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WO2013019393A1 - Système de régulation de la pollution pour une évacuation de four - Google Patents

Système de régulation de la pollution pour une évacuation de four Download PDF

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Publication number
WO2013019393A1
WO2013019393A1 PCT/US2012/046848 US2012046848W WO2013019393A1 WO 2013019393 A1 WO2013019393 A1 WO 2013019393A1 US 2012046848 W US2012046848 W US 2012046848W WO 2013019393 A1 WO2013019393 A1 WO 2013019393A1
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WO
WIPO (PCT)
Prior art keywords
filter
gas
particulate matter
catalyst
kiln
Prior art date
Application number
PCT/US2012/046848
Other languages
English (en)
Inventor
Iver Schmidt
Jørn Møller RASMUSSEN
Peter T. Paone Iii
John S. Salmento
Original Assignee
Flsmidth A/S
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Flsmidth A/S filed Critical Flsmidth A/S
Priority to US14/235,915 priority Critical patent/US20140170046A1/en
Publication of WO2013019393A1 publication Critical patent/WO2013019393A1/fr

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/46—Removing components of defined structure
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23J—REMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J15/00—Arrangements of devices for treating smoke or fumes
    • F23J15/02—Arrangements of devices for treating smoke or fumes of purifiers, e.g. for removing noxious material
    • F23J15/022—Arrangements of devices for treating smoke or fumes of purifiers, e.g. for removing noxious material for removing solid particulate material from the gasflow
    • F23J15/025—Arrangements of devices for treating smoke or fumes of purifiers, e.g. for removing noxious material for removing solid particulate material from the gasflow using filters
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86—Catalytic processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86—Catalytic processes
    • B01D53/8621—Removing nitrogen compounds
    • B01D53/8625—Nitrogen oxides
    • B01D53/8631—Processes characterised by a specific device
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86—Catalytic processes
    • B01D53/8643—Removing mixtures of carbon monoxide or hydrocarbons and nitrogen oxides
    • B01D53/8646—Simultaneous elimination of the components
    • B01D53/8653—Simultaneous elimination of the components characterised by a specific device
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B7/00—Hydraulic cements
    • C04B7/36—Manufacture of hydraulic cements in general
    • C04B7/364—Avoiding environmental pollution during cement-manufacturing
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23J—REMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J15/00—Arrangements of devices for treating smoke or fumes
    • F23J15/006—Layout of treatment plant
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23J—REMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J15/00—Arrangements of devices for treating smoke or fumes
    • F23J15/02—Arrangements of devices for treating smoke or fumes of purifiers, e.g. for removing noxious material
    • F23J15/04—Arrangements of devices for treating smoke or fumes of purifiers, e.g. for removing noxious material using washing fluids
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27—FURNACES; KILNS; OVENS; RETORTS
    • F27B—FURNACES, KILNS, OVENS OR RETORTS IN GENERAL; OPEN SINTERING OR LIKE APPARATUS
    • F27B7/00—Rotary-drum furnaces, i.e. horizontal or slightly inclined
    • F27B7/20—Details, accessories or equipment specially adapted for rotary-drum furnaces
    • F27B7/2016—Arrangements of preheating devices for the charge
    • F27B7/2025—Arrangements of preheating devices for the charge consisting of a single string of cyclones
    • F27B7/2033—Arrangements of preheating devices for the charge consisting of a single string of cyclones with means for precalcining the raw material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/10—Oxidants
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/30—Alkali metal compounds
    • B01D2251/304—Alkali metal compounds of sodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/40—Alkaline earth metal or magnesium compounds
    • B01D2251/404—Alkaline earth metal or magnesium compounds of calcium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10—Inorganic adsorbents
    • B01D2253/102—Carbon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/40—Nitrogen compounds
    • B01D2257/404—Nitrogen oxides other than dinitrogen oxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/50—Carbon oxides
    • B01D2257/502—Carbon monoxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/60—Heavy metals or heavy metal compounds
    • B01D2257/602—Mercury or mercury compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/70—Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
    • B01D2257/708—Volatile organic compounds V.O.C.'s
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2258/00—Sources of waste gases
    • B01D2258/02—Other waste gases
    • B01D2258/0233—Other waste gases from cement factories
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2259/00—Type of treatment
    • B01D2259/12—Methods and means for introducing reactants
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23J—REMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J2217/00—Intercepting solids
    • F23J2217/10—Intercepting solids by filters
    • F23J2217/101—Baghouse type
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23J—REMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J2217/00—Intercepting solids
    • F23J2217/10—Intercepting solids by filters
    • F23J2217/104—High temperature resistant (ceramic) type
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23—COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23J—REMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J2219/00—Treatment devices
    • F23J2219/10—Catalytic reduction devices

Definitions

  • VOCs volatile organic compounds
  • combustion byproducts such as carbon monoxide and ⁇
  • dioxin/furans from industrial plants such as cement manufacturing facilities.
