japan Iron and Steel Federation standard
- the hole expansion rate ( ⁇ ) was measured by conducting a hole expansion test with a 60 ° conical punch. ⁇ (%) was 65% or more to make a steel sheet having good stretch flangeability.
- volume fractions of ferrite, martensite and pearlite were determined by the following method.
- the microstructure of the steel sheet corrodes the cross section in the rolling direction of the steel sheet (depth position at 1/4 of the plate thickness) using 3% Nital reagent (3% nitric acid + ethanol), and is observed with an optical microscope at 500 to 1000 times.
- the volume fraction of ferrite, the volume fraction of martensite, and the volume fraction of pearlite were quantified using tissue photographs observed and photographed with an electron microscope (scanning type and transmission type) of 1000 to 100,000 times.
- ferrite is a region with a slightly black contrast, and martensite has a white contrast.
- Pearlite is a layered structure in which plate-like ferrite and cementite are alternately arranged.
- bainite is a plate-like bainite having a higher dislocation density than polygonal ferrite in the observation using the above-described optical microscope or electron microscope (scanning type and transmission type). It is a structure containing tick ferrite and cementite, and spherical cementite is cementite having a spheroidized shape.
- the surface polished to 1/4 thickness from the surface layer was used, and the K ⁇ ray of Mo was used as the radiation source at an acceleration voltage of 50 keV by an X-ray diffraction method (apparatus: RINT2200 manufactured by Rigaku).
- Measure the integrated intensity of the X-ray diffraction lines of the ⁇ 200 ⁇ , ⁇ 211 ⁇ , ⁇ 220 ⁇ , and ⁇ 200 ⁇ , ⁇ 220 ⁇ , and ⁇ 311 ⁇ planes of austenite. was used to determine the volume fraction of retained austenite from the calculation formula described in Non-Patent Document 1, and the presence or absence of retained austenite was determined.
- Table 2 shows the measurement results of tensile properties, stretch flangeability, and steel sheet structure.
- all of the examples of the present invention have a steel sheet structure in which the volume fraction of ferrite is 80% or more, the volume fraction of martensite is 3 to 15%, and the volume fraction of pearlite is 0.5 to 10%.
- good formability with a tensile strength of 590 MPa or more and a yield ratio of 70% or less, and an elongation of 29.0% or more and a hole expansion ratio of 65% or more can be obtained.
- the steel sheet structure does not satisfy the scope of the present invention, and as a result, at least one characteristic of tensile strength, yield ratio, elongation, and hole expansion ratio is inferior.
- the volume fraction has a composite structure including ferrite of 80% or more, martensite of 3 to 15%, and pearlite of 0.5 to 10%, a tensile strength of 590 MPa or more, and a yield ratio of 70% or less. Further, a high strength cold-rolled steel sheet having a low yield ratio and excellent elongation and stretch flangeability having an elongation of 29.0% or more and a hole expansion ratio of 65% or more can be obtained.
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Abstract
Description
Cは鋼板の高強度化に有効な元素であり、パーライト及びマルテンサイトの第2相形成により高強度化に寄与する。この効果を得るためには、0.05%以上の添加が必要である。好ましくは0.08%以上である。一方、過剰に添加するとスポット溶接性が低下することから、上限を0.13%とする。 C: 0.05 to 0.13%
C is an element effective for increasing the strength of a steel sheet, and contributes to increasing the strength by forming a second phase of pearlite and martensite. In order to obtain this effect, 0.05% or more must be added. Preferably it is 0.08% or more. On the other hand, if it is added excessively, spot weldability is lowered, so the upper limit is made 0.13%.
