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WO2011016991A3 - Agents de transfert réversible de chaînes à têtes doubles ou multiples, et leur utilisation pour la préparation de copolymères séquencés - Google Patents

Agents de transfert réversible de chaînes à têtes doubles ou multiples, et leur utilisation pour la préparation de copolymères séquencés Download PDF

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Publication number
WO2011016991A3
WO2011016991A3 PCT/US2010/042605 US2010042605W WO2011016991A3 WO 2011016991 A3 WO2011016991 A3 WO 2011016991A3 US 2010042605 W US2010042605 W US 2010042605W WO 2011016991 A3 WO2011016991 A3 WO 2011016991A3
Authority
WO
WIPO (PCT)
Prior art keywords
headed
dual
shuttling agents
preparation
block copolymers
Prior art date
Application number
PCT/US2010/042605
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English (en)
Other versions
WO2011016991A2 (fr
Inventor
Daniel Arriola
Thomas Clark
Kevin Frazier
Sara Klamo
Francis Timmers
Original Assignee
Dow Global Technologies Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Global Technologies Inc. filed Critical Dow Global Technologies Inc.
Priority to KR1020127002417A priority Critical patent/KR101688253B1/ko
Priority to EP18212194.7A priority patent/EP3489264B1/fr
Priority to BR112012001948-1A priority patent/BR112012001948B1/pt
Priority to US13/377,451 priority patent/US8501885B2/en
Priority to SG2012005534A priority patent/SG178111A1/en
Priority to JP2012522894A priority patent/JP5726873B2/ja
Priority to CN201080033597XA priority patent/CN102498133B/zh
Priority to ES10737196.5T priority patent/ES2651292T3/es
Priority to EP10737196.5A priority patent/EP2459598B1/fr
Priority to EP17164138.4A priority patent/EP3243846B1/fr
Publication of WO2011016991A2 publication Critical patent/WO2011016991A2/fr
Publication of WO2011016991A3 publication Critical patent/WO2011016991A3/fr

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
    • C07F5/06—Aluminium compounds
    • C07F5/061—Aluminium compounds with C-aluminium linkage
    • C07F5/062—Al linked exclusively to C
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F3/00—Compounds containing elements of Groups 2 or 12 of the Periodic Table
    • C07F3/02—Magnesium compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F3/00—Compounds containing elements of Groups 2 or 12 of the Periodic Table
    • C07F3/06—Zinc compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/60—Polymerisation by the diene synthesis
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F299/00—Macromolecular compounds obtained by interreacting polymers involving only carbon-to-carbon unsaturated bond reactions, in the absence of non-macromolecular monomers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2420/00—Metallocene catalysts
    • C08F2420/02—Cp or analog bridged to a non-Cp X anionic donor
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Graft Or Block Polymers (AREA)
  • Polymerisation Methods In General (AREA)

Abstract

L'invention concerne des catalyseurs de polymérisation d'oléfines et des compositions associées, leur fabrication et la production de polyoléfines à l'aide de compositions catalytiques spécifiques, y compris l'utilisation d'agents de transfert réversible de chaînes dans le processus de polymérisation d'oléfines. En particulier, l'invention concerne des agents de transfert réversible de chaînes à têtes doubles ou multiples (CSA ou MSA), et leur utilisation pour la préparation de copolymères séquencés. La commande du rapport enter les sites CSA à têtes doubles ou multiples et les sites CSA à tête unique, permet d'obtenir un copolymère séquencé présentant des propriétés telles qu'une distribution étroite des poids moléculaires et/ou des propriétés de fusion améliorées.
PCT/US2010/042605 2009-07-29 2010-07-20 Agents de transfert réversible de chaînes à têtes doubles ou multiples, et leur utilisation pour la préparation de copolymères séquencés WO2011016991A2 (fr)

Priority Applications (10)

