WO2013016734A1 - System and method for performing wellbore fracture operations - Google Patents
System and method for performing wellbore fracture operations Download PDFInfo
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- WO2013016734A1 WO2013016734A1 PCT/US2012/048877 US2012048877W WO2013016734A1 WO 2013016734 A1 WO2013016734 A1 WO 2013016734A1 US 2012048877 W US2012048877 W US 2012048877W WO 2013016734 A1 WO2013016734 A1 WO 2013016734A1
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Classifications
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- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21B—EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B43/00—Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells
- E21B43/25—Methods for stimulating production
- E21B43/26—Methods for stimulating production by forming crevices or fractures
- E21B43/267—Methods for stimulating production by forming crevices or fractures reinforcing fractures by propping
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21B—EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B41/00—Equipment or details not covered by groups E21B15/00 - E21B40/00
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21B—EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B43/00—Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells
Definitions
- the present disclosure relates generally to methods and systems for performing wellsite operations. More particularly, this disclosure is directed to methods and systems for performing fracture and production operations, such as investigating subterranean formations and characterizing hydraulic fracture networks in a subterranean formation.
- Hydraulic fracturing may be used to create cracks in subsurface formations to allow oil or gas to move toward the well.
- a formation is fractured by introducing a specially engineered fluid (referred to as “fracturing fluid” or “fracturing slurry” herein) at high pressure and high flow rates into the formation through one or more wellbore.
- Hydraulic fractures may extend away from the wellbore hundreds of feet in two opposing directions according to the natural stresses within the formation. Under certain circumstances, they may form a complex fracture network.
- the fracturing fluids may be loaded with proppants, which are sized particles that may be mixed with the fracturing fluid to help provide an efficient conduit for production of hydrocarbons to flow from the formation/reservoir to the wellbore.
- Proppant may comprise naturally occurring sand grains or gravel, man-made or specially engineered proppants, e.g. fibers, resin-coated sand, or high-strength ceramic materials, e.g. sintered bauxite.
- the proppant collects heterogeneously or homogenously inside the fracture to "prop" open the new cracks or pores in the formation.
- the proppant creates a plane of permeable conduits through which production fluids can flow to the wellbore.
- the fracturing fluids are preferably of high viscosity, and therefore capable of carrying effective volumes of proppant material.
- the fracturing fluid may be realized by a viscous fluid, sometimes referred to as "pad” that is injected into the treatment well at a rate and pressure sufficient to initiate and propagate a fracture in hydrocarbon formation. Injection of the "pad” is continued until a fracture of sufficient geometry is obtained to permit placement of the proppant particles.
- the fracturing fluid may consist of a fracturing fluid and proppant material.
- the fracturing fluid may be gel, oil based, water based, brine, acid, emulsion, foam or any other similar fluid.
- the fracturing fluid can contain several additives, viscosity builders, drag reducers, fluid-loss additives, corrosion inhibitors and the like.
- the proppant may have a density close to the density of the fracturing fluid utilized.
- Proppants may be comprised of any of the various commercially available fused materials, such as silica or oxides. These fused materials can comprise any of the various commercially available glasses or high-strength ceramic products.
- the well may be shut-in for a time sufficient to permit the pressure to bleed off into the formation. This causes the fracture to close and exert a closure stress on the propping agent particles. The shut-in period may vary from a few minutes to several days.
- Conventional hydraulic fracture models may also assume a bi-wing type induced fracture. These bi-wing fractures may be short in representing the complex nature of induced fractures in some unconventional reservoirs with preexisting natural fractures. Published models may map the complex geometry of discrete hydraulic fractures based on monitoring microseismic event distribution.
- models may not be constrained by accounting for either the amount of pumped fluid or mechanical interactions both between fractures and injected fluid and among the fractures.
- Some of the constrained models may provide a fundamental understanding of involved mechanisms, but may be complex in mathematical description and/or require computer processing resources and time in order to provide accurate simulations of hydraulic fracture propagation.
- Patterns of hydraulic fractures created by the fracturing stimulation may be complex and form a fracture network as indicated by the distribution of associated microseismic events.
- Complex hydraulic fracture networks have been developed to represent the created hydraulic fractures. Examples of fracture models are provided in US Patent/Application Nos. 6101447, 7363162, 7788074, 20080133186, 20100138196, and 20100250215.
- the present application discloses methods and systems for characterizing hydraulic fracturing of a subterranean formation based upon inputs from sensors measuring field data in conjunction with a hydraulic fracture network model.
- the fracture model constrains geometric properties of the hydraulic fractures of the subterranean formation using the field data in a manner that significantly reduces the complexity of the fracture model and thus significantly reduces the processing resources and time required to provide accurate characterization of the hydraulic fractures of the subterranean formation.
- Such characterization can be generated in realtime to manually or automatically manipulate surface and/or down-hole physical components supplying fracturing fluids to the subterranean formation to adjust the hydraulic fracturing process as desired, such as by optimizing fracturing plan for the site (or for other similar fracturing sites).
- the methods and systems of the present disclosure are used to design wellbore placement and hydraulic fracturing stages during the planning phase in order to optimize hydrocarbon production.
- the methods and systems of the present disclosure are used to adjust the hydraulic fracturing process in real-time by controlling the flow rates, compositions, and/or properties of the fracturing fluid supplied to the subterranean formation.
- the methods and systems of the present disclosure are used to adjust the hydraulic fracturing process by modifying the fracture dimensions in the subterranean formation in real time.
- the method and systems of the present disclosure may also be used to facilitate hydrocarbon production from a well, and subterranean fracturing (whereby the resulting fracture dimensions, directional positioning, orientation, and geometry, and the placement of a proppant within the fracture more closely resemble the desired results).
- the disclosure relates to a method of performing an oilfield operation about a wellbore penetrating a subterranean formation.
- the method involves performing a fracture operation.
- the fracture operation involves generating a plurality of fractures about the wellbore and generating a fracture network about the wellbore.
- the fracture network includes the fractures and a plurality of matrix blocks positioned thereabout. The fractures are intersecting and hydraulically connected.
- the matrix blocks are positioned about the fractures.
- the method also involves generating flow rate through the fracture network, generating a fluid distribution based on the flow rate, and performing a production operation, the production operation comprising generating a production rate from the fluid distribution.
