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WO2013037622A3 - Pfropfung oder vernetzung von ungesättigten polyolefinen durch basen/isocyanat-initiierung - Google Patents

Pfropfung oder vernetzung von ungesättigten polyolefinen durch basen/isocyanat-initiierung Download PDF

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Publication number
WO2013037622A3
WO2013037622A3 PCT/EP2012/066522 EP2012066522W WO2013037622A3 WO 2013037622 A3 WO2013037622 A3 WO 2013037622A3 EP 2012066522 W EP2012066522 W EP 2012066522W WO 2013037622 A3 WO2013037622 A3 WO 2013037622A3
Authority
WO
WIPO (PCT)
Prior art keywords
grafting
polyolefins
unsaturated polyolefins
crosslinking
isocyanate
Prior art date
Application number
PCT/EP2012/066522
Other languages
English (en)
French (fr)
Other versions
WO2013037622A2 (de
Inventor
Friedrich Georg Schmidt
Stefan Spange
Ingmar Polenz
Original Assignee
Evonik Degussa Gmbh
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Evonik Degussa Gmbh filed Critical Evonik Degussa Gmbh
Priority to EP12753698.5A priority Critical patent/EP2756006A2/de
Priority to US14/343,591 priority patent/US20140249242A1/en
Publication of WO2013037622A2 publication Critical patent/WO2013037622A2/de
Publication of WO2013037622A3 publication Critical patent/WO2013037622A3/de

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F279/00—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00
    • C08F279/02—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00 on to polymers of conjugated dienes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
    • C08C19/00—Chemical modification of rubber
    • C08C19/22—Incorporating nitrogen atoms into the molecule
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F136/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F136/02—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F136/04—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F136/06—Butadiene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/67—Unsaturated compounds having active hydrogen
    • C08G18/69—Polymers of conjugated dienes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/73—Polyisocyanates or polyisothiocyanates acyclic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/75—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic
    • C08G18/751—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring
    • C08G18/752—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group
    • C08G18/753—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group containing one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group having a primary carbon atom next to the isocyanate or isothiocyanate group
    • C08G18/755—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group containing one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group having a primary carbon atom next to the isocyanate or isothiocyanate group and at least one isocyanate or isothiocyanate group linked to a secondary carbon atom of the cycloaliphatic ring, e.g. isophorone diisocyanate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/75—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic
    • C08G18/758—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing two or more cycloaliphatic rings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00—Processes of treating or compounding macromolecular substances
    • C08J3/24—Crosslinking, e.g. vulcanising, of macromolecules
    • C08J3/243—Two or more independent types of crosslinking for one or more polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L47/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
    • C08L75/04—Polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2309/00—Characterised by the use of homopolymers or copolymers of conjugated diene hydrocarbons

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Graft Or Block Polymers (AREA)
  • Other Resins Obtained By Reactions Not Involving Carbon-To-Carbon Unsaturated Bonds (AREA)

Abstract

Die vorliegende Erfindung betrifft eine neuartige Pfropfungs- bzw. Vernetzungsmethode für ungesättigte Polyolefine, bei der die Reaktion durch Isocyanate und spezielle Basen mit Imin-Struktur initiiert wird. Mit dieser neuen und gezielt einsetzbaren Methode können Polyolefine, welche Doppelbindungen aufweisen, bepfropft bzw. bei geeigneter Reaktionsführung vernetzt werden. Weiterhin können diese ungesättigten Polyolefine nach einer Reaktion mit (Poly)isocyanaten zur Herstellung von Pfropf- oder Block-Copolymeren oder auch für die Anbindung der modifizierten ungesättigten Polyolefine an Polyamide, Polyester, Polycarbonate, Polyimine oder Polyurethane verwendet werden.
PCT/EP2012/066522 2011-09-13 2012-08-24 Pfropfung oder vernetzung von ungesättigten polyolefinen durch basen/isocyanat-initiierung WO2013037622A2 (de)

Priority Applications (2)

Application Number Priority Date Filing Date Title
EP12753698.5A EP2756006A2 (de) 2011-09-13 2012-08-24 Pfropfung oder vernetzung von ungesättigten polyolefinen durch basen/isocyanat-initiierung
US14/343,591 US20140249242A1 (en) 2011-09-13 2012-08-24 Grafting or crosslinking of unsaturated polyolefins by base/isocyanate initiation

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102011112963A DE102011112963A1 (de) 2011-09-13 2011-09-13 Pfropfung oder Vernetzung von ungesättigten Polyolefinen durch Basen/Isocyanat-Initiierung
DE102011112963.8 2011-09-13

Publications (2)

