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WO2013003051A3 - Silane terminated polycarbonate-polyester copolymers for coating, adhesives, sealant and elastomer applications - Google Patents

Silane terminated polycarbonate-polyester copolymers for coating, adhesives, sealant and elastomer applications Download PDF

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Publication number
WO2013003051A3
WO2013003051A3 PCT/US2012/042357 US2012042357W WO2013003051A3 WO 2013003051 A3 WO2013003051 A3 WO 2013003051A3 US 2012042357 W US2012042357 W US 2012042357W WO 2013003051 A3 WO2013003051 A3 WO 2013003051A3
Authority
WO
WIPO (PCT)
Prior art keywords
polymer
sealant
adhesives
coating
reaction product
Prior art date
Application number
PCT/US2012/042357
Other languages
French (fr)
Other versions
WO2013003051A2 (en
Inventor
Kamesh R. VYAKARANAM
Harpreet Singh
Ling Zhang
William H. HEATH
Amarnath SINGH
William A. Koonce
Original Assignee
Dow Global Technologies Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Global Technologies Llc filed Critical Dow Global Technologies Llc
Publication of WO2013003051A2 publication Critical patent/WO2013003051A2/en
Publication of WO2013003051A3 publication Critical patent/WO2013003051A3/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/64—Polyesters containing both carboxylic ester groups and carbonate groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/44—Polycarbonates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/80—Masked polyisocyanates
    • C08G18/8061—Masked polyisocyanates masked with compounds having only one group containing active hydrogen
    • C08G18/8083—Masked polyisocyanates masked with compounds having only one group containing active hydrogen with compounds containing at least one heteroatom other than oxygen or nitrogen
    • C08G18/809—Masked polyisocyanates masked with compounds having only one group containing active hydrogen with compounds containing at least one heteroatom other than oxygen or nitrogen containing silicon
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/68—Polyesters containing atoms other than carbon, hydrogen and oxygen
    • C08G63/695—Polyesters containing atoms other than carbon, hydrogen and oxygen containing silicon
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/91—Polymers modified by chemical after-treatment
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D169/00—Coating compositions based on polycarbonates; Coating compositions based on derivatives of polycarbonates
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04—Polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J169/00—Adhesives based on polycarbonates; Adhesives based on derivatives of polycarbonates
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J175/00—Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
    • C09J175/04—Polyurethanes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • General Chemical & Material Sciences (AREA)
  • Polyurethanes Or Polyureas (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Sealing Material Composition (AREA)

Abstract

Crosslinkable silyl group-containing polymers that may be made using polycarbonate-polyester copolymer polyols and methods for making the same are provided. The crosslinkable silane-terminated polymer is the reaction product of a polycarbonate-polyester copolymer polyol and an isocyanate capped hydrosilylated polymer. The isocyanate capped hydrosilylated polymer is the reaction product of at least one isocyanate and a hydrosilylated polymer. The hydrosilylated polymer is the reaction product of a polymer having at least one unsaturated group and at least one alcohol hydroxyl group in each molecule and a compound having a hydrogen-silicon bond and a crosslinkable silyl group in each molecule. The crosslinkable silane-terminated polymer exhibits improved viscosity properties, UV stability and weatherability.
PCT/US2012/042357 2011-06-30 2012-06-14 Silane terminated polycarbonate-polyester copolymers for coating, adhesives, sealant and elastomer applications WO2013003051A2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201161503525P 2011-06-30 2011-06-30
US61/503,525 2011-06-30

Publications (2)

Publication Number Publication Date
WO2013003051A2 WO2013003051A2 (en) 2013-01-03
WO2013003051A3 true WO2013003051A3 (en) 2013-06-06

Family

ID=46395723

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2012/042357 WO2013003051A2 (en) 2011-06-30 2012-06-14 Silane terminated polycarbonate-polyester copolymers for coating, adhesives, sealant and elastomer applications

Country Status (1)

