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WO2009038125A1 - Pyrroline nitroxide polymer and battery using the same - Google Patents

Pyrroline nitroxide polymer and battery using the same Download PDF

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Publication number
WO2009038125A1
WO2009038125A1 PCT/JP2008/066855 JP2008066855W WO2009038125A1 WO 2009038125 A1 WO2009038125 A1 WO 2009038125A1 JP 2008066855 W JP2008066855 W JP 2008066855W WO 2009038125 A1 WO2009038125 A1 WO 2009038125A1
Authority
WO
WIPO (PCT)
Prior art keywords
battery
polymer
pyrroline nitroxide
same
pyrroline
Prior art date
Application number
PCT/JP2008/066855
Other languages
French (fr)
Japanese (ja)
Inventor
Hiroyuki Nishide
Kenichi Oyaizu
Nobutaka Fujimoto
Yuji Kinpara
Shigeyuki Iwasa
Kentaro Nakahara
Original Assignee
Waseda University
Sumitomo Seika Chemicals Co., Ltd.
Nec Corporation
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Waseda University, Sumitomo Seika Chemicals Co., Ltd., Nec Corporation filed Critical Waseda University
Priority to JP2009533174A priority Critical patent/JP5424402B2/en
Publication of WO2009038125A1 publication Critical patent/WO2009038125A1/en

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Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/60—Selection of substances as active materials, active masses, active liquids of organic compounds
    • H01M4/602—Polymers
    • H01M4/606—Polymers containing aromatic main chain polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F234/00—Copolymers of cyclic compounds having no unsaturated aliphatic radicals in a side chain and having one or more carbon-to-carbon double bonds in a heterocyclic ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F34/00—Homopolymers and copolymers of cyclic compounds having no unsaturated aliphatic radicals in a side chain and having one or more carbon-to-carbon double bonds in a heterocyclic ring
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/137—Electrodes based on electro-active polymers
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
    • H01M4/381—Alkaline or alkaline earth metals elements
    • H01M4/382—Lithium
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/60—Selection of substances as active materials, active masses, active liquids of organic compounds
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/10—Primary casings; Jackets or wrappings
    • H01M50/102—Primary casings; Jackets or wrappings characterised by their shape or physical structure
    • H01M50/109—Primary casings; Jackets or wrappings characterised by their shape or physical structure of button or coin shape
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/583—Carbonaceous material, e.g. graphite-intercalation compounds or CFx
    • H01M4/587—Carbonaceous material, e.g. graphite-intercalation compounds or CFx for inserting or intercalating light metals
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

Disclosed is a pyrroline nitroxide polymer which is used as an electrode material for a battery which is capable of outputting a large current, while being small in capacity decrease even when repeatedly charged/discharged. Also disclosed are an electrode active material containing such a polymer, and a battery using such an electrode active material. Specifically disclosed is a pyrroline nitroxide polymer which is obtained by polymerizing a pyrroline nitroxide compound represented by the following general formula (1). (In the formula, n is 0 or 1.)
PCT/JP2008/066855 2007-09-21 2008-09-18 Pyrroline nitroxide polymer and battery using the same WO2009038125A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2009533174A JP5424402B2 (en) 2007-09-21 2008-09-18 Pyrroline-based nitroxide polymer and battery using the same

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2007-245589 2007-09-21
JP2007245589 2007-09-21

Publications (1)

Publication Number Publication Date
WO2009038125A1 true WO2009038125A1 (en) 2009-03-26

Family

ID=40467935

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2008/066855 WO2009038125A1 (en) 2007-09-21 2008-09-18 Pyrroline nitroxide polymer and battery using the same

Country Status (2)

Country Link
JP (1) JP5424402B2 (en)
WO (1) WO2009038125A1 (en)

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2010285408A (en) * 2009-06-15 2010-12-24 Sumitomo Seika Chem Co Ltd Method for producing 3-oxiranyl-2,2,5,5-tetramethylpyrrolin-1-oxyl
WO2012133202A1 (en) * 2011-03-31 2012-10-04 学校法人早稲田大学 Radical composition and battery using same
WO2012133204A1 (en) * 2011-03-31 2012-10-04 学校法人早稲田大学 Battery
DE102014003300A1 (en) 2014-03-07 2015-09-10 Evonik Degussa Gmbh New tetracyanoanthraquinone dimethyne polymers and their use
DE102014004760A1 (en) 2014-03-28 2015-10-01 Evonik Degussa Gmbh New 9,10-bis (1,3-dithiol-2-ylidene) -9,10-dihydroanthracene polymers and their use
EP3136410A1 (en) 2015-08-26 2017-03-01 Evonik Degussa GmbH Use of certain polymers as charge storage
EP3135704A1 (en) 2015-08-26 2017-03-01 Evonik Degussa GmbH Use of certain polymers as charge storage
EP3279223A1 (en) 2016-08-05 2018-02-07 Evonik Degussa GmbH Use of polymers containing thianthrene as charge storage
WO2018024901A1 (en) 2016-08-05 2018-02-08 Evonik Degussa Gmbh Use of thianthrene-containing polymers as a charge store
WO2018046387A1 (en) 2016-09-06 2018-03-15 Evonik Degussa Gmbh Method for the improved oxidation of secondary amine groups
DE102017005924A1 (en) 2017-06-23 2018-12-27 Friedrich-Schiller-Universität Jena Use of benzotriazinyl-containing polymers as charge storage
US10756348B2 (en) 2015-08-26 2020-08-25 Evonik Operations Gmbh Use of certain polymers as a charge store
US10844145B2 (en) 2016-06-02 2020-11-24 Evonik Operations Gmbh Method for producing an electrode material
US10957907B2 (en) 2015-08-26 2021-03-23 Evonik Operations Gmbh Use of certain polymers as a charge store

