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WO2012000773A1 - Couche de recouvrement semi-rigide - Google Patents

Couche de recouvrement semi-rigide Download PDF

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Publication number
WO2012000773A1
WO2012000773A1 PCT/EP2011/059707 EP2011059707W WO2012000773A1 WO 2012000773 A1 WO2012000773 A1 WO 2012000773A1 EP 2011059707 W EP2011059707 W EP 2011059707W WO 2012000773 A1 WO2012000773 A1 WO 2012000773A1
Authority
WO
WIPO (PCT)
Prior art keywords
binder
covering according
reaction resin
aggregate
acrylate
Prior art date
Application number
PCT/EP2011/059707
Other languages
German (de)
English (en)
Inventor
Elo Yde
Luc Bruno Jozef Westhof
Original Assignee
Construction Research & Technology Gmbh
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Construction Research & Technology Gmbh filed Critical Construction Research & Technology Gmbh
Publication of WO2012000773A1 publication Critical patent/WO2012000773A1/fr

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
    • C04B41/5076—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with masses bonded by inorganic cements
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • C04B26/02—Macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
    • C04B26/02—Macromolecular compounds
    • C04B26/10—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C04B26/16—Polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/04—Portland cements
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B38/00—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
    • C04B38/0038—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof by superficial sintering or bonding of particulate matter
    • E—FIXED CONSTRUCTIONS
    • E01—CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
    • E01C—CONSTRUCTION OF, OR SURFACES FOR, ROADS, SPORTS GROUNDS, OR THE LIKE; MACHINES OR AUXILIARY TOOLS FOR CONSTRUCTION OR REPAIR
    • E01C7/00—Coherent pavings made in situ
    • E01C7/08—Coherent pavings made in situ made of road-metal and binders
    • E01C7/35—Toppings or surface dressings; Methods of mixing, impregnating, or spreading them
    • E01C7/356—Toppings or surface dressings; Methods of mixing, impregnating, or spreading them with exclusively synthetic resin as a binder; Aggregate, fillers or other additives for application on or in the surface of toppings having exclusively synthetic resin as binder
    • E—FIXED CONSTRUCTIONS
    • E01—CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
    • E01C—CONSTRUCTION OF, OR SURFACES FOR, ROADS, SPORTS GROUNDS, OR THE LIKE; MACHINES OR AUXILIARY TOOLS FOR CONSTRUCTION OR REPAIR
    • E01C7/00—Coherent pavings made in situ
    • E01C7/08—Coherent pavings made in situ made of road-metal and binders
    • E01C7/35—Toppings or surface dressings; Methods of mixing, impregnating, or spreading them
    • E01C7/358—Toppings or surface dressings; Methods of mixing, impregnating, or spreading them with a combination of two or more binders according to groups E01C7/351 - E01C7/356
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
    • C04B2111/0075—Uses not provided for elsewhere in C04B2111/00 for road construction

Definitions

  • the invention relates to a covering, which is suitable in particular as a cover layer for a traffic area, a method for its production and its use.
  • cover layers for traffic routes such as, for example, roads, parking decks, industrial floors or aircraft operating areas are produced either from asphalt or concrete.
  • the use of concrete is particularly advantageous in terms of the high wear resistance of the material.
  • precast concrete parts these must be prefabricated in a complex manner and then laid just as consuming.
  • the intermediate space of the individual laid prefabricated parts is to shed and is a weak point.
  • Fresh concrete has the disadvantage that it must be cured after laying for several days and then post-treated before it can be released for traffic.
  • when laying the concrete expansion joints must be provided to prevent the formation of shrinkage cracks. This is associated with a high cost and has the additional disadvantage that no larger uniform areas can be laid, but just as in the use of precast concrete parts, the expansion joints represent weak points.
  • Asphalt is a mixture of aggregates and bitumen as a binder, with variations in the components of the properties of the asphalt can be adjusted within certain limits.
  • Asphalt can be laid relatively quickly and over a large area. Laying here essentially comprises the application of hot asphalt with a temperature of over 100 ° C to a base course and subsequent compacting.
  • Asphalted traffic areas can be opened to traffic after a short time, but it is disadvantageous that asphalt has a significantly lower wear resistance than concrete and thus causes high maintenance costs over time. In particular, the effect of frost can cause severe damage to the asphalt surface.
  • Another disadvantage is that asphalt pavements, especially based on hot bitumen, too strong Cause odor nuisance. This usually precludes the use of such coverings indoors.
  • coating materials are provided which are intended to combine the high strength of the concrete with the plasticity (low modulus of elasticity) and chemical resistance of the asphalt.
  • These materials are based on a binder combination of reaction resin and cement.
  • mixtures of epoxy resin / hardener and cement are used.
  • coverings of polyurethane resin and cement are also known.
  • the individual components (reaction resin, hardener, cement mortar and possibly water) are mixed with each other before use and applied similar to fresh concrete.
  • PCC polymer-cement-concrete
  • ECC systems epoxy-cement concrete
  • cover layers are described, for example, in GB 2 053 329 and GB 2 331 540 and are commercially available, for example, under the brand name Densiphalt® from Densit ApS.