Application Number Priority Date Filing Date Title
KR1020127002417A KR101688253B1 (ko) 2009-07-29 2010-07-20 이중- 또는 다중-헤드 사슬 이동제 및 그의 블록 공중합체의 제조에서의 용도
EP18212194.7A EP3489264B1 (fr) 2009-07-29 2010-07-20 Agents de transfert de chaînes et leur utilisation pour la préparation de copolymères séquencés
BR112012001948-1A BR112012001948B1 (pt) 2009-07-29 2010-07-20 Agente de translado de cadeia, processo para a polimerização de pelo menos um monômero polimerizável por adição, copolímero em multi-bloco e composição de catalisador
US13/377,451 US8501885B2 (en) 2009-07-29 2010-07-20 Dual- or multi-headed chain shuttling agents and their use for preparation of block copolymers
SG2012005534A SG178111A1 (en) 2009-07-29 2010-07-20 Dual- or multi-headed chain shuttling agents and their use for the preparation of block copolymers
JP2012522894A JP5726873B2 (ja) 2009-07-29 2010-07-20 二頭又は多頭連鎖シャトリング剤、及びブロックコポリマーの調製のためのそれらの使用
CN201080033597XA CN102498133B (zh) 2009-07-29 2010-07-20 双头基或多头基的链穿梭剂以及它们用于制备嵌段共聚物的用途
ES10737196.5T ES2651292T3 (es) 2009-07-29 2010-07-20 Agentes de transferencia de cadena de doble o múltiple cabeza y su uso para la preparación de copolímeros de bloque
EP10737196.5A EP2459598B1 (fr) 2009-07-29 2010-07-20 Agents de transfert réversible de chaînes à têtes doubles ou multiples, et leur utilisation pour la préparation de copolymères séquencés
EP17164138.4A EP3243846B1 (fr) 2009-07-29 2010-07-20 Agents de transfert réversible de chaînes à têtes multiples et leur utilisation pour la préparation de copolymères séquencés

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US22961009P 2009-07-29 2009-07-29
US61/229,610 2009-07-29

Publications (2)

Publication Number Publication Date
WO2011016991A2 WO2011016991A2 (fr) 2011-02-10
WO2011016991A3 true WO2011016991A3 (fr) 2011-06-16

Family

ID=43023262

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2010/042605 WO2011016991A2 (fr) 2009-07-29 2010-07-20 Agents de transfert réversible de chaînes à têtes doubles ou multiples, et leur utilisation pour la préparation de copolymères séquencés

Country Status (9)

Country Link
US (1) US8501885B2 (fr)
EP (3) EP2459598B1 (fr)
JP (3) JP5726873B2 (fr)
KR (1) KR101688253B1 (fr)
CN (1) CN102498133B (fr)
BR (1) BR112012001948B1 (fr)
ES (3) ES2894689T3 (fr)
SG (1) SG178111A1 (fr)
WO (1) WO2011016991A2 (fr)