- the disclosure relates to a method of performing an oilfield operation about a wellbore penetrating a subterranean formation.
- the method involves performing a fracture operation.
- the fracture operation involves stimulating the wellbore and generating a fracture network about the wellbore.
- the stimulating involves injecting fluid into the subterranean formation such that fractures are generated about the wellbore.
- the fracture network includes the fractures and a plurality of matrix blocks positioned thereabout.
- the fractures are intersecting and hydraulically connected.
- the plurality of matrix blocks is positioned about the fractures.
- the method also involves placing proppants in the fracture network, generating flow rate through the fracture network, generating a fluid distribution based on the flow rate, and performing a production operation.
- the production operation involves generating a production rate from the fluid distribution.
- the disclosure relates to a method of performing an oilfield operation about a wellbore penetrating a subterranean formation.
- the method involves designing a fracture operation based on job parameters and performing the fracture operation.
- the fracture operation involves generating a fracture network about the wellbore.
- the fracture network includes a plurality of fractures and a plurality of matrix blocks.
- the fractures are intersecting and hydraulically connected.
- the matrix blocks are positioned about the fractures.
- the method also involves optimizing the fracture operation by adjusting the fracture operation based on a comparison of a simulated production rate with actual data, generating flow rate through the fracture network, generating a fluid distribution based on the flow rate, and performing a production operation.
- the simulated production rate is based on the fracture network.
- the production operation involves generating a production rate from the fluid distribution.
- FIGs. 1.1-1.4 are schematic views illustrating various oilfield operations at a wellsite
- FIGs. 2.1-2.4 are schematic views of data collected by the operations of Figures 1.1-1.4;
- FIG. 3 is a pictorial illustration of geometric properties of an exemplary hydraulic fracture model in accordance with the present disclosure
- FIG. 4 is a schematic illustration of a hydraulic fracturing site that embodies the present disclosure
- Figs. 5.1 and 5.2 collectively, is a flow chart illustrating operations carried out by the hydraulic fracturing site of Fig. 4 for fracturing treatment of the illustrative treatment well in accordance with the present disclosure.
- Figs. 6.1-6.4 depict exemplary display screens for visualizing properties of the treatment well and fractured hydrocarbon reservoir during the fracturing treatment of the illustrative treatment well of Fig. 4 in accordance with the present disclosure
- Figs. 7.1-7.4 depict exemplary display screens for visualizing properties of the treatment well and fractured hydrocarbon reservoir during the fracturing treatment and during a subsequent shut-in period of the illustrative treatment well of Fig. 4 in accordance with the present disclosure
- FIGs. 8.1 - 8.3 are schematic diagrams illustrating an elliptical hydraulic fracture network about a well
- Fig. 9 is a schematic diagram depicting proppant placement
- Fig. 10 is a schematic diagram illustrating a cross-sectional view of the elliptical hydraulic fracture network of Fig. 8.1 and a detailed view of a matrix block therefrom, respectively;
- FIG. 11 is a schematic diagram illustrating fluid flow through a dual porosity medium
- Figs 12 is schematic flow diagrams depicting methods of performing production operations
- Figs. 13.1 and 13.2 are various schematic diagrams for depicting fluid flow through a medium
- Fig. 14 is a flow chart depicting a fracture design and optimization
- Fig. 15 is a flow chart depicting a post-production operation.
- Fig. 16 is a flow chart depicting a method for performing a production operation.
- the present disclosure relates to techniques for performing fracture operations to estimate and/or predict production.
- the fracture operations involve fracture modeling that utilize elliptical and wire mesh modeling to estimate production.
- Figures 1.1-1.4 depict various oilfield operations that may be performed at a wellsite, and Figures 2.1-2.4 depict various information that may be collected at the wellsite.
- Figures 1.1-1.4 depict simplified, schematic views of a representative oilfield or wellsite 100 having subsurface formation 102 containing, for example, reservoir 104 therein and depicting various oilfield operations being performed on the wellsite 100.
- FIG. 1.1 depicts a survey operation being performed by a survey tool, such as seismic truck 106.1, to measure properties of the subsurface formation.
- the survey operation may be a seismic survey operation for producing sound vibrations.
- one such sound vibration 112 generated by a source 110 reflects off a plurality of horizons 114 in an earth formation 116.
- the sound vibration(s) 112 may be received in by sensors, such as geophone -receivers 118, situated on the earth's surface, and the geophones 118 produce electrical output signals, referred to as data received 120 in FIG. 1.1.
- the geophones 118 may produce electrical output signals containing data concerning the subsurface formation.
- the data received 120 may be provided as input data to a computer 122.1 of the seismic truck 106.1, and responsive to the input data, the computer 122.1 may generate a seismic and microseismic data output 124.
- the seismic data output may be stored, transmitted or further processed as desired, for example by data reduction.
- FIG. 1.2 depicts a drilling operation being performed by a drilling tool 106.2 suspended by a rig 128 and advanced into the subsurface formations 102 to form a wellbore 136 or other channel.
- a mud pit 130 may be used to draw drilling mud into the drilling tools via flow line 132 for circulating drilling mud through the drilling tools, up the wellbore 136 and back to the surface. The drilling mud may be filtered and returned to the mud pit.
- a circulating system may be used for storing, controlling or filtering the flowing drilling muds.
- the drilling tools are advanced into the subsurface formations to reach reservoir 104. Each well may target one or more reservoirs.
- the drilling tools may be adapted for measuring downhole properties using logging while drilling tools.
- the logging while drilling tool may also be adapted for taking a core sample 133 as shown, or removed so that a core sample may be taken using another tool.
- a surface unit 134 may be used to communicate with the drilling tools and/or off site operations.
- the surface unit may communicate with the drilling tools to send commands to the drilling tools, and to receive data therefrom.
- the surface unit may be provided with computer facilities for receiving, storing, processing, and/or analyzing data from the operation.
- the surface unit may collect data generated during the drilling operation and produce data output 135 which may be stored or transmitted.
- Computer facilities, such as those of the surface unit may be positioned at various locations about the wellsite and/or at remote locations.
- Sensors (S), such as gauges, may be positioned about the oilfield to collect data relating to various operations as described previously. As shown, the sensor (S) may be positioned in one or more locations in the drilling tools and/or at the rig to measure drilling parameters, such as weight on bit, torque on bit, pressures, temperatures, flow rates, compositions, rotary speed and/or other parameters of the operation. Sensors (S) may also be positioned in one or more locations in the circulating system.