Siは高強度化に寄与する元素であり、高い加工硬化能をもつことから強度上昇に対して伸びの低下が比較的少なく、強度−伸びバランスの向上にも寄与する元素である。さらにフェライト相の固溶強化により、硬質な第2相との硬度差を小さくするため、伸びフランジ性の向上にも寄与する。Siを適量添加することでフェライト相とパーライト相との界面からのボイドの発生を抑制することができるが、その効果を得るためには、0.6%以上含有することが必要である。伸びと伸びフランジ性の観点からは上限は特に規定されないが、1.2%超添加すると化成処理性が低下するため、その含有量は1.2%以下とする。好ましくは1.0%以下である。 Si: 0.6-1.2%
Si is an element that contributes to high strength, and since it has a high work-hardening ability, it has a relatively small decrease in elongation with respect to an increase in strength, and is an element that also contributes to an improvement in strength-elongation balance. Furthermore, the solid solution strengthening of the ferrite phase reduces the hardness difference from the hard second phase, thereby contributing to the improvement of stretch flangeability. The addition of an appropriate amount of Si can suppress the generation of voids from the interface between the ferrite phase and the pearlite phase, but in order to obtain the effect, it is necessary to contain 0.6% or more. The upper limit is not particularly defined from the viewpoint of elongation and stretch flangeability, but if it exceeds 1.2%, the chemical conversion treatment property is lowered, so the content is made 1.2% or less. Preferably it is 1.0% or less.
Mnは固溶強化およびマルテンサイトを生成することで高強度化に寄与する元素であり、この効果を得るためには1.6%以上含有することが必要である。一方、過剰に含有した場合、成形性の低下が著しくなることから、その含有量を2.4%以下とする。好ましくは2.2%以下である。 Mn: 1.6 to 2.4%
Mn is an element that contributes to strengthening by forming solid solution strengthening and martensite. To obtain this effect, it is necessary to contain 1.6% or more. On the other hand, when the content is excessive, the moldability is significantly lowered. Therefore, the content is set to 2.4% or less. Preferably it is 2.2% or less.
Pは固溶強化により高強度化に寄与するが、過剰に添加された場合には、粒界への偏析が著しくなって粒界を脆化させることや、溶接性が低下することから、その含有量を0.10%以下とする。好ましくは0.05%以下である。 P: 0.10% or less P contributes to high strength by solid solution strengthening, but when excessively added, segregation to the grain boundary becomes remarkable and the grain boundary becomes brittle, and weldability. Therefore, the content is made 0.10% or less. Preferably it is 0.05% or less.
Sの含有量が多い場合には、MnSなどの硫化物が多く生成し、伸びフランジ性に代表される局部伸びが低下するため含有量の上限を0.0050%とする。好ましくは、0.0030%以下である。下限は特に限定しないが、極低S化は製鋼コストが上昇するため、0.0005%以上含有することが好ましい。 S: 0.0050% or less When the content of S is large, a large amount of sulfides such as MnS are generated, and the local elongation represented by stretch flangeability is reduced, so the upper limit of the content is 0.0050%. To do. Preferably, it is 0.0030% or less. Although a minimum is not specifically limited, Since ultra-low S raises steelmaking cost, it is preferable to contain 0.0005% or more.
Alは脱酸に必要な元素であり、この効果を得るためには0.01%以上含有することが必要であるが、0.10%を超えて含有しても効果が飽和するため、その含有量は0.10%以下とする。好ましくは0.05%以下である。 Al: 0.01 to 0.10%
Al is an element necessary for deoxidation. In order to obtain this effect, it is necessary to contain 0.01% or more, but even if it exceeds 0.10%, the effect is saturated. The content is 0.10% or less. Preferably it is 0.05% or less.
Nは、粗大な窒化物を形成し、伸びフランジ性を劣化させることから、含有量を抑える必要がある。Nが0.0050%以上では、この傾向が顕著となることから、Nの含有量を0.0050%未満とする。 N: Less than 0.0050% Since N forms coarse nitrides and deteriorates stretch flangeability, it is necessary to suppress the content. When N is 0.0050% or more, this tendency becomes remarkable, so the N content is less than 0.0050%.
