WO2008125841A1 - Ironing aid composition - Google Patents
Ironing aid composition Download PDFInfo
- Publication number
- WO2008125841A1 WO2008125841A1 PCT/GB2008/001304 GB2008001304W WO2008125841A1 WO 2008125841 A1 WO2008125841 A1 WO 2008125841A1 GB 2008001304 W GB2008001304 W GB 2008001304W WO 2008125841 A1 WO2008125841 A1 WO 2008125841A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- silicone
- ironing aid
- ironing
- aid composition
- aid according
- Prior art date
Links
- 238000010409 ironing Methods 0.000 title claims abstract description 24
- 239000000203 mixture Substances 0.000 title claims abstract description 14
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 22
- 229920000642 polymer Polymers 0.000 claims abstract description 12
- 229920005646 polycarboxylate Polymers 0.000 claims abstract description 11
- 238000005406 washing Methods 0.000 claims abstract description 11
- 230000001153 anti-wrinkle effect Effects 0.000 claims abstract description 5
- 239000007788 liquid Substances 0.000 claims description 5
- 239000000243 solution Substances 0.000 claims description 4
- 235000013870 dimethyl polysiloxane Nutrition 0.000 claims description 3
- 239000000839 emulsion Substances 0.000 claims description 3
- 229940008099 dimethicone Drugs 0.000 claims description 2
- 239000004205 dimethyl polysiloxane Substances 0.000 claims description 2
- 229920002689 polyvinyl acetate Polymers 0.000 claims description 2
- 239000011118 polyvinyl acetate Substances 0.000 claims description 2
- 239000000725 suspension Substances 0.000 claims description 2
- 229920001577 copolymer Polymers 0.000 claims 1
- 229920006136 organohydrogenpolysiloxane Polymers 0.000 claims 1
- 239000003795 chemical substances by application Substances 0.000 description 9
- 239000004094 surface-active agent Substances 0.000 description 8
- 239000002518 antifoaming agent Substances 0.000 description 5
- -1 bleaches Substances 0.000 description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 239000003752 hydrotrope Substances 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 239000003205 fragrance Substances 0.000 description 3
- 239000007921 spray Substances 0.000 description 3
- 229920002472 Starch Polymers 0.000 description 2
- 125000002091 cationic group Chemical group 0.000 description 2
- RWGFKTVRMDUZSP-UHFFFAOYSA-N cumene Chemical compound CC(C)C1=CC=CC=C1 RWGFKTVRMDUZSP-UHFFFAOYSA-N 0.000 description 2
- 230000001627 detrimental effect Effects 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- 239000003112 inhibitor Substances 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 2
- 229920002545 silicone oil Polymers 0.000 description 2
- 238000004513 sizing Methods 0.000 description 2
- 235000019698 starch Nutrition 0.000 description 2
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- ZZXDRXVIRVJQBT-UHFFFAOYSA-M Xylenesulfonate Chemical compound CC1=CC=CC(S([O-])(=O)=O)=C1C ZZXDRXVIRVJQBT-UHFFFAOYSA-M 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 239000000443 aerosol Substances 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 235000019568 aromas Nutrition 0.000 description 1
- 150000005840 aryl radicals Chemical class 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 239000007844 bleaching agent Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 239000002274 desiccant Substances 0.000 description 1
- 239000000645 desinfectant Substances 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 239000000284 extract Substances 0.000 description 1
- 238000005562 fading Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 229920006158 high molecular weight polymer Polymers 0.000 description 1
- 125000001183 hydrocarbyl group Chemical group 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 235000000396 iron Nutrition 0.000 description 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000003605 opacifier Substances 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 230000002829 reductive effect Effects 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- QUCDWLYKDRVKMI-UHFFFAOYSA-M sodium;3,4-dimethylbenzenesulfonate Chemical compound [Na+].CC1=CC=C(S([O-])(=O)=O)C=C1C QUCDWLYKDRVKMI-UHFFFAOYSA-M 0.000 description 1
- 230000003019 stabilising effect Effects 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 125000000026 trimethylsilyl group Chemical group [H]C([H])([H])[Si]([*])(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 229940071104 xylenesulfonate Drugs 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/373—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/001—Softening compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3753—Polyvinylalcohol; Ethers or esters thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
Definitions
- This invention relates to an ironing aid composition which is suitable for adding directly into the wash liquor of a ware-washing machine.
- ironing aids on such washed and dried garments including spray compositions and liquid compositions (for inclusion in the steam chambers of the irons) , which include fragrances, has been found to have inherent problems concerning the application of measurable, controllable, effective and consistent quantities of freshening agent (e.g., fragrance and/or malodour maskant) to the garment .
- freshening agent e.g., fragrance and/or malodour maskant
- an ironing aid composition for use in a washing process in a ware washing machine comprising:
- the ironing aid is in the form of a liquid, such as a solution, suspension or emulsion.