  • the semi-rigid pavement is mostly used as a jointless under high stress surfacing where conventional asphalt is not sufficient or where the joints are problematic when using concrete. It is suitable for long-term loads and for applications with very large temperature fluctuations and is resistant to salt and frost.
  • the underlying base courses are usually constructed in the usual way as asphalt or cement-bound base courses, resulting in a total of a "mixed load-bearing system" Reason for the rapid strength development, the semi-rigid coating depending on
  • the object of the present invention was therefore to provide a covering which is suitable as a cover layer for a traffic area and does not have the known disadvantages of the previous systems.
  • the desired cover layer should have high strengths in conjunction with a low modulus of elasticity and no cracking.
  • the top layer should be applied faster and more economically even on small areas.
  • Another object of the present invention was to provide a cover layer which is more environmentally friendly than the asphalt used hitherto and can also be applied indoors.
  • This object is achieved by providing a covering comprising a porous matrix of an aggregate and a binder based on a reaction resin, wherein the particles of the aggregate are clamped together by the binder based on a reaction resin and the cavities of the porous matrix with a hardened inorganic binder are filled.
  • the cover layer of the invention has a higher compressive strength, in comparison to cover layers, which are known from GB 2 331 540 or commercially available under the brand name Densiphalt ® . It is also surprising that the modulus of elasticity is very low despite high strength and that cracking is reliably prevented thereby.
  • the system according to the invention has the advantage that the porous matrix can be applied from an additive and a binder based on a reaction resin at ambient temperature and to no appreciable emissons and also leads to no odor nuisance. The binder is cured after a few hours and the porous matrix can then be filled immediately with the mortar.
  • the reaction resin is at least one of the series polyurethane, polyurea, epoxy, acrylate and polyester.
  • the binder based on a reaction resin is preferably at least 70 wt .-%, in particular at least 85 wt .-% and particularly preferably at least 95 wt .-% of at least one compound of the reaction resin. If the reaction resin comprises polyurethanes and / or polyureas, these are composed of at least one polyol or polyamine component and one polyisocyanate component and may optionally contain chain extenders.
  • the method of preparation of the polyurethane or polyurea prepolymers is not critical to the present invention. It may thus be a one-step process, wherein the polyols and / or polyamines, polyisocyanates and chain extenders are simultaneously reacted with each other, which may, for example. In a batch reaction, or it may be a two-stage process, in For example, a prepolymer is first formed, which is subsequently reacted with chain extenders.
  • the polyurethanes or polyureas may also contain further structural units, in particular these may be allophanates, biurets, uretdiones or cyanates.
  • the abovementioned groups are only examples in which the polyurethanes and polyureas according to the invention may also contain further structural units.
  • the degree of branching is not critical to the present invention, so that both linear and highly branched polymers can be used.
  • the molar ratio of the isocyanate component contained in the polymer to the sum of the polyol or polyamine component is 0.01 to 50, preferably 0.5 to 3.0.
  • the isocyanate component is preferably an aliphatic, cycloaliphatic, araliphatic and / or aromatic compound, preferably a diisocyanate or triisocyanate, which may also be mixtures of these compounds.
  • it is to be regarded as preferred that it is hexamethylene diisocyanate-1, 6 (HDI), HDI uretdione, HDI isocyanurate, HDI biuret, HDI allophanate, 1-isocyanato-3,3,5-trimethyl-5-isocyanatomethylcyclohexane (IPDI), 2,4- and / or 2,6-toluene diisocyanate (TDI) and / or 4,4'-, 2,4'- and / or 2,2'-
  • HDI hexamethylene diisocyanate-1, 6
  • HDI uretdione HDI isocyanurate
  • HDI biuret HDI allophanate
  • IPDI 1-isocyana
  • Diphenylmethane diisocyanate (MDI), polymeric MDI, carbodiimide-modified 4, 4'-MDI, m-xylene diisocyanate (MXDI), m- or p-tetramethylxylene diisocyanate (m-TMXDI, p-TMXDI), 4,4'-dicyclohexylmethane diisocyanate (H12MDI) , Naphthalene-1, 5-diisocyanate, cyclohexane-1, 4-diisocyanate, hydrogenated xylylene diisocyanate (H6XDI), 1-methyl-2,4-diisocyanato-cyclohexane, tetramethoxybutane-1,4-diisocyanate, butane-1, 4 diisocyanate, 1,6-diisocyanato-2,2,4-trimethylhexane, 1,6-diisocyanato-2,4,
  • polyisocyanates having two or three isocyanate groups per molecule are suitable.
  • it may also be mixtures of polyisocyanates, wherein the average NCO functionality of the isocyanate component in the mixture in particular at 2.1 to 2.3, 2.2 to 2.4, 2.6 to 2.8 or 2, 8 to 3.0 can lie.
  • Derivatized polyisocyanates may also be used, for example, sulfonated isocyanates, blocked isocyanates, isocyanurates and biuret isocyanates.
  • the polyol or polyamine component is preferably polyetherresterpolyol, fatty acid ester polyols, polyether polyols, polyester polyols, polybutadiene polyols and polycarbonate polyols, which may also be mixtures of these compounds.
  • the polyols and / or polyamines preferably contain between two and 10, more preferably between two and three hydroxyl groups and / or amino groups and have a weight-average molecular weight between 32 and 30,000, more preferably between 90 and 18,000 g / mol.