- the data gathered by the sensors may be collected by the surface unit and/or other data collection sources for analysis or other processing.
- the data collected by the sensors may be used alone or in combination with other data.
- the data may be collected in one or more databases and/or transmitted on or offsite. All or select portions of the data may be selectively used for analyzing and/or predicting operations of the current and/or other wellbores.
- the data may be may be historical data, real time data or combinations thereof.
- the real time data may be used in real time, or stored for later use.
- the data may also be combined with historical data or other inputs for further analysis.
- the data may be stored in separate databases, or combined into a single database.
- the collected data may be used to perform analysis, such as modeling operations.
- the seismic data output may be used to perform geological, geophysical, and/or reservoir engineering analysis.
- the reservoir, wellbore, surface and/or processed data may be used to perform reservoir, wellbore, geological, and geophysical or other simulations.
- the data outputs from the operation may be generated directly from the sensors, or after some preprocessing or modeling. These data outputs may act as inputs for further analysis.
- the data may be collected and stored at the surface unit 134.
- One or more surface units may be located at the wellsite, or connected remotely thereto.
- the surface unit may be a single unit, or a complex network of units used to perform the necessary data management functions throughout the oilfield.
- the surface unit may be a manual or automatic system.
- the surface unit 134 may be operated and/or adjusted by a user.
- the surface unit may be provided with a transceiver 137 to allow communications between the surface unit and various portions of the current oilfield or other locations.
- the surface unit 134 may also be provided with or functionally connected to one or more controllers for actuating mechanisms at the wellsite 100. The surface unit 134 may then send command signals to the oilfield in response to data received.
- the surface unit 134 may receive commands via the transceiver or may itself execute commands to the controller.
- a processor may be provided to analyze the data (locally or remotely), make the decisions and/or actuate the controller. In this manner, operations may be selectively adjusted based on the data collected. Portions of the operation, such as controlling drilling, weight on bit, pump rates or other parameters, may be optimized based on the information. These adjustments may be made automatically based on computer protocol, and/or manually by an operator. In some cases, well plans may be adjusted to select optimum operating conditions, or to avoid problems.
- FIG. 1.3 depicts a wireline operation being performed by a wireline tool 106.3 suspended by the rig 128 and into the wellbore 136 of FIG. 1.2.
- the wireline tool 106.3 may be adapted for deployment into a wellbore 136 for generating well logs, performing downhole tests and/or collecting samples.
- the wireline tool 106.3 may be used to provide another method and apparatus for performing a seismic survey operation.
- the wireline tool 106.3 of FIG. 1.3 may, for example, have an explosive, radioactive, electrical, or acoustic energy source 144 that sends and/or receives electrical signals to the surrounding subsurface formations 102 and fluids therein.
- the wireline tool 106.3 may be operatively connected to, for example, the geophones 118 and the computer 122.1 of the seismic truck 106.1 of FIG. 1.1.
- the wireline tool 106.3 may also provide data to the surface unit 134.
- the surface unit 134 may collect data generated during the wireline operation and produce data output 135 which may be stored or transmitted.
- the wireline tool 106.3 may be positioned at various depths in the wellbore to provide a survey or other information relating to the subsurface formation.
- Sensors (S), such as gauges, may be positioned about the wellsite 100 to collect data relating to various operations as described previously. As shown, the sensor (S) is positioned in the wireline tool 106.3 to measure downhole parameters which relate to, for example porosity, permeability, fluid composition and/or other parameters of the operation.
- FIG. 1.4 depicts a production operation being performed by a production tool 106.4 deployed from a production unit or Christmas tree 129 and into the completed wellbore 136 of FIG. 1.3 for drawing fluid from the downhole reservoirs into surface facilities 142. Fluid flows from reservoir 104 through perforations in the casing (not shown) and into the production tool 106.4 in the wellbore 136 and to the surface facilities 142 via a gathering network 146.
- Sensors (S), such as gauges, may be positioned about the oilfield to collect data relating to various operations as described previously. As shown, the sensor (S) may be positioned in the production tool 106.4 or associated equipment, such as the Christmas tree 129, gathering network, surface facilities and/or the production facility, to measure fluid parameters, such as fluid composition, flow rates, pressures, temperatures, and/or other parameters of the production operation.
- fluid parameters such as fluid composition, flow rates, pressures, temperatures, and/or other parameters of the production operation.
- oilfield or wellsite 100 may cover a portion of land, sea and/or water locations that hosts one or more wellsites. Production may also include injection wells (not shown) for added recovery or for storage of hydrocarbons, carbon dioxide, or water, for example.
- One or more gathering facilities may be operatively connected to one or more of the wellsites for selectively collecting downhole fluids from the wellsite(s).
- FIGS. 1.2-1.4 depict tools that can be used to measure not only properties of an oilfield, but also properties of non-oilfield operations, such as mines, aquifers, storage, and other subsurface facilities.
- various measurement tools e.g., wireline, measurement while drilling (MWD), logging while drilling (LWD), core sample, etc.
- MWD measurement while drilling
- LWD logging while drilling
- core sample e.g., core sample, etc.
- Various sensors (S) may be located at various positions along the wellbore and/or the monitoring tools to collect and/or monitor the desired data. Other sources of data may also be provided from offsite locations.
- FIGS. 1.1-1.4 depict examples of a wellsite 100 and various operations usable with the techniques provided herein. Part, or all, of the oilfield may be on land, water and/or sea. Also, while a single oilfield measured at a single location is depicted, reservoir engineering may be utilized with any combination of one or more oilfields, one or more processing facilities, and one or more wellsites.
- FIGS. 2.1-2.4 are graphical depictions of examples of data collected by the tools of FIGS. 1.1-1.4, respectively.
- FIG. 2.1 depicts a seismic trace 202 of the subsurface formation of FIG. 1.1 taken by seismic truck 106.1. The seismic trace may be used to provide data, such as a two-way response over a period of time.
- FIG. 2.2 depicts a core sample 133 taken by the drilling tools 106.2. The core sample may be used to provide data, such as a graph of the density, porosity, permeability or other physical property of the core sample over the length of the core. Tests for density and viscosity may be performed on the fluids in the core at varying pressures and temperatures.
