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WO2012024364A2 - Compositions de revitalisant pour cheveux et peau - Google Patents

Compositions de revitalisant pour cheveux et peau Download PDF

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Publication number
WO2012024364A2
WO2012024364A2 PCT/US2011/048028 US2011048028W WO2012024364A2 WO 2012024364 A2 WO2012024364 A2 WO 2012024364A2 US 2011048028 W US2011048028 W US 2011048028W WO 2012024364 A2 WO2012024364 A2 WO 2012024364A2
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WO
WIPO (PCT)
Prior art keywords
hair
composition according
composition
carbon atoms
compositions
Prior art date
Application number
PCT/US2011/048028
Other languages
English (en)
Other versions
WO2012024364A3 (fr
Inventor
Adam P. Schrott
Original Assignee
Kao Corporation
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kao Corporation filed Critical Kao Corporation
Publication of WO2012024364A2 publication Critical patent/WO2012024364A2/fr
Publication of WO2012024364A3 publication Critical patent/WO2012024364A3/fr

Links

Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/12—Preparations containing hair conditioners
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/37—Esters of carboxylic acids
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8105—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • A61K8/8111—Homopolymers or copolymers of aliphatic olefines, e.g. polyethylene, polyisobutene; Compositions of derivatives of such polymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89—Polysiloxanes
    • A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89—Polysiloxanes
    • A61K8/896—Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate
    • A61K8/898—Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate containing nitrogen, e.g. amodimethicone, trimethyl silyl amodimethicone or dimethicone propyl PG-betaine
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring

Definitions

  • Non-volatile silicones and non-volatile hydrocarbons are known in the art to provide a number of consumer recognized hair and skin care benefits, such as smoothing, anti-static control, color protection, frizz control and moisturization.
  • those materials are very difficult to deliver in a consumer acceptable or efficacious manner to the skin or hair in their concentrated form or when they are added to a formulation in their concentrated form.
  • compositions utilize very high viscosity polydimethylsiloxanes in volatile compounds, such as cycfopentasiloxane, cycfomethicone; low molecular weight polydimethylsiloxanes; or low molecular weight hydrocarbons, such as isododecane or isoparaffins. While these compositions may be the best available, they are not particularly effective in delivering the benefits which can be provided by the high viscosity PDMS materials. [0004] Thus, there is a recognized need to find a delivery system which is useful for delivering the hair and skin care benefits of high viscosity linear polydimethylsiloxane materials. That is the focus of the present invention.
  • the present invention provides hair and skin conditioning compositions, incorporating very high viscosity nonvolatile silicone and hydrocarbon materials, which may be delivered "neat” for applications such as, but not limited to, hair serums and hair shine sprays, or may be added as a "pre-mix” to known personal care compositions such as, but not limited to, shampoos, conditioners, styling creams, lotions (for hair or skin), moisturizers (for hair or skin), hair colors, permanent wave compositions or styling gels, in order to effectively deliver the benefits which are seen with the non-volatile high viscosity PDMS and hydrocarbon materials. Additionally, the compositions of the present invention maintain clarity and show no separation upon standing, remaining a flowable liquid at room temperature.
  • the present invention relates to hair and skin conditioning
  • compositions which comprise (a) a silicone or a hydrocarbon component, having a viscosity of from about 2,500 to about 600,000 cSt at 25°C; and (b) a carrier fluid having a viscosity less than about 100 cSt at 25°C and a flash point greater than about 85°C.
  • the present invention relates to hair and skin conditioning
  • compositions which comprise a silicone or a hydrocarbon component having a viscosity of from about 2,500 to about 600,000 cSt at 25°C, together with a carrier having a viscosity less than about 100 cSt at 25°C, and a flash point greater than about 85°C.
  • the compositions can be applied "neat" directly to hair or skin, or can be applied by conventional conditioning compositions, such as shampoos, conditioners, styling creams, lotions (for hair or for skin), moisturizers (for hair or skin), hair colors, permanent wave compositions, or styling gels.
  • the compositions of the present invention maintain clarity, show no separation upon standing, and remain flowable liquids at room temperature.
  • the carriers that fall outside those defined herein provide compositions that tend to show haziness, cloudiness and separation upon standing.
  • high viscosity silicones and high viscosity hydrocarbons having a viscosity of from about 2,500 to about 600,000 cSt at 25°C
  • examples of such materials include silicone compounds having a viscosity between about 60,000 and about 600,000 cSt; polymers of decene; polymers of isobutylene; copolymers of decene and isobutylene together; hydrogenated polymers of decene and/or isobutylene; and mixtures of the foregoing materials. These materials are well-known in the art.
  • non-volatile high viscosity materials include dimethicone gum (such as that marketed as ShinEtsu KE-76-BSR); dimethicone (100,000 cSt or 60,000 cSt) (commercially marketed as Dow Corning 200 Fluid); bis-cetearyl amodimethicone (commercially available as Silsoft AX); hydrogenated polydecene (commercially available as Exxon Mobile Pure Syn 300); hydrogenated polyisobutene (commercially available as Fancor Polyiso 1200); and polyisobutene (commercially available as Permethyl 104 A, 105 A, or 106A). Mixtures of the foregoing materials may also be utilized.
  • the second component utilized in the mixtures of the present invention include carrier fluids having a viscosity less than about 100 cSt at 25°C and a flash point greater than about 85°C. These carriers generally have a specific gravity less than about 0.9, and a refractive index of about 1.35 or greater.
  • Examples of these materials include mono esters containing 20 or fewer carbon atoms; linear or branched hydrocarbons containing from 12 to 20 carbon atoms; linear ethers containing 20 or fewer carbon atoms; polymers containing 12 to 20 carbon atoms formed from the polymerization of isobutylene; hydrogenated polymers containing 12 to 20 carbon atoms formed from the polymerization and hydrogenation of isobutylene; alkyl methyl siloxane fluids having fewer than 10 silicon atoms and wherein the alkyl group contains 12 or fewer carbon atoms; and mixtures of the foregoing materials.
  • those materials include isodecyl neopentanoate, isodecyl isononanoate, isononyl isononanoate, tridecyl neopentanoate, hydrogenated polyisobutene (250), caprylyl methicone, dicaprylyl ether, isohexadecane, and mixtures of those materials. Mixtures of isopropyl palmitate and high molecular weight hydrocarbon blends may also be used as the carrier.
  • the silicone and hydrocarbon materials are generally used at levels of from about 5 to about 25%, for example from about 10% to about 20%, of the binary mixture.
  • the carrier component of the mixture is used at levels of from about 75% to about 95%, for example from about 80% to about 90%, of the binary mixture. Specific examples of these binary mixtures are set forth in the following Tables 1(A) and (B): Table 1(A)
  • the binary mixture compositions may be applied directly to hair and skin (i.e., "neat” application) such as from a hair serum or a hair shine spray, or they may be applied from known hair and skin conditioning compositions.