  • Suitable polyols are preferably the liquid at room temperature, glassy solid / amorphous or crystalline polyhydroxy compounds. Typical examples would be difunctional polypropylene glycols.
  • Suitable polyether polyols are the polyethers known in polyurethane chemistry, such as the polyols prepared using starter molecules by means of KOH or DMC catalysis of styrene oxide, ethylene oxide, propylene oxide, butylene oxide, tetrahydrofuran or epichlorohydrin.
  • poly (oxytetramethylene) glycol (poly-THF), 1, 2-polybutylene glycol, or mixtures thereof are particularly suitable.
  • Particularly suitable are polypropylene oxide, polyethylene oxide and butylene oxide and mixtures thereof.
  • polyesterdi- or polyols obtained by condensation of di- or tricarboxylic acids such as adipic acid, sebacic acid, glutaric acid, azelaic acid, suberic acid, undecanedioic acid, dodecanedioic acid, 3rd , 3-dimethylglutaric acid, terephthalic acid, isophthalic acid, hexahydrophthalic acid and / or dimer fatty acid, with low molecular weight diols, triols or polyols, such as ethylene glycol, propylene glycol, diethylene glycol, triethylene glycol, dipropylene glycol, 1, 4-butanediol, 1, 6-hexanediol, 1, 8- octanediol, 1, 10-decanediol, 1, 12-dodecanediol, dimer
  • polystyrene resin e.g. based on caprolactone, which are also referred to as "polycaprolactones”.
  • polycaprolactones Further usable polyols are polycarbonate polyols, dimer fatty alcohols and dimer diols, as well as polyols based on vegetable oils and their derivatives, such as castor oil and its derivatives or epoxidized soybean oil.
  • hydroxyl-containing polycarbonates in question which by reaction of carbonic acid derivatives, for. B.
  • Diphenyl carbonate, dimethyl carbonate or phosgene are available with diols. Particularly suitable are, for example, ethylene glycol, 1,2,3- and 1,3-propanediol, 1,3- and 1,4-butanediol, 1,6-hexanediol, 1,8-octanediol, neopentyl glycol, 1,4-bishydroxymethylcyclohexane, 2-Methyl-1,3-propanediol, 2,2,4-trimethylpentanediol-1, 3, dipropylene glycol, polypropylene glycols, dibutylene glycol, polybutylene glycols, bisphenol A, tetrabromobisphenol A, glycerol, trimethylolpropane, 1, 2,6-hexanetriol, 1, 2,4-butanetriol, trimethylolpropane, pentaerythritol, quinitol,
  • hydroxy-functional polybutadienes which are commercially available under the trade name "Polybd®", can also serve as the polyol component as well as their hydrogenated analogs.Otherwise there are hydroxy-functional polysulfides which are sold under the trade name “Thiokol® NPS-282 "as well as hydroxy-functional polysiloxanes in question.
  • Hydrazine, hydrazine hydrate and substituted hydrazines such as N-methylhydrazine, ⁇ , ⁇ '-dimethylhydrazine, acid hydrazides of adipic acid, methyladipic acid, sebacic acid, hydracrylic acid, terephthalic acid, isophthalic acid, semicarbazidoalkylene hydrazides, such as 13-semicarbazidopropionic acid hydrazide are particularly suitable as inventively employable polyamine component , Semicarbazidoalkylen-carbazinester such.
  • 2-semicarbazidoethyl carbazine ester and / or aminosemicarbazide compounds such as 13-aminoethyl semicarbazidocarbonate.
  • Polyamines based on polyesters, polyolefins, polyacetals, polythioethers, polyethercarbonates, polyethylene terephthalates, polyesteramides, polycaprolactams, polycarbonates, polycaprolactones and polyacrylates, which have at least two amine groups, are also suitable for the preparation of the polyurethanes and polyureas.
  • Polyamines eg those marketed under the trade name Jeffamine® (polyether polyamines), are also suitable.
  • Suitable polyol components and / or polyamine components are also the species known as chain extenders, which react with excess isocyanate groups in the preparation of polyurethanes and polyureas, normally having a molecular weight (Mn) of less than 400 and often in the form of polyols , Aminopolyols or aliphatic, cycloaliphatic or araliphatic see polyamines.
  • chain extenders which react with excess isocyanate groups in the preparation of polyurethanes and polyureas, normally having a molecular weight (Mn) of less than 400 and often in the form of polyols , Aminopolyols or aliphatic, cycloaliphatic or araliphatic see polyamines.
  • Suitable chain extenders are, for example:
  • Alkanediols such as ethanediol, 1,2- and 1,3-propanediol, 1,4- and 2,3-butanediol, 1,5-pentanediol, 1,3-dimethylpropanediol, 1,6-hexanediol, neopentylglycol, cyclohexane xandimethanol, 2-methyl-1, 3-propanediol, hexylene glycol, 2,5-dimethyl-2,5-hexanediol, ethylene glycol, 1, 2 or 1, 3-propanediol, 1, 2, 1, 3 or 1 , 4-butanediol, 1, 2, 1, 3, 1, 4 or 1, 5-pentanediol, 1, 2, 1, 3, 1, 4, 1, 5 or 1, 6 Hexanediol, neopentylhydroxypivalate, neopentylglycol, dipropyleneglycol,
  • the polyol component and / or polyamine component may contain double bonds, which may be e.g. may result from long-chain, aliphatic carboxylic acids or fatty alcohols.
