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WO2009095849A3 - Deep purification technology of syngas and its first application in a coal-based oil pilot plant - Google Patents

Deep purification technology of syngas and its first application in a coal-based oil pilot plant Download PDF

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Publication number
WO2009095849A3
WO2009095849A3 PCT/IB2009/050320 IB2009050320W WO2009095849A3 WO 2009095849 A3 WO2009095849 A3 WO 2009095849A3 IB 2009050320 W IB2009050320 W IB 2009050320W WO 2009095849 A3 WO2009095849 A3 WO 2009095849A3
Authority
WO
WIPO (PCT)
Prior art keywords
syngas
ppm
oxygen
years
chlorine
Prior art date
Application number
PCT/IB2009/050320
Other languages
French (fr)
Other versions
WO2009095849A2 (en
Inventor
Yuhua Kong
Mailing Zhao
Hongjun Hu
Dianming Hu
Junming Chen
Xinhui Zhao
Xianhou Wang
Zhenrong Yu
Huilin Zheng
Lili Jia
Yulong Li
Xiaoding Li
Bing Xu
Yangang Huang
Lili Zhang
Qingjian Zhang
Original Assignee
Shaanxi Jin Chao Investment Corporation
Hubei Research Institute Of Chemistry
Shanghai Design Institute Of Chemical Industry
Van Der Walt, Louis, Stephanus
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shaanxi Jin Chao Investment Corporation, Hubei Research Institute Of Chemistry, Shanghai Design Institute Of Chemical Industry, Van Der Walt, Louis, Stephanus filed Critical Shaanxi Jin Chao Investment Corporation
Priority to AU2009208699A priority Critical patent/AU2009208699B8/en
Publication of WO2009095849A2 publication Critical patent/WO2009095849A2/en
Publication of WO2009095849A3 publication Critical patent/WO2009095849A3/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/50—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
    • C01B3/56—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by contacting with solids; Regeneration of used solids
    • C01B3/58—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by contacting with solids; Regeneration of used solids including a catalytic reaction
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0435—Catalytic purification
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0435—Catalytic purification
    • C01B2203/045—Purification by catalytic desulfurisation
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465—Composition of the impurity
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465—Composition of the impurity
    • C01B2203/0485—Composition of the impurity the impurity being a sulfur compound

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

A deep purification technology of syngas based on coal, coke, heavy oil, residual oil or natural gas. The syngas including 0.01 ~10ppm H2S + COS, 0.01 ~5ppm chlorine, 0.02~5ppm metal carbonyl compound, 1 ~5000ppm oxygen, 0.02~2ppm arsenic passes deep hydrolysis catalyst, deep fine desulfurizer, chlorine, Fe(CO)5 + Ni(CO)4, oxygen, arsenic-removal guard or purifying agent to remove H2S + COS to<0.01 ppm (i.e. 10ppb), chlorine to < 0.01 ppm (i.e. 10ppb), carbonyl compound to < 0.02ppm (i.e. 20ppb), oxygen to< 1 ppm, arsenic to<0.02ppm (i.e. 20ppb), to ensure the life of methanol synthesis catalyst can be prolonged from 2 years to 4-6 years, the life of F-T synthesis catalyst can be prolonged from 8-12 months to 2-3 years, the life of Pd, Pt, Rh, Au, Ag etc. catalysts producing acetic acid, anhydride acetic acid, butyl alcohol- octyl alcohol etc. can be prolonged considerably.
PCT/IB2009/050320 2008-02-03 2009-01-27 Deep purification technology of syngas and its first application in a coal-based oil pilot plant WO2009095849A2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AU2009208699A AU2009208699B8 (en) 2008-02-03 2009-01-27 Deep purification technology of syngas and its first application in a coal-based oil pilot plant

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN200810046867.5 2008-02-03
CN2008100468675A CN101224871B (en) 2008-02-03 2008-02-03 Deeply purifying method for synthetic gas

Publications (2)

Publication Number Publication Date
WO2009095849A2 WO2009095849A2 (en) 2009-08-06
WO2009095849A3 true WO2009095849A3 (en) 2009-12-10

Family

ID=39857112

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/IB2009/050320 WO2009095849A2 (en) 2008-02-03 2009-01-27 Deep purification technology of syngas and its first application in a coal-based oil pilot plant

Country Status (4)

