WO2009038125A1 - Pyrroline nitroxide polymer and battery using the same - Google Patents
Pyrroline nitroxide polymer and battery using the same Download PDFInfo
- Publication number
- WO2009038125A1 WO2009038125A1 PCT/JP2008/066855 JP2008066855W WO2009038125A1 WO 2009038125 A1 WO2009038125 A1 WO 2009038125A1 JP 2008066855 W JP2008066855 W JP 2008066855W WO 2009038125 A1 WO2009038125 A1 WO 2009038125A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- battery
- polymer
- pyrroline nitroxide
- same
- pyrroline
- Prior art date
Links
- -1 Pyrroline nitroxide Chemical class 0.000 title abstract 4
- 229920000642 polymer Polymers 0.000 title abstract 4
- 239000007772 electrode material Substances 0.000 abstract 3
- 230000000379 polymerizing effect Effects 0.000 abstract 1
Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/60—Selection of substances as active materials, active masses, active liquids of organic compounds
- H01M4/602—Polymers
- H01M4/606—Polymers containing aromatic main chain polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F234/00—Copolymers of cyclic compounds having no unsaturated aliphatic radicals in a side chain and having one or more carbon-to-carbon double bonds in a heterocyclic ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F34/00—Homopolymers and copolymers of cyclic compounds having no unsaturated aliphatic radicals in a side chain and having one or more carbon-to-carbon double bonds in a heterocyclic ring
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/137—Electrodes based on electro-active polymers
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
- H01M4/381—Alkaline or alkaline earth metals elements
- H01M4/382—Lithium
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/60—Selection of substances as active materials, active masses, active liquids of organic compounds
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/10—Primary casings; Jackets or wrappings
- H01M50/102—Primary casings; Jackets or wrappings characterised by their shape or physical structure
- H01M50/109—Primary casings; Jackets or wrappings characterised by their shape or physical structure of button or coin shape
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
- H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
- H01M4/583—Carbonaceous material, e.g. graphite-intercalation compounds or CFx
- H01M4/587—Carbonaceous material, e.g. graphite-intercalation compounds or CFx for inserting or intercalating light metals
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Materials Engineering (AREA)
- Engineering & Computer Science (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
Disclosed is a pyrroline nitroxide polymer which is used as an electrode material for a battery which is capable of outputting a large current, while being small in capacity decrease even when repeatedly charged/discharged. Also disclosed are an electrode active material containing such a polymer, and a battery using such an electrode active material. Specifically disclosed is a pyrroline nitroxide polymer which is obtained by polymerizing a pyrroline nitroxide compound represented by the following general formula (1). (In the formula, n is 0 or 1.)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2009533174A JP5424402B2 (en) | 2007-09-21 | 2008-09-18 | Pyrroline-based nitroxide polymer and battery using the same |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2007-245589 | 2007-09-21 | ||
JP2007245589 | 2007-09-21 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2009038125A1 true WO2009038125A1 (en) | 2009-03-26 |
Family
ID=40467935
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/JP2008/066855 WO2009038125A1 (en) | 2007-09-21 | 2008-09-18 | Pyrroline nitroxide polymer and battery using the same |
Country Status (2)
Country | Link |
---|---|
JP (1) | JP5424402B2 (en) |
WO (1) | WO2009038125A1 (en) |
Cited By (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2010285408A (en) * | 2009-06-15 | 2010-12-24 | Sumitomo Seika Chem Co Ltd | Method for producing 3-oxiranyl-2,2,5,5-tetramethylpyrrolin-1-oxyl |
WO2012133202A1 (en) * | 2011-03-31 | 2012-10-04 | 学校法人早稲田大学 | Radical composition and battery using same |
WO2012133204A1 (en) * | 2011-03-31 | 2012-10-04 | 学校法人早稲田大学 | Battery |
DE102014003300A1 (en) | 2014-03-07 | 2015-09-10 | Evonik Degussa Gmbh | New tetracyanoanthraquinone dimethyne polymers and their use |
DE102014004760A1 (en) | 2014-03-28 | 2015-10-01 | Evonik Degussa Gmbh | New 9,10-bis (1,3-dithiol-2-ylidene) -9,10-dihydroanthracene polymers and their use |
EP3136410A1 (en) | 2015-08-26 | 2017-03-01 | Evonik Degussa GmbH | Use of certain polymers as charge storage |
EP3135704A1 (en) | 2015-08-26 | 2017-03-01 | Evonik Degussa GmbH | Use of certain polymers as charge storage |
EP3279223A1 (en) | 2016-08-05 | 2018-02-07 | Evonik Degussa GmbH | Use of polymers containing thianthrene as charge storage |