  • the exhaust gas from a preheater/precalciner system is typically in such a range. While this temperature range is conducive to a high activity for the catalyst, these systems often see issues associated with the loading of particulate matter in the exhaust gas stream.
  • Typical dust loadings in these gas streams may be in the range of 20 to 50 grams of particulate per cubic meter of exhaust gas, although dust contents exceeding 150 grams of particulate per cubic meter of exhaust gas can be seen.
  • the particulate matter is typically comprised of the fine dust fraction of feed material introduced to the kiln system which is not completely captured within the kiln or preheater system.
  • This fine dust is comprised of varying amounts of and compositions containing calcium, aluminum, silica, and iron, as well as sodium, potassium, chlorides, sulfur and minor constituents such as phosphorous, arsenic, thallium, and zinc.
  • any of these compounds can cause degradation of the catalytic effect of the system through de-activation of the surface, poisoning of the catalyst, erosion of the catalytic surface, or the blocking of the catalyst surface from contact with the gaseous constituents.
  • the dust content of the gas stream requires larger openings in the catalytic structures in use in these systems, requiring larger catalyst structures to obtain the same catalytic surface as is found in other industrial applications. In systems where SCR is practiced, soot blowers for dedusting and periodic cleaning of the catalyst surface are required. The loss in efficiency associated with dust loading therefore leads to higher costs for these systems for design and operation than in comparable industries with low dust loads.
  • This "low dust SCR” arrangement offers several advantages over the “high dust SCR” arrangement, including a longer lifetime for catalyst structures before replacement, the usage of smaller openings between catalyst plates or honeycombs which allows for a smaller and less costly catalytic structure, and lower operating costs associated with less replacement of catalyst.
  • This arrangement does come with several disadvantages.
  • the requirement for a dust collection device such as a filter or precipitator is an added piece of process equipment that comes with installation and long term operating and maintenance expenses,
  • the additional pressure drop through the precipitator or filter, in addition to the catalyst structure will increase the power requirements on any fans utilized for drafting gas through the overall system.
  • the objects of the present invention include improving the control of various undesirable emissions from cement and minerals, and obtaining a high efficiency of catalytic activity such as is found in a "low dust SCR” applications while having a high inlet dust loading similar to that encountered in "high dust SCR” applications, while utilizing fewer pieces of equipment and a lower pressure drop than a "low dust SCR” system.
  • the invention there is a method for the reduction of organic compounds and other emissions from an industrial plant having a cement or mineral kiln or calciner system that has a high level of emissions.
  • the invention treats the exhaust gas stream from the cement or minerals processing plant on a filter medium in order to remove entrained particulate, and destroys the targeted pollutant within the structure of the filter medium.
  • Particulate captured on the surface of the filter medium is periodically removed from the surface of the medium to prevent blockage of the porous filter medium and to avoid undesireable increases in energy consumption at the processing plant.
  • Such removal can be achieved by a number of methods, including subjecting the filter medium to sonic or ultrasonic vibration or the mechanical removal of particulate matter with a solid object.
  • Pre-treatment of the exhaust gas stream can be used to enhance the pollutant destruction capabilities of the filtration device, or to prevent oxidation of entrained pollutants to less desirable compounds.
  • This invention is not limited to cement or lime plants. It can be used in any industrial processing plant where the emission of organic compounds, total organic carbons or volatile organic carbons, carbon monoxide, nitrogen oxides, or dioxin/furans require a very high degree of treatment for attainment of regulatory requirements, such as, for example, in plants that use long dry cement kilns, short cement kilns with precalciners, and lime kilns.
  • FIG. 1 is a diagram of a plant for the production of cement clinker adapted to the cleaning of hydrocarbons and other contaminants according to the invention.
  • FIG. 2A is a diagram of one embodiment of the invention in a cement or minerals kiln system.
  • FIG. 2B is a more detailed view of a filter element utilized in the invention.
  • FIG. 3 is a diagram of another embodiment of the invention utilizing a different method for holding and supporting the catalytic filter elements.
  • FIG. 4A is a diagram of another embodiment of the invention utilizing another method for holding and supporting the catalytic filter elements and for removal of the collected particulate matter.
  • FIG. 4B is an isometric view of the embodiment of the invention depicted in FIG. 4A.
  • FIG. 5 is another general diagram of a plant for the production of cement clinker adapted to the cleaning of hydrocarbons and other contaminants according to the invention.