Families Citing this family (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0642994B2 (ja) 1986-12-19 1994-06-08 古河アルミニウム工業株式会社 ドロンカツプ型熱交換器用アルミニウムブレ−ジングシ−ト
KR101688253B1 (ko) * 2009-07-29 2016-12-20 다우 글로벌 테크놀로지스 엘엘씨 이중- 또는 다중-헤드 사슬 이동제 및 그의 블록 공중합체의 제조에서의 용도
EP3356374A1 (fr) * 2015-09-30 2018-08-08 Dow Global Technologies LLC Compositions multitêtes ou à double tête utiles dans le transfert de chaîne et leur procédé de préparation
BR112018004696B1 (pt) * 2015-09-30 2022-06-28 Dow Global Technologies Llc Processo para a preparação de um polímero funcional
EP3293002A1 (fr) 2016-09-09 2018-03-14 Dow Global Technologies LLC Films multicouches et laminés et emballages formés à partir de ceux-ci
KR102464765B1 (ko) * 2016-09-30 2022-11-09 다우 글로벌 테크놀로지스 엘엘씨 사슬 이동에 유용한 다중 또는 이중 헤드 조성물의 제조 방법
JP7096236B2 (ja) * 2016-09-30 2022-07-05 ダウ グローバル テクノロジーズ エルエルシー チェーンシャトリングに有用なマルチヘッドまたはデュアルヘッド組成物、およびそれを調製するプロセス
EP3519456B1 (fr) * 2016-09-30 2024-07-03 Dow Global Technologies Llc Compositions à plusieurs têtes ou à deux têtes coiffées, utiles pour la polymérisation en chaîne par navette, et leur procédé de préparation
EP3372401B1 (fr) 2017-03-10 2020-02-05 Dow Global Technologies Llc Films multicouches et procédés correspondants
EP3596143B1 (fr) 2017-03-15 2023-04-26 Dow Global Technologies LLC Système catalytique pour la formation d'un copolymère multi-séquencé
EP3596142B1 (fr) 2017-03-15 2023-05-24 Dow Global Technologies LLC Système catalytique pour formation de copolymère à blocs multiples
CN110582518B (zh) 2017-03-15 2022-08-09 陶氏环球技术有限责任公司 用于形成多嵌段共聚物的催化剂体系
ES2979233T3 (es) 2017-03-15 2024-09-25 Dow Global Technologies Llc Sistema de catalizador para la formación de copolímero multibloque
KR102711048B1 (ko) 2017-03-15 2024-09-27 다우 글로벌 테크놀로지스 엘엘씨 다중-블록 공중합체 형성을 위한 촉매 시스템
CA3068535A1 (fr) 2017-06-29 2019-01-03 Dow Global Technologies Llc Charnieres souples en plastique avec polymere composite sequence
US11131130B2 (en) 2017-06-29 2021-09-28 Dow Global Technologies Llc Plastic living hinges with block composite polymer
EP3732211B1 (fr) 2017-12-29 2024-05-22 Dow Global Technologies Llc Compositions d'organoaluminium à deux têtes coiffées
CN119684341A (zh) * 2017-12-29 2025-03-25 陶氏环球技术有限责任公司 双头有机铝组合物
CN111868110A (zh) 2018-03-19 2020-10-30 陶氏环球技术有限责任公司 硅封端的远螯聚烯烃组合物和其制备方法
JP7378416B2 (ja) 2018-03-19 2023-11-13 ダウ シリコーンズ コーポレーション ポリオレフィン－ポリジオルガノシロキサンブロックコポリマーおよびその合成のための方法
CN111868196B (zh) 2018-03-19 2022-08-30 美国陶氏有机硅公司 含有聚烯烃-聚二有机硅氧烷共聚物的聚有机硅氧烷热熔胶组合物和其制备和使用方法
BR112020019180A2 (pt) 2018-03-19 2021-01-05 Dow Global Technologies Llc Compostos organometálicos terminados em silício e processos para preparar os mesmos
BR112020019193A2 (pt) 2018-03-19 2021-01-05 Dow Global Technologies Llc Compostos organometálicos terminados em silício e processos para preparar os mesmos
CN111886314B (zh) 2018-03-19 2022-06-17 美国陶氏有机硅公司 含有聚烯烃-聚二有机硅氧烷嵌段共聚物的热熔胶组合物和其制备和使用方法
CN111741997B (zh) 2018-03-19 2022-08-09 美国陶氏有机硅公司 聚烯烃-聚二有机硅氧烷嵌段共聚物及用于其合成的氢化硅烷化反应方法
JP2021518406A (ja) 2018-03-19 2021-08-02 ダウ グローバル テクノロジーズ エルエルシー シリル系官能化剤で有機金属化合物を官能化するためのプロセスおよびそれにより調製されたシリル官能化化合物
WO2020000337A1 (fr) 2018-06-29 2020-01-02 Dow Global Technologies Llc Bille de mousse et structure de mousse frittée
JP7334195B2 (ja) 2018-07-17 2023-08-28 ダウ シリコーンズ コーポレーション ポリシロキサン樹脂－ポリオレフィンコポリマー並びにその調製方法及び使用方法
CN110804130A (zh) * 2019-10-30 2020-02-18 上海交通大学 支化链长可控、支化程度可控的超支化聚烯烃的合成方法

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2007035493A2 (fr) * 2005-09-15 2007-03-29 Dow Global Technologies Inc. Regulation de l'architecture et de la distribution du poids moleculaire des polymeres par le biais d'un agent navette multicentre