- FIG. 2.1 depicts a seismic trace 202 of the subsurface formation of FIG. 1.1 taken by seismic truck 106.1. The seismic trace may be used to provide data, such as a two-way response over a period of time.
- FIG. 2.2 depicts a core sample 133 taken by the drilling tools 106.2
- FIG. 2.3 depicts a well log 204 of the subsurface formation of FIG. 1.3 taken by the wireline tool 106.3.
- the wireline log may provide a resistivity or other measurement of the formation at various depts.
- FIG. 2.4 depicts a production decline curve or graph 206 of fluid flowing through the subsurface formation of FIG. 1.4 measured at the surface facilities 142.
- the production decline curve may provide the production rate Q as a function of time t.
- the respective graphs of FIGS. 2.1, 2.3, and 2.4 depict examples of static measurements that may describe or provide information about the physical characteristics of the formation and reservoirs contained therein. These measurements may be analyzed to define properties of the formation(s), to determine the accuracy of the measurements and/or to check for errors. The plots of each of the respective measurements may be aligned and scaled for comparison and verification of the properties.
- FIG. 2.4 depicts an example of a dynamic measurement of the fluid properties through the wellbore.
- measurements are taken of fluid properties, such as flow rates, pressures, composition, etc.
- the static and dynamic measurements may be analyzed and used to generate models of the subsurface formation to determine characteristics thereof. Similar measurements may also be used to measure changes in formation aspects over time.
- these techniques employ a model for characterizing a hydraulic fracture network as described below.
- a model includes a set of equations that quantify the complex physical process of fracture propagation in a formation driven by fluid injected through a wellbore.
- these equations are posed in terms of 12 model parameters: wellbore radius xw and wellbore net pressure pw-oc, fluid injection rate q and duration tp, matrix plane strain modulus E, fluid viscosity ⁇ (or other fluid flow parameter(s) for non- Newtonian fluids), confining stress contrast ⁇ , fracture network sizes h, a, e, and fracture spacing dx and dy.
- Various fracture networks as used herein may have natural and/or man-made fractures.
- the wellbore may be stimulated by performing fracture operations.
- a hydraulic fracture network can be produced by pumping fluid into a formation.
- a hydraulic fracture network can be represented by two perpendicular sets of parallel planar fractures. The fractures parallel to the x-axis may be equally separated by distance dy and those parallel to the y-axis are separated by distance dx as illustrated in Figure 3. Consequently, the numbers of fractures, per unit length, parallel to the x-axis and the y-axis, respectively, are
- the pumping of fracturing fluid over time produces a propagating fracture network that can be represented by an expanding volume in the form of an ellipse with height h, major axis a, minor axis b or aspect ratio
- p is the density of injected fluid
- the average fluid velocity v e may be approximated as
- k x and k y are permeability factors for the formation along the jc-direction and the _ -direction, respectively.
- equations below are presented for an incompressible fluid as an example, with the understanding that fluid compressibility may be accounted for by using a corresponding equation of state for the injected fluid.
- the width w of a hydraulic fracture may be calculated as
- H is the Heaviside step function
- a c is the confining stress perpendicular to the fracture
- E is the plane strain modulus of the formation
- h and d are the height and the length, respectively, of the fracture segment.
- ⁇ cx and ⁇ cy are the confining stresses, respectively, along the x-direction and the y- direction, respectively, and A ⁇ x and A Ey are the coefficients for defining the effective plane strain modulus along the x-axis and -axis, respectively.
- l x and l y are the characteristic length scale along the x-axis and the y-axis , respectively.
- the fracture permeability along the x-axis (k x ) and the fracture permeability along the y-axis (k y ) can be determined as
- Equation (7b) can be integrated from x w to y using equation (12b) for the permeability (k y ) to yield
- x w is the radius of the wellbore and q is the rate of fluid injection into the formation via the wellbore.
- the inject rate q is treated as a constant and quantified in volume per unit time per unit length of the wellbore.
- Equation (14a) can be integrated from x to a and yields a solution for the net pressure inside the fracture along the x-axis as
- Equation (14b) can be integrated from y to b yields a solution for the net pressure inside the fractures along the as
- the time tp for the ellipse edge propagating from xw to a along the x-axis and xw to b along the y-axis is determined as
- x ⁇ is defined as x w ⁇ x ⁇ ⁇ ⁇
- Equation (15a) can be rewritten for the case as follows
- the surface area of the open fractures may be calculated as follows
- equations (25a), (26) and (27) can be solved to obtain any three of the model parameters.
- Certain geometric and geomechanical parameters of the model as described above can be constrained using field data from a fracturing treatment and associated microseismic events.
- the geometric properties (dx and dy) and the stress contrast are constrained given wellbore radius xw and wellbore net pressure pw-oc, fluid injection rate q and duration tp, matrix plane strain modulus E, fluid viscosity ⁇ , and fracture network sizes h, a, e, as follows. Note that since ⁇ in equation (27) is calculated using equation (28) as a function of Aoc, the solution procedure is necessarily of an iterative nature.
- Equations (26) and (27) become, respectively.
- equations (31) and (32) can be solved to obtain
- equation (36) can be solved for d x .
- Aa c can then be calculated using equation (35).
- equation (29) leads to solution (30). Furthermore, if , equations (26) and (27) lead to solutions (33) and (34). On the other hand, if
- equations (26) and (27) lead to equations (35) and (36).
- equations (26) and (27) become, respectively,
- Equation (38) can be solved for d x and then Aa c can be calculated by equation (37).
- Equation (26) and (27) becomes, respectively.
- Equation (41) can be solved for d x and then Aa c can be calculated by equation (40).
- Equations (42), (43) and (44) can be solved for d x , d y and Aa c .
- equation (29) leads to solution (39) while equations (26) and (27) become equations (40) and (41), respectively.
- the fracture network may consist of a number of parallel equally-spaced planar fractures whose spacing d is usually smaller than fracture height h. In other cases, the opposite is true. Both can lead to significant simplifications.