  • FIG.6 is an example of organic compound reduction curves comparing removal efficiencies of the invention at varying temperatures and for various organic compounds.
  • the invention is particularly directed to the reduction in emissions of organic compound emissions
  • the present invention also applies to the removal of other products of incomplete or partial combustion such as carbon monoxide, condensable VOC's, nitrogen oxides, and dioxin/furans that contaminate manufacturing processes.
  • Many of the organic compounds that this invention is directed towards fall under numerous overlapping categories of compounds, such as Total Organic Carbon (TOC), Total Hydrocarbons (THC), and Volatile Organic Compounds (VOC), and this invention is broadly aimed to the various compounds which are classified under these general categories.
  • TOC Total Organic Carbon
  • THC Total Hydrocarbons
  • VOC Volatile Organic Compounds
  • the present invention is applicable to other minerals and kiln manufacturing processes, such as lime manufacturing processes and other industrial processes where very high starting emission levels of these contaminate compounds can not be sufficiently controlled using existing methods, or where existing methods of control are cost prohibitive.
  • Emissions of organic compounds from industrial process may originate from a variety of different sources within a system.
  • these sources may include incomplete combustion of fuels fired within the system, decomposition or partial combustion of organic species within feed components, contamination of gas streams with organic materials such as from oiled-compressors, introduction of organic components in process water used for cooling, and from introduction of ambient air which may contain organic components in small quantities.
  • the oxygen concentrations at the exhaust of many industrial processes such as cement kilns are kept low in order to improve efficiencies within the systems, but such low oxygen concentrations inhibit full combustion of these various organic compounds prior to release from the system.
  • These minor components may contribute to localized conditions such as smog, and are therefore seeing increased levels of regulation.
  • the invention in part comprises the use, in conjunction with a kiln exhaust, of a device fitted with a filter element or filter elements which are pretreated with the catalyst or composed of the catalytic materials dispersed through the filter elements.
  • the catalyst utilized in the pretreatment or the construction of the filter element is chosen prior to installation of the filter elements within the device in order to treat those gaseous emissions within the exhaust stream from the industrial process which must be controlled in order to achieve regulatory compliance.
  • the catalysts are designed for the control of organic compound emissions such as Volatile Organic Compounds (VOC), Total Hydrocarbons (THC), Total Organic Carbon (TOC), and similar classifications of emissions
  • the catalyst for the pretreatment of the filter elements or the dispersal through the filter elements may also be chosen for the reaction or destruction of other compounds including dioxins, furans, carbon monoxide, or oxides of nitrogen ( ⁇ ), or can be used for the oxidation of mercury for further treatment and capture after the device.
  • the catalytic elements used in the treatment or manufacture of the filter elements can contain a mixture of any of vanadium, platinum, palladium, ruthenium, titanium, lanthanum, cerium, yttrium, zirconium, tungsten, manganese, niobium, molybdenum, nickel, iron and copper in compositions designed to remove those emissions which must be reduced in the gas stream.
  • the filter elements are porous membranes which allow for the passing of exhaust gases through the elements, but of sufficiently small pore size to capture a significant quantity of the dust on the surface of the elements which is exposed to the process exhaust gas containing entrained dust.
  • the surface of the filter element exposed to the process exhaust gas containing entrained dust is referred to as the "dirty side” of the filter element, while the surface of the filter opposite the “dirty side” and through which the dedusted process gases pass to the outlet of the filter is referred to as the “clean side” of the filter elements.
  • the filter element is comprised of the porous substrate as well as the catalytic component of the filter element during the manufacturing process.
  • the filter elements are treated with the catalysts either in whole or in part, with catalysts deposited on both the "clean side” surface and the "dirty side” of the filter element penetrating through a depth to the inside of the filter element, with the maximum penetration of the catalysts being through the entire thickness of the filter element, i.e. from the "clean side” to the "dirty side” of the filter element.
  • the non-catalytic portion of the filter element which serves as a substrate to the catalyst and as the porous filter for entrained dust in the gas stream, is composed of a material which is designed to retain sufficient filtering properties through the design range at which the filter elements will be exposed for filtration of dust and for catalytic reduction of gaseous pollutants.
  • the non-catalytic composition of the filter element may be comprised of any of porous ceramic, glass fibers, ground quartz, alumino-silicate ceramic fiber, rutile, calcite, corundum, kaolinite, and diatomaceous earth, among others.
  • the surface of the filter elements which is exposed to the process exhaust gas entering the device is periodically cleaned to prevent excessive accumulations of dust, which would otherwise increase the pressure drop of the device, and thus increase the power consumption of the system in operation.