Family Cites Families (102)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US204017A (en) 1878-05-21 Improvement in cartridge-packages
US3485706A (en) 1968-01-18 1969-12-23 Du Pont Textile-like patterned nonwoven fabrics and their production
US3758643A (en) 1971-01-20 1973-09-11 Uniroyal Inc D polyolefin plastic thermoplastic blend of partially cured monoolefin copolymer rubber an
US3806558A (en) 1971-08-12 1974-04-23 Uniroyal Inc Dynamically partially cured thermoplastic blend of monoolefin copolymer rubber and polyolefin plastic
US4130535A (en) 1975-07-21 1978-12-19 Monsanto Company Thermoplastic vulcanizates of olefin rubber and polyolefin resin
US4104210A (en) 1975-12-17 1978-08-01 Monsanto Company Thermoplastic compositions of high unsaturation diene rubber and polyolefin resin
US4340684A (en) 1977-06-13 1982-07-20 The Firestone Tire & Rubber Company Thermoplastic elastomer blends
US4250273A (en) 1977-06-13 1981-02-10 The Firestone Tire & Rubber Company Thermoplastic elastomer blends
US4311628A (en) 1977-11-09 1982-01-19 Monsanto Company Thermoplastic elastomeric blends of olefin rubber and polyolefin resin
US4202801A (en) 1977-12-30 1980-05-13 Uniroyal, Inc. Thermoplastic elastomer composition
US4271049A (en) 1979-09-10 1981-06-02 Monsanto Company Elastoplastic compositions of cured diene rubber and polypropylene
US4322027A (en) 1980-10-02 1982-03-30 Crown Zellerbach Corporation Filament draw nozzle
US4413110A (en) 1981-04-30 1983-11-01 Allied Corporation High tenacity, high modulus polyethylene and polypropylene fibers and intermediates therefore
US4543399A (en) 1982-03-24 1985-09-24 Union Carbide Corporation Fluidized bed reaction systems
US4588790A (en) 1982-03-24 1986-05-13 Union Carbide Corporation Method for fluidized bed polymerization
US4430563A (en) 1982-04-30 1984-02-07 Minnesota Mining And Manufacturing Company Data processing form
US4663220A (en) 1985-07-30 1987-05-05 Kimberly-Clark Corporation Polyolefin-containing extrudable compositions and methods for their formation into elastomeric products including microfibers
US4668566A (en) 1985-10-07 1987-05-26 Kimberly-Clark Corporation Multilayer nonwoven fabric made with poly-propylene and polyethylene
US4798081A (en) 1985-11-27 1989-01-17 The Dow Chemical Company High temperature continuous viscometry coupled with analytic temperature rising elution fractionation for evaluating crystalline and semi-crystalline polymers
US5153157A (en) 1987-01-30 1992-10-06 Exxon Chemical Patents Inc. Catalyst system of enhanced productivity
PL276385A1 (en) 1987-01-30 1989-07-24 Exxon Chemical Patents Inc Method for polymerization of olefines,diolefins and acetylene unsaturated compounds
US5248729A (en) 1987-12-28 1993-09-28 Nippon Petrochemicals Company Limited Process for preparing thermoplastic resin composition
FR2634212B1 (fr) 1988-07-15 1991-04-19 Bp Chimie Sa Appareillage et procede de polymerisation d'olefines en phase gazeuse dans un reacteur a lit fluidise
US4927882A (en) 1988-10-11 1990-05-22 The West Company, Incorporated SBR thermoplastic elastomer
US5064802A (en) 1989-09-14 1991-11-12 The Dow Chemical Company Metal complex compounds
FR2656314B1 (fr) 1989-12-22 1992-04-17 Bp Chemicals Snc Catalyseur a base de zirconium supporte sur du chlorure de magnesium, procede de preparation et utilisation du catalyseur dans la polymerisation des olefines.
US5032562A (en) 1989-12-27 1991-07-16 Mobil Oil Corporation Catalyst composition and process for polymerizing polymers having multimodal molecular weight distribution
JP2545006B2 (ja) 1990-07-03 1996-10-16 ザ ダウ ケミカル カンパニー 付加重合触媒
US5051478A (en) 1990-07-26 1991-09-24 Advanced Elastomer Systems, L. P. Ethylene copolymer - modified dynamically vulcanized alloys
US5721185A (en) 1991-06-24 1998-02-24 The Dow Chemical Company Homogeneous olefin polymerization catalyst by abstraction with lewis acids
US5210338A (en) 1991-10-25 1993-05-11 Ethyl Corporation Catalyzed chain growth process
US6545088B1 (en) 1991-12-30 2003-04-08 Dow Global Technologies Inc. Metallocene-catalyzed process for the manufacture of EP and EPDM polymers
DE69211569T2 (de) 1991-12-30 1997-01-23 Dow Chemical Co Ethyleninterpolymeren polymerisation
KR100262023B1 (ko) 1992-01-06 2000-07-15 그레이스 스티븐 에스. 개선된 촉매 조성물
US5436304A (en) 1992-03-19 1995-07-25 Exxon Chemical Patents Inc. Process for polymerizing monomers in fluidized beds