Country Link
CN (1) CN101224871B (en)
AU (1) AU2009208699B8 (en)
WO (1) WO2009095849A2 (en)
ZA (1) ZA200900792B (en)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102219186B (en) * 2010-04-15 2012-11-14 中国石油化工股份有限公司 Removing method of carbonyl iron and carbonyl nickel in syngas
CN102259835B (en) 2011-06-20 2013-03-27 中国科学院广州能源研究所 Method for purifying and upgrading crude synthesis gas based on molten salt characteristics
CN102390807B (en) * 2011-08-10 2013-02-13 西南化工研究设计院 Copper series purifying agent and preparation method thereof
WO2013067287A1 (en) * 2011-11-03 2013-05-10 Fluor Technologies Corporation Conversion of organosulfur compounds to hydrogen sulfide in mixed alcohol synthesis reactor effluent
CN103372369A (en) * 2012-04-13 2013-10-30 中国石油化工股份有限公司 Method for removing trace impurities from synthesis gas and application of synthesis gas
CN103372364A (en) * 2012-04-13 2013-10-30 中国石油化工股份有限公司 Method for removing carbonyl metal compounds from synthesis gas
CN102814160A (en) * 2012-08-20 2012-12-12 西南化工研究设计院有限公司 Cleaning agent for removing iron carbonyl and nickel carbonyl in synthesis gas and preparation method and application of cleaning agent
CN103432896B (en) * 2013-08-23 2015-09-09 西南化工研究设计院有限公司 A kind of cleanser and Synthesis and applications thereof removing impurity oxygen in the reducibility gas such as synthesis gas
CN104624197B (en) * 2015-01-30 2017-01-25 武汉科林精细化工有限公司 A deoxidizing and desulfurizing double-functional fine desulfurizer and its preparation method
CN105776138A (en) * 2016-04-25 2016-07-20 张家港市华昌新材料科技有限公司 A method for syngas purification
CN110272021B (en) * 2018-03-13 2021-04-13 国家能源投资集团有限责任公司 Methanol catalyst protective agent and preparation method thereof
KR20210018932A (en) * 2018-06-12 2021-02-18 할도르 토프쉐 에이/에스 Methanol production process using low-iron catalyst
CN110052113A (en) * 2019-05-23 2019-07-26 河南开祥精细化工有限公司 A method of for reducing carbonyl nickel content in low pressure reaction tail gas
CN113562698A (en) * 2021-06-29 2021-10-29 湖北宜化化工股份有限公司 Raw material gas deoxidation and purification method
CN113999085B (en) * 2021-12-02 2023-12-22 西安元创化工科技股份有限公司 Deep purification method of hydrocarbon raw material

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0324526A1 (en) * 1988-01-13 1989-07-19 Comprimo B.V. Process for converting and removing sulfur compounds from a CO containing gas
WO2006008317A1 (en) * 2004-07-22 2006-01-26 Shell Internationale Research Maatschappij B.V. Process for the removal of cos from a synthesis gas stream comprising h2s and cos

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0324526A1 (en) * 1988-01-13 1989-07-19 Comprimo B.V. Process for converting and removing sulfur compounds from a CO containing gas
WO2006008317A1 (en) * 2004-07-22 2006-01-26 Shell Internationale Research Maatschappij B.V. Process for the removal of cos from a synthesis gas stream comprising h2s and cos

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
DEVULAPALLI VENU GOPAL ET AL: "Hydrogenation of acetophenone over bifunctional multimetal oxide catalysts", REACTION KINETICS AND CATALYSIS LETTERS, KLUWER ACADEMIC PUBLISHERS, DO, vol. 83, no. 1, 1 September 2004 (2004-09-01), pages 63 - 70, XP019265243, ISSN: 1588-2837 *
SAWICKI J A ET AL: "EXAFS and Mossbauer analysis of Pt-Ir catalysts", PHYSICA B. CONDENSED MATTER, AMSTERDAM, NL, vol. 158, no. 1-3, 1 June 1989 (1989-06-01), pages 203 - 205, XP024661544, ISSN: 0921-4526, [retrieved on 19890601] *

Also Published As

Publication number Publication date
AU2009208699B8 (en) 2014-09-11
AU2009208699A8 (en) 2014-09-11
CN101224871A (en) 2008-07-23
ZA200900792B (en) 2009-12-30
AU2009208699B2 (en) 2014-05-01
AU2009208699A1 (en) 2009-08-06
WO2009095849A2 (en) 2009-08-06
CN101224871B (en) 2011-02-16

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