  • Cleaning of the device may be performed through mechanical cleaning, such as scraping or "rapping" of the filter elements, but is preferentially performed through periodic "pulsing" of gas counter to the flow of the industrial process exhaust gas entering the filter element. Dust which is released from the filter element may be returned to the cement or mineral processing facility, or may be withdrawn and stored for use elsewhere.
  • the filter element is placed such that the exhaust gases from the cement or minerals industrial process, which contain entrained particulate matter, are passed through its porous filter.
  • the majority of the entrained particulate matter is captured on the surface of the filter element and will not come into contact with the interior of the filter element.
  • Gases passing through the pores of the filter element come in direct contact with the catalytic compounds with which the element has been treated, ensuring contact time between the gas and the catalyst. This reduces the required residence time with the catalyst and allows for the possibility of a smaller installation.
  • the filter elements as the catalyst substrate, the steps of separation (of the dust from the gases) and catalytic contact may occur within the same device, also reducing the size and cost of an installation.
  • a sorbent for sulfur emissions may be injected before the device to capture sulfur dioxide emissions prior to the filter elements and the catalyst. In this manner, the sulfur dioxide may be captured prior to the gases contacting the catalyst, preventing the potential formation of sulfur trioxide within the filter elements through catalytic oxidation.
  • a sorbent for capture of mercury emissions is injected after the filter device in order to capture mercury emissions which have been oxidized in contact with the catalyst.
  • a nitrogenated agent such as ammonia, urea, ammonium bisulfate, or flyash may be injected prior to the filter device in order to reduce ⁇ emissions.
  • injection of ammonia may be placed immediately prior to the inlet of the filter device, or may be injected in excess within the industrial process producing the exhaust gas with the resulting ammonia slip further reacting within the filter device.
  • Placement of the catalytic filter device into the industrial process is dependent upon the pollutants in the exhaust gas stream that are to be destroyed.
  • the activity of the catalyst and the selectivity of the catalyst for destruction of gaseous emissions are dependent upon the temperature of the gas stream.
  • Organic compounds such as methanol can be destroyed in large percentages even at temperatures as low as 120°C, while organic compounds such as propane may require temperatures as high as 300°C. It is preferential for the destruction or reaction of shorter-chain (less than 7 carbon atoms) hydrocarbons, of single-bonded (i.e.
  • the device may preferentially be used in the temperature range of 80 °C to 250 °C, and more
  • the catalytic activity of the filter elements may also be enhanced through the treatment of the gas stream with other means. These means would include the use of ozone, peroxide, potassium permanganate, calcium chloride, sodium hydroxide, or other oxidizing species injected upstream of the filter element or within the filter device.
  • material is treated in a kiln 1, which heats the material to undergo chemical changes.
  • the feed entering kiln 1 through conduit 2 may first be preheated in a preheater system 50
  • the material may also pass through a calciner or pre-calciner 52 for removal of carbon dioxide prior to entering kiln 1.
  • Product from kiln 1 is discharged into a material cooler 3 which serves the purpose of cooling the kiln product before discharge 4, and of recuperating heat from the product to be returned to the kiln 1 or to the calciner 52.
  • Cooling air is passed over the material and is heated before passing through the kiln hood 5 to enter kiln 1 or to enter the calciner 52 through conduit 6.
  • the air flowing to kiln 1 and calciner 52 is utilized in combustion process.
  • Excess air that enters cooler 3 for product cooling is directed to an exhaust vent 7.
  • the air exiting cooler 3 through exhaust vent 7 are cooled in a heat exchanger 8, and entrained particulate matter is removed in a dust collector 9 and removed as a product stream 10.
  • the cooler excess air may then be vented to atmosphere at 11, or used in other means within the process.
  • Gases exiting from kiln 1 are directed through calciner 52 and into preheater system 50.
  • Feed material 20 to the system is directed to the preheater system 50 for thermal treatment, and may be split between various counter current heat exchangers 51 for the control of temperature from the exhaust gas 21 or for the high temperature treatment of the feed material.
  • the feed material is directed to the uppermost cyclone heat exchanger as depicted. Emissions of organic compounds, mercury, and carbon monoxide from the thermal treatment of feed material 20 within preheater system 50, and emissions of organic compounds, carbon monoxide, and other products of incomplete combustion from the calciner 52 or kiln 1, will leave the system in the exhaust gas stream 21. Nitrogen oxides created and mercury released from combustion processes in calciner 52 and kiln 1 will also leave the system in the exhaust gas stream 21.
  • the exhaust gas from the kiln system is then directed through the catalytic filter system 100 for the destruction or reaction of gaseous emissions in exhaust gas stream 21.
