WO2013050367A3 - Procédé de production d'acide formique par réaction de dioxyde de carbone avec de l'hydrogène - Google Patents
Procédé de production d'acide formique par réaction de dioxyde de carbone avec de l'hydrogène Download PDFInfo
- Publication number
- WO2013050367A3 WO2013050367A3 PCT/EP2012/069458 EP2012069458W WO2013050367A3 WO 2013050367 A3 WO2013050367 A3 WO 2013050367A3 EP 2012069458 W EP2012069458 W EP 2012069458W WO 2013050367 A3 WO2013050367 A3 WO 2013050367A3
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- phase
- formic acid
- tertiary amine
- mixture
- raffinate
- Prior art date
Links
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 title abstract 16
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 title abstract 8
- 235000019253 formic acid Nutrition 0.000 title abstract 8
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 title abstract 4
- 229910002092 carbon dioxide Inorganic materials 0.000 title abstract 2
- 239000001569 carbon dioxide Substances 0.000 title abstract 2
- 229910052739 hydrogen Inorganic materials 0.000 title abstract 2
- 239000001257 hydrogen Substances 0.000 title abstract 2
- 238000004519 manufacturing process Methods 0.000 title abstract 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title 1
- 150000003512 tertiary amines Chemical class 0.000 abstract 10
- 238000005984 hydrogenation reaction Methods 0.000 abstract 8
- 239000000203 mixture Substances 0.000 abstract 8
- 239000012967 coordination catalyst Substances 0.000 abstract 7
- 239000002798 polar solvent Substances 0.000 abstract 6
- 150000001412 amines Chemical class 0.000 abstract 5
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 abstract 2
- 229910002091 carbon monoxide Inorganic materials 0.000 abstract 2
- 239000003795 chemical substances by application Substances 0.000 abstract 2
- 238000000605 extraction Methods 0.000 abstract 2
- 238000004821 distillation Methods 0.000 abstract 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 abstract 1
- 239000011541 reaction mixture Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0201—Oxygen-containing compounds
- B01J31/0202—Alcohols or phenols
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
- B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
- B01J31/0235—Nitrogen containing compounds
- B01J31/0237—Amines
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
- B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
- B01J31/2409—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring with more than one complexing phosphine-P atom
- B01J31/2414—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring with more than one complexing phosphine-P atom comprising aliphatic or saturated rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/02—Preparation of carboxylic acids or their salts, halides or anhydrides from salts of carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/41—Preparation of salts of carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/42—Separation; Purification; Stabilisation; Use of additives
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/42—Separation; Purification; Stabilisation; Use of additives
- C07C51/48—Separation; Purification; Stabilisation; Use of additives by liquid-liquid treatment
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/60—Reduction reactions, e.g. hydrogenation
- B01J2231/62—Reductions in general of inorganic substrates, e.g. formal hydrogenation, e.g. of N2
- B01J2231/625—Reductions in general of inorganic substrates, e.g. formal hydrogenation, e.g. of N2 of CO2
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/821—Ruthenium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/90—Catalytic systems characterized by the solvent or solvent system used
- B01J2531/98—Phase-transfer catalysis in a mixed solvent system containing at least 2 immiscible solvents or solvent phases
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Priority Applications (8)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CA2851175A CA2851175A1 (fr) | 2011-10-07 | 2012-10-02 | Procede de production d'acide formique par reaction de dioxyde de carbone avec de l'hydrogene |