- the ironing aid according to the present invention has been found to provide excellent properties. Indeed the ironing aid provides outstanding gliding properties (for the iron as it passes over the surface being ironed) and stiffness to the item being ironed.
- the silicone comprises a non-ionic silicone.
- non-ionic silicones have a more favourable interaction (than their ionic counterparts) with polycarboxylate polymers.
- non-ionic silicones do not cause detrimental precipitation of polycarboxylate polymers.
- the silicone comprises a liquid organohydro- genpolysiloxane of the formula below
- n is an integer greater than 1.
- n is equal to 20.
- the silicone comprises a divinyldimethicone / dimethicone copolymer
- Surfactants may need to be used to emulsify the silicone oils. Although surfactant (typically cationic or non- ionic) is important for stabilising the silicone emulsion, it is preferred to use the lowest level of surfactant possible. Preferred methods of emulsifying suitable silicone oils are disclosed in WO 01/07710 or US2003143176.
- the polycarboxylate polymer comprises a polyvinyl acetate.
- composition may also optionally contain up to 5% by weight of additional components of at least one of the following; antioxidants and reductive agents, bacterio- cides, natural or synthetic extracts, antifoam agents, desiccants, enzymes, bleaches, bleach activators, hydro- tropes, opacifiers, foam controllers, preservatives, disinfectants, pearlising agents) , optical brighteners, dye transfer inhibitors, colour fading inhibitors, and aesthetic ingredients, for example fragrances and colorants.
- antioxidants and reductive agents bacterio- cides, natural or synthetic extracts, antifoam agents, desiccants, enzymes, bleaches, bleach activators, hydro- tropes, opacifiers, foam controllers, preservatives, disinfectants, pearlising agents
- optical brighteners dye transfer inhibitors
- colour fading inhibitors for example fragrances and colorants.
- an antifoam agent may be necessary to avoid excess generation of foam during the rinse cycle. Preferably up to 5%wt, ideally less than 3%wt or 2%wt. Typically such agents are silicones.
- silicone antifoam agents can be described as siloxanes having the general structure: wherein n is from 20 to 2,000, and where each R independently can be an alkyl or an aryl radical. Examples of such substituents are methyl, ethyl, propyl, isobutyl, and phenyl.
- Preferred polydiorganosiloxanes are polydimethylsiloxanes having trimethylsilyl endblock- ing units.
- the antifoam agent of the typically further comprises as a water-soluble or water-dispersable organic carrier a surfactant-containing solution.
- the surfactant containing solution comprises a surfactant which can be selected from nonionic and/or anionic and/or cationic and/or ampholytic and/or zwitterionic and/or semi-polar surfactants.
- Hydrotropes aid in the solubility or dispersibility of different surfactants in aqueous solution. This usually has the side effect of lowering the viscosity of the resulting mixture.
- Suitable and preferred hydrotropes are the alkali metal salts of a benzene, cumene, toluene and xylene sulfonate, ideally the sodium salt.
- Hydroptopes may be added from 0.1 to 10% by weight, ideally no more that 5% by weight.
- an ironing aid composition comprising:
- the ware washing machine is an automatic clothes washing machine.
- Example 1 The invention is illustrated in the following non limiting examples, in which all percentages are on an active weight % basis unless otherwise stated.
- Example 1 The invention is illustrated in the following non limiting examples, in which all percentages are on an active weight % basis unless otherwise stated.
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Detergent Compositions (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Confectionery (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Gripping Jigs, Holding Jigs, And Positioning Jigs (AREA)
- Seeds, Soups, And Other Foods (AREA)
- Beans For Foods Or Fodder (AREA)
Abstract
An ironing aid composition for use in a washing process in a ware washing machine comprises (a) 3 to 10 wt.% of an anti-wrinkle silicone; and (b) 20 to 30 wt. % of a polycarboxylate polymer.
Description
IRONING AID COMPOSITION
This invention relates to an ironing aid composition which is suitable for adding directly into the wash liquor of a ware-washing machine.
Garments, when washed using harsh detergents or bleaches and subsequently dried, in many instances, evolve subtle undesirable aromas.
The use of ironing aids on such washed and dried garments, including spray compositions and liquid compositions (for inclusion in the steam chambers of the irons) , which include fragrances, has been found to have inherent problems concerning the application of measurable, controllable, effective and consistent quantities of freshening agent (e.g., fragrance and/or malodour maskant) to the garment .
Most of the ironing aids heretofore available are in the form of spray starches or sizing products offered in conventional aerosol or trigger spray delivery systems. Thus, for example, U.S. Letters Patent No. 4,238,057 discloses a spray-type sizing composition comprising a modified low viscosity starch and, to make the iron move smoothly during the ironing operation, a minor amount of dipropylene glycol is added. PCT Published Patent No. 91/19037 discloses the use of a silicone gel for ease of ironing and improvement in the appearance of ironed garments.