US5352749A (en) 1992-03-19 1994-10-04 Exxon Chemical Patents, Inc. Process for polymerizing monomers in fluidized beds
US5296433A (en) 1992-04-14 1994-03-22 Minnesota Mining And Manufacturing Company Tris(pentafluorophenyl)borane complexes and catalysts derived therefrom
US5350723A (en) 1992-05-15 1994-09-27 The Dow Chemical Company Process for preparation of monocyclopentadienyl metal complex compounds and method of use
BE1005957A5 (fr) 1992-06-05 1994-04-05 Solvay Procede de preparation d'un systeme catalytique, procede de (co)polymerisation d'olefines et (co)polymeres d'au moins une olefine.
US5276220A (en) 1992-06-18 1994-01-04 Ethyl Corporation Actinide catalyzed chain growth process
EP0662979B1 (fr) 1992-10-02 1997-07-16 The Dow Chemical Company Complexes de catalyseurs supportes et homogenes utilises dans la polymerisation d'olefines
US5332706A (en) 1992-12-28 1994-07-26 Mobil Oil Corporation Process and a catalyst for preventing reactor fouling
US5608019A (en) 1992-12-28 1997-03-04 Mobil Oil Corporation Temperature control of MW in olefin polymerization using supported metallocene catalyst
US6448341B1 (en) 1993-01-29 2002-09-10 The Dow Chemical Company Ethylene interpolymer blend compositions
ATE195538T1 (de) 1993-01-29 2000-09-15 Dow Chemical Co Äthylen copolymerisation
TW298593B (fr) 1993-02-12 1997-02-21 Hoechst Ag
JP3077940B2 (ja) 1993-04-26 2000-08-21 エクソン・ケミカル・パテンツ・インク 流動層重合法のための安定な操作条件を決定する方法
US5462999A (en) 1993-04-26 1995-10-31 Exxon Chemical Patents Inc. Process for polymerizing monomers in fluidized beds
BE1007148A3 (fr) 1993-05-17 1995-04-11 Solvay Support pour catalyseurs, procede pour la fabrication d'un gel precurseur d'un support pour catalyseurs, procede de preparation d'un support pour catalyseurs, catalyseur pour la polymerisation d'olefines et procede pour la polymerisation d'olefines au moyen de ce catalyseur.
FR2705252B1 (fr) 1993-05-19 1995-07-21 Bp Chemicals Snc Procédé d'introduction d'un solide dans un réacteur et appareillage.
ZA943399B (en) 1993-05-20 1995-11-17 Bp Chem Int Ltd Polymerisation process
US5372682A (en) 1993-06-24 1994-12-13 The Dow Chemical Company Electrochemical preparation of addition polymerization catalysts
DE69421411T2 (de) 1993-11-19 2000-06-08 Exxon Chemical Patents, Inc. Polymerisationskatalysatorsysteme, ihre herstellung und verwendung
JPH07144455A (ja) 1993-11-25 1995-06-06 Canon Inc インクジェット記録装置
US5648310A (en) 1993-12-23 1997-07-15 Union Carbide Chemicals & Plastics Technology Corporation Spray dried, filled metallocene catalyst composition for use in polyolefin manufacture
US5672669A (en) 1993-12-23 1997-09-30 Union Carbide Chemicals & Plastics Technology Corporation Spray dried, filled metallocene catalyst composition for use in polyolefin manufacture
US5461123A (en) 1994-07-14 1995-10-24 Union Carbide Chemicals & Plastics Technology Corporation Gas phase fluidized bed polyolefin polymerization process using sound waves
US5453471B1 (en) 1994-08-02 1999-02-09 Carbide Chemicals & Plastics T Gas phase polymerization process
US5625087A (en) 1994-09-12 1997-04-29 The Dow Chemical Company Silylium cationic polymerization activators for metallocene complexes
US5616661A (en) 1995-03-31 1997-04-01 Union Carbide Chemicals & Plastics Technology Corporation Process for controlling particle growth during production of sticky polymers
US5869723A (en) 1995-06-08 1999-02-09 Showa Denko K.K. Ionic compound and olefin polymerization catalyst containing the same
US5869575A (en) 1995-08-02 1999-02-09 The Dow Chemical Company Ethylene interpolymerizations
US6051681A (en) 1995-11-17 2000-04-18 Dsm N.V. Process for the preparation of a thermoplastic elastomer
KR20000005027A (ko) 1996-03-27 2000-01-25 그레이스 스티븐 에스. 분산된 촉매 활성화제를 사용하는 용액 중합 방법
BR9708232A (pt) 1996-03-27 1999-08-03 Dow Chemical Co Ativador de catalisador sistema de catalisador para polimerização de alfa-olefinas e processo de polimerização
US5977251A (en) 1996-04-01 1999-11-02 The Dow Chemical Company Non-adiabatic olefin solution polymerization
KR100528754B1 (ko) 1996-08-08 2006-01-09 다우 글로벌 테크놀로지스 인크. 3-헤테로원자 치환된 사이클로펜타디에닐-함유 금속 착체 및 올레핀 중합 방법
US5854166A (en) 1996-08-19 1998-12-29 Northwestern University Synthesis and use of (perfluoroaryl) fluoro-aluminate anion
