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WO2010053264A3 - METHOD FOR PREPARING ELASTOMERIC COPOLYMERS OF ETHYLENE AND α-OLEFINS - Google Patents

METHOD FOR PREPARING ELASTOMERIC COPOLYMERS OF ETHYLENE AND α-OLEFINS Download PDF

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Publication number
WO2010053264A3
WO2010053264A3 PCT/KR2009/006024 KR2009006024W WO2010053264A3 WO 2010053264 A3 WO2010053264 A3 WO 2010053264A3 KR 2009006024 W KR2009006024 W KR 2009006024W WO 2010053264 A3 WO2010053264 A3 WO 2010053264A3
Authority
WO
WIPO (PCT)
Prior art keywords
ethylene
olefin
preparing
copolymers
catalyst
Prior art date
Application number
PCT/KR2009/006024
Other languages
French (fr)
Other versions
WO2010053264A2 (en
Inventor
Myungahn Ok
Daeho Shin
Seungbum Kwon
Jongsok Hahn
Hoseong Lee
Choonsik Shim
Hyeongtaek Ham
Jisu Jeong
Sungseok Chae
Original Assignee
Sk Energy Co., Ltd.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sk Energy Co., Ltd. filed Critical Sk Energy Co., Ltd.
Priority to EP09824947.7A priority Critical patent/EP2344552B1/en
Priority to JP2011534377A priority patent/JP2012507589A/en
Priority to CN2009801253480A priority patent/CN102083871A/en
Priority to ES09824947.7T priority patent/ES2684566T3/en
Priority to RU2010154457/04A priority patent/RU2512536C2/en
Priority to CA2728110A priority patent/CA2728110C/en
Publication of WO2010053264A2 publication Critical patent/WO2010053264A2/en
Publication of WO2010053264A3 publication Critical patent/WO2010053264A3/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/01—Processes of polymerisation characterised by special features of the polymerisation apparatus used
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2420/00—Metallocene catalysts
    • C08F2420/04—Cp or analog not bridged to a non-Cp X ancillary anionic donor
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

Provided is a process for preparing copolymers of ethylene with α-olefin. More specifically, provided are transition metal compound being useful as catalyst for preparing those copolymers, a catalyst composition comprising the same, and a process for preparing elastic copolymers of ethylene with α-olefin, having the density of not more than 0.910, which can be adopted to a wide variety of applications including film,, electric wires, and hot-melt adhesives. The catalyst composition is a catalytic system which comprises transition metal catalyst comprising a cyclopentadiene derivative and at least one anionic ligand(s) of aryloxy group with an aryl derivative at ortho-position, and boron or aluminum compound as an activator. Provided is a process for copolymerizing ethylene with α-olefin to produce copolymer having narrow molecular weight distribution and uniform density distribution with the density of not more than 0.910, with high activity and excellent reactivity on higher α-olefin.
PCT/KR2009/006024 2008-11-05 2009-10-19 METHOD FOR PREPARING ELASTOMERIC COPOLYMERS OF ETHYLENE AND α-OLEFINS WO2010053264A2 (en)

Priority Applications (6)

Application Number Priority Date Filing Date Title
EP09824947.7A EP2344552B1 (en) 2008-11-05 2009-10-19 Method for preparing elastomeric copolymers of ethylene and alpha-olefins
JP2011534377A JP2012507589A (en) 2008-11-05 2009-10-19 Method for producing an elastic copolymer of ethylene and α-olefin
CN2009801253480A CN102083871A (en) 2008-11-05 2009-10-19 Method for preparing elastomeric copolymers of ethylene and alpha-olefins
ES09824947.7T ES2684566T3 (en) 2008-11-05 2009-10-19 Process for the preparation of elastomeric copolymers of ethylene and alpha-olefins
RU2010154457/04A RU2512536C2 (en) 2008-11-05 2009-10-19 Method of obtaining elastic copolymers of ethylene and alpha-olefins
CA2728110A CA2728110C (en) 2008-11-05 2009-10-19 Method for preparing elastomeric copolymers of ethylene and .alpha.-olefins

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
KR20080109174 2008-11-05
KR10-2008-0109174 2008-11-05
KR1020090082288A KR101167082B1 (en) 2008-11-05 2009-09-02 Method for preparing elastomeric copolymers of ethylene and a-olefins
KR10-2009-0082288 2009-09-02

Publications (2)

Publication Number Publication Date
WO2010053264A2 WO2010053264A2 (en) 2010-05-14
WO2010053264A3 true WO2010053264A3 (en) 2010-07-29

Family

ID=42276532

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/KR2009/006024 WO2010053264A2 (en) 2008-11-05 2009-10-19 METHOD FOR PREPARING ELASTOMERIC COPOLYMERS OF ETHYLENE AND α-OLEFINS

Country Status (10)