Country Link
WO (1) WO2013003051A2 (en)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP6993345B2 (en) * 2016-03-10 2022-01-13 モメンティブ パフォーマンス マテリアルズ インコーポレイテッド Moisture-curable silylated resin derived from polycarbonate diol and coatings, sealants and adhesive compositions containing it.
JP7197518B2 (en) * 2017-06-26 2022-12-27 ダウ シリコーンズ コーポレーション Silicone polyether copolymers, isocyanate-functional silicone polyether copolymers formed therefrom, silicone polyether urethane copolymers, sealants containing them, and related methods
CN108068176B (en) * 2017-12-26 2020-09-08 芜湖市长江起重设备制造有限公司 Preparation method of high-temperature-resistant polycarbonate type waterborne polyurethane-based plywood
JP7076644B2 (en) 2018-12-21 2022-05-27 ダウ シリコーンズ コーポレーション Silicone-polyester copolymers, sealants containing them, and related methods
US11760841B2 (en) 2018-12-21 2023-09-19 Dow Silicones Corporation Silicone-polycarbonate copolymer, sealants comprising same, and related methods
JP7469310B2 (en) 2018-12-21 2024-04-16 ダウ シリコーンズ コーポレーション Silicone-organic copolymers, sealants containing same, and related methods
CN110862797A (en) * 2019-11-01 2020-03-06 上海应用技术大学 Silane-terminated polyether sealant and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20020013427A1 (en) * 2000-04-12 2002-01-31 Ryotaro Tsuji Method of producing crosslinkable silyl group-containing polyoxyalkylene polymers
JP2003246830A (en) * 2002-02-25 2003-09-05 Dainippon Ink & Chem Inc Solvent-free, moisture-curable hot-melt urethane resin composition excellent in durability, foam, and sheet structure using the same
JP2009235257A (en) * 2008-03-27 2009-10-15 Konishi Co Ltd Aqueous silylated urethane-based resin composition
WO2012003187A1 (en) * 2010-06-30 2012-01-05 Dow Global Technologies Llc Silyl-terminated polymers

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4633021A (en) 1985-11-29 1986-12-30 National Distillers And Chemical Corporation Olefin hydroformylation
US4731486A (en) 1986-11-18 1988-03-15 Union Carbide Corporation Hydroformylation using low volatile phosphine ligands
CA2330384A1 (en) 1998-04-27 1999-11-04 The Dow Chemical Company Cure on demand adhesives and window module with cure on demand adhesive thereon
MY144123A (en) 2003-04-25 2011-08-15 Dow Global Technologies Inc Aldehyde and alcohol composition derived from seed oils
WO2009009271A2 (en) 2007-07-06 2009-01-15 Dow Global Technologies Inc. Purification of hydroformylated and hydrogenated fatty alkyl ester compositions

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20020013427A1 (en) * 2000-04-12 2002-01-31 Ryotaro Tsuji Method of producing crosslinkable silyl group-containing polyoxyalkylene polymers
JP2003246830A (en) * 2002-02-25 2003-09-05 Dainippon Ink & Chem Inc Solvent-free, moisture-curable hot-melt urethane resin composition excellent in durability, foam, and sheet structure using the same
JP2009235257A (en) * 2008-03-27 2009-10-15 Konishi Co Ltd Aqueous silylated urethane-based resin composition
WO2012003187A1 (en) * 2010-06-30 2012-01-05 Dow Global Technologies Llc Silyl-terminated polymers

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
DATABASE CA [online] CHEMICAL ABSTRACTS SERVICE, COLUMBUS, OHIO, US; KANEKAW, YOSHINORI ET AL: "Solvent-free moisture-curable hot-melt urethane compositions, cured foams therefrom, and artificial leather sheets therewith", XP002689895, retrieved from STN Database accession no. 139:215499 *
DATABASE CA [online] CHEMICAL ABSTRACTS SERVICE, COLUMBUS, OHIO, US; KASHIRO, SHOHEI ET AL: "Aqueous silylated urethane coating compositions with good solvent resistance", XP002689896, retrieved from STN Database accession no. 151:450603 *

Also Published As

Publication number Publication date
WO2013003051A2 (en) 2013-01-03

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