- An example is presented below. 2. SIMPLIFICATION OF MODEL FOR PARALLEL EQUALLY-SPACED PLANAR FRACTURES WHOSE SPACING DX AND DY ARE SMALLER THAN FRACTURE HEIGHT H
- equations (11a) and (l ib) can be simplified as
- Equations (50a) and (50b) can be used to simplify equations (10a) and (10b) as follows
- Equations (50a) and (50b) can also be used to simplify equation (12) as follows
- Equations (50a and (50b) can be used to simplify equations (13a) and (13b) as follows
- equations (51a) and (51b) become
- equations (53a) and (53b) become
- Equation (60a) can be solved for d as follows
- Equations (61), (63) and (64) can be solved iteratively for d x and Aa c .
- equations (51a) and (51b) become
- equations (53a) and (53b) become
- Equations (70), (71), (72) and (73) can be combined and solved iteratively for d x , d y and Aa c .
- equations (51a) and (51b) become
- equations (53a) and (53b) become
- Equations (79), (80), (81) and (82) can be combined and solved iteratively for d x , d y and Aa c .
- FIG 3 illustrates an exemplary operational setting for hydraulic fracturing of a subterranean formation (referred to herein as a "fracture site") in accordance with the present disclosure.
- the fracture site 400 can be located on land or in a water environment and includes a treatment well 401 extending into a subterranean formation as well as a monitoring well 403 extending into the subterranean formation and offset from the treatment well 401.
- the monitoring well 403 includes an array of geophone receivers 405 (e.g., three-component geophones) spaced therein as shown.
- microseismic events 410 which emit both compressional waves (also referred to as primary waves or P-waves) and shear waves (also referred to as secondary waves or S-waves) that propagate through the earth and are recorded by the geophone receiver array 405 of the monitoring well 403.
- the distance to the microseismic events 410 can be calculated by measuring the difference in arrival times between the P-waves and the S-waves.
- hodogram analysis which examines the particle motion of the P-waves, can be used to determine azimuth angle to the event.
- the depth of the event 410 is constrained by using the P- and S-wave arrival delays between receivers of the array 405.
- the distance, azimuth angle and depth values of such microseismic events 410 can be used to derive a geometric boundary or profile of the fracturing caused by the fracturing fluid over time, such as an elliptical boundary defined by a height h, elliptic aspect ratio e and major axis a as illustrated in Figure 3.
- the site 401 also includes a supply of fracturing fluid and pumping means (not shown) for supplying fracturing fluid under high pressure to the treatment well 401.
- the fracturing fluid can be stored with proppant (and possibly other special ingredients) pre-mixed therein.
- the fracturing fluid can be stored without pre-mixed proppant or other special ingredients, and the proppant (and/or other special ingredients) mixed into the fracturing fluid in a controlled manner by a process control system as described in U.S. Patent No. 7,516,793, herein incorporated by reference in its entirety.
- the treatment well 401 also includes a flow sensor S as schematically depicted for measuring the pumping rate of the fracturing fluid supplied to the treatment well and a downhole pressure sensor for measuring the downhole pressure of the fracturing fluid in the treatment well 401.
- a data processing system 409 is linked to the receivers of the array 405 of the monitoring well 403 and to the sensor S (e.g., flow sensor and downhole pressure sensor) of the treatment well 401.
- the data processing system 409 may be incorporated into and/or work with the surface unit 134.
- the data processing system 409 carries out the processing set forth in Figure 5 and described herein.
- the data processing system 409 includes data processing functionality (e.g., one or more microprocessors, associated memory, and other hardware and/or software) to implement the disclosure as described herein.
- the data processing system 409 can be realized by a workstation or other suitable data processing system located at the site 401.
- the data processing system 409 can be realized by a distributed data processing system wherein data is communicated (preferably in real time) over a communication link (typically a satellite link) to a remote location for data analysis as described herein.
- the data analysis can be carried out on a workstation or other suitable data processing system (such as a computer cluster or computing grid).
- the data processing functionality of the present disclosure can be stored on a program storage device (e.g., one or more optical disks or other hand-holdable non-volatile storage apparatus, or a server accessible over a network) and loaded onto a suitable data processing system as needed for execution thereon as described herein.
- a program storage device e.g., one or more optical disks or other hand-holdable non-volatile storage apparatus, or a server accessible over a network
- the data processing system 409 stores (or inputs from suitable measurement means) parameters used in subsequent processing, including the plain strain modulus E (Young's modulus) of the hydrocarbon reservoir 407 that is being fractured as well as the fluid viscosity ( ⁇ ) of the fracturing fluid that is being supplied to the treatment well 401 and the radius (xw) of the treatment wellbore.
- E plain strain modulus
- ⁇ fluid viscosity
- xw radius
- steps 503-511 the data processing system 409 is controlled to operate for successive periods of time (each denoted as At) that fracturing fluid is supplied to the treatment well 401.
- step 505 the data processing system 409 processes the acoustic signals captured by the receiver array 405 over the period of time At to derive the distance, azimuth angle and depth for the microseismic events produced by fracturing of the hydrocarbon reservoir 407 over the period of time At.
- the distance, azimuth and depth values of the microseismic events are processed to derive an elliptical boundary characterizing the profile of the fracturing caused by the fracturing fluid over time.
- the elliptical boundary is defined by a height h, elliptic aspect ratio e and major axis a as illustrated in Figure 3.
- the data processing system 409 obtains the flow rate q, which is the pumping rate divided by the height of the elliptic fractured formation, of the fracturing fluid supplied to the treatment well for the period of time At, and derives the net downhole pressure pw-oc of the fracturing fluid at the end of the period of time At.
- the wellbore net pressure pw-oc can be obtained from the injection pressure of the fracturing fluid at the surface according to the following:
- p sur face is the injection pressure of the fracturing fluid at the surface
- BHTP is the bottom hole treating pressure
- p P i pe is the friction pressure of the tubing or casing of the treatment well while the fracturing fluid is being injected into the treatment well; this friction pressure depends on the type and viscosity of the fracturing fluid, the size of the pipe and the injection rate;
- p pei f is the friction pressure through the perforations of the treatment well that provide for injection of the fracturing fluid into the reservoir; and phydrostatic is the hydrostatic pressure due to density of the fracturing fluid column in the treatment well.
- the wellbore net pressure p w - ⁇ J c can also be derived from BHTP at the beginning of treatment and the injection pressure p SU rf ace at the beginning of the shut-in period.