  • treated exhaust gas stream 22 may be directed to a gas conditioning tower 23 which utilizes cooling water 24 for the cooling of the gas stream for further processing.
  • Conditioned gas 25 from the gas conditioning tower 23 may be directed to a raw mill system 60 or multiple mill systems, or to a main dust collector 70 for final particulate control.
  • Raw feed materials 61 are introduced to the raw mill system 60 which grinds the feed materials to a size suitable for the production of cement clinker.
  • the product material from the mill exits the mill 60 with an exhaust gas stream 65 and is separated in a collection device such as a cyclone 62 or cyclones.
  • the material 63 captured in the cyclone 62 is transported to a blending and/or storage silo 90 for use in the kiln system.
  • the gases 64 from cyclone 62 are then directed to a main dust collector 70 for collection of fine particulate matter not captured in the cyclone.
  • the gases from the main dust collector may then be vented from the system 80.
  • Material 71 captured in the main dust collector is then transported to the blending and/or storage silo 90, or to some other storage area for further treatment or disposal.
  • Material blended and/or stored in silo 90 is used as kiln feed 20 for the kiln system.
  • hot gases may be removed from the system 31 for use in a milling system for the solid fuel or for other heating processes within the plant facility.
  • the hot gases may alternatively be removed from the system after the catalytic filter system and before the gas conditioning tower, or after the gas conditioning tower and before the main dust collector.
  • Exhaust gases from the solid fuel grinding system may be returned to the system in a gas stream 41 prior to the catalytic filter system, may be directly vented to atmosphere, or may be combined with the exhaust gases 80 from the main dust collector 70 before being vented to the atmosphere.
  • the catalytic filter system 100 is depicted as being positioned between the
  • the catalytic filter system may alternatively be placed at a number of other locations within the system.
  • the catalytic filter system may be placed at location A (between the exit of the preheater system 50 and the hot gas stream 31 removed from the preheater exhaust gas stream 21), at location B (between the hot gas stream 31 removed from preheater exhaust gas stream and the returned gas stream 41 from the solid fuel grinding system), or at location C (after the exhaust of the gas conditioning tower 23).
  • sorbents in the process prior to the position of the catalytic filter system in order to capture items that otherwise may oxidize to less preferable components in the catalytic filter systems.
  • Sorbents such as calcium oxide, calcium hydroxide or hydrated lime, trona, activated carbon, or proprietary sorbents such as MinsorbTM or SorbacalTM, may be utilized in this capacity in one or all of locations SI, S2, and S3.
  • injection of additional reactive agents such as ozone, peroxide, potassium permanganate, calcium chloride, sodium hydroxide, or other oxidizing species, or ammonia, urea, or other nitrogenous compounds for conversion of emission components to those more readily destroyed within the catalytic filter system or to directly improve the destruction of compounds in the catalytic filter system may be utilized in one or all of locations SI, S2, S3, S4 and S5.
  • FIG.2A shows one embodiment of the present invention, with emphasis on area 100 of FIG. 1.
  • Process gases 101 from the exit of the kiln installation such as the exit of a cement kiln, preheater, or precalciner system or a lime kiln or preheater system are directed via a conduit 102 to the catalytic filter unit 103.
  • Filter unit 103 comprises housing XXX, which encloses an interior portion of the unit which is partitioned by a sheet 105 through which filter elements 104 are inserted.
  • the filter elements are a porous material, such as a fiberglass bag or a porous ceramic structure, which will allow the process gases to pass through, but which will trap a large portion of particulate matter on the surface of the filter element.
  • the porous filter will reduce the dust load of the gas passing through the filter element to 5 grams per cubic meter of process gas or less, preferentially less than 30 milligrams per cubic meter of process gas, and most preferentially less than 5 milligrams of particulate per cubic meter of process gas.
  • Particulate matter collected on the surface of the filter elements is removed from the surface of the filter and collected in the bottom of the device at 106 and removed through a withdrawal system 107. Cleaning of the material on the surface may be conducted on a routine basis at set time intervals, or may be controlled by monitoring the accumulation of material on the filter element surface by means of a pressure monitoring device 108 to monitor the difference in pressures attained across the partition between the clean and dirty sides of the filter. Gases passing through the filter elements come into contact with the catalytic material with which the filter elements have been treated or produced.
  • Contaminants such as organic compounds react upon the catalytic elements of the filter elements and are destroyed.
  • the reaction activity of the catalyst to increase the reduction of hydrocarbons present in the filtering element may be improved by contacting the catalytic agents with a reactive agent, such as by injecting one or more reactive agents at a point located prior to the catalytic filter as described previously.