Publication Number Publication Date
WO2013037622A2 WO2013037622A2 (de) 2013-03-21
WO2013037622A3 true WO2013037622A3 (de) 2013-06-06

Family

ID=46785394

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2012/066522 WO2013037622A2 (de) 2011-09-13 2012-08-24 Pfropfung oder vernetzung von ungesättigten polyolefinen durch basen/isocyanat-initiierung

Country Status (4)

Country Link
US (1) US20140249242A1 (de)
EP (1) EP2756006A2 (de)
DE (1) DE102011112963A1 (de)
WO (1) WO2013037622A2 (de)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111533883B (zh) * 2020-05-11 2022-10-28 青岛爱尔家佳新材料股份有限公司 一种舰船灌注密封阻尼减振材料及其制备方法
CN117209638B (zh) * 2023-11-08 2024-02-13 传化智联股份有限公司 一种两性离子稀土元素烷基催化剂及其制备方法和应用

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3582508A (en) * 1969-11-28 1971-06-01 Goodyear Tire & Rubber Rubber modified with organic polyisocyanates in presence of promoters
DE2233359A1 (de) * 1972-07-07 1974-01-31 Bayer Ag Niedrigviskose pastoese kautschukmassen
DE2547741A1 (de) * 1974-10-25 1976-05-06 Yokohama Rubber Co Ltd Kautschukmischungen
GB1482864A (en) * 1974-10-04 1977-08-17 Goodrich Co B F Vulcanizable compositions
EP0318878A2 (de) * 1987-12-04 1989-06-07 Henkel Kommanditgesellschaft auf Aktien Heisshärtende Klebstoffe auf Basis von Hydroxylgruppen enthaltendem Polybutadien
US20050143499A1 (en) * 2003-12-10 2005-06-30 Hidetoshi Aoki Moderately resistive rubber composition and rubber member
WO2011085856A1 (de) * 2009-12-21 2011-07-21 Evonik Degussa Gmbh Neues initiierungsverfahren zur polymerisation von (meth) acrylaten

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10150898A1 (de) 2001-02-07 2002-08-22 Roehm Gmbh Heißversiegelungsmasse für Aluminiumfolien gegen Polypropylen und Polystyrol
ITTO20030478A1 (it) 2003-06-25 2004-12-26 Univ Pisa Procedimento di funzionalizzazione radicalica controllata

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3582508A (en) * 1969-11-28 1971-06-01 Goodyear Tire & Rubber Rubber modified with organic polyisocyanates in presence of promoters
DE2233359A1 (de) * 1972-07-07 1974-01-31 Bayer Ag Niedrigviskose pastoese kautschukmassen
GB1482864A (en) * 1974-10-04 1977-08-17 Goodrich Co B F Vulcanizable compositions
DE2547741A1 (de) * 1974-10-25 1976-05-06 Yokohama Rubber Co Ltd Kautschukmischungen
EP0318878A2 (de) * 1987-12-04 1989-06-07 Henkel Kommanditgesellschaft auf Aktien Heisshärtende Klebstoffe auf Basis von Hydroxylgruppen enthaltendem Polybutadien
US20050143499A1 (en) * 2003-12-10 2005-06-30 Hidetoshi Aoki Moderately resistive rubber composition and rubber member
WO2011085856A1 (de) * 2009-12-21 2011-07-21 Evonik Degussa Gmbh Neues initiierungsverfahren zur polymerisation von (meth) acrylaten

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
DUCK-JEI PARK ET AL: "SYNTHESIS AND PROPERTIES OF METHYL METHACRYLATE-EPDM-STYRENE GRAFT TERPOLYMER", JOURNAL OF APPLIED POLYMER SCIENCE, JOHN WILEY & SONS, INC, US, vol. 54, no. 6, 7 November 1994 (1994-11-07), pages 763 - 770, XP000475867, ISSN: 0021-8995, DOI: 10.1002/APP.1994.070540607 *
KOTHANDARAMAN H ET AL: "THE KINETICS OF THE POLYMERIZATION REACTION OF TOLUENE DIISOCYANATE WITH HTPB PREPOLYMER", JOURNAL OF APPLIED POLYMER SCIENCE, JOHN WILEY & SONS, INC, US, vol. 50, no. 9, 5 December 1993 (1993-12-05), pages 1611 - 1617, XP000464181, ISSN: 0021-8995, DOI: 10.1002/APP.1993.070500915 *

Also Published As

Publication number Publication date
WO2013037622A2 (de) 2013-03-21
EP2756006A2 (de) 2014-07-23
US20140249242A1 (en) 2014-09-04
DE102011112963A1 (de) 2013-03-14

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