- the wellbore net pressure p w -(7 c at the end of treatment can be calculated by plugging these values into equation (83) while neglecting both friction pressures p pipe and p per f , which are zero during the shut-in period.
- the data processing system 409 utilizes the parameters (E, ⁇ , xw) stored in 501, the parameters (h, e and a) defining the elliptical boundary of the fracturing as generated in step 505, and the flow rate q, the pumping period tp and the net downhole pressure pw-oc as generated in step 507 in conjunction with a model for characterizing a hydraulic fracture network as described herein to solve for relevant geometric properties that characterize the hydraulic fracture network at the end of the time period At, such as parameters dx and dy and the stress contrast Aoc as set forth above.
- step 511 the geometric and geomechanical properties (e.g., dx, dy, Aac) that characterize the hydraulic fracture network as generated in step 509 are used in conjunction with a model as described herein to generate data that quantifies and simulates propagation of the fracture network as a function of time and space, such as width w of the hydraulic fractures from equations (10a) and (10b) and the times needed for the front and tail of the fracturing formation, as indicated by the distribution of induced microseismic events, to reach certain distances from equation (19).
- a model as described herein to generate data that quantifies and simulates propagation of the fracture network as a function of time and space, such as width w of the hydraulic fractures from equations (10a) and (10b) and the times needed for the front and tail of the fracturing formation, as indicated by the distribution of induced microseismic events, to reach certain distances from equation (19).
- the geometric and geomechanical properties generated in step 509 can also be used in conjunction with the model to derive data characterizing the fractured hydrocarbon reservoir at the time period tp, such as net pressure of fracturing fluid in the treatment well (from equations (17a) and (17b), or (25a) and (25b)), net pressure inside the fractures (from equations (17a) and (17b), or (25a) and (25b)), net pressure inside the fractures (from equations
- the data generated in step 511 is used for real-time visualization of the fracturing process and/or optimization of the fracturing plan.
- Various treatment scenarios may be examined using the forward modeling procedure described below.
- Exemplary display screens for real-time visualization of net pressure change of fracturing fluid in the treatment well along the x-axis, fracture width w along the x-axis, changes in porosity and permeability along the x-axis are illustrated in Figures 6.1 - 6.4.
- step 515 it is determined if the processing has been completed for the last fracturing time period. If not, the operations return to step 503 to repeat the operations of step 505-513 for the next fracturing time period. If so, the operations continue to step 517.
- step 517 the model as described herein is used to generate data that quantifies and simulates propagation of the fracture network as a function of time and space during the shut-in period, such as width w of hydraulic fractures and the distance of the front and tail of the fracturing formation over time.
- the model can also be used to derive data characterizing the fractured hydrocarbon reservoir during the shut-in period, such as net pressure of fracturing fluid in the treatment well (from equations (17a) and (17b), or (25a) and (25b)), net pressure inside the fractures (from equations (16a) and (16b), or (24a) and (24b)), change in fracture porosity ( ⁇ from equation 12), and change in fracture permeability (kx and ky from equations (13a) and (13b)).
- net pressure of fracturing fluid in the treatment well from equations (17a) and (17b), or (25a) and (25b)
- net pressure inside the fractures from equations (16a) and (16b), or (24a) and (24b)
- change in fracture porosity ⁇ from equation 12
- change in fracture permeability kx and ky from equations (13a) and (13b)
- step 519 the data generated in step 511 and/or the data generated in step 517 is used for real-time visualization of the fracturing process and/or shut-in period after fracturing and/or optimization of the fracture plan.
- Figures 7.1-7.4 illustrate exemplary display screens for real-time visualization of net pressure of fracturing fluid in the treatment well as a function of time during the fracturing process and then during shut-in (which begins at the time of 4 hours), net pressure inside the fractures as a function of distance at a time at the end of fracturing and at a time during shut-in, the distance of the front and tail of the fracturing formation over time during the fracturing process and then during shut-in, fracture width as a function of distance at a time at the end of fracturing and at a time during shut-in, respectively.
- the circles of Figure 7.3 represent locations of microseismic events as a function of time and distance away from the treatment well during the fracturing process and then during shut-in.
- the hydraulic fracture model and fracturing process based thereon constrains geometric and geomechanical properties of the hydraulic fractures of the subterranean formation using the field data to reduce the complexity of the fracture model and the processing resources and time required to provide characterization of the hydraulic fractures of the subterranean formation.
- Such characterization can be generated in real-time to manually or automatically manipulate surface and/or down-hole physical components supplying fracturing fluids to the subterranean formation to adjust the hydraulic fracturing process as desired, such as by optimizing fracturing plan for the site (or for other similar fracturing sites).
- these techniques employ fracture models for determining production estimates. Such estimations may be made, for example, by applying the HFN modeling techniques, such as those using a wiremesh HFN model with an elliptical structure, to production modeling. These techniques may be used in cases with multiple or complex fractures, such as shale or tight-sand gas reservoirs. Such models may use, for example, an arbitrarily time- dependent fluid pressure along hydraulic fractures. Corresponding analytical solutions may be expressed in the time-space domain. Such solutions may be used in high speed applications for hydraulic fracturing stimulation job design, optimization or post-job analysis.
- These techniques employ an analytical approach that provides a means to forecast production from reservoirs, such as shale reservoirs, using an HFN of elliptic form.
- Such forecasts may involve the use of analytical models for forecasting or analyzing production from oil and gas reservoirs with imbedded hydraulic fractures.
- the forecasting models may be empirical or analytical in nature.
- Empirical forecasts may involve an estimate of well production using various types of curves with adjustable parameters for different flow regimes separately during a reservoir's lifespan.
- the analytical approach may involve obtaining pressure or production rate solutions by solving partial differential equations describing gas flow in the reservoir formation and through the fractures.
- Laplace transform and numerical inversion may be used.
- Laplace transformation may be used to obtain asymptotic solutions for early and late production periods, respectively, from a horizontally radial reservoir subject to either a constant pressure drop or a constant production rate at the wellbore.
- the ordinary differential equations in the Laplace domain may be solved using Green's and point source functions, and then transforming the solutions back to the time-space domain through a numerical inversion to study production from horizontal wells with multiple transverse fractures.
- the analytical approach may also involve using the time-space domain.