Vは微細な炭窒化物を形成することで、強度上昇に寄与することができる。このような効果を発揮させるには、Vの添加量を0.01%以上含有させることが好ましい。一方、0.10%を超えて添加しても強度上昇効果は小さく、却って合金コストの増加を招くため、その含有量は0.10%以下が好ましい。 V: 0.10% or less V can contribute to an increase in strength by forming fine carbonitrides. In order to exhibit such an effect, it is preferable to contain the addition amount of V 0.01% or more. On the other hand, even if added over 0.10%, the effect of increasing the strength is small, and on the contrary, the cost of the alloy is increased, so the content is preferably 0.10% or less.
TiもVと同様に、微細な炭窒化物を形成することで、強度上昇に寄与することができるため、必要に応じて添加することができる。このような効果を発揮させるためには、Tiの含有量を0.005%以上とすることが好ましい。一方、多量にTiを添加すると、YRが著しく上昇するため、その含有量は0.10%以下が好ましい。 Ti: 0.10% or less Ti, like V, can contribute to an increase in strength by forming fine carbonitride, and can be added as necessary. In order to exert such an effect, the Ti content is preferably 0.005% or more. On the other hand, when a large amount of Ti is added, YR increases remarkably, so the content is preferably 0.10% or less.
NbもVと同様に、微細な炭窒化物を形成することで、強度上昇に寄与することができるため、必要に応じて添加することができる。このような効果を発揮させるためには、Nbの含有量を0.005%以上とすることが好ましい。一方、多量にNbを添加すると、YRが著しく上昇するため、その含有量は0.10%以下が好ましい。 Nb: 0.10% or less Nb, like V, can contribute to an increase in strength by forming fine carbonitrides, and can be added as necessary. In order to exhibit such an effect, the Nb content is preferably 0.005% or more. On the other hand, when a large amount of Nb is added, YR increases remarkably, so the content is preferably 0.10% or less.
Crは焼入れ性を向上させ、第2相を生成することで高強度化に寄与する元素であり、必要に応じて添加することができる。この効果を発揮させるためには、0.10%以上含有させることが好ましい。一方、0.50%を超えて含有させても効果が飽和するため、その含有量は0.50%以下が好ましい。 Cr: 0.50% or less Cr is an element that contributes to increasing the strength by improving the hardenability and generating the second phase, and can be added as necessary. In order to exhibit this effect, it is preferable to make it contain 0.10% or more. On the other hand, since the effect is saturated even if the content exceeds 0.50%, the content is preferably 0.50% or less.
Moは焼入れ性を向上させ、第2相を生成することで高強度化に寄与し、さらに一部炭化物を生成して高強度化に寄与する元素であり、必要に応じて添加することができる。これらの効果を発揮させるためには、0.05%以上含有させることが好ましい。0.50%を超えて含有させても効果が飽和するため、その含有量は0.50%以下が好ましい。 Mo: 0.50% or less Mo is an element that improves hardenability and contributes to high strength by generating the second phase, and further contributes to high strength by generating some carbides. Can be added accordingly. In order to exhibit these effects, it is preferable to make it contain 0.05% or more. Since the effect is saturated even if the content exceeds 0.50%, the content is preferably 0.50% or less.
Cuは固溶強化により高強度化に寄与して、また焼入れ性を向上させ、第2相を生成することで高強度化に寄与する元素であり、必要に応じて添加することができる。これらの効果を発揮するためには0.05%以上含有させることが好ましい。一方、0.50%を超えて含有させても効果が飽和し、またCuに起因する表面欠陥が発生しやすくなるため、その含有量は0.50%以下が好ましい。 Cu: 0.50% or less Cu is an element that contributes to high strength by solid solution strengthening, improves hardenability, and contributes to high strength by generating a second phase. Can be added. In order to exhibit these effects, it is preferable to make it contain 0.05% or more. On the other hand, even if the content exceeds 0.50%, the effect is saturated and surface defects due to Cu are likely to occur. Therefore, the content is preferably 0.50% or less.