  • a functionalization with olefinic double bonds is z.
  • the polyol component and / or polyamine component are polypropylene diol, polypropylene triol, polypropylene polyol, polyethylene diol, polyethylene triol, polyethylene polyol, polypropylenediamine, polypropylenetriamine, polypropylene polyamine, polyTHF-diamine , Polybutadiene diol, polyester ether diol, polyester triol, polyester polyol, polyester ether diol, polyester ether triol, polyester ether polyol, more preferably polypropylenediol, polypropylene triol, polyTHF diol, polyhexanediol carbamate diol, polycaprolactam diol and polycaprolactam triol. Furthermore, it may also be mixtures of the compounds mentioned.
  • the polyurethanes or polyureas polyols having a molecular weight between 1000 and 10,000, in particular 2000 to 6000 and particularly preferably 3000 to 5000 g / mol.
  • These polyols are more preferably polyTHF-diol, polypropylene glycol and random copolymers and / or block copolymers of ethylene oxide and propylene oxide.
  • they may be polyether polyols, which were prepared in a preferred embodiment by DMC catalysis and in a particularly preferred embodiment by KOH catalysis.
  • the chain extenders used are diols having a molecular weight of from 60 to 500, in particular from 60 to 180, with the dioligomers of glycols being particularly preferred.
  • TDI 2,4- and / or 2,6-tolylene diisocyanate
  • MDI 4,4'-, 2,4'- and / or 2,2'-diphenylmethane diisocyanate
  • IPDI 3,5-trimethyl-5-isocyanatomethyl
  • the polyurethanes or polyureas of the present invention may also contain crosslinker components, chain stopper components, and other reactive components.
  • Some crosslinkers have already been listed among the chain extenders with at least three NCO-reactive hydrogens.
  • it may be glycerin, tetra (2-hydroxypropyl) ethylene diamine, pentaerythritol, trimethylol propane, sorbitol, sucrose, triethanolamine, and polymers having at least three reactive hydrogens (e.g., polyether amines having at least three amine groups, polymeric triols, etc.).
  • Suitable chain stoppers are in particular compounds with reactive hydrogens, such as monools, monoamines, monothiols and monocarboxylic acids.
  • monools are used, with C1 to C12 alcohols (in particular methanol to dodecyl alcohol), higher alcohols, polymers such as polyethers and polyesters having an OH group and structural units such as glycerol or sucrose, in which all but one OH - Group have been implemented, with no further reactive hydrogens were introduced in the implementation, can be used.
  • C1 to C12 alcohols in particular methanol to dodecyl alcohol
  • higher alcohols polymers such as polyethers and polyesters having an OH group and structural units such as glycerol or sucrose, in which all but one OH - Group have been implemented, with no further reactive hydrogens were introduced in the implementation, can be used.
  • UV-resistant variant are as polyol preferably polyester having at least two OH groups, polycarbonates having at least two OH groups, polycarbonate esters having at least two OH groups, PolyTHF, polypropylene glycol, random copolymers and / or block copolymers of ethylene oxide and propylene oxide used.
  • the polyurethanes and polyureas may further contain stabilizing additives, e.g. for protection against UV radiation, oxidation, in particular, additives of the neck type are used.
  • stabilizing additives e.g. for protection against UV radiation, oxidation, in particular, additives of the neck type are used.
  • this is called 4-amino-2,2,6,6-tetramethylpiperidine.
  • polyurethanes and polyureas may be used as latent hardeners oxazolidines, especially oxazolidines from diethanolamine and isobutylaldehyde or pivalaldehyde and / or aldemines from isophoronediamine, e.g. Incozole HP and Imine e.g. Vestamin A139, low molecular weight aliphatic diamines e.g. Hexanediamine and / or polyether polyamines such as e.g. Jeffamine® and isobutyraldehyde or pivalaldehyde and / or a polyamine, e.g. Hexamethylenediamine or a Jeffamine® blocked with a hydroxypivalaldehyde ester can be used.
  • oxazolidines especially oxazolidines from diethanolamine and isobutylaldehyde or pivalaldehyde and / or aldemines from isophoron
  • the binder according to the invention contains polyurethanes or polyureas which have free isocyanate groups.
  • polyurethanes or polyureas which have free isocyanate groups.
  • the isocyanate groups can react with water (including moisture from the atmosphere) to form amine groups which react with the isocyanate groups of the other polyurethane or polyurea molecules thereby forming urea linkages, thereby curing the binder.
  • the polyurethane and / or polyurea may be a one-component system, preferably based on polyether polyol isocyanate prepolymers.
  • the polyurethane and / or polyurea may be a two-component system, preferably based on diphenylmethane diisocyanate (MDI) and a mixture of polyols or amines.
  • the first component here is a polyisocyanate and / or NCO prepolymer and the second component is a polyol and / or polyamine, which may also contain a chain extender. After mixing the two components, the components react with each other, whereby the binder hardens.