WO2018024901A1 (en) | 2016-08-05 | 2018-02-08 | Evonik Degussa Gmbh | Use of thianthrene-containing polymers as a charge store |
WO2018046387A1 (en) | 2016-09-06 | 2018-03-15 | Evonik Degussa Gmbh | Method for the improved oxidation of secondary amine groups |
DE102017005924A1 (en) | 2017-06-23 | 2018-12-27 | Friedrich-Schiller-Universität Jena | Use of benzotriazinyl-containing polymers as charge storage |
US10756348B2 (en) | 2015-08-26 | 2020-08-25 | Evonik Operations Gmbh | Use of certain polymers as a charge store |
US10844145B2 (en) | 2016-06-02 | 2020-11-24 | Evonik Operations Gmbh | Method for producing an electrode material |
US10957907B2 (en) | 2015-08-26 | 2021-03-23 | Evonik Operations Gmbh | Use of certain polymers as a charge store |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2002151084A (en) * | 2000-02-25 | 2002-05-24 | Nec Corp | Secondary battery |
JP2002304996A (en) * | 2001-04-03 | 2002-10-18 | Nec Corp | Electric storage device |
JP2005097409A (en) * | 2003-09-24 | 2005-04-14 | Mitsubishi Gas Chem Co Inc | Method for producing polymer compound having stable radical |
-
2008
- 2008-09-18 WO PCT/JP2008/066855 patent/WO2009038125A1/en active Application Filing
- 2008-09-18 JP JP2009533174A patent/JP5424402B2/en not_active Expired - Fee Related
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2002151084A (en) * | 2000-02-25 | 2002-05-24 | Nec Corp | Secondary battery |
JP2002304996A (en) * | 2001-04-03 | 2002-10-18 | Nec Corp | Electric storage device |
JP2005097409A (en) * | 2003-09-24 | 2005-04-14 | Mitsubishi Gas Chem Co Inc | Method for producing polymer compound having stable radical |
Non-Patent Citations (2)
Title |
---|
KENICHI OYAIZU ET AL.: "Synthesis and Characterization of Radical-Bearing Polyethers as an Electrode-Active Material for Organic Secondary Batteries", MACROMOLECULES, vol. 41, no. 18, 19 August 2008 (2008-08-19), pages 6646 - 6652 * |
OZHOGINA OLGA A.: "Synthesis of bifunctionalized nitroxyls via intramolecular epoxide ring opening", TETRAHEDRON LETTERS, vol. 43, no. 4, 21 January 2002 (2002-01-21), pages 553 - 555 * |
Cited By (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2010285408A (en) * | 2009-06-15 | 2010-12-24 | Sumitomo Seika Chem Co Ltd | Method for producing 3-oxiranyl-2,2,5,5-tetramethylpyrrolin-1-oxyl |
US9356292B2 (en) | 2011-03-31 | 2016-05-31 | Sumitomo Seika Chemicals Co., Ltd. | Radical composition and battery using same |
WO2012133202A1 (en) * | 2011-03-31 | 2012-10-04 | 学校法人早稲田大学 | Radical composition and battery using same |
WO2012133204A1 (en) * | 2011-03-31 | 2012-10-04 | 学校法人早稲田大学 | Battery |
JP5969981B2 (en) * | 2011-03-31 | 2016-08-17 | 住友精化株式会社 | Radical composition and battery using the same |
DE102014003300A1 (en) | 2014-03-07 | 2015-09-10 | Evonik Degussa Gmbh | New tetracyanoanthraquinone dimethyne polymers and their use |
US9890230B2 (en) | 2014-03-07 | 2018-02-13 | Evonik Degussa Gmbh | Tetracyanoanthraquinodimethane polymers and use thereof |
DE102014004760A1 (en) | 2014-03-28 | 2015-10-01 | Evonik Degussa Gmbh | New 9,10-bis (1,3-dithiol-2-ylidene) -9,10-dihydroanthracene polymers and their use |
US10263280B2 (en) | 2014-03-28 | 2019-04-16 | Evonik Degussa Gmbh | 9,10-Bis(1,3-dithiol-2-ylidene)-9,10-dihydroanthracene polymers and use thereof |
EP3136410A1 (en) | 2015-08-26 | 2017-03-01 | Evonik Degussa GmbH | Use of certain polymers as charge storage |
EP3135704A1 (en) | 2015-08-26 | 2017-03-01 | Evonik Degussa GmbH | Use of certain polymers as charge storage |
US10957907B2 (en) | 2015-08-26 | 2021-03-23 | Evonik Operations Gmbh | Use of certain polymers as a charge store |
US10756348B2 (en) | 2015-08-26 | 2020-08-25 | Evonik Operations Gmbh | Use of certain polymers as a charge store |
US10844145B2 (en) | 2016-06-02 | 2020-11-24 | Evonik Operations Gmbh | Method for producing an electrode material |
WO2018024901A1 (en) | 2016-08-05 | 2018-02-08 | Evonik Degussa Gmbh | Use of thianthrene-containing polymers as a charge store |
US10608255B2 (en) | 2016-08-05 | 2020-03-31 | Evonik Operations Gmbh | Use of thianthrene-containing polymers as a charge store |
EP3279223A1 (en) | 2016-08-05 | 2018-02-07 | Evonik Degussa GmbH | Use of polymers containing thianthrene as charge storage |
WO2018046387A1 (en) | 2016-09-06 | 2018-03-15 | Evonik Degussa Gmbh | Method for the improved oxidation of secondary amine groups |
US11001659B1 (en) | 2016-09-06 | 2021-05-11 | Evonik Operations Gmbh | Method for the improved oxidation of secondary amine groups |
DE102017005924A1 (en) | 2017-06-23 | 2018-12-27 | Friedrich-Schiller-Universität Jena | Use of benzotriazinyl-containing polymers as charge storage |
Also Published As
Publication number | Publication date |
---|---|
JP5424402B2 (en) | 2014-02-26 |
JPWO2009038125A1 (en) | 2011-01-06 |
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