  • Such compositions include, but are not limited to, shampoos, conditioners, styling creams, lotions, moisturizers, hair coloring compositions, permanent wave compositions and styling gels. They are well-known to those skilled in the art; for example, shampoo compositions are described in U.S. Patent 6,706,258, Gallagher et al, issued March 16, 2004, incorporated herein by reference.
  • Such shampoos comprise one or more cleansing surfactants which are cosmetically acceptable and suitable for topical application to the hair.
  • Suitable surfactants which may be used singularly or in combination, are selected from anionic, amphoteric and zwitterionic surfactants, and mixtures thereof.
  • anionic surfactants include alkyl sulfates, alkyl ether sulfates, alkaryl sulfonates, alkanoyl isethionates, alkyl succinates, alkyl sulfosuccinates, n-alkyl sarcosinates, alkyl phosphates, alkyl ether phosphates, alkyl ether carboxylates, and alpha-olefin sulfonates, especially their sodium, magnesium, ammonium and mono-, di- and triethanolamine salts.
  • the alkyl and acyl groups generally contain from 8 to 18 carbon atoms and may be unsaturated.
  • the alkyl ether sulfates, alkyl ether phosphates and alkyl ether carboxylates may contain from 1 to 10 ethylene oxide or propylene oxide units per molecule.
  • Typical anionic surfactants for use in shampoos include sodium oleyl succinate, ammonium lauryl sulfosuccinate, ammonium lauryl sulfate, sodium dodecylbenzene sulfonate, triethanolamine dodecyl benzene sulfonate, sodium cocoyl isethionate, sodium lauryl isethionate and sodium n-lauroyl sacrocinate.
  • the most preferred anionic surfactants are sodium lauroyl sulfate, triethanolamine mono lauroyl phosphate, sodium lauroyl ether sulfate (1EO, 2 EO and 3 EO), ammonium lauroyl sulfate and ammonium lauroyl ether sulfate (1 EO, 2 EO, and 3 EO).
  • amphoteric and zwitterionic surfactants include alkyl amine oxides, alkyl betaines, alkyl amidopropylbetaines, alkyl sulfobetaines (sultaines), alkyl glycinates, alkyl carboxy glycinates, alkyl amphopropionates, alkyl amphoglycinates, alkyl amidopropyl hydroxyl sultaines, acyl taurates, and acyl glutamates, wherein the alkyl and acyl groups contain from 8 to 19 carbon atoms.
  • Typical amphoteric and zwitterionic surfactants for use in shampoos include lauryl amine oxide, cocodimethyl amine oxide, sulfopropyl betaine, lauryl betaine, cocamidopropyl betaine and sodium
  • the shampoo compositions may additionally contain cationic
  • deposition enhancing polymers non-silicone conditioning agents, antimicrobial agents, and aesthetic agents, such as colorants, fragrances, and pearlescing agents.
  • Other components which may be included include viscosity modifiers, preservatives, polyols (such as glycerin and polypropylene glycol), chelating agents (such as EDTA), antioxidants, sunscreens, and carriers (which can be, for example, ethanol and/or water).
  • Hair conditioning compositions are also well-known in the art. For example, they are described in U.S. Patent 6,287,545, Su, issued September 11, 2001, incorporated herein by reference.
  • Such hair conditioner compositions commonly include long chain mono-, di- or even tri- higher alkyl quaternary ammonium compounds, such cetyl trimonium chloride, fatty alcohols (such as cetyl alcohol or stearyl alcohol), mineral oil, humectants, surfactants/emulsifiers, thickeners (such as cellulose derivatives), polycationic polymers (known as polyquaterniums), colorants, perfumes, opacifiers, pearlescent aides, buffers, preservatives, antioxidants, and carriers (which can be, for example, ethanol and/or water).
  • fatty alcohols such as cetyl alcohol or stearyl alcohol
  • mineral oil such as humectants
  • surfactants/emulsifiers such as cellulose derivatives
  • thickeners such as cellulose derivative
  • conditioner formulations in general terms, which include the binary compositions of the present invention are set forth in the following Table 2: Table 2
  • compositions described can also be used to provide moisturization benefits to skin.
  • Skin care compositions can include any of the composition types known in the art, such as, for example, lotions. Examples of skin care lotions are taught in U.S. Patent 7,816,310, Landa et al, issued October 19, 2010, incorporated herein by reference.
  • compositions of the present invention are applied in an "effective amount", i.e., an amount which provides the hair or skin conditioning and/or moisturizing benefits desired, but not so much as to result in undesirable effects to the user (e.g., greasiness to the hair or skin).
  • compositions of the present invention are set forth below.
  • Conditioner formulations incorporating the binary mixtures of the present invention contain the following components and are prepared using conventional techniques:
  • compositions are made by conventional means.
  • the compositions are made as follows.
  • purified water is heated to 80°C.
  • Components (B) comprise the "oil phase" and should be pre-mixed in a separate vessel, heated to 80°C, and mixed until homogeneous.
  • the resulting emulsion may then be cooled to 40°C.
  • Components (C) should be pre-mixed in a separate vessel until homogeneous.
  • components (C) may be added with mixing to incorporate them into the emulsion.
  • components (D) may be added with mixing to incorporate them into the emulsion.
  • the conditioners When applied to hair, the conditioners provide excellent conditioning and frizz control characteristics.
  • the silicone/hydrocarbon and the carrier fluid components, defined herein are pre-mixed prior to mixing with other components. This pre-mixing can provide performance and formulational benefits.
  • Lotion formulations of the present invention contain the components listed in the following table and are made using the procedure described above. When applied to skin, the lotions provide excellent skin conditioning and moisturizing.