NiもCuと同様、固溶強化により高強度化に寄与して、また焼入れ性を向上させ、第2相を生成することで高強度化に寄与する元素であり、必要に応じて添加することができる。これらの効果を発揮させるためには0.05%以上含有させることが好ましい。また、Cuと同時に添加すると、Cu起因の表面欠陥を抑制する効果があるため、Cu添加時に有効である。一方、0.50%を超えて含有させても効果が飽和するため、その含有量は0.50%以下が好ましい。 Ni: 0.50% or less Ni, like Cu, is an element that contributes to strengthening by solid solution strengthening, improves hardenability, and generates a second phase to contribute to strengthening. It can be added as necessary. In order to exhibit these effects, it is preferable to make it contain 0.05% or more. Moreover, since it has the effect of suppressing the surface defect resulting from Cu when it adds simultaneously with Cu, it is effective at the time of Cu addition. On the other hand, since the effect is saturated even if the content exceeds 0.50%, the content is preferably 0.50% or less.
鋼スラブに、粗圧延、仕上げ圧延を施し、熱延板とする。圧延前にスラブを加熱することが好ましい。スラブ加熱温度が1100℃未満になると圧延負荷が増大し、生産性が低下し、1300℃を超えると加熱コストが増大するため、スラブ加熱温度は1100~1300℃とすることが好ましい。一旦室温まで冷却したスラブを加熱炉で再加熱してもよいし、鋼スラブを室温まで冷却しないで、温片のままで加熱炉に装入して再加熱してもよい。また、スラブ加熱を行うことなく、鋼スラブを保熱した後に直ちに熱間圧延する、あるいは鋳造後そのまま熱間圧延する直送圧延・直接圧延などの省エネルギープロセスを適用してもよい。 [Hot rolling process]
The steel slab is subjected to rough rolling and finish rolling to obtain hot rolled sheets. It is preferable to heat the slab before rolling. When the slab heating temperature is less than 1100 ° C., the rolling load is increased, the productivity is lowered, and when it exceeds 1300 ° C., the heating cost is increased. Therefore, the slab heating temperature is preferably 1100 to 1300 ° C. The slab once cooled to room temperature may be reheated in a heating furnace, or the steel slab may be charged into the heating furnace as it is without being cooled to room temperature and reheated. Moreover, you may apply energy saving processes, such as direct feed rolling and direct rolling which carry out hot rolling immediately after heat-retaining steel slab, or hot-rolling as it is after casting, without performing slab heating.
熱間圧延工程後、酸性工程を実施し、熱延板表層のスケールを除去するのが好ましい。酸洗工程は特に限定されず、常法に従って実施すればよい。 [Pickling process]
After the hot rolling step, it is preferable to carry out an acidic step and remove the scale of the hot rolled sheet surface layer. The pickling step is not particularly limited, and may be performed according to a conventional method.
酸洗後の熱延板に対し、所定の板厚の冷延板に圧延する冷間圧延工程を行う。冷間圧延工程は特に限定されず常法で実施すればよい。 [Cold rolling process]
The hot-rolled sheet after pickling is subjected to a cold rolling process for rolling into a cold-rolled sheet having a predetermined thickness. A cold rolling process is not specifically limited, What is necessary is just to implement by a conventional method.
焼鈍工程は、再結晶を進行させるとともに、高強度化のためマルテンサイト及びパーライトの第2相組織を形成するために実施する。そのために、焼鈍工程は、Ac1~Ac3点の温度域(均熱温度または保持温度とも言う)に加熱して保持した後、該均熱温度から500~550℃の温度まで1℃/s~25℃/sの平均冷却速度で冷却し、その後は5℃/s以下の平均冷却速度で冷却する。 [Annealing process]
The annealing process is carried out in order to advance recrystallization and to form a second phase structure of martensite and pearlite for high strength. For this purpose, the annealing step is performed by heating to a temperature range of Ac 1 to Ac 3 points (also referred to as a soaking temperature or holding temperature) and then holding the temperature from the soaking temperature to a temperature of 500 to 550 ° C. at 1 ° C./s. Cool at an average cooling rate of ˜25 ° C./s, and then cool at an average cooling rate of 5 ° C./s or less.