  • the binder based on a reaction resin comprises acrylates
  • these are preferably composed of at least one monomer from the series of acrylic esters and methacrylic esters, preferably at least 70% by weight of the polymer being at least one compound of the series of acrylic esters, methacrylic esters and Styrole exists.
  • the monomers of the acrylate component are preferably at least one compound from the series Ethyldiglycolacrylat, 4-tert.
  • it is two or more monomers from the series n-butyl (meth) acrylate, 2-hydroxyethyl (meth) acrylate, acrylic acid, methacrylic acid and methyl methacrylate.
  • copolymers of at least two of the abovementioned monomers are used, the ratio being selected in such a form that the copolymers obtained have the desired performance properties for adhesives and sealants.
  • the skilled worker is familiar with suitable copolymers having the desired performance properties.
  • copolymers of n-butyl acrylate and methyl methacrylate are preferred, which are used in a molar ratio in which the copolymer obtained has a glass transition temperature which lies between those of the corresponding homopolymers.
  • the acrylates of the present invention may be both copolymer and homopolymers.
  • the acrylic acid polymers can furthermore also contain other ethylenically unsaturated monomers, for example isoprenol or hydroxybutyl vinyl ether.
  • ethylenically unsaturated monomers for example isoprenol or hydroxybutyl vinyl ether.
  • examples include mono- and polyunsaturated hydrocarbon monomers, Vinylester (eg. Vinylester C r to C 6 saturated monocarboxylic acids), vinyl ethers, monoethylenically unsaturated mono- and polycarboxylic acids and alkyl esters of these monocarboxylic and polycarboxylic acids (eg.
  • Acrylate and methacrylate esters such as C R to Ci 2 alkyl and in particular C r to C 4 alkyl esters), amino monomers and nitriles, vinyl and alkylvinylidenes and amides of unsaturated carboxylic acids mentioned.
  • unsaturated hydrocarbon monomers comprising styrene compounds (for example styrene, carboxylated styrene and ⁇ -methylstyrene), ethylene, propylene, butylene and conjugated dienes (butadiene, isoprene and copolymers of butadiene and isoprene).
  • vinyl and halovinylidene monomers mention may be made of vinyl chloride, vinylidene chloride, vinyl fluoride and vinylidene fluoride.
  • vinyl esters include aliphatic vinyl esters such as vinyl formate, vinyl acetate, vinyl propionate, vinyl butyrate, vinyl isobutyrate, vinyl valerate, vinyl caproate and allyl esters of saturated monocarboxylic acids such as allyl acetate, allyl propionate and allyl lactate.
  • vinyl ethers mention may be made of methyl vinyl ether, ethyl vinyl ether and n-butyl vinyl ether.
  • Typical vinyl ketones include methyl vinyl ketones, ethyl vinyl ketones and isobutyl vinyl ketones.
  • dialkyl esters of monoethylenically unsaturated dicarboxylic acids include dimethyl maleate, diethyl maleate, dibutyl maleate, dioctyl maleate, diisooctyl, Dinonylmaleat, Diisodecylmaleat, decylmaleat Ditri-, dimethyl fumarate, diethyl fumarate, dipropyl fumarate, dibutyl fumarate, dioctyl tylfumarat, Diisooctylfumarat, Didecylfumarat, dimethyl itaconate, diethyl itaconate, Dibuty- litaconat and dioctyl itaconate.
  • the monoethylenically unsaturated monocarboxylic acids are acrylic acid, methacrylic acid, ethacrylic acid and crotonic acid.
  • the monoethylenically unsaturated dicarboxylic acids maleic acid, fumaric acid, itaconic acid and citric acid.
  • monoethylenically unsaturated tricarboxylic acids for example, aconitic acid and its halogen-substituted derivatives can be used in view of the present invention.
  • the anhydrides and esters of the abovementioned acids for example maleic anhydride and citric anhydride
  • nitriles of ethylenically unsaturated mono-, di- and tricarboxylic acids include acrylonitrile, ⁇ -chloroacrylonitrile and methacrylonitrile.
  • the amides of the carboxylic acids may be acrylamides, methacrylamides and other ⁇ -substituted acrylamides and N-substituted amides, for example N-methylolacrylamide, N-methylolmethylacrylamide, alkylated N-methylolacrylamides and N-methylolmethacrylamides (for example N-methoxymethylacrylamide and N-methoxymethylmethacrylamide).
  • amino monomers it is possible to use substituted and unsubstituted aminoalkyl acrylates, hydrochloride salts of the amino monomers and methacrylates such as ⁇ -aminoethyl acrylate, ⁇ -aminoethyl methacrylate, dimethylaminomethyl acrylate, ⁇ -methylaminoethyl acrylate and dimethylaminomethyl methacrylate.
  • o and ⁇ -ethylenically unsaturated compounds which are suitable for the polymerization and contain primary, secondary or tertiary amino groups, for example dimethylaminoethyl methacrylate, dimethylaminoneopentyl acrylate, dimethylamino-propyl methacrylate and tert-butylaminoethyl methacrylate, or organic and organic compounds, may be mentioned with regard to the cationic monomers inorganic salts of these compounds and / or alkylammonium compounds such as trimethylammoniumethyl methacrylate chloride, diallyldimethylammonium chloride, ⁇ -acetamididiethylaminoethyl acrylate chloride and methacrylamidopropyltrimethylammonium chloride.