  • the temperature of the gas stream is monitored at position 109 to ensure that the interior of the filter device is maintained at a temperature that facilitates sufficient activity of the catalyst, and if the temperature within the filter device is not suitable for the destruction of the targeted pollutant(s), process changes can be made prior to the catalytic filter to ensure sufficient temperature for efficient destruction of the entrained pollutants.
  • the temperature within the filter device can also be controlled through the introduction of a gas stream 120 prior to the catalytic filter system.
  • gas streams for temperature control include ambient air introduced by a fan or damper to reduce inlet temperature, hot gas streams from heat sources such as stand-by heaters, or waste heat from other areas of the cement or minerals processing kiln system such as from a cooler vent exhaust stream. While depicted as being located on the clean side of the filter elements at 109, the temperature monitor can be placed on the dirty side of the filter, or in the duct work prior to or after the catalytic filter.
  • the cleaned gases 110 exit the catalytic filter via a duct 111, and can be used elsewhere in the process or vented to atmosphere.
  • FIG. 2B shows a more detailed view of a filter element 104.
  • the gas stream with entrained particulate matter 152 impacts on the surface of the filter element adjacent to the filter elements 156.
  • the gas stream follows the direction of flow as shown by dotted line 151 and is forced through the porous portion 150 of the filter element to come into contact with catalytic agents container therein.
  • the clean gas stream from which particulate matter has been removed passes to the "clean side" 155 of the filter.
  • the particulate matter 154 entrained in the gas stream is collected on the surface of the dirty side of filter elements 104 and is removed periodically.
  • filter elements are depicted in FIG.2A as being supported by the partition within the catalytic filter, and the inlet gas enters below the partition and exits above the partition, multiple arrangements of partition, filter elements, and gas inlets and outlets may be utilized depending on the possible layouts within the system and the materials of construction used for the catalytic filter and the filter elements.
  • a porous ceramic filter element may be limited in length by the strength of the filter element at the support point, which may necessitate a large number of filter elements to achieve sufficient particulate matter control or catalytic activity.
  • FIG. 3 depicts another embodiment of the system and method of the present invention in the context of a cement or minerals processing kiln installation.
  • Process gases 201 from the exit of the kiln installation such as the exit of a cement kiln, preheater, or precalciner system or a lime kiln or preheater system are directed via a conduit 202 to the catalytic filter unit 203.
  • the filter unit is partitioned by sheet 215 and sheet 216 through which filter elements 204 are inserted.
  • the support provided to filter element 204 by sheet 215 is in tension, while the support provided to filter element 204 by sheet 216 is in compression.
  • a ceramic filter as element 204 gets longer its weight becomes a concern at the support point.
  • FIG. 4A depicts another embodiment of the system and method of the present invention. Process gases 301 from the exit of the kiln installation are directed via a conduit 302 to the catalytic filter unit 303.
  • the filter unit features a number of filter elements 304 supported on a series of chambers or plenums 317 through which air passes from the interior of the filter elements to the exterior of the filter device via exit 311.
  • Each plenum 317 supports a plurality of filter elements, an arrangement shown more clearly in Fig. 4B, and plenums 317 are closed from the inlet stream with a partition 316.
  • the filter elements are supported from lateral movement with a support structure 315.
  • the support provided to the element by partition 316 is in compression. Particulate matter collected on the surface of the filter elements is removed from the surface of the filter, falls between the clean air plenums at 319, and is collected in the device 306 and removed at 307.
  • the arrangement allows for a flow of gas to exit at 311 from the bottom of the filter, that is, below the elements. This allows for the installation of this filter in line with the existing gas flow from the exhaust duct of some types of kiln systems using cyclone preheaters, and is an advantage in retrofit applications.
  • the K) fan can be closer to the tower, and the support of the elements is such that a longer element could be used. Overall, this would allow for the tallest and skinniest installation, allowing for the easiest retrofit in many installations.
  • Pressure monitoring device 308 monitors the difference in pressures attained across the partition between the clean and dirty sides of the filter. The temperature of the gas stream is monitored at 309 The cleaned gases 311 in the chambers or plenums are removed from the catalytic filter via a duct 310.
  • FIG. 4B depicts an isometric view of the embodiment depicted in Figure 4A, with similar numbers depicting similar elements
  • Process gases 301 from the exit of the kiln installation such as the exit of a cement kiln, preheater, or precalciner system or a lime kiln or preheater system are directed via a conduit 302 to the catalytic filter unit 303.
  • the filter unit features a number of filter elements 304 supported on a series of chambers or plenums closed from the inlet stream with a partition 316.
  • the filter elements are supported from lateral movement with a support structure 315.
  • Particulate matter collected on the surface of the filter elements is removed at 307.