均熱温度がAc1点未満ではオーステナイトが生成しないため、その後、マルテンサイトを得る事ができず、Ac3点超では粗大なオーステナイトとなるため、その後、所定のマルテンサイトおよびパーライトの体積分率を得ることができない。そのため、均熱温度はAc1~Ac3点の範囲とする。好ましくはAc3点−100℃~Ac3点である。均熱温度までの加熱速度が大きすぎると再結晶が進行しにくくなり、加熱速度が小さすぎるとフェライト粒が粗大になり強度が低下するため、均熱温度までの平均加熱速度は3~30℃/sの範囲とするのが好ましい。また、再結晶の進行および一部オーステナイト変態を十分にするため、均熱時間は30s~300s(秒)とすることが好ましい。 Soaking temperature (holding temperature): Ac 1 to Ac 3 points Since austenite is not generated when the soaking temperature is less than Ac 1 point, then martensite cannot be obtained, and if it exceeds Ac 3 points, coarse austenite is obtained. Therefore, the predetermined martensite and pearlite volume fraction cannot be obtained thereafter. Therefore, the soaking temperature is in the range of Ac 1 to Ac 3 points. Ac 3 points-100 ° C. to Ac 3 points are preferred. If the heating rate up to the soaking temperature is too high, recrystallization will not proceed easily. If the heating rate is too low, the ferrite grains will become coarse and the strength will decrease, so the average heating rate up to the soaking temperature will be 3-30 ° C. / S is preferable. Further, the soaking time is preferably set to 30 s to 300 s (seconds) in order to sufficiently advance the recrystallization and partially austenite transformation.
焼鈍工程後に最終的に得られる鋼板のミクロ組織を、フェライトの体積分率を80%以上、マルテンサイトの体積分率を3~15%、パーライトの体積分率を0.5~10%に制御するため、上記均熱温度から、1次冷却温度として500~550℃の温度までを1℃/s~25℃/sの平均冷却速度で冷却する1次冷却を行う。 Cooling from a soaking temperature to a temperature of 500 to 550 ° C at an average cooling rate of 1 ° C / s to 25 ° C / s (primary cooling)
The microstructure of the steel sheet finally obtained after the annealing process is controlled so that the volume fraction of ferrite is 80% or more, the volume fraction of martensite is 3 to 15%, and the volume fraction of pearlite is 0.5 to 10%. Therefore, primary cooling is performed by cooling from the soaking temperature to a temperature of 500 to 550 ° C. as a primary cooling temperature at an average cooling rate of 1 ° C./s to 25 ° C./s.
1次冷却温度(500~550℃)まで冷却した後は5℃/s以下の平均冷却速度で冷却する2次冷却を行う。2次冷却の平均冷却速度が5℃/sを超えるとマルテンサイトの体積分率が増加し、所定のマルテンサイトとパーライトの体積分率を得られなくなるため、1次冷却温度からの平均冷却速度は5℃/s以下とする。好ましくは3℃/s以下である。 Cool from the primary cooling temperature at an average cooling rate of 5 ° C / s or less (secondary cooling)
After cooling to the primary cooling temperature (500 to 550 ° C.), secondary cooling is performed at an average cooling rate of 5 ° C./s or less. When the average cooling rate of the secondary cooling exceeds 5 ° C./s, the volume fraction of martensite increases and the predetermined martensite and pearlite volume fraction cannot be obtained, so the average cooling rate from the primary cooling temperature Is 5 ° C./s or less. Preferably it is 3 degrees C / s or less.