  • cationic monomers can be used alone or in combination with the aforementioned other monomers.
  • hydroxy-containing monomers are the ⁇ -hydroxyethyl (meth) acrylates, ⁇ -hydroxypropyl (meth) acrylates and Y-hydroxypropyl (meth) acrylates.
  • the binder based on a reaction resin comprises epoxy resins, these are preferably liquid below 160 ° C.
  • epoxy resins are:
  • A) polyglycidyl and poly (.beta.-methylglycidyl) esters obtainable by reacting a compound having at least two carboxyl groups in the molecule and epichlorohydrin or beta-methylpichlorohydrin. The reaction is conveniently carried out in the presence of bases.
  • aliphatic polycarboxylic acids can be used as a compound having at least two carboxyl groups in the molecule. Examples of such polycarboxylic acids are oxalic acid, succinic acid, glutaric acid, adipic acid, pimelic acid, suberic acid, azelaic acid or dimerized or trimerized linoleic acid.
  • cycloaliphatic polycarboxylic acids for example tetrahydrophthalic acid, 4-methyltetrahydrophthalic acid, hexahydrophthalic acid or 4-methylhexahydrophthalic acid.
  • aromatic polycarboxylic acids for example phthalic acid, isophthalic acid or terephthalic acid.
  • polyglycidyl or poly ( ⁇ -methylglycidyl) ethers obtainable by reacting a compound having at least two free alcoholic hydroxyl groups and / or phe- nolic hydroxy groups and epichlorohydrin or ⁇ -methylepichlorohydrin under alkaline conditions, or in the presence of an acid catalyst and subsequent alkali treatment.
  • the glycidyl ethers of this type are derived, for example, from acyclic alcohols, such as ethylene glycol, diethylene glycol and higher poly (oxyethylene) glycols, propane-1, 2-diol or poly (oxypropylene) glycols, propane-1,3 -diol, butane-1,4-diol, poly (oxytetramethylene) glycols, pentane-1, 5-diol, hexane-1, 6-diol, hexane-2,4,6-triol, glycerine, 1 , 1, 1 -Trimethylolpropan, pentaerythritol, sorbitol, and of polyepichlorohydrins.
  • acyclic alcohols such as ethylene glycol, diethylene glycol and higher poly (oxyethylene) glycols, propane-1, 2-diol or poly (oxypropylene) glycols, propane-1,3 -diol, but
  • cycloaliphatic alcohols such as 1,4-cyclohexanedimethanol, bis (4-hydroxycyclohexyl) methane or 2,2-bis (4-hydroxycyclohexyl) propane, or they have aromatic nuclei, such as N , N-bis (2-hydroxyethyl) aniline or p, p'-bis (2-hydroxyethylamino) diphenylmethane.
  • the glycidyl ethers may also be derived from mononuclear phenols, such as resorcinol or hydroquinone, or based on polynuclear phenols, such as bis (4-hydroxyphenyl) methane, 4,4'-dihydroxybiphenyl, bis (4-hydroxyphenyl) methane.
  • hydroxyphenyl) sulfone 1,1,2,2-tetrakis- (4-hydroxyphenyl) -ethane, 2,2-bis- (4-hydroxyphenyl) -propane, 2,2-bis- (3,5-dibromo-) 4-hydroxyphenyl) -propane and novolaks obtainable by condensation of aldehydes, such as formaldehyde, acetaldehyde, chloral or furfuraldehyde, with phenols, such as phenol, or with phenols which are substituted in the nucleus by chlorine atoms or C r C 9 alkyl groups , such as 4-chlorophenol, 2-methylphenol, or 4-tert-butylphenol or by condensation with bisphenols, those of the type mentioned above.
  • aldehydes such as formaldehyde, acetaldehyde, chloral or furfuraldehyde
  • phenols such as phenol
  • C r C 9 alkyl groups such as 4-ch
  • the poly (N-glycidyl) compounds also include triglycidyl isocyanurate, ⁇ , ⁇ '-diglycidyl derivatives of cycloalkylene ureas, such as ethyleneurea or 1,3-propyleneurea, and diglycidyl derivatives of hydantoins, such as of 5,5-dimethylhydantoin.
  • D) Poly (S-glycidyl) compounds for example di-S-glycidyl derivatives derived from dithiols such as ethane-1,2-dithiol or bis (4-mercaptomethylphenyl) ether.
  • cycloaliphatic epoxy resins for example bis (2,3-epoxycyclopentyl) ether, 2,3-epoxycyclopentyl glycidyl ether, 1,2-bis (2,3-epoxycyclopentyloxy) ethane or 3,4-
  • Epoxycyclohexylmethyl-3 ', 4'-epoxycyclohexane Epoxycyclohexylmethyl-3 ', 4'-epoxycyclohexane.
  • epoxy resins in which the 1,2-epoxide groups are bonded to different heteroatoms or functional groups; these compounds include, for example, the ⁇ , ⁇ , ⁇ -triglycidyl derivative of 4-aminophenol, the glycidyl ether glycidyl ester of salicylic acid, N-glycidyl-N '- (2-glycidyloxypropyl) -5, 5-dimethylhydantoin or 2-glycidyloxy-1, 3-bis- (5,5-dimethyl-1-glycidylhydantoin-3-yl) -propane.