- FIGS 8.1 - 8.3 depict alternate views of HFN models 800.1, 800.2 and 800.3, respectively, usable for hydraulic fracture modeling.
- the HFN models may be created using the HFN techniques described above.
- Application of the disclosed models to hydraulic fracturing stimulation job design and post-job analysis is described using wiremesh HFN models 800.1,800.2,800.3 as an example.
- These figures each depict a wellbore 820 with a hydraulic fracture network (HFN) 822 thereabout.
- HFN hydraulic fracture network
- the HFN 822 is an elliptical structure with a plurality of vertical fractures 824 perpendicular to another a plurality of vertical fractures 826 forming a wiremesh configuration.
- the plurality of vertical fractures define a plurality of matrix blocks 828 of the HFN 822.
- the HFN 822 is a complex fracture network having a plurality of intersecting fractures 824 and 826 that are hydraulically connected for fluid flow therebetween.
- the intersecting fractures may be generated by fracturing of the formation. Fractures as used herein may be natural and/or man made.
- the HFN 822 has a height h along a minor diameter, a radius b along its minor axis and aligned with the wellbore 820, and a radius a along its major axis. Some of the dimensions of the HFN are also shown in Figure 3.
- Figures 8.1-8.3 depict complex HFN models 800.1, 800.2, 800.3, the models may also be used with reservoirs having single or parallel hydraulic fractures. Also, while the wellbore 820 is depicted as passing through the HFN 822 parallel to the vertical lines, the HFN 822 may be oriented as desired about the wellbore 820. Application of the disclosed models to hydraulic fracturing stimulation job design and post-job analysis is described using a wiremesh HFN 822 as an example. Application to reservoirs with single or parallel hydraulic fractures or a fracture network of non-elliptic shape can be done in a similar manner, but adjusted as needed to a comparably simpler or more complicated configuration.
- Figures 8.1-8.3, may be used to quantify production from the HFN.
- One or more types of proppant may be injected with an injection or treatment fluid during stimulation to keep the hydraulic fractures open after a fracturing job is done.
- Figures 9 and 10 depict views of proppant placement about an HFN and fractures of an HFN, respectively.
- Figure 9 shows a cross- sectional view of the HFN 822 of Figure 8.2 taken along line 9-9.
- proppant 823 is positioned in wellbore 820, and extends horizontally through the wellbore 820 along a major fracture and into the surrounding formation.
- the proppant 823 may transport in different transport patterns 827, 829.
- FIG. 10 is picture of a fracture 827 with proppant extending therein. Fluid flows through the fracture 827 from the left to the right. The proppant 823 is carried by the fluid 827, but settles on the left side of the fracture as it travels from left to right. The proppant 827 as depicted entering a left portion of the fracture 827 as indicated by the lighter shaded regions.
- the flow of proppant through an HFN may be defined by an analysis of transport of the proppant.
- N types of proppant particles each with volume fraction V p the total proppant volume fraction is
- proppant type i is transported in all directions by the transport pattern 825. This can be mathematically described by the following:
- Hindering factors may account for effects of fracture width, proppant size & concentration, fiber, flow regime, etc. Proppant movement may be further hindered by other factors such as fluid flow regime and the presence of fiber.
- FIG. 11 shows the HFN 822 taken along line 9-9. As shown in this view, the
- HFN 822 is depicted as having a plurality of concentric ellipses 930 and a plurality of radial flow lines 932.
- the radial flow lines 932 initiate from a central location about the wellbore 820 and extend radially therefrom.
- the radial flow lines 932 represent a flow path of fluid from the formation surrounding the wellbore 820 and to the wellbore 820 as indicated by the arrows.
- the HFN 822 may also be represented in the format as shown in Fig. 3.
- HFN 822 global gas flow through the reservoir consisting of both the HFN 822 and the formation matrix can be separated into the gas flow through the HFN 822 and that inside of the matrix blocks 828.
- the pattern of gas flow through the HFN 822 may be described approximately as elliptical as shown in Figure 11.
- the HFN 822 uses an elliptical configuration to provide a coupling between the matrix and HFN flows that is treated explicitly.
- a partial differential equation is used to describe fluid flow inside a matrix block that is solved analytically.
- Three-dimensional gas flow through an elliptic wiremesh HFN can be approximately described by:
- t time
- x is the coordinate aligned with the major axis of the ellipse
- p and p are fluid pressure and density of fluid
- rq are the porosity and the -component of the pressure diffusivity of the HFN
- q g is the rate of gas flow from the matrix into the HFN. All involved properties may be a function of either t or x or both.
- equation (94) there are various ways available to solve equation (94), either analytically or numerically. Due to the complex nature of the HFN and fluid properties, numerical approaches may be used for the sake of accuracy. An example of numerical solution is given below.
- a x t and A y t are the total surface area of the fractures inside of the ring, parallel to the major axis (the -axis) and the minor axis (the y-axis), respectively, and q gx k and q ⁇ are the corresponding rates of fluid flow per unit fracture surface area from the matrix into the fractures parallel to the x- and y-axis, respectively.
- Fluid pressure p and the rate of gas production at the wellborn can be obtained by numerically (either finite difference, finite volume or a similar method) solving equation (94) for any user specified initial and boundary conditions and by coupling the model with a wellbore fluid flow model.
- Total surface area of fractures contained inside of the k-th ring can be calculated by
- N xo and N x i are the number of fractures parallel to and at either side of the -axis inside the outer and the inner boundaries, respectively, of the k- th ring
- N yo and N y i are the number of fractures parallel to and at either side of the y-axis inside the outer and the inner boundaries, respectively, of the k-t ring.
- FIG. 12 is a detailed view of one of the blocks 828 of HFN 822 of Figure 11. As shown in this view, the direction of gas flow inside of a matrix block 828 can be approximated as perpendicular to the edges of the matrix block 828. Fluid flow is assumed to be linear flow toward outer boundaries 1240 of the block 828 as indicated by the arrows, with no flow boundaries 1242 positioned within the block 828.
- Fluid flow inside a rectangular matrix block 828 can be approximately described by
- Equation (97) can be solved to obtain the rate of fluid flow from the matrix into the fractures inside the k-t ring
- ⁇ ⁇ is the pressure of the fluid residing in fractures in the fc-th ring and p m is the density of the fluid residing in the matrix.