BR112014008338A BR112014008338A2 (pt) | 2011-10-07 | 2012-10-02 | processo para preparar ácido fórmico |
SG11201400997TA SG11201400997TA (en) | 2011-10-07 | 2012-10-02 | Method for producing formic acid by reacting carbon dioxide with hydrogen |
RU2014118032/04A RU2014118032A (ru) | 2011-10-07 | 2012-10-02 | Способ получения муравьиной кислоты путем превращения диоксида углерода с водородом |
IN3122DEN2014 IN2014DN03122A (fr) | 2011-10-07 | 2012-10-02 | |
KR1020147011873A KR20140074373A (ko) | 2011-10-07 | 2012-10-02 | 이산화탄소와 수소의 반응에 의한 포름산의 제조 방법 |
CN201280059095.3A CN103974927A (zh) | 2011-10-07 | 2012-10-02 | 通过使二氧化碳与氢气反应制备甲酸的方法 |
EP12766684.0A EP2763950A2 (fr) | 2011-10-07 | 2012-10-02 | Procédé de production d'acide formique par réaction de dioxyde de carbone avec de l'hydrogène |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP11184297.7 | 2011-10-07 | ||
EP11184297 | 2011-10-07 |
Publications (2)
Publication Number | Publication Date |
---|---|
WO2013050367A2 WO2013050367A2 (fr) | 2013-04-11 |
WO2013050367A3 true WO2013050367A3 (fr) | 2013-10-03 |
Family
ID=46963751
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP2012/069458 WO2013050367A2 (fr) | 2011-10-07 | 2012-10-02 | Procédé de production d'acide formique par réaction de dioxyde de carbone avec de l'hydrogène |
Country Status (10)
Country | Link |
---|---|
EP (1) | EP2763950A2 (fr) |
JP (1) | JP2014530216A (fr) |
KR (1) | KR20140074373A (fr) |
CN (1) | CN103974927A (fr) |
BR (1) | BR112014008338A2 (fr) |
CA (1) | CA2851175A1 (fr) |
IN (1) | IN2014DN03122A (fr) |
RU (1) | RU2014118032A (fr) |
SG (1) | SG11201400997TA (fr) |
WO (1) | WO2013050367A2 (fr) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB201112231D0 (en) | 2011-07-15 | 2011-08-31 | Verdant Bioproducts Ltd | Micro-organism |
US8596013B2 (en) | 2012-04-04 | 2013-12-03 | Valinge Innovation Ab | Building panel with a mechanical locking system |
US9428438B2 (en) | 2012-11-27 | 2016-08-30 | Basf Se | Process for preparing formic acid |
WO2016024293A1 (fr) | 2014-08-12 | 2016-02-18 | Council Of Scientific & Industrial Research | Processus catalysé au métal pour la réduction de co2 en formate de sodium et en acide formique |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0095321A2 (fr) * | 1982-05-22 | 1983-11-30 | BP Chemicals Limited | Production de sels de formiates |
EP0181078A1 (fr) * | 1984-09-29 | 1986-05-14 | BP Chemicals Limited | Procédé de préparation de l'acide formique |
EP0329337A2 (fr) * | 1988-02-17 | 1989-08-23 | BP Chemicals Limited | Production d'acide formique à partir d'une base azotée, d'anhydride carbonique et d'hydrogène |
WO2008116799A1 (fr) * | 2007-03-23 | 2008-10-02 | Basf Se | Procédé de production d'acide formique |
WO2010149507A2 (fr) * | 2009-06-26 | 2010-12-29 | Basf Se | Procédé de préparation d'acide formique |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102004040789A1 (de) | 2004-08-23 | 2006-03-02 | Basf Ag | Verfahren zur Herstellung von Ameisensäure |
-
2012
- 2012-10-02 IN IN3122DEN2014 patent/IN2014DN03122A/en unknown
- 2012-10-02 SG SG11201400997TA patent/SG11201400997TA/en unknown
- 2012-10-02 BR BR112014008338A patent/BR112014008338A2/pt not_active IP Right Cessation
- 2012-10-02 EP EP12766684.0A patent/EP2763950A2/fr not_active Withdrawn
- 2012-10-02 WO PCT/EP2012/069458 patent/WO2013050367A2/fr active Application Filing
- 2012-10-02 KR KR1020147011873A patent/KR20140074373A/ko not_active Withdrawn
- 2012-10-02 RU RU2014118032/04A patent/RU2014118032A/ru not_active Application Discontinuation
- 2012-10-02 CA CA2851175A patent/CA2851175A1/fr not_active Abandoned
- 2012-10-02 CN CN201280059095.3A patent/CN103974927A/zh active Pending
- 2012-10-02 JP JP2014533856A patent/JP2014530216A/ja not_active Withdrawn
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0095321A2 (fr) * | 1982-05-22 | 1983-11-30 | BP Chemicals Limited | Production de sels de formiates |
EP0181078A1 (fr) * | 1984-09-29 | 1986-05-14 | BP Chemicals Limited | Procédé de préparation de l'acide formique |