  • these compounds include, for example, the ⁇ , ⁇ , ⁇ -triglycidyl derivative of 4-aminophenol, the glycidyl ether glycidyl ester of salicylic acid, N-glycidyl-N '- (2-glycidyloxypropyl) -5, 5-dimethylhydantoin or 2-gly
  • a liquid polyglycidyl ether or ester in particular a liquid bisphenol diglycidyl ether or a liquid diglycidyl ester of a cycloaliphatic or aromatic dicarboxylic acid. It is also possible to use mixtures of epoxy resins.
  • the binder based on a reaction resin in an amount of 0.5 to 5 wt .-%, preferably 1 to 3 wt .-%, based on the aggregate are used. This ensures an effective clamping of the Zuscherstoffs, which also form the required cavities in the form of a porous matrix. Since it is the polyurethane and / or polyurea is the most expensive component of the covering, it is economically advantageous to use the smallest possible amount of this component.
  • the aggregate is preferably an aggregate, in particular quartz sand, basalt, granite, greywacke and / or diabase with an average particle diameter between 1 and 20 mm, preferably between 2 and 12 mm, particularly preferably between 4 and 8 mm.
  • the choice of aggregate has an influence on the abrasion of the coating, which is determined according to DIN 52108. Granite and basalt should be mentioned as particularly abrasion-resistant.
  • the porous matrix has a volume fraction of void fraction of 15 to 45%, preferably 20 to 40%, in particular 25 to 35%.
  • the traffic area according to the invention preferably comprises a supporting layer, as is known in the prior art.
  • the base layer comprises an antifreeze layer on which additional soft layers are applied.
  • the further layers may be an asphalt base course, an asphalt binder course and a stress relieving sealing adhesive bridge.
  • a concrete floor or concrete screed is usually sufficient as the base course.
  • the thickness of the respective layers must be adapted to the respective application and can be found, for example, in the "Guidelines for the Standardization of the Traffic Areas - RStO", published by the FGSV, Anlagensgesellschaft fürense- und pulp- nen eV, Cologne, and the "Merkblatt for the production of semi-rigid surface layers M HD ".
  • the covering according to the invention which is preferably applied to a base layer, has in particular a thickness of between 1 and 25 cm, preferably between 2 and 12 cm, particularly preferably between 3 and 8 cm.
  • the cured inorganic binder, with which the cavities of the porous matrix are filled preferably contains at least one hydraulic binder, in particular cement, particularly preferably Portland cement.
  • the cured inorganic binder may contain at least one latent hydraulic binder, in particular pozzolan, volcanic slag, volcanic tuff, fly ash, blast furnace slag, microsilica, kaolin, metakaolin, activated clay, Trass, pozzolanic earth, kieselguhr, diatomaceous earth and an alkaline excipient, most preferably waterglass ,
  • the cured inorganic binder comprises at least one filler from the series quartz sand, quartz, limestone, barite, calcite, dolomite, talc, kaolin, mica and chalk.
  • the hardened inorganic binder may contain at least one additive from the series of plasticizers, redispersible polymer powders, defoamers, stabilizers, water retention agents, thickeners, dedusting agents, accelerators, retarders and pigments.
  • the covering according to the invention has a preferred compressive strength of> 5 N / mm 2 , in particular> 10 N / mm 2 and particularly preferably> 20 N / mm 2 , 24 hours after it has been produced.
  • the present invention also proposes a process for producing a coating according to the invention, wherein the additive is mixed with a binder based on a reaction resin and the mixture is applied in the desired thickness on a substrate and after curing of the binder based on a reaction resin, the resulting Cavities are filled with the inorganic binder.
  • the mixing of the additive with a binder based on a reaction resin can be carried out in any manner known to those skilled in the art.
  • compulsory mixers such as concrete or screed mixers are suitable.
  • the use of a drill with attached basket stirrer is possible.
  • the inorganic binder is introduced in the form of a flowable mortar into the cavities, which are formed by the aggregate clasped with the binder based on a reaction resin. the.
  • the maximum particle size should be ⁇ 2 mm, preferably ⁇ 1 mm, particularly preferably ⁇ 0.4 mm.
  • the cavities of the porous matrix of an aggregate and the binder based on a reaction resin are filled as completely as possible with the mortar. It is particularly advantageous if the mortar used has a high flowability to penetrate into small cavities. As a result, a particularly dense and high-strength coating is formed, which holds high mechanical loads particularly well.
  • the mortar is applied to the surface of the porous matrix and should preferably have a fluidity such that the mortar penetrates as completely as possible into all cavities of the porous matrix by gravity and displaces the air contained therein. In special cases, the introduction of the mortar into the cavities of the porous matrix can be supported mechanically, for example by vibration.
  • the mortar is incorporated into the porous matrix in an amount such that the cured inorganic binder and the porous matrix together form the surface of the pad.
  • condenser When cement is used for the high-strength cured inorganic binder, it is advantageous to apply the mortar with the least possible amount of water and to use a condenser.
  • the condenser is also essential to achieve the desired high flowability of the mortar.
  • all known condenser can be used.
  • liquefiers for hydraulically setting mortar systems substances based on lignin sulfonate are known, for example, from WO 97/13732.