- the coupling of ⁇ ⁇ and q gk calculations can be either explicit or implicit. It may be implicit for the first time step even if the rest of the time is explicit.
- the wiremesh fracturing model may be applied to generate an HFN and associated proppant placement using reservoir formation properties and fracturing job parameters as the input.
- the result including the geometry of the fracture network and individual fractures and proppant distribution along the fractures can be used as part of the input for production simulation using the wiremesh production model described above.
- hydraulic fracturing software such as MANGROVETM software commercially available from Schlumberger Technology Corporation (see:www.slb.com) may be used to produce an HFN with the information needed for production calculations.
- Production from the HFN can be calculated using the models described above. Production rates calculated for various designs may then be compared and analyzed in combination with other economic, environmental and logistic considerations. The job parameters can then be adjusted accordingly for a better design. The best design for each of the stages may be chosen for the job.
- Figure 14 depicts an example fracture operation 1400 involving fracture design and optimization.
- the fracture operation 1400 includes 1430 - obtaining job parameters relating to formation parameters (e.g., dimensions, stresses, etc.) and 1432 - obtaining job parameters relating to stimulation parameters, such as pumping (e.g., flow rate, time), fluid (e.g., viscosity, density) and proppant parameters (e.g., dimension, material).
- the fracture operation 1400 also includes 1434 - generating plots of formation parameters 1436 (e.g, slurry rate and proppant concentration over time) from the obtained parameters.
- a wiremesh HFN and proppant placement simulation 1438 may be performed to model the HFN based on the plots 1436 and obtained parameters 1430, 1432. Visualization 1440.1 of an HFN 822 and its proppant placement 1440.2 may be generated. A wiremesh production simulation 1442 may then be performed. An analysis 1444 of the simulation, for example, by comparison of actual with simulated results to evaluate the fracture operation 1400. If satisfied, a production operation may be executed 1446. If not, job design may be analyzed 1448, and adjustments to one or more of the job parameters may be made 1450. The fracture operation may then be repeated.
- Reservoir properties and hydraulic fracturing treatment data can be used to obtain information about the created HFN, such as fracture spacing d x and d y and stress anisotropy ⁇ , by matching the modeled HFN with a cloud of microseismic events recorded during the job.
- the techniques for hydraulic fracture modeling as described with respect to Figures 3-7 may be used to simulate the growth and proppant placement of the HFN.
- Figure 15 depicts an example of a post-fracture operation 1500.
- the post-fracture operation involves 1550 - obtaining job parameters, such a formation, microseismic, fluid/proppant and other data.
- wellsite parameters such as formation, job, microseismic and other data
- Proppant data may also be determined 1554 from the job parameters.
- the wellsite parameters may be used to characterize a wiremesh HFN 1556.
- the wiremesh HFN can be configured in an elliptical configuration 1558.
- the HFN parameters e.g., matrix and ellipse dimensions
- the HFN parameters e.g., dimensions, stresses
- the proppant parameters may be used to define the HFN model as shown in visualization 1562.1, and proppant placement as shown in the visualization 1562.2.
- a wiremesh production simulation 1564 may then be performed based on the
- An analysis 1566 of the simulation may be performed, for example, by comparison of actual with simulated results to evaluate the fracture operation 1400. If satisfied, a production operation may be executed 1446. If not, job design may be analyzed 1448, and adjustments to one or more of the job parameters may be made 1450. The fracture operation may then be repeated.
- Figure 16 illustrates a method 1600 of performing a production operation.
- This method 1600 depicts how the models and solutions are applied to a wiremesh HFN obtained by hydraulic fracturing modeling.
- the method involves performing a fracture operation 1660.
- the fracture operation involves 1662 - designing a fracture operation, 1664 - optimizing a fracture operation, 1667 - generating fractures by injecting fluid into the formation, 1668 - measuring job parameters, and 1670 - performing a post- fracture operation.
- the method also involves 1672 - generating a fracture network about the wellbore.
- the fracture network includes a plurality of the fractures and a plurality of matrix blocks. The fractures are intersecting and hydraulically connected, and the plurality of matrix blocks are positioned about the intersecting fractures.
- the method also involves 1674 - placing proppants in the elliptical hydraulic fracture network, 1676 -generating a fluid distribution through the hydraulic fracture network, 1678 - performing a production operation, the production operation comprising generating a production rate from the fluid pressure distribution, and 1680 - repeating over time. Part or all of the method may be performed in any order and repeated as desired.
- a concentration range listed or described as being useful, suitable, or the like is intended that any and every concentration within the range, including the end points, is to be considered as having been stated.
- a range of from 1 to 10 is to be read as indicating each and every possible number along the continuum between about 1 and about 10.
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Abstract
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Priority Applications (7)
Application Number | Priority Date | Filing Date | Title |
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US14/126,209 US20140151033A1 (en) | 2011-07-28 | 2012-07-30 | System and method for performing wellbore fracture operations |
CN201280047792.7A CN103857876A (en) | 2011-07-28 | 2012-07-30 | System and method for performing wellbore fracture operations |
RU2014107705/03A RU2014107705A (en) | 2011-07-28 | 2012-07-30 | SYSTEM AND METHOD FOR PERFORMING OPERATIONS OF A GAP IN A WELL |
MX2014000772A MX2014000772A (en) | 2011-07-28 | 2012-07-30 | System and method for performing wellbore fracture operations. |
GB1401193.6A GB2506805A (en) | 2011-07-28 | 2012-07-30 | System and method for performing wellbore fracture operations |
CA2843051A CA2843051A1 (en) | 2011-07-28 | 2012-07-30 | System and method for performing wellbore fracture operations |
US14/845,783 US10060241B2 (en) | 2009-06-05 | 2015-09-04 | Method for performing wellbore fracture operations using fluid temperature predictions |
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US61/574,130 | 2011-07-28 |
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Also Published As
Publication number | Publication date |
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WO2013016734A8 (en) | 2014-02-13 |
CA2843051A1 (en) | 2013-01-31 |
US20140151033A1 (en) | 2014-06-05 |
GB2506805A (en) | 2014-04-09 |
MX2014000772A (en) | 2014-05-01 |
GB201401193D0 (en) | 2014-03-12 |
RU2014107705A (en) | 2015-09-10 |
CN103857876A (en) | 2014-06-11 |
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