  • the cleaned gases 311 in the chambers or plenums are removed from the catalytic filter via a duct 310.
  • FIG. 5 shows a similar system as depicted in FIG. 1, but utilizes the catalytic filter system 100 in place of the main dust collector 80 shown in FIG. 1.
  • FIG.5 similar numbers to those of FIG. 1 depict similar elements.
  • This arrangement offers the advantage that the use of pollution control equipment is minimized, as the catalytic filter system is used as the main dust collector, which in turn reduces the installation and operational costs as well as power consumption.
  • the use of this arrangement is more difficult to implement in that the operating temperatures of the incoming gas stream are typically lower than the operating temperatures found nearer to the exit of the kiln or preheater system. This arrangement is preferred when the primary emissions that the catalytic filter system is intended to destroy can be effectively reduced in the temperature range found in this location.
  • a hot gas source 95 such as a portion or all of the gas stream leaving the cooler vent and removed from gas stream 7, between heat exchanger 8 and dust collector 9, or from the stack gas 11, may be used to return the gas temperature to a higher range which will improve the activity of the catalytic filter system.
  • the use of waste heat from the cooler vent system is preferred in that dust collector 9 may also be eliminated in whole or reduced in size if sufficient gas flow is continuously removed from this location, further reducing installation and operational costs as well as system power consumption.
  • FIG. 6 shows an example set of organic compound reduction curves comparing the removal efficiency of a catalytic filter system operated at varying temperatures for different examples of organic compounds for a catalytic filter system of the invention.
  • the catalyst in use exhibits greater than 90% destruction of methanol at temperatures ranging between 100 and 225 °C, increasing rates of toluene removal from less than 30% at approximately 120 °C to greater than 90% destruction above approximately 200 °C, increasing rates of heptanes destruction ranging from less than 50% at approximately 160 °C to greater than 90% above approximately 240 °C, and increasing propane removal from 20% at 300 °C to greater than 60% at approximately 370 °C.
  • Organic compound reduction curves such as that depicted in FIG.6 will vary with the selection of the catalytic elements used in the production of the filter elements utilized in the catalytic filter system, as well as any reactive agents utilized in conjunction with the catalytic filter elements.
  • Knowledge of the constituent organic compounds in the cement or minerals kiln or calciner exhaust gas, through direct measurement or previously established predictive means, in comparison to organic compound reduction curve with regard to operating temperature, can be utilized to select the location and specific design configuration of the catalytic filter system as depicted in FIGS. 1 through 5, or in similar variations.
  • the control of a process gas stream containing high levels of methanol and toluene may more efficiently utilize the catalytic filter system as depicted in FIG. 5 and FIG. 6, while the control of a process gas stream containing high levels of propane may more efficiently utilize the catalytic filter system as depicted in FIG. 1 and FIG. 6.
  • the exhaust gases from an industrial plant such as a cement or mineral kiln can be treated to reduce or destroy organic compounds and other pollutants from the exhaust until the total content of organic compounds and other pollutants in the gas stream is below levels that may be considered safe for release to the atmosphere. Treatment of the gas stream may also allow for removal of other pollutants, or additional treatment downstream.

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Abstract

L'invention concerne une méthode et un appareil permettant la réduction des émissions de composés organiques et d'autres composés d'un équipement industriel utilisant un four à ciment ou à minéraux créant des émissions élevées de composés organiques. L'invention est constituée d'un filtre pour la régulation des émissions de particules qui a été traité avec un catalyseur afin de permettre la destruction catalytique des émissions gazeuses lors du passage des gaz de procédé au travers de la substance poreuse du filtre.