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Dermatology (AREA)
  • Emergency Medicine (AREA)
  • Cosmetics (AREA)

Abstract

L'invention porte sur des compositions qui apportent des avantages aux soins des cheveux et de la peau, tel qu'un lissage, un effet antistatique, une protection de la couleur, un effet anti-boucles et une hydratation. Les compositions gardent une transparence, ne présentent pas de séparation lorsqu'on les laisse reposer, et restent des liquides pouvant s'écouler à température ambiante. Les compositions comportent un composant silicone ou hydrocarboné ayant une viscosité d'environ 2 500 à environ 600 000 cSt à 25° C (tel que la gomme de diméthicone ou le polydécène hydrogéné), conjointement avec un fluide véhicule ayant une viscosité inférieure à environ 100 cSt à 25° C et un point d'éclair supérieur à environ 85° C (tel que la caprylyl méthicone, le néopentanoate d'isodécyle, ou le polyisobutène hydrogéné (250)). L'invention porte également sur des compositions de soins capillaires, telles que des shampooings et des revitalisants contenant ces combinaisons, ainsi que sur le procédé de revitalisation des cheveux à l'aide de ces compositions. Les compositions peuvent être appliquées directement sur les cheveux, (c'est-à-dire « non diluées ») ou par l'intermédiaire d'une composition de traitement capillaire classique, telle qu'un shampooing ou un revitalisant. L'invention porte également sur des compositions de soins de la peau et sur des procédés associés.
PCT/US2011/048028 2010-08-18 2011-08-17 Compositions de revitalisant pour cheveux et peau WO2012024364A2 (fr)

Applications Claiming Priority (2)

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US37482910P 2010-08-18 2010-08-18
US61/374,829 2010-08-18

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WO2012024364A2 true WO2012024364A2 (fr) 2012-02-23
WO2012024364A3 WO2012024364A3 (fr) 2013-09-12

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2012079915A3 (fr) * 2010-12-16 2014-01-09 Henkel Ag & Co. Kgaa Agents pour la modification de couleur et/ou de forme de fibres kératiniques
WO2014114975A3 (fr) * 2013-01-22 2014-12-31 Kao Corporation Compositions de traitement des cheveux et de la peau
WO2015027302A1 (fr) * 2013-09-02 2015-03-05 L'oreal Composition de soin capillaire comprenant une aminosilicone, un alcool gras et de l'huile de paraffine
WO2020061658A1 (fr) * 2018-09-28 2020-04-02 L'oreal Compositions de traitement des cheveux comportant un ester d'ammonium quaternaire
WO2023123196A1 (fr) * 2021-12-30 2023-07-06 L'oreal Composition d'huiles pour le soin des matières kératiniques