  • DE 19538821 describes sulfonate-containing condensation products based on amino-s-triazines having at least two amino groups and formaldehyde.
  • condensates of sulfonated aromatics and formaldehyde are described.
  • EP 792850 further cementitious compositions which contain as the condenser copolymers of short-chain polyalkylene glycol (meth) acrylates, long-chain polyalkylene glycol (meth) acrylates and ethylenically unsaturated carboxylic acids.
  • EP 590983 relates to cement liquefiers based on copolymers of (meth) acrylic acid, ethylenically unsaturated sulfonates, polyethylene glycol (meth) allyl ethers, esters of (meth) acrylic acid with polyethylene glycol monoethers, and optionally (meth) acrylic acid esters.
  • DE 10063291 describes polycarboxylate-based cement liquefiers, in which copolymer comonomer units with polyoxyalkylene groups and comonomer units with OH, CO or sulfonate groups are also contained.
  • EP 816298 describes plasticizers which are obtained by copolymerization of polyoxyethylene-functional monomers, polyoxyethylene-polyoxypropylene-containing monomers and ethylenically unsaturated sulfonate-functional comonomers.
  • polycarboxylate or polycarboxylate ether base have proven to be suitable as plasticizers for the present invention.
  • the amount of condenser used is generally between 0.1 and 5 wt .-% based on the dry mortar.
  • the inorganic binder is introduced in the form of a dry mortar in the cavities, in particular by einlawen.
  • a gentle entry of the water in the form of a spray and / or surface irrigation is preferred.
  • the way in which water is introduced can be done for example with a lawn sprinkler, a water sprinkler, a garden hose with or without dispensing nozzle and / or a watering can. It is advantageous that the duration of the irrigation is chosen so that the water can penetrate as possible through the entire surface, so that the mortar has enough water for hydration.
  • the covering according to the invention can be modified on its surface depending on the intended use. In this case, it is possible, for example, for the surfaces to be ground, polished or shot peened. Before the inorganic binder is cured, the surface of the coating can also be subjected to a fine-grained material, in particular sand or split, in order to increase the initial grip of the coating.
  • the covering according to the invention is preferably a covering layer for a traffic area, which may be, in particular, parking decks, industrial floors such as warehouses, assembly and manufacturing spaces, port facilities, order picking areas, exhibition halls, hangars, loading areas, aircraft operating areas, container shelves and roads ,
  • the coating according to the invention has the advantage that it is particularly resistant and resistant to abrasion in the respective applications and can withstand high pressure loads in the long run.
  • the coating according to the invention is still
  • the covering has a good grip and a very good freeze-thaw resistance and can be installed within a very short time and released for traffic.
  • Microsilica (Eikern microsilica, Eikern AS) 4.70% by weight
  • Elastopave 6551/102 component A additive-containing polyol blend, Elastogran GmbH
  • Elastopave 6551/102 component B diphenylmethane diisocyanate (MDI) containing formulation, Elastogran GmbH
  • PU component 98 parts of quartz sand with a grain size of 4-8mm were mixed homogeneously with 2 parts PU component and placed in three prismatic molds with the dimensions 160x40x40mm.
  • the prisms (PU-sand matrix) were 24 h at 23 ° C and 50% rel. Moisture stored.
  • the grout was mixed with the required quantity of mixing water to form a homogenous fresh mortar.
  • the prism shapes with the PU sand matrix were filled with the fresh mortar and at 23 ° C and 50% rel. Moisture stored. After 24 h hardening time, the prism shapes were removed and the prism body
  • Grout 1 150g 8.4MPa / 61.6MPa
  • Grout 2 240g 3.3MPa / 16.0MPa
  • 3 140g 28MPa / 40MPa

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Structural Engineering (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Architecture (AREA)
  • Civil Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Polyurethanes Or Polyureas (AREA)

Abstract

L'invention concerne un revêtement comprenant une matrice poreuse, constituée d'un granulat et d'un liant à base d'une résine réactive. Dans ce cadre, les particules de granulat sont mutuellement bloquées par le liant à base d'une résine réactive et les vides de la matrice poreuse sont remplis d'un liant inorganique durci. L'invention concerne en outre un procédé de fabrication dudit revêtement, ainsi que son utilisation.
PCT/EP2011/059707 2010-06-29 2011-06-10 Couche de recouvrement semi-rigide WO2012000773A1 (fr)

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EP10167717 2010-06-29
EP10167717.7 2010-06-29

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE202013102414U1 (de) 2013-06-05 2014-09-08 René Scheitenberger Mehrkomponentenkit zur Herstellung einer raumfüllenden elastischen Strukturmasse als Endprodukt
WO2015124313A1 (fr) * 2014-02-22 2015-08-27 Heidelbergcement Ag Mortier sec, suspension de mortier et procédé de fabrication de revêtements semi-solidifiés

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE202013102414U1 (de) 2013-06-05 2014-09-08 René Scheitenberger Mehrkomponentenkit zur Herstellung einer raumfüllenden elastischen Strukturmasse als Endprodukt
WO2015124313A1 (fr) * 2014-02-22 2015-08-27 Heidelbergcement Ag Mortier sec, suspension de mortier et procédé de fabrication de revêtements semi-solidifiés

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