EP0329337A2 (fr) * | 1988-02-17 | 1989-08-23 | BP Chemicals Limited | Production d'acide formique à partir d'une base azotée, d'anhydride carbonique et d'hydrogène |
WO2008116799A1 (fr) * | 2007-03-23 | 2008-10-02 | Basf Se | Procédé de production d'acide formique |
WO2010149507A2 (fr) * | 2009-06-26 | 2010-12-29 | Basf Se | Procédé de préparation d'acide formique |
Also Published As
Publication number | Publication date |
---|---|
KR20140074373A (ko) | 2014-06-17 |
JP2014530216A (ja) | 2014-11-17 |
CA2851175A1 (fr) | 2013-04-11 |
BR112014008338A2 (pt) | 2017-04-18 |
EP2763950A2 (fr) | 2014-08-13 |
RU2014118032A (ru) | 2015-11-20 |
WO2013050367A2 (fr) | 2013-04-11 |
SG11201400997TA (en) | 2014-09-26 |
IN2014DN03122A (fr) | 2015-05-22 |
CN103974927A (zh) | 2014-08-06 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
MY159513A (en) | Process for preparing formic acid | |
WO2013050367A3 (fr) | Procédé de production d'acide formique par réaction de dioxyde de carbone avec de l'hydrogène | |
UA104324C2 (ru) | Способ получения муравьиной кислоты | |
MX356188B (es) | Procedimiento para producir acido acetico. | |
MX338849B (es) | Procedimiento para producir acido acetico. | |
WO2011097220A3 (fr) | Procédé de production d'éthanol à l'aide d'une colonne de distillation extractive | |
MX2012008937A (es) | Proceso para producir etanol utilizando una columna de destilacion por extraccion. | |
EA201070357A1 (ru) | Способ получения диметилового эфира | |
WO2012115422A3 (fr) | Procédé pour préparer un composé d'éther mono-tert-butylique de glycol | |
EA201390504A1 (ru) | Способ разделения и способ получения изоцианата | |
UA107714C2 (ru) | Способ гидрирования изо-альфа-кислот или тетрагидро-изо-альфа-кислот до гексагидро-изо-альфа-кислот | |
JP2010229049A (ja) | 高純度ビニルエーテルの製造法 | |
RU2013103602A (ru) | Способ получения муравьиной кислоты путем взаимодействия диоксида углерода с водородом | |
MX2013013374A (es) | Proceso para la recuperacion de acido acetico. | |
EP3004037B1 (fr) | Procédé pour la séparation d'alkylène glycol | |
EP3004039B1 (fr) | Procédé de séparation de 1,4-butanediol et de coproduits | |
RU2014104137A (ru) | Способ получения муравьиной кислоты путем реакции диоксида углерода с водородом | |
RU2016142388A (ru) | Способ получения фурана из фурфурола | |
EP3415499B1 (fr) | Procédé de production de 1-méthylpyrrolidin-3-ol | |
MY174962A (en) | Process for the removal of co2 from acid gas | |
CN105121397B (zh) | 用于分离1,4-丁二醇的方法 | |
EP3004038B1 (fr) | Procédé de séparation d'alcools | |
CN104974129A (zh) | 用于分离4,4-二甲基-1,3-二氧六环生产过程中产生的高沸物的萃取剂及其应用 | |
WO2011092270A3 (fr) | Procédé pour la préparation d'épichlorhydrine à partir du dichlorhydrine | |
CN105585404A (zh) | 一种分离环戊烷和2,2-二甲基丁烷的方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
121 | Ep: the epo has been informed by wipo that ep was designated in this application |
Ref document number: 12766684 Country of ref document: EP Kind code of ref document: A2 |
|
DPE1 | Request for preliminary examination filed after expiration of 19th month from priority date (pct application filed from 20040101) | ||
ENP | Entry into the national phase |
Ref document number: 2851175 Country of ref document: CA |
|
ENP | Entry into the national phase |
Ref document number: 2014533856 Country of ref document: JP Kind code of ref document: A |
|
WWE | Wipo information: entry into national phase |
Ref document number: 2012766684 Country of ref document: EP |
|
ENP | Entry into the national phase |
Ref document number: 20147011873 Country of ref document: KR Kind code of ref document: A |
|
ENP | Entry into the national phase |
Ref document number: 2014118032 Country of ref document: RU Kind code of ref document: A |
|
REG | Reference to national code |
Ref country code: BR Ref legal event code: B01A Ref document number: 112014008338 Country of ref document: BR |
|
121 | Ep: the epo has been informed by wipo that ep was designated in this application |
Ref document number: 12766684 Country of ref document: EP Kind code of ref document: A2 |
|
ENP | Entry into the national phase |
Ref document number: 112014008338 Country of ref document: BR Kind code of ref document: A2 Effective date: 20140407 |