It is an object of the present invention to obviate / mitigate the disadvantages described above.
According to one aspect of the present invention, there is provided an ironing aid composition for use in a washing process in a ware washing machine comprising:
(a) 3 to 10 wt .% of an anti-wrinkle silicone; and
(b) 20 to 30 wt .% of a polycarboxylate polymer.
Generally the ironing aid is in the form of a liquid, such as a solution, suspension or emulsion.
The ironing aid according to the present invention has been found to provide excellent properties. Indeed the ironing aid provides outstanding gliding properties (for the iron as it passes over the surface being ironed) and stiffness to the item being ironed.
Without wishing to be bound by theory it is postulated that these two affects arise from the combination of the silicone and polycarboxylate polymer used. Indeed, as such the realisation of these two advantages is surprising: usually polycarboxylate polymers are recognised to detrimentally affect the gliding properties of an ironing aid and as such their presence in ironing aids is avoided. In the present invention this detrimental effect is not observed.
Preferably the silicone comprises a non-ionic silicone. In this regard it has been noted that non-ionic silicones have a more favourable interaction (than their ionic counterparts) with polycarboxylate polymers. In this regard non-ionic silicones do not cause detrimental precipitation of polycarboxylate polymers.
Preferably the silicone comprises a liquid organohydro- genpolysiloxane of the formula below
where n is an integer greater than 1.
Preferably n is equal to 20.
Preferably the silicone comprises a divinyldimethicone / dimethicone copolymer
Surfactants may need to be used to emulsify the silicone oils. Although surfactant (typically cationic or non- ionic) is important for stabilising the silicone emulsion, it is preferred to use the lowest level of surfactant possible. Preferred methods of emulsifying suitable silicone oils are disclosed in WO 01/07710 or US2003143176.
Most preferably the polycarboxylate polymer comprises a polyvinyl acetate.
It is recognised that the polymer provides a stiffening function to the ironing aid composition
Additional Components
The composition may also optionally contain up to 5% by weight of additional components of at least one of the following; antioxidants and reductive agents, bacterio- cides, natural or synthetic extracts, antifoam agents, desiccants, enzymes, bleaches, bleach activators, hydro- tropes, opacifiers, foam controllers, preservatives, disinfectants, pearlising agents) , optical brighteners, dye transfer inhibitors, colour fading inhibitors, and aesthetic ingredients, for example fragrances and colorants.
Antifoam Agent
The addition of an antifoam agent may be necessary to avoid excess generation of foam during the rinse cycle. Preferably up to 5%wt, ideally less than 3%wt or 2%wt. Typically such agents are silicones.
The term "silicone" has become a generic term which encompasses a variety of relatively high-molecular weight polymers containing siloxane units and hydrocarbyl groups of various types. Generally, the silicone antifoam agents can be described as siloxanes having the general structure: wherein n is from 20 to 2,000, and where each R independently can be an alkyl or an aryl radical. Examples of such substituents are methyl, ethyl, propyl, isobutyl, and phenyl. Preferred polydiorganosiloxanes are polydimethylsiloxanes having trimethylsilyl endblock- ing units.
The antifoam agent of the typically further comprises as a water-soluble or water-dispersable organic carrier a surfactant-containing solution.
The surfactant containing solution comprises a surfactant which can be selected from nonionic and/or anionic and/or cationic and/or ampholytic and/or zwitterionic and/or semi-polar surfactants.
Hydrotrope
Hydrotropes aid in the solubility or dispersibility of different surfactants in aqueous solution. This usually has the side effect of lowering the viscosity of the resulting mixture.
Examples of suitable and preferred hydrotropes are the alkali metal salts of a benzene, cumene, toluene and xylene sulfonate, ideally the sodium salt.
Hydroptopes may be added from 0.1 to 10% by weight, ideally no more that 5% by weight.
According to a second aspect of the invention there is provided the use of an ironing aid composition comprising:
(a) 3 to 10 wt .% of an anti-wrinkle silicone; and
(b) 20 to 30 wt .% of a polycarboxylate polymer.
in a ware washing machine.
Preferably the ware washing machine is an automatic clothes washing machine.
The invention is illustrated in the following non limiting examples, in which all percentages are on an active weight % basis unless otherwise stated.
Example 1
The formula below was prepared.
Claims
1. An ironing aid composition for use in a washing process in a ware washing machine comprising:
(a) 3 to 10 wt .% of an anti-wrinkle silicone; and
(b) 20 to 30 wt . % of a polycarboxylate polymer.
2. An ironing aid according to claim 1, wherein the ironing aid is in the form of a liquid, such as a solution, suspension or emulsion.