Claims (2)
- 鋼板の化学成分が、質量%で、C:0.05~0.13%、Si:0.6~1.2%、Mn:1.6~2.4%、P:0.10%以下、S:0.0050%以下、Al:0.01~0.10%、N:0.0050%未満を含有するとともに、残部がFeおよび不可避的不純物からなり、鋼板のミクロ組織は、体積分率でフェライトを80%以上、マルテンサイトを3~15%、パーライトを0.5~10%含む複合組織を有し、降伏比が70%以下で引張強さが590MPa以上であることを特徴とする伸びと伸びフランジ性に優れた低降伏比高強度冷延鋼板。 The chemical composition of the steel sheet is mass%, C: 0.05 to 0.13%, Si: 0.6 to 1.2%, Mn: 1.6 to 2.4%, P: 0.10% or less , S: 0.0050% or less, Al: 0.01 to 0.10%, N: less than 0.0050%, the balance is made of Fe and inevitable impurities, and the microstructure of the steel sheet is volume fraction Characterized by having a composite structure containing 80% or more of ferrite, 3 to 15% of martensite, and 0.5 to 10% of pearlite, a yield ratio of 70% or less, and a tensile strength of 590 MPa or more. Low yield ratio high strength cold-rolled steel sheet with excellent elongation and stretch flangeability.
- 請求項1に記載の化学成分を有する鋼スラブに、熱間圧延、冷間圧延を施した後に、Ac1~Ac3点の温度域に加熱して保持した後、前記保持温度から500~550℃の温度まで1℃/s~25℃/sの平均冷却速度で冷却し、その後は5℃/s以下の平均冷却速度で冷却することを特徴とする伸びと伸びフランジ性に優れた低降伏比高強度冷延鋼板の製造方法。 The steel slab having the chemical composition according to claim 1 is hot-rolled and cold-rolled, and then heated and held in a temperature range of Ac 1 to Ac 3 points, and then from the holding temperature to 500 to 550 Cooling at an average cooling rate of 1 ° C./s to 25 ° C./s to a temperature of 1 ° C., followed by cooling at an average cooling rate of 5 ° C./s or less, and low yield with excellent elongation and stretch flangeability A method for producing a high strength cold-rolled steel sheet.
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JP5234893B2 (en) | 2007-05-31 | 2013-07-10 | 株式会社神戸製鋼所 | High-strength steel sheet excellent in elongation and stretch flangeability and method for producing the same |
KR20120055743A (en) * | 2007-01-29 | 2012-05-31 | 제이에프이 스틸 가부시키가이샤 | High tensile cold-rolled steel sheet and process for production thereof |
JP5194878B2 (en) * | 2007-04-13 | 2013-05-08 | Jfeスチール株式会社 | High-strength hot-dip galvanized steel sheet excellent in workability and weldability and method for producing the same |
JP5058892B2 (en) | 2008-06-16 | 2012-10-24 | 新日本製鐵株式会社 | DP steel sheet with excellent stretch flangeability and method for producing the same |
JP5162382B2 (en) * | 2008-09-03 | 2013-03-13 | 株式会社神戸製鋼所 | Low yield ratio high toughness steel plate |
JP4998756B2 (en) * | 2009-02-25 | 2012-08-15 | Jfeスチール株式会社 | High-strength hot-dip galvanized steel sheet excellent in workability and manufacturing method thereof |
-
2012
- 2012-06-01 KR KR1020147034518A patent/KR101674283B1/en active Active
- 2012-06-01 CN CN201280073571.7A patent/CN104350170B/en active Active
- 2012-06-01 WO PCT/JP2012/064735 patent/WO2013179497A1/en active Application Filing
Patent Citations (3)
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JP2006176807A (en) * | 2004-12-21 | 2006-07-06 | Kobe Steel Ltd | Dual-phase steel sheet superior in elongation and formability for extension flange |
WO2011090180A1 (en) * | 2010-01-22 | 2011-07-28 | Jfeスチール株式会社 | High-strength hot-dip galvanized steel sheet with excellent material stability and processability and process for producing same |
JP2011214073A (en) * | 2010-03-31 | 2011-10-27 | Sumitomo Metal Ind Ltd | Cold-rolled steel sheet, and method for producing the same |
Also Published As
Publication number | Publication date |
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CN104350170B (en) | 2018-03-06 |
KR101674283B1 (en) | 2016-11-08 |
KR20150004430A (en) | 2015-01-12 |
CN104350170A (en) | 2015-02-11 |
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