EP0927201B1 (fr) 1996-09-06 2004-04-14 Hyundai Petrochemical Co., Ltd. Systeme de catalyseur destine a la (co)polymerisation d'olefines, et procede de preparation de (co)polymeres olefiniques mettant en oeuvre ce systeme
US5783512A (en) 1996-12-18 1998-07-21 The Dow Chemical Company Catalyst component dispersion comprising an ionic compound and solid addition polymerization catalysts containing the same
FI970349A7 (fi) 1997-01-28 1998-07-29 Borealis As Uudet metalloseeniyhdisteiden aktivaattorisysteemit
ES2187005T3 (es) 1997-02-07 2003-05-16 Exxonmobil Chem Patents Inc Polimeros de propileno que incorporan macromeros de polietileno.
US6319989B1 (en) 1997-07-21 2001-11-20 The Dow Chemical Company Broad MWD, compositionally uniform ethylene interpolymer compositions, process for making the same and article made therefrom
CA2302173A1 (fr) 1997-09-19 1999-04-01 The Dow Chemical Company Activateur modifie de catalyseur d'alumoxane
CN1270611A (zh) 1997-09-19 2000-10-18 陶氏化学公司 组成上优化的窄分子量分布的乙烯共聚物组合物及其制备方法和所得制品
US6696379B1 (en) 1997-09-19 2004-02-24 The Dow Chemical Company Supported modified alumoxane catalyst activator
DE19744102A1 (de) 1997-10-06 1999-04-15 Targor Gmbh Katalysatorsystem
US6169151B1 (en) 1998-01-09 2001-01-02 The Board Of Trustees Of The Leland Stanford Junior University High-melting polyolefin copolymer elastomers, catalysts and methods of synthesis
US6380341B1 (en) 1998-01-09 2002-04-30 The Board Of Trustees Of Leland Stanford Jr. University Ethylene copolymers with narrow composition distribution and high melting temperatures, and methods of production thereof
JP4722287B2 (ja) 1998-02-20 2011-07-13 ダウ グローバル テクノロジーズ インコーポレーテッド 拡大したアニオンを含む触媒活性化剤
JP3385981B2 (ja) 1998-06-01 2003-03-10 日本電気株式会社 半導体装置及びその製造方法
CA2337024A1 (fr) 1998-08-11 2000-02-24 Peter N. Nickias Complexes d'aluminium et de metal du groupe 4 ansa bis (.mu.-substitues)
US6214760B1 (en) 1998-08-11 2001-04-10 The Dow Chemical Company Catalyst activator composition
DE69904088T2 (de) 1999-02-19 2003-10-09 Dow Global Technologies, Inc. Verfahren zur herstellung von trifluorarylaluminiumetheratverbindungen
CA2276282A1 (fr) * 1999-06-23 2000-12-23 Bayer Inc. Processus de polymerisation des olefines et systeme de catalyseur utilise a cette fin
US6825295B2 (en) 1999-12-10 2004-11-30 Dow Global Technologies Inc. Alkaryl-substituted group 4 metal complexes, catalysts and olefin polymerization process
US6444867B1 (en) 2001-05-17 2002-09-03 Bp Corporation North America Inc. Process for linear alpha olefins
WO2003010171A1 (fr) 2001-07-23 2003-02-06 Dow Global Technologies, Inc. Sel d'acide de lewis/d'adduits acides et activateurs de catalyseur correspondants
US6960635B2 (en) 2001-11-06 2005-11-01 Dow Global Technologies Inc. Isotactic propylene copolymers, their preparation and use
CA2483192A1 (fr) 2002-04-24 2003-11-06 Symyx Technologies, Inc. Ligands biaromatiques pontes, complexes, catalyseurs et procedes de polymerisation et polymeres obtenus
US7031450B2 (en) 2002-08-27 2006-04-18 Itxl Ip Holdings, S.A.R.L. Call routing system and method
AU2003259792A1 (en) 2002-09-12 2004-04-30 Dow Global Technologies Inc. Preparation of metal complexes
US7608668B2 (en) 2004-03-17 2009-10-27 Dow Global Technologies Inc. Ethylene/α-olefins block interpolymers
SG151302A1 (en) 2004-03-17 2009-04-30 Dow Global Technologies Inc Catalyst composition comprising shuttling agent for higher olefin multi- block copolymer formation
US7355089B2 (en) 2004-03-17 2008-04-08 Dow Global Technologies Inc. Compositions of ethylene/α-olefin multi-block interpolymer for elastic films and laminates
BRPI0508148B1 (pt) 2004-03-17 2015-09-01 Dow Global Technologies Inc Interpolímero de etileno em multibloco, derivado reticulado e composição”
US7858707B2 (en) * 2005-09-15 2010-12-28 Dow Global Technologies Inc. Catalytic olefin block copolymers via polymerizable shuttling agent
US8053529B2 (en) 2005-09-15 2011-11-08 Dow Global Technologies Llc Catalytic olefin block copolymers with controlled block sequence distribution
JP4973928B2 (ja) * 2007-03-26 2012-07-11 Ｄｉｃ株式会社 電子写真トナー用結晶性ポリエステル樹脂、電子写真トナー用樹脂組成物及び電子写真トナー
US8476393B2 (en) 2007-07-13 2013-07-02 Dow Global Technologies, Llc Ethylene/α-olefin interpolymers containing low crystallinity hard blocks
WO2011002000A1 (fr) * 2009-07-01 2011-01-06 三井化学株式会社 Composés organométalliques et leur procédé de préparation
KR101688253B1 (ko) * 2009-07-29 2016-12-20 다우 글로벌 테크놀로지스 엘엘씨 이중- 또는 다중-헤드 사슬 이동제 및 그의 블록 공중합체의 제조에서의 용도