PCT/US2012/046848 2011-07-29 2012-07-16 Système de régulation de la pollution pour une évacuation de four WO2013019393A1 (fr)

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CN104458804A (zh) * 2014-12-05 2015-03-25 浙江大学宁波理工学院 富氧燃烧气氛下烟气中氧化性Cl形成装置
DE102014005508A1 (de) * 2014-04-12 2015-10-15 Khd Humboldt Wedag Gmbh Verfahren und Anlage zur Entstickung von Rauchgasen mit SNCR (Selektive nichtkatalytische Reduktion) und nachgeschaltetem Katalysator zum Ammoniakabbau
CN106000038A (zh) * 2016-07-07 2016-10-12 无锡市昂益达机械有限公司 一种整体式的废气处理装置
US20170115062A1 (en) * 2014-05-27 2017-04-27 Scheuch Gmbh Apparatus for producing cement clinker
CN106659972A (zh) * 2014-08-29 2017-05-10 杜尔系统股份公司 处理装置和用于处理废气流的方法
CN108939877A (zh) * 2016-07-15 2018-12-07 缪琼华 一种去除废气中苯系物的钨线圈表面活化-臭氧氧化处理装置
EP3055266B1 (fr) 2013-10-08 2019-08-21 KHD Humboldt Wedag GmbH Procédé de dénitrification d'effluents gazeux de dérivation dans une installation de production de clinker de ciment
CN110465161A (zh) * 2019-08-05 2019-11-19 潜江宜生新材料有限公司 一种用于生产硅烷偶联剂的尾气吸收系统
CN110785230A (zh) * 2017-04-28 2020-02-11 优美科触媒日本有限公司 废气净化用催化剂及使用其的废气净化方法
CN112495124A (zh) * 2021-02-05 2021-03-16 矿冶科技集团有限公司 从中性气氛的脱砷烟气中收集硫化砷的方法及系统、应用
WO2022146872A1 (fr) * 2020-12-30 2022-07-07 W.L. Gore & Associates, Inc. Amélioration de l'efficacité catalytique de filtration de gaz de combustion par formation de sel à l'aide d'au moins un agent oxydant
US11566842B2 (en) * 2018-05-15 2023-01-31 Flsmidth A/S Emission abatement apparatus for processing of particulates and method of using same

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WO2020245243A1 (fr) 2019-06-07 2020-12-10 Haldor Topsøe A/S Procédé d'élimination de dioxines assistée par ozone
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WO2021142076A1 (fr) * 2020-01-07 2021-07-15 Environmental Energy Services, Inc. Silicates modifiés pour le piégeage et la destruction de dioxines/furanes et d'autres matières organiques dans des flux et des effluents de procédés industriels
BE1030235B1 (de) * 2022-02-01 2023-08-29 Smidth As F L Standby-Betrieb einer Vorrichtung zur Wärmebehandlung bei Wartung einer Abgasreinigung

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EP3055266B1 (fr) 2013-10-08 2019-08-21 KHD Humboldt Wedag GmbH Procédé de dénitrification d'effluents gazeux de dérivation dans une installation de production de clinker de ciment
DE102014005508A1 (de) * 2014-04-12 2015-10-15 Khd Humboldt Wedag Gmbh Verfahren und Anlage zur Entstickung von Rauchgasen mit SNCR (Selektive nichtkatalytische Reduktion) und nachgeschaltetem Katalysator zum Ammoniakabbau
DE102014005508B4 (de) * 2014-04-12 2017-12-21 Khd Humboldt Wedag Gmbh Verfahren und Anlage zur Entstickung von Rauchgasen mit SNCR (Selektive nichtkatalytische Reduktion) und nachgeschaltetem Katalysator zum Ammoniakabbau
US20170115062A1 (en) * 2014-05-27 2017-04-27 Scheuch Gmbh Apparatus for producing cement clinker
CN106659972A (zh) * 2014-08-29 2017-05-10 杜尔系统股份公司 处理装置和用于处理废气流的方法
CN104458804A (zh) * 2014-12-05 2015-03-25 浙江大学宁波理工学院 富氧燃烧气氛下烟气中氧化性Cl形成装置
CN106000038A (zh) * 2016-07-07 2016-10-12 无锡市昂益达机械有限公司 一种整体式的废气处理装置
CN108939877A (zh) * 2016-07-15 2018-12-07 缪琼华 一种去除废气中苯系物的钨线圈表面活化-臭氧氧化处理装置
CN110785230A (zh) * 2017-04-28 2020-02-11 优美科触媒日本有限公司 废气净化用催化剂及使用其的废气净化方法
CN110785230B (zh) * 2017-04-28 2022-09-23 优美科触媒日本有限公司 废气净化用催化剂及使用其的废气净化方法
US11566842B2 (en) * 2018-05-15 2023-01-31 Flsmidth A/S Emission abatement apparatus for processing of particulates and method of using same
CN110465161A (zh) * 2019-08-05 2019-11-19 潜江宜生新材料有限公司 一种用于生产硅烷偶联剂的尾气吸收系统
WO2022146872A1 (fr) * 2020-12-30 2022-07-07 W.L. Gore & Associates, Inc. Amélioration de l'efficacité catalytique de filtration de gaz de combustion par formation de sel à l'aide d'au moins un agent oxydant
CN112495124A (zh) * 2021-02-05 2021-03-16 矿冶科技集团有限公司 从中性气氛的脱砷烟气中收集硫化砷的方法及系统、应用
CN112495124B (zh) * 2021-02-05 2021-05-14 矿冶科技集团有限公司 从中性气氛的脱砷烟气中收集硫化砷的方法及系统、应用

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