3. An ironing aid according to claim 1 or 2, wherein the silicone is a non-ionic silicone.
4. An ironing aid according to claim 3, wherein the silicone comprises a liquid organohydrogenpolysiloxane of the formula below
where n is an integer greater than 1, preferably n is equal to 20.
5. An ironing aid according to claim 3, wherein the silicone comprises silicone is a divinyldimethicone / dime- thicone copolymer
6. An ironing aid according to any one of claims 1 to 5, wherein the polycarboxylate polymer comprises a polyvinyl acetate .
7. The use of an ironing aid composition comprising:
(a) 3 to 10 wt .% of an anti-wrinkle silicone; and
(b) 20 to 30 wt. % of a polycarboxylate polymer,
in a ware washing machine.
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE602008004344T DE602008004344D1 (en) | 2007-04-13 | 2008-04-14 | BAR TOOLS |
| AT08736967T ATE494354T1 (en) | 2007-04-13 | 2008-04-14 | IRONING TOOLS |
| PL08736967T PL2155849T3 (en) | 2007-04-13 | 2008-04-14 | Ironing aid composition |
| EP08736967A EP2155849B1 (en) | 2007-04-13 | 2008-04-14 | Ironing aid composition |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB0707102.0 | 2007-04-13 | ||
| GBGB0707102.0A GB0707102D0 (en) | 2007-04-13 | 2007-04-13 | Composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO2008125841A1 true WO2008125841A1 (en) | 2008-10-23 |
Family
ID=38116636
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/GB2008/001304 WO2008125841A1 (en) | 2007-04-13 | 2008-04-14 | Ironing aid composition |
Country Status (7)
| Country | Link |
|---|---|
| EP (1) | EP2155849B1 (en) |
| AT (1) | ATE494354T1 (en) |
| DE (1) | DE602008004344D1 (en) |
| ES (1) | ES2357332T3 (en) |
| GB (1) | GB0707102D0 (en) |
| PL (1) | PL2155849T3 (en) |
| WO (1) | WO2008125841A1 (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2012036184A (en) * | 2010-08-09 | 2012-02-23 | Dow Global Technologies Llc | Composition containing 1,2-benzoisothiazolin-3-one |
| EP3275983A1 (en) * | 2016-07-25 | 2018-01-31 | Henkel AG & Co. KGaA | Polymers of vinylpyrrolidone and/or vinylacetate as textile care agents |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1999041346A1 (en) * | 1998-02-11 | 1999-08-19 | Rhodia Chimie | Dirt removing detergent compositions |
| US20030162689A1 (en) * | 2002-01-25 | 2003-08-28 | Tatiana Schymitzek | Conditioning preparation for fabric care |
| US20030195136A1 (en) * | 2002-04-03 | 2003-10-16 | Unilever Home & Personal Care Usa, Division Of Conopco, Inc. | Fabric care composition |
-
2007
- 2007-04-13 GB GBGB0707102.0A patent/GB0707102D0/en not_active Ceased
-
2008
- 2008-04-14 WO PCT/GB2008/001304 patent/WO2008125841A1/en active Application Filing
- 2008-04-14 EP EP08736967A patent/EP2155849B1/en not_active Not-in-force
- 2008-04-14 ES ES08736967T patent/ES2357332T3/en active Active
- 2008-04-14 DE DE602008004344T patent/DE602008004344D1/en active Active
- 2008-04-14 AT AT08736967T patent/ATE494354T1/en not_active IP Right Cessation
- 2008-04-14 PL PL08736967T patent/PL2155849T3/en unknown
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1999041346A1 (en) * | 1998-02-11 | 1999-08-19 | Rhodia Chimie | Dirt removing detergent compositions |
| US20030162689A1 (en) * | 2002-01-25 | 2003-08-28 | Tatiana Schymitzek | Conditioning preparation for fabric care |
| US20030195136A1 (en) * | 2002-04-03 | 2003-10-16 | Unilever Home & Personal Care Usa, Division Of Conopco, Inc. | Fabric care composition |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2012036184A (en) * | 2010-08-09 | 2012-02-23 | Dow Global Technologies Llc | Composition containing 1,2-benzoisothiazolin-3-one |
| EP3275983A1 (en) * | 2016-07-25 | 2018-01-31 | Henkel AG & Co. KGaA | Polymers of vinylpyrrolidone and/or vinylacetate as textile care agents |
Also Published As
| Publication number | Publication date |
|---|---|
| GB0707102D0 (en) | 2007-05-23 |
| ES2357332T3 (en) | 2011-04-25 |
| EP2155849A1 (en) | 2010-02-24 |
| DE602008004344D1 (en) | 2011-02-17 |
| EP2155849B1 (en) | 2011-01-05 |
| ATE494354T1 (en) | 2011-01-15 |
| PL2155849T3 (en) | 2011-06-30 |
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