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2007035493A2 (fr) * 2005-09-15 2007-03-29 Dow Global Technologies Inc. Regulation de l'architecture et de la distribution du poids moleculaire des polymeres par le biais d'un agent navette multicentre

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
DATABASE CA [online] CHEMICAL ABSTRACTS SERVICE, COLUMBUS, OHIO, US; FUJITA, KENICHI ET AL: "Zinc -containing dendrimers , their preparation, and their use as Lewis acids", XP002609165, retrieved from STN Database accession no. 2006:886134 *
ERDIK, ENDER ET AL: "Reactivities of mixed organozinc and mixed organocopper reagents, Part 2. Selective n-alkyl transfer in tri-n-butylphosphine-catalyzed acylation of n-alkylphenylzincs; an atom economic synthesis of n-alkyl aryl ketones Reactivities of mixed organozinc and mixed organocopper reagents, Part 2. Selecti", TETRAHEDRON LETTERS, vol. 50, no. 13, 2009, pages 1501 - 1503, XP025937000, ISSN: 0040-4039 *
KIM, YOUNG SEOK ET AL KIM, YOUNG SEOK ET AL: "Homogeneous decomposition mechanisms of diethylzinc by Raman spectroscopy and quantum chemical calculations Homogeneous decomposition mechanisms of diethylzinc by Raman spectroscopy and quantum chemical calculations", JOURNAL OF PHYSICAL CHEMISTRY A, vol. 112, no. 18, 2008, pages 4246 - 4253, XP002609164, ISSN: 1089-5639 *

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US20120165486A1 (en) 2012-06-28
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ES2858349T3 (es) 2021-09-30
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