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Publication number Priority date Publication date Assignee Title
US6136296A (en) 1997-04-25 2000-10-24 The Procter & Gamble Company Personal care compositions
US6287545B1 (en) 1994-12-19 2001-09-11 Colgate-Palmolive Company Hair conditioner compositions having improved freezing and freeze-thaw stability
US6586378B2 (en) 1999-12-20 2003-07-01 Unilever Home & Personal Care Usa, Division Of Conopco, Inc. Aqueous hair styling compositions
US6706258B1 (en) 1998-04-20 2004-03-16 Unilever Home & Personal Care Usa, Division Of Conopco, Inc. Shampoo compositions comprising and emulsified silicone an a microemulsified silicone
US7785575B2 (en) 2007-10-22 2010-08-31 Living Proof, Inc. Hair care compositions and methods of treating hair using same
US7816310B2 (en) 2003-11-26 2010-10-19 Akzo Nobel N.V. Increased moisturization efficacy using hydroxyalkylurea and ammonium lactate
US7850952B2 (en) 2003-03-24 2010-12-14 Conopco, Inc. Hair treatment compositions

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Publication number Priority date Publication date Assignee Title
US5525344A (en) * 1995-01-03 1996-06-11 Chesebrough-Pond's Usa Co., Division Of Conopco, Inc. Clear cold cream cosmetic compositions
FR2811565B1 (fr) * 2000-07-13 2003-01-17 Oreal Emulsion eau-dans-huile et ses utilisations notamment dans le domaine cosmetique
FR2876902B1 (fr) * 2004-10-21 2007-04-27 Oreal Produit de maquillage bicouche de tenue amelioree, ses utilisations et kit de maquillage contenant ce produit
US20070286837A1 (en) * 2006-05-17 2007-12-13 Torgerson Peter M Hair care composition comprising an aminosilicone and a high viscosity silicone copolymer emulsion
WO2009132881A1 (fr) * 2008-04-29 2009-11-05 Unilever Plc Composition revitalisante capillaire comportant trois types de silicone
US20110286950A1 (en) * 2008-12-16 2011-11-24 L'oreal S.A. Cosmetic compositions of varying viscoelasticity

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6287545B1 (en) 1994-12-19 2001-09-11 Colgate-Palmolive Company Hair conditioner compositions having improved freezing and freeze-thaw stability
US6136296A (en) 1997-04-25 2000-10-24 The Procter & Gamble Company Personal care compositions
US6706258B1 (en) 1998-04-20 2004-03-16 Unilever Home & Personal Care Usa, Division Of Conopco, Inc. Shampoo compositions comprising and emulsified silicone an a microemulsified silicone
US6586378B2 (en) 1999-12-20 2003-07-01 Unilever Home & Personal Care Usa, Division Of Conopco, Inc. Aqueous hair styling compositions
US7850952B2 (en) 2003-03-24 2010-12-14 Conopco, Inc. Hair treatment compositions
US7816310B2 (en) 2003-11-26 2010-10-19 Akzo Nobel N.V. Increased moisturization efficacy using hydroxyalkylurea and ammonium lactate
US7785575B2 (en) 2007-10-22 2010-08-31 Living Proof, Inc. Hair care compositions and methods of treating hair using same

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2012079915A3 (fr) * 2010-12-16 2014-01-09 Henkel Ag & Co. Kgaa Agents pour la modification de couleur et/ou de forme de fibres kératiniques
WO2014114975A3 (fr) * 2013-01-22 2014-12-31 Kao Corporation Compositions de traitement des cheveux et de la peau
WO2015027302A1 (fr) * 2013-09-02 2015-03-05 L'oreal Composition de soin capillaire comprenant une aminosilicone, un alcool gras et de l'huile de paraffine
US10653611B2 (en) 2013-09-02 2020-05-19 L'oreal Hair care composition comprising amino silicone, fatty alcohol and paraffin oil
WO2020061658A1 (fr) * 2018-09-28 2020-04-02 L'oreal Compositions de traitement des cheveux comportant un ester d'ammonium quaternaire
WO2023123196A1 (fr) * 2021-12-30 2023-07-06 L'oreal Composition d'huiles pour le soin des matières kératiniques

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