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002151084A (en) * 2000-02-25 2002-05-24 Nec Corp Secondary battery
JP2002304996A (en) * 2001-04-03 2002-10-18 Nec Corp Electric storage device
JP2005097409A (en) * 2003-09-24 2005-04-14 Mitsubishi Gas Chem Co Inc Method for producing polymer compound having stable radical

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002151084A (en) * 2000-02-25 2002-05-24 Nec Corp Secondary battery
JP2002304996A (en) * 2001-04-03 2002-10-18 Nec Corp Electric storage device
JP2005097409A (en) * 2003-09-24 2005-04-14 Mitsubishi Gas Chem Co Inc Method for producing polymer compound having stable radical

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
KENICHI OYAIZU ET AL.: "Synthesis and Characterization of Radical-Bearing Polyethers as an Electrode-Active Material for Organic Secondary Batteries", MACROMOLECULES, vol. 41, no. 18, 19 August 2008 (2008-08-19), pages 6646 - 6652 *
OZHOGINA OLGA A.: "Synthesis of bifunctionalized nitroxyls via intramolecular epoxide ring opening", TETRAHEDRON LETTERS, vol. 43, no. 4, 21 January 2002 (2002-01-21), pages 553 - 555 *

Cited By (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2010285408A (en) * 2009-06-15 2010-12-24 Sumitomo Seika Chem Co Ltd Method for producing 3-oxiranyl-2,2,5,5-tetramethylpyrrolin-1-oxyl
US9356292B2 (en) 2011-03-31 2016-05-31 Sumitomo Seika Chemicals Co., Ltd. Radical composition and battery using same
WO2012133202A1 (en) * 2011-03-31 2012-10-04 学校法人早稲田大学 Radical composition and battery using same
WO2012133204A1 (en) * 2011-03-31 2012-10-04 学校法人早稲田大学 Battery
JP5969981B2 (en) * 2011-03-31 2016-08-17 住友精化株式会社 Radical composition and battery using the same
DE102014003300A1 (en) 2014-03-07 2015-09-10 Evonik Degussa Gmbh New tetracyanoanthraquinone dimethyne polymers and their use
US9890230B2 (en) 2014-03-07 2018-02-13 Evonik Degussa Gmbh Tetracyanoanthraquinodimethane polymers and use thereof
DE102014004760A1 (en) 2014-03-28 2015-10-01 Evonik Degussa Gmbh New 9,10-bis (1,3-dithiol-2-ylidene) -9,10-dihydroanthracene polymers and their use
US10263280B2 (en) 2014-03-28 2019-04-16 Evonik Degussa Gmbh 9,10-Bis(1,3-dithiol-2-ylidene)-9,10-dihydroanthracene polymers and use thereof
EP3136410A1 (en) 2015-08-26 2017-03-01 Evonik Degussa GmbH Use of certain polymers as charge storage
EP3135704A1 (en) 2015-08-26 2017-03-01 Evonik Degussa GmbH Use of certain polymers as charge storage
US10957907B2 (en) 2015-08-26 2021-03-23 Evonik Operations Gmbh Use of certain polymers as a charge store
US10756348B2 (en) 2015-08-26 2020-08-25 Evonik Operations Gmbh Use of certain polymers as a charge store
US10844145B2 (en) 2016-06-02 2020-11-24 Evonik Operations Gmbh Method for producing an electrode material
WO2018024901A1 (en) 2016-08-05 2018-02-08 Evonik Degussa Gmbh Use of thianthrene-containing polymers as a charge store
US10608255B2 (en) 2016-08-05 2020-03-31 Evonik Operations Gmbh Use of thianthrene-containing polymers as a charge store
EP3279223A1 (en) 2016-08-05 2018-02-07 Evonik Degussa GmbH Use of polymers containing thianthrene as charge storage
WO2018046387A1 (en) 2016-09-06 2018-03-15 Evonik Degussa Gmbh Method for the improved oxidation of secondary amine groups
US11001659B1 (en) 2016-09-06 2021-05-11 Evonik Operations Gmbh Method for the improved oxidation of secondary amine groups
DE102017005924A1 (en) 2017-06-23 2018-12-27 Friedrich-Schiller-Universität Jena Use of benzotriazinyl-containing polymers as charge storage

Also Published As

Publication number Publication date
JP5424402B2 (en) 2014-02-26
JPWO2009038125A1 (en) 2011-01-06

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