Country Link
US (2) US8013086B2 (en)
EP (1) EP2344552B1 (en)
JP (1) JP2012507589A (en)
KR (2) KR101167082B1 (en)
CN (2) CN102083871A (en)
CA (1) CA2728110C (en)
ES (1) ES2684566T3 (en)
RU (1) RU2512536C2 (en)
TW (1) TWI476214B (en)
WO (1) WO2010053264A2 (en)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101454693B1 (en) * 2009-12-23 2014-11-06 에스케이이노베이션 주식회사 Process for producing an elastic copolymer of ethylene and an? -Olefin
KR101248421B1 (en) * 2010-07-15 2013-03-28 에스케이이노베이션 주식회사 Ethylene copolymer with improved elasticity and processibility
JP6992171B2 (en) * 2017-12-22 2022-01-13 エルジー・ケム・リミテッド Olefin polymer
US11732071B2 (en) 2018-05-04 2023-08-22 Lg Chem, Ltd. Olefin-based copolymer and method for preparing the same
CN111116783A (en) * 2018-10-31 2020-05-08 中国石油化工股份有限公司 Olefin polymer and preparation method thereof
WO2021197769A1 (en) * 2020-03-30 2021-10-07 Sabic Global Technologies B.V. Thermoplastic materials for use in slurry transportation pipes
CN115873046B (en) * 2021-09-29 2024-11-15 中化学科学技术研究有限公司 Metal complex, preparation method and application thereof
CN114989339A (en) * 2022-07-05 2022-09-02 宁夏清研高分子新材料有限公司 Method for improving regularity of TPX polymer
CN117986422A (en) * 2022-10-27 2024-05-07 中国石油化工股份有限公司 Ethylene/alpha olefin copolymer and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100639696B1 (en) * 2005-07-01 2006-10-30 에스케이 주식회사 Arylphenoxy Catalyst System for Making Ethylene Homopolymer or Copolymer with α-olefin
KR20070104845A (en) * 2006-04-24 2007-10-29 에스케이에너지 주식회사 Bis-arylaryloxy catalyst system for preparing ethylene homopolymer or copolymer with α-olefin
KR20080070989A (en) * 2007-01-29 2008-08-01 주식회사 엘지화학 Method for producing ultra low density polyolefin copolymer
KR20090095403A (en) * 2008-03-05 2009-09-09 에스케이에너지 주식회사 Ethylene copolymer film and a method of preparing the same

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4752597A (en) * 1985-12-12 1988-06-21 Exxon Chemical Patents Inc. New polymerization catalyst
JPS6392621A (en) 1986-10-08 1988-04-23 Mitsubishi Petrochem Co Ltd Manufacturing method of ethylene copolymer
US5198401A (en) 1987-01-30 1993-03-30 Exxon Chemical Patents Inc. Ionic metallocene catalyst compositions
US5055438A (en) 1989-09-13 1991-10-08 Exxon Chemical Patents, Inc. Olefin polymerization catalysts
DE3742934A1 (en) 1987-12-18 1989-06-29 Hoechst Ag METHOD FOR PRODUCING A CHIRAL, STEREORIGIDAL METALLOCEN COMPOUND
JPH0284405A (en) 1988-09-20 1990-03-26 Mitsubishi Petrochem Co Ltd Production method of ethylene polymer
GB8828206D0 (en) 1988-12-02 1989-01-05 Shell Int Research Process for conversion of hydrocarbonaceous feedstock
JP2926836B2 (en) 1989-02-22 1999-07-28 住友電気工業株式会社 Nitrogen-containing cermet alloy
NZ235032A (en) 1989-08-31 1993-04-28 Dow Chemical Co Constrained geometry complexes of titanium, zirconium or hafnium comprising a substituted cyclopentadiene ligand; use as olefin polymerisation catalyst component
DE69633569T2 (en) 1995-07-14 2005-10-13 Sumitomo Chemical Co. Ltd. TRANSITION METAL COMPLEX CONTAINING POLYMERIZATION CATALYST AND METHOD FOR PRODUCING OLEFIN POLYMERS
US5814714A (en) * 1995-11-30 1998-09-29 The Dow Chemical Company Mono-olefin/polyene interpolymers, method of preparation, compositions containing the same, and articles made thereof
CA2243783C (en) 1998-07-21 2007-06-05 Nova Chemicals Ltd. Bis-phosphinimine catalyst
EP1674490A1 (en) * 2004-12-23 2006-06-28 Borealis Technology Oy Copolymer
ES2509343T3 (en) * 2006-10-18 2014-10-17 Sk Innovation Co., Ltd. Arylphenoxy catalyst system for the production of ethylene homopolymers or co-polymers of ethylene and alpha-olefins

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100639696B1 (en) * 2005-07-01 2006-10-30 에스케이 주식회사 Arylphenoxy Catalyst System for Making Ethylene Homopolymer or Copolymer with α-olefin
KR20070104845A (en) * 2006-04-24 2007-10-29 에스케이에너지 주식회사 Bis-arylaryloxy catalyst system for preparing ethylene homopolymer or copolymer with α-olefin
KR20080070989A (en) * 2007-01-29 2008-08-01 주식회사 엘지화학 Method for producing ultra low density polyolefin copolymer
KR20090095403A (en) * 2008-03-05 2009-09-09 에스케이에너지 주식회사 Ethylene copolymer film and a method of preparing the same

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
KOTOHIRO NOMURA ET AL.: "Ethylene/Styrene Copolymerization by Various (Cyclo pentadienyl)(aryloxy)titanium(IV) Complexes-MAO Catalyst Systems", MACROMOLE CULES, vol. 35, 2002, pages 5388 - 5395, XP008139170 *

Also Published As

Publication number Publication date
CA2728110A1 (en) 2010-05-14
TW201026722A (en) 2010-07-16
ES2684566T3 (en) 2018-10-03
KR101470564B1 (en) 2014-12-10
RU2512536C2 (en) 2014-04-10
KR20120007087A (en) 2012-01-19
EP2344552A2 (en) 2011-07-20
EP2344552A4 (en) 2013-11-06
WO2010053264A2 (en) 2010-05-14
EP2344552B1 (en) 2018-08-01
US20100113720A1 (en) 2010-05-06
KR101167082B1 (en) 2012-07-20
KR20100050385A (en) 2010-05-13
CA2728110C (en) 2013-10-15
TWI476214B (en) 2015-03-11
CN107365398A (en) 2017-11-21
US20110282011A1 (en) 2011-11-17
JP2012507589A (en) 2012-03-29
RU2010154457A (en) 2012-07-10
US8013086B2 (en) 2011-09-06
CN102083871